The Effect of Aqueous Alteration and Metamorphism in the Survival of Presolar Silicate Grains in Chondrites
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Presolar Grains As Tracers of Nebular and Parent Body Process- Ing of Chondritic Material
Workshop on Parent-Body and Nebular Modification of Chondritic Materials 4019.pdf PRESOLAR GRAINS AS TRACERS OF NEBULAR AND PARENT BODY PROCESS- ING OF CHONDRITIC MATERIAL. Gary R. Huss, Lunatic Asylum of the Charles Arms Laboratory, Division of Geological and Planetary Sciences, 170-25, California Institute of Tech- nology, Pasadena, CA 91125 Presolar grains such as diamond, SiC, These observations show that a single wide- graphite, and Al2O3 are present in the least al- spread reservoir of presolar grains was sam- tered members of all chondrite classes [1,2]. pled by all chondrite classes. This reservoir is These grains reside in the fine-grained “matrix” most plausibly the dust from the solar system’s and did not experience the chondrule-forming parent molecular cloud. process. Because most types of presolar grains The CI chondrite, Orgueil, and the matrices are chemically unstable in putative nebular of CM2 chondrites have the highest matrix- conditions and in chondritic meteorites, they normalized abundances of silicon carbide, and serve as sensitive monitors of nebular and par- graphite; have among the highest diamond ent-body conditions. abundances; and have diamonds with high ni- Tracers of Metamorphism: Isotopic and trogen contents and the highest contents of P3 trace element characteristics of some presolar noble gases [1-4]. These characteristics indi- material and the abundances of presolar grains cate that CI chondrites and the matrices of in “matrix” are functions of the metamorphic CM2 chondrites contain the least processed history of the host meteorite [1–4]. Currently sample of the presolar-grains reservoir from recognized presolar grains show a range of the sun’s parent molecular cloud. -
Origin and Evolution of Carbonaceous Presolar Grains in Stellar Environments
Bernatowicz et al.: Origin and Evolution of Presolar Grains 109 Origin and Evolution of Carbonaceous Presolar Grains in Stellar Environments Thomas J. Bernatowicz Washington University Thomas K. Croat Washington University Tyrone L. Daulton Naval Research Laboratory Laboratory microanalyses of presolar grains provide direct information on the physical and chemical properties of solid condensates that form in the mass outflows from stars. This informa- tion can be used, in conjunction with kinetic models and equilibrium thermodynamics, to draw inferences about condensation sequences, formation intervals, pressures, and temperatures in circumstellar envelopes and in supernova ejecta. We review the results of detailed microana- lytical studies of the presolar graphite, presolar silicon carbide, and nanodiamonds found in primitive meteorites. We illustrate how these investigations, together with astronomical obser- vation and theoretical models, provide detailed information on grain formation and growth that could not be obtained by astronomical observation alone. 1. INTRODUCTION versed the interstellar medium (ISM) prior to their incorpor- ation into the solar nebula, they serve as monitors of physi- In recent years the laboratory study of presolar grains has cal and chemical processing of grains in the ISM (Bernato- emerged as a rich source of astronomical information about wicz et al., 2003). stardust, as well as about the physical and chemical condi- In this review we focus on carbonaceous presolar grains. tions of dust formation in circumstellar -
Origins of Life: Transition from Geochemistry to Biogeochemistry
December 2016 Volume 12, Number 6 ISSN 1811-5209 Origins of Life: Transition from Geochemistry to Biogeochemistry NITA SAHAI and HUSSEIN KADDOUR, Guest Editors Transition from Geochemistry to Biogeochemistry Staging Life: Warm Seltzer Ocean Incubating Life: Prebiotic Sources Foundation Stones to Life Prebiotic Metal-Organic Catalysts Protometabolism and Early Protocells pub_elements_oct16_1300&icpms_Mise en page 1 13-Sep-16 3:39 PM Page 1 Reproducibility High Resolution igh spatial H Resolution High mass The New Generation Ion Microprobe for Path-breaking Advances in Geoscience U-Pb dating in 91500 zircon, RF-plasma O- source Addressing the growing demand for small scale, high resolution, in situ isotopic measurements at high precision and productivity, CAMECA introduces the IMS 1300-HR³, successor of the internationally acclaimed IMS 1280-HR, and KLEORA which is derived from the IMS 1300-HR³ and is fully optimized for advanced U-Th-Pb mineral dating. • New high brightness RF-plasma ion source greatly improving spatial resolution, reproducibility and throughput • New automated sample loading system with motorized sample height adjustment, significantly increasing analysis precision, ease-of-use and productivity • New UV-light microscope for enhanced optical image resolution (developed by University of Wisconsin, USA) ... and more! Visit www.cameca.com or email [email protected] to request IMS 1300-HR³ and KLEORA product brochures. Laser-Ablation ICP-MS ~ now with CAMECA ~ The Attom ES provides speed and sensitivity optimized for the most demanding LA-ICP-MS applications. Corr. Pb 207-206 - U (238) Recent advances in laser ablation technology have improved signal 2SE error per sample - Pb (206) Combined samples 0.076121 +/- 0.002345 - Pb (207) to background ratios and washout times. -
Lifetimes of Interstellar Dust from Cosmic Ray Exposure Ages of Presolar Silicon Carbide
Lifetimes of interstellar dust from cosmic ray exposure ages of presolar silicon carbide Philipp R. Hecka,b,c,1, Jennika Greera,b,c, Levke Kööpa,b,c, Reto Trappitschd, Frank Gyngarde,f, Henner Busemanng, Colin Madeng, Janaína N. Ávilah, Andrew M. Davisa,b,c,i, and Rainer Wielerg aRobert A. Pritzker Center for Meteoritics and Polar Studies, The Field Museum of Natural History, Chicago, IL 60605; bChicago Center for Cosmochemistry, The University of Chicago, Chicago, IL 60637; cDepartment of the Geophysical Sciences, The University of Chicago, Chicago, IL 60637; dNuclear and Chemical Sciences Division, Lawrence Livermore National Laboratory, Livermore, CA 94550; ePhysics Department, Washington University, St. Louis, MO 63130; fCenter for NanoImaging, Harvard Medical School, Cambridge, MA 02139; gInstitute of Geochemistry and Petrology, ETH Zürich, 8092 Zürich, Switzerland; hResearch School of Earth Sciences, The Australian National University, Canberra, ACT 2601, Australia; and iEnrico Fermi Institute, The University of Chicago, Chicago, IL 60637 Edited by Mark H. Thiemens, University of California San Diego, La Jolla, CA, and approved December 17, 2019 (received for review March 15, 2019) We determined interstellar cosmic ray exposure ages of 40 large ago. These grains are identified as presolar by their large isotopic presolar silicon carbide grains extracted from the Murchison CM2 anomalies that exclude an origin in the Solar System (13, 14). meteorite. Our ages, based on cosmogenic Ne-21, range from 3.9 ± Presolar stardust grains are the oldest known solid samples 1.6 Ma to ∼3 ± 2 Ga before the start of the Solar System ∼4.6 Ga available for study in the laboratory, represent the small fraction ago. -
Brecciation and Chemical Heterogeneities of CI Chondrites
Geochimica et Cosmochimica Acta 70 (2006) 5371–5394 www.elsevier.com/locate/gca Brecciation and chemical heterogeneities of CI chondrites Andreas Morlok a,b,*, Addi Bischoff a, Thomas Stephan a, Christine Floss c, Ernst Zinner c, Elmar K. Jessberger a a Institut fu¨r Planetologie, Wilhelm-Klemm-Strasse 10, 48149 Mu¨nster, Germany b Department of Earth and Planetary Sciences, Faculty of Science, Kobe University, Kobe 657-8501, Japan c Laboratory for Space Sciences and Physics Department, Washington University, St. Louis, MO, USA Received 5 December 2005; accepted in revised form 3 August 2006 Abstract Fragments in the size range from 40 lm to several hundred lm in the CI chondrites Orgueil, Ivuna, Alais, and Tonk show a wide range of chemical compositions with variations in major elements such as iron (10.4–42.4 wt% FeO), silicon (12.7–42.2 wt% SiO2), and sulfur (1.01–15.8 wt% SO3), but also important minor elements such as phosphorous (up to 5.2 wt% P2O5) or calcium (up to 6.6 wt% CaO). These variations are the result of the varying mineralogical compositions of these fragments. The distribution of phyl- losilicates, magnetites, and possibly ferrihydrite, in particular, control the abundances of these elements. High REE contents—up to 150 times the solar abundances—were observed in phosphates, while matrix and sulfates are REE-depleted. The studied 113 fragments were subdivided into eight lithologies with similar mineralogical and thus chemical properties. The most common is the CGA lithology, consisting of a groundmass of Mg-rich, coarse-grained phyllosilicates and varying abundances of inclusions such as magnetite. -
Appendix A: Scientific Notation
Appendix A: Scientific Notation Since in astronomy we often have to deal with large numbers, writing a lot of zeros is not only cumbersome, but also inefficient and difficult to count. Scientists use the system of scientific notation, where the number of zeros is short handed to a superscript. For example, 10 has one zero and is written as 101 in scientific notation. Similarly, 100 is 102, 100 is 103. So we have: 103 equals a thousand, 106 equals a million, 109 is called a billion (U.S. usage), and 1012 a trillion. Now the U.S. federal government budget is in the trillions of dollars, ordinary people really cannot grasp the magnitude of the number. In the metric system, the prefix kilo- stands for 1,000, e.g., a kilogram. For a million, the prefix mega- is used, e.g. megaton (1,000,000 or 106 ton). A billion hertz (a unit of frequency) is gigahertz, although I have not heard of the use of a giga-meter. More rarely still is the use of tera (1012). For small numbers, the practice is similar. 0.1 is 10À1, 0.01 is 10À2, and 0.001 is 10À3. The prefix of milli- refers to 10À3, e.g. as in millimeter, whereas a micro- second is 10À6 ¼ 0.000001 s. It is now trendy to talk about nano-technology, which refers to solid-state device with sizes on the scale of 10À9 m, or about 10 times the size of an atom. With this kind of shorthand convenience, one can really go overboard. -
Book of Abstracts
THE PHYSICS AND CHEMISTRY OF THE INTERSTELLAR MEDIUM Celebrating the first 40 years of Alexander Tielens' contribution to Science Book of Abstracts Palais des Papes - Avignon - France 2-6 September 2019 CONFERENCE PROGRAM Monday 2 September 2019 Time Speaker 10:00 Registration 13:00 Registration & Welcome Coffee 13:30 Welcome Speech C. Ceccarelli Opening Talks 13:40 PhD years H. Habing 13:55 Xander Tielens and his contributions to understanding the D. Hollenbach ISM The Dust Life Cycle 14:20 Review: The dust cycle in galaxies: from stardust to planets R. Waters and back 14:55 The properties of silicates in the interstellar medium S. Zeegers 15:10 3D map of the dust distribution towards the Orion-Eridanus S. Kh. Rezaei superbubble with Gaia DR2 15:25 Invited Talk: Understanding interstellar dust from polariza- F. Boulanger tion observations 15:50 Coffee break 16:20 Review: The life cycle of dust in galaxies M. Meixner 16:55 Dust grain size distribution across the disc of spiral galaxies M. Relano 17:10 Investigating interstellar dust in local group galaxies with G. Clayton new UV extinction curves 17:25 Invited Talk: The PROduction of Dust In GalaxIES C. Kemper (PRODIGIES) 17:50 Unravelling dust nucleation in astrophysical media using a L. Decin self-consistent, non steady-state, non-equilibrium polymer nucleation model for AGB stellar winds 19:00 Dining Cocktail Tuesday 3 September 2019 08:15 Registration PDRs 09:00 Review: The atomic to molecular hydrogen transition: a E. Roueff major step in the understanding of PDRs 09:35 Invited Talk: The Orion Bar: from ALMA images to new J. -
Laboratory Astrophysics: from Observations to Interpretation
April 14th – 19th 2019 Jesus College Cambridge UK IAU Symposium 350 Laboratory Astrophysics: From Observations to Interpretation Poster design by: D. Benoit, A. Dawes, E. Sciamma-O’Brien & H. Fraser Scientific Organizing Committee: Local Organizing Committee: Farid Salama (Chair) ★ P. Barklem ★ H. Fraser ★ T. Henning H. Fraser (Chair) ★ D. Benoit ★ R Coster ★ A. Dawes ★ S. Gärtner ★ C. Joblin ★ S. Kwok ★ H. Linnartz ★ L. Mashonkina ★ T. Millar ★ D. Heard ★ S. Ioppolo ★ N. Mason ★ A. Meijer★ P. Rimmer ★ ★ O. Shalabiea★ G. Vidali ★ F. Wa n g ★ G. Del-Zanna E. Sciamma-O’Brien ★ F. Salama ★ C. Wa lsh ★ G. Del-Zanna For more information and to contact us: www.astrochemistry.org.uk/IAU_S350 [email protected] @iaus350labastro 2 Abstract Book Scheduley Sunday 14th April . Pg. 2 Monday 15th April . Pg. 3 Tuesday 16th April . Pg. 4 Wednesday 17th April . Pg. 5 Thursday 18th April . Pg. 6 Friday 19th April . Pg. 7 List of Posters . .Pg. 8 Abstracts of Talks . .Pg. 12 Abstracts of Posters . Pg. 83 yPlenary talks (40') are indicated with `P', review talks (30') with `R', and invited talks (15') with `I'. Schedule Sunday 14th April 14:00 - 17:00 REGISTRATION 18:00 - 19:00 WELCOME RECEPTION 19:30 DINNER BAR OPEN UNTIL 23:00 Back to Table of Contents 2 Monday 15th April 09:00 { 10:00 REGISTRATION 09:00 WELCOME by F. Salama (Chair of SOC) SESSION 1 CHAIR: F. Salama 09:15 E. van Dishoeck (P) Laboratory astrophysics: key to understanding the Universe From Diffuse Clouds to Protostars: Outstanding Questions about the Evolution of 10:00 A. -
The Early Geological History of the Moon Inferred from Ancient Lunar Meteorite Miller Range 13317
Meteoritics & Planetary Science 54, Nr 7, 1401–1430 (2019) doi: 10.1111/maps.13295 The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317 N. M. CURRAN 1,2,*, K. H. JOY1, J. F. SNAPE3, J. F. PERNET-FISHER1, J. D. GILMOUR 1, A. A. NEMCHIN4, M. J. WHITEHOUSE3, and R. BURGESS1 1School of Earth and Environmental Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, UK 2NASA Goddard Space Flight Center, 8800 Greenbelt Road, Greenbelt, Maryland 20771, USA 3Department of Geosciences, Swedish Museum of Natural History, SE-104 05 Stockholm, Sweden 4Department of Applied Geology, Curtin University, Perth, Western Australia 6845, Australia *Corresponding author. E-mail: [email protected] (Received 17 October 2018; revision accepted 14 March 2019) Abstract–Miller Range (MIL) 13317 is a heterogeneous basalt-bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 Æ 780 Ma and 1570 Æ 470 Ma where it experienced a complex near- surface irradiation history for ~835 Æ 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al2O3 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare-highland boundary that is KREEP-rich (i.e., K, rare earth elements, and P). -
Six Phases of Cosmic Chemistry
Six Phases of Cosmic Chemistry Lukasz Lamza The Pontifical University of John Paul II Department of Philosophy, Chair of Philosophy of Nature Kanonicza 9, Rm. 203 31-002 Kraków, Poland e-mail: [email protected] 1. Introduction The steady development of astrophysical and cosmological sciences has led to a growing appreciation of the continuity of cosmic history throughout which all known phenomena come to being. This also includes chemical phenomena and there are numerous theoretical attempts to rewrite chemistry as a “historical” science (Haken 1978; Earley 2004). It seems therefore vital to organize the immense volume of chemical data – from astrophysical nuclear chemistry to biochemistry of living cells – in a consistent and quantitative fashion, one that would help to appreciate the unfolding of chemical phenomena throughout cosmic time. Although numerous specialist reviews exist (e.g. Shaw 2006; Herbst 2001; Hazen et al. 2008) that illustrate the growing appreciation for cosmic chemical history, several issues still need to be solved. First of all, such works discuss only a given subset of cosmic chemistry (astrochemistry, chemistry of life etc.) using the usual tools and languages of these particular disciplines which does not facilitate drawing large-scale conclusions. Second, they discuss the history of chemical structures and not chemical processes – which implicitly leaves out half of the totality chemical phenomena as non-historical. While it may now seem obvious that certain chemical structures such as aromatic hydrocarbons or pyrazines have a certain cosmic “history”, it might cause more controversy to argue that chemical processes such as catalysis or polymerization also have their “histories”. -
Invited Review
INVITED REVIEW Presolar grains from meteorites: Remnants from the early times of the solar system Katharina Lodders a,* and Sachiko Amari b a Planetary Chemistry Laboratory, Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, Campus Box 1169, One Brookings Drive, St. Louis, MO 63130, USA b Department of Physics and McDonnell Center for the Space Sciences, Washington University, Campus Box 1105, One Brookings Drive, St. Louis, MO 63130, USA Received 5 October 2004; accepted 4 January 2005 Abstract This review provides an introduction to presolar grains – preserved stardust from the interstellar molecular cloud from which our solar system formed – found in primitive meteorites. We describe the search for the presolar components, the currently known presolar mineral populations, and the chemical and isotopic characteristics of the grains and dust-forming stars to identify the grains’ most probable stellar sources. Keywords: Presolar grains; Interstellar dust; Asymptotic giant branch (AGB) stars; Novae; Supernovae; Nucleosynthesis; Isotopic ratios; Meteorites 1. Introduction The history of our solar system started with the gravitational collapse of an interstellar molecular cloud laden with gas and dust supplied from dying stars. The dust from this cloud is the topic of this review. A small fraction of this dust escaped destruction during the many processes that occurred after molecular cloud collapse about 4.55 Ga ago. We define presolar grains as stardust that formed in stellar outflows or ejecta and remained intact throughout its journey into the solar system where it was preserved in meteorites. The survival and presence of genuine stardust in meteorites was not expected in the early years of meteorite studies. -
Nitrogen in Planetary Materials
CosmoELEMENTS NITROGEN IN PLANETARY MATERIALS Nitrogen forms a variety of compounds that are signifi cant in the inter- materials, resistant to dissolution in acids and solvents. Their survival in interstellar space, transport and processing in the protoplanetary stellar medium, star formation, planetary formation and the evolution disk and their distribution through asteroidal parent bodies make it of life. Through the study of planetary materials, we recognize three likely that presolar grains also survive alteration on the parent bodies generations of nitrogen and nitrogen-bearing compounds: primary, of primitive meteorites. secondary and tertiary. Species from different sources are recognized Organic Material: The interstellar medium is rich in organic mole- by characteristic isotopic compositions or specifi c modes of occurrence cules formed by several different processes, such as ion–molecule reac- tions on the surface of icy grains. The effect of such reactions is to (e.g. Grady and Wright 2003). increase the heavier isotope over the lighter one, producing material with characteristic isotopic signatures (e.g. Herbst 2003). Inventories PRIMARY NITROGEN of interstellar molecules (e.g. www.astro.uni-koeln.de/cdms/molecules) indicate that there are ~60 N-bearing species, most of which are organic Primary nitrogen is nitrogen that has been inherited directly from the in nature. As a result, a variety of N-bearing organic species are avail- molecular cloud from which the Solar System evolved. The isotopic able for incorporation into meteorite parent bodies, and these species composition of primary nitrogen refl ects the original source reservoirs may be subsequently altered during parent-body evolution. These inter- and is preserved in presolar grains, organic molecules and high-tem- stellar species include molecules (e.g.