Mercury Emission from the Aluminium Industry: a Review

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Mercury Emission from the Aluminium Industry: a Review MOJ Ecology & Environmental Sciences Mini Review Open Access Mercury emission from the aluminium industry: a review Abstract Volume 5 Issue 3 - 2020 There has been a rising global concern of mercury because of its persistent nature, long- KO Ansah Amano,1 AG Ntiri-Asiedu2 range transport and toxicity. Mercury possesses serious health effects on living organisms 1Department of Systems Engineering and Plant Safety, Institute and the environment. Mercury, mostly in inorganic form, is present in almost all categories of Instrumental and Environmental Technology, Otto von of rocks. It may be released through natural occurrences and/or anthropogenic activities Guericke Universität, Germany such as aluminum production. Stable organic mercury compounds, for example methyl 2Regional Centre for Energy and Environmental Sustainability, mercury (CH3Hg), are formed by the attachment of mercury to one or two carbon atoms. University of Energy and Natural Resources, Ghana Depending on the source of bauxite, a substantial amount of elemental mercury is released by aluminum industries. Emitted elemental mercury contributes to increasing global Correspondence: KO Ansah Amano, Otto von Guericke atmospheric reserve of mercury hence decreasing mercury emissions plays a key role in Universität, Institute of Instrumental and Environmental lowering the contribution of anthropogenic activities to the global atmospheric mercury Technology, Department of Systems Engineering and Plant budget. In general, all three forms of mercury (elemental, inorganic and organic mercury) Safety, 39106, Magdeburg, Germany, Tel +4915213037071, have the potential of causing adverse health effects at sufficiently high doses. Mercury Email emissions are readily absorbed through the alveoli membranes and gastrointestinal tract Received: May 14, 2020 | Published: June 19, 2020 affecting other systems. Fetuses and individuals often exposed to mercury (chronic exposure) are two classes of people who are more susceptible to harm caused by mercury. This paper discusses mercury metal and oxide emission from the Aluminum industry. Keywords: aluminum, anthropogenic activities, bauxite, bioaccumulation, metal mercury Introduction Possessing serious adverse effects on living organisms, and the environment, there has been a rise of global concern on the presence of mercury compounds. This is because of the persistent nature, long-range transport, and high toxicity of most mercury compounds.1 Mercury has a high potential of bioaccumulation through the air, food, and drinking water giving long term detrimental effects on the lungs, neurological, digestive and immune systems.2 Chemically, mercury exists in three forms namely elemental (or metallic, Hg0) mercury, inorganic mercury compounds, and organic mercury compounds. At room temperature, elemental mercury exists as a liquid and it is used in some thermometers, fluorescent light bulbs and various industrial processes. It is also used for dentistry and consists of about 50 % of amalgams.3 If metallic mercury is not enclosed at room temperature, some amount of it will evaporate to form mercury vapours. Mercury Figure 1 Chemical structure of some mercury compounds.4 vapours are colorless and odorless. Also, when mercury (Hg+, mercurous or mercury I, and Hg2+, mercuric or mercury II) combines Mercury is an atmospheric pollutant with a complex with elements such as chlorine, sulphur or oxygen, it produces biogeochemical cycle. The atmospheric cycling comprises chemical inorganic compounds in the form of salts.4 As shown in Figure 1, oxidation/reduction in both gaseous and aqueous states, deposition some of the salts produced from the combination of such elements are and release from natural surfaces as well as emissions from both 5 mercury sulphide (HgS, purified from cinnabar), mercurous chloride natural and anthropogenic sources. Even though mercury can be released through natural occurrences such as volcanic eruption (Hg2Cl2, also named as calomel), and mercuric chloride (HgCl2). Mercury, mostly in inorganic form, exists in all categories of rocks and weathering of rocks, a significant amount of studies show including bauxite, limestone, shales, sandstone, basalt, and others. that anthropogenic activities can initiate its dispersion into the Furthermore, stable organic metallic compounds such as methyl atmosphere, water and soil using complex transport and chemical transformation.6 Anthropogenic activities occurring in numerous mercury (CH3Hg), dimethyl mercury (CH3)2Hg) and ethyl mercury industrial processes such as Aluminium production, hazardous waste (C2H5Hg) are formed by the attachment of mercury to one or two carbon atoms. incineration, coal combustion, incineration, gold mining, and certain Submit Manuscript | http://medcraveonline.com MOJ Eco Environ Sci. 2020;5(3):129‒135. 129 ©2020 Amano et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and build upon your work non-commercially. Copyright: Mercury emission from the aluminium industry: a review ©2020 Amano et al. 130 chemical manufacturing operations, do increase mercury emission coal or oil and production of pig iron and steel.9 As shown in Table 1, into the environment.7 An estimate of approximately 2220 metric a study in 2005 indicates highest global emission of mercury occurs tons of mercury is emitted worldwide each year from anthropogenic from the combustion of fossil fuels followed by cement production sources.8 Studies indicate about 50–75% of atmospheric mercury is and production of non-ferrous metals such as aluminium.10 Additional released in the United States as a result of anthropogenic activities.5 studies by Pirrone et al signifies, China released a greater share of The principal source of mercury emissions in sectors involving the global atmospheric mercury emission between the periods of 2003- manufacture of non- ferrous metals including aluminium, cement, 2006 as shown in Table 2. Table 1 Global emission of mercury by-product from anthropogenic sources (tonnes)10 Mercury Non-ferrous Pig iron Caustic Stationary Cement Gold Production Waste Other Region metals and steel Soda Total combustion production production (Primary Incineration Sources production production Production sources) Africa 37.3 2.1 1.6 10.9 8.9 0 0.6 0.1 0 61.6 Asia (Excluding 622 90 24.1 138 58.9 8.8 5.7 28.7 0.6 977 Russia) Europe (Excluding 76.6 18.7 18.8 0 0 10.1 6.3 14.7 145 Russia) North 71.2 5.7 14.4 10.9 12.9 0 15.1 6.5 7.2 144 America Oceania 19 6.1 0.8 0.4 10.1 0 0 0.2 0 36.6 Russia 46 5.2 2.6 3.9 4.3 0 3.5 2.8 1.5 69.8 South 8 13.6 1.8 6.4 16.2 0 0 2.2 1.5 49.6 America World 880 141 45.4 189 111 8.8 35.5 46.8 25.5 1480 Table 2 Global emissions of total mercury from major anthropogenic sources (Mg .yr−1)7 Region SCa NFMP PISP CP CSP MP GP WD OP T Reference year Australia1 2.2 11.6 0.8 0.9 0 0 0.3 0.2 0.6 16.6 2005 S. Africa2 32.6 0.3 1.3 3.8 0 0 0.3 0.6 1.3 40.2 2004 S. America3 8 13.6 1.8 6.4 2.2 0 16.2 0 1.5 49.7 2005 Russia3 46 5.2 2.6 3.9 3.9 0 4.3 3.5 1.5 69.8 2005 Europe3 76.6 18.7 0 18.8 6.3 0 0 10.1 14.7 145.2 2005 N. America4 65.2 34.7 12.8 15.1 15.1 0 0 13 1.7 152.8 2005 India5 124.6 15.5 4.6 4.7 6.2 0 0.5 77.4 7.5 240.9 2004 China2 268 203.3 8.9 35 0 27.5 44.7 14.1 7.6 609.1 2003 Total 623.2 302.9 32.8 88.6 27.8 27.5 66.3 118.9 36.4 1324.3 Rest of the world6 186.8 7.1 10.4 147.1 135.1 22.5 333.7 68.5 28.2 989.4 2006 Total 810 310 43.2 235.7 162.9 50 400 187.4 64.6 2313.7 Mg, mega grams( 1 tonne); SC, stationary combustion; NFMP, non-ferrous metal production; PISP, pig iron and steel production; CP, cement production; CSP, caustic soda production; MP, mercury production; GP17, gold production; WD, waste disposal; OP, other processes; T, total References: (1)11; (2)12; (3)10, (4)13–15; (5)16; (6)17 Presently, mercury concentration in air has been identified to consequences.20 Aluminum production has been identified as a major be of the range 2-10ng/m3 with the level of mercury in drinking- source of mercury emission from non-ferrous process. This paper water found to be nearly equivalent to that of rain, with an average discusses mercury metal and oxide(s) emission from the Aluminium of approximately 25ng/L and the average ingestion of mercury from industry and its harmful effects. food is in the range 2–20μg/day.18 Interestingly, just about 7–15% of consumed mercury in food is absorbed into the human body.19 Mercury Mercury emission from aluminum industry emissions are readily absorbed through the alveoli membranes and Aluminum is known to be the third most abundant element in gastrointestinal tract affecting other systems. Exposure at maximum the earth’s crust.21 Due to the physical and chemical properties of contaminant level (MCL) for an extended period causes serious health aluminum it has found its application in transportation, construction, Citation: Amano KOA, Ntiri-Asiedu AG. Mercury emission from the aluminium industry: a review. MOJ Eco Environ Sci. 2020;5(3):129‒135. DOI: 10.15406/mojes.2020.05.00185 Copyright: Mercury emission from the aluminium industry: a review ©2020 Amano et al.
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