Emission Factors for the Disposal of Energetic Materials by Open Burning and Open Detonation (OB/OD)

Home , Calcium stearate, Dioctyl adipate, Neopentane

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EPA/600/R-98/103

William J. Mitchell and Jack C. Suggs US Environmental Protection Agency, MD-46 Research Triangle Park, NC 27711

AUGUST 1998

This emission factor database was created using data collected by the U.S. Department of Defense

000959 Contents

Page No. Disclaimer ...... iii

Abstract ...... iv

Tables ...... • .... . v

Listing of Abbreviations and Definitions of Terms ...... vi

Acknowledgments ...... · ...... viii

Executive Surrnnary ...... 1

Chapter 1 Introduction...... 4

Chapter 2 Methods and Materials ...... 14

Chapter 3 Construction and Validation of the Database . . . 21

Chapter 4 Overview o.f the Validated Database 29

Chapter 5. Discussion of Results for Open Detonations 30

Chapter 6. Discussion of Results for Water-Suppressed Detonations ...... 37

Chapter 7 Discussion of Results from Burns ...... 40

Chapter 8 Guidance on Using the Database: ...... 45

Chapter 9 Recommendations for Future Work ...... 47

References 49

Appendices

A. Detailed Descriptions of the Energetic Materials ... 50

B. Sampling and Analysis Methodologies Used ...... 62

c. Target Analytes ...... 65

D. Emission Factors for Burns ...... 68

E. Emission Factors for Detonations ...... 87

000960 Disclaimer

The U.S. Environmental Protection Agency through its Office of research and development funded the data analysis and validation study described in this report. It has been subjected to the agency's peer and administrative review and has been approved for publication as an EPA document.

iii

000961 Abstract

This report contains a validated database of pollutant emission factors applicable to the disposal of energetic-containing materials through open-air burning (in burn pans) and unconfined detonation processes (OB/OD). The emission factors in the database were compiled using data from studies, which measured the quantities of particles, semivolatile organic compounds, polychlorinated dibenzo-p-dioxins and furans, toxic metals, volatile organic compounds, and inorganic gases released when 0.22 kg of energetic materials were detonated and 2.2 kg of these materials were burned in 930 m3 chambers, called BangBoxes. Air samples from the chamber were analyzed for over 275 analytes. The actions taken in validating the database are also described along with the minimum quantification limits for each pollutant measurement system. Summary statistics were calculated and compared to the results from smaller (0.02 kg)and larger (250-3,200 kg) scale detonations and burns of energetic materials. These comparisons confirm and expand upon results from earlier studies which determined that emission factors derived from chamber-based results can be used to predict the emission products that would be released from much larger scale detonations and burns, that is, the results are scalable. These comparisons also indicate that OB- and OD-based processes can be environmentally friendly ways to dispose of many of the energetic materials in the demil inventories of the world.

000962 Tables Page No.

1-1. Distribution of Carbon in Emission Products from Detonating TNT in Different Atmospheres ...... 12

1-2. Heats of reaction (kcal/mol) for Selected Gas Phase Reactions at 1 Atmosphere ...... 13

2-1. Energetic Materials Burned and Detonated in the BangBoxes ...... 16

2-2. Weights (grams) of Energetic Materials in Items Detonated ...... 18

2-3. Weights (grams) of Energetic Materials in Items Burned ...... 19

2-4. Sampling Systems Used in Each Study 20

3-1. Representative MQL Emission Factors (kg Analyte/kg MEM) ...... 28

5-1. Mean Emission Factors (kg Analyte/kg MEM) for Selected Analytes for Detonations ...... 33

5-2. % Recoveries of C and N as the Oxides for Detonations ...... 34

5-3. Emission Factor Averages Across Categories for Detonations ...... 34

5-4. Mean Emission Factors (kg Analyte/kg C in Energetic) for Selected Analytes for Detonations ...... 35

5-5. Original and Adjusted Emission Factors for PETN and RDX ...... 3 6

6-1. Comparison of Emission Factors for Unsuppressed and Water-Suppressed Detonations ...... 38

6-2. Distribution of C and N Across Selected Analyte Classes for Tritonal and Arnatol Detonations ...... 39

7-1. Mean Emission Factors (kg. Analyte/kg. MEM) for Selected Analytes for Burns ...... 43

7-2. % Recoveries of C and N as the Oxides for Burns ...... 44

7-3. Emission Factor Averages Across Categories for Burns . 44

000963 List Of Abbreviations And Terms

Abbreviations

DPG: Dugway Proving Ground, UT

LLNL: Lawrence Livermore National Laboratories

SNL: Sandia National laboratories

Definition of Terms

Blast effect: the high pressure generated by the explosion.

Brisance: the ability of an explosive to provide shock waves to shatter the target. After shattering the target, the shock wave can continue moving through the target. In this respect, brisance differs from blast effect. The blast itself can not transmit the energy through solid material without moving the target, but shock waves can.

Composite Explosive: A solid propellant comprised of an oxidizer (e.g., ammonium perchlorate) and a metallic fuel (e.g., aluminum powder) held together by a polymeric substance (e.g., polybutadiene).

Double-base Propellant: A solid propellant comprised of nitrocellulose (NC) and nitroglycerin (NG).

Emission Factor: The mass of an analyte released by a detonation or burn normalized to the energetic mass of the material (MEM) detonated. In the database, the emission factors are in terms of Kg analyte/kg MEM.

Encapsulated Energetic: An assembled energetic-containing material, such as a mine or a fuze.

Energetic: A substance, either a pure compound or a mixture of compounds, capable of undergoing a very rapid chemical change, releasing large quantities of heat and large volumes of hot gases. Includes high explosives, low explosives (propellants and pyrotechnics), incendiaries, fuse powders and thermites.

Explosive: A chemical compound or mixture which, when subjected to heat, impact, friction, shock or other suitable stimulous, undergoes a very rapidchemical reaction with the evolution of large volumes of heated gases that exert high pressures in the surrounding medium. Explosives are a subset of energetics, excluding those which do not produce large volumes of hot gases (e.g., incendiaries, fuse powders and thermi tes) .

High Explosive: An energetic material in which the decomposition process (detonation) proceeds through the entire material at

000964 supersonic speed. The rate at which the decomposition process passes through the explosive is determined by the velocity of the shock wave. TNT, RDX and PETN are examples of high explosives.

Low Explosive: An energetic material in which the decomposition process (deflagration) occurs at subsonic speed. The decomposition occurs on the surface of the explosive only; there is no shock wave. Propellants and pyrotechnics are examples of low explosives.

Single -base Propellant: A solid propellant containing only nitrocellulose (NC) as the primary energetic material.

Target Analytes: The chemical species sought in the emissions from the detonations and burns, e.g., Pb, Al, acetylene. The target analytes are identified in Appendix C.

Triple-base Propellants: A solid propellant comprised of nitrocellulose (NC), nitroglycerin (NG) and nitroguanidine (NQ).

Vll

000965 Acknowledgments

This database of emission factors was constructed from seven studies funded by the U.S. Department of Defense (DOD). The authors wish to acknowledge the support, cooperation and encouragement they received from Mr. MacDonald Johnson (retired) and Mr. Casey Wilcox (retired), the project officers at Dugway proving ground, UT for the seven studies. We want to particularly acknowledge the substantial contribution of Mr. Johnson, the project officer for the first five studies. It was Mr. Johnson's vision, personal integrity and personal sacrifice which brought about the DOD emission factor development program and which established its credibility with the regulatory community. It is regrettable that his health prevented him from completing the program and receiving the recognition he deserves for his significant contributions towards solving the demilitarization problem.

The authors also wish to acknowledge the contributions of the following individuals for their suggestions on ways to improve the readability of the document; Mr. R. J. Black of Dugway Proving Ground, UT: Mr Thomas E. Ward and Mr Jeff Gaines of the U.S. Environmental Protection Agency, Research Triangle Park, NC and Washington DC, respectively; Mr. Robert O'Brien of Brooks AFB; Dr. Charles Lind of the U.S. Naval Research Laboratory, Washington DC and Mr. Ed Patterson of the Department of Energy's Pantex Plant, Amarillo, TX.

viii

000966 Executive Summary

A database of emission factors applicable to the open burning (in burn pans, OB) and open detonation (OD) practices routinely used to destroy surplus or unserviceable energetic materials has been constructed and validated using emissions data from 16 energetic materials which were burned and 23 materials which were detonated in a 930 m3 chamber called a BangBox. Both high and low explosives in bulk and assembled (encapsulated) form were detonated, but only low explosives in bulk and encapsulated forms were burned.

The database also contains emission factors from the burning of two surrogate materials, dunnage and an energetic-containing waste. The waste simulated one that would result from cleaning the processing equipment after an aluminized ammonium perchlorate (Al-AP) waste had been manufactured. The burns of these surrogate materials were initiated with diesel fuel.

A comparison of the emission factors in the database to those generated in other chamber studies and in large scale, unconfined field tests showed that all test results conformed to detonation theory. This finding indicates strongly that it should be possible to classify energetic materials into broad categories for the purpose of predicting the emission products and confirmed that chambers can be used to derive emission factors for use in predicting the emissions from unconfined detonations and burns.

Significant findings from these comparisons follow.

Findings Applicable To Both OB and OD (1) Unconfined detonations, lightly-confined detonations and burns yield similar emission products, but the mix of products is different. If the energetic materials do not contain toxic metals, chlorine, plastic, wood or diesel fuel, the emission products will be C02 , H20 and N2 along with small quantities of NOx and light hydrocarbons. Consistent with detonation theory, molecules larger than the starting molecules are not formed, even when the detonation is partially confined.

(2) The following four parameters are statistically the same across all the items detonated and burned in an unconfined state: %C as COx, %CO/COX, %N as NOx, and %NO/N0x.

(3) The emission products from most energetic materials destroyed by OB and OD processes will be adequately represented by the following analytes: C02 , CO, NO, N02 , total saturated hydrocarbons (e.g., ethane, propane, butane), acetylene, ethylene, propene, benzene, toluene, and particulate.

(4) Low recoveries of aluminum, lead, sulfur and chlorine were common across all detonation and burn studies used in these comparisons. In all studies 98 to 99% of the chlorine recovered was

000967 determined to be HCl. The high reactivity of chlorine is a likely explanation for the low recoveries. The reasons for the low recoveries for sulfur and the metals still need to be determined to more fully characterize the environmental safety of OB and OD practices.

(5) Because most of the emission products from OB and OD operations are all species commonly found in the environment, it is particularly difficult to correct for contamination of metals and semi-volatile organic compounds (SVOCs)released from the walls of the chamber or the soil by the blast wave or the rapid movement of heated air. To compensate for the sample contamination from these sources when measuring the emission products from OB and OD activities, background samples should be collected by sampling the emissions from burning or detonating a material that would not be expected to release SVOC's or metals, e.g., detonation cord and nitrocellulose.

Findings Applicable to OD Only (1) For the unconfined detonations, the median % recovery of carbon as carbon oxides (C02 +CO) was 98.5%; only 1.6% of the carbon was recovered as CO. The median % recovery of nitrogen as NOx was 1.2%. The remaining nitrogen was likely converted to N2 in conformance with detonation theory and the results from large scale detonations conducted in the tunnels at the Nevada Test Site.

(2) Detonation-based processes can be an environmentally-safe way to dispose of bulk energetic materials, particularly for those which have been recovered from assembled munitions and for which there is no commercial or military use. This is especially applicable when: (1) the detonation occurs in an unconfined or lightly-confined state; (2) the detonation goes high order; (3) the soil particles released to the atmosphere are not hazardous in their own right; and (4) the toxic metals in the energetic materials are either at concentrations low enough not to endanger the health of humans or ecosystems or, their release to the environment can be kept below these levels. Coupling OB with phytoremediation techniques could be particularly rewarding in terms of protecting human health and the environment in both the short term and long term.

(3) It is also possible that many assembled munitions could be destroyed in an environmentally safe manner using detonation-based processes, provided research can provide a better understanding on how the following variables affect the emission products: donor charge placement, stacking geometry, mass of energetic material, degree of blast confinement and the type of casing.

(4) Compared to an unconfined detonation of the same material, detonating an energetic under a soil cover (buried detonation) , or under other conditions which inhibit the formation of a fireball, will

cause a decrease in C0 2 and an increase in soot (free carbon), CO, light saturated hydrocarbons, acetylene, ethylene, propene, benzene and toluene. It will very likely also increase the quantities of

000968 undegraded or partially degraded energetic starting materials. Placing an oxygen source next to a buried energetic material will not automatically ensure that detonation will convert all the carbon in the energetic to carbon oxides.

(5) Buried detonations should be avoided whenever possible. For those situations where OB is not acceptable and blast noise control is needed, numerous, small scale detonations in chambers should be considered as an alternate to buried detonations.

Findings Applicable to OB Only

(1) The median % recovery of carbon as carbon oxides (C02 + CO} from the materials burned was 98.5%; only 0.2% of the carbon was recovered as CO. The median% recovery of nitrogen as NOx was 0.9%. The remaining nitrogen was likely converted to N2 in conformance with detonation theory and the results from large scale detonations conducted in the tunnels at the Nevada Test Site.

(2) Open burning is an environmentally-safe means to dispose of single, double and triple base (organic-based) propellants when the propellants do not contain significant amounts of other combustible materials, such as diesel fuel, wood and chlorinated plastics or toxic metals. OB may be particularly appropriate for destroying energetic materials which result from stearnout, water jet cutting and other demilitarization processes. Coupling OB with phytoremediation techniques could be particularly rewarding in terms of protecting human health and the environment in both the short term and long term.

(3) Open burning may also be appropriate for energetic materials containing AP, if the HCl and any metals in the energetic released could be prevented from entering the environment in quantities which could endanger the health of humans or ecosystems. Pollution control technologies that could accomplish this are available, although their suitability for this application needs to be established.

(4) Burning energetics containing plastics and chlorine in the presence of diesel fuel and wood may produce dioxins and furans.

000969 Chapter 1 Introduction

U.S. EPA Regulations For the Disposal of Energetic Materials During the Cold War, the United States of America, its allies and the former Soviet Union accumulated over 9,000,000 tons of energetic materials. With the ending of the Cold War, the United States, as well as these other countries, are now faced with disposing of large inventories of these materials in an environmentally sound manner. For example, in 1997, the U.S. Department of Defense (DoD) had 450,000 tons in its "demil inventory" and the inventory has been increasing by 40,000 to 50,000 tons per year.

The four methods commonly used to dispose of unneeded energetic materials are: (1) incineration; (2) disassembly, recovery and recycling (DRC); (3) burning in pans in an open area (OB); and (4) detonating either at ground level (OD) or under a soil cover (buried OD).

Although incineration and DRC are the environmentally-preferred methods of disposal, for the following reasons, they are not suitable for disposing of many of the items already in the demil inventory or likely to enter the inventory in the near future. First, the composition of many of the materials is either unknown, unstable, obsolete or has degraded. Second, the materials cannot be safely disassembled. Third, the financial and environmental expense of developing a recovery and reuse technology for them cannot be justified based on the quantity in the demil inventory or the commercial value of the material that would be recovered. For these materials, OB and OD are the only disposal techniques currently available and, thus, they continue to be an integral part of this nation's demil progrcµns.

In the U.S., as elsewhere, there are concerns about the impact of OB and OD-based practices on human health and the environment. In the U.S., the disposal of energetic materials by OB and OD has been regulated under the Resource Conservation and Recovery Act (Subpart X 1 of 40CFR264) , since 1984. One of the major concerns is the degree to which the energetic and its associated packing or containment materials are converted to innocuous chemicals. Other concerns relate to the toxicities and dispersion in the environment of the ash, soil and chemical pollutants released and the impact of the blast waves and sound waves released.

Because of these concerns the Subpart X permits that have been issued are very restrictive in terms of the conditions under which OB and OD can be carried out and the quantities that can be destroyed at one time, and over selected periods. To obtain a Subpart X permit, a facility must, at a minimum, provide the following information to the regulatory agency. First, the identity and quantities of pollutants and debris that will be released per event and over time. Second, the

000970 intensity of the blast waves and sound waves that will be generated. Third, a description of how these pollutants, debris, blast waves and sound waves will be distributed in the environment. Fourth, the degree to which the health of humans and the environment may be endangered in the short term (event basis) and over the lifetime of the OB and OD program.

The Detonation Process Explosives are the class of energetic materials normally disposed of by OB and OD procedures. Explosives fall into two general classes: high and low2 • High explosives are energetic materials in which the decomposition process (detonation) proceeds through the entire material at supersonic speed. The rate at which the decomposition process passes through the explosive is determined by the velocity of the shock wave and not by the rate of heat transfer. Low explosives (propellants and pyrotechnics) are energetic materials in which the decomposition process (deflagration) occurs at subsonic speed. The decomposition occurs on the surface of the explosive only and there is no shock wave. The rate determining factors in the deflagration process are the rate of heat transfer into the propellant itself from the burning surface and the rate of decomposition of the propellant formulation. The rate of the heat transfer is affected by the pressure of the combustion products.

The amount of energy released by propellant burning is comparable to that released when a high explosive of that same mass is detonated; the difference is in the rate at which the energy is released. In high explosives, a fast reaction produces a very high pressure shock in the surrounding medium. This shock is capable of shattering objects. In propellants (low explosives), a lower pressure is produced that extends over a longer period of time. High explosives produce peak pressure of 36,000 to 360,000 atmospheres in less than 4 microseconds; this pressure wave radiates through the material at a velocity (detonation velocity) between 2,500 and 10,200 m/s. The detonation also produces a 2-10 second fireball (afterburn) which has initial dimensions 1.2 to 1.5 times the dimensions of the material detonated. Propellants on the other hand, seldom produce peak pressures in excess of 3,500 atmospheres. TNT, RDX, Comp Bare examples of high explosives and nitrocellulose (NC) and nitroguanidine (NQ) are examples of low explosives. Nitroglycerin (NG) by itself is a high explosive, but when added to NC, it becomes part of a low explosive. For both types of explosives, the initial release of energy results from adiabatic, oxidation reduction processes, which involve oxidant (e.g., -ON02 , -N02 , -NHN02 ) and reductant (e.g., CxHy) radicals within the energetic material.

Cook3 and Ornellas"' have published extensively regarding the mechanisms involved when explosives are detonated and burned. The information presented in this section was taken primarily from their publications.

Cook's publication provides a very lucid, comprehensive description of

000971 how explosives are made and how their performance is modified by the addition of accelerators and retardants. Ornellas's publications, on the other hand, describe results from experiments conducted to derive thermodynamic codes for use in predicting the explosive performance of C,H,N,O,Al-based explosives. These studies primarily assessed the effect the following factors had on the efficiency and effectiveness of the detonation process: explosive density, purity, and particle size; degree of confinement; and type of initiating charge. One of his reports4 presents a comprehensive summary of the results obtained from detonating 25g cylindrical pellets (6.4 to 12.7 mm diameter, 114 mm long) of 43 energetic materials in a 5.3L bomb calorimeter at Lawrence Livermore National Laboratories (LLNL) . Most of the detonations were done with the calorimeter evacuated, but a few were done when the calorimeter was pressurized with either C02 or 0 2 • Some of the detonations were done with the energetic simply suspended by a string (unconfined detonation), others were done with the energetic encased in glass or metal cylinders; sometimes the ends of the cylinders were open (partially-confined detonation), but at other times they were closed (fully-confined detonation). Approximately 90 minutes after the detonation, gas samples were taken from the bomb calorimeter and analyzed for N2 , CO, C02 , H2 , H20, CH4 , NO, N02 , HCN,

HCl, HF, C2H2 • C2H4 C2H6 , and CH20, as appropriate. The calorimeter itself was also rinsed out and the rinse analyzed for solid carbon (C"), HCl,

HF Al2 0 3 , and Zr20 3 , as appropriate.

Ornellas's studies determined the following:

( 1) The major reaction products from an unconfined detona '.:::: ~. are primarily the fully oxidized, thermodynamically-stable compo:..::.::: :

N2 , C02 , and H2 0. The detonation also produces small quantities o: incompletely-oxidized, combustible products such as elemental ca:-:. - :.

(C 5 or soot}, CO.- H2 , CH 4 , NO, N0 2 , HCN, HCl, .HF, C2H2 • C2H4 • C,H, an:: ~-;; but, as the fireball expands all or most all of these latter pr:·:~:·~

react with 0 2 in the air or with each other to form C02 , N2 , and i-i • The oxidation (afterburn) of these initial products releases en<-·: '_ which helps support additional combustion. After the burning CT~ · mass cools to about 1800° K, the reaction rates fall to a poin: ·.-.:.· further chemical change takes hours or longer to occur.

(2) The actual composition of initial detonation produc:: depends on a variety of factors; one of the most important of tL•.. · . _ the amount and form of oxygen in the energetic molecule. If the energetic is oxygen-balanced or only slightly oxygen-deficient, rK•c-: of the carbon is converted to C02 and most of the hydrogen is conver:ed to H20 at the instant of detonation. As the oxygen-balance becomes more negative, the amount of soot, CO and other incompletely oxidized products formed increases and the fireball must occur if the incompletely oxidized products formed by the detonation are to

converted to C02 , N2 , and H2 0.

(3) Generally, at least 97% of the nitrogen in the energetic is

released as N2 ; almost all the rest is released as NO and N02 •

000972 (4) As noted above, the initial release of energy by an explosive results from an adiabatic oxidation reduction mechanism. This was dramatically demonstrated by Ornellas using a 20:80 blend (by weight) of ammonium nitrate (AN) and TNT. In his experiments, Ornellas used unlabeled AN (contains 99.8% 14N), labeled AN (contains

99 .1% 15N isotope) and unlabeled TNT (contains 99. 8% 14N). In one of the experiments he made a slurry of TNT and AN in toluene, dried the slurry, blended it, sieved it through a 30-mesh screen and pressed the resulting powder into 12.7 mm diameter pellets, which he then detonated in the calorimeter. In the other experiment he detonated a 12.7 mm diameter AN pellet containing a 6.4 mm diameter core of labeled AN and an annulus of unlabeled AN. After each detonation, Ornellas measured the isotopic content of the N2 formed, i.e. , 14 N14 N, 14N15N, and 15N15N. The two experiments yielded similar results, i.e. , only about 13% of the nitrogen in the TNT and the AN mixed.

(5) If the oxygen in the energetic is bonded with nitrogen, the energy released upon detonation is much greater than that which is released when the oxygen is bonded to hydrogen.

(6) The composition of the initial detonation products is not greatly affected by the degree of confinement, but, the composition of the final products is affected. The more oxygen-deficient the energetic, the more the degree of confinement affects the final product mix.

(7) If an oxygen-deficient energetic is detonated in an oxygen

enriched environment, the final products will be C02 , N2 and H20. On the other hand, the products formed by detonating an energetic in an inert atmosphere (e.g., C02 ) will be essentially the same as those formed when the energetic is detonated in a vacuum, regardless of the degree the energetic is oxygen-balanced (Table 1-1). The oxygen-rich atmosphere will also yield a much higher total energy release (Table 1-1), because of the heat released when the incompletely oxidized radicals are oxidized by the oxygen.

(8) Generally, less than 20% of the Cl and F in the energetics detonated in the bomb calorimeter was recovered, but all of the Cl and F recovered was in the form of HCl and HF. The missing Cl and F were assumed to have reacted with the steel walls of the calorimeter, because they were not found in the rinse of the calorimeter.

(9) Al and Zr in the energetic were usually not quantitatively recovered, but the portion recovered was all in the oxide form.

(10) The packing density has a profound influence on the ratios of initial products formed from a detonation. For example, free flowing loose granules do not explode as efficiently as cast explosives.

(11) As the density of a high explosive is increased, the detonation pressure and temperature also increases. On the other hand,

000973 when the density of a propellant is increased the detonation pressure decreases, even though the reaction (deflagration) temperature increases.

(12) A trace impurity can substantially increase or decrease the efficiency with which the detonation will occur.

(13) The manner in which the charges are placed, the priming method, and the placement of the initiating charge can influence the effectiveness of the detonation in destroying all of the energetic. The most desirable circumstance would be to assure that the explosive detonates ideally. An explosive stack with an irregular shape will usually impact much more force in the direction of the longest dimension.

The studies described above were conducted to improve the in-use performance of energetic materials. The nature of the emissions and the impact of these emission products on the health of humans and ecosystems when surplus or unserviceable energetic materials are destroyed by OB and OD processes were not addressed. These latter energetic materials frequently contain degraded or below specification grade energetics and other materials, such as asphalt, resinous shell linings, binders, cardboard, wood, metal foil, etc., which could adversely impact the efficiency of the detonation and burning processes.

Also, real world OD processes are usually not truly adiabatic, because the fireball and plume encounter a myriad of heat sinks which prematurely quench the fireball or cool the plume and therefore can hinder the oxidation of the incompletely oxidized products released by the detonation. For example, even in a truly spherical fireball having the lowest possible ratio of surface to mass· of any geometrical form, the outermost layer of the expanding fireball will be in direct contact with the ambient air. Also, the expanding gases penetrate the earth under the cloud, where they are both cooled by conduction and denied access to air for further oxidation until below equilibrium maintaining temperature. Further, for noise control purposes, at many facilities the detonations are conducted under a soil cover.

Studies To Assess The Environmentally Important Emissions From OB and OD Activities In response to public concerns about the ability of OB and OD processes to convert degraded energetics into innocuous products, the Department of Defense (DOD) began its first comprehensive study to characterize the emissions from OB and OD activities in 1984. The DOD hoped to demonstrate that OB and OD would yield emission products which were similar to those from energetics when used for their intended purpose.

In this study, helicopters equipped with commonly-used air pollutant sampling equipment measured the pollutants in the plumes released when

000974 900 to 5000 kg quantities of energetic materials were open burned and open detonated at DPG, UT. The results were inconclusive. 6 Few of the target compounds (analytes} were detected, but it wasn't clear if this was because they weren't present or because they were present at concentrations which were below the detection limits of the sampling equipment. Also, it was subsequently established that the helicopter frequently sampled only the outer portion of the plume and that the plume volume measurement technique was not reliable.

In 1988, the United States Army initiated a second study which had two major objectives: (1) to determine if toxic or hazardous pollutants were released when energetic materials were detonated or burned; and (2) to determine if emission factors produced by detonating and burning small quantities of energetic materials in large chambers containing ambient air would provide emission factors equivalent to those determined when large quantities of energetic materials were open-detonated and open-burned in the ambient air in the unconfined state.

Detonating and burning the energetic materials in large chambers provided DOD the opportunity to: (1) characterize ten or more energetic materials at a cost comparable to conducting field tests on one energetic material; (2) collect sufficient sample to meet the minimum quantification limits of the pollution measurement systems; (3) study the decay rates of the primary and secondary products released from detonations and burns; (4) minimize testing delays due to adverse weather conditions; and (5) obtain the minimum number of detonations and burns required to calculate statistically valid emission factors on each type of PEP material under repeatable and controlled conditions.

In this second study, 225 g quantities of flaked TNT were detonated and 2 kg quantities of two types of propellants were burned in a 930 m3 hemispherical chamber (BangBox} at Sandia National Laboratories (SNL) in Albuquerque, NM and the emission products were measured with state of-the-art air sampling equipment. This sampling equipment was then installed in a twin-engine, turboprop aircraft and used to sample the plumes released when 900 kg quantities of four explosives (reclaimed TNT, PBXN, Explosive D and Composition B) contained in treated wood boxes were detonated on the ground and 2,000-3100 kg quantities of four bulk propellants (Ml, M6, M30 and a composite propellant} were 7 8 burned in steel pans in the open at Dugway Proving Ground (DPG), UT. · Three, 2000-kg TNT detonations were also conducted with the TNT in iron cages suspended 10 m above the ground.

Based on their review of the test results, the U.S. Army concluded that the emission factors derived from the BangBox tests were: (1) more reliable and reproducible than those from the field tests; (2) were statistically equivalent to those determined from the field tests; and (3) supported the original assumption that the detonations and burns were producing emission products consistent with detonation

theory. For example, the C02 and CO emission factors derived from the

000975 TNT-BangBox detonations (TNT block suspended 1 m above the floor) were the same as those from the 2000-kg, suspended, reclaimed-TNT detonation, but both were substantially higher than those from the 2000-kg surface reclaimed-TNT detonatio.n' In this latter detonation, the expanding gases likely penetrated the earth under the detonating TNT and some of the energy released by the detonation was lost (transferred) to the soil. The resultant "cooling" of the fireball in combination with the reduced access to 0 2 prevented the complete oxidation of the incompletely-oxidized products which were released by the detonation of the severely oxygen-deficient TNT molecules.

In their test reports the Army also noted the similarity of the emission products from the BangBox and field tests across all the

materials tested, i.e., the emission products were primarily: N2 (assumed), H20 and C02 ; particles and metals; and small quantities of co, NO, N0 2 , low molecular weight volatile organic compounds (VOCs)and a few semivolatile organic compounds (SVOCs) commonly found in the ambient air. The report also noted: (1) that the soil at DPG had a high organic content and that the soil could have been the primary source for the SVOC's associated with the detonations; and (2) that

the% C Recovered as C02 followed detonation theory, i.e., 99% for the 900 kg suspended field detonations (no detonation energy losses to soil), 97.5% for the 0.2 kg detonation in the BangBox and 95% for the 900 kg surface field detonations.'

In 1992, the U.S. EPA concurred with the Army's conclusion and agreed to accept BangBox derived emission factors for energetic materials as representative of those that would be derived through ground level, open-air tests. The Army then installed a BangBox at DPG identical to the one at SNL and initiated a program to characterize the compounds released when a wide variety of bulk and assembled munitions representative of those in the demil inventory were destroyed by OB and OD.

BangBox Study Results Used To Construct Database Seven studies to characterize the emissions from the detonation and burning of energetic materials have now been conducted in BangBoxes. In these studies, 16 energetic materials have been burned and 23 have been detonated under conditions representing standard, unconfined OB and OD disposal practices. Since the seven studies used similar sampling and analysis procedures and had extensive documentation on what was done, it was possible to develop and validate the database of emission factors described in this report.

The database also includes the results from two special experiments. One experiment involved burning a surrogate dunnage to determine the contribution the burning dunnage makes to the emissions when it is used to initiate or support burning of an energetic material.

The other experiment involved using bags of water to suppress the detonations of two, TNT-based energetic materials, amatol and tritonal. These suppressed detonations were done primarily to assess how

000976 detonating an energetic under a soil cover could change the emission products compared to detonating the same weight of the energetic material on the ground. (As mentioned above, buried detonations are frequently used in the U.S. to mitigate the sound and blast waves released by the detonation.) Amatol and tritonal were selected for this experiment because they represent two extre~es in the oxygen content of commonly used explosives. When detonated, amatol, an oxygen balanced explosive, contains sufficient oxygen to convert its C and H

to C02 and H20, whereas tritonal contains only 20% of the oxygen required to convert all its carbon to C02 and H20.

These suppressed detonation experiments were also done to provide some robust emission factors for a blast and noise suppression technology 9 10 11 12 developed in the U.S. , but refined in Europe • and South Africa • The technology involves detonating munitions in contact with plastic bags containing water. This technology reduces the blast noise by more 10 than 90% when compared to an equivalent unrestricted detonation • However, the water also quenches the fireball which, based on the amount of sooty particulate found after the detonation, reduces the overall destruction efficiency of the detonation process.

000977 Table 1-1. Distribution of Carbon in Emission Products from Detonating TNT in Different Atmospheres in Bomb Calorimetera.

Calorimeter Atmosphere

Vacuum co, (1. 66 Atm.) o, (2.46 Atm.)

Total Energy Released 1093 1116 3575 (kcal/moll

% c Recovered as co, 18 17 97

% c Recovered as co 28 29 5

% c Recovered as(soot) 52 52 Not Detected

Total % Carbon Recovered 98 98 102

a.) Data taken from Table 44 on page 77 of Reference 4.

000978 Table 1-2.Heats of Reaction (kcal/mol) for Selected Gas Phase Reactions at 1 Atmosphere and 298° K

REACTANTS PRODUCTS HEATS OF REACTION

c + 'h o, = co -26 c + o, = co, -94 co + 'h o, = co, -68 2 co = co, + c -41

CH, + 'h o, = co, + H20 (gas) -192

H, + 'h o, = H20 (gas) -58

H, +CO = c + H20 (gas) -31 Vi N, + 'h o, = NO +22

NO + 'h o, = N0 2 -14 3/2 H, + 'h N, = NH1 -11

NH1 + 3/4 o, = 'h N, + 3/2 H20 (gas) -78

NH1 + 3/2 NO = 5/4 N, + 3/2 H20 (gas) -108

4/3 NH, + N02 = 7 /6 N2 + 2 H20 (gas) -108

CH, + 2 N02 = N, + 2 H20 (gas) + co, -208 s + o, = so, -71 so, + 'h o, = so, -23

H, + s = H2S -5

000979 Chapter 2 Methods and Materials

Composition of the Energetic Materials Characterized Table 2-1 identifies the materials detonated and burned in the seven studies. Table 2-1 also presents: the abbreviation used for each material in the other tables in this paper; the total weight (mass) of each energetic material (MEM) tested; and the number of times (trials) each material was detonated or burned. MEM includes the weight of all supplemental energetic materials such as blasting caps, donor charge, smokeless powder, etc. used in initiating the detonation or burn.

Tables 2-2 and 2-3 present the weights of the energetic components and Pb and Al in each material detonated and burned to the extent information is available. The abbreviations used in these tables represent the following compounds: TNT (2,4,6 trinitrotoluene); RDX (l,3,5-trinitro-1,3,5-triazacyclohexane); PETN (pentaeyrthritol tetranitrate); TETRYL (2,4,6, N-tetranitro-N-methylaniline); NC (nitrocellulose); NG (nitroglycerin); NQ (nitroguanidine); HMX (l,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane); AP (ammonium perchlorate); and AN (ammonium nitrate), KN (potassium nitrate); zinc powder (Zn) and aluminum powder (Al).

Appendix A contains detailed descriptions of the compositions of each energetic material.

Description of the BangBoxes Each BangBox sits on a concrete pad and is divided into two sections: 3 an inflatable, 930 m , 16.5 m diameter hemispherical test chamber made from a flexible polyvinyl-coated polyester fabric and a 5.5 x 2.1 x 2.5 m building (airlock) with a plywood front and a wood frame covered with the same material as the BangBox. The test chamber is kept inflated by two high-capacity blowers; six fans spaced 60° apart circulate the air in the test chamber to produce a homogeneous pollutant mix that is sampled with instruments in the chamber and the attached air lock. The energetic materials are burned in stainless steel burn pans placed on a steel pad located in the center of the test chamber and detonated in a 1 m3 steel-lined pit after the steel cover is removed. The test chamber is purged with air for at least 60 minutes (two air volume exchanges) between trials.

When detonations and burns are initiated, a known quantity of SF6 is released in the chamber. The concentration of the SF6 is then measured over the time air pollutant samples are taken and used to establish the actual volume of the chamber and the dilution of the emission products which occurred (due to the chamber blowers) between initiation of the burn/detonation and completion of sample collection. This information is used to calculate the initial concentrations of the compounds released by the burn/detonation. (The SF6 was collected in 0.85 L Summa canisters and analyzed by a gas chromatograph equipped with a flame photometric detector (GC/FPD).

000980 Sampling and Analysis Procedures used in the DPG BangBox The following sampling equipment was located in the test chamber: (1) high volume samplers (Hi-Vol) for measuring particle mass, metals, and EPA SW846 Method 8270 semivolatile organic compounds (SVOCs); (2) Hi Vol-based PM-10 sampler for measuring particles and metals in the respirable range; (3) EPA PS-1 samplers for measuring Method 8270 SVOCs and chlorinated dioxins and furans; (4) EPA Method 26 samplers

for HCl and Cl2 •

The following sampling equipment for gases was located in the airlock attached to the chamber: (1) continuous emission monitors (CEMs) for

C02 , CO, NO, N0 2 , 0 3 , and HCl; and (2) canisters for measuring volatile organic compounds (VOCs}, C0 2 , and CO.

Background samples were collected in the test chamber at the beginning of every test day, analyzed in a manner identical to the test samples, and the results used to correct the emission factors for any contribution background levels of the target compounds (analytes) rnade to the measured (uncorrected) emission factors.

The sampling equipment used in each study was selected based on the composition of the materials being tested and the objective(s) of the study. Table 2-4 identifies the sampling systems used in each study.

Appendix B contains a more detailed description of the actual sampling systems used and Appendix C delineates the target analytes used in the seven studies.

Sampling and Analysis Procedures Used in the SNL BangBox The procedures used at SNL were similar to those used at DPG. The differences are: (1) particle mass was determined from the PS-1 filter; (2) the extract from the PS-1 sampler was analyzed by selective-ion SFC/MS as well as by the full scan GC/MS procedurE· __ .-:: for the DPG BangBox samples; (3) the PS-1 samplers for dioxins a:.:: furans contained polyurethane foam rather than XAD-2; (4) sampl~' metals were collected on Teflon filters and analyzed using x-ra·. fluorescence; (5) individual VOC compounds from the canister ana. were not reported except for acetylene and benzene; and (6) two, ; . SVOC, two PS-1 dioxins/furans samples, two metals samples and f: ·.·._ canister samples were collected during each detonation or burn.

000981 Table 2-1. Energetic Materials Burned and Detonated in the BangBoxes Study Item Abbreviation MEM OB OD (g) Trials Trials

1 TNT (block) TNT-SNL 230 1

TNT (block) TNT-SNL 230 1

Foam-suppressed TNT OD TNT-foam 225 1

Double-based Propellant Dbl-base-SNL 471 1

MK-6 Propellant MK-6 448 1

2 PBXN-110 PBXN 1064 1

MK-23 MK-23 1030 1

M-43-LOVA M-43 1060 1

Smokeless Powder Smkles-pwdr 454 1

Smokey Sam Smky-sam 273 1

3 TNT (flake) TNT-ACCl 230 3

20 mm HEI cartridge 20 mm 189 3

40 mm HEI cartridge 40 mm 158 3

Ml8Al Claymore mine Claymore 229 3

T45E7 Adapter Booster T45E7 193 3

4 M-9 Propellant in Bags M-9 2406 3

M-1 Propellant in M-3 Bag M-1 2273 3

5 TNT (block) TNT-ACC2 230 1

Detonation Train Det. train 178 3

M187 Impulse Cartridge ARD-446 215 3

BBU-36B Impulse Cartridge BBU-36 144 3

Gas Generator GCU-2A GGU-2A. 139 3

MK-107 Impulse Cartridge MK-107 208 3

Signal, Red Star, M-158 M-158 239 3

Fuze, Tail Bomb, FMU-54 FMU-54 210 3

000982 Table 2-1. Continued. Study Item Abbreviation MEM OB OD (g) Trials Trials

5 IR Flare, M-206 M-206 241 3

Fuze, Tail Bomb, FMU-139 FMU-139 172 3

Signal, Red Star, M43A2 M43A2 260 3

6 M31A1El Propellant M31A1El 2276 3

Double-based Propellant Dbl-base-DPG 2227 2

Ammonium Perchlorate AP 2270 2

Aluminized AP Propellant Al-AP 1183 2

7 Detonation Cord Det cord 205 3

Tri tonal Tri tonal 235 3

Tri tonal With Wax Tri tonal-wax 235 3

Amatol Amatol 235 3

Composition B Comp B 235 3

Composition B With Alum. HBX 220 3

H20-suppressed Tritonal Tritonal-H20 235 3

Manufacturing Waste AP-waste 1139 3

H20-Suppressed Amatol Amatol-H20 235 3

Diesel Fuel/Dunnage Dunnage 913 3

000983 Table 2-2. Weights (grams) of Energetic Materials in Items Detonated

Item TNT RDX TETRYL PETN Al KN03 AN NC NG

TNT 227 2

Tri tonal 182 8 46

Tri tonal-wax 173 8 43

Amatol 114 8 113

Comp B 86 136

HBX 72 111 39

FMU-139 28 126 17

FMU-54 28 163 18

T45E7 28 177

ARD-446 54 32 50 53 15

BBU-36 54 32 45 28 8

MK-107 54 32 6 87 25

Det train 108 65

M43A2 54 32

M-158 54 32 44

M-206 54 32

Claymore 229

20 mm 79 100 10

40 mm 145 7 2

Det cord 203

GCU-2Aa 26 15

a Energetic composition and weight classified.

000984 Table 2-3. Weights (grams) of Energetic Materials in Items Burned

Item RDX AP Al Zn KN01 NC NG NQ HMX

Dbl-base-SNL 240 184

M-1 1815

M-9 36 1387 960

Dbl-base-DPG (a) (a)

M31A1El 493 410 1245

PBXN 16 1 924

M-43 775 38 2

Smkles pwdr 435 23

MK-6 381 1

APb 1946

Al-APb 821 226 4 0.2

MK-23 BOO 20 28 2

Smky-samb 110 100 22 1

AP-waste 738 140 4

a Actual weights classified

b. Identity and weights of other energetic materials either classified or not available

000985 Table 2-4. Sampling Systems Used in Each Studya- System Analyte Study 1 Study 2 Study 3 Study 4 Study 5 Study 6 Study 7 CEM C02 s s NA NS s s s co s s NA NS s s s NO/N02 s s NA NS s s s S02 s .s NA NS s s s 03 s s NA NS s s s HCl s NS s NS NS s s

Bubbler HC1/Cl2 s NS NS NS NS s s

Canister voe s s s s s s s CO/C02 s s s s s s s

Hi-Vol Mass NS NA s s s s s

SVOC/GCMS NS NA s s s s s

SVOC/SFCMS s NA s s s NA NA

Metals s NA s s s s s

PM-10 Mass NS s s s s s s

Metals NS NS s s s s s

PS-1 Mass s NS NS NS NS NS NS

SVOC/GCMS s NA s s s s s

SVOC/SFCMS s NS NS NS NS NS NS

Dioxins/Furans s NS NS NS s s s

Teflon filter Metals s NS NS NS NS NS NS

a. s sample taken; NS no sample taken; NA sample taken, results not valid or not available.

000986 Chapter 3 Construction and Validation of the Database

Construction of the Raw Database A matrix was developed to accommodate all the emission factors that could exist if every study had used the complete suite of sampling systems available. This matrix was then completed using data from each study's documentation file, e.g., test design plans, final reports, field notes, calibration data, laboratory reports, QA and QC reports, etc. Instances where data were missing were identified and the reason(s) determined. Some of these reasons were: (1) no sample collected; (2) sample collected, but no emission factor calculated because the sample was determined to be invalid; and (3) only those target compounds (analytes) actually detected were specifically identified in the final report. In this latter case, the Experimental Section of that final report listed all the target analytes and, if a target analyte was not mentioned in the Results Section of that report, then the reader was to assume that it was not detected. This latter situation was common for the voe and SVOC analytes.

In addition to the previously reported results, previously unreported results were converted to emission factors and placed in the database, except when the analyte had not been detected in any study. There were a large number of analytes in the not detected category, e.g., 103 of the 108 Method 8270 analytes and 65% of the voes. Thus, if an analyte is listed in Appendix C, but is not in the database, the user of the database can safely assume that it was never detected, or if it was detected, it was not above the concentration in the associated background sample.

After all quantitative values had been put into the database, the matrix was filled in using the following codes: (1) NS (no sample collected I; (2) ND (sample collected, but analyte either not detected or not detected above background concentration); and (3) NA (sample was supposed to have been collected, but either no results were found ~· result had been invalidated). The emission factors were then exa::.:::•·::: tc· assure that the total mass of the energetic material (MEM) detonated/burned had been used in calculating each emission factor When this was not the case, the emission factors were recalcula:e= us:ng the correct MEM and the corrected emission factors were then entered into the database.

The emission factors from the seven studies had been adjusted to compensate for the concentrations of the analyte in the background sample(s) taken the day of the test, hereafter designated as (EF 8 ~). The uncorrected emission factors were not reported. Since it is helpful to know the extent to which an emission factor has been adjusted for the background concentration, the concentration of each analyte measured in each background sample was converted to the equivalent emission factor

for that test (EF8 ) and entered in the database. In Studies 1, 5, 6, and 7 (Table 2-1), the actual volume of gas sampled was used for this

000987 calculation. Because the original sampling volumes were not available for the other three studies, the average volume of gas collected by the sampling systems used in Studies 5, 6 and 7 was used instead.

Two additional types of emission factors were also calculated, the minimum quantitation limit (MQL) emission factors (EFMOL), which are shown in Table 3-1, and the "uncorrected (for background)" emission factors (EFucl. Each EFMOL was calculated by entering the laboratory determined MQL for the analyte (expressed in units of mass/m3 ) into the pollutant concentration term of the emission factor equation. Each EFuc was calculated by adding the average background-corrected emission factor (EFBclto the associated background emission factor (EFB).

After these additional types of emission factors were added to the database, statistical outlier tests were done to identify anomalous values. The records associated with these values were examined to determine if there was an explanation for them being identified as an anomalous value, e.g., transcription error, misspelled word, etc. Values that could not be rejected for scientifically-defendable reasons were left in the database.

After these outlier tests were completed, it was clear that most of the uncorrected Method 8270 SVOC emission factors were considerably less than the corresponding MQL emission factors. A subsequent investigation showed that in the actual test report, these SVOC emission factors were identified as qualitative or tentative in nature; thus, they were not useful in calculating quantitative emission factors. To address this situation, it was decided to change the uncorrected emission factor (EFucl and the associated background-corrected emission factor (EFBc) to ND if the EFBc was less than 30% of the associated MQL emission factor.

Because Hg; As, Ni and Be were never detected·above background levels, they were not included in the validated database. It was also apparent that the PM-10 mass emission factors for metals were less reproducible and sometimes were larger than the corresponding Hi-Vol values. Much of this variation likely occurred because each PM-10 mass emission factor represented a single measurement whereas each Hi-Vol value represented the average of three measurements. Also, most of the uncorrected PM-10 mass emission factors were at or below the EFMOL· For the above reasons, the PM-10 mass emission factors for metals were not included in the "raw database". The PM-10 emission factors themselves, however, were included, because there wasn't an alternative source for these emission factors.

At this point, the raw database contained approximately 100,000 values. However, 80% of these values were identified as either ND, NS or NA. To facilitate the validation and statistical analysis of the database using SAS , all NS and NA values were changed to " " and all ND values were changed to "0.0E+OO".

000988 Validation of the Database

Adjustment of the Emission Factors for Metals from the Floor Bulk explosives which did not contain any metals still yielded emission factors above the MQL emission factors for: Al, Ba, Cu, Pb, Ti and Zn. These "emission factors" likely came from metals in or on the concrete floor of the BangBox, since dust from the floor was commonly found on Hi-Vol filters collected after detonations. Thus, it was decided to use the emission factors from the bulk explosives to derive the detonation related, background emission factors for these six metals rather than use the pre-test background samples. These detonation-related, background emission factors were calculated by averaging the emission factors for the following five bulk explosives : TNT-DPGl; TNT-DPG2; Arnatol; Comp B; and Det. train. These calculations yielded the following background emission factors (g analyte/g MEM): Al (7.2E-04); Ba (3.7E-04); Cu (4.8E-04); Zn (3.8E-04) and Pb (5.9E-04). The averages were then subtracted from the individual and average trial emission factors and the uncorrected emission factors to obtain the corrected emission factors.

Comparisons Between Sampling Systems As part of the validation effort and to remove redundant data from the database, the following comparisons were done using the average emission factor for each analyte: (1) CO/C02 (CEM vs canister); (2) voe (GC/FID vs GC/MS); aria (3) PS-1/GCMS vs Hi-Vol GCMS vs Hi-Vol/SFCMS. These comparisons yielded the following results.

Canister vs CEM for CO and CO,: The CEM CO emission factors are statistically equivalent to the corresponding canister values at the 95% confidence level (based on a comparison of 53 paired values). In contrast, the CEM C02 emission factors are on the average 5% higher than the corresponding canister emission factors (based on a comparison of 48 paired values) and the CEM mean difference is statistically different from the canister mean value at the 95% confidence level. Because the canisters were also used to measure the voe emissions, it was decided to include the canister-derived CO and C02 emission factors in the validated database and to include the CEM-derived values if the canister-derived values were not available.

GC/FID vs GC/MS for VOCs: The GC/FID emission factors for (o,m,p) xylene, are statistically equivalent to the corresponding GC/MS values, but fcor the seven other voes (measured by GC/FID and GC/MS) the emission factors are statistically different at the 95% confidence level. For 1,3-butadiene, the GC/FID mean emission factor is 66% of the GC/MS value (based on a comparison of 12 paired values), but for the other six voes, the GC/FID mean values are larger than the GC/MS values. The magnitudes of these mean differences are: benzene (34% larger, 51 paired values); ethylbenzene (21% larger, 38 paired values); styrene (102% larger, 19 paired values); toluene (39% larger, 38 paired values); and 1,3,5- trimethylbenzene (130% larger, 9 paired values). On an absolute basis, however, the mean differences are small, i.e., benzene (0.00002);

000989 ethylbenzene (0.0000006); styrene (0.000002); toluene (0.000004); and 1,3,5-trimethylbenzene (0.000001). Since the GC/FID emission factors were larger than the GC/MS values for most compounds and GC/FID was also used for all the other VOC compounds, it was decided to include the GC/FID-derived emission factors in the validated database and to include the GC/MS-derived values only when the GC/FID va+ues were not available.

PS-1/GCMS vs Hi-Vol/GCMS vs Hi-Vol/SFCMS: The PS-1 sampling system yielded non-zero emission factors for 5 of the 108 Method 8270 (non energetic SVOC) target compounds. These compounds and the energetic materials they were associated with are: acenaphthalene (AP-waste); fluoranthene (AP-waste); phenol AP-waste); 2-chlorophenol (AP-waste) and diethylphthalate (BBU-36, FMU-139, MK-107, GGU and M-9).

(1) Phenol: The PS-1 sampler detected phenol only in the first of the two AP-waste burns; it also detected phenol in the background sample (at a concentration only slightly less than that measured in the burn sample) taken in the BangBox before this burn. The Hi-Vol/SFCMS system also detected phenol for only the first burn and the emission factor (3.8E-05) is essentially the same as that from the PS-1 sampling system (3.4E-05). The phenol emission factors for the AP-waste burn were excluded from the validated database for three reasons. First, it was a common component of background samples in the concentration levels equivalent to the emission factors calculated from the burn. Second, it was in the background sample for the surrogate waste burn. Third, phenol was not found in the samples from the second burn. The Hi Vol/SFCMS sampling system did detect phenol in the detonation products from the following four energetic-containing items: ARD-446 (1.9E-06); MK-107 (8.4E-07); FMU-54 (4.7E-06); and 40mm (l.5E-06). These emission factors are very close to the MQL emission factor (2.9E-06), and, as noted above, phenol was a common constituent of the ambient air in the BangBox. Also, ~he PS-1 sampling system detected phenol in the background samples associated with these four items at levels which would have yielded emission factors of the same magnitude reported for these four items. Therefore, these latter phenol emission factors were not included in the validated database.

(2) Acenaphthalene and Fluoranthene: The Hi-Vol GC/MS sampling system yielded emission factors for only two of the 108 EPA-8270 compounds (acenaphthalene and fluoranthene) and both compounds were associated only with the AP-waste burn. These two compounds are normally released when diesel fuel and wood, two of the materials in the AP-waste material, are burned. These two compounds were also found by the corresponding PS-1 sampler. For acenaphthalene the average PS-1 emission factor was 1.0E-04 and the corresponding Hi-vol emission factor was 1.6E-04. Similarly, for fluoranthene the PS-1 emission factor was 2.0E-04 and the Hi-Vol value was l.OE-04. Since it is highly likely that these are valid emission factors, the PS-1 derived emission factors were included in the validated database.

(3) 2-Chlorophenol: This compound was detected only by the PS-1

000990 sampler during the two AP propellant burns conducted July 31, 1995. Both trials yielded the same emission factor (1.0E-05), a value approximately 30% of the MQL. Since 2-chlorophenol was not found in the associated background samples and it was not a common background contaminant, the 2-chlorophenol emission factors were included in the validated database.

(4) Diethylphthalate: Non-zero emission factors for diethylphthalate came only from the PS-1 sampler. They were associated with the four items which were detonated {BBU-36,MK-107,FMU-139 and GGU- 2A) and one item which was burned (M-9). For the following reasons the emission factors associated with the four items detonated (BBU-36, MK- 107; FMU-139, and GGU-2A) were included in the validated database. First, diethylphthalate was not detected in the background samples associated with these energetic materials. Second, the MQL emission factor (2.lE-04) associated with the four materials is less than the average emission factors reported for these materials. Third, it was found in almost all samples.

The emission factor from the single M-9 propellant burn was excluded from the validated database for the following reasons. First, the MQL for diethylphthalate is higher than the emission factor from the M-9 propellant burn. Second, although diethylphthalate was not found in the background sample associated with this burn, it was frequently found in background samples at levels tenfold greater than the M-9 emission factor.

Mass Balance Assessments for C, N, s, Cl, Al and Pb

carbon Mass Balance The carbon mass balance was conducted by calculating the total mass (weight) of carbon in the material (MEM) detonated or burned and comparing it to the mass of carbon found using the sum of the average emission factors for C02 and CO (expressed as their carbon equivalent values). Sufficient composition data was available to conduct the mass balance calculation for 23 of the materials detonated and burned. Only the detonation cord gave a % Conversion (210%) which differed by more than 18% from the value of 100% that was expected if all the carbon had

been converted to CO and C02 • The extremely high % Conversion value for the det. cord was unexpected because each of the three trials involved detonating 203 g of PETN with an electric blasting cap and because the emission factors for the three trials agreed so closely. A subsequent review of the raw data also showed that this material had an usually

large difference between the CEM and canister values for both C0 2 and CO. It also showed that PETN was not detected in the emission from any of the three detonations. This was particularly unusual, because, when much lower quantities of PETN had been detonated (as part of donor charges), measurable quantities of PETN had been detected. For the above reasons all emission factors for the det. cord were excluded from the validated database.

000991 Nitrogen Mass Balance Although N was not measured directly in the BangBox studies, there is solid scientific evidence from detonation and burn experiments on 4 5 13 14 explosives where the N2 emissions were measured directly. • • • The experiments described in references 13 and 14 are particularly relevant here because they involved detonating M107, 155 mm artillery rounds (965 - 2260 kg) and burning NIKE rocket motors in a 4,100 m3 chamber. More than 99.8% of the Nin the Comp Bin the M107 rounds and 99.7% of the N in the NIKE's double base propellant were converted to N2 • These low %N Conversion are particularly striking when compared to those for other CHNO-based materials. For example, the percentages of N (in the fuel) converted to NOx in utility boilers firing residual fuel oil, distillate 15 16 oil and coal are: 50-60%, 60-80% and 20-25%, respectively • •

The N mass balance calculations used the NO and N0 2 emission factors (expressed as N) to determine how much of the N in the energetic material was converted to nitrogen oxides. Sufficient chemical composition data was available to conduct the assessment on 25 of the materials detonated and burned. The AP-waste burn, which had a % Conversion of N to nitrogen oxides of 17%, was the only material with a % Conversion of N value greater than 6%. Since all the% Conversion of N values are reasonable based on the work of Cook3 and Ornellas•, all the NO and N02 emission factors were included in the validated database.

Chlorine Mass Balance Percent recoveries for Cl could be calculated for five energetic materials. These materials and the associated% recoveries are: AP (85%), Al-AP (102%), MK-23 (99%), MK-6 (37%) and AP-waste (60%). Since these % Recoveries are reasonable based on the work of Ornellas', all HCl and Cl2 emission factors were included in the validated database.

Sulfur Mass Balance Four of the materials detonated contained known quantities of S. These materials and their associated % Conversion to S02 are: M31A1El (28%), HBX (5%), M43A2 (5%), and Ml58(1%). Because no literature references on

recovery of S from detonations was found, the S02 emission factors were included in the validated database.

Lead Mass Balance The two materials known to contain Pb (Dbl-SNL and Dbl-DPG) yielded % Recoveries of 37% ((Dbl-DPG) and 128% (Dbl-SNL). The reason for the low % Recovery for Dbl-DPG burn is not known. (Pb was found in the residue from this latter burn, but, the quantity in the residue was not reported.) Because Pb is one of the most likely toxic compounds potentially released from OB and OD activities, the Pb emission factors were included in the validated database.

Aluminum Mass Balance The six materials known to contain measurable quantities of Al yielded a wide range of % Recoveries. These materials and the associated % Recoveries are: tritonal (6%), tritonal-wax (9%), HBX (5%), Al-AP (7%),

000992 AP-waste (29%) and MK-6 (60%). Although Al was found in the residue from the three burns and observed on the floor of the BangBox for the three detonations, the actual amount was never determined. Because Ornellas4 also reported low recoveries for Al, all the Al emission factors were included in the validated database.

Energetic Material Mass Balance The database contained non-zero emission factors for only four of the original energetic compounds: NG, HMX, RDX and PETN; all were associated with detonations. The other target energetics (including TETRYL and TNT) were never detected. However, it should be noted that sampling results for energetics were only available for the energetic materials detonated and burned in Studies 1,3,4 and 5. Air samples for energetics were also taken in Studies 6 and 7, but the samples were not analyzed because the SFC/MS unit was broken and it was not repaired until six months after the samples had been extracted. (The analytical method specified that the extract must be analyzed within 60 days after extraction). Thus, it is possible that additional energetic emission factors would have resulted had these latter samples been analyzed.

NG was associated only with detonations of energetic materials which did not contain NG and it was found in the background samples associated with these detonations. Therefore, the NG emission factors were not included in the validated database.

The PETN and RDX emission factors were included in the validated database, because they were associated only with detonations in which materials containing these energetics were used to initiate the detonation.

The emission factors for HMX were included in the validated database because: (1) the HMX was consistently detected only when RDX was also detected in the emission products; (2) military grades of RDX contain between 4 to 15% HMX by weight; and (3) with one exception, the HMX emission factors were 3 to 24% of the corresponding RDX emission factor.

Validation of Chlorinated Dioxins and Furans Results The validation of the dioxin and furan data was difficult because of the excellent MQLEF (E-10 to E-11) and the ubiquitous nature of these 17 compounds in all environmental media • Dioxin and furan samples were collected during four burns (AP propellant, aluminized AP propellant, AP-waste and diesel fuel and dunnage) and after the detonations of the M-158, M43A2 and M-206 flares.

Furans were detected only in the emissions from the AP waste burn. The five isomers (octochlorinated dibenzo-p-furan (OCDF), 1234678 HpCDF, 1234789 HpCDF, 123478 HxCDF and 123678 HxCDF) were detected at levels 100 to 1,000 times larger than the MQL emission factor (2.6E-11) and therefore, were included in the validated database. No total furan values (e.g., total HxCDF) were reported.

Octochlorinated dibenzo-p-dioxin (OCDD) was detected in the emissions

000993 from the detonation of the M43A2 flare and the burning of the diesel fuel and dunnage surrogate. The OCDD emission factor for the M43A2 was included in the validated database, because: (1) it was not found in the background sample; and (2) was found at levels 4 to 10 times larger than the EFMQL (2.lE-10) for the three trials (detonations).

The OCDD emission factor for the dunnage burn was not included because: (1) it was found for only one of the three trials; (2) the background emission factor accounted for 70% of the corrected emission factor; and (3) the uncorrected emission factor was only 30% larger than the MQL emission factor (2.lE-10). A total HpCDD emission factor was also reported for the M43A2 detonation. It was included in the validated database, because it was found in each of the three trials (detonations) at levels which were 1.3, 2.5 and 5 times the EFMQL (2.lE-10). No other dioxins were reported for any of the items tested.

Table 3-1. Representative MQL Emission Factors (kg.analyte/kg MEM) Analyte MQL for MQL for Detonations Burns

HCl 9.2E-05 1. 2E-05

Cl2 4.6E-05 6.0E-06

C02 4. 3E-07 5.5E-08 co 4.3E-07 5.5E-08

NO 3.lE-05 3.9E-06

N02 4.?E-05 6.0E-06

S02 2.2E-05 2.8E-06 SVOCs 2.0E-04 2.6E-05

Dioxins & Fur ans 2.0E-10 2. 6E-ll

RDX, PETN & HMX 2.9E-07 3.?E-08

voes 4.3E-07 5.5E-08

Al 2.?E-04 3.5E-05

Sb & Ba 6.7E-04 8.6E-05

Cd 3.9E-05 4.9E-06

Cu 8.?E-05 1.lE-05

Pb 3.6E-04 4.6E-05

Ti 1.lE-05 1. 4E-06

Zn 9.0E-04 1. 2E-05

000994 Chapter 4 overview of the Validated Database

Appendices D and E contain printouts of the BangBox-derived emission factor databases for burns and detonations, respectively. These emission factors apply to the disposal of energetic materials through OB in a pan and through unconfined, surface detonations (OD) with the £ollowing exceptions: dunnage burn; AP-manufacturing waste burn; gas generator detonation; and water-suppressed tritonal and amatol detonations. The reasons these latter materials were designated as exceptions is discussed below.

The validated database contains emission factors for 83 analytes: 7 inorganic gases; total nonmethane hydrocarbons (TNMHC); total unidentified hydrocarbons; 22 unsaturated hydrocarbons (including a total unsaturated hydrocarbons); 16 saturated hydrocarbons (including total unsaturated hydrocarbons); 10 aromatics (including total aromatics); 8 chlorinated hydrocarbons; 8 metals; 5 chlorinated furans; 1 chlorinated dioxin; 4 non-energetics SVOCs; and 3 energetic SVOCs. Most of the analytes are nonhazardous compounds commonly found in ambient air. If an analyte is listed in Appendix C, but is not in the database, the user of the database can safely assume that it was never detected, or if it was detected, it was not above the concentration in the associated background sample.

The many similarities between the emission products from detonations 7 8 and burns reported earlier ' are also present in the expanded database. For example, ethane, propane and isobutane were associated with almost every energetic material tested and their emission factors were usually much greater than those for the other saturated hydrocarbons. Also, almost every energetic material tested released ethylene, propene and acetylene and these three compounds represented a very substantial part of the emission factor for total unsaturated compounds.

000995 Chapter 5 Discussion of Results from Unsuppressed Detonations

The materials detonated in the BangBoxes without water suppression, were placed into two categories: BangBox bulk explosives and BangBox assembled (encapsulated) explosives, e.g., fuzes, flares and impulse cartridges. A third category (DPG field bulk explosives) was also created using the emission factors from the 900-kg surface detonations (TNT-Phase A, TNT-Phase B, TNT-Phase C, Comp B, Explosive D and PBXN) and the 900-kg suspended detonations conducted at DPG in 1989 and 1990. 8 The mean emission factors and associated standard deviations were then calculated for the following analytes within each category (if the data were available): total saturated hydrocarbons; ethylene, propene, acetylene, and (total of) other unsaturated hydrocarbons; benzene, toluene and (total of) other aromatics; and PM-10 (Table 5.1). The mean %C and %N converted to the corresponding oxides (COx, NOx)

and the ratios %CO/C02 and %NO/N0 2 and the associated standard deviations were also calculated (Table 5.2).

These analytes were selected because they are found in the emissions from most of the materials detonated. Emission factors for individual saturated hydrocarbon compounds, such as ethane, propane and butane, were excluded for two reasons. First, these compounds are environmentally benign. Second, the background concentrations of these saturated hydrocarbons averaged approximately 50 percent of the concentrations found in the samples collected after the detonations (compared to average values of 10% and 30% for the unsaturated hydrocarbons and aromatic hydrocarbons, respectively.

The means were then subjected to a Student's t-test to determine if the means for the same ratio or analyte were statistically the same across at least ·two of the three categories. These t-tests determined that the means were statistically equivalent across all three categories for %C Converted to COx; %CO/C0x and PM-10 mass and therefore the individual values could be combined to create larger data sets (Table 5.3).

No other means were equivalent. However, because the absolute differences between the mean values for the %N Converted to NOx were small across the three categories, the individual values were ranked from highest to lowest to see if they were sufficiently intermixed across the three data sets to justify combining them into one large data set. For this exercise, the BangBox bulk detonations, the DPG field detonations, and the BangBox encapsulated detonations were designated by the numbers l, 2 and 3, respectively.

This ranking exercise, which is shown below, demonstrated that for all practical purposes, there is sufficient overlap of values across the three categories to rationalize combining them (Table 5.3).

%N as NOx : 3 , 1 , 3 , 3 , 3 , 1 , 1 , 3 , 1 , 3 , 3 , 3 , 1 , 2 , 1 , 1 , 2 , 2 , 1 , 2 , 2 , 2 , 2 , 2

000996 As shown below, a similar ranking exercise performed on the %NO/NOx ratios also yielded results which justified combining the three data sets into one large data set (Table 5.3).

%NO/ NOx : 1 , 1 , 1 , 1 , 1 , 3 , 1 , 3 , 3 , 3 , 3 , 3 , 2 , 2 , 3 , 3 , 2 , 2 , 2 , 2 , 1 , 2 , 2 , 3 , 3 .

Users of the database who are estimating the emissions from a variety of energetic materials should consider using the data in Table 5.3 rather than the average C02 , CO, NO and N0 2 emission factors in the validated database. Users should also assume that BangBox-derived PM- 10 mass emission factors will likely underestimate the PM-10 emissions from detonations, since they do not include the soil particles that are entrained in the plume by the surface detonations.

On the other hand, the differences between the means for the organic analytes were too large to rationalize combining them into larger data sets. The means in Table 5.1 are normalized to the mass of the energetic material (MEM) detonated, but for some applications, having the emission factors normalized to the carbon content of the material detonated might be more appropriate. Users who need the organic analytes normalized to the carbon content of the material detonated will find this information in Table 5.4.

Other VOC Compounds Other than benzene and toluene, styrene, a common air pollutant, was the only other aromatic found at high levels. It was found after the detonation of the Claymore mines (average emission factor of l.7E-03) and the T-45E7 adapter boosters (average emission factor of l.2E-04). These emission factors are likely valid, because both materials contained polystyrene (the casing of the Claymore mine contained 150g and the T45E7 contained a 31g polystyrene plug).

Sulfur and Aluminum The low and variable recoveries for S and Al should be investigated further. It is possible that the S was converted to compounds, such

as 803 , H2 S04 , H2 S, metallic sulfates or even free S(S8 ); none of which were target analytes. The low recovery of Al may be completely, or at least partly, explained by the silvery-gray residue observed on the floor after each detonation of an Al-containing material. Unfortunately, the identity and mass of this residue was never determined. However, Ornellas• also reported low recoveries of Al for some materials. Until the reasons for the low recoveries are determined, it would be prudent to assume that all the Al (and any other metal in the explosive detonated) is released to the environment.

Method 8270 Compounds (SVOCs) Diethylphthalate was the only Method 8270 compound found in the detonation samples and it was associated with items which were either known to contain phthalates or were likely to contain them. Consistent with detonation theory, no SVOC's attributable to molecular rearrangement reactions of the energetic molecule were found.

000997 Dioxins and Furans Furans were not detected, despite the extremely sensitive sampling and analysis method employed (MQL emission factor of 2.0E-10). One dioxin, OCDD (octochlorinated dibenzo-p-dioxin) was found (average emission factor of l.BE-09) in the samples from the detonation of the M43A2 flare and likely resulted from the reaction of the chloride containing compound(s) and the plastic materials in the flare.

Residual Energetics The presence of HMX, RDX and PETN in some of the air samples collected after detonations is expected, because detonations are usually not 100.0% efficient. However, it must be noted that for most of these detonations, the ratio of the donor charge mass to the total mass (MEM) detonated was two to four times greater than that used in a routine OD activities. The emission factors in the validated database are calculated based on the total MEM detonated, rather than the actual mass of PETN and RDX used. Table 5.5 compares these original emission factors to those which result when the actual mass of PETN and RDX detonated is used to calculate the emission factors.

As noted in Chapter 3, HMX is an accepted contaminant in RDX; military-grade RDX contains between 4 to 15% HMX by weight. If the percentage of HMX in the RDX being used is known, one should consider using an emission factor for HMX derived by multiplying the RDX emission factor by the percentage of HMX in the RDX rather than using the values in the database.

000998 Table 5.1 Mean Emission Factors (kg Analyte/kg MEM) for Selected Analytes for Detonations Analyte Category MEM No. Of Mean Std. Dev. (kg) Values

PM-10 BB, Encapsulated 0.2 12 0.30 0.26

BB, Bulk 0.2 8 0 .13 0 .13

Total Saturated HC BB, Encapsulated 0.2 11 55E-06 59E-06

BB, Bulk 0.2 7 llE-06 llE-06

Ethylene BB, Encapsulated 0.2 11 256E-06 132E-06

BB, Bulk 0.2 8 69E-06 130E-06

Propene BB, Encapsulated 0.2 11 SOE-06 40E-06

BB, Bulk 0.2 8 14E-06 24E-06

Acetylene BB, Encapsulated 0.2 11 300E-06 171E-06

BB, Bulk 0.2 8 56E-06 70E-06

Other Unsaturated BB, Encapsulated 0.2 11 61E-06 NM HC

BB, Bulk 0. 2 8 llE-06 NM

Benzene BB, Encapsulated 0.2 11 69E-06 41E-06

BB, Bulk 0.2 8 9E-06 9E-06

Field, Bulk 900 6 69E-06 37E-06

Toluene BB, Encapsulated 0.2 11 26E-06 12E-06

BB, Bulk 0.2 8 4E-06 2E-06

Other Aromatics BB, Encapsulated 0.2 11 42E-06 NM

BB, Bulk 0.2 8 lOE-06 NM

000999 Table 5.2 % Recoveries of C and N as the Oxides for Detonations

Parameter Category MEM No. Of Mean Std. Dev. (kg) Values

%C as cox BB, Encapsulated 0.2 5 100% 10%

BB, Bulk 0.2 9 102% 10%

Field, Bulk 900 8 96% 2%

%CO/COx BB, Encapsulated 0.2 13 6.6% 16%

BB, Bulk 0.2 9 0.6% 4%

Field, Bulk 900 8 3.4% 2.0%

%N as NOx BB, Encapsulated 0.2 8 2.9% 2.0%

BB, Bulk 0.2 8 1. 9% 1. 4%

Field, Bulk 900 8 0.6% 0.3%

%NO/NOX BB, Encapsulated 0.2 9 69% 201

BB, Bulk 0.2 8 92% lRt

Field, Bulk 900 8 55% s. ; .•.

Table 5.3 Emission Factor Averages Across Categories for Detonations Parameter No. Of Values Median Mean Std. ... .

%C as cox 22 98.55 99.6% r.;, .;

%CO/COx 30 1. 60% 3.96% '. .. "

%N as NOx 24 1. 20% 1.78% 1. 5 ·:.

%NO I NOx 25 66.0% n-. 0% 22.3%

PM-10 20 0.21 0.230 0.180

001000 Table 5.4 Mean Emission Factors (kg Analyte/kg C in Energetic) for Selected Analytes for Detonations Analyte Category No. Of Mean Values

Total Saturated HC BB, Encapsulated 5 11 ?E-06

BB, Bulk 8 14E-06

Ethylene BB, Encapsulated 5 1302E-06

BB, Bulk 8 239E-06

Propene BB, Encapsulated 5 209E-06

BB, Bulk 8 47E-06

Acetylene BB, Encapsulated 5 1267E-06

BB, Bulk 8 187E-06

Other Unsaturated HC BB, Encapsulated 5 6700E-06

BB, Bulk 8 38E-06

Benzene BB, Encapsulated 5 231E-06

BB, Bulk ·s 32E-06

Field, Bulk 6 244E-06

Toluene BB, Encapsulated 5 95E-06

BB, Bulk 8 12E-06

Other Aromatics BB, Encapsulated 5 137E-06

BB, Bulk 8 33E-06

001001 Table 5.5 Original and Adjusted Emission Factors for PETN and RDX PETN Emission Factors RDX Emission Factors

Original Adjusted Original Adjusted

FMU-139 l.7E-05 l.7E-04 3.4E-04 2.lE-03

FMU-54 9.6E-06 l. lE-04 9.0E-05 6.4E-04

T45E7 PETN Not Used PETN Not Used 2.4E-04 1.6E-03

ARD-446 0 0 8.4E-04 3.3E-03

BBU-36 5.8E-04 2.6E-03 0 0

MK-107 5.lE-05 3.4E-03 0 0

Det. Train 5.6E-04 1. 5E-03 7.4E-03 1. 2E-02

M43A2 1. 2E-05 1. 5E-03 l.9E-04 9.lE-04

M-158 8.4E-06 6.2E-05 5.5E-05 2.4E-04

M-206 1.6E-06 1. OE-05 6.0E-05 2.5E-04

GGU-2A 4.9E-05 4.5E-04 1.4E-04 7.4E-04

Claymore PETN Not Used PETN Not Used 9.9E-06 1.0E-05

20-mm PETN Not Used PETN Not Used 1. 2E-05 2.7E-05

40-mm PETN Not Used PETN Not Used 3.7E-05 4.0E-05

Number of Values . 10 10 14 14 Median 1. 45E-05 2.55E-04 1.7E-04 7.4E-04

Mean 1. 28E-04 6.74E-04 6.84E-04 l.61E-03

Standard dev. 2.33E-04 8.87E-04 1. 94E-03 3.14E-03

001002 Chapter 6 Results for Water-Suppressed Detonations

Tables 6.1 and 6.2 compare the emission factors derived from the water-suppressed detonations of amatol and tritonal to those derived from the unsuppressed detonations of these materials. The suppressed detonations were done primarily to assess in a robust manner the impact that detonating oxygen balanced (amatol) and severely oxygen deficient (tritonal) explosives under a soil or water-blanket cover might have on the emissions. Amatol, an oxygen balanced explosive comprised of a mixture of TNT and AN, contains sufficient oxygen to convert its C and H to C02 and H20, whereas tritonal contains only 20% of the oxygen required. The water quenched the fireball (afterburn) required by the tritonal to convert its C, N and H to cox, NOx, and

H2 0.

These experiments were also done to provide some robust emission factors for a blast and noise suppression technology developed in the 9 10 11 12 U.S. , but refined in Europe • and South Africa • This technology involves detonating munitions in contact with plastic bags containing water. Th~s technology reduces the blast noise by more than 90% when 11 compared to an equivalent unrestricted detonation • However, the water also quenches the fireball which, based on the amount of sooty particulate found after the detonation, reduces the overall destruction efficiency of the detonation process.

The data in Tables 6.1 and 6.2 are consistent with the results from Ornellas.4. 5 That is, quenching the afterburn significantly increases the emissions of incompletely-oxidized species such as soot and the hydrocarbons, and sharply decreases the emissions of C02 • The results 3 5 also are in general agreement with detonation theory. ·., For example, the increase in hydrocarbons is limited to molecules which are smaller than the starting energetic molecules (Table 6.2), i.e., rearrangement into larger molecules did not occur.

The decrease in the C02 and increase in the CO and hydrocarbon emissions for the water-suppressed detonation of amatol (an oxygen balanced energetic) may seem surprising, but conforms to detonation theory. That is, the oxygen balance in amatol is achieved by mixing a strong oxidizer (AN) with the oxygen-deficient TNT. Thus, for the optimum energy release from amatol, the oxidant and reductant radicals formed behind the shock wave must diffuse between two molecules in order to react with each other. In contrast, when the redox reaction occurs within the same molecule, the affect of fireball-suppression on the emissions is less severe.

The results show that placing an oxygen source in contact with the explosive molecule will not ensure an efficient detonation when it is conducted under a soil or water blanket cover. Unfortunately, there is no information on the TNT emissions which might have resulted from the water suppressed detonations, because the air samples collected for the energetic analytes were not analyzed (SFC/MS unit was broken) .

001003 Table 6.1. Comparison of Emission Factors for Unsuppressed and Water-Suppressed Detonations of Tritonal and Amatol.

Analyte Tritonal-H 0 Tri tonal 2 (T-H2 0) I (T) Amatol-H20 Amatol (A-H2 0) I (A) (T-H 0) 2 (T) (A-H20) (A)

co, 0. 28 1. 2 0.23 0.3 0.7 0.43

co 2700E-04 29E-04 93 2. 3E-04 97E-04 0.24

. NO 40E-04 59E-04 0.68 77E-04 180E-04 0.43

N02 2.7E-04 0. 3E-04' · 9 2.4E-04 1.2E-04 2

Ethane 120E-06 0.4E-06 300 1100E-06 4. lE-06 268

Propane 55E-06 0.7E-06 78 190E-06 O.lE-06 1900

Butane 15E-06 0. 3E-06 50 52E-06 0.6E-06 87

Other Saturated HC 30E-06 8E-06 4 158E-06 135E-06 1

Ethylene llOOE-06 25E-06 44 980E-06 31E-06 32

Propene 160E-06 SE-06 32 360E-06 5.SE-06 65

Acetylene 4400E-06 43E-06 102 140E-06 1.0E-06 140

Other Unsaturated HC 240E-06 87E-06 6 20E-06 103E-06 5

Benzene 200E-06 1. SE-06 133 270E-06 23E-06 12

Toluene 73E-06 1.8E-06 40 120E-06 6.7E-06 18

Other Aromatics 87E-06 11E-06 8 O.OE+OO 13E-06 NM

001004 Table 6.2. Distribution of C and N Across Selected Analyte Classes for Tritonal and Amatol Detonations

Analyte Class Tritonal-H20 Tri tonal Arnatol-H,O Arnatol

%C as COx 65% 106% 98% 104%

%CO/C0x 49% 0.2% 0.07% 1. 3%

%N as NOx 2.7% 0.95 2.2% 5.0%

%NO/NOx 94% 99% 97% 99%

%(E+P+B)/Total Saturated HCa 86% 14% 100% 30%

%(E+P+A)/Total Unsaturated HCb 96% 46% 99% 27%

%(B+T)/Total Aromaticsc 76% 24% 100% 55%

a. (Ethane + propane + butane) emission factors/total saturated HC emission factor.

b. (Ethylene + propene + acetylene) emission factors/total unsaturated HC emission factor.

c. (Benzene+ toluene)/total aromatic HC emission factor.

001005 Chapter 7 Discussion of Results from Burns

AP-Waste Burn Results This surrogate waste was supposed to simulate the mix of AP contaminated plastic gloves, cotton rags, Kimwipes, wood towel rods and similar materials that result from the clean-up of the vessels used to manufacture AP-based propellants. These materials are usually disposed of by open burning in pans or by incineration. The original plan was to bring an actual AP-based manufacturing waste to DPG for the experiment, however, this was prohibited because DPG did not have a permit for destroying this type of waste. In hindsight, the surrogate waste burned was not truly representative of a real manufacturing waste. The chemical composition was appropriate, i.e., 65% aluminized AP (69% AP, 19% aluminum), 20% plastic material (polyethylene gloves), 11% paper/wood/cloth and 4% diesel fuel; the problem lies with the manner in which the propellant was placed in contact with the combustible materials. That is, 1-in. cubes randomly dispersed on top of the combustible materials. In an actual waste, the propellant would be dispersed on the combustible materials as a fine powder.

Also, because the first burn resulted in a hole in the bottom of the pan, the second and third burns were done with the surrogate waste sitting on top of a 7.6 cm layer of pea gravel. At the completion of each of these last two burns, holes were found in the side of the burn pan, and melted plastic was found in the pea gravel. Approximately llOg of ash remained in the burn pan after the first burn, 40g of ash after the second burn and 65g of ash after the third burn. It was difficult to determine the weight of ash remaining when the pea gravel was used; The weight of waste surrogate burned in the three trials was l,139g, including the 4g of Hercules Unique Smokeless Powder used to initiate each burn.

The unique mix of emission products, the melted plastic and the 17% conversion of N to NOx observed for the surrogate AP-manufacturing waste demonstrates that this burn was very different from all other burns which involved energetic materials. Most of the emission factors for chlorinated VOC's, those for the five furans, and two of those for the SVOCs are associated only with this material. There were also notable quantities of diesel-fuel-related voes in the emissions.

These results are consistent with a combination deflagration (AP) and incineration type burn (melting of polyvinyl gloves and charring of the wood dowel sticks by the heat released from the deflagration) . This environment would have provided the conditions which favor the 17 formation of SVOCs and dioxins and furans. These conditions are : low temperature (250-400°C), long residence time (seconds), presence of Cl and organic materials and a metal that could serve as a catalyst. Additional work should be done on this type of material.

001006 Dunnage Burn Results The dunnage burn is unique in that it did not involve any energetic containing materials. Not surprising, almost all of the emission

factors in the database for C7 and higher saturated hydrocarbons are associated with the diesel fuel used in this burn and the AP-waste burn. These emission factors could be useful for predicting the VOC emissions from diesel fuel-initiated or supported burns of energetic containing materials.

Smokey Sam Burn Results The smokey sam is an HC-type obscurant (Chemical Agent, Group B Class). Its energetic composition is: 110.0g AP, 100.2g Zn, 30g hydroxyl-terminated polybutadiene and 7.Sg dioctyl adipate. It was the only encapsulated propelling material burned in the BangBox. In use, its purpose is to provide a screening smoke of ZnC1 2 particles. The burn was very dirty; the BangBox airlock was filled with a pungent, noxious odor and the BangBox test chamber was filled with a dense fog. In comparison to the other AP-based propellant burns, its CO emissions were very high (17%) relative to its C02 emissions. Although the emission factors are included in the database, this item is sufficiently unique to justify not using it to calculate summary statistics for bulk propellants.

Discussion of Results for Other Energetic Materials The other materials burned in the BangBoxes were placed into two categories: BangBox organic-based propellants and BangBox AP-based propellants. A third category (DPG field organic-based propellants) was also created using the emission factors from the 2000-3100 kg propellant burns conducted at DPG in 1989 and 1990. 8 The mean emission factors and associated standard deviations were then calculated for the following analytes within each category (if the data were available): total saturated hydrocarbons; ethylene; propene; acetylene; (total of) other unsaturated hydrocarbons; benzene; toluene; (total of) other aromatics;'"'"and PM - 10 (Table 7 .1). The mean %C and %N converted to the corresponding oxides (COx, NOx) and the

ratios %CO/C0 2 and %NO./N0 2 and the associated standard deviations were also calculated (Table 7.2).

The means were then subjected to a Student's t-test to determine if the means for the same ratio or analyte were statistically the same across at least two of the three categories. These t-tests determined that the means were statistically equivalent across all three categories for %C Converted to cox, %CO/COx. %N Converted to NOx, %NO/NOx and PM-10 mass, and, therefore the individual values could be combined to create larger data sets (Table 7.3).

Users of the database should consider using the data in Table 7.3

rather than the average C02 , CO, NO and N0 2 emission factors in the validated database. Also, in contrast to the detonation PM-10 data, the BangBox-derived PM-10 mass emission factors likely provide reasonable estimates of the emissions from the open burning of propellants.

001007 Analogous to the detonation data, the differences between the means for the organic analytes are too large to permit combining them into larger data sets. The means in Table 7.1 are normalized to the mass of the energetic material (MEM) burned. While it would be desirable for some applications to have these emission factors normalized to the carbon content of the material burned, this could not be done because the information necessary to do the calculations was available for too few materials.

Other VOC Compounds No other voe compounds were found at notable levels for the bulk propellant burns. This is consistent with the theory of propellant 4 5 burns. •

HCl and Cl 2 The mean, median and standard deviation of the mean % Recoveries for the five Cl-containing materials burned in the BangBox are: 68%, 73% and 32.8%, respectively. For the four materials for which both HCl and Cl2 values were available, at least 98% of the Cl was found as HCl, regardless of the amount of total Cl recovered. These results are similar to those obtained by Ornellas for AP-based explosive materials. 5 At this time, it would be prudent to assume that all the Cl in an AP-based propellant will be released to the environment as HCl.

Lead and Aluminum The low and variable recoveries for Pb and Al were not expected and should be investigated further. It is possible that some of the Pb is converted to a chemical form which is not collected by a quartz fiber filter. Until the reasons for the low recoveries are determined, it would be prudent to assume that all the Pb and Al not accounted for in the ash, was released to the environment.

Method 8270 Compounds (SVOCs) No Method 8270 SVOC compounds were found for the bulk propellant burns. This is consistent with detonation theory.

Dioxins and Furans Dioxins and furans were not detected, despite the extremely sensitive sampling and analysis method employed (MQL emission factor of 2.6E- 11).

Residual Energetics No residual energetics were detected for any of the bulk propellant burns. However, as mentioned earlier, the air samples collected for energetic analyses in the last two studies were not be analyzed because the SFC/MS unit was broken.

001008 Table 7.1. Mean Emission Factors (kg Analyte/kg MEM) for Selected Burn Analytes

Analyte Category MEM No. Of Mean Std .. (kg) Values Dev.

PM-10 BB, AP-Based 0.2 4 0.15 0.19

BB, Organic-Based 0.2 7 0.28 0.36

Total Saturated HC BB, AP-Based 0.2 4 O.OE+OO NM

BB, Organic-Based 0.2 7 4.7E-06 9.7E-06

Ethylene BB, AP-Based 0.2 4 O.OE+OO Nli

BB, Organic-Based 0.2 7 3.7E-06 3.SE-06

Propene BB, AP-Based 0.2 4 O.OE+OO NM

BB, Organic-Based 0.2 7 l.OE-06 1 .lE-UC

Acetylene BB, AP-Based 0.2 4 9.0E-06 9. :JI:,-·,

BB, Organic-Based 0.2 7 4.6E-06 5. CE~~ t

Other Unsaturated HC BB, AP-Based 0.2 4 26E-06 : :!-~

BB, Organic-Based 0.2 7 3E-06 r:?~

Benzene BB, AP-Based 0.2 4 l.SE-06 0 ..

BB, Organic-Based 0. 2 7 3.0E-06

Toluene BB, AP-Based 0.2 3 0.0E+OO ..

BB, Organic-Based 0.2 7 0.BE-06 1 ' .5 E, -

Other Aromatics BB, AP-Based 0.2 4 0.0E+OO NM

BB, Organic-Based 0.2 7 BE-06 NM

NC = not calculable

001009 Table 7.2. % Conversion of c and N to the Oxides from Burns

Parameter Category MEM No. Of Mean Std. (kg) Values Dev.

%C as cox BB, AP-Based 02 4 99% 14%

BB, Organic-Based 0.2 3 91% 8%

Field, organic-Based 3200 3 100% 2%

%CO/C0x BB, AP-Based 0.2 4 0.55% 0.32%

BB, Organic-Based 0.2 7 0.27% 0.37%

Field, Organic-Based 3200 3 0. 007% 0. 01%

%N as NOx BB, AP-Based 0.2 2 1. 8% 1. 0%

BB, Organic-Based 0.2 4 0.5% 0.4%

Field, Organic-Based 3200 3 0.9% 0.4%

%NO/N0x BB, AP-Based 0.2 3 75% 16%

BB, Organic-Based 0.2 4 72% 46%

Field, Organic-Based 3200 3 75% 6%

Table 7.3. Emission Factor Averages Across Categories for Burns

Parameter No of Values Median Mean Std. Dev

%C as cox 10 98.5% 95.0% 9. 87%

%CO/C0x 14 0.20% 0.300% 0.366%

%N as NOx 9 0.90% 0.89% 0.74%

77.0% 73.9% 25.6% %NO/N0x 10 c<

PM-10 10 0.019 0.233 0.300

001010 Chapter 8 Suggestions For Using the Database

Detonation Emission Factors Rather than using all the emission factors, user's of the database should consider using the means and medians in Tables 5.1, 5.3 and 5.4 as the starting point for predicting the emissions from OD-based processes and adjust the data for their own situation using commonly accepted information on detonation theory and processes, such as that presented in Chapter 1 and the information presented in Chapters 5 and 6 of this document.

For example, a database user attempting to estimate the emissions at a facility which surface-detonated a wide variety of bulk and assembled energetic-containing materials, could calculate an average emission factor for each analyte which covers both bulk and encapsulated energetic materials. On the other hand, if the detonations are to be conducted under a soil cover, one should consider the likelihood that the fireball will be suppressed and use either the data in Tables 6.1 and 6.2 or select the uppermost part of the ranges for %CO/C0x and hydrocarbons species in Tables 5.3 and 5.4.

Unfortunately, if the energetic contains Pb or Al, at this time, one has to assume that all the Pb and Al is released to the atmosphere. More research is needed on these release of these and other metals from OD activities. The low and variable % recoveries for Cl and S observed in all the studies also needs to be studied further to more fully characterize the environmental safety of OD practices. At this time, one has to assume that all the metals, S and Cl enter the environment and.attempt to estimate how they will disperse in the environment.

The most difficult emissions to estimate are those for PM-10 and undegraded energetic starting materials. It would be reasonable to assume that the PM-10 emission factors in Table 5.1 and 5.3 underestimate the PM-10 emissions for a surface detonation, but how low is the estimate? Also, if the mass of the energetic being detonated is small and the ratio "donor charge to total energetic mass," is large, one can assume that some amount of undegraded energetic will be released to the environment. But again, how much?

Open Burning Emission Factors Users should apply the data in Tables 7.1, 7.2 and 7.3 and the other information presented in Chapter 7 in a manner analogous to that recommended above for the detonation emission factors, e.g., one has to assume that all Pb, Al Cl and S in the energetic material being burned will be released to the environment, except for whatever was recovered in the burn pan ash. However, for burns, one can assume that

001011 undegraded energetic emissions would be low and that the PM-10 emission factors in Tables 7.1 and 7.3 are reasonable estimates of the PM-10 emissions expected.

001012 Chapter 9 Recommendations for Future Work

The low and variable % recoveries for metals and for Cl and S observed in all studies reviewed needs to be determined to more fully characterize the environmental safety of OB and OD practices. At this time, one has to assume that all the metals, S and Cl enter the environment.

All emission products studies to date have used relatively clean energetic materials. Recovered high and low explosives should be burned and detonated in chambers to confirm the representativeness of these earlier studies.

Existing knowledge on the affect that accelerators and retardants have on the rate of energetic processes should be applied to OB and OD technologies to see if the environmental safety of OB and OD can be improved further.

Buried detonations should be avoided until the impact that burial and partial confinement have on the emission is established through rigorous research testing. Computer simulations using computational fluid dynamic techniques followed by experimental confirmation should be an integral part of these studies, because of the large number of factors which could affect the emissions. Other noise suppression techniques which do not inhibit the formation of the fireball, such as detonating in chambers, should also be developed and evaluated.

001013 References

1. Title 40, Code of Federal Regulations, Part 264, Subpart X, Miscellaneous Units.

2. Military Explosives. Chapter 3 in Department of the Army Technical Manual TM 9-1300-214. Headquarters, Department of the Army, September 1984.

3. M. A. Cook and G. Thompson, "Chemical Explosives - Rocket Propellants". Chapter 19 in Riegel's Handbook of Industrial Chemistry, Seventh Edition. J.A. Kent, Editor. Van Nostrand Reinhold Co., NY, NY. 1974 (pp 570-595).

4. D.L. Ornellas, "Calorimetric Determinations of the Heat and Products of Detonation for Explosives; October 1961 to April 1982." Lawrence Livermore Laboratory Publication No. UCRL-52821, University of California, Livermore, CA 94550 (April 1982). Available from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Road, Springfield VA 22161.

5. R. R. McGuire and D. L. Ornellas, "Detonation Chemistry: Diffusion Control in Non-Ideal Explosions." Propellants and Explosives, 4, 23-26, 1979.

6. M. Johnson, "Development of Methodology and Techniques for Identifying and Quantifying Products from Open Burning and Open Detonation Thermal Treatment Methods - Proceedings of the Technical Steering Committee Symposium (July 6-8,1988) ."U.S. Army, AMMCOM, Rock Island, IL 61299-6000, August 1991.

7. M. Johnson, "Development of Methodology and Techniques for Identifying and Quantifying Products from Open Burning and Open Detonation Thermal Treatment Methods - Bang Box Test Series, Volume 1 (Test Summary) ."U.S. Army, AMMCOM, Rock Island, IL 61299-6000, January 1992.

8. M. Johnson, "Development of Methodology and Techniques for Identifying and Quantifying Products from Open Burning and Open Detonation Thermal Treatment Methods - Field Test Series A, B and C, Volume 1 (Test Summary)." U.S. Army, AMMCOM, Rock Island, IL 61299- 6000, January 1992.

9. W.A. Keenan and P.C. Wager, "Mitigation of Confined Explosive Effects by Placing Water in Proximity of Explosives." In Proceedings of the 25th U.S. Department of Defense Explosive Safety Seminar, Anaheim, CA, August 1992, pp. 311-339.

10. S.H. Salter and J.H. Parkes "The Use of Water-filled bags to reduce the effects of explosives." In Proceedings of the 27th U.S. Department of Defense Explosive Safety Seminar, Miami, FL, August, 1994.

001014 11. A.E.A. Wilkinson and P. Goddard, "Explosive ordnance engineering at the Defence Test and Evaluation Organization's Shoeburyness facility in the UK." Paper presented at the 1995 COPEX Conference, Washington, D.C., May 1995

12. G. Barrett, "The Use of Water in the Mitigation of Explosives." Realtor, October 1988, pp 51-52.

13. Summary Report for 1997 on the Emissions Released from the Detonation of M107, 155 mm Artillery Rounds in the NTS (Nevada Test Site) Tunnels, in Preparation.

14. Summary Report for 1997 on the Emissions Released from the Burning of NIKE Rocket Motors in the NTS (Nevada test Site) Tunnels, in Preparation.

15. Operating Experience with NOx Abatement at Stationary Sources. Special Report form the NOx Task Force to the Economic Commission for Europe, December 1992. pp. 6-12.

16. Pulverized Coal Combustion: Pollutant Formation and Control, 1970-1980. U.S. Environmental Protection Agency Report Number EPA 600/8-90-049, Research Triangle Park, NC 27711, May 1990, p. 4-17.

17. K. Olie, R. Addink andM. Schoonenboom., "Metals as Catalysts During the Formation of Dioxins and Furans." J. Air and Waste management Association, 48, 101-105, 1998.

001015 Appendix A Detailed Descriptions of the Energetic Materials

Description of Materials Used in Study 1 This study, which was funded by the United States Army Materiel Command (AMCCOM), was conducted in the SNL Bang Box between January 30 and February 16, 1989. In this study TNT blocks were detonated while suspended approximately 1 m above the concrete floor and two propellants were burned in stainless steel pans 103 cm in diameter and 12.7 cm deep. During the propellant burns, the pan was covered with a coarse stainless steel screen to prevent pieces of the propellant from sputtering out of the pan during the burn. The propellants were ignited with an Atlas electric match.

'l'N'l' Block TNT blocks weighing 227g were detonated on January 31, February 2 and February 6, 1989. The TNT was obtained by removing the Mylar film from TNT demolition block and cutting the TNT into the shape and weight desired. The TNT block was made from pressed TNT grains ranging in size from 35 to 65 mesh; graphite (used to facilitate the pressing process} was the only other component in the block. An RP-83 initiator, which consisted of PETN and RDX encased in an aluminum alloy casing, was used as the initiator.

Foam Suppressed 'l'N'1' Block Detonation The suspended TNT block was encased in a glycol-based foam which had an expansion ratio of 130:1. The foam contained glycol ether, a 5- carbon alcohol, xanthin biopolymer, formaldehyde, a sulfonate

surfactant and C12 - C14 fatty acids. The foam blanket was held in place with polyethylene sheeting. The diameter of the foam to that of the block was approximately 17:1. The TNT block was detonated on February 13, 1989 in the same manner as the bare TNT blocks had been detonated. This test was done to determine the capability of foam to reduce the blast wave and improve the environmental safety of OD activities. It was found that the foam did not substantially reduce the blast wave to the degree expected and that it impaired the efficiency of the detonation (as evident by the sharp reduction of the

C02 emissions and the free carbon in the residue left on the floor after the detonation) . The results from this single test were not included in the database because of the uniqueness of the test.

Double-base Propellant-NOSIH-AA2 The MEM burned was 471g. The major constituents of the propellant were: 240g NC, 184g NG, 26.6g ethyl cellulose, 12.3g triacetin, 9.lg of di-n-propyl adipate and 4.5g lead. A single burn was conducted on February 9, 1989.

Composite Propellant MK-6, 88 P-217 The MEM burned was 448g. The major energetic constituents of the propellant were: 381g AP, 35.9g hydroxy-terminated polybutadiene, 20.2g dioctyl sebacate and 4.5g aluminum oxide.

001016 Description of Materials Used in Study 2 This Navy-funded study, which was conducted from January 19 to January 21, 1993, was the first study conducted in the DPG BangBox. Its objective was to collect emissions data for use in designing a confined-burn facility for propellants. Five propellants were burned in stainless steel pans and the dimensions of the pans were not recorded in the final report. The burn pans were placed at the center of the BangBox on the steel plate covering the 1 x 1 x 1 m detonation pit. The burns were ignited using Hercules Unique Smokeless Powder, which is a mixture of NC (95%) and NG (5%). A single burn was done on each material.

PBXN-110 Propellant The MEM burned on January 19, 1993 was 1064g, which included 14g of smokeless powder. The major energetic components of the 1050g of PBXN-110 burned were: 924.lg HMX, 53g hydroxyl-terminated polybutadiene, and 53g isodecyl pelargonate.

MK-23 CTBN Propellant The MEM of energetic material burned on January 19, 1993 was 1030g, including 30g Hercules smokeless powder. The major energetic components of the lOOOg of MK-23 propellant burned were 800g AP, 142g carboxyl-terminated polybutadiene and 20 g Al.

MK-43 LOVA Propellant, MIL-P-70818 The MEM of energetic material burned on January 20, 1993 was 1060g, including 40g Hercules smokeless powder. The energetic composition of the MK-43 propellant burned was: 775g RDX, 4lg NC, 122g cellulose acetate butyrate (CAB) and 78g of a mix of bis(2,2- dinitropropyl)acetal and bis(2,2-dinitropropyl)formal (BDNPA/F)

Hercules Unique Smokeless Powder The MEM burned on January 21, 1993 was 454g; it was comprised only of smokeless powder (431.3g NC and 22.7g NG).

Smokey Sam (Obscurant) The MEM of energetic material burned on January 21, 1993 was 273g, including 23g of Hercules smokeless powder. One smokey sam was burned in each trial. The energetic components of the smokey sam were: 110.0g AP, 100.2g Zn, 30g hydroxyl-terminated polybutadiene and 7.5g dioctyl adipate. The burn was very dirty; the BangBox airlock was filled with a pungent, noxious odor and the BangBox test chamber was filled with a dense fog.

Description of Materials Used in Study 3 Study 3 was funded by the United States Air Force (USAF) and was conducted from February 8 to February 12, 1993. Its objective was to obtain emissions data for a Subpart X permit application for a USAF base. Four USAF items were detonated in the BangBox; the detonations were initiated using C-4 and an electric blasting cap (EBC). (C-4 is the donor charge used in the routine detonation of the four USAF

001017 of the reducer charge was not given in the final report. The major energetic constituents of the 2,156g of M-1 propellant burned were: l,815g NC, 213g dinitrotoluene, 106g dibutylphthalate and 22g diphenylamine. The three M-1 propellant burns were conducted on March 17 and 18, 1993; each burn was conducted under different temperature and humidity conditions. These conditions were generated using electric heaters and pans containing water. The first burn was conducted at low humidity and at a temperature above ambient temperature; the second burn was conducted early in the morning of March 18 under conditions of cool temperature and high relative humidity, and the third burn was conducted at ambient temperature. Unfortunately, the specific temperatures and humidities used are not given in the final report. Because the three trials gave emission factors which were essentially the same, the emission factors are identified in the database as M-1 propellant burn without referencing the environmental conditions under which each burn was done.

Description of Materials Used in Study 5 This study, which was funded by the USAF, was conducted from February 23 to March 9, 1995. Its objective was to obtain emissions data for a Subpart X permit application at a USAF base. During this study, the emission from 10 USAF items were characterized when these materials were detonated. C-4, detonation cord and an EBC assembly (detonation train) were use to initiate each detonation. Three detonations were conducted for each item. Each item detonated was suspended either 1 m or 0.5 m above the floor of the 1 x 1 x 1 m detonation pit. The C-4 was obtained by removing the Mylar film from Mll2 demolition charges; it was shaped to the size and weight needed for the test and then wrapped in a 12.7 cm x 30 cm sheet of polyethylene (weighing l.9g) to prevent C-4 particles from falling to the floor of the BangBox before the detonation was initiated.

'!'NT Block To ensure that the pollutant measurement instruments and other BangBox equipment was operating properly, three TNT blocks with a total MEM of 222g were tied together with 16 gauge iron wire, wrapped with l.9g of polyethylene sheeting and detonated (using an EBC inserted in the bottom of the assembly) on February 23, 1995.

Detonation Train This item represents the detonation train used to initiate the detonation of the other nine items used in the study. It was detonated to determine the effect that its detonation could have on the emissions measured from the other nine items. Each detonation train contained 57g C-4, 32g detonation cord (PETN), and an EBC. The C-4 was shaped into blocks weighing 57g with dimensions approximately 7.7 x 2.5 x 2.5 cm and the detonation cord was cut into 3 m lengths and coiled around the polyethylene-wrapped C-4. For this test, two detonation train assemblies were tied together with 16 gauge iron wire, wired in parallel to the firing line and detonated above the floor of the detonation pit using one EBC on each detonation train. The MEM used in each of the three detonations conducted on February

001018 24, 1995 was 178g.

Cartridge, Impulse, M187 Mod O, ARD446-1, NSN 1377-00-516-9924 This item has a MEM of 12.5g. For each trial, ten ARD446's were wrapped together in polyethylene sheeting and detonated using one detonation train. The MEM of the assembly was 216g, including 91g from the detonation train. Each cartridge was stated to contain 0.9g charcoal, 0.9g sulfur and 5.0g potassium nitrate and approximately Bg of smokeless powder. It is assumed that the smokeless powder was 70% NC and 20% NG and 10% ethyl centralite. Three detonations were done on February 25, 1995.

Cartridge, Impulse, BBU 36B, NSN 1377-01-037-8650, Lot T0592A002012 This item deploys chaff from aircraft and contains a pyrotechnic filler which readily burns when initiated. Each cartridge has a MEM of 875mg. Sixty cartridges were used in each of the three detonations conducted on February 27, 1995. In each detonation, 42 cartridges were clustered around a 57g block of C-4 and 18 cartridges were placed on the sides of a 0.5 m length of detonation cord which had been folded into a 0.25 m length. In trial l, the two assemblies were hung separately with one end of the detonation cord inserted in the block of C-4. An EBC was used to detonate the C-4. In trials 2 and 3, the C-4 and detonation cord assemblies were bound together using 16 gauge iron wire. The MEM of the assemblies detonated was 144g, including 91g from the detonation train. The energetic composition of the cartridge is not fully known; it did contain O.lg potassium nitrate, O.lg charcoal 0.7g NC, 0.2g NG and 0.06g amorphous boron.

Generator, Gas Pressure, Propellant Actuated, GCU-2/A, NSN-1336-00- 420-2980 This item, which is used in the LGM30 minuteman missile, has a MEM of 95.3g; its energetic composition is classified. The item was prepared for detonation by removing the outer metal jacket to expose the solid propellant which is cast as a short hollow cylinder. Twenty-eight and a half grams of C-4 was packed into the hollow cylinder and the cylinder wrapped in polyethylene sheeting. This assembly was then wrapped with 1.5 m of detonation cord and the gas generator's plastic shipping plug was taped on top of the detonation cord. The gas generator was then oriented with its steel plug facing into the detonation pit and detonated with an EBC. One gas generator was used in each detonation; three detonations were done on March 1, 1995. The MEM of each assembly detonated was 139g.

Cartridge, Impulse, MK107, Mod 01, NSN-1377-00-779-2601 This cartridge has a MEM of 24.5g. Five cartridges were placed around a 57g block of C-4. Tney were parallel to each other, but alternated tip to base. This assembly was wrapped with 3 m of detonation cord and detonated over the detonation pit using an EBC. The MEM of each assembly was 208g, including 91g for the detonation train. The energetic composition of the MK107 cartridge was 17.4g NC, 5.0g NG, lg barium nitrate and 1.2g of potassium nitrate. Three detonations were

001019 conducted on March 3, 1995.

Signal, Illumination, Ground, Red Star, M158 NSN 1370-00-490-7363 This flare has a MEM of 36.Bg. Four flares along with their bandoliers were used in each detonation. Two flares were placed on one side of a 57g block of C-4 and two were placed on the opposite side. This assembly was wrapped in polyethylene sheeting; 3 m of detonation cord was then wrapped around the assembly and secured with 16 gauge iron wire. This final assembly was detonated with the flare releasing end pointed down into the pit. An EBC was used to initiate each of the three detonations conducted on March 4, 1995. The MEM of each assembly was 239g, including 91g from the detonation train. The complete energetic composition of the item is unknown. It did contain 2.5g of black powder, 5.2g of strontium nitrate, 2.5g magnesium, llg potassium nitrate, 2.5g charcoal and milligram quantities of cadmium and zinc.

Fuze, Tail Bomb, Fuze Mechanical Unit (FMU) 54A/B, NSN-1325-00-613- 0484 This fuze, which contains 163g of TETRYL, initiates the longitudinal detonator cast into general purpose (GP) air-dropped bombs such as the M117 and MK82. The MEM of the fuze is 163.3g. One fuze was used in each of the three detonations conducted on March 6, 1995. Each fuze was prepared for detonation as follows. A 28.5g block of C-4 was taped to the side of the fuze near its main explosive charge and the assembly wrapped in polyethylene sheeting. 1.5 m of detonation cord was then wrapped around the fuze and the fuze was screwed onto a threaded shaft. (The opposite end of the shaft was attached to al.~ cm thick by 30.5 cm diameter steel plate. The purpose of the stee·: plate was to break up any focused blast effect resulting from the detonation.) The fuze was detonated 0.5 m above the floor of the detonation pit using an EBC. The MEM was 20.9g, including 46g fro~. ::.he detonation train.

Flare, Countermeasure, Aircraft, M206, NSN-1370-01-0482138 This flare is used to decoy heat-seeking missiles away from ai.!·:·: '· Each flare has a MEM of 150. 2g and contains 102g powered magnt-c- . .,:: potassium nitrate, 5g NC and 13g rubber. The flare, which haci

Fuze, Tail Bomb, Fuze Mechanical Unit, 139A/B, NSN 1325-01-214-7311 This fuze contains 126g of TETRYL; it initiates the longitudinal

001020 detonation cast into GP air-dropped bombs. The MEM of the fuze is 126g. One fuze was detonated in each of the three detonations conducted on March 8, 1997. The procedure employed was similar to that used for the FMU 54 A/B fuzes detonated on March 6, 1995. The MEM of the each assembly detonated was 172g, including 46g from the detonation train.

Signal, Illwnination, Aircraft, Red Star M43A2, NSN-1370-00-618-5790 This flare has a MEM of 56.8g with 56.6g of this MEM in the illuminating charge. The illuminating charge contains 10.2g magnesium powder, 13.6g potassium perchlorate, 24.9g strontium nitrate, 3.4g hexachlorobenzene, 4g asphaltum and mg quantities of cadmium, barium, ·and lead. Three flares along with their bandoliers were used in each of the three detonations conducted on March 9, 1997. The three flares were tied to a 57g block of C-4 and detonated employing a procedure similar to that used for the M158 flares detonated on March 4, 1995. The MEM of each assembly detonated was 260g, including 91g from the detonation train.

Description of Materials Used in Study 6 Study 6 was a R&D study funded by the Strategic Environmental Research and Development Program (SERDP); its objective was to determine the emissions released when double-based and AP-based propellants were burned. The testing was conducted from July 26 to August 3, 1995. The four propellants burned were placed in stainless steel pans and ignited with an electric squib and'4g of Hercules Unique Smokeless Powder.

M31A1E1, Triple Based Propellant, NSN 1376-01-213-5669 During the first burn, the stick propellant was burned in an upright position, which resulted in extensive propellant kickout. To reduce propellant kickout, for the second and third burns, the propellant sticks were placed horizontally in the pan. For these latter burns, four propellant sticks were broken into fourths (18.4 cm) and placed in the pan. Then additional propellant sticks were broken in half (36.8 cm) and placed crosswise on top of the other propellant sticks. The MEM (including the 4g of smokeless powder) used in the three burns conducted on July 26, 1995 were 2,284g, 2,280g and 2,264g, for the first, second and third burns, respectively. The major energetic constituents of the M31A1El propellant burned were: 492g NC, 410g NG, l,245g NQ, 34g ethyl centralite and lg of charcoal.

Double-Based Propellant Other than the following elemental composition, no information is available for this cast propellant which was burned on July 27, 1995: 20.36% C, 2.97% H, 28.73% N, 46.14% 0, 0.89% Pb, 0.89% Zr and 0.02% Sn. The MEM of propellant burned in each of the two burns was 2,227g, including 4g of smokeless powder. Each propellant burn would potentially release 19.8g of Pb.

Ammonium Perchlorate (AP) Propellant Other than the following elemental composition, no information is

001021 available for this propellant which was burned on July 31, 1995: 25.87% Cl, 11.32% C, 4.31% H, 10.35% N, 47.31%0, and 0.89% Zr. This formulation implies that the propellant was 85% AP. The MEM burned in each of the two trials was 2,270g, including the 4g of smokeless powder used to initiate each burn. Based on the above elemental composition, the 2,270g of propellant burned contained: 1946g AP, 300g

of a material or materials with the elemental formula of C21H 32 , 3. 8g NC, 0.2g NG and 20g Zr.

Alwainized Ammonium Perchlorate (AP) Propellant Other than the following elemental composition, no information is available for this propellant which was burned on August 3, 1995: 19% Al, 20.8% Cl, 10.09% C, 3.7% H, 8.3% N, 38.1% 0 and 0.008% P. This formulation implies that the propellant contained 69% AP by weight. The MEM (including 4g of smokeless powder) for the first and second burns were l,216g and l,159g, respectively for an average MEM of 1192g (82lg AP, 226g Al, 14lg of a material or materials with an elemental

composition of C20H340, 3. 8g NC and 0. 2g NG) . Description of Materials Used in Study 7 Study 7 was a SERDP-funded R & D project designed to determine the emissions released when TNT-based explosives are detonated at ground level and underground. This study was also done to obtain information on the emissions released to the atmosphere when waste from an aluminized AP propellant manufacturing process and diesel fuel-soaked dunnage are burned. All detonations and burns were done in triplicate. Except as indicated below, all detonations were done using an M-6 EBC and a 6.5g block of C-4 cut from an Mll2 demolition charge. The detonations were done with the material suspended 1 m above the floor of the BangBox.

Detonating Cord.· Twenty-one and three tenths (21.3) meters of PETN-based detonating cord were shaped into a 61 cm diameter coil and the coil suspended over the detonating pit such that a 2.5 cm space existed between each successive turn of the coil. The MEM used in each of the three detonations conducted on August 15, 1995 was 205g, including the M6 EBC used to detonate the detonation cord. For the reasons discussed in Chapter 3, all the detonation cord results were determined to be invalid and, therefore, were not included in the validated database.

Tritonal Surrogate Low density tritonal is used in 750 lb. air-dropped bombs; it consists of 80% TNT and 20% Al by weight. There is no commercial or military use for tritonal recovered from these out-of-date bombs. A tritonal surrogate was prepared using crushed TNT block and aluminum powder. These components were placed in a jar and mixed until the mixture appeared to be homogeneous. This mix contained 1274g TNT and 43lg Al. Three, 227g portions of this mix were placed in thin polyethylene bags and the bags closed with cotton string. One bag was used in each detonation; the detonations were done with the bags suspended approximately 1 m above the concrete floor of the Bang Box. In the

001022 first two trials, a single M-6 EBC was used to initiate the detonation. It was apparent from the noise of the blast and the residues on the floor that the two detonations did not go high order. To ensure that the third detonation went high order, the EBC was inserted into a 6.5g block of C-4 for this detonation. The MEM of the material detonated in the three detonations was 229g for the first two detonations and 235g for the last detonation. Because they were not high order detonations, the results from the first two detonations are not included in the database. The detonations were done on August 16, 1995.

Tritonal Surrogate with 2.5% Calcium Stearate The calcium stearate served as a surrogate for the organic materials associated with tritonal when it is steamed out of 750 lb. bombs. Three detonations were done on August 17, 1995; a 6.4g block of C-4 and an EBC were used to initiate each detonation. The tritonal/calcium stearate mixes detonated were contained in thin polyethylene bags in a manner identical to the tritonal surrogate detonations. Each bag contained 216g of the tritonal surrogate mix prepared earlier and llg of calcium stearate. The MEM of the material detonated was 226g, including Bg from the C-4/EBC.

Water-Suppressed Tritonal surrogate Detonation The purpose of these water-suppressed detonations was to obtain a preliminary comparison between the emissions from unconfined, surface and buried detonations. The purpose of the water was to quench the fireball that forms when an energetic material is detonated. This fireball is important for ensuring that the molecular fragments of the energetic materials formed in the detonation are converted to CO and

C02 • Three, water-suppressed detonations of tritonal were done on August 22, 1995 using 227g of tritonal surrogate, l,362g of water, a 6.5g block of C-4 and an EBC. For the first· two detonations, the tritonal was in contact with three bags each of which contained 454g of water. (The four bags (3 water, 1 tritonal) were in a larger bag which was tied with cotton string such that the water bags remained in contact with the tritonal bag.) For the third detonation the l,362g of water was divided equally among five polyethylene bags to increase the tritonal surface area covered by the water. In this latter detonation, three of the water bags were in the same plane as the tritonal bag, one was on top of the tritonal bag and the last was underneath the tritonal bag. The six bags were held in a larger bag which was tied with cotton string to keep the water bags in contact with the tritonal bag. The MEM detonated in each trial was 235g, including Bg from the C-4/EBC.

Amatol Surrogate Amatol is a secondary explosive comprised of TNT and ammonium nitrate (AN). It is used in a wide variety of munitions. Three detonations of an amatol surrogate containing 113.5g of TNT and 113.5g AN were done on August 18, 1995. The amatol was prepared by mixing crushed TNT block with AN powder in a manner similar to that used to prepare the tritonal surrogate. The amatol surrogate was placed in the

001023 polyethylene bags and detonated in the same manner as the tritonal surrogate. The MEM of the material detonated in each of the three trials was 235g, including 8g from the C-4/EBC.

Water-suppressed Amatol Surrogate Detonation Three detonations of 227g amatol surrogate in contact with 5 bags containing a total of 1362g of water were done on August 28, 1995. The five water bags were distributed around the amatol surrogate bag in a manner similar to that used for the third water-suppressed tritonal detonation on August 22, 1995. The MEM detonated was 235g, including 8g from the C-4/EBC.

Low-Density Composition B Surrogate Composition B, a secondary explosive found in a wide variety of bombs and artillery projectiles, is a combination of RDX and TNT. The Composition B surrogate detonated on August 19, 1995 was prepared by mixing crushed TNT block with C-4. Three, 227g mixtures of the Composition B surrogate in thin polyethylene bags were detonated. The energetic composition of this composition B was 128g RDX, 86.3g TNT and 12.7g of mineral oil/polyisobutylene (from the C-4). The MEM detonated was 235g, including 8g from the C-4/EBC.

HBX Surrogate HBX is an aluminized form of Composition B; it is used in a variety of bombs, depth charges and torpedoes. The HBX surrogate was prepared by mixing aluminum powder with Composition B surrogate. Two hundred and twenty seven gram quantities of the HBX surrogate were placed in thin polyethylene bags and detonated on August 21, 1995. Three detonations were done. The energetic composition of the HBX surrogate detonated was: 109g RDX, 72g TNT, 7.8g mineral oil/polyisobutylene and 38.5g Al. The MEM of the material detonated was 235g, including 8g from the c- 4/EBC.

Aluminized Propellant Manufacturing Waste Surrogate This surrogate waste simulated the mix of plastic gloves, cotton rags, kimwipes, wood towel rods and similar materials that result from the clean-up of the vessels used to manufacture propellants; it is usually disposed of by open burning. The composition of the surrogate waste burned in the stainless steel pans on August 23, 1995 was: 65% aluminized AP (69% AP, 19% aluminum), 20% plastic material (gloves, anti-static polyethylene), 11% paper/wood/cloth and 4% diesel fuel. The propellant in one inch cubes was randomly dispersed in the combustible materials. Because the first burn resulted in a hole in the bottom of the pan, the second and third burns were done with the surrogate waste sitting on top of a 7.6 cm layer of pea gravel. At the completion of each of these last two burns, holes were found in the side of the burn pan, and melted plastic was found in the pea gravel. Approximately llOg of ash remained in the burn pan after the first burn, 40g of ash after the second burn and 65g of ash after the third burn. It was difficult to determine the weight of ash remaining when the pea gravel was used. The weight of waste surrogate burned in the three trials was l,139g, including the 4g of Hercules Unique

001024 Smokeless Powder used to initiate each burn. Since this burn was done to characterize the emissions from the waste itself, the mass of the material burned (l,139g), rather than the mass of energetic burned (741.8g) was used to calculate the emission factors.

Diesel Fuel and Dunnage Surrogate Scrap wood from ammunition boxes, dead branches from bushes/trees, styrofoam packing materials and other combustible materials (dunnage) are sometimes used with diesel fuel or other flammable liquid to assist in the open burning of munitions and other energetic materials found on training ranges, battlefields, etc. A surrogate diesel fuel soaked dunnage was burned on August 29, 1995 to determine the emissions released when dunnage is burned. Three burns were done in unlined stainless steel pans using 909g of the surrogate material and 4g of smokeless powder. The composition of the surrogate material, which was prepared using styrofoam, pasteboard and irregularly shaped pieces of wood, was: 87.5% cellulose (795.4g), and 12.5% plastic/diesel fuel (114g). Since this burn was done to characterize the emissions from the diesel fuel and dunnage mixture itself, i.e., the mixture did not contain any energetic materials, the mass of the material burned (909g) was used to calculate the emission factors.

001025 Appendix B Sampling and Analysis Methodologies Used

Continuous Emission Monitors (CEMs) Thermo Environmental (TECO) CEMs were used to measure the concentrations of C02 , CO, NO, N02 , S02 , 0 3 and HCl in the test chamber for a minimum of 25 minutes after a detonation or burn was initiated. The CEMs were located in the airlock and connected to the test chamber via a passivated stainless steel sampling manifold; their output voltages were recorded by a calibrated data acquisition system (DAS) comprised of five computers and a LAN. The pollutant concentrations measured before the detonation/burn was initiated were used to correct the pollutant concentrations measured after the detonation/burn was initiated. The model numbers and measurement principles of the TECO analyzers are: C02 (Model 41H, gas filter correlation); CO (Model 48, gas filter correlation); NO/N02 (Model 42, chemiluminescence); SO: (Model 43A, pulsed fluorescence); 0 3 (Model 49, UV absorption); and HCl (Model 15, gas filter correlation). The analyzers were calibrated at least once each test day using NIST-traceable gas standards.

EPA Method 26 Sampling System for HCl and Cl2 . Two EPA Method 26 samplers, located in the test chamber, were used to measure Cl2 and HCl concentrations when chlorine-containing propellants were burned. This sampler uses a set of Midget impingers connected in series to collect HCl and Cl2 . The second and third impingers, wr.1 ch contain O.lN H2 S04 , remove HCl from the sampled gas stream, and th~ forth impinger, which contains 0.1 N NaOH, removes Cl 2 . The imp:~~er contents are analyzed for Cl by ion chromatography. The sampling : ~ o·,.,· rate is 1 L/min.

Evacuated Canisters for CO, C02 , and SF6 Evacuated canisters were used to measure the C02 , CO and SF 6 concentrations in the test chamber. Generally, three C02 /CO sami:-><· a--"' five SF6 samples were collected from the sampling manifold in th•" airlock during each trial. These samples were taken at 5 to lC ~. : . .c: •. intervals and spanned the time during which the other pollutant samples were being collected/measured. Depending on the conce~:: of the gases, the CO and C02 analyses were done using a GC equ:;; · with either a flame ionization detector (GC/FID) or a thermal conductivity detector (GC/TCD) and the SF6 analyses were done u::- .:. : -·· electron capture detector (GC/ECD) . Evacuated Canisters for Volatile Organic Compounds (VOCs) Three, 6-L canister samples were collected from the test chamber ·.·~a the sampling manifold during each burn/detonation event. The first sample was taken approximately 5 min after the burn/detonation was initiated, the second was taken 5 to 10 minutes later and the third was taken 5 to 10 minutes after the second. Each sample was taken over a 1 to 3-min. period. The canister samples were analyzed for total non-methane hydrocarbons using EPA Method T0-12 (GC/FID) and for over 200 individual compounds using GC/FID and GC/MS. Most of these compounds were qµantified by GC/FID; approximately 20 were quantified by GC/MS. Ten of these latter compounds were also quantified by GC/FID. The voe target analytes are listed in Appendix c.

001026 High Volume Sampler This sampler collected samples for determination of: (1) particle mass; (2) metals; (3) EPA SW-846 Method 8270 SVOC compounds (Soxhlet extraction with analysis by GC/MS); and (4) remnants of the energetic materials (e.g., TNT, PETN, RDX, NG, NC, etc.) and other thermally labile analytes. Three samplers, equipped with 20.3 x 30.8 cm quartz filters, were used for each detonation/burn event. They collected test chamber samples for 20 to 30 minutes after a defonation/burn was initiated. Although the initial flow rate was 1.1 m /min, the flow rate generally decreased over the sampling period. Sometimes the filters were recovered after each trial; at other times they were recovered after the last trial had been done (composite samples). The filters were processed in the laboratory as follows.

Particle Mass and Metals The weight gain of each filte7 was determined using a laboratory balance, and then two, 6.5-cm sections were taken from each filter, combined, acid extracted and the extract analyzed using inductively coupled plasma atomic emission spectrometry (ICP) for Al, Sb, Ba, Be, Cd, Cr, Cu, Pb, Ni, Ti; and Zn. A portion of each filter was also analyzed for mercury using EPA SW-846 Method 7000. In some studies all filter sections from the. same detonation/burn were combined, but in others, all filters from the same sampler were combined.

Method 8270 svocs The composited filters were Soxhlet-extracted with 700 ml of acetonitrile, the extract was concentrated to 1 to 2 ml via rotary evaporation, and an aliquot analyzed using a HP Model 5890/5970 GC/MS operated in the full scan GC/MS mode. In some studies all filters from the same detonation/burn were combined before the Soxhlet extraction was done, but in other studies all filters from the same sampler were combined before the extraction was done. The Method 8270 target compounds are listed in Appendix C.

Energetic and Other Thermally-labile CoJ11Pounds To determine if these compounds were present, an aliquot from the above SVOC extract was analyzed by SFC/MS (supercritical fluid chromatography/MS) and, at times by SFC/TEA using a modified Lee Scientific Model 600/ Finnigan-Mat Incos 50. Two complementary SFC/MS analyses were performed: (1) negative chemical ionization for nitroaromatics, nitramines, nitrate esters and nitroso compounds; and (2) positive chemical ionization for polynuclear aromatic hydrocarbons, their nitrogen and oxygen heterocyclic counterparts, amines, and nitrosoamines. The SFC unit was run in the selected ion mode, rather than full scan mode. Extracts from some studies were also analyzed using full scan, SFC/TEA to seek out untargeted nitroso and nitro compounds and nitrate esters. The target energetic compounds are listed in Appendix C.

PM-10 Sampler (General Metals Works, Model GUV-lOH) This sampler is essentially a high volume sampler equipped with an inlet which prevents particles with aerodynamic size diameters larger than 10 microns from reaching the 20.3 by 30.8 cm, quartz filter; provided the sampling flow rate is maintained at 1.1 m /min. Only one PM-10 sampler was used in the BangBox; it was located in the test chamber. The filter samples were recovered after each

001027 detonation/burn, weighed, and analyzed for metals in a manner analogous to that used for the high volume samples. PS-1 Sampler (General Metal Works, Inc. Model PS-1} This sampler was used to collect air samples for determination of Method 8270 SVOCs and chlorinated dioxins and furans. (See Appendix A.) Separate samplers were used for the SVOCs and the dioxins/furans, because the extraction solvent for the SVOCs (methylene chloride) was not the same as that used for the dioxins/furans (toluene). Three SVOC samplers were used for each detonation/burn, but no more than two dioxins/furans samplers were used in any detonation or burn. The PS-1 samplers contained 65 to 75 g of XAD-2 resin in either a glass or aluminum cartridge. The cartridge had an internal diameter of 6 cm and was 12.5 cm in length; it contained a 10-cm diameter quartz fiber filter in its inlet. This filter was replaced after each detonation/burn, but the XAD-2 resin was not recovered until all detonation/burn trials planned for the test item had been accomplished. All filters from the same sampler were combined with the corresponding XAD-2 cartridge, extracted and analyzed using either full-scan GC/MS (SVOCs) or selective-ion-mode high resolution gas chromatography/high resolution MS (HRGC/HRMS) . Floor and Burn Pan Samples In some studies, floor sweepings and burn pan residues were analyzed for metals, Method 8270 SVOC compounds, and dioxins and furans using procedures similar to those used for the air samplers. Unfortunately, the total mass of the metal in the ash/residue was not reported.

001028 APPENDIX C TARGET ANALYTES voes The individual target voe compounds were: acetaldehyde; acetone; acetonitrile; acetylene; acrylonitrile; allyl chloride benzaldehyde; benzene; benzyl chloride; bromochloromethane; bromodichloromethane; bromoforrn; bromomethane; 1,3-butadiene; n-butane; 1-butanol; 2-butanone; 1-butene; cis-2-butene; trans-2-butene; butylacrylate; n-butylbenzene; tert-butylbenzene; butylaldehyde; carbon tetrachloride; chlorobenzene; chlorodifluoromethane; chloroethane; chloroform; chloromethane; chloroprene; (o,m,p)-chlorotoluene; cyclohexane; cyclohexene; cyclopentane; cyclopentene; n-decane; 1-decene; dibromochloromethane; dichloromoethane; (o,m,p)-dichlorobenzene; dichlorodifluoromethane; 1,1-dichloroethane; 1,2-dichloroethane; 1,1-dichloroethene; cis-1,2-dichloroethene; trans-1,2-dichloroethene; trichlorofluoromethane; 1,2-dichloropropane; cis-1,3-dichloropropene; diethyl ether; trans-1,3-trichloropropene; (m, p)-diethylbenzene; 2,3-dimethylbutane; 2,2-dimethylheptane; 2,3-dimethylhexane; 2,5-dimethylhexane; 2,3-dimethylpentane; 2,4-dimethylpentane; 1,4-dioxane; ethane; ethanol; ethylbenzene; 2-ethyl-1-butene; ethyl chloride; 3-ethylhexane; ethylene; (o,m,p)-ethyltoluene; heptanal; n-heptane; 1-heptene; hexachloro-1,3-butadiene; hexanal; n-hexane; 1-hexene; cis-2-hexene; trans-2-hexene; cis-3-hexene; indan; indene; isobutane; isobutene; isobutylbenzene; isoheptane; isohexane; isopentane; isoprene; isopropylbenzene; p-isopropyltoluene; methane; methyl bromide; methyl tert-butyl ether; 2-methylpentane; 2-methyl-1-butene; 2-methyl-2-butene; 3-methyl-1-butene; 2-methyl-1-pentene; 4-methyl-1-pentene; 2-methyl-2-pentene; cis-3-methyl-2-pentene; methylcyclohexane cis-4-methyl-2-pentene; trans-4-methyl-2-pentene; methylcyclohexane; 1-methylcyclohexene; methylcyclopentane; methylcyclopentene; methylene chloride; 2-methylheptane; 3-methylheptane; 3-methylhexane; methylisobutylketone; 3-methylpentane naphthalene; neohexane; neopentane; n-nonane; 1-nonene; 4-nonene; n-octane; 1-octene; cis-2-octene; n-pentane; 1-pentene; cis-2-pentene; trans-2-pentene; alpha-pinene; beta-pinene; propane; 1-propanol; 2-propanol; n-propylbenzene; propylene; styrene; Tetrachloroethene; 1,1,2,2-tetrachloroethane; toluene; 1,2,4-trichlorobenzene; 1,1,1-trichloroethane; 1,1,2-trichloroethane; trichloroethene; trichloroethylene; trichlorofluoromethane; 1,2,3-trimethylbenzene; 1,2,4-trimethylbenzene; 1,3,5-trimethylbenzene; 2,2,4-trimethylhexane; 2,2,4-trimethylpentane; 2,3,4-trimethylpentane; 2,2,5-trimethylhexane 2,4,4- trimethyl-1-pentene; 2,4,4-trimethyl-2-pentene; 2,2,3-trimethylpentane; n-undecane; 1-undecene; vinyl acetate; (o,m,p) -xylene; vinylidine chloride; vinyl chloride.

In addition to the above individual compounds, the following classes of voe compounds were also measured and converted to emission factors:

001029 Total Alkanes (saturated hydrocarbos) sum of all alkanes measured in the sample, including non-target alkanes;

Total Alkenes (unsaturated hydrocarbons) sum of all alkenes measured in the sample, including non-target alkenes and acetylene

Total Aromatics = sum of all aromatic compounds measured in the sample, including non target aromatics;

Total Non-methane Hydrocarbons (TNMHC) = sum of total alkanes, total alkenes, total aromatics, and all other chromatographic peaks which did not contain halogen compounds;

Total Unidentified Hydrocarbons (TUHC) = sum of all chromatographic peaks known to be hydrocarbon compounds but not identified.

Method 8270 Analytes (Hi-Vol and PS-1 Sampling Systems) Acenaphthylene; acetophenone; 2-acetylrnninofluorene; 4-aminobiphenyl; aniline; anthracene; benz(a)anthracene; benz(a)pyrene; benzidine; benzo(b)fluoranthene; benzo(g,h,i)perylene; benzoic acid; benzo(k)fluoranthene; benzyl alcohol; biphenyl; bromophenylphenylether; butylbenzylphthalate; p-chloroaniline; chlorobenzilate; bis(2-chloroethoxy)methane; bis(2-chloroethyl)ether; bis(2-chloroisopropylether; 4-chloro-3-methylphenol; 2-chloronaphthalene; 2-chlorophenol; 4-chlorophenylphenyl ether; chrysene; diallate; dibenz(a,h)anthracene; dibenzofuran; 1,2-dichlorobenzene; 1,3-dichlorobenzene; 1,4-dichlorobenzene; 3,3'-dichlorobenzidine; 2,4-dichlorophenol; 2,6-dichlorophenol; diethylphthalate; p-dimethylaminoazobenzene; dimethylbenz(a)anthracene; 3,3'-dimethylbenzidine; dimethylphenethylamine; 2,4-dimethylphenol; dimethylphthalate; di-n-butylphthalate; 1,3-dinitrobenzene; 4,6-dinitro-2-methylphenol; 2,4-dinitrophenol; 2,4-dinitrotoluene; 2,6-dinitrotoluene; di-n-octylphthalate; 1,4-diphenylamine; 1,2 diphenylhydrazine; bis(2-ethylhexyl)phthallate; N-nitrosodiphenylamine; ethyl methanesulfonate; fluoranthene; fluorene; hexachlorobenzene; hexachlorobutadiene; hexachlorocyclopentadiene; hexachloroethane; hexachloropropene; indeno(l,2,3~cd)pyrene; isophoron; isosafrole; kepone; methapyrilene; 3-methylcholanthrene; methyl methanesulfonate; 2-methylnaphthalene; 2-methylphenol; 4-methylphenol; 3-methylphenol; naphthalene; 1,4-naphthoquinone; 1-naphthylamine; 2-naphthylamine; 2-nitroaniline; 3-nitroaniline; 4-nitroaniline; nitrobenzene; 5-nitro-o-toluidine; 2-nitrophenol; 4-nitrophenol; 4-nitroquinoline-1-oxide; N-nitrosodiethylamine; N-nitrosodimethylamine; N-nitroso-di-n-butylamine; N-nitroso-di-n-propylamine; N-nitrosomethylethylamine; N-nitrosomorpholine; N-nitrosopiperidine; N-nitrosopyrrolidine; pentachlorobenzene; pentachloroethane; pentachloronitrobenzene; pentachlorophenol; perylene; phenacetin; phenanthrene; phenol; 2-picoline; pronamide; pyrene; pyridine; safrole; 1,2,4,5-tetrachlorobenzene; 2,3,4,6-tetrachlorophenol; o-toluidine; 1,2,4-trichlorobenzene; 2,4,5-trichlorophenol; 2,4,6-trichlorophenol; triethylphosphorothioate; 1,3,5-trinitrobenzene. Energetic Target Analytes Octahydro-l,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX); dibenzofuran; hexahydro-l,3,5-trinitro-1,3,5-triazine (RDX); 2,6-dichlorophenol; methyl-2,4,5-trinitrophenylnitramine (TETRYL); 1,3,5-trinitrobenzene; 2,6 dichlorphenol; 1,3-dinitrobenzene; nitrobenzene; 2-nitrodiphenylamine;

001030 2,4,6-trinitrotoluene (TNT); 4-amino-2,6-dinitrotoluene; 2-amino-4,6-dinitrotoluene; 2,6-dinitrotoluene; 2,4-dinitrotoluene; 2-methylnaphthalene; 2-nitronaphthalene; naphthalene; 1-nitropyrene; 2-nitrotoluene; 4-nitrotoluene ; 3-nitrotoluene; nitroglycerin (NG); nitroguanidine (NQ); nitrocellulose (NC); Benz(A)pyrene; pentaerythritol tetranitrate (PETN); benz(a)anthracene; phenol.

Polychlorinated dibenzo-p-furan Analytes (Furans) Total chlorinated dibenz-p-dioxin (TCDD) ; Total pentachlorinated dibenzo-p-dioxin (PeCDD); Total hexachlorinated dibenzo-p-dioxin (HxCDD); Total heptachlorinated dibenzo-p-dioxin (HpCDD); Octachlorinated dibenzo-p-dioxin (OCDD); 2378-TCDD; 1234678-HpCDD.

Polychorinated dibenzo-p-dioxin Analytes (Dioxins} Total tetrachlorinated dibenzofurans (TCDF); Total pentachlorinated dibenzofurans (PeCDF); Total hexachlorinated dibenzofurans (HxCDF) ; Total heptachlorinated dibenzofurans (HpCDF); Octachlorinated dibenzofuran (OCDF); 2378-TCDF; 12378-PeCDF; 23478-PeCDF; 123478-HxCDF; 123678-HxCDF; 234678-HxCDF; 1234678-HpCDF; 1234789-HpCDF.

001031 Appendix D Emission Factors for Burns

SPECIAL NOTES:

The emission factors in this database apply to the open burning of energetic materials in a burn pan. A value of O.OOe+OO means that the compound (analyte) was either not detected, or, was detected at only the background level. Values of 0.00e+OO were not used in calculating the average (AVG) emission factors in the database. A blank cell means that either no sample was collected or that the sample collected was either lost or not valid.

The emission factors in this table are unitless. The user can convert them to any mass units desired (e.g., grams compound per gram NEW). A value e-06 means that the quantity in the ntunerator is to be multiplied by 10 to the -6 power. For example, 1.1 e-06 could be written as either 1.1 x 10-6 g/g NEW or 1 microgram/g NEW.

NOTE - fl'J-3 /'K 0 ;>r;-L.t.../l/f)/ S/lou~D 13t· /11-/ ~/(or>;"·LL/1/f/T /N 7111.5 /t/'/'Ell/0/-1,

001032 EMISSION FACTORS

COMPOUND ITEM TRIAL 1 TRIAL 2 TRIAL 3 !AVERAGE UN CORR cis-2-Pentene diesel furel and dunnage 0.00e+OO O.OOe+OO 0.00e+OO 0.00e+OO 0.00e+OO cis-2-Pentene Manufacturer's waste - aluminized propellant with diesel 3.80e-07 3.lOe-07 1. OOe-06 5.60e-07 6.60e-07 cis-2 Pentene Propellant, ammonium perchlorate, aluminized 0.00e+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, ammonium perchlorate, nonaluminized 0.00e+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, double base O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, M-3 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 9.lOe-08 cis-2-Pentene Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, MK-23 O.OOe+OO O.OOe+OO 9.BOe-08 cis-2 Pentene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Propellant, PBXN-110 O.OOe+OO O.OOe+OO 1. OOe-07 cis-2-Pentene Propellant, Smokey Sam O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO 0.00e+OO cis-2-Pentene Smokeless Powder {Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO i-Butane Diesel fuel and dunnage O.OOe+OO 1.20e-06 O.OOe+OO 1.20e-06 l.40e-06 i-Butane Manufacturer's waste - aluminized propellant with diesel 2 .,lOe-07 l.BOe-06 2.lOe-06 l.40e-06 2.30e-06 i-Butane Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO i-Butane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-But.ane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Butane Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.BOe-06 i-Butane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO l.80e-07 i-Butane Propellant, M-9 4.30e-08 4.30e-08 8.50e-08 i-Butane Propellant, MK-23 0.00e+OO O.OOe+OO 2.00e-07 i-Butane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Butane Propellant, PBXN-110 O.OOe+OO O.OOe+OO 2.00e-07 i-Butane Propellant, Smokey Sam O.OOe+OO 0.00e+OO 7.80e-07 i-Butane Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 9.60e-07 i-Butene Diesel fuel and dunnage O.OOe+OO 1.70e-06 2.30e-06 2.00e-06 2.00e-06 i-Butene Manufacturer's waste - aluminized propellant with diesel 1. 30e-05 2.lOe-06 2.60e-06 5.80e-06 5.BOe-06 i-Butene Propellant, ammonium perchlorate, aluminized 1. OOe-05 O.OOe+OO l.OOe-05 l.OOe-05 i-Butene Propellant, arranonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO i-Butene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Butene Propellant, M-3 7.90e-07 0.00e+OO O.OOe+OO 7.90e-07 8.00e-07 i-Butene Propellant, M-43 (USN) 5.40e-07 5.40e-07 5.40e-07 i-Butene Propellant, M-9 2.60e-07 2.60e-07 2.60e-07 i-Butene Propellant, MK-23 4.90e-07 4.90e-07 4.90e-07 i-Butene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO i-Butene Propellant, PBXN-110 l.30e-06 1.30e-06 l. 30e-06 i-Butene Propellant, Smokey Sam 2.40e-06 2.40e-06 2.40e-06 i-Butene Smokeless Powder (Hercules Uniatle) 9.60e-07 9.60e-07 9.60e-07

001033 i-Pentane Diesel fuel and dunnage 0.00e+OO 6.90e-06 l.lOe-05 8.90e-06 1. OOe-05 i-Pentane Manufacturer's waste - aluminized propellant with diesel O.OOe+OO O.OOe+OO 2.30e-05 2.30e-05 1. 80e-05 i-Pentane Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Pentane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Pentane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Pentane Propellant, M-3 3.00e-08 O.OOe+OO O.OOe+OO 3.00e-08 l.80e-07 i-Pentane Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 3.60e-07 i-Pentane Propellant, M-9 O.OOe+OO O.OOe+OO 8.50e-08 i-Pentane Propellant, MK-23 O.OOe+OO O.OOe+OO 6.90e-07 i-Pentane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Pentane Propellant, PBXN-110 O.OOe+OO O.OOe+OO l.OOe-06 i-Pentane Propellant, Smokey Sam 7.80e-07 7.80e-07 2.70e-06 i-Pentane Smokeless Powder (Hercules Unique) 1. 20e-06 l.20e-06 3.80e-06 m-Ethyltoluene Diesel fuel and dunnage l.lOe-04 l.40e-04 l.40e-04 l.30e-04 4.60e-04 m-Ethyltoluene Manufacturer's waste - aluminized propellant with diesel 2.20e-06 1. 50e-06 4.lOe-06 2.60e-06 6.90e-05 m-Ethyltoluene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO m-Ethyltoluene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO m-Ethyltoluene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO m-Ethyltoluene Propellant, M-3 5.00e-08 0.00e+OO l.40e-07 9.70e-08 5.50e-07 m-Ethyltoluene Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 3.60e-07 m-Ethyltoluene Propellant, M-9 4.30e-08 4.30e-08 6.00e-07 m-Ethyltoluene Propellant, MK-23 3.00e-07 3.00e-07 9.80e-07 m-Ethyltoluene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO m-Ethyltoluene Propellant, PBXN-110 2.00e-07 2.00e-07 7.00e-07 m-Ethyltoluene Propellant, Smokey Sam 2.00e-06 2.00e-06 5.90e-06 m-Ethyltoluene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 2.20e-06 n-Butane Diesel fuel and dunnage 1. 30e-06 6.BOe-06 5.70e-06 4.60e-06 5.40e-06 n-Butane Manufacturer's waste - alumini-zed propellant with diesel 5.50e-06 2.40e-06 2.00e-05 9.30e-06 l.80e-05 n-Butane Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Butane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Butane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO n-Butane Propellant, M-3 9.00e-08 l.80e-07 O.OOe+OO l.50e-07 5.60e-07 n-Butane Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 5.40e-07 n-Butane Propellant, M-9 4.30e-08 4.30e-08 3.40e-07 n-Butane Propellant, MK-23 O.OOe+OO O.OOe+OO 5.90e-07 n-Butane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Butane Propellant, PBXN-110 l.OOe-07 l.OOe-07 6.00e-07 n-Butane Propellant, Smokey Sam O.OOe+OO O.OOe+OO 2.70e-06 n-Butane Smokeless Powder (Hercules Unique) 4.80e-07 4.80e-07 3.80e-06 n-Decane Diesel fuel and dunnage l.50e-03 O.OOe+OO 2.00e-03 l.80e-03 l.80e-03 n Decane Manufacturer's waste - aluminized nrooellant with diesel 9.20e-06 l. lOe-05 2.30e-05 l.40e-05 3.lOe 05

001034 n-Decane Propellant, ammonium perchlorate, aluminized O.OOe+OO o.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO n-Decane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO o.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO n-Decane Propellant, double base O.OOe+OO o.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO n-Decane Propellant, M-3 4.20e-07 8.70e-07 l.40e-07 5.90e-07 l.90e-06 n-Decane Propellant, M-43 (USN) 8.20e-07 B.20e-07 3.70e-06 n-Decane Propellant, M-9 O.OOe+OO O.OOe+OO 1. 30e-06 n-Decane Propellant, MK-23 O.OOe+OO O.OOe+OO 3.20e-06 n-Decane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Decane Propellant, PBXN-110 l.30e-06 l.30e-06 4.40e-06 n-Decane Propellant, Smokey Sam 5.90e-06 5.90e-06 2.20e-05 n-Decane Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO B.60e-06 n-Heptane Diesel fuel and dunnage 3.lOe-05 8.00e-05 6.60e-05 5.90e-05 6.00e-05 n-Heptane Manufacturer's waste - aluminized propellant with diesel 3.50e-06 2.40e-06 B.30e-06 4.70e-06 7.30e-06 n-Heptane Propellant, anunonium perchlorate, aluminized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Heptane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Heptane Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Heptane Propellant, M-3 2.70e-07 5.lOe-07 9.40e-08 3.lOe-07 l.60e-06 n-Heptane Propellant, M-43 (USN) 9.lOe-08 9.10•-08 2.?0e-07 n-Heptane Propellant, M-9 O.OOe+OO O.OOe+OO l.lOe-06 n-Heptane Propellant, MK-23 O.OOe+OO O.OOe+OO 4.90e-07 n-Heptane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Heptane Propellant, PBXN-110 O.OOe+OO O.OOe+OO 8.00e-07 n-Heptane Propellant, Smokey Sam 2.00e-06 2.00e-06 3.lOe-06 n-Heptane Smokeless Powder (H'ercules Unique) 7.20e-07 7.20e-07 l.20e-06 n-Hexane Diesel fuel and dunnage 6.40e-06 2.30e-05 1.90e-05 l.60e-05 l.70e-05 n-Hexane Manufacturer's waste - aluminized propellant with diesel 2.70e-06 l.SOe-06 6.?0e-06 3.70e-06 5.70e-06 n-Hexane Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Hexane Propellant, ammonium perchlorate, nonal umini zed O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO n-Hexane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Hexane Propellant, M-3 1.60e-05 l.40e-05 4.90e-06 l.90e-05 9:00e-05 n-Hexane Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 3.60e-07 n-Hexane Propellant, MK-23 O.OOe+OO O.OOe+OO 7.90e-07 n-Hexane Propellant, M31A1El O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO n-Hexane Propellant, PBXN-110 0. OOe+OO O.OOe+OO 1. 30e-06 n-Hexane Propellant, Smokey Sam 2.?0e-06 2.70e-06 3.90e-06 n-Hexane Smokeless Powder (Hercules Unique) 9.60e-07 9.60e-07 2.20e-06 n-Nonane Diesel fuel t=1nd dunnage 8.00e-04 l.20e-03 l.lOe-03 1. OOe-03 1.00e-03 n-Nonane H<1.n1.lfar:tc11Pr s ...... ,s~ e alu1:Linized prop<:>llant with diesel l.lOe-05 7.60e-06 2.lOe-05 l.30e-05 2.40e-05

n-Nonane rr~r"'l :.v,·. 'p ;· 1::·:~ r"r -!il, r:He, ;il·-~minized 0. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

: : .. .. , .. ; . ~ : \'<', . ' .l ; ' J ~· l : : i :- "' l 0 OOe-l-00 O.OOe+OO O.OOe+OO O.OOe+OO n-Nonane , ' ' O.OOe+OO n-Nonane : ! .. o 00~+00 C 0(ie+00 O.OOe+OO O.OOe+OO O.OOe+OO

7 1

001035 n Nonane Propellant, M-3 7.80e-08 l.40e-07 0.00e+OO l.20e-07 2.30e-07 n-Nonane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 9.lOe-08 n-Nonane Propellant, M-9 O.OOe+OO O.OOe+OO l.70e-07 n-Nonane Propellant, MK-23 O.OOe+OO O.OOe+OO 2.00e-07 n-Nonane Propellant, M31A1El O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Nonane Propellant, PBXN-110 2.00e-07 2.00e-07 5.00e-07 n-Nonane Propellant, Smokey Sam 1. 20e-06 1. 20e-06 l.60e-06 n-Nonane Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 4.SOe-07 n-Octane Diesel fuel and dunnage 1. 50e-04 3. 20e-04 2.80e-04 2.50e-04 2.50e-04 n-Octane Manufacturer's waste - alumini;ed propellant with diesel 6.30e-06 4.20e-06 l.20e-05 7.60e-06 l.30e-05 n-Octane Propellant, ammonium perchlorate, aluminized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Octane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Octane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Octane Propellant, M-3 2.90e-07 6.40e-07 l.90e-07 4.30e-07 l.60e-06 n-Octane Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 2.70e-07 n-Octane Propellant, M-9 O.OOe+OO O.OOe+OO l.lOe-06 n-Octane Propellant, MK-23 O.OOe+OO O.OOe+OO 2.00e-07 n-Octane Propellant, M31A1El O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Octane Propellant, PBXN-110 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Octane Propellant, Smokey Sam 1. 20e-06 l.20e-06 1. 60e-06 n-Octane Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 4.80e-07 n-Pentane Diesel fuel and dunnage 2.00e-06 1. 30e-05 l.20e-05 9.lOe-06 1. OOe-05 n-Pentane Manufacturer's waste - aluminized propellant with diesel 2.60e-06 l.lOe-06 9.00e-06 4.30e-06 7.20e-06 n-Pentane Propellant, amnoniutn perchlorate, aluminized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Pentane Propellant, amnonium perchlorate, nonalurninized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Pentane Propellant, double base O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Pentane Propellant, M-3 5.30e-07 l.50e-06 4.20e-07 8.60e-07 3.30e-06 n-Pentane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 3.60e-07 n-Pentane Propellant, M-9 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Pentane Propellant, MK-23 O.OOe+OO O.OOe+OO 7:9oe-07 n-Pentane Propellant, M31A1El O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO n-Pentane Propellant, PBXN-110 O.OOe+OO O.OOe+OO l.lOe-06 n-Pentane Propellant, Smokey Sam 7.80e-07 7.80e-07 2.70e-06 n-Pentane Smokeless Powder (Hercules Unique) 9.60e-07 9.60e-07 2.60e-06 p-Ethyltoluene Diesel fuel and dunnage l.20e-04 l.70e-04 l.70e-04 1. 50e-04 l.60e-04

p-Ethyltoluene . Manufacturer's waste - aluminized propellant with diesel 5.40e-06 2.90e-06 6.70e-06 5.00e-06 B.lOe-06 p-Ethyltoluene Propellant, ammonium perchlorate, aluminized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO o.ooe+oo O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, double base O.OOe+OO o.ooe+oo O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, M-3 5.60e-07 3.20e-07 2.20e-06 9.80e-07 2.lOe-06 p-Ethvltoluene Pronellant, M-43 (USN) l.80e-07 l.80e-07 9.lOe-07

001036 p Ethyltoluene Propellant, M-9 4.00e-06 4.00e-06 5.50e-06 p-Ethyltoluene Propellant, MK-23 O.OOe+OO O.OOe+OO l.lOe-06 p-Ethyltoluene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-.Ethyltoluene Propellant, PBXN-110 3.00e-07 3.00e-07 l.40e-06 p-Ethyltoluene Propellant, Smokey Sam 7.lOe-06 7.lOe-06 1.lOe-05 p-Ethyltoluene Smokeless Powder (Hercules Unique) 4.BOe-07 4.BOe-07 2.40e-06 p-Ethyltoluene Diesel fuel and dunnage 1. 20e-04 6.60e-06 6.90e-07 4.lOe-05 4.20e-05 p-Ethyltoluene Manufacturer's waste - aluminized propellant with diesel 2.00e-06 2.00e-06 O.OOe+OO 2.00e-06 5.30e-06 p-Ethyltoluene Propellant, am:monium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, M-3 O.OOe+OO 2.00e-07 2.BOe-08 3.70e-08 5.70e-07 p-Ethyltoluene Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 3.90e-07 p-Ethyltoluene Propellant, M-9 O.OOe+OO O.OOe+OO 7.20e-07 p-Ethyltoluene Propellant, MK-23 O.OOe+OO O.OOe+OO 4.20e-07 p-Ethyltoluene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene Propellant, PBXN-110 4.30e-07 4.30e-07 8.SOe-07 p-Ethyltoluene Propellant, Smokey Sam 1.70e-06 1.70e-06 3.30e-06 p-Ethyltoluene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO l.OOe-06 trans-2-Butene Diesel fuel and dunnage 3.60e-06 1.80e-06 3.30e-06 2.90e-06 2.90e-06 trans-2-Butene Manufacturer's waste - aluminized propellant with diesel 2.70e-05 1.40e-05 2.lOe-05 2.lOe-05 2.lOe-05 trans-2-Butene Propellant, ammonium perchlorate, aluminized . O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Propellant, M-3 1.90e-07 O.OOe+OO O.OOe+OO 1.90e-07 l.90e-07 trans-2-Butene Propellant, M-43 (USN) 1.BOe-07 1.SOe-07 l.BOe-07 trans-2-Butene Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Propellant, MK-23 2.00e-07 2.00e-07 2.00e-07 trans-2-Butene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Propellant, PBXN-110 4.00e-07 4.00e-07 !l.OOe-07 trans-2-Butene Propellant, Smokey Sam 2.40e-06 2.40e-06 2.40e-06 trans-2-Butene Smokeless Powder (Hercules Uniqu'e) O.OOe+OO O.OOe+OO Q.OOe+OO O.OOe+OO O.OOe+OO trans-2-Hexene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Hexene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.ODe+OO O.OOe+OO trans-2-Pentene Diesel fuel and dunnage O.OOe+OO O.OOe+OO 1.lOe-06 1.lOe-06 l.lOe-06 trans-2-Pentene Manufacturer's waste - aluminized propellant with diesel O.OOe+OO 3.80e-07 1.SOe-06 9.60e-07 1. 20e-06 trans-2-Pentene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO o.ooe~oo O.OOe+OO trans-2-Pentene Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Propellant, M-43 IUSNJ O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Prone} lant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

001037 trans 2-Pentene Propellant, MK 23 O.OOe+OO O.OOe+OO 9.80e-08 trans-2 Pentene Propellant, M31A1E1 O.OOe+OO O.OOe+OD D.OOe+OD O.OOe+DO O.OOe+OO trans 2-Pentene Propellant, PBXN-110 O.OOe+OO O.OOe+OO 2.00e-07 trans 2 Pentene Propellant, Smokey Sam O.QOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe•OO O.OOe+OO Acetylene Diesel fuel and dunnage l.20e-04 7.30e-05 9.lOe-05 9.50e-05 9.60e-05 Acetylene Manufacturer's waste - aluminized propellant with diesel l.80e-03 1. 30e-03 1. 50e-03 1.60e-03 1.60e-03 Acetylene Propellant, ammonium perchlorate, aluminized l.OOe-05 O.OOe+OO 1. OOe-05 1.00e-05 Acetylene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Acetylene Propellant, composite (MK-6) (Sandia) 2.lOe-05 2.10e-05 Acetylene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Acetylene Propellant, double base (Sandia) 2.00e-04 2.00e-04 Acetylene Propellant, M-3 7.70e-06 1. 50e-05 l.90e-05 1. 30e-05 7.90e-06 Acetylene Propellant, M-43 (USN) 5.90e-06 5.90e-06 6.40e-06 Acetylene Propellant, M-9 9.00e-06 9.00e-06 9.20e-06 Acetylene Propellant, MK-23 5.50e-06 5.50e-06 6.20e-06 Acetylene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Acetylene Propellant, PBXN-110 3.lOe-06 3.10e-06 3.70e-06 Acetylene Propellant, Smokey Sam 8.30e-04 8 .30e-04 8.30e-04 Acetylene Smokeless Powder (Hercules Uniqtie} 1. 2De-D6 1. 2De-D6 3.6De-D6 Acenaphthalene Manufacturer's waste - aluminized propellant with diesel 1.1De-D4 5.DDe-04 3.20e-04 1. 60e-04 O.OOe+OO Aluminum Diesel fuel and dunnage O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 2.SOe-06 Aluminum Manufacturer's waste - aluminized propellant with diesel 6.lOe-03 8.50e-03 9.30e-02 3.60e-02 3.60e-02 Aluminum Propellant, ammonium perchlorate, aluminized 9.40e-03 1.20e-02 1. lOe-02 1.10e-02 Aluminum Propellant, arranonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1.00e-05 Aluminum Propellant, composite IMK-61 (Sandia) 1. 30e-03 1.30e-03 Aluminum Propellant, M-3 6.SOe-07 8.50e-07 l.40e-05 5.10e-06 5.lOe-06 Aluminum Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO D.ODe+OO O.OOe+OO Barium Manufacturer's waste - aluminized propellant with diesel l.60e-05 2.00e-05 2.20e-04 8.60e-05 B.90e-05 Barium Propellant, ammonium perchlorate, aluminized 1.00e-05 l.OOe-05 1.00e-05 1.00e-05 Barium Propellant, ammonium perchlorate, nonalum.inized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium Propellant, composite (MK-61 (Sandia) l.60e-06 1.60e-06 Barium Propellant, double base (Sandia) O.OOe+OO O.OOe+OO Barium Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Barium Propellant, M-9 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO Barium Propellant, M31A1El O.OOe+OO 0.00e•OO O.OOe+OO O.OOe+OO 0.00e+OO Benzene Diesel fuel and dunnage l.OOe-04 5.20e-05 8.10e-05 7.80e-05 8.00e-05 Benzene Manufacturer's waste· aluminized propellant with diesel 6.40e-04 2.90e-04 4.lOe-04 4.50e-04 4.SOe-04 Benzene Propellant, ammcnium rerchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Benzene Prooellant. am!TY:'nium r::er-:hl".lrate. nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

001038 Benzene Propellant, composite (MK-6) (Sandia) 5.70e-05 5.70e-05 Benzene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Benzene Propellant, double base (Sandia) l.20e-04 l.20e-04 Benzene Propellant, M-3 6.40e-06 l.!Oe-05 1. 40e-05 l.OOe-05 7.70e-06 Benzene Propellant, M-43 IUSN) 1. 70e-06 1. 70e-06 2.30e-06 Benzene Propellant, M-9 3.20e-06 3.20e-06 4.20e-06 Benzene Propellant, MK-23 O.OOe+OO O.OOe+OO 2.00e-06 Benzene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Benzene Propellant, PBXN-110 4.90e-06 4.90e-06 7.70e-06 Benzene Propellant, Smokey Sam 6.60e-05 6.60e-05 7.00e-05 Benzene Smokeless Powder (Hercules Unique) 1. 20e-06 1. 20e-06 3.lOe-06 Carbon tetrachloride Diesel fuel and dunnage 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.90e-07 Carbon tetrachloride Manufacturer's waste - alurninized propellant with diesel 3.30e-06 6.30e-06 7.30e-06 5.60e-06 6.00e-06 Carbon tetrachloride Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+-00 O.OOe+OO Carbon tetrachloride Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Carbon tetrachloride Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Carbon tetrachloride Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Carbon tetrachloride Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 5.00e-07 Carbon tetrachloride Propellant, M-9 2.30e-07 2.30e-07 2.30e-07 Carbon tetrachloride Propellant, MK-23 l. lOe-06 1.lOe-06 l.60e-06 Carbon tetrachloride Propellant. M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Carbon tetrachloride Propellant, PBXN-110 O.OOe+OO O.OOe+OO 5.SOe-07 Carbon tetrachloride Propellant, Smokey Sam O.OOe+OO O.OOe+OO 2.20e-06 Carbon tetrachloride Smokeless Powder (Hercules Unique) O.OOe+OO o.ooe+oo l.30e-06 Chloroform Diesel fuel and dunnage O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Manufacturer's waste - aluminized propellant with diesel 2.20e-06 2.40e-06 2.30e-06 2.30e-06 2.50e-06 Chloroform Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO Chloroform Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+-00 O.OOe+OO Chloroform Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO Chloroform Propellant, M-43 (USN) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Propellant, MK-23 4.20e-07 4.20e-07 4.20e-07 Chloroform Propellant, M31A1El 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Chloroform Propellant, PBXN-110 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Propellant, Smokey Sam O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO Chloroform Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO Q.OOe+OO O.OOe+OO 0.00e+OO Chromium Diesel fuel and dunnage O.OOe+OO 0.00e+OO O.OOe+-00 O.OOe+OO O.OOe+OO Chromium Manufacturer's waste - aluminized propellant with diesel O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO 0.00e+OO Chromium Propellant, ammonium perchlorate, aluminized 1. ooe-05 l.OOe-05 l.OOe-05 l.OOe-05 Chromium Prooellant, ammonium nerchlorate, nonaluminized 1. OOe-05 l.OOe-05 1. OOe-05 1. OOe 05

001039 Chromium Propellant, composite IMK-6) (Sandia) 4.80e-05 4.80e-05 Chromium Propellant, double base (Sandia) O.OOe+OO O.OOe+OO Chromium Propellant, M 3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO C12 Manufacturer's waste - aluminized propellant with diesel 2.80e-04 l.50e-05 1.60e-04 2.00e-04 Cl2 Propellant, ammonium perchlorate, alurninized 5.00e-03 4.20e-03 4.60e-03 Cl2 Propellant, ammonium perchlorate, nonaluminized 1. lOe-02 8.20e-03 9.20e-03 Copper Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Copper Manufacturer's waste - aluminized propellant with diesel 1. 50e-05 O.OOe+OO O.OOe+OO 1.50e-05 1.90e-05 Copper Propellant, ammonium perchlorate, nonaluminized 5.00e-05 1.00e-04 8.0De-05 8.00e-05 Copper Propellant, double base O.OOe+OO 3.20e-04 1.60e-04 l.60e-04 Copper Propellant, double base (Saodia) 3.70e-02 3.70e-02 Copper Propellant, M-3 3.40e-06 8.30e-06 2.SOe-06 4.40e-06 2.90e-05 Copper Propellant, M-9 6.50e-06 6.50e-06 4.60e-05 Copper Propellant, M31A1El 1.00e-05 1.00e-05 Cyclohexane Diesel fuel and dunnage l.30e-05 3.80e-05 3.00e-05 2.70e-05 2.70e-05 Cyclohexane Manufacturer's waste - aluminized propellant with diesel 1 .'70e-06 9.20e-07 3.30e-06 2.00e-06 3.40e-06 Cyclohexane Propellant, ammonium perchlorate, aluminized 0. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Propellant, ammonium perchlorate, nonalurninized O.OOe+OO O.OOe+OO O.OOe+OO o.ooe+oo O.OOe+OO Cyclohexane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Propellant, M-3 1.30e-07 l.40e-07 O.OOe+OO 1.50e-07 5.00e-07 Cyclohexane Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 l.BOe-07 Cyclohexane Propellant, M-9 O.OOe+OO O.OOe+OO 4.70e-07 Cyclahexane Propellant, MK-23 O.OOe+OO O.OOe+OO 3.90e-07 Cyclahexane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Propellant, PBXN-110 O.OOe+OO O.OOe+.00 8.00e-07 Cyclohexane Propellant, Smokey Sam 1. 20e-06 l.20e-06 2.00e-06 Cyclohexane Smokeless Powder (Hercules Unique) 4.80e-07 4.80e-07 9.60e-07 Cyclopentane Diesel fuel and dunnage 0. OOe+OO 1.SOe-06 l.40e-06 l.50e-06 l.50e-06 Cyclopentane Manufacturer's waste - aluminized propellant with diesel 1. 50e-07 7.60e-08 5.40e-07 2.SOe-07 4.30e-07 Cyclopentane Propellant, ammonium perchlorate, aluminized O.OOe+.00 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclapentane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.70e-08 Cyclopentane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 9.lOe-08 Cyclopentane Propellant, M-9 4.30e-08 4.30e-08 8.50e-08 Cyclopentane Propellant, MK-23 O.OOe+OO O.OOe+OO 9.80e-08 Cyclopentane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Propellant, PBXN-110 O.OOe+OO O.OOe+OO 2.00e-07 Cyclopentane Propellant, Smokey Sam O.OOe+OO O.OOe+OO 3.90e-07 Cyclonentane Smokeless Powder (Hercules Uni~·e) O.OOe+OO O.OOe+OO 2.40e-07

001040 Cyclopentene Diesel fuel and dunnage 0.00e+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Cyclopentene Manufacturer's waste - aluminized propellant with diesel 9.80e-07 7.60e-07 l.lOe-06 9.40e-07 9.40e-07 Cyclopentene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Cyclopentene Propellant, double base O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Cyclopentene Propellant, M-3 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Cyclopentene Propellant, M-43 \USN) 9.lOe-08 9.lOe-08 9.lOe-08 Cyclopentene Propellant, M-9 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Cyclopentene Propellant, MK-23 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.QOe+OO Cyclopentene Propellant, M31A1El O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO Cyclopentene Propellant, PBXN-110 . 1. OOe-07 1.00e-07 l.OOe-07 Cyclopentene Propellant, Smokey Sam O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO co Diesel fuel and dunnage 7.40e-03 4.70e-03 6.00e-03 6.00e-03 co Manufacturer's waste - aluminized propellant with diesel 2.20e-02 l.90e-02 l.90e-02 2.00e-02 co Propellant, ammonium perchlorate, aluminized 2.lOe-03 3.SOe-04 l.20e-03 co Propellant, ammonium perchlorate, nonaluminized l.30e-04 l.SOe-04 1.40e-04 co Propellant, composite (MK-6) (Sandia) 4.20e-03 4.20e-03 co Propellant, double base 1. SOe-03 l.SOe-03 1. SOe-03 co Propellant, double base (Sandia) 9.SOe-04 9.SOe-04 co Propellant, M-3 l.60e-02 l.60e-02 l.SOe-02 l.40e-02 co Propellant, M-43 (USN) 6.60e-04 6.60e-04 co Propellant, M-9 2.70e-03 2.?0e-03 co Propellant, MK-23 2.?0e-04 2.70e-04 co Propellant, M31A1El l.40e-04 l.lOe-04 l.30e-04 l.30e-04 co Propellant, PBXN-110 l.20e-03 l.20e-03 co Propellant, Smokey Sam 7.20e-02 7.20e-02 co Smokeless Powder (Hercules Unique) l.60e-03 1.60e-03 C02 Diesel fuel and dunnage 1.SOe+OO 1.SOe+OO l.SOe+OO l.SOe+OO C02 Manufacturer's waste - aluminized propellant with diesel l.lOe+OO l.lOe+OO 1.20e+OO l.lOe+OO C02 Propellant, anunonium perchlorate, aluminized 3.lOe-01 3.20e-01 3. 20e-Ol C02 Propellant, ammonium perchlorate, nonaluminized 3. ?Oe-01 3.?0e-01 3.70e-Ol C02 Propellant, composite (MK-6) (Sandia) 4.20e-01 4.20e-Ol C02 Propellant, double base 6.70e-01 6.70e-01 6.70e-Ol C02 Propellant, double base (Sandia) 9.?0e-01 9.70e-Ol C02 Propellant, M-3 l.20e+OO 1.20e+OO l.20e+OO l.20e+OO C02 Propellant, M-43 (USN) 7.70e-01 7.70e-Ol C02 Propellant. M-9 9.40e-01 9.40e-Ol C02 PrcrPl}rl;it. M!'-;' l 5.40e-01 5.40e-Ol

C02 f' r ' I " l l I ~l: . ~· · '. .\ : : ! S.40e-01 5.60e-01 6.80e-Ol 5.90e-Ol C02 : : ! . '' , .. I'.·· 1. ooe..r;c l.OOe+OO C02 ; : .. 4 20f>- c, I 4.20e-Ol

-i 7

001041 C02 Smokeless Powder (Hercules Unique) 8.70e-01 8.70e-Ol Ethane Diesel fuel and dunnage O.OOe+OO 7.20e-06 1. 20e-05 9.30e-06 1. OOe-05 Ethane Manufacturer's waste - aluminized propellant with diesel 1.80e-05 3.80e-06 6.90e-06 9.50e-06 1. OOe-05 Ethane Propellant, ammonium perchlorate, aluminized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethane Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe.+.00 O.OOe+OO Ethane Propellant, M-3 l.lOe-06 l.20e-06 2.80e-07 1. 30e-06 1.50e-06 Ethane Propellant, M-43 (USN) l.80e-07 l.80e-07 1.50e-06 Ethane Propellant, M-9 5.60e-07 5.60e-07 1.40e-06 Ethane Propellant, MK-23 O.OOe+OO O.OOe+OO 9.80e-07 Ethane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethane Propellant, PBXN-110 l.OOe-06 1.00e-06 2.lOe-06 Ethane Propellant, Smokey Sam O.OOe+OO O.OOe+OO 5.50e-06 Ethane Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 2.60e-06 Ethylbenzene Diesel fuel and dunnage 4.30e-05 6.20e-05 6.lOe-05 5.50e-05 5.70e-05 Ethylbenzene Manufacturer's waste - aluminized propellant with diesel 2.30e-06 1. 30e-06 3.50e-06 2.40e-06 4.20e-06 Ethylbenzene Propellant~ ammonium perchlorate, aluminized O.OOe+OO O.ODe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylbenzene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylbenzene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylbenzene Propellant, M-3 3.00e-07 O.OOe+OO 1.40e-07 2.60e-07 1. OOe-06 Ethylbenzene Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 3.60e-07 Ethylbenzene Propellant, M-9 O.OOe+OO O.OOe+OO 8.50e-07 Ethyl benzene Propellant, MK-23 O.OOe+OO O.OOe+OO 6.90e-07 Ethyl benzene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylbenzene Propellant, PBXN-110 8.00e-07 8.00e-07 1. 60e-06 Ethylbenzene Propellant, Smokey Sam 1. 20e-06 1. 20e-06 2.70e-06 Ethylbenzene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO l.20e-06 Ethylene Diesel fuel and dunnage 6.60e-05 7.20e-05 8.50e-05 7.40e-05 7.50e-05 Ethylene Manufacturer's waste - alum.inized propellant with diesel 3.lOe-04 1. 60e-04 2.30e-04 2.30e-04 2.30e-04 Ethylene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylene Propellant, M-3 5.80e-06 8.80e-06 J.30e-06 7.80e-06 5.90e-06 Ethylene Propellant, M-43 (USN) 4.80e-06 4.80e-06 5.00e-06 Ethylene Propellant, M-9 6.50e-06 6.50e-06 6.60e-06 Ethylene Propellant, MK-23 9.80e-07 9.80e-07 1. 20e-06 Ethylene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylene Propellant, PBXN-110 6.70e-06 6.70e-06 6.80e-06 Ethylene Propellant, Smokey Sam 7.20e-05 7.20e-05 7.JOe-05 Ethylene Smokeless Powder (Hercules Unique) 2.40e-07 2.40e-07 l.40e-06 Fluoranthene Manufacturer's waste - aluminized orooellant with diesel 5.00e-05 O.OOe+OO 3.60e-04 2.00e-04 2.00e-04

001042 HCl Propellant, ammonium perchlorate, aluminized 2.lOe-01 2.lOe-01 2.lOe-01 2.lOe-01 HCl Propellant, ammonium perchlorate, nonaluminized 2.lOe-01 2.lSe-01 2.lSe-01 2.lSe-01 HCl Propellant, composite (MK-6) (Sandia) 9.40e-02 9.40e-02 HCl Propellant, M-43 (USN) l.OOe-03 1. OOe-03 l.OOe-03 HCl Propellant, MK-23 1. 90e-03 l.90e-03 l.90e-03 HCl Propellant, PBXN-110 l.SOe-04 l.80e-04 l.80e-04 HCl Propellant, Smokey Sam 2.90e-02 2.90e-02 2.90e-02 HCl Manufacturer's waste - aluminized propellant with diesel 8.SOe-02 7.70e-02 8.80e-02 8.30e-02 Lead Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Lead Manufacturer's waste - alurninized propellant with diesel 0.00e+OO 7.30e-05 4.90e-04 2.80e-04 2.80e-04 Lead Propellant, arornonium perchlorate, alurninized 4.00e-05 4.00e-05 4.00e-05 Lead Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead Propellant, double base 5.80e-03 5.SOe-03 5.60e-03 5.60e-03 Lead Propellant, double base (Sandia) 1. 30e-02 l.30e-02 Lead Propellant, M-3 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloride Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Methyl chloride Manufacturer's waste - aluminized propellant with diesel 2.70e-05 1.40e-05 l.90e-05 2.00e-05 2.00e-05 Methyl chloride Propellant, armnonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Methyl chloride Propellant, armnonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloride Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloride Propellant, M-3 1.60e-07 Q.OOe+OO l.lOe-07 1.40e-07 4.50e-07 Methyl chloride Propellant, M-43 (USN) O.OOe+OO O.OOe+OO l.60e-07 Methyl chloride Propellant, M-9 l.SOe-07 1.SOe-07 J.lOe-07 Methyl chloride Propellant, MK-23 7.lOe-07 7.lOe-07 8.90e-07 Methyl chloride Propellant, M3ll\1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Methyl chloride Propellant, PBXN-110 1.80e-07 l.80e-07 l.80e-07 Methyl chloride Propellant, Smokey Sam 5.70e-06 5.70e-06 6.40e-06 Methyl chloride Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 4.JOe-07 Methylcyclohexane Diesel fuel and dunnage 8.40e-05 2.lOe-04 l.70e-04 l.60e-04 l.60e-04 Methylcyclohexane Manufacturer's waste - alurninized propellant with diesel 7.30e-06 4.40e-06 l.20e-05 8.00e-06 l.40e-05 Methylcyclohexane Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Methylcyclohexane Propellant, double base O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO Methylcyclohexane Propellant, M-3 9.90e-08 O.OOe+OO 4.70e-08 5.80e-08 4.30e-07 Methylcyclohexane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO l.80e-07 Methylcyclohexane Propellant, M-9 O.OOe+OO O.OOe+OO 4.70e-07 Methylcyclohexane Propellant, MK-23 O.OOe+OO O.OOe+OO 3.90e-07 Methylcyclohexane Propellant, M31A1El O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Methylcyclohexane Propellant, PBXN-110 O.OOe+OO O.OOe+OO 5.00e-07 Methvlcvclohexane Propellant, Smokev Sam 7.SOe-07 7.80e-07 l.60e-06

001043 Methylcyclohexane Smokeless Powder (Hercules Unique> 4.BOe-07 4.BOe-07 9.60e-07 Methylcyclopentane Diesel fuel and dunnage 4.20e-06 l.40e-05 1. lOe-05 9.90e-06 1. OOe-05 Methylcyclopentane Manufacturer's waste - aluminized propellant with diesel 7.60e-OB 3.BOe-07 2.70e-06 1.lOe-06 2.00e-06 Methylcyclopentane Propellant, ammonium perchlorate, alurninized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclopentane Propellant, ammonium perchlorate, nonaluminized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclopentane Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclopentane Propellant, M-3 2.lOe-06 2.00e-06 6.60e-07 2.50e-06 l.lOe-05 Methylcyclopentane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO l.BOe-07 Methylcyclopentane Propellant, M-9 0.00e+OO O.OOe+OO l.70e-06 Methylcyclopentane Propellant, MK-23 0.00e+OO O.OOe+OO 4.90e-07 Methylcyclopentane Propellant, M31A1El 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclopentane Propellant, PBXN-110 0.00e+OO O.OOe+OO 7.00e-07 Methylcyclopentane Propellant, Smokey Sam l.60e-06 1.60e-06 2.00e-06 Methylcyclopentane Smokeless Powder (Hercules Unique) 7.20e-07 7.20e-07 1.20e-06 Methylenechloride Diesel fuel and dunnage 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylenechloride Manufacturer's waste - aluminized propellant with diesel 1. 50e-05 9.BOe-06 O.OOe+OO l.20e-05 1. lOe-05 Methylenechloride Propellant, ammonium perchlorate, alurninized 0.00e+OO a·. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylenechloride Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylenechloride Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylenechloride Propellant, M-3 5.60e-06 O.OOe+OO 5.20e-05 2.JOe-05 5.80e-05 Methylenechloride Propellant, M-43 (USN) 0.00e+OO O.OOe+OO 1.lOe-06 Methylenechloride Propellant, M-9 O.OOe+OO O.OOe+OO 4.30e-05 Methylenechloride Propellant, MK-23 6.00e-07 6.00e-07 6.00e-07 Methylenechloride Propellant, M31A1Bl 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylenechloride Propellant, PBXN-110 0.00e•OO O.OOe+OO 9.00e-07 Methylenechloride Propellant, Smokey Sam l.20e-06 1.20e-06 4.70e-06 Methylenechloride Smokeless Powder (Hercules Unique) 7.20e-07 7.20e-07 7.20e-07 NO Diesel fuel and dunnage 6.30e-04 8.9De-04 8.BOe-04 8.00e-04 NO Manufacturer's waste - aluminized propellant with diesel 9.30e-04 B.BOe-04 1.20e-03 l.OOe-03 NO Propellant, ammonium perchlorate, aluminized 2.20e-03 1.60e-03 l.90e-03 NO Propel !ant, ammonium perchlorate, nonaluminized 4.lOe-03 3.90e-03 4.00e-03 NO Propellant, composite (MK-6) (Sa'ndial 2.lOe-03 2.lOe-03 NO Propellant, double base l.70e-03 l.70e-03 l.70e-03 NO Propellant, double base (Sandia) 2.40e-02 2.40e-02 NO Propellant, M-43 (USN) 6.30e-03 6.30e-03 NO Propellant, M31A1E1 l. lOe-03 1.20e-03 l.20e-03 NO Propellant, PBXN-110 2. 60e-03 2.60e-03 NO Propellant, Smokey Sam 1.lOe-02 1.loe-02 N02 Diesel fuel and dunnage O.OOe+OO 5.lOe-05 3.20e-05 4.20e-05 N02 Manufacturer's waste - alumini-zed propellant with diesel 4.40e-07 9.BOe-06 9.70e-06 6.60e-06 N02 Propellant, anunonium nerchlorate, aluminized 2.lOe-04 7.00e-05 l.40e-04

001044 N02 Propellant, ammonium perchlorate, nonaluminized 4.30e-03 4.70e-04 2.40e-OJ N02 Propellant, composite (MK-6) {Sandia) 1. OOe-03 l.OOe-03 N02 Propellant, double base 9.00e-05 l.OOe-04 l.OOe-04 N02 Propellant, double base (Sandia) 2.BOe-03 2.BOe-03 N02 Propellant, M-43 (USN) 4.70e-04 4.70e-04 N02 Propellant, M31A1El l.OOe-04 1. OOe-04 1. OOe-04 N02 Propellant, PBXN-110 2.BOe-04 2.80e-04 N02 Propellant, Smokey Sam 2.70e-04 2.70e-04 OCDD Diesel fuel and dunnage l.OOe-11 O.OOe+OO O.OOe+OO l.OOe-11 3.20e-11 OCDF Manufacturer's waste - aluminized propellant with diesel 4.00e-08 4.00e-08 Propane Diesel fuel and dunnage l.40e-06 2.20e-06 3.lOe-06 2.20e-06 2.SOe-06 Propane Manufacturer's waste - aluminized propellant with diesel 4.20e-06 2.BOe-06 6.50e-06 4.SOe-06 s.ooe-06 Propane Propellant, ammonium perch1orate, aluminized O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Propane Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Propane Propellant, double base O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO O.OOe+OO Propane Propellant, M-3 3.30e-07 S.lOe-07 5.20e-07 5.00e-07 7.20e-07 Propane Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 9.lOe-07 Propane Propellant, M-9 O.OOe+OO O.OOe+OO 3.40e-07 Propane Propellant, MK-23 4.90e-07 4.90e-07 l.30e-06 Propane Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Propane Propellant, PBXN-110 3.00e-07 3.00e-07 l.OOe-06 Propane Propellant, Smokey Sam l.60e-06 l.60e-06 4.30e-06 Propane Smokeless Powder (Hercules Unique) 2.40e-07 2.40e-07 3.40e-06 Propene Diesel fuel and dunnage l.OOe-05 1.30e-05 l.60e-05 l.30e-05 1.30e-05 Propene Manufacturer's waste - aluminized propellant with diesel 2.SOe-05 2.lOe-05 3.20e-05 2.60e-05 2.60e-05 Propene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Propene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Propene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Propene Propellant, M-3 1. 40e-06 2.00e-06 2.lOe-06 2.00e-06 1.SOe-06 Propene Propellant, M-43 (USN) l. lOe-06 l.lOe-06 l.20e-06 Propene Propellant, M-9 7.30e-07 7.30e-07 8.lOe-07 Propene Propellant, MK-23 l.70e-06 l.70e-06 l.BOe-06 Propene Propellant, PBXN-110 3.00e-06 3.00e-06 3.lOe-06 Propene Propellant, Smokey Sam 2.70e-06 2.70e-06 2.70e-06 Propene . Smokeless Powder (Hercules Unique) 2.40e-07 2.40e-07 7.20e-07 PMlO Diesel fuel and dunnage 4.70e-03 4. 90e-03 6.BOe-03 5.40e-03 PMlO Manufacturer's waste - aluminized propellant with diesel 3.BOe-01 4.40e-01 4.90e+OO 1.90e+OO PMlO Propellant, ammonium perchlorate, aluminized 4.lOe-01 4.30e-01 4.20e-01 PMlO Propellant, ammonium perchlorate, nonaluminiz~d l.lOe-02 l.BOe-02 l.SOe-02 PMlO Propellant, double base l.90e-02 l.90e-02 l.90e-02 PMlO Pronellant, M-3 8.BOe-03 8.70e-03 8.20e-03 8.60e-03

001045 PMlO Propellant, M 43 (USN) 1. 20e-03 1. 20e 03 PMlO Propellant, M 9 l.60e-02 l.60e-02 PMlO Propellant, MK 23 5.90e-02 5.90e-02 PMlO Propellant, M31A1El 8.90e-01 9.30e-01 9.lOe 01 9.lOe 01 PMlO Propellant, PBXN 110 4.90e-01 4.90e-01 PM10 Propellant, Smokey Sam 2.60e-Dl 2.60e-01 PMlO Smokeless Powder (Hercules Unique) l.BOe-03 1.BOe-03 Styrene Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Manufacturer's waste - aluminized propellant with diesel O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, M-43 (USN) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, M-9 4.70e-07 4.70e-07 4.70e-07 Styrene Propellant, MK-23 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, M31A1El O.OOe+OO O.OOe+OO 1. OOe-05 Styrene Propellant, PBXN-110 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Propellant, Smokey Sam O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Smokeless Powder (Hercules Unique) o:ooe+oo O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO S02 Diesel fuel and dunnage 2.lOe-04 7.90e-05 2.BOe-04 l.90e-04 S02 Manufacturer's waste - aluminized propellant with diesel B.60e-04 B.40e-04 8.BOe-04 8.60e-04 S02 Propellant, ammonium perchlorate, aluminized 6.00e-05 4.00e-05 5.00e-05 S02 Propellant, ammonium perchlorate, nonaluminized 1.lOe-04 l.lOe-04 1.lOe-04 S02 Propellant, composite (MK-6) (Sandia) 1. lOe-03 1.lOe-03 S02 Propellant, double base 3.00e-05 2.00e-05 3.00e-05 S02 Propellant, double base (Sandia)· 3.20e-03 3.20e-03 S02 Propellant, M-43 (USN) 1. 20e-04 1.20e-04 S02 Propellant, M31A1El 1. OOe-03 1.20e-03 1.20e-03 S02 Propellant, PBXN-110 3.SOe-04 3.50e-04 S02 Propellant, Smokey Sam l.50e-04 l.50e-04 S02 Smokeless Powder (Hercules Unique) 6.lOe-04 6.lOe-04 Tetrachloroethylene Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Tetrachloroethy1ene Manufacturer's waste - aluminized propellant with diesel O.OOe+OO l.60e-06 1. BOe-06 l.70e-06 l.70e-06 Tetrachloroethylene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Tetrachloroethylene Propellant, M-43 (USN) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Tetrachloroethylene Propellant, M-9 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Propellant. MK-23 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Propellant, PBXN-110 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Propellant, Smokey Sam O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethvlene Smokeless Powder (Hercules Uni~·e} O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

001046 Toluene Diesel fuel and dunnage 8.00e-05 l.50e-04 l.40e-04 l.20e-04 1.30e-04 Toluene Manufacturer's waste - aluminized propellant with diesel 3.40e-05 1.50e-05 3.40e-05 2.BOe-05 3.90e-05 Toluene Propellant, ammonium perchlorate, aluminized 0.00e+OO O.OOe+OO 1.00e-05 Toluene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO 0 .OOe+OO 1. OOe-05 Toluene Propellant, double base 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Toluene Propellant, M-3 l.80e-06 2.00e-06 8.90e-07 l.80e-06 6.60e-06 Toluene Propellant, M-43 \USN) 5.40e-07 5.40e-07 1.80e-06 Toluene Propellant, M-9 O.OOe+OO O.OOe+OO 5.40e-06 Toluene Propellant, MK-23 0.00e+OO O.OOe+OO 2.90e-06 Toluene Propellant, M31A1El 0.00e+OO O.OOe+OO 3.00e-05 Toluene Propellant, PBXN-110 O.OOe+OO O.OOe+OO 4.50e-06 Toluene Propellant, Smokey Sam 8.60e-06 8.60e-06 1.50e-05 Toluene Smokeless Powder (Hercules Unique) 3.40e-06 3.40e-06 7.40e-06 Total Alkanes (Paraffins) Diesel fuel and dunnage 2.70e-03 3.90e-03 3.90e-03 3.50e-03 3.SOe-03 Total Alkanes (Paraffins) Manufacturer's waste - aluminized propellant with diesel 9.40e-05 S.BOe-05 2.30e-04 1. 30e-04 2.30e-04 Total Alkanes (Paraffins) Propellant, anunoniwn perchlorate, aluminized 0.00e+OO O.OOe+OO 2.00e-05 Total Alkanes (Paraffins) Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO 0.00e+OO 1.00e-05 Total Alkanes (Paraffins) Propellant, composite \MK-6) (Sandia) 5.90e-05 5.90e-05 Total Alkanes (Paraffins) Propellant, double base O.OOe+OO l.OOe-05 Total Alkanes (Paraffins) Propellant, double base (Sandia) 2.20e-04 2.20e-04 Total Alkanes {Paraffins) Propellant, M-3 3.00e-05 2.lOe-05 7.40e-06 2.60e-05 1.30e-04 Total Alkanes (Paraffins) Propellant., M-43 \USN) 5.40e-07 5.40e-07 1.00e-05 Total Alkanes (Paraffins) Propellant, M-9 O.OOe+OO 0.00e+OO 2.30e-05 Total Alkanes (Paraffins) Propellant, MK-23 O.OOe+OO O.OOe+OO 1.40e-05 Total Alkanes (Paraffins) Propellant, M31A1El 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Total Alkanes (Paraffins) Propellant, PBXN-110 O.OOe+OO O.OOe+OO 2.00e-05 Total Alkanes (Paraffins} Propellant., Smokey Sam 2.30e-05 2.30e-05 7.20e-05 Total Alkanes (Paraffins) Smokeless Powder (Hercules Unique) 6.70e-06 6.70e-06 4.20e-05 Total Alkenes (Olefins) Diesel fuel and dunnage 2.00e-04 l.70e-04 2.lOe-04 l.90e-04 2.00e-04 Total Alkenes (Olefins) Manufacturer's waste - aluminized propellant with diesel 2.20e-03 l.SOe-03 1.90e-03 1. 90e-03 1.90e-03 Total Alkenes (Olefins) Propellant, anunonium perchlorate, aluminized 3.00e-05 l.OOe-05 2.00e-05 2.00e-05 Total Alkenes (Olefins) Propellant, arranonium perchlorate, nonaluminized l.OOe-05 l.OOe-05 l.DOe-05 1.00e-05 Total Alkenes (Olefins) Propellant, composite (MK-6) (Sandia) 1. OOe-04 l.OOe-04 Total Alkenes (Olefins) Propellant, double base O.OOe+OO l.OOe-05 l.OOe-05 1.00e-05 Total Alkenes (Olefins) Propellant, double base (SaniJ.ia) 7.30e-04 7.30e-04 Total Alkenes (Olefinsl Propellant, M-3 3.60e-05 2.80e-05 2.50e-05 2.90e-05 3.70e-05 Total Alkenes (Olefins) Propellant, M-43 (USN) l.30e-05 1. 30e-05 1.40e-05 Total Alkenes (Olefins) Propellant, M-9 1.70e-05 l.70e-05 1.80e-05 Total Alkenes (Olefins) Propellant, MK-23 . l. lOe-05 l. lOe-05 1. 30e-05 Total Alkenes (Olefins) Propellant, M31A1El . O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO l.OOe-05 Total Alkenes (Olefins) Prooellant, PBXN-110 1.60e-05 1.60e-05 1. 80e-05

001047 Total Alkenes {Olefins) Propellant, Smokey Sam 9.lOe-04 9.lOe 04 9.20e-04 Total Alkenes (Olefins) Smokeless Powder (Hercules Unique) 2.20e-06 2.20e 06 7.40e-06 Total Aromatics Diesel fuel and dunnage 1. 60e-03 2.70e-03 2.60e-03 2.30e-03 2.30e-03 Total Aromatics Manufacturer's waste aluminized propellant with diesel 7.BOe-04 3.60e-04 5.60e-04 5.70e-04 6.20e-04 Total Aromatics Propellant, ammonium perchlorate, alurninized O.OOe+OO 2.00e-05 Total Aromatics Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO 2.00e-05 Total Aromatics Propellant, composite IMK-61 (Sandia) l.60e-04 l.60e-04 Total Aromatics Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO l.OOe-05 Total Aromatics Propellant, double base (Sandia) 4.40e-04 4.40e-04 Total Aromatics Propellant, M-3 1. 60e-05 l. lOe-05 l.90e-05 l.40e-05 3.50e-05 Total Aromatics Propellant, M-43 (USN) 2.BOe-06 2.BOe-06 l.30e-05 Total Aromatics Propellant, M-9 5.40e-06 5.40e-06 2.70e-05 Total Aromatics Propellant, MK-23 O.OOe+OO O.OOe+OO l.70e-05 Total Aromatics Propellant, M31A1El 6.00e-05 7.00e-05 3.00e-05 5.00e-05 9.00e-05 Total Aromatics Propellant, PBXN-110 7.lOe-06 7.lOe-06 2.BOe-05 Total Aromatics Propellant, Smokey Sam l.OOe-04 l.OOe-04 1.50e-04 Total Aromatics Smokeless Powder (Hercules Unique) 6.20e-06 6.20e-06 3.50e-05 Total Non-methane Hydrocarbons Diesel fuel and dunnage 9.90e-03 l.30e-02 l.30e-02 l.20e-02 1.20e-02 Total Non-methane Hydrocarbons Manufacturer's waste - aluminized propellant with diesel 3.50e-03 2. 20e-03 3.lOe-03 2.90e-03 3.20e-03 Total Non-methane Hydrocarbons Propellant, ammonium perchlorate, aluminized 6.00e-05 3.00e-05 5.00e-05 l.lOe-04 Total Non-methane Hydrocarbons Propellant, ammonium perchlorate, nonaluminized 5.ooe-05 4.00e-05 4.00e-05 7.00e-05 Total Non-methane Hydrocarbons Propellant, double base l.OOe-05 1.00e-05 1. OOe-05 4.00e-05 Total Non-methane Hydrocarbons Propellant, M-3 1.lOe-04 9.50e-05 5.30e-05 9.30e-05 3.00e-04 Total Non-methane Hydrocarbons Propellant, M-43 (USN) 4.lOe-05 4.lOe-05 l.lOe-04 Total Non-methane Hydrocarbons Propellant, M-9 l.50e-05 1. 50e-05 l.30e-04 Total Non-methane Hydrocarbons Propellant, MK-23 O.OOe+OO O.OOe+OO 1.40e-04 Total Non-methane Hydrocarbons Propellant, MJlAlEl l.OOe-04 9.00e-05 l.20e-04 1. OOe-04 1. 70e-04 Total Non-methane Hydrocarbons Propellant, PBXN-110 5.lOe-05 5.lOe-05 l.BOe-04 Total Non-methane Hydrocarbons Propellant, Smokey Sam l.lOe-03 l.lOe-03 1.60e-03 Total Non-methane Hydrocarbons Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO 2.30e-04 Total Unidentified Hydrocarbons Diesel fuel and dunnage 5.SOe-03 6.00e-03 6. 60e-03 6. OOe-03 6.20e-OJ Total Unidentified Hydrocarbons Manufacturer's waste - aluminized propellant with diesel 4.lOe-04 2.30e-04 4.20e-04 3.50e-04 4.70e-04 Total Unidentified Hydrocarbons Propellant, armnonium perchlorate, aluminized 2.00e-05 3.00e-05 2.50e-05 4.00e-05 Total Unidentified Hydrocarbons Propellant, armnonium perchlorate, nonalurninized 3.00e-05 2.00e-05 2.50e-05 3.00e-05 Total Unidentified Hydrocarbons Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO l.OOe-05 Total Unidentified Hydrocarbons Propellant, M-3 2.BOe-05 3.50e-05 1. 70e-06 2.40e-05 9.lOe-05 Total Unidentified Hydrocarbons Propellant, M-43 (USN) 2.50e-05 2.50e-05 7.40e-05 Total Unidentified Hydrocarbons Propellant, H > 0. OOe+OO O.OOe+OO 5.BOe-05

Total Unidentified Hydrocarbons rr.-.r~llllr~· ,.~\" - ' 2.90e-06 2.90e-06 9.lOe-05 u.' .. t. Total Unidentified Hydrccar~~ns r r 1 ... ! ! i • • 3 .OOe-05 l.OOe-05 2.00e-05 2.00e-05 4.00e-05 Total Unidentified Hvdre'c;:i;tb"n~ ! r t•·:: '""' ' 4.40e-05 4.40e-05 l.lOe 04

001048 Total Unidentified Hydrocarbons Propellant, Smokey Sam 7.50e-05 7.50e-05 4.30e-04 Total Unidentified Hydrocarbons Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO l.40e-04 Vinyl chloride Diesel fuel and dunnage O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Manufacturer's waste - aluminized propellant with diesel O.OOe+OO o.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Vinyl chloride Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Propellant, ammonium perchlorate, nonal umini zed O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Propellant, M-3 O.OOe+OO o.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Propellant, M-43 (USN) O.OOe+OO O.OOe+OO 0. OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Propellant, M-9 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Propellant, MK-23 l.50e-06 l.50e-06 l.SOe-06 Vinyl chloride Propellant, PBXN-110 2.20e-07 2.20e-07 2.20e-07 Vinyl chloride Propellant, Smokey Sam 8.BOe-07 B.BOe-07 B.BOe-07 Vinyl chloride Smokeless Powder (Hercules Unique) 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Diesel fuel and dunnage 6.40e-05 6.SOe-05 5.90e-05 6.30e-05 6.40e-05 Zinc Manufacturer's waste - aluminized propellant with diesel l.60e-04 l.lOe-04 l.40e-03 5.70e-04 5.BOe-04 Zinc Propellant, ammonium perchlorate, aluminized 6.00e-05 2.00e-05 4.00e-05 4.00e-05 Zinc Propellant, ammonium perchlorate, nonaluminized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Propellant, double base O.OOe+OO 1.00e-05 l.OOe-05 l.OOe-05 Zinc Propellant, M-3 O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO Zinc Propellant, M-9 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Propel !ant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Butene Diesel fuel and dunnage O.OOe+OO 4. 70e-06 4.60e-06 4.70e-06 4.70e-06 1-Butene Manufacturer's waste - aluminized propellant with diesel l. lOe-05 5.70e-06 B.OOe-06 B.30e-06 8.30e-06 1-Butene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 1-Butene Propellant, ammonium perchlorate, nonalurninized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Butene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Butene Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Butene Propellant, M-43 (USN) 2.70e-07 2.?0e-07 2.70e-07 1-Butene Propellant, M-9 2.60e-07 2.60e-07 2.60e-07 1-Butene Propellant, MK-23 5.90e-07 5.90e-07 5:90e-07 1-Butene Propellant, MllA!El O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 1-Butene Propellant, PBXN-110 6.00e-07 6.00e-07 6.00e-07 1-Butene Propellant, Smokey Sam l.20e-06 l.20e-06 l.20e-06 1-Butene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Hexene Diesel fuel and dunnage l.lOe-06 2.70e-06 2.BOe-06 2.20e-06 2.20e-06 1-Hexene Manufacturer's waste - aluminized propellant with diesel l.lOe-06 6.lOe-07 l.30e-05 4.BOe-06 4.BOe-06 1-Hexene Propellant, ammonium perchlorate, aluminized 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Hexene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Hexene Propellant, double base O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO 1-Hexene Propellant, M-3 l.BOe-07 O.OOe+OO O.OOe+OO l.BOe-07 l.80e-07 1-Hexene Pronellant, M-43 IUSNJ O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

001049 1-Hexene Propellant, M 9 2.lOe-07 2.lOe-07 2.lOe-07 1-Hexene Propellant, MK-23 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 1-Hexene Propellant, M31A1El O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Hexene Propellant, PBXN-110 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 1-Hexene Propellant, Smokey Sam O.OOe+OO O.OOe""OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Hexene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Diesel fuel and dunnage O.OOe+OO l.70e-06 O.OOe+OO l.70e-06 l.80e-06 1-Pentene Manufacturer's waste - alurninized propellant with diesel 4.80e-06 3.30e-06 7.00e-06 5.lOe-06 5.30e-06 1-Pentene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Propellant, ammonium perchlorate, nonaluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Propellant, double base O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Propellant, M-3 1.60e-07 O.OOe+OO O.OOe+OO l.60e-07 2.20e-07 1-Pentene Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 9.lOe-08 1-Pentene Propellant, M-9 4.30e-08 4.30e-08 8.50e-08 1-Pentene Propellant, MK-23 o.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Propellant, M31A1El O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Propellant, PBXN-110 l.OOe-07 1.00e-07 2.00e-07 1-Pentene Propellant, Smokey Sam O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l,3-Butadiene Diesel fuel and dunnage O.OOe+OO l.30e-06 9.80e-07 1. 20e-06 1. 20e-06 l,3-Butadiene Manufacturer's waste - aluminized propellant with diesel 5.40e-06 4.20e-06 2.40e-06 4.00e-06 4.00e-06 1,3-Butadiene Propellant, ammonium perchlorate, aluminized O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1,3-Butadiene Propellant, M-3 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l,3-Butadiene Propellant, M-43 (USN) 9.lOe-08 9.lOe-08 9.lOe-08 l,3-Butadiene Propellant, M-9 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1,3-Butadiene Propellant, MK-23 2.00e-07 2.00e-07 2.00e-07 1,3-Butadiene Propellant, PBXN-110 5.00e-07 5.00e-07 5.00e-07 1,3-Butadiene Propellant, Smokey Sam l.20e-06 1.20e-06 l.20e-06 1,3-Butadiene Smokeless Powder (Hercules Unique) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.Ooe+OO 1234678-HpCDF Manufacturer's waste - alwninized propellant with diesel 3.40e-08 3.40e-08 123478-HxCDF Manufacturer's waste - aluminized propellant with diesel 2.00e-08 2.lOe-08 1234789-HpCDF Manufacturer's waste - aluminized.propellant with diesel 7.90e-09 7.90e-09 123678-HxCDF Manufacturer's waste - aluminized propellant with diesel 9.50e-09 9.50e-09 2-Chlorophenol Propellant, ammonium perchlorate, nonaluminized l.OOe-05 l.OOe-05 l.OOe-05 l.OOe-05

001050 Appendix E Emission Factors for Detonations

SPECIAL NOTES:

The emission factors in this database apply primarily to unconfined, ground level detonations of bulk and assembled energetic materials. They do not apply confined or otherwise suppressed detonations, except for the emission factors for the water-suppressed detonations of tritonal and amatol.

A value of O.OOe+OO means that the compound (analyte) was either not detected, or, was detected at only the background level. Values of O.OOe+OO were not used in calculating the average (AVG) emission factors in the database. A blank cell means that either no sample was collected or that the sample collected was either lost or not valid.

The emission factors in this table are unitless. The user can convert them to any mass units desired (e.g., grams compound per gram NEW). A value e-06 means that the quantity in the numerator is to be multiplied by 10 to the -6 power. For example, l.le-06 could be written as either 1.1 x 10-6 g/g NEW or 1 microgram/g NEW.

001051 COMPOUND ITEM EMISSION FACTORS TRIAL 1 TRIAL 2 TRIAL 3 AVERAGE UN CORR cis-2-Pentene Amato! O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Amato! surrogate with water 6.30e-06 l.lOe-05 7.80e-06 8.50e-06 9.lOe-06 cis-2-Pentene Cartridge, Impulse, ARD 446-1 7.80e-07 2.60e-07 5.00e-07 5.lOe-07 8.70e-07 cis-2-Pentene Cartridge, Impulse, BBU-36/B 2.70e-07 2.80e-07 5.60e-07 3.70e-07 9.00e-07 cis-2-Pentene Cartridge, Impulse, MK 107 2.60e-07 2.60e-07 2.60e-07 2.60e-07 2.60e-07 cis-2-Pentene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Detonating train 5.80e-07 3.00e-07 3.00e-07 3.90e-07 9.lOe-07 cis-2-Pentene Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO 3.40e-07 3.40e-07 3.40e-07 cis-2-Pentene Fuze, Tail Bomb FMU-139 A/B 4.90e-07 9.70e-07 4.80e-07 6.50e-07 6.50e-07 cis-2-Pentene Fuze, Tail Bomb FMU-54 A/B 5.90e-07 8.90e-07 O.OOe+OO 7.40e-07 9.30e-07 cis-2-Pentene Gas Generator, GGU-2/A 5.90e-07 1. 20e-06 6.lOe-07 7.90e-07 9.90e-07 cis-2-Pentene HBX surrogate 3.70e-07 4.lOe-07 O.OOe+OO 3.90e-07 3.80e-07 cis-2-Pentene Mine, Claymore, Ml8Al O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene Signal, Illumination, Red Star AN-M43A2 3.50e-07 3.50e-07 3.50e-07 3.50e-07 3.50e-07 cis-2-Pentene Signal, Illumination, Red Star Ml58 3.50e-07 3.50e-07 O.OOe+OO 3.SOe-07 3.50e-07 cis-2-Pentene Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.70e-07 cis-2-Pentene Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 3.60e-07 cis-2-Pentene Tritonal surrogate with water 2.30e-06 3.70e-06 3.40e-06 3.lOe-06 3.30e-06 cis-2-Pentene TNT (ACCl) 4.60e-07 O.OOe+OO O.OOe+OO 4.60e-07 4.60e-07 cis-2-Pentene TNT (ACC2)· O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO cis-2-Pentene T45E7 Adapter Booster 3.00e-06 2.40e-06 2.90e-06 2.70e-06 2.70e-06 cis-2-Pentene 20 mm HEI Cartridge O.OOe+OO 0.00e+OO 6.80e-07 6.80e-07 6.80e-07 cis-2-Pentene 40 mm HEI Cartridge 8.30e-07 O.OOe+OO O.OOe+OO 8.30e-07 3.30e-06 i-Butane Amato! surrogate 7.50e-07 7.50e-07 3.70e-07 6.20e-07 6.20e-07 i-Butane Amato! surrogate with water 6.70e-06 6.30e-06 6.30e-06 6.40e-06 7.50e-06 i-Butane Cartridge, Impulse, ARD 446-1 O.OOe+OO 2.60e-07 2.50e-06 l.40e-06 5.lOe-06 i-Butane Cartridge, Impulse, BBU-36/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.lOe-06 i-Butane Cartridge, Impulse, MK 107 O.OOe+OO l. lOe-06 O.OOe+OO l.lOe-06 l.90e-06 i-Butane Composition B surrogate 3.70e-07 3.70e-07 O.OOe+OO 3.70e-07 3.70e-07 i-Butane Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 6.00e-06 i-Butane Flare, IR Countermeasure M206 6.60e-07 O.OOe+OO O.OOe+OO 6.60e-07 5.00e-06 i-Butane Fuze, Tail Bomb FMU-139 A/B 2.00e-06 3.90e-06 9.70e-07 2.30e-06 3.90e-06 i-Butane Fuze, Tail Bomb FMU-54 A/B 3.00e-07 3.00e-07 O.OOe+OO 3.00e-07 3.70e-06 i-Butane Gas Generator, GGU-2/A l.20e-06 5.90e-07 O.OOe+OO 8.80e-07 9.50e-06 i-Butane . HBX surrogate 7 .30e-07 O.OOe+OO 3.70e-07 5.50e-07 9.20e-07 i-Butane :hne. Claymore. Hl8Al 4.90e-07 9.BOe-07 O.OOe+OO 7.30e-07 2.40e-06 i-Butane .-;iqnal, Illumination, Red Star AN-M43A2 3.50e-07 3.SOe-07 O.OOe+OO 3.50e-07 3.lOe-06

001052 i-Butane Signal, Illumination, Red Star M158 2.lOe-06 l.80e-06 6.90e-07 1.50e-06 5.70e-06 i-Butane Tritonal surrogate 7.40e-07 O.OOe+OO 3.60e-07 5.50e-07 5.50e-07 i-Butane Tritonal surrogate with calcium stearate O.OOe+OO 7.30e-07 7.30e-07 9.lOe-07 i-Butane Tritonal surrogate with water 4.lOe-06 4.40e-06 4.lOe-06 4.20e-06 4.60e-06 i-Butane TNT (ACCl) 4.60e-07 O.OOe+OO O.OOe+OO 4.60e-07 4.60e-07 i-Butane TNT (ACC2) 0.00e+OO O.OOe+OO 5.20e-06 i-Butane T45E7 Adapter Booster O.OOe+OO l.2Qe-06 2.30e-06 l. 70e-06 3.50e-06 i-Butane 20 mm HE! Cartridge 7.00e-07 l.40e-06 2.00e-06 1. 40e-06 3.90e-06 i-Butane 40 mm HE! Cartridge 0.00e+OO O.OOe+OO 1. 60e-06 l.60e-06 2.90e-06 i-Butene Arnatol surrogate 2.30e-06 O.OOe+OO 7.40e-07 l.50e-06 l.50e-06 i-Butene Amatol surrogate with water l.50e-05 3.lOe-05 1. 30e-05 2.00e-05 2.00e-05 i-Butene Cartridge, Impulse, ARD 446-1 2.50e-05 2.00e-05 2.20e-05 2.20e-05 3.20e-05 i-Butene Cartridge, Impulse, BBU-36/B 2.00e-05 2.lOe-05 2.60e-05 2.20e-05 2.20e-05 i-Butene Cartridge, Impulse, MK 107 6.BOe-06 O.OOe+OO 2.90e-06 4.90e-06 4.90e-06 i-Butene Composition B surrogate 3.70e-07 7.40e-07 1. BOe-06 9.SOe-07 9.BOe-07 i-Butene Detonating train l.OOe-05 3.lOe-05 3.00e-05 2.40e-05 3.60e-05 i-Butene Flare, IR Countermeasure M206 2.30e-06 2.40e-06 2.70e-06 2.50e-06 2.5oe-06 i-Butene Fuze, Tail Bomb FMU-139 A/B 5.40e-06 5.JOe-06 5.30e-06 5.30e-06 5.50e-06 i-Butene Fuze, Tail Bomb FMU-54 A/B 4.40•-06 5.60e-06 4.JOe-06 4.BOe-06 4.BOe-06 i-Butene Gas Generator, GGU-2/A O.OOe+OO 2.90e-06 O.OOe+OO 2.90e-06 2.90e-06 i-Butene HBX surrogate 3.70e-06 2.SOe-06 4.50e-06 3.50e-06 3.SOe-06 i-Butene Mine, Claymore, MlBAl 3.40e-06 3.40e-06 4.20e-06 3.70e-06 5.lOe-06 i-Butene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO 2.BOe-06 3.50e-06 3.lOe-06 3.30e-06 i-Butene Signal, Illumination, Red star Ml 5 8 O.OOe+OO O.OOe+OO 4.50e-06 4.50e-06 4.50e-06 i-Butene Tritonal surrogate 3.00e-06 3.70e-07 7.30e-07 l.40e-06 l.40e-06 i-Butene Tritonal surrogate with calcium stearate 2.60e-06 l.SOe-06 2.00e-06 2.00e-06 i-Butene Tritonal surrogate with water 1. 30e-05 O.OOe+OO o.ooe ... oo 1. 30e-05 l.JOe-05

i-Butene . TNT (ACCl) 3. 70e-06 3.40e-06 3. BOe-06 3.60e-06 3.60e-06 i-Butene TNT (ACC2) 1.50e-06 l.SOe-06 l.50e-06 i-Butene T45E7 Adapter Booster 7.30e-05 8.20e-06 1.30e-05 3.lOe-05 3.lOe-05 i-Butene 20 mm HE! Cartridge 4.lOe-05 9.40e-06 l.70e-05 2.20e-05 2.20e-05 i-Butene 40 mm HE! Cartridge l.20e-05 9.00e-06 4.90e-06 8.80e-06 8.BOe-06 i-Pentane Amato! surrogate 1. 50e-06 l.50e-06 0.00e+OO l.50e-06 l.50e-06 i-Pentane Amato! surrogate with water l.50e-06 l.lOe-05 5.60e-06 6 .20e-06 3.70e-05 i-Pentane Cartridge, Impulse, ARD 446-1 O.OOe+OO 0.00e+OO O.OOe,..00 O.OOe+OO l.90e-06 i-Pentane Cartridge, Impulse, BBU-36/B O.OOe+OO 5.60e-07 l.40e-06 9. 70e-07 4.lOe-06 i-Pentane Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1. 20e-06 i-Pentane Composition B surrogate 3.70e-07 O.OOe+OO O.OOe+OO 3.70e-07 7.40e-07 i-Pentane Detonating train O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 4.lOe-06 i-Pentane Flare, IR Countermeasure M206 O.OOe+OO 3.40e-07 O.OOe+OO 3.40e-07 2.lOe-06 i-Pentane Fuze, Tail Bomb FMU-139 A/B O.OOe+OO 4.80e-07 O.OOe+OO 4.80e-07 l.lOe-06

001053 i-Pentane Fuze, Tail Bomb FMU-54 A/B 2.7De-06 O.OOe+OO O.OOe+OO 2.70e-06 l.OOe-05 i-Pentane Gas Generator, GGU-2/A O.OOe+OO 5.90e-07 O.OOe+OO 5.90e-07 l.lOe-05 i-Pentane HBX surrogate O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO l.70e-06 i-Pentane Mine, Claymore, M18Al 3.90e-06 O.OOe+OO 0.00e+OO 3.90e-06 3.lOe-06 i-Pentane Signal, Illumination, Red Star AN-M43A2 3.50e-07 O.OOe+OO O.OOe+OO 3.50e-07 5.aoe-07 i-Pentane Signal, Illumination, Red Star M158 O.OOe+OO O.OOe+OO 0. OOe+OO O.OOe+OO 2.20e-06 i-Pentane Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.lOe-06 i-Pentane Tritonal surrogate with calcium stearate O.OOe+Oo O.OOe+OO O.OOe+OO 4.20e-06 i-Pentane Tritonal surrogate with water 3.70e-07 3.70e-07 3.70e-07 3.70e-07 4.70e-06 i-Pentane TNT (ACCl) l.40e-06 O.OOe+OO O.OOe+OO 1.40e-06 1.20e-06 i-Pentane TNT (ACC2) 7.40e-07 7.40e-07 1. 50e-06 i-Pentane T45E7 Adapter Booster 1.20e-06 2.90e-06 1.40e-05 6.20e-06 l.lOe-05 i-Pentane 20 mm HE! Cartridge 0.00e+OO l.lOe-05 1. 20e-05 1. 20e-05 1.50e-05 i-Pentane 40 mm HEI Cartridge 9.lOe-06 O.OOe+OO O.OOe+OO 9.lOe-06 1. 80e-05 i-Propylbenzene Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Amato! surrogate with water 1. 90e-06 3.20e-06 O.OOe+OO 2.50e-06 3.20e-06 i-Propylbenzene Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 7.SOe-07 i-Propylbenzene Cartridge, Impulse, BBU-36/B 8.20e-07 l.lOe-06 8.40e-07 9.20e-07 9.20e-07 i-Propylbenzene Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO 5.20e-07 5.20e-07 5.20e-07 i-Propylbenzene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Flare, IR Countermeasure M206 O.OOe+OO 6.BOe-07 1. OOe-06 B.50e-07 8.50e-07 i-Propylbenzene Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Fuze, Tail Bomb FMU-54 A/B O.OOe+OO 3.00e-07 O.OOe+OO 3.00e-07 7.90e-07 i-Propylbenzene Gas Generator, GGU-2/A 1. 20e-06 O.OOe+OO 0. OOe+OO l.20e-06 B.80e-07 i-Propylbenzene HBX surrogate 7.30e-07 O.OOe+OO 3.70e-07 5.50e-07 1.SOe-06 i-Propylbenzene Mine, Claymore, Ml8A1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene Signal, Illumination, Red Star M158 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OD i-Propylbenzene Tritonal surrogate 7.40e-07 O.OOe+OO 1.lOe-06 6.lOe-07 l.70e-06 i-Propylbenzene Tritonal surrogate with calcium stearate O.OOe+OO 7.30e-07 7.30e-07 7.30e-07 i-Propylbenzene Tritonal surrogate with water O.OOe+OO O.OOe+OO l.lOe-06 1.lOe-06 l.90e-06 i-Propylbenzene TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene T4SE7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene 20 mm HE! Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO i-Propylbenzene ~0 mm HFI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

m-Ethyltoluene . ~.-1• 1 !""Jr r :,"\!(' O.OOe+OO 3.70e-07 O.OOe+OO 3.70e-07 l.50e-05 . m-Ethyltoluene ,. . l. " ,; : • ~: ...... '. &> ! l.50e-06 1.90e-06 l.SOe-06 l.60e-06 3.BOe-05 m-Ethyltoluene , .. '. ; .. ·i. : : ~ 1 5 20e·C7 2 6Ce-07 7.SOe-07 5.lOe-07 3.00e-06 m-Ethvltoluene .. I' " ,. 1 lQe-Of l. 40e-06 5.60e-07 l.OOe-06 4.20e-06

lJO

001054 m-Ethyltoluene Cartridge, Impulse, MK 107 O.OOe+OO 7.90e-07 5. 20e-07 6.60e-07 l.20e-06 m-Ethyltoluene Composition B surrogate O.OOe+OO 3. 70e-07 3.60e-07 3.70e-07 l.90e-05 m-Ethyltoluene Detonating train O.OOe+OO 3.00e-07 3.00e-07 3.00e-07 3.20e-06 m-Ethyltoluene Flare, IR Countermeasure M206 3.30e-07 O.OOe+OO 3.40e-07 3.40e-07 7.90e-07 m-Ethyl toluene Fuze, Tail Bomb FMU-139 A/B 9.70e-07 9. 70e-07 O.OOe+OO 9.70e-07 1. 30e-06 m-Ethyltoluene Fuze, Tail Bomb FMU-54 A/B 3.00e-07 3.00e-07 6.lOe-07 4.00e-07 l.30e-06 m-Ethyltoluene Gas Generator, GGU-2/A O.OOe+OO 5.90e-07 O.OOe+OO 5.90e-07 2.BOe-06 m-Ethyltoluene HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.50e-05 m-Ethyltoluene Mine, Claymore, MlBAl 6.BOe-06 3.40e-06 6.60e-06 5.60e-06 6.60e-06 m-Ethyltoluene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 5.BOe-07 m-Ethyltoluene Signal, Illumination, Red Star MlSB O.OOe+OO O.OOe+OO 3.SOe-07 3.50e-07 8.lOe-07 m-Ethyltoluene Tritonal surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.20e-05 m-Ethyltoluene Tritonal surrogate with calcium stearate O.OOe+OO 0.00e+OO O.OOe+OO 3.70e-05 m-Ethyltoluene Tritonal surrogate with water l.50e-06 O.OOe+OO 7.SOe-07 l. lOe-06 4.70e-05 m-Ethyltoluene TNT IACCl) O.OOe+OO 4.BOe-07 4.BOe-07 4.BOe-07 l.70e-06 m-Ethyltoluene TNT (ACC2) O.OOe+OO O.OOe+OO l.lOe-06 m-Ethyltoluene T45E7 Adapter Booster 1. BOe-06 2.90e-06 2.90e-06 2.SOe-06 2.50e-06 m-Ethyltoluene 20 mm HEI Cartridge l.40e-06 4.30e-06 5.40e-06 3.70e-06 7.lOe-06 m-Ethyltoluene 40 mm HEI Cartridge 0. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.BOe-06 n-Butane Amato! surrogate 7.SOe-07 7. SOe-07 3.70e-07 6 .20e-07 6.20e-07 n-Butane Amato! surrogate with water 3.BOe-05 6.BOe-05 4.90e-05 5.20e-05 6.30e-05 n-Butane Cartridge, Impulse, ARD 446-1 1. 50e-06 2.30e-06 2.70e-06 2.20e-06 4.BOe-06 n-Butane Cartridge, Impulse, BBU-36/B 5.40e-06 3.60e-06 5 .JOe-06 4.BOe-06 4.BOe-06 n-Butane Cartridge, Impulse, MK 107 O.OOe+OO 5.JOe-07 7.90e-07 6.60e-07 3.lOe-06 n-Butane Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.70e-07 n-Butane Detonating train 3.BOe-06 3.30e-06 2.lOe-06 3.lOe-06 l.OOe-05 n-Butane Flare, IR Countermeasure M206 3.30e-07 6.BOe-07 6.BOe-07 5.70e-07 S.lOe-06 n-Butane Fuze, Tail Bomb FMU-139 A/B 9.70e-07 l.90e-06 4.40e-06 2.40e-06 5.20e-06 n-Butane Fuze, Tail Bomb FMU-54 A/B 3. OOe-06 2.lOe-06 O.OOe+OO 2.50e-06 l.90e-05 n-Butane Gas Generator, GGU-2/A 3.50e-06 2.90e-06 O.OOe+OO 3.20e-06 3.SOe-05 n-Butane HBX surrogate 7.30e-07 4.lOe-07 3.70e-07 5.00e-07 8.90e-07 n-Butane Mine, Claymore, Ml8Al 2.90e-06 l.50e-06 9.40e-07 1. BOe-06 6.60e-06 n-Butane Signal, Illumination, Red Star AN-M43A2 2.BOe-06 2.40e-06 1. 40e-06 2.20e-06 4.lOe-06 n-Butane Signal, Illumination, Red Star M158 3.SOe-07 2.lOe-06 O.OOe+OO l.20e-06 7.lOe-06 n-Butane Tritonal surrogate 1. 90e-06 O.OOe+OO 3.60e-07 l.30e-06 l.40e-06 n-Butane Tritonal surrogate with calcium stearate O.OOe+OO 3.60e-07 3.60e-07 9.20e-07 n-Butane Tritonal surrogate with water 8.60e-06 l.80e-05 l.BOe-05 l.50e-05 l.60e-05 n-Butane TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.30e-06 n-Butane TNT (ACC2) O.OOe+OO O.OOe+OO 7.40e-07 n-Butane T45E7 Adapter Booster 5.30e-06 6.SOe-06 l.60e-05 9.lOe-06 l.60e-05 n Butane 20 mm HE! Cartridae 2.lOe-06 7.20e-06 l.30e-05 7.40e-06 l.40e 05

001055 n-Butane 40 mm HEI Cartridge l.70e-06 8.20e-07 l.60e-06 l.40e-06 1.lOe-05 n-Decane Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.70e-07 n-Decane Amato! surrogate with water 1.lOe-06 l.30e-06 l.90e-06 1. 40e-06 3.50e-06 n-Decane Cartridge, Impulse, ARD 446-1 2.60e-07 5.lOe-07 2.50e-07 3.40e-07 8.70e-07 n-Decane Cartridge, Impulse, BBU-36/B 3.50e-06 3.90e-06 5.30e-06 4.20e-06 9.lOe-06 n-Decane Cartridge, Impulse, MK 107 2.60e-07 2.60e-07 2.60e-07 2.60e-07 6.40e-07 n-Decane Composition B surrogate O.OOe+OO O.OOe+OO 3.60e-07 3.60e-07 4.90e-07 n-Decane Detonating train O.OOe+OO 9.00e-07 3.00e-07 6.00e-07 l.80e-06 n-Decane Flare, IR Countermeasure M206 3 .30e-07. 3.40e-07 3.40e-07 3.40e-07 4.50e-07 n-Decane Fuze, Tail Bomb FMU-139 A/B 9.70e-07 9.70e-07 1. 50e-06 1.lOe-06 l.30e-06 n-Decane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.00e-07 n-Decane Gas Generator, GGU-2/A 5.90e-07 5.90e-07 6.lOe-07 6.00e-07 l.20e-06 n-Decane HBX surrogate 3.70e-07 O.OOe+OO O.OOe+OO 3.70e-07 6.40e-07 n-Decane Mine, Claymore, MlBAl 3.90e-06 l.OOe-05 1. 60e-05 1. OOe-05 l.30e-05 n-Decane Signal, Illumination, Red Star AN-M43A2 3.50e-07 7.00e-07 O.OOe+OO 5.20e-07 4.60e-07 n-Decane Signal, Illumination, Red Star Ml58 7.00e-07 3.50e-07 6.90e-07 s.eoe-07 8.lOe-07 n-Decane Tritonal surrogate O.OOe+OO 3.70e-07 3.60e-07 3.70e-07 6.lOe-07 n-Decane Tritonal surrogate with calcium stearate O.OOe+OO 3.60e-07 3.60e-07 5.50e-07 n-Decane Tritonal surrogate with water O.OOe+OO O.OOe+OO l.lOe-06 l.lOe-06 l.70e-06 n-Decane TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1.00e-05 n-Decane TNT IACC2) O.OOe+OO O.OOe+OO 3.70e-07 n-Decane T45E7 Adapter Booster l.20e-06 O.OOe+OO O.OOe+OO 1. 20e-06 l.40e-05 n-Decane 20 Iml HE! Cartridge 4.90e-06 5.00e-06 9.50e-06 6.50e-06 2.90e-05 n-Decane 40 mm IIEI Cartridge 5.00e-06 2.50e-06 8.20e-06 5.20e-06 4.20e-05 n-Heptane Amato! surrogate l.lOe-06 3.70e-07 7.40e-07 7.50e-07 1. 60e-06 n-Heptane Amato! surrogate with water 5.90e-06 1. 30e-05 7.40e-06 8.70e-06 1.20e-05 n-Heptane Cartridge, Impulse, ARD 446-1 1. 50e-06 1.50e-06 2.20e-06 1.80e-06 4.30e-06 n-Heptane cartridge, Impulse, BBU-36/B 1. 60e-06 l.70e-06 l. lOe-06 1.50e-06 4.70e-06 n-Heptane Cartridge, Impulse, MK 107 1.00e-06 1.lOe-06 1. OOe-06 1.00e-06 l.90e-06 n-Heptane Composition B surrogate O.OOe+OO 3.70e-07 1.lOe-06 7.30e-07 1.20e-06 n-Heptane Detonating train 8.70e-07 l.50e-06 l.80e-06 1.40e-06 5.00e-06 n-Heptane Flare, IR Countermeasure M206 3.30e-07 3.40e-07 6.80e-07 4.50e-07 1.00e-06 n-Heptane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 9.70e-07 4.80e-07 6.SOe-07 l.lOe-06 n-Heptane Fuze, Tail Bomb FMU-54 A/B 5.90e-07 5.90e-07 O.OOe+OO S.90e-07 l.SOe-06 n-Heptane Gas Generator, GGU-2/A 5.90e-07 5.90e-07 1.20e-06 8.00e-07 2.80e-06 n-Heptane HBX surrogate 7.30e-07 O.OOe+OO 3.70e-07 5.SOe-07 3.30e-06 n-Heptane Mine, Claymore, M18Al 2.90e-06 3.40e-06 4.70e-06 3.70e-06 5.60e-06 n-Heptane Signal, Illumination, Red Star AN-M43A2 3.SOe-07 l. lOe-06 3.SOe-07 5.80e-07 l.OOe-06 n-Heptane Signal, Illumination, Red Star MlSB 1.lOe-06 7.00e-07 l.OOe-06 9. 30e-07 1. 60e-06 n-Heptane Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 4.30e-06 n-Hentane Tritonal surronate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 4.20e-06

001056 n-Heptane Tritonal surrogate with water 2.30e-06 1.80e-06 5.60e-06 3.20e-06 9.SOe-06 n-Heptane TNT IACCl) 4.60e-07 l.40e-06 O.OOe+OO 9.50e-07 5.50e-06 n-Heptane TNT (ACC2) 3.70e-07 3.70e-07 l.SOe-06 n-Heptane T45E7 Adapter Booster 3.60e-06 l.80e-06 4.60e-06 3.30e-06 8.00e-06 n-Heptane 20 mm HEI Cartridg_e 2.lOe-06 5.00e-06 8.90e-06 5.30e-06 l.50e-05 n-Heptane 40 mm HE! Cartridge 5. OOe-06 O.OOe+OO 0.00e+OO 5.00e-06 2.20e-05 n-Hexane Amatol surrogate 0.00e+OO 3. 70e-07 7.40e-07 5.60e-07 9.90e-07 n-Hexane Amatol surrogate with water 7.lOe-06 l.50e-05 l.lOe-05 l.lOe-05 l.60e-05 n-Hexane Cartridge, Impulse, ARD 446-1 l.50e-06 l.SOe-06 l.50e-06 l.50e-06 4.00e-06 n-Hexane Cartridge, Impulse, BBU-36/B l.60e-06 1. 40e-06 2.20e-06 l.70e-06 5.40e-06 n-Hexane Cartridge, Impulse, MK 107 2.60e-07 7.90e-07 5.20e-07 5.30e-07 l.40e-06 n-Hexane Composition B surrogate O.OOe+OO 7.40e-07 3.60e-07 5.50e-07 1. 20e-06 n-Hexane Detonating train 1. 50e-06 l.SOe-06 2.40e-06 l.BOe-06 5.BOe-06 n-Hexane Flare, IR Countermeasure M206 6. 60e-07 6.80e-07 6.BOe-07 6.80e-07 l.20e-06 n-Hexane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 9.70e-07 4.80e-07 6.SOe-07 l.lOe-06 n-Hexane Fuze, Tail Bomb FMU-54 A/B 3.00e-07 5.90e-07 O.OOe+OO 4.40e-07 1. 30e-06 n-Hexane Gas Generator, GGU-2/A 1. 20e-06 l.20e-06 6.lOe-07 9.90e-07 3.20e-06 n-Hexane HBX surrogate 7 .30e-07 O.OOe+OO 3.70e-07 5. SOe-07 4.70e-06 n-Hexane Mine, Claymore, Ml8Al 2.00e-06 l.50e-06 4.70e-07 1. 30e-06 3.20e-06 n-Hexane Signal, Illumination, Red Star AN-M43A2 6.90e-07 l.lOe-06 6.90e-07 8.lOe-07 1. 30e-06 n-Hexane Signal, Illumination, Red Star Ml58 l.40e-06 l.lOe-06 6.9De-07 l.lOe-06 l.90e-06 n-Hexane Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 7.00e-06 n-Hexane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 6.80e-06 n-Hexane Tritonal surrogate with water l.90e-06 l.SOe-06 4.50e-06 2.60e-06 1. 30e-05 n-Hexane TNT (ACCl) 1.40e-06 4.BOe-07 O.OOe+OO 9.30e-07 3.30e-06 n-Hexane TNT (ACC2) 0.00e+OO O.OOe+OO l.lOe-06 n-Hexane T45E7 Adapter Booster 3.00e-06 4.?0e-06 9.BOe-06 5.80e-06 9.90e-06 n-Hexane 20 mm HEI Cartridge l.40e-06 3. 60e-06 5.40e-06 3.50e-06 1. 30e-05 n-Hexane 40 mm HEI Cartridge l.90e-05 O.OOe+OO O.OOe+OO l.90e-05 3.50e-05 n-Nonane Amato! surrogate 3.70e-07 3.70e-07 0.00e+OO 3.70e-07 3.70e-07 n-Nonane Amato! surrogate with water 2.20e-06 4.40e-06 3.00e-06 3.20e-06 3.70e-06 n-Nonane Cartridge, Impulse, ARD 446-1 2.60e-07 7.?0e-07 7.50e-07 5.90e-07 l.40e-06 n-Nonane Cartridge, Impulse, BBU-36/B 2.70e-06 3.60e-06 3.30e-06 J.20e-06 6.90e-06 n-Nonane Cartridge, Impulse, MK 107 O.OOe+OO 2.60e-07 7.90e-07 5.20e-07 9.60e-07 n-Nonane Composition B surrogate 2.20e-06 J.70e-07 O.OOe+OO 1. 30e-06 1. 20e-06 n-Nonane Detonating train 5.80e-07 9.00e-07 9.00e-07 7.90e-07 2.00e-06 n-Nonane Flare, IR Countermeasure M206 6.GOe-07 6.80e-07 6.80e-07 6.80e-07 9.00e-07 n-Nonane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 4.SOe-07 0.00e+OO 4.90e-07 7.30e-07 n-Nonane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO 1. 20e-06 l.20e-06 9.40e-07 n-Nonane Gas Generator, GGU-2/A 5.90e-07 5.90e-07 O.OOe+OO 5.90e-07 1. 20e-06 n-Nonane HEX surroaate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 5.20e-07

001057 n-Nonane Mine, Claymore, MlBAl 4.90e-07 1.50e-06 1.90e-06 1.30e-06 1. BOe-06 n-Nonane Signal, Illumination, Red Star AN-M43A2 l.OOe-06 3.50e-07 O.OOe+OO 7.00e-07 9.30e-07 n-Nonane Signal, Illumination, Red Star M158 1. lOe-06 7.00e-07 1. OOe-06 9.30e-07 1. 30e-06 n-Nonane Tritonal surrogate 3.40e-06 O.OOe+OO 3.60e-07 1.20e-06 l.60e-06 n-Nonane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 5.50e-07 n-Nonane Tritonal surrogate with water O.OOe+OO 7.30e-07 7.50e-07 7.40e-07 l.50e-06 n-Nonane TNT (ACCl) O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO l.40e-06 n-Nonane TNT (ACC2) O.OOe+OO O.OOe+OO 3.70e-07 n-Nonane T45E7 Adapter Booster 1. BOe-06 5.90e-07 1.70e-06 1. 40e-06 2.50e-06 n-Nonane 20 mm HEI Cartridge 7.00e-07 O.OOe+OO 6.BOe-07 6.90e-07 3.60e-06 n-Nonane 40 mm HEI Cartridge l.70e-06 l.70e-06 2.50e-06 1.90e-06 4.BOe-06 n-Octane Amato! surrogate O.OOe+OO 3.70e-07 3.70e-07 3.70e-07 6.20e-07 n-Octane Amato! surrogate With water 3.30e-06 7.00e-06 4.40e-06 4.90e-06 5.BOe-06 n-Octane Cartridge, Impulse, ARD 446-1 5.20e-07 1. OOe-06 O.OOe+OO 7.70e-07 l.40e-06 n-Octane Cartridge, Impulse, BBU-36/B 1.40e-06 2.BOe-07 1.90e-06 l.20e-06 4.00e-06 n-Octane Cartridge, Impulse, MK 107 5.30e-07 5.30e-07 2.60e-07 4.40e-07 7.70e-07 n-Octane Composition B surrogate 3.70e-07 3.70e-07 3.60e-07 3.70e-07 7.40e-07 n-Octane Detonating train O.OOe+OO l.SOe-06 0.00e+OO 1. 50e-06 2.70e-06 n-Octane Flare, IR Countermeasure M206 1. OOe-06 3.40e-07 O.OOe+OO 6.70e-07 7.80e-07 n-Octane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 4.80e-07 O.OOe+OO 4.90e-07 9.70e-07 n-Octane Fuze, Tail Bomb FMU-54 A/B 3.00e-07 3.00e-07 6.lOe-07 4.00e-07 l. lOe-06 n-Octane Gas Generator, GGU-2/A o.ooe+oo O.OOe+OO 1. 20e-06 1. 20e-06 l.BOe-06 n-Octane HBX surrogate l.lOe-06 O.OOe+OO 3.70e-07 7.30e-07 l.BOe-06 n-Octane Mine, Claymore, MlBAl 2.00e-06 7.SOe-06 l.20e-05 7.20e-06 9.lOe-06 n-Octane Signal, Illumination, Red Star AN-M43A2 3.SOe-07 3.50e-07 0.00e+OO 3.SOe-07 5.80e-07 n-Octane Signal, Illumination, Red Star Ml58 l.40e-06 l.lOe-06 6.90e-07 l. lOe-06 l.40e-06 n-Octane Tritonal surrogate 3.70e-07 O.OOe+OO 3.60e-07 3.70e-07 l.70e-06 n-Octane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 1. 50e-06 n-Octane Tritonal surrogate with water 1. 50e-06 l.SOe-06 2.20e-06 1. 70e-06 3.70e-06 n-Octane TNT (ACCl) O.OOe+OO 2.90e-06 O.OOe+OO 2.90e-06 l.OOe-05 n-Octane TNT (ACC2) O.OOe+OO O.OOe+OO 7.40e-07 n-Octane T45E7 Adapter Booster 2.40e-06 O.OOe+OO l.20e-06 l.BOe-06 B.BOe-06 n-Octane 20 mm HEI Cartridge 4.90e-06 7.90e-06 l.60e-05 9.SOe-06 2.SOe-05 n-Octane 40 mm HEI Cartri~ge 2.50e-06 8.20e-07 7.40e-06 3.60e-06 2.90e-05 n-Pentane Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 6.20e-07 n-Pentane Amato! surrogate with water l.30e-05 2.30e-05 1.50e-05 l.70e-05 2.40e-05 n-Pentane Cartridge, Impulse, ARD 446-1 7.BOe-07 1.30e-06 l.30e-06 1. lOe-06 4.00e-06 n-Pentane Cartridge, Impulse, BBU-36/B l.lOe-06 l.!Oe-06 l.40e-06 1. 20e-06 5.20e-06 n-Pentane Cartridge, Impuls_e, MK 107 0. OOe+OO 2.60e-07 2.60e-07 2.60e-07 l.50e-06 n-Pentane Composition B surrogate 3.70e-07 O.OOe+OO 3.60e-07 3.70e-07 7.40e-07 n-Pentane Detonatino train 5.BOe-07 1.20e-06 l.20e-06 1.00e-06 6.lOe-06

001058 n-Pentane Flare, IR Countermeasure M206 O.OOe+OO 6.80e-07 3.40e-07 5.lOe-07 1.50e-06 n-Pentane Fuze, Tail Bomb FMU-139 A/B 9.70e-07 l.50e-06 4.BOe-07 9.70e-07 l.90e-06 n-Pentane Fuze, Tail Bomb FMU-54 A/B 3.00e-07 5.90e-07 O.OOe+OO 4.40e-07 3.70e-06 n-Pentane Gas Genera tor, GGU-2/A l.20e-06 l.20e-06 O.OOe+OO 1.20e-06 4.BOe-06 n-Pentane HEX surrogate 7.30e-07 O.OOe+OO 7.40e-07 7.40e-07 2. 3 Oe-06 n-Pentane Mine, Claymore, MlBAl 4.40e-06 B.BOe-06 1. 40e-05 9.lOe-06 1. 30e-05 n-Pentane Signal, Illumination, Red Star AN-M43A2 3.50e-07 7.00e-07 6.90e-07 5.BOe-07 l.20e-06 n-Pentane Signal, Illumination, Red Star M158 7.00e-07 7.00e-07 3.50e-07 5.BOe-07 2.lOe-06 n-Pentane Tritonal surrogate O.OOe+OO O.OOe+OO 7.30e-07 7.30e-07 3.BOe-06 n-Pentane Tritonal surrogate with calcium stearate O.OOe+OO 0.00e+OO O.OOe+OO 3.30e-06 n-Pentane Tritonal surrogate with water l. lOe-06 O.OOe+OO 6.70e-06 3.90e-06 5.50e-06 n-Pentane TNT (ACCl) l.BOe-06 4.BOe-06 O.OOe+OO 3.30e-06 l.lOe-05 n-Pentane TNT (ACC2) 3.70e-07 3.70e-07 1.90e-06 n-Pentane T45E7 Adapter Booster 3.60e-06 1. BOe-06 9.BOe-06 5.00e-06 l.60e-05 n-Pentane 20 mm HEI Cartridge 5.60e-06 l.20e-05 2.20e-05 1. 30e-05 3.20e-05 n-Pentane 40 mm HEI Cartridge l.30e-05 O.OOe+OO O.OOe+OO l.30e-05 5.20e-05 p-Ethyltoluene Amato! surrogate O.OOe+OO 6.00e-06 9.30e-06 7.60e-06 l.lOe-05 p-Ethyltoluene Amato! surrogate with water 2.00e-05 4.00e-05 3. 70e-05 3.20e-05 3.BOe-05 p-Ethyltoluene Cartridge, Impulse, BBU-36/B 4.90e-06 5.60e-07 1.40e-06 2.30e-06 9.40e-06 p-Ethyltoluene Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO p-Ethyltoluene Composition B surrogate 7.40e-07 7.40e-07 l.50e-06 9.BOe-07 3.30e-06 p-Ethyltoluene Detonating train 8.70e-07 1. 50e-06 1. 20e-06 l.20e-06 8.20e-06 p-Ethyltoluene Flare., JR Countermeasure M206 O.OOe+OO 3.40e-07 6.SOe-07 5.lOe-07 2.20e-06 p-Ethyltoluene Fuze, Tail Bomb FMU-139 A/B 2.00e-06 4.SOe-07 9. 70e-07 l.lOe-06 2.30e-06 p-Ethyltoluene Fuze, Tail Bomb FMU-54 A/B 5.90e-07 5.90e-07 4.60e-06 l.90e-06 4.70e-06 p-Ethyltoluene Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 6.BOe-06 p-Ethyltoluene HBX surrogate 7,30e-07 O.OOe+OO O.OOe+OO 7.30e-07 5.SOe-06 p-Ethyl toluene Mine, Claymore, Ml8Al l.50e-05 7.30e-06 2.80e-05 l.70e-05 l.90e-05 p-Ethyltoluene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO 7.00e-07 O.OOe+OO 7.00e-07 l .. 60e-06 p-Ethyltoluene Signal, Illumination, Red Star Ml58 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO l.70e-06 p-Ethyltoluene Tritonal surrogate 7.40e-06 4.lOe-06 1. 50e-06 4.30e-06 9.20e-06 p-Ethyl toluene Tritonal surrogate with calcium stearate 0.00e+OO 7.30e-07 7 .30e-07 4.60e-06 p-Ethyltoluene Tritonal surrogate with water 3.90e-05 1.SOe-05 2.BOe-05 2.70e-05 3.40e-05 p-Ethyltoluene TNT (ACCl) 4.60e-07 l.90e-06 O.OOe+OO 1. 20e-06 7.70e-06 p-Ethyltoluene TNT (ACC2) O.OOe+OO O.OOe+OQ 2.60e-06 p-Ethyltoluene T45E7 Adapter Booster l.lOe-05 9.40e-06 l.20e-05 l.lOe-05 1.lOe-05 p-Ethyltoluene 20 mm HE! Cartridge O.OOe+OO l.lOe-05 1. 60e-05 1. 40e-05 2.60e-05 p-Ethyltoluene 40 mm HE! Cartridge 7.50e-06 4.lOe-06 4.lOe-06 5.20e-06 2.60e-05 p-Ethyltoluene Amato! surrogate 3.70e-07 O.OOe+OO O.OOe+OO 3.?0e-07 l.60e-06 p-Ethyltoluene Amato! surrogate with water 2.20e-06 2.20e-06 l.90e-06 2.lOe-06 4.lOe-06 lo Ethvltoluene Cartridne, Imnulse. ARD 446-1 l. lOe-06 l.lOe-06 l. lOe-06 l.lOe-06 4.20e-06

001059 p-Ethyltoluene Cartridge, Impulse, BBU-36/B 2.30e-06 l.20e-06 l.20e-06 1. 60e-06 5.40e-06 p-Ethyltoluene Cartridge, Impulse, MK 107 O.OOe+OO l.lOe-06 l.lOe-06 l.lOe-06 l.lOe-06 p-Ethyltoluene Composition B surr-ogate 7.40e-07 3.70e-07 l.lOe-06 7.40e-07 2.60e-06 p-Ethyltoluene Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.90e-06 p-Ethyltoluene Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO l.50e-06 p-Ethyltoluene Fuze, Tail Bomb FMU-139 A/B 2.lOe-06 O.OOe+OO O.OOe+OO 2.lOe-06 2.lOe-06 p-Ethyltoluene Fuze, Tail Bomb FMU-54 A/B l.JOe-06 2.60e-06 1. 30e-06 l.70e-06 2.90e-06 p-Ethyltoluene Gas Generator, GGU-2/A 2.50e-06 5.lOe-06 O.OOe+OO 3.BOe-06 4.20e-06 p-Ethyltoluene HBX surrogate J.70e-07 O.OOe+OO 7.40e-07 5.60e-07 4.BOe-06 p-Ethyltoluene Mine, Claymore, MlBAl 4.20e-06 4.20e-06 4.20e-06 p-Ethyltoluene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO l.SOe-06 O.OOe+OO l.50e-06 l.50e-06 p-Ethyltoluene Signal, Illumination, Red Star Ml58 O.OOe+OO 1. 50e-06 O.OOe+OO l.50e-06 1. SOe-06 p-Ethyltoluene Tritonal surrogate O.OOe+OO 0.00e+OO 3.60e-07 J.60e-07 3.30e-06 p-Ethyltoluene Tritonal surrogate with calcium stearate 3.70e-07 O.OOe+OO 3.70e-07 4.20e-06 p-Ethyltoluene Tritonal surrogate with water l.lOe-06 O.OOe+OO O.OOe+OO l.lOe-06 4.70e-06 p-Ethyltoluene TNT (ACCl) O.OOe+OO O.OOe+OO 2.00e-06 p-Ethyltoluene TNT (ACC2) O.OOe+OO O.OOe+OO l.60e-06 p-Ethyltoluene T45E7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO p-Ethyltoluene 20 mm HEI Cartridge O.OOe+OO O.OOe+OO 4.lOe-06 p-Ethyltoluene 40 rran HEI Cartridge O.OOe+OO O.OOe+OO 9.50e-06 trans-2-Butene l~m~tol surrogate O.OOe+OO O.OOe+OO l.50e-06 l.50e-06 1. 50e-06 trans-2-Butene Amato! surrogate with water 2.40e-05 4.60e-05 3.40e-05 3.50e-05 3.50e-05 trans-2-Butene Cartridge, Impulse, ARD 446-1 1. OOe-05 7.70e-06 7.20e-06 B.30e-06 B.30e-06 trans-2-Butene Cartridge, Impulse, BBU-36/B O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO trans-2-Butene Cartridge, Impulse, MK 107 1. ooe-05 B.20e-06 7.lOe-06 B.40e-06 B.40e-06 trans-2-Butene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Butene Detonating train 4.70e-06 2.70e-06 4.BOe-06 4.00e-06 4.00e-06 trans-2-Butene Flare, IR Countermeasure M206 3.00e-06 2.70e-06 2.70e-06 2.BOe-06 2.BOe-06 trans-2-Butene Fuze, Tail Bomb FMU-139 A/B l.20e-05 l.30e-05 l.40e-05 l.30e-05 1. 30e-05 trans-2-Butene Fuze, Tail Bomb FMU-54 A/B 5.90e-06 9.50e-06 7.90e-06 7.BOe-06 l. lOe-05 trans-2-Butene Gas Generator, GGU-2/A l.40e-05 l.50e-05 l.60e-05 l.50e-05 l.50e-05 trans-2-Butene HBX surrogate 4.00e-06 2.SOe-06 7.lOe-06 4.50e-06 4.50e-06 trans-2-Butene Mine, Claymore, MlBAl l.50e-05 l.90e-05 2.lOe-05 l.BOe-05 l.BOe-05 trans-2-Butene Signal, Illumination, Red Star AN-M43A2 6.90e-06 9.lOe-06 7.30e-06 7.BOe-06 7.BOe-06 trans-2-Butene Signal, Illumination, Red Star Ml58 5.JOe-06 6.00e-06 4.BOe-06 5.40e-06 5.40e-06 trans-2-Butene Tritonal surrogate O.OOe+OO l.90e-06 l.lOe-06 l.50e-06 l.50e-06 trans-2-Butene Tritonal surrogate with calcium stearate 2.90e-06 7.30e-07 l.BOe-06 l.SOe-06 trans-2-Butene Tritonal surrogate with water 4.lOe-05 2.BOe-05 4.60e-05 3.BOe-05 3.BOe-05 trans-2-Butene TNT (ACCl) 9.20e-07 9.60e-07 9.60e-07 9.50e-07 9.50e-07 trans-2-Butene TNT IACC2) 7.40e-07 7.40e-07 7.40e-07 trans-2-Butene T45E7 Adanter Booster 2.60e-05 1. BOe-05 l.60e-05 2.00e-05 2.00e-05

001060 trans-2-Butene 20 mm HEI Cartridge l.lOe-05 7.20e-06 1. OOe-05 9.50e-06 9.50e-06 trans-2-Butene 40 mm HEI Cartridge 2.50e-06 l.70e-06 l.60e-06 l.90e-06 l.90e-06 trans-2-Pentene Amatol surrogate O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO trans-2-Pentene Amatol surrogate with water 8.50e-06 l.70e-05 1. 20e-05 l.20e-05 1. 3 Oe-05 trans-2-Pentene Cartridge, Impulse, ARD 446-1 5.20e-07 7. 70e-07 5.00e-07 6.00e-07 l.20e-06 trans-2-Pentene Cartridge, Impulse, BBU-36/B 8.20e-07 5.60e-07 5.60e-07 6.40e-07 l.40e-06 trans-2-Pentene Cartridge, Impulse, MK 107 2.60e-07 2.60e-07 2.60e-07 2.60e-07 2.60e-07 trans-2-Pentene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Detonating train 1. 50e-06 9.00e-07 3.00e-07 8.80e-07 2.00e-06 trans-2-Pentene Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.40e-07 trans-2-Pentene Fuze, Tail Bomb FMU-139 A/B 9.70e-07 3.90e-06 9.70e-07 l.90e-06 1. 90e-06 trans-2-Pentene Fuze, Tail Bomb FMU-54 A/B 5.90e-07 1. 20e-06 9.20e-07 9.00e-07 1. 60e-06 trans-2-Pentene Gas Generator, GGU-2/A 2.40e-06 l.20e-06 6.lOe-07 l.40e-06 2.00e-06 trans-2-Pentene HBX surrogate 3.70e-07 O.OOe+OO O.OOe+OO 3.70e-07 3.80e-07 trans-2-Pentene Mine, Claymore, Ml8Al O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene Signal, Illumination, Red Star AN-M43A2 3.50e-07 7.00e-07 3.SOe-07 4.60e-07 4.60e-07 trans-2-Pentene Signal, Illumination, Red Star Ml58 7.00e-;07 l.40e-06 3.SOe-07 8.20e-07 9.30e-07 trans-2-Pentene Tritonal surrogate 3.70e-07 3.70e-07 O.OOe+OO 3.?0e-07 8.60e-07 trans-2-Pentene Tritonal surrogate with calcium stearate O.OOe+OO 3.60e-07 3.60e-07 7 .30e-07 trans-2-Pentene Tritonal surrogate with water 2.30e-06 3.30e-06 3.70e-06 3.lOe-06 3.60e-06 trans-2-Pentene TNT (ACCl) 4.60e-07 0.00e+OO 0.00e+OO 4.60e-07 4.60e-07 trans-2-Pentene TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO trans-2-Pentene T45E7 Adapter Booster 4. 20e-06 4.lOe-06 4.00e-06 4.lOe-06 4.lOe-06 trans-2-Pentene 20 mm HEI Cartridge O.OOe+OO 1. 40e-06 1. 40e-06 l.40e-06 l.40e-06 trans-2-Pentene 40 mm HEI Cartridge 5.00e-06 O.OOe+OO O.OOe+OO 5.00e-06 1.lOe-05 Acetylene Amato! surrogate l.90e-04 4.60e-05 5.40e-05 9.60e-05 9.70e-05 Acetylene Amato! surrogate with water 7.60e-05 l.30e-04 2.20e-04 l.40e-04 l.40e-04 Acetylene Cartridge, Impulse, ARD 446-1 2.80e-04 l.90e-04 l.SOe-04 2.20e-04 3.20e-04 Acetylene Cartridge, Impulse, BBU-36/B l.50e-04 l.30e-04 l.70e-04 l.50e-04 3.00e-04 Acetylene Cartridge, Impulse, MK 107 2.80e-04 2.50e-04 l.90e-04 2.40e-04 3.50e-04 Acetylene Composition B surrogate 6.70e-06 8.90e-06 2.70e-05 l.40e-05 1.50e-05 Acetylene Detonating train 1. 80e-04 7.30e-05 l.40e-04 1. 30e-04 2.lOe-04 Acetylene Flare, IR Countermeasure M206 2.60e-04 3.lOe-04 2.80e-04 2.90e-04 2.90e-04 Acetylene Fuze, Tail Bomb FMU-139 A/B 5.40e-04 6.60e-04 6.60e-04 6.20e-04 6.20e-04 Acetylene Fuze, Tail Bomb FMU-54 A/B 3.00e-04 5.70e-04 5.00e-04 4.60e-04 6.lOe-04 Acetylene Gas Generator, GGU-2/A 5.50e-04 6.30e-04 7.30e-04 6.40e-04 6.40e-04 Acetylene HBX surrogate 1.80e-05 l.80e-05 5.20e-05 2.90e-05 3.00e-05 Acetylene Mine, Cla:y:more, Ml8Al 7.70e-04 l. lOe-03 l.lOe-03 9.80e-04 9.80e-04 Acetylene Signal, Illumination, Red Star AN-M43A2 2.80e-04 3.SOe-04 2.90e-04 3.lOe-04 3.lOe-04 Acetylene Signal, Illumination, Red Star M158 2.80e-04 2.80e-04 2.30e-04 2.70e-04 2.70e-04 Acetvlene Tritonal surroaate 2.00e-04 1. 30e-04 4.30e-05 1.20e-04 1. 3 Oe-04

001061 Acetylene Tritonal surrogate with calcium stearate 2.lOe-05 l.6De-05 l.90e-05 2.00e-05 Acetylene Tritonal surrogate with water 4.30e-03 4.40e-03 4. 50e-03 4.40e-03 4.40e-03 Acetylene TNT (ACCl) 2.20e-05 l.60e-05 l.40e-05 l.70e-05 l.SOe-05 Acetylene TNT (ACC2) l.60e-05 l.60e-05 l.70e-05 Acetylene TNT (Sandia) S.OOe-06 2.40e-06 8.50e-06 S.30e-06 Acetylene T45E7 Adapter Booster 7.SOe-04 4.50e-04 3.60e-04 S.20e-04 S.30e-04 Acetylene 20 mm HE! Cartridge 2.20e-04 l.30e-04 1. 90e-04 1. SOe-04 2.SOe-04 Acetylene 40 nun HEI Cartridge S.20e-05 4.30e-OS 3.20e-05 4.20e-OS 6.40e-05 Allylchloride Arna.tel surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Amatol surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Cartridge, Impulse, BB0-36/B 5.20e-06 l.lOe-05 l.lOe-05 9.30e-06 9.30e-06 Allylchloride Cartridge, Impulse, MK 107 1. OOe-05 2.90e-06 2.lOe-06 5.lOe-06 5.lOe-06 Allylchloride Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Detonating train O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Flare, IR Countermeasure M206 2.lOe-05 l.60e-05 l.BOe-05 l.SOe-05 l.BOe-05 Allylchloride Fuze, Tail Bomb FMU-139 A/B 3.00e-05 3.30e-05 2.80e-05 3.00e-05 3.00e-05 Allylchloride Fuze, Tail Bomb FMU-54 A/B 2.lOe-05 8.30e-06 O.OOe+OO l.50e-05 l.50e-05 Allylchloride Gas Generator, GG0-2/A 9.20e-05 8.BOe-05 1. 60e-04 l.lOe-04 l.lOe-04 Allylchloride HBX surrogate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Mine, Claymore, M18Al O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Signal, Illumination, Red Star AN-M43A2 l.60e-05 l.40e-05 2.30e-05 l.BOe-05 l.BOe-05 Allylchloride Signal, Illumination, Red Star M158 2.20e-05 l. lOe-05 l.40e-05 l.60e-05 l.60e-05 Allylchloride Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride T45E7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride 20 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Allylchloride 40 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO 0. OOe+OO O.OOe+OO Aluminum Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Aluminum Amato! surrogate with water O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Aluminum Cartridge, Impulse, ARD 446-1 3.90e-03 3.40e-03 4.30e-03 3.90e-03 6.00e-03 Aluminum Cartridge, Impulse, BB0-36/B 8.40e-03 1. 20e-02 1. 30e-02 l. lOe-02 2.30e-02 Aluminum Cartridge, Impulse, MK 107 8.70e-03 9.70e-03 1. OOe-02 9.50e-03 1. 40e-02 Aluminum Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Aluminum Detonating train O.OOe+OO 9.20e-05 0.00e+OO O.OOe+OO 3.00e-04 Aluminum Flare, IR Countermeasure M206 1. 90e-02 l.40e-02 1. 20e-02 l.50e-02 l.50e-02 Aluminum Fuze, Tail Bomb FMU-139 A/B 4.00e-02 3.20e-02 3.20e-02 3.40e-02 3.50e-02 Aluminum Fuze Tail Bomb FMU-54 A/B l.OOe-02 1. 30e-02 l.30e-02 1. 20e-02 l.60e-02

001062 Aluminum Gas Generator, GGU-2/A 6.30e-03 5. 60e-03 4.30e-03 5.40e-03 5.80e-03 Aluminum HBX surrogate 6.lOe-03 8.90e-03 l.lOe-02 8.60e-03 8.60e-03 Aluminum Mine, Claymore, MlBAl 6. 20e-03 6.20e-03 8.60e-04 Aluminum Signal, Illumination, Red Star AN-·M43A2 l.90e-02 l.70e-02 2.lOe-02 1. 90e-02 l.90e-02 Aluminum Signal, Illumination, Red Star M158 2.80e-03 l.80e-03 l.80e-03 2.lOe-03 2.70e-03 Aluminum Tritonal surrogate 4.20e-02 l.80e-02 l.60e-02 2.SOe-02 2.SOe-02 Aluminum Tritonal surrogate with calcium stearate l.60e-02 l.70e-02 l.70e-02 1.70e-02 Aluminum Tritonal surrogate with water 3.lOe-03 7.00e-03 8.00e-03 6.00e-03 6.00e-03 Aluminum TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO Aluminum TNT (ACC2) 1. 30e-03 1. 30e-03 1. 30e-03 Aluminum T45E7 Adapter Booster 8.80e-03 8.BOe-03 1.70e-03 Aluminum 20 mm HEI Cartridge 9.60e-04 9.60e-04 7.lOe-05 Aluminum 40 mm HEI Cartridge l.SOe-02 1. SOe-02 3.90e-03 Antimony Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Amato! surrogate with water 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Antimony Cartridge, Impulse, ARD 446-1 l.80e-04 1.60e"04 2.00e-04 l.BOe-04 1.BOe-04 Antimony Cartridge, Impulse, BBU-36/B 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Composition B surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Detonating train O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Antimony Fuze, Tail Bomb FMU-139 A/B 2.90e-04 2.20e-04 l.SOe-04 2.20e-04 2.20e-04 Antimony Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO Antimony HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Mine, Claymore, M18Al O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Antimony Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Signal, Illumination, Red star M158 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO o. o.oe+oo Antimony Tritonal surrogate with calcium stearate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Antimony TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony TNT (Sandia) 3.20e-07 7.00e-07 1.00e-06 6.70e-07 Antimony T45E7 Adapter Booster O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO 0.00e+OO Antimony 20 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Antimony 1:' ~ .. !!FI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium • •. 1· ' '".1! t -~"HP O.OOe+OO 2.40e-05 3.20e-05 6.00e-06 8.00e-06 Barium : l" <' .>."i • h "A"l. ''! O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO O.OOe+OO

... ~. 0 • Barium ·.•.: .: ' ; 01:' 00 0 C'Oe+OO 0.00e+OO O.OOe+OO l.OOe-06 . ·• l C':'e• C'Cl (\Qp .. co Cl OOe+OO O.OOe+OO Barium : '' " 0.00e+OO 99

001063 Barium Cartridge, Impulse, MK 107 0.00e+OO 2.50e-05 3. 70e-05 l.60e-05 l.90e-04 Barium Composition B surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium Detonating train O.OOe+-00 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+-00 Barium Flare, IR Countermeasure M206 l.SOe-04 3.lOe-04 2.60e-04 2.40e-04 2.40e-04 Barium Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium Fuze, Tail Bomb FMlJ-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Barium Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium HBX surrogate 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Barium Mine, Claymore, M18Al O.OOe+-00 0.00e+OO O.OOe+OO Barium Signal, Illumination, Red Star AN-M43A2 7.BOe-05 7.70e-05 l.BOe-04 l.lOe-04 l.lOe-04 Barium Signal, Illumination, Red Star Ml58 2.lOe-04 l.60e-04 1. 40e-04 l.70e-04 2.60e-04 Barium Tritonal surrogate 4.70e-04 O.OOe+OO 1. 60e-04 l.60e-04 l.60e-04 Barium Tritonal surrogate with calcium stearate 3.lOe-04 4.lOe-04 3.60e-04 3.60e-04 Barium Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Barium TNT (ACCl) 1. lOe-04 l.lOe-04 l. lOe-04 Barium TNT (ACC2) 3.60e-04 3.60e-04 3.70e-04 Barium TNT {Sandia) 7.90e-03 7.70e-03 B.90e-03 B.20e-03 Barium T45E7 Adapter Booster 6.lOe-04 6.lOe-04 6.lOe-04 Barium 20 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO Barium 40 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO Benzene Amato! surrogate 4.20e-05 l.OOe-05 1. 60e-05 2.30e-05 2.50e-05 Benzene Amato! surrogate with water 1.90e-04 3.60e-04 2.70e-04 2.70e-04 2.BOe-04 Benzene Cartridge, Impulse, ARD 446-1 7.70e-05 6.30e-05 6.lOe-05 6.70e-05 l.OOe-04 Benzene Cartridge, Impulse, BBU-36/B 2.lOe-05 l.90e-05 2.30e-05 2.lOe-05 4.70e-05 Benzene Cartridge, Impulse, MK 107 6.90e-05 6.70e-05 5.SOe-05 6.40e-05 9.60e-05 Benzene Composition B surrogate 2.20e-06 2.20e-06 3.30e-06 2.60e-06 5.00e-06 Benzene Detonating train 2.40e-05 2.30e-05 2.60e-05 2.50e-05 4.60e-05 Benzene Flare, IR Countermeasure M206 4.60e-05 3.90e-05 5.00e-05 4.50e-05 4.BOe-05 Benzene Fuze, Tail Bomb FMU-139 A/B l.lOe-04 l.20e-04 l.30e-04 l.20e-04 l.2.0e-04 Benzene Fuze, Tail Bomb FMU-54 A/B 6.40e-05 l.70e-04 l.OOe-04 l. lOe-04 l.SOe-04 Benzene Gas Generator, GGU-2/A l. lOe-04 l.30e-04 l.50e-04 1. 30e-04 l.40e-04 Benzene HBX surrogate 6.60e-06 4.50e-06 l.OOe-05 7.20e-06 l.40e-05 Benzene Mine, Claymore, MlBAl 5.50e-04 9.40e-04 9.30e-04 B.lOe-04 B.lOe-04 Benzene Signal, Illumination, Red Star AN-M43A2 3.00e-05 3.60e-05 3.50e-05 3.40e-05 3.60e-05 Benzene Signal, Illumination, Red Star M158 3.00e-05 3.40e-05 2.60e-05 3.00e-05 3.30e-05 Benzene Tritonal surrogate 1. 20e-05 3.30e-06 l.50e-06 5.70e-06 l.60e-05 Benzene Tritonal surrogate with calcium stearate 4.40e-06 l.BOe-06 3.lOe-06 l.40e-05 Benzene Tritonal surrogate with water 2.90e-04 l.20e-04 2.lOe-04 2.00e-04 2.20e-04 Benzene TNT (ACCl) 4.60e-06 4.BOe-06 2.90e-06 4.lOe-06 B.BOe-06 Benzene TNT (ACC2) 4.lOe-06 4.lOe-06 7.40e-06 Benzene TNT (Sandia) 1. 40e-06 3.30e-06 4.20e-06 3.00e-06

100

001064 Benzene T45E7 Adapter Booster l.60e-04 l.40e-04 8. OOe-05 1. 30e-04 l.30e-04 Benzene 20 mm HE! Cartridge 1.SOe-04 8.90e-05 9.90e-05 l. lOe-04 l.70e-04 Benzene 40 mm HEI Cartridge 2.80e-05 O.OOe+OO O.OOe+OC 2.SCe-05 4.90e-05 Cadmium Amatol surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Amatol surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Cartridge, Impulse, ARD 446-1 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Cartridge, Impulse, BBU-36/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Cartridge, Impulse, MK 107 l.OOe-03 l.80e-03 1. 40e-03 l.40e-03 l.40e-03 Cadmium Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Detonating train· l.lOe-05 l.40e-05 7.00e-06 l.lOe-05 l.lOe-05 Cadmium Flare, IR Countermeasure M206 4.90e-05 3.00e-05 2.30e-05 3.40e-05 3.SOe-05 Cadmium Fuze, Tail Bomb FMU-139 A/B 2. 40e-03 2.lOe-03 2. 20e-03 2.30e-03 2. 3 Oe-03 Cadmium Fuze, Tail Bomb FMU-54 A/B l.80e-04 l.50e-04 5.90e-04 3.lOe-04 4.lOe-04 cadmium Gas Generator, GGU-2/A 4.50e-05 2.lOe-04 4.90e-05 1. OOe-04 l.OOe-04 Cadmium HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Mine, Claymore, MlBAl 2.40e-04 2. 40e-04 2.40e-04 Cadmium Signal, Illumination, Red Star AN-M43A2 l.30e-04 7.00e-05 6.lOe-05 8.BOe-05 9.00e-05 Cadmium Signal, Illumination, Red Star Ml58 1. 30e-03 9.40e-04 l.lOe-03 l.lOe-03 1.30e-03 Cadmium Tritonal surrogate O.DOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Tritonal surrogate with calcium stearate o.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cadmium TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO cadmium TNT (ACC2) 4.00e-05 4.00e-05 4.00e-05 Cadmium TNT (Sandia) 2.90e-06 2.50e-06 2.BOe-06 2.70e-06 Cadmium T45E7 Adapter Booster 5.BOe-03 5.80e-03 5.80e-03 Cadmium 20 mm HEI Cartridge 8.60e-04 8.60e-04 4.00e-04. Cadmium 40 nun HE! Cartridge 3.20e-05 3.20e-05 3.20e-05 Carbon tetrachloride Amato! surrogate 3.70e-C7 O.OOe+OO O.OOe+OO 3.70e-07 2.lOe-06 Carbon tetrachloride Amato! surrogate with water 3.70e-07 3.70e-07 3.?0e-07 3.?0e-07 2.20e-06 Carbon tetrachloride Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Carbon tetrachloride Cartridge, Impulse, BBU-36/B o.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO O.OOe+OO Carbon tetrachloride Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Carbon tetrachloride Composition B surrogate O.OOe+OO 0.00e+OO 3.60e-07 3.60e-07 2.20e-06 Carbon tetrachloride Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Carbon tetrachloride Flare, IR Countermeasure M206 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO l.90e-06 Carbon tetrachloride Fuz.e, Tail Bomb FMU-139 A/B O.OOe+OO 2.70e-06 O.OOe+OO 2.70e-06 2.70e-06 Carbon tetrachloride Fuze, Tail Bomb FMU-54 A/B O.ODe+OO O.OOe+OO 0.00e+OO O.OOe+OO 2.20e-06 Carbon tetrachloride Gas Generator, GGU-2/A O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 3.30e-06 Carbon tetrachloride HBX surroqate O.OOe+OO 4.lOe-07 3.70e-07 3.90e-07 2.30e-06 Carbon tetrachloride ~: i r.~' Cla:,":T10re, MIBAl O.OOe+OO O.OOe+OO O.OOe+OO 0. OOe+OO 0.00e+OO Carbon tetrachloride .::i ~nal IlluMination Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.90e-06

IOI

001065 Carbon tetrachloride Signal, Illumination, Red Star M158 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.90e-06 Carbon tetrachloride Tritonal surrogate O.OOe+OO 3.70e-07 O.OOe+OO 3.70e-07 2.00e-06 Carbon tetrachloride Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 1.BOe-06 Carbon tetrachloride Tritonal surrogate with water 3. 70e-07 3.70e-07 7.50e-07 4.BOe-07 2.40e-06 Carbon tetrachloride TNT (ACCl) O.OOe+OO O.OOe+OO 2.50e-06 Carbon tetrachloride TNT (ACC2) 0. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Carbon tetrachloride T45E7 Adapter Booster 3.20e-06 3.20e-06 6.50e-06 carbon tetrachloride 20 mm HEI Cartridge 7.60e-06 7.60e-06 1.60e-05 Carbon tetrachloride 40 mm HEI Cartridge 4.50e-06 4.50e-06 l.20e-05 Chloroform Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.70e-07 Chloroform Amato! surrogate with water 3.70e-07 3.70e-07 O.OOe+OO 3.70e-07 7.40e-07 Chloroform Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Chloroform Cartridge, Impulse, BBU-36/B 0.00e+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Composition B surrogate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 3.70e-07 Chloroform Detonating train O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Chloroform Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Fuze, Tail Bomb FMq"-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Gas Generator, GGU-2/A 2.50e-06 2.50e-06 2.60e-06 2.60e-06 2.60e-06 Chloroform HBX surrogate 3.70e-07 4. lOe-07 3.70e-07 3.BOe-07 7.60e-07 Chloroform Mine, Claymore, MlBAl O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO chioroform Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Signal, Illumination, Red Star Ml58 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform Tritonal surrogate O.OOe+OO O.OOe+OO 3.60e-07 3.60e-07 7.40e-07 Chloroform Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 3.70e-07 Chloroform Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform T45E7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chloroform 20 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Chloroform 40 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO 0. OOe+OO O.OOe+OO O.OOe+OO Chromium Cartridge, Impulse, BBU-36/B 2.00e-05 O.OOe+OO 2.50e-05 2.20e-05 2.20e-05 Chromium Cartridge, Impulse, MK 107 4.30e-05 2.90e-05 2.BOe-05 3.30e-05 3.30e-05 Chromium Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Flaire, IP. Countermeasure H206 l.40e-04 l.70e-04 l.60e-04 1. 60e-04 l.60e-04 Chromium Fu::~ T<"il e")rrl::: rr-ru-139 A/B l.60e-04 l.20e-04 l.30e-04 l.40e-04 l.40e-04

102

001066 Chromium Fuze, Tail Bomb FMU-54 A/B 5.50e-05 3.50e-05 2.BOe-05 3.90e-05 5.50e-05 Chromium Gas Generator, GGU-2/A 5.30e-05 9.70e-05 1. 40e-04 9.60e-05 9.60e-05 Chromium HBX surrogate 0.00e+OO 0.-00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Chromium Mine, claymore, MlBAl 3.BOe-05 3.BOe-05 3.80e-05 Chromium Signal, Illumination, Red Star AN-M43A2 6.60e-05 5.20e-05 5.30e-05 5.70e-05 5.BOe-05 Chromium Signal, Illumination, Red Star Ml58 1. 30e-04 l.50e-04 l.SOe-04 1. 50e-04 1.50e-04 Chromium Tritonal surrogate 0.00e+OO D.OOe+OD O.OOe+OO O.OOe+OO O.OOe+OO Chromium Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 9.lOe-06 Chromium Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.20e-06 Chromium TNT IACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.00e-06 Chromium TNT (ACC2) 2.30e-OS 2.30e-05 2.50e-05 Chromium TNT (Sandia) l.30e-06 3.SOe-06 2.50e-06 2.40e-06 Chromium T45E7 Adapter.Booster 9.40e-05 9.40e-05 9.40e-05 Chromium 20 mm HEI Cartridge 3.50e-05 3.50e-05 3.50e-05 Chromium 40 mm HE! Cartridge 8.BOe-05 8.80e-05 8.BOe-05 Copper Aro.a.to! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Copper Amato! surrogate with water 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Copper Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 9.SOe-05 Copper Cartridge, Impulse, BBU-36/B 8.BOe-04 1.40e-03 l.40e-03 1. 20e-03 2.90e-03 Copper Cartridge, Impulse, MK 107 l .30e-03 l.50e-03 l.SOe-03 1.40e-03 2.40e-03 Copper Composition B surrogate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Copper Detonating train O.OOe+OO 4.?0e-04 O.OOe+OO O.OOe+OO 2.60e-04 Copper Flare, IR Countermeasure M206 6.SOe-05 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Copper Fuze, Tail. Bomb FMU-139 A/B 7.?0e-03 6.60e-03 5.90e-03 6.80e-03 6.80e-03 Copper Fuze, Tail Bomb FMU-54 A/B 4.40e-04 4.SOe-04 6.40e-04 5.lOe-04 8.60e-04 Copper Gas Generator, GGU-2/A 6.60e-04 7.00e-04 5.50e-04 6.40e-04 7.lOe-04 Copper HBX surrogate l.90e-03 4.SOe-03 3.lOe-03 3.20e-03 3.20e-03 Copper Mine, Claymore, M18Al 4.70e-03 4.70e-03 7.lOe-04 Copper Signal, Illumination, Red Star AN-M43A2 6.90e-04 2.00e-04 2.30e-04 3.?0e-04 3.90e-04 copper Signal, Illumination, Red Star M158 O.OOe+OO l.80e-03 O.OOe+OO O.OOe+OO O.OOe+OO Copper Tritonal surrogate O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO Copper Tritonal surrogate with calcium stearate 1. OOe-04 O.OOe+OO 4.40e-05 7.50e-05 Copper Tritonal surrogate with water 9.20e-04 7.70e-04 9.60e-04 8.80e-04 9.lOe-04 Copper TNT (ACCl) 3.00e-04 3.00e-04 0.00e+OO Copper TNT (ACC2) 5.00e-04 5.00e-04 5.20e-04 Copper T45E7 Adapter Booster 2.70e-03 2.70e-03 3.20e-04 Copper 20 mm HEI Cartridge 2.60e-02 2.60e-02 1. 20e-02 Copper 40 mm HEI Cartridge 8.90e-03 8.90e-03 2.30e-03 Cyclohexane Amatol surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Alnatol surrogate with water 7.40e-07 O.OOe+OO O.OOe+OO 7.40e-07 l.50e-06 Cvclohexane Cartridne, Imnulse ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO

103

001067 Cyclohexane Cartridge, Impulse, BBU-36/B 0.00e+OO 5.60e-07 O.OOe+OO 5.60e-07 1.70e-06 Cyclohexane Cartridge, Impulse, MK 107 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Composition B surrogate 0.00e+OO O.DDe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Detonating train 8.70e-07 O.OOe+OO 6.00e-07 7.30e-07 1.BOe-06 Cyclohexane Flare, IR Countermeasure M206 3.30e-07 O.OOe+OO O.OOe+OO 3.30e-07 3.30e-07 Cyclohexane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 O.OOe+OO O.OOe+OO 4.90e-07 4.90e-07 Cyclohexane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 5.BOe-07 Cyclohexane . Mine, Claymore, MlBAl 2.00e-06 4.90e-07 1.40e-06 1.30e-06 1.BOe-06 Cyclohexane Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Signal, Illumination, Red Star Ml58 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclohexane Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 7.40e-07 Cyclohexane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 7.30e-07 Cyclohexane Tritonal surrogate with water O.OOe+OO 0. OOe+OO O.OOe+OO O.OOe+OO 1.BOe-06 Cyclohexane TNT (ACCl) 2.30e-06 9.60e-07 0. OOe+OO l.60e-06 3.00e-06

Cyclohexane TNT (ACC2) . O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Cyclohexane T45E7 Adapter Booster l.BOe-06 l.20e-06 4.00e-06 2.30e-06 4.70e-06 Cyclohexane 20 mm HE! Cartridge 7.00e-07 O.OOe+OO 6.BOe-07 6.90e-07 6.50e-06 Cyclohexane 40 mn HEI Cartridge 7.50e-06 O.OOe+OO O.OOe+OO 7.50e-06 l.60e-05 Cyclopentane Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Cyclopentane Amato! surrogate with water 2.20e-06 4.40e-06 2.20e-06 3.00e-06 3.50e-06 Cyclopentane Cartridge, Impulse, ARD 446-1 O.OOe+OO 2.60e-07 O.OOe+OO 2.60e-07 7.50e-07 Cyclopentane Cartridge, Impulse, BBU-36/B 2.70e-07 2.80e-07 2.BOe-07 2.BOe-07 9.00e-07 Cyclopentane Cartridge, Impulse, MK 107 a. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Composition B surrogate O.OOe+OO O.OOe•OO 0. OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Detonating train O.OOe+OO O.OOe+OO 3.00e-07 3.00e-07 6.lOe-07 Cyclopentane Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO O.OOe+-00 O.OOe+-00 O.OOe+OO Cyclopentane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentane Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Cyclopentane HBX surrogate O.OOe+OO O.OOe+OO 1. lOe-06 l. lOe-06 7.50e-07 Cyclopentane Mine, Claymore, M18Al O.OOe+OO 9.BOe-07 4.70e-07 7.20e-07 7.20e-07 Cyclopentane Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OQ O.OOe+OO O.OOe+OO Cyclopentane Signal, Illumination, Red Star Ml58 O.OOe+-00 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+-00 Cyclopentane Tritonal surrogate 3.?0e-07 3.70e-07 3.60e-07 3.70e-07 7.40e-07 Cyclopentane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 5.50e-07 Cyclopentane Tri tonal surrogate _with water O.OOe+OO 1.50e-06 7.50e-07 l.lOe-06 l.90e-06 Cyclopentane TNT (ACCl) 4.60e-07 4.BOe-07 O.OOe+OO 4.70e-07 4.70e-07 Cyclopentane TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1(",.,clooentane T45E7 Adaoter Booster O.ODe+OO 5.90e-07 5.BOe-07 5.BOe-07 9.70e-07

104

001068 Cyclopentane 20 mm HEI Cartridge O.OOe+OO 7.20e-07 6.BOe-07 7.00e-07 l.60e-06 Cyclopentane 40 mm HEI Cartridge l.70e-06 O.OOe+OO O.OOe+OO l.70e-06 3.30e-06 Cyclopentene Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentene Arnatol surrogate with water 4.lOe-06 2.00e-05 O.OOe+OO l.20e-05 l.20e-05 Cyclopentene Cartridge, Impulse, ARD 446-1 2.lOe-06 5.lOe-06 2.00e-06 3.lOe-06 3.lOe-06 Cyclopentene Cartridge, Impulse, BBU-36/B 2.70e-06 O.OOe+OO 2.80e-06 2.70e-06 2.70e-06 Cyclopentene Cartridge, Impulse, MK 107 l.OOe-06 7.90e-07 l.OOe-06 9.70e-07 9.70e-07 Cyclopentene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Cyclopentene Detonating train 3. BOe-06 3.90e-06 3.30e-06 3.70e-06 3.70e-06 Cyclopentene Flare, IR Countermeasure M206 6.60e-07 6.BOe-07 l.OOe-06 7.90e-07 7.90e-07 Cyclopentene Fuze, Tail Bomb FMU-139 A/B 9. 70e-07 9.70e-07 4.80e-07 B.lOe-07 B.lOe-07 Cyclopentene Fuze, Tail Bomb FMU-54 .A/B 1.20e-06 1. 50e-06 1.20e-06 1. 30e-06 1.30e-06 Cyclopentene Gas Generator, GGU-2/A 4.lOe-06 1. 80e-06 4.90e-06 3.60e-06 3.60e-06 Cyclopentene HBX surrogate 3.70e-07 4.lOe-07 O.OOe+OO 3.90e-07 5.70e-07 Cyclopentene Mine, Claymore, M18Al 4.90e-07 O.OOe+OO O.OOe+OO 4.90e-07 4.90e-07 Cyclopentene Signal, Illumination, Red Star AN-M43A2 1. OOe-06 l.70e-06 l.OOe-06 1. 30e-06 1. 30e-06 Cyclopentene Signal, Illumination, Red star Ml58 3.SOe-06 2.lOe-06 1.70e-06 2.50e-06 2.50e-06 Cyclopentene Tritonal surrogate O.OOe+OO O.OOe+OO 1.30e-07 7.30e-07 7.30e-07 Cyclopentene Tritonal surrogate with calcium stearate D.OOe+OO 3.60e-07 3.60e-07 3.60e-07 Cyclopentene Tritonal surrogate with water O.OOe+DO 0.00e+OO 2.60e-06 2.60e-06 2.60e-06 Cyclopentene TNT IACCll 4.60e-07 O.OOe+OO O.OOe+OO 4.60e-07 4.60e-07 Cyclopentene TNT (ACC2) 3.70e-07 3.?0e-07 3.?0e-07 Cyclopentene T45E7 Adapter Booster 4.20e-06 4.lOe-06 2.90e-Of5 3.70e-06 3.70e-06 Cyclopentene 20 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Cyclopentene 40 mm HEI Cartridge 8.30e-07 O.OOe+OO O.OOe+OO 8.30e-07 1.70e-06 co Amato! surrogate 9.BOe-03 8.60e-03 l.lOe-02 9.70e-03 co Amato! surrogate with water 1. 90e-Ol 3.lOe-01 l.90e-Ol 2.30e-01 co Cartridge, Impulse, ARD 446-1 l.40e-02 l.20e-02 l.30e-02 l.30e-02 co Cartridge, Impulse, BBU-36/B 8.lOe-03 8.lOe-03 9.00e-03 8.40e-03 co Cartridge, Impulse, MK 107 1. 40e-02 1.50e-02 l.30e-02 l.40e-02 co Composition B surrogate 3.40e-03 4.70e-03 4.40e-03 4.20e-03 co Detonating train 1. 30e-02 7.90e-03 7.40e-03 9.40e-03 co Flare, IR Countermeasure M206 7.40e-03 9.50e-03 7.90e-03 8.30e-03 co Fuze, Tail Bomb FMU-139 A/B 2.lOe-02 2.40e-02 2.50e-02 2.30e-02 co Fuze, Tail Bomb FMU-54 A/B 1. 50e-02 2.40e-02 l.70e-02 l.80e-02 co Gas Generator, GGU-2/A 2.70e-02 2.BOe-02 3. OOe-02 2.80e-02 co HP:-'. surr0gate 4.40e-03 4.20e-03 7.00e-03 5. 20e-03 co "! f.P ::·1a;T': r~. Ml8Al 2.90e-02 3.20e-02 3.00e-02 3.00e-02 ' ··: 11;1• P•·j S~ _,: ; ..r1 .i ;,2 co '· .. i · n. rn 1 70e-02 2.lOe-02 2.AOe-02 2.20e-02 co - ,. : r ,. l c•. ·'\ ! !·I! ' ~ 1 10~-02 1.lOe-02 1 .20e-02 1.20e-02 co . ,• S i;rie-OJ ') ISO~· IJ 3 2.90e-03 4.70e-03

105

001069 co Tritonal surrogate with calcium stearate 3.30e-03 2.00e-03 2.70e-03 co Tritonal surrogate with water 2.80e-01 2.40e-Ol 2.BOe-01 2.70e-01 co 'INT (ACCl) 9.50e-03 1. 30e-02 9.30e-03 1. OOe-02 co TNT (ACC2) 6.70e-03 6.70e-03 co T45E7 Adapter Booster 3.lOe-02 3.lOe-02 2.60e-02 2.90e-02 co 20 mm HE! Cartridge l.20e-01 9.lOe-02 l. lOe-01 l.lOe-01 co 40 mm HEI Cartridge 2.30e-02 2.30e-02 l.80e-02 2.lOe-02 C02 Amato! surrogate 5.lOe-01 7.80e-01 8.00e-01 7.00e-01 C02 Amato! surrogate with water 2.30e-01 4.SOe-01 2.40e-01 3.lOe-01 C02 Cartridge, Impulse, ARD 446-1 4.80e-01 4.60e-01 5.00e-01 4.80e-01 C02 Cartridge, Impulse, BBU-36/B 5.00e-01 4.80e-01 5.30e-Ol 5.00e-01 C02 Cartridge, Impulse, MK 107 8.40e-Ol 8.50e-01 8.60e-01 8.50e-01 C02 Composition B surrogate l.lOe+OO l.20e+OO 1.lOe+OO 1.lOe+OO C02 Detonating train 5.70e-01 l.lOe+OO 1.lOe+OO 9.lOe-01 C02 Flare, IR Countermeasure M206 7.?0e-01 8.lOe-01 8.50e-01 8.lOe-01 C02 Fuze, Tail Bomb FMU-139 A/B l.50e+OO l.40e+OO l.50e+OO l.40e+OO C02 Fuze, Tail Bomb FMU-54 A/B 9.20e-01 9.lOe-01 9.80e-01 9.40e-Ol C02 Gas Generator, GGU-2/A 4.40e-Ol 4.30e-Ol 4.80e-Ol 4.50e-01 C02 HBX surrogate 9.70e-01 9.40e-01 1.lOe+OO l.OOe+OO C02 Mine, Claymore, MlBAl 4.90e+OO 5.lOe+OO S.OOe+OO 5.00e+OO C02 Signal, Illumination, Red Star AN-M43A2 1.00e+OO 1.lOe+OO 1.lOe+OO 1.lOe+OO C02 Signal, Illumination, Red Star Ml58 5.00e-01 5.30e-01 5.lOe-01 5.lOe-01 C02 Tritonal surrogate 5. OOe-01 2.20e-01 l.20e+OO 6.40e-Ol C02 Tritonal surrogate with calcium stearate 1.30e+OO 1.30e+OO 1. 30e+OO C02 Tritonal surrogate with water 2.SOe-01 3.30e-Ol 2.60e-Ol 2.80e-01 C02 'INT (ACCl) 1.40e+OO l.50e+OO 1.50e+OO 1.50e+OO C02 'INT (ACC21 l.40e+OO 1.40e+OO C02 TNT (Sandia) 1.30e+OO l.30e+OO C02 T45E7 Adapter Booster 5.lOe+OO 4.60e+OO 4.70e+OO 4.80e+OO C02 20 nun HEI Cartridge 2.30e+OO 2.20e+OO 1.90e+OO 2.lOe+OO C02 40 mm HEI Cartridge 9.lOe-01 8.70e-01 8.80e-Ol 8.90e-Ol Diethyl phthalate Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.40e-05 Diethyl phthalate Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.80e-06 Diethyl phthalate Cartridge, Impulse, BBU-36/B 4.40e-05 6.70e-04 4.90e-04 4.00e-04 7.80e-04 Diethyl phthalate cartridge, Impulse, MK 107 3.00e-04 O.OOe+OO O.OOe+OO 3.00e-04 4.40e-04 Diethyl phthalate Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Flare, IR Countermeasure M206 O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO Diethyl phthalate Fuze, Tail Bomb FMU-139 A/B 1.40e-03 l.70e-03 l.50e-03 1. 50e-03 l.50e-03 Diethvl ohthalate Fuze Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO

106

001070 Diethyl phthalate Gas Generator, GGU-2/A 2.30e-04 O.OOe+OO l.60e-03 8.90e-04 O.OOe+OO Diethyl phthalate HEX surrogate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Mine, Claymore, MlBAl O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Signal, Illumination, Red star AN-M43A2 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Signal, Illumination, Red Star Ml58 0.00e+OO 7.70e-05 O.OOe+OO 7.70e-05 7.70e-05 Diethyl phthalate Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Tritonal surrogate with calcium stearate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO 2.40e-06 Diethyl phthalate TNT (ACCll O.OOe+OO O.OOe+OO O.OOe-+00 O.OOe+OO O.OOe+OO Diethyl phthalate TNT (ACC2) 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Diethyl phthalate T45E7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate 20 nun HE! Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Diethyl phthalate 40 mm HE! Cartridge 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Ethane Amato! surrogate O.OOe+OO 2.20e-06 6.00e-06 4.lOe-06 5.20e-06 Ethane Amato! surrogate with water B.70e-04 l.SOe-03 l.OOe-03 l.lOe-03 l.lOe-03 Ethane Cartridge, Impulse, ARD 446-1 3.00e-05 l.20e-05 2.90e-05 2.40e-05 3.90e-05 Ethane Cartridge, Impulse, BBU-36/B 1. 40e-06 5.60e-07 B.40e-06 3.40e-06 l.30e-05 Ethane Cartridge, Impulse, MK 107 5.30e-07 2.60e-06 1.60e-06 1.60e-06 9.50e-06 Ethane Composition B surrogate l.90e-06 O.OOe+OO 7.30e-07 l.30e-06 4.70e-06 Ethane Detonating train 1. 70e-06 l.BOe-06 9.60e-06 4.40e-06 1. 40e-05 Ethane Flare, IR Countermeasure M206 1.00e-06 O.OOe+OO 1.00e-06 1. OOe-06 7.60e-06 Ethane Fuze, Tail Bomb FMU-139 A/B O.OOe+OO 9.20e-06 O.OOe+OO 9.BOe-06 1.90e-05 Ethane Fuze, Tail Bomb FMU-54 A/B 9.BOe-06 l.20e-05 O.OOe+OO 1.lOe-05 1. 90e-05 Ethane Gas Generator, GGU-2/A 2.SOe-05 3.70e-05 3.00e-05 3.00e-05 3.90e-05 Ethane HBX surrogate O.OOe+OO l.60e-06 l.50e-06 1.60e-06 4.90e-06 Ethane Mine, Claymore, M18Al B.BOe-06 l.SOe-06 5.60e-06 5.30e-06 7.20e-06 Ethane Signal, Illumination, Red Star AN-M43A2 9.00e-06 O.OOe+OO 9. OOe-06 9.00e-06 1. 30e-05 Ethane Signal, Illumination, Red Star M158 1. 50e-05 2.40e-05 O.OOe+OO 2.00e-05 2.60e-05 Ethane Tritonal surrogate 0.00e+OO O.OOe+OO 3.60e-07 3.60e-07 2.60e-06 Ethane Tritonal surrogate with calcium stearate 7.40e-07 O.OOe+OO 7.40e-07 4.4.{)e-06 Ethane Tritonal surrogate with water 5.00e-05 l.lOe-04 2.lOe-04 l.20e-04 1. 30e-04 Ethane TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.70e-06 Ethane TNT (ACC2) 7.40e-07 7.40e-07 4.lOe-06 Ethane T45E7 Adapter Booster 2.BOe-05 2.40e-05 2.40e-05 2.50e-05 3.90e-05 Ethane 20 mm HEI Cartridge 1.lOe-04 7.60e-05 9.90e-05 9.40e-05 1. 40e-04 Ethane 40 mm HE! Cartridge 2.90e-05 3.60e-05 2.50e-05 3.00e-05 4.60e-05 Ethyl chloride Amato! surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Ethyl chloride Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Cartridge, Impulse, BBU-36/B O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethvl chloride Cartridqe Irnoulse. MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

107

001071 Ethyl chloride Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Detonating train O.OOe+OO 6.90e-07 6.90e-07 6.90e-07 6.90e-07 Ethyl chloride Flare, IR Countermeasure M206 3.90e-06 3.20e-06 2.40e-06 3.lOe-06 3.lOe-06 Ethyl chloride Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Ethyl chloride Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO 0. OOe+OO O.OOe+OO Ethyl chloride Gas Generator, GGU-2/A 2.70e-06 4.lOe-06 7.lOe-06 4.70e-06 4.70e-06 Ethyl chloride HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Mine, Claymore, Ml8Al O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Signal, Illumination, Red Star Ml58 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+QO O.OOe+OO Ethyl chloride Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride TNT (ACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride T45E7 Adapter Booster O.OOe+OO o.ooe+oo O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride 20 rran HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethyl chloride 40 mm HE! Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Ethylbenzene Amato! surrogate 7.50e-07 1.lOe-06 l.90e-06 1. 20e-06 4.00e-06 Ethylbenzene Amato! surrogate with water 1. 20e-05 2.20e-05 l.50e-05 1. 60e-05 2.lOe-05 Ethylbenzene Cartridge, Impulse, ARD 446-1 l.OOe-06 2.lOe-06 2.70e-06 l.90e-06 8.lOe-06 Ethylbenzene Cartridge, Impulse, BBU-36/B 2.70e-06 2.SOe-06 l.90e-06 2.40e-06 l.OOe-05 Ethylbenzene Cartr:idge, Impulse, MK 107 7.90e-07 l. lOe-06 1.00e-06 9.70e-07 2.90e-06 Ethylbenzene Composition B surrogate 1. lOe-06 1.90e-06 2.90e-06 2.00e-06 5.30e-06 Ethylbenzene Detonating train 2.90e-07 6.00e-07 9.00e-07 6.00e-07 9.30e-06 Ethylbenzene Flare, IR Countermeasure M206 2.70e-06 l.?Oe-06 2.?0e-06 2.40e-06 4.lOe-06 Ethylbenzene Fuze, Tail Bomb FMU-139 A/B 3.40e-06 3.40e-06 2.90e-06 3.20e-06 4.50e-06 Ethyl benzene Fuze, Tail Bomb FMU-54 A!B 1. 50e-06 3.30e-06 2.40e-06 2.40e-06 6.00e-06 Ethyl benzene Gas Generator, GGU-2/A 5.90e-07 l.80e-06 l.20e-06 1.20e-06 9 .-lOe-06 Ethylbenzene HBX surrogate 1. 50e-06 l.60e-06 2.20e-06 1. 80e-06 8.80e-06 Ethylbenzene Mine, Claymore, M18Al 3.lOe-05 4.lOe-05 4.20e-05 3.80e-05 3.90e-05 Ethylbenzene Signal, Illumination, Red Star AN-M43A2 6.90e-07 3.SOe-07 3.50e-07 4.60e-07 l.90e-06 Ethylbenzene Signal, Illumination, Red Star Ml58 7.00e-07 7.00e-07 O.OOe+OO 7.00e-07 2.20e-06 Ethylbenzene Tritonal surrogate l.50e-06 2.60e-06 3.30e-06 2.50e-06 l.lOe-05 Ethylbenzene Tritonal surrogate with calcium stearate 7.40e-07 2.60e-06 1.60e-06 9.90e-06 Ethylbenzene Tritonal surrogate with water 8.20e-06 3.30e-06 7.50e-06 6.30e-06 l.50e-05 Ethylbenzene TNT (ACCl) 4.60e-07 4.BOe-07 O.OOe+OO 4.?0e-07 2.?0e-06 Ethylbenzene TNT (ACC2) O.OOe+OO O.OOe+OO 3.30e-06 Ethylbenzene T45E7 Adapter Booster l.OOe-05 7.70e-06 9.80e-06 9.20e-06 l.OOe-05 Ethylbenzene 20 mm HE! Cartridge 2.80e-06 5.00e-06 6.lOe-06 4.60e-06 l.OOe-05 Ethvlbenzene 40 mm HEI Cartridae 2.50e-06 O.OOe+OO O.OOe+OO 2.50e-06 9.60e-06

108

001072 Ethylene Amato! surrogate 4.40e-05 2.00e-05 2.90e-05 3.lOe-05 3.20e-05 Ethylene Amato! surrogate with water 7.30e-04 l.30e-03 8.80e-04 9.80e-04 9.80e-04 Ethylene Cartridge, Impulse, ARD 446-1 3.90e-04 3.lOe-04 3.lOe-04 3.30e-04 4.90e-04 Ethylene Cartridge, Impulse, BBU-36/B 2.60e-04 2.SOe-04 3.00e-04 2.?0e-04 5.30e-04 Ethylene Cartridge, Impulse, MK 107 2. OOe-04 l.80e-04 l.60e-04 1. BOe-04 2.60e-04 Ethylene Composition B surrogate l.20e-05 l.20e-05 1.70e-05 l.40e-05 l.50e-05 Ethylene Detonating train 4.20e-04 4.lOe-04 3.SOe-04 3.90e-04 6.00e-04 Ethylene Flare, IR Countermeasure M206 l.30e-04 7.70e-05 1.40e-04 l.20e-04 1.20e-04 Ethylene Fuze, Tail Bomb FMU-139 A/B 2.40e-04 4.00e-04 3.BOe-04 3.40e-04 3.40e-04 Ethylene Fuze, Tail Bomb FMU-54 A/B l.60e-04 2.60e-04 1.?0e-04 l.90e-04 2.60e-04 Ethylene Gas Generator, GGU-2/A 6.00e-04 5.80e-04 6.70e-04 6.lOe-04 6.20e-04 Ethylene HBX surrogate 2.BOe-05 2.50e-05 4.30e-05 3.20e-05 3.30e-05 Ethylene Mine, Claymore, M-18Al l.BOe-04 2.30e-04 3.00e-04 2.40e-04 2.40e-04 Ethylene Signal, Illumination, Red Star AN-M43A2 2.lOe-04 2.20e-04 2.20e-04 2.20e-04 2.20e-04 Ethylene Signal, Illumination, Red Star M158 2.30e-04 3.50e-04 1. OOe-04 2.30e-04 2.30e-04 Ethylene Tritonal surrogate 2.70e-05 l.30e-05 2.SOe-05 2.20e-05 2.30e-OS Ethylene Tritonal surrogate with calcium stearate 3.20e-05 l.BOe-05 2.50e-05 2.60e-05 Ethylene Tritonal surrogate with water 1.20e-03 9.00e-04 l.30e-03 l.lOe-03 l.lOe-03 Ethylene TNT (ACCl) 3.00e-05 2.90e-05 8.60e-06 2.20e-05 2.30e-05 Ethylene TNT IACC2) 1. 60e-05 l.60e-05 l.60e-05 Ethylene T45E7 Adapter Booster 6.50e-04 5.60e-04 4.90e-04 5.?0e-04 5.70e-04 Ethylene 20 mm HEI Cartridge 3.30e-04 2.40e-04 3.00e-04 2.90e-04 4.00e-04 Ethylene 40 mm HEI Cartridge 8.90e-05 9.00e-05 6.50e-05 8.lOe-05 l.lOe-04 Lead Amato! sur_rogate O.OOe+OO 3.20e-05 9.?0e-05 3.30e-05 3.30e-05 Lead Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Lead Cartridge, Impulse, ARD 446-1 3.60e-04 2.lOe-04 3.60e-04 3.lOe-04 3.lOe-04 Lead Cartridge, Impulse, BBU-36/B 1. 20e-05 l.OOe-04 8.80e-05 6.80e-05 6.BOe-05 Lead Cartridge, Impulse, MK 107 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Lead Detonating train 2.BOe-05 2.20e-04 2.90e-04 l.BOe-04 l.BOe-04 Lead Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Lead Fuze, Tail Bomb FMU-139 A/B 2.BOe-03 2.40e-03 2.SOe-03 2.60e-03 2.60e-03 Lead Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO Q.OOe+OO O.OOe+OO O.OOe+OO Lead Gas Generator, GGU-2/A 4.lOe-04 4.lOe-04 2.BOe-04 3.70e-04 3.70e-04 Lead HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead Mine, Claymore, M18Al O.OOe+OO O.OOe+OO O.OOe+OO Lead Signal, Illumination, Red Star AN-M43A2 2.lOe-04 O.OOe+OO 2.BOe-05 7.00e-05 7.00e-05 Lead Signal, Illumination, Red Star Ml58 7.00e-05 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead Tritonal surrogate l.90e-03 7.20e-04 6.70e-04 l.lOe-03 l.lOe-03 Lead Tritonal surrogate with calcium stearate 9.lOe-04 9.30e-04 9.20e-04 9.20e-04 Lead Tritonal surroqate with water lo. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

109

001073 Lead 'INT (ACCl I O.OOe+OO O.OOe+OO O.OOe+OO Lead 'INT (ACC2) 9.00e-06 9.00e-06 9.00e-06 Lead TNT (Sandia) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Lead T45E7 Adapter Booster 1.BOe-04 1.BOe-04 1. BOe-04 Lead 20 mm HEI Cartridge 7.00e-04 7.00e-04 8.00e-06 Lead 40 mm HEI Cartridge 3.70e-04 3.70e-04 3.70e-04 Methyl chloride Amato! surrogate l.lOe-06 7.50e-07 3.70e-07 7.50e-07 7.50e-07 Methyl chloride Amato! surrogate with water 2.20e-06 l.80e-06 2.60e-06 2.20e-06 2.20e-06 Methyl chloride Cartridge, Impulse, ARD 446-1 l.90e-06 9.20e-07 9.00e-07 l.20e-06 2.00e-06 Methyl chloride Cartridge, Impulse, BBU-36/B 4.90e-07 l.50e-06 l.OOe-06 l.OOe-06 3.00e-06 Methyl chloride Cartridge, Impulse, MK 107 1.90e-06 4.BOe-07 4.70e-07 9.60e-07 l.60e-06 Methyl chloride Composition B surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloride Detonating train l.lOe-06 5. 30e-07 5.30e-07 7.00e-07 1.90e-06 Methyl chloride Flare, IR Countermeasure M206 1. 20e-06 6.00e-07 1. 20e-06 1. OOe-06 l.60e-06 Methyl chloride Fuze, Tail Bomb FMU-139 A/B 4.50e-06 6.lOe-06 3.50e-06 4.70e-06 5.30e-06 Methyl chloride Fuze, Tail Bomb FMU-54 A/B l.lOe-06 2.20e-06 6.20e-06 3.lOe-06 4.90e-06 Methyl chloride Gas Generator, GGU-2/A 5.30e-06 7.60e-06 3.60e-05 l.60e-05 l.70e-OS Methyl chloride HBX surrogate 3.70e-07 4.lOe-07 1.lOe-06 6.JOe-07 1. OOe-06 Methyl chloride Mine, Claymore, Ml8Al 4.40e-06 4.40e-06 4.40e-06 Methyl chloride Signal, Illumination, Red Star AN-M43A2 1.90e-06 1.20e-06 1.BOe-06 l.70e-06 2.lOe-06 Methyl chloride Signal, Illumination, Red Star MlSB O.OOe+OO 1.30e-06 1.30e-06 1.30e-06 1. lOe-06 Methyl chloride Tritonal surrogate 7.40e-07 3.70e-07 O.OOe+OO S.60e-07 5.60e-07 Methyl chloride Tritonal surrogate with calcium stearate 3.70e-07 3.60e-07 3.70e-07 3.70e-07 Methyl chloride Tritonal surrogate with water 3.70e-06 3.70e-06 4.lOe-06 3.BOe-06 3.BOe-06 Methyl chloride 'INT IACCl I O.OOe+OO O.OOe+OO 1.70e-06 Methyl chloride 'INT (ACC2) O.OOe+OO O.OOe+OO 6.70e-07 Methyl chloride T45E7 Adapter Booster 2.20e-06 2.20e-06 3.20e-06 Methyl chloride 20 mm HE! Cartridge l.30e-06 1.30e-06 3.50e-06 Methyl chloride 40 nun HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloroform Amato! surrogate 3.70e-07 3.70e-07 O.OOe+OO 3.70e-07 l.70e-06 Methyl chloroform Amato! surrogate with water 3.70e-07 O.OOe+OO 3.70e-07 3.70e-07 l.70e-06 Methyl chloroform Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO l.20e-06 l.20e-06 1.BOe-06 Methyl chloroform Cartridge, Impulse, BBU-36/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.60e-06 Methyl chloroform Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1.BOe-06 Methyl chloroform Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methyl chloroform Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.20e-06 Methyl chloroform Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.60e-06 Methyl chloroform Fuze, Tail Bomb FMU-139 A/B 1. 20e-05 l.BOe-05 l.BOe-05 l.60e-05 l.90e-05 Methyl chloroform Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.90e-06 Methyl chloroform Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 2.90e-06 Methvl chloroform HBX surroaate 3.70e-07 4.lOe-07 3.70e-07 3.BOe-07 l.90e-06

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001074 Methyl chloroform Mine, Claymore, Ml8Al 2.30e-06 2.30e-06 4.60e-06 Methyl chloroform Signal, Illumination, Red Star AN-M43A2 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO 1.60e-06 Methyl chloroform Signal, Illumination, Red Star M158 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO l.70e-06 Methyl chloroform Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1.60e-06 Methyl chloroform Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 1.BOe-06 Methyl chloroform Tritonal surrogate with water 3.70e-07 O.OOe+OO 3.70e-07 3.70e-07 1.70e-06 Methyl chloroform TNT (ACCl) O.OOe+OO O.OOe+OO 6.60e-06 Methyl chloroform TNT (ACC2) O.OOe+OO O.OOe+OO 1. BOe-06 Methyl chloroform T45E7 Adapter Booster O.OOe+OO O.OOe+OO 5.60e-06 Methyl chloroform 20 nun HEI Cartridge 3.30e-06 3.30e-06 1.40e-05 Methyl chloroform 40 mm HEI Cartridge O.OOe+OO O.OOe+OO 2.lOe-05 Methylcyclohexane Amato! surrogate 7.SOe-07 2.20e-06 4.50e-06 2.SOe-06 4.40e-06 Methylcyclohexane Amato! surrogate with water 4.50e-06 l.20e-05 7.40e-06 8.00e-06 l.lOe-05 Methylcyclohexane Cartridge, Impulse, ARD 446-1 0. OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Cartridge, Impulse, BBU-36/B 5.40e-07 2.80e-07 O.OOe+OO 4.lOe-07 l.60e-06 Methylcyclohexane Cartridge, Impulse, MK 107 7.90e-07 O.OOe+OO 2.60e-07 5.20e-07 9.60e-07 Methylcyclohexane Composition B surrogate 2.20e-06 3.00e-06 l.80e-06 2.30e-06 4.lOe-06 Methylcyclohexane Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO 3.40e-07 3.40e-07 6.BOe-07 Methylcyclohexane Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane HBX surrogate 4.40e-06 7.00e-06 7.lOe-06 6.lOe-06 l.OOe-05 Methylcyclohexane Mine, Claymore, Ml8Al 5.40e-06 5.90e-06 4.70e-06 5.30e-06 6.30e-06 Methylcyclohexane Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Methylcyclohexane Signal, Illumination, Red Star Ml58 3.SOe-07 O.OOe+OO O.OOe+OO 3.SOe-07 7.00e-07 Methylcyclohexane Tritonal surrogate 4.80e-06 5.90e-06 1. OOe-05 7.00e-06 l.40e-05 Methylcyclohexane Tritonal surrogate with calcium stearate O.OOe+OO 4.40e-06 4.40e-07 6.20e-06 Methylcyclohexane Tritonal surrogate with water 4.90e-06 5.lOe-06 9.40e-06 6.50e-06 l.lOe-05 Methylcyclohexane TNT (ACCl) 9.20e-06 9.60e-07 O.OOe+OO 5.lOe-06 4.30e-06 Methylcyclohexane TNT (ACC2) O.OOe+OO O.OOe+OO 3.70e-07 Methylcyclohexane T45E7 Adapter Booster 2.40e-06 2.90e-06 3.50e-06 2.90e-06 4.lOe-06 Methylcyclohexane 20 mm HE! Cartridge l.40e-06 2.90e-06 4.lOe-06 2.BOe-06 5.BOe-06 Methylcyclohexane 40 mm HEI Cartridge 2.50e-06 O.OOe+OO O.OOe+OO 2.50e-06 l.40e-05 Methylcyclopentane Amato! surrogate O.OOe+OO O.OOe+OO 3.70e-07 l.90e-07 5.00e-07 Methylcyclopentane Amato! surrogate with water 4.BOe-06 l.20e-OS 3.00e-06 6.60e-06 8.90e-06 Methylcyclopentane Cartridge, Impulse, ARD 446-1 1. OOe-06 2.60e-07 5.00e-07 6.00e-07 l.70e-06 Methylcyclopentane Cartridge, Impulse, BBU-36/B O.OOe+OO 1.lOe-06 O.OOe+OO l.lOe-06 l.90e-06 Methylcyclopentane Cartridge, Impulse, MK 107 O.OOe+OQ 5.30e-07 O.OOe+OO 5.30e-07 7.70e-07 Methylcyclopentane Composition B surrogate O.OOe+OO O.OOe+OO 3.60e-07 3.60e-07 4.90e-07 Methylcvclonentane Detonatina train 2.90e-07 O.OOe+OO O.OOe+OO 2.90e-07 1.70e-06

111

001075 Methylcyclopentane Flare, IR Countermeasure M206 0.00e+OO 3.40e-07 O.OOe+OO 3.40e-07 4.50e-07 Methylcyclopentane Fuze, Tail Bomb FMU-139 A/B 4.90e-07 0.00e+OO O.OOe+OO 4.90e-07 4.90e-07 Methylcyclopentane Fuze, Tail Bomb FMU-54 A/B O.OOe+OO 3.00e-07 O.OOe+OO 3.00e-07 B.OOe-07 Methylcyclopentane Gas Generator, GGU-2/A 2.40e-06 5.90e-07 O.OOe+OO l.50e-06 l.BOe-06 Methylcyclopentane HBX surrogate 3.70e-07 8.20e-07 7.40e-07 6.40e-07 2.40e-06 Methylcyclopentane Mine, Claymore, MlBAl 1. 40e-05 l.50e-05 l.BOe-05 l.60e-05 l.70e-05 Methylcyclopentane Signal, Illumination, Red Star AN-M43A2 O.OOe+OO 3.50e-07 O.OOe+OO 3.50e-07 7.00e-07 Methylcyclopentane Signal, Illumination, Red Star M158 l.lOe-06 O.OOe+OO O.OOe+OO l.lOe-06 8.20e-07 Methylcyclopentane Tritonal surrogate 7.40e-07 3.70e-07 O.OOe+OO 5.60e-07 3.50e-06 Methylcyclopentane Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 2.90e-06 Methylcyclopentane Tritonal surrogate with water O.OOe+OO 0.00e+OO 7.50e-07 7.50e-07 4.70e-06 Methylcyclopentane TNT (ACCl) 9.20e-07 4.BOe-07 O.OOe+OO 7.00e-07 l.60e-06 Methylcyclopentane TNT (ACC2) 3.70e-07 3.70e-07 7.40e-07 Methylcyclopentane T45E7 Adapter Booster l.20e-06 2.90e-06 4.60e-06 2.90e-06 4.70e-06 Methylcyclopentane 20 mm HEI Cartridge 7.00e-07 2.90e-06 4.BOe-06 2.BOe-06 7.70e-06 Methylcyclopentane 40 mm HE! Cartridge 9.lOe-06 O.OOe+OO O.OOe+OO 9.lOe-06 l.60e-05 Methylenechloride Amato! surrogate l.SOe-04 2.00e-04 l.lOe-04 l.50e-04 2.00e-04 Methylenechloride Amato! surrogate with water 2.lOe-04 2.00e-04 2.20e-04 2.lOe-04 2.60e-04 Methylenechloride Cartridge, Impulse, ARD 446-1 l.30e-05 3.20e-05 l.lOe-04 5.00e-05 l.90e-04 Methylenechloride Cartridge, Impulse, BBU-36/B B.20e-06 3.00e-04 2.lOe-04 l.70e-04 l. lOe-03 Methylenechloride Cartridge, Impulse, MK 107 6.30e-04 3.lOe-05 2.00e-05 2.30e-04 9.30e-04 Methylenechloride Composition B surrogate O.OOe+OO 3.70e-07 2.BOe-04 1. 40e-04 l.90e-06 Methylenechloride Detonating train O.OOe+OO 5.00e-05 3.50e-05 4.20e-05 5.60e-04 Methylenechloride Flare, IR Countermeasure M206 4.BOe-04 3.BOe-04 3.80e-04 4.lOe-04 l.90e-03 Methylenechloride Fuze, Tail Bomb FMU-i39 A/B l.20e-04 l.60e-04 5.50e-05 l.lOe-04 B.60e-04 Methylenechloride Fuze, Tail Bomb FMU-54 A/B O.OOe+OO 7.lOe-04 7.BOe-04 7.40e-04 2.40e-03 Methylenechloride Gas Generator, GGU-2/A 2.BOe-04 7.00e-05 2.30e-03 8.70e-04 2.90e-03 Methylenechloride HBX surrogate 0. OOe+OO 0.00e+OO 2.70e-04 2.70e-04 2.BOe-04 Methylenechloride Mine, Claymore, MlBAl l.lOe-04 l.lOe-04 l.lOe-04 Methylenechloride Signal, Illumination, Red Star AN-M43A2 O.OOe+OO 8.lOe-06 O.OOe+OO 8.lOe-06 3.JOe-04 Methylenechloride Signal, Illumination, Red Star Ml58 l.OOe-04 9.60e-05 1. OOe-04 l.OOe-04 3.20e-04 Methylenechloride Tritonal surrogate 3.40e-06 4.BOe-05 2.50e-06 l.BOe-05 l.80e-05 Methylenechloride Tritonal surrogate with calcium stearate 6.30e-06 3.lOe-04 1. 60e-04 l.60e-04 Methylenechloride Tritonal surrogate with water O.OOe+OO B.BOe-06 1. lOe-06 5.00e-06 6.70e-06 Methylenechloride TNT IACCI I l.80e-04 l.80e-04 2.40e-04 Methylenechloride TIJT (ACC2 l O.OOe+OO O.OOe+OO 2.70e-04 Methylenechloride r4'::E~ ;.... -hrter e ..-.r..Jster 5.00e-04 5.00e-04 5.90e-04 Methylenechloride '" ~"'." l'f ! ":"' 1r • r i-°i"lP 4.SOe-04 4.50e-04 9.00e-04 .. 11·. Methylenechloride I ! ' f ~ ! 1 o P 70e-04 8.70e-04 l.40e-03 NO ' .. . ,. ' : 201" 04 1 4C'e-02 l.70e-02 l.80e-02 7 NO ,. . •'. .. :· . . ' . . ~ , ( ""' 0 3 SOr> 0 3 A.OOe-03 7.?0e-03

112

001076 NO Cartridge, Impulse, ARD 446-1 6.SOe-03 6.20e-03 6.50e-03 6.40e 03 NO Cartridge, Impulse, BBU-36/B 5.30e-03 3.50e-03 3.30e-03 4.00e 03 NO Cartridge, Impulse, MK 107 1.70e-02 l.40e-02 l.30e-02 1. 50e 02 NO Composition B surrogate 9.20e-03 8.90e-03 9.70e-03 9.30e-03 NO Detonating train 6.80e-03 3.60e-03 4.30e-03 4.90e-03 NO Flare, IR Countermeasure M206 4.90e-03 6.00e-03 5.lOe-03 5.30e-03 NO Fuze, Tail Bomb FMU-139 A/B 9.BOe-03 l.OOe-02 9.BOe-03 9.90e-03 NO Fuze, Tail Bomb FMU-54 A/B 7.30e-03 6.90e-03 6.90e-03 7.00e-03 NO Gas Generator, GGU-2/A 1. 50e-03 l.30e-03 l.90e-03 1.60e-03 NO HBX surrogate 9 .30e-03 9.80e-03 l.OOe-02 9.90e-03 NO Signal, Illumination, Red Star AN-M43A2 1. 20e-02 l.SOe-02 l. lOe-02 l.30e-02 NO Signal, Illumination, Red Star M158 2.60e-03 2.70e-03 2.70e-03 2.60e-03 NO Tritonal surrogate 1. 30e-03 l.70e-02 5.90e-03 8.20e-03 NO Tritonal surrogate with calcium stearate 6.SOe-03 6.70e-03 6. 60e-03 NO Tritonal surrogate with water 4.30e-03 3.90e-03 3.BOe-03 4.00e-03 NO TNT IACC2) 9 .20e-03 . 9.20e-03 NO TNT (Sandia) 9.80e-03 l.OOe-02 9.20e-03 9.70e-03 N02 Amatol surrogate 3.40e-04 l.80e-04 4.20e-04 l.20e-04 N02 Amato! surrogate with water 2.00e-04 2.lOe-04 2.90e-04 2.40e-04 N02 Cartridge, Impulse, ARD 446-1 1. 90e-03 1. 60e-03 l.70e-03 1. 70e-03 N02 Cartridge, Impulse, BBU-36/B l.SOe-03 1. 70e-03 l.30e-03 l.SOe-03 N02 Cartridge, Impulse, MK 107 7.70e-04 S.40e-04 5.30e-04 6.lOe-04 N02 Composition B surrogate l.lOe-04 l.70e-04 3.00e-04 l.90e-04 N02 Detonating train 8.lOe-03 3.30e-03 1. 90e-03 4.40e-03 N02 Flare, IR Countermeasure M206 2.60e-03 3.lOe-03 2.BOe-03 2.80e-03 N02 Fuze, Tail Bomb FMU-139 A/B 1. 70e-02 l.70e-02 l.70e-02 l.70e-02 N02 Fuze, Tail Bomb FMU-54 A/B 2.40e-03 2.SOe-03 2.60e-03 2.SOe-03 N02 Gas Generator, GGU-2/A 2.60e-03 2.40e-03 2.30e-03 2.40e-03 N02 HBX surrogate 5.90e-05 4.00e-05 3.40e-05 4.40e-05 N02 Signal, Illumination, Red Star AN-M43A2 9.80e-04 1.30e-03 1. OOe-03 1.lOe-03 N02 Signal, Illumination, Red Star M158 1. 40e-03 1. 60e-03 1. 60e-03 l.SOe-03 N02 Tritonal surrogate 2.50e-04 l.90e-04 l.80e-05 l.SOe-04 N02 Tritonal surrogate with calcium stearate 3.00e-05 5.90e-05 4.50e-05 N02 Tritonal surrogate with water 2.60e-04 1. SOe-04 3.90e-04 2.70e-04 N02 TNT IACC2) 6.60e-05 6.60e-05 N02 TNT (Sandia) 3.90e-04 9.60e-04 9.20e-04 7.60e-04 OCDD Signal, Illumination, Red Star AN-M43A2 8.30e-10 l.60e-09 2.90e-09 l.80e-09 l.80e-09 Propane Amato! surrogate l. lOe-06 7.SOe-07 1.lOe-06 l.OOe-06 l.40e-06 Propane Amato! surrogate with water l.40e-04 2.40e-04 l.70e-04 1. 90e-04 l.90e-04 Propane Cartridge, Impulse, ARD 446-1 6.20e-06 5.40e-06 5.50e-06 5.70e-06 l.OOe-05 Pronane Cartridae, Imnulse. BBU-36/B 2.70e-06 3.90e-06 l.90e-06 3.SOe-06 8.50e-06

113

001077 Propane Cartridge, Impulse, MK 107 O.OOe+OO 1. 30e-06 1. 60e-06 1. 40e-06 5.20e-06 Propane Composition B surrogate 7.40e-07 O.OOe+OO 7.30e-07 7.40e-07 l.40e-06 Propane Detonating train 4.70e-06 4.50e-06 4.80e-06 4.70e-06 l.lOe-05 Propane Flare, IR Countermeasure M206 O.OOe+OO 6.80e-07 2.00e-06 l.40e-06 3.90e-06 Propane Fuze, Tail Bomb FMU-139 A/B 4.40e-06 3.40e-06 3.90e-06 3.90e-06 7.90e-06 Propane Fuze, Tail Bomb FMU-54 A/B 8.90e-07 l.80e-06 l.80e-06 1. 50e-06 6.00e-06 Propane Gas Generator, GGU-2/A 7.70e-06 7.lOe-06 8.5oe-06 7.70e-06 1. lOe-05 Propane HBX surrogate l.50e-06 4.lOe-07 7.40e-07 8.70e-07 2.20e-06 Propane Mine, Claymore, M18Al 3.40e-06 4.40e-06 2.80e-06 3.60e-06 9.80e-06 Propane Signal, Illumination, Red Star AN-M43A2 l.70e-06 3.50e-06 2.40e-06 2.60e-06 4.60e-06 Propane Signal, Illumination, Red Star M158 6.00e-06 5.30e-06 3.lOe-06 4.80e-06 8.00e-06 Propane Tritonal surrogate O.OOe+OO 7.40e-07 7.30e-07 7.30e-07 1.20e-06 Propane Tritonal surrogate with calcium stearate O.OOe+OO 3.60e-07 3.60e-07 2.20e-06 Propane Tritonal surrogate with water 5.20e-05 5.00e-05 6.30e-05 5.50e-05 5.70e-05 Propane TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO 9.50e-07 Propane TNT (ACC2) 3.70e-07 3.70e-07 1.50e-06 Propane T45E7 Adapter Booster 1.50e-05 B.20e-06 8.60e-06 l.lOe-05 2.lOe-05 Propane 20 mm HE! Cartridge 9.lOe-06 6.50e-06 2.40e-05 1.30e-05 2.30e-05 Propane 40 mm HEI Cartridge 1.70e-06 5.00e-06 4.90e-06 3.80e-06 l.50e-05 Propene lAmatol surrogate 6.70e-06 3.40e-06 6.30e-06 5.50e-06 5.BOe-06 Propene Amato! surrogate with water 2.60e-04 4.90e-04 3.40e-04 3.60e-04 3.60e-04 Propene Cartridge, Impulse, ARD 446-1 6.70e-05 5.50e-05 5.70e-05 6.00e-05 B.70e-05 Propene Cartrii:Jge, Impulse, BBU-36/B 4.30e-05 4.60e-05 5.80e-05 4.90e-05 9.70e-05 Propene Cartridge, Impulse, MK 107 2.80e-05 2.60e-05 2.40e-05 2.60e-05 3.80e-05 Propene Composition B surrogate 3.70e-06 1.lOe-06 4.40e-06 3.lOe-06 4.lOe-06 Propene Detonating train 7.50e-05 7.lOe-05 7.lOe-05 7.30e-05 l.lOe-04 Propene Flare, IR Countermeasure M206 2.20e-05 2.00e-05 2.60e-05 2.20e-05 2.30e-05 Propene Fuze, Tail Bomb FMU-139 A/B 5.90e-05 6.30e-05 5.50e-05 5.90e-05 5.90e-05 Propene Fuze, Tail Bomb FMU-54 A/B 3.80e-05 5.20e-05 3.90e-05 4.30e-05 4.3De-05 Propene Gas Generator, GGU-2/A 6.90e-05 6.80e-05 7.80e-05 7.20e-05 7.30e-05 Propene HBX surrogate 8.40e-06 7.80e-06 1. 20e-05 9.40e-06 9.90e-06 Propene Mine, Claymore, MlBAl 2.lOe-05 2.70e-05 2.60e-05 2.40e-05 2.50e-05 Propene Signal, Illumination, Red Star AN-M43A2 3.20e-05 3.90e-05 3.40e-05 3.50e-05 3.50e-05 Propene Signal, Illumination, Red Star M158 6.00e-05 5.80e-05 5.00e-05 5.60e-05 5.60e-05 Propene Tritonal surrogate 2.60e-06 1. 50e-06 5.40e-06 3.20e-06 3.60e-06 Propene Tritonal surrogate with calcium stearate 8.!0e-06 4.00e-06 6.lOe-06 6.60e-06 Propene Tritonal surrogate with water l.70e-04 l.20e-04 1. 80e-04 l.60e-04 l.60e-04 Propene TNT IACCl) 7.80e-06 8.lOe-06 5.80e-06 7.20e-06 7.70e-06 Propene TNT IACC2) 4.lOe-06 4.lOe-06 4.lOe-06 Propene T45E7 Adapter Booster 2.00e-04 l.60e-04 l.30e-04 l.60e-04 l.60e-04 Prooene 20 mm HE! Cartridne 6.20e-05 4.00e-05 5.00e-05 5.lOe-05 7.20e-05

114

001078 Propene 40 mm HEI Cartridge 1. 80e-05 l.70e-05 l.20e-05 l.60e-05 2.40e-05 PETN Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO PETN Cartridge, Impulse, BBU-36/B O.OOe+OO 9.30e-04 2.30e-04 5.SOe-04 5.SOe-04 PETN Cartridge, Impulse, MK 107 2.30e-05 l.lOe-04 1. SOe-05 5.lOe-05 7.60e-05 PETN Detonating train 5.60e-04 7.30e-04 4.lOe-04 5.60e-04 8.80e-04 PETN Flare, IR Countermeasure M206 2.40e-06 l.90e-06 4.00e-07 l.60e-06 2.lOe-06 PETN Fuze, Tail Bomb FMU-139 A/B 2.60e-05 l.50e-05 8.90e-06 l.70e-05 l.90e-05 PETN Fuze, Tail Bomb FMU-54 A/B l.20e-05 l. lOe-05 5.80e-06 9.60e-06 1. 40e-05 PETN Gas Generator, GGU-2/A 1.lOe-04 2.90e-05 l. lOe-05 4.90e-05 6.30e-05 PETN Signal, Illumination, Red Star AN-M43A2 l.70e-05 8.20e-06 l. lOe-05 l.20e-05 l.20e-05 PETN Signal, Illumination, Red Star Ml58 1. 30e-05 5.60e-06 6.lOe-06 8.40e-06 8.40e-06 PETN TNT (ACC2) O.OOe+OO O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO PMlO Amato! surrogate 1.50e-02 2.lOe-02 2.00e-02 1.90e-02 PMlO Amato! surrogate with water 2.40e-02 3.lOe-02 4.00e-02 3.20e-02 PMlO Cartridge, Impulse, ARD 446-1 8.30e-02 1.20e-Ol 8.60e-02 8.30e-02 PMlO Cartridge, Impulse, BBU-36/B l.60e-Ol l.90e-01 l.90e-Ol l.80e-Ol PMlO Cartridge, Impulse, MK 107 2.40e-01 2.60e-01 2.50e-01 2.SOe-01 PMlO Composition B surrogate l.OOe-02 1.!0e-02 l.SOe-02 1. 20e-02 PMlO Detonating train 3.60e-02 4.00e-02 3.20e-02 3.60e-02 PMlO Flare, IR Countermeasure M206 4..90e-Ol 5.90e-01 5.80e-01 5.50e-01 PMlO Fuze, Tail Bomb FMU-139 A/B 6.SOe-01 5.60e-01 5.90e-01 6.00e-01 PMlO Fuze, Tail Bomb FMU-54 A/B 3.lOe-01 3.40e-01 3.40e-01 3.30e-01 PMlO Gas Generator, GGU-2/A 9.BOe-02 9.20e-02 8.90e-02 9.30e-02 PMlO HBX surrogate 6.80e-02 3./0e-02 4.40e-01 l.80e-Ol PMlO Mine, Claymore, Ml8Al 2.40e-01 2.30e-01 2.lOe-01 2.JOe-01 PMlO Signal, Illumination, Red Star AN-M43A2 4.JOe-01 4.SOe-01 4.80e-01 4.SOe-01 PMlO Signal, Illumination, Red Star M158 9.20e-02 8.30e-02 7.20e-02 8.20e-02 PMlO Tritonal surrogate 6.JOe-01 2.SOe-01 2.20e-01 3.70e-01 PMlO Tritonal surrogate with calcium stearate 2.JOe-01 3.00e-01 2.60e-01 PMlO Tritonal surrogate with water l. lOe-01 2.20e-01 2.30e-01 1.90e-01 PMlO TNT IACCl) 7.20e-02 7.30e-02 7.50e-02 7.30e-02 PMlO TNT (ACC2) 9.JOe-02 9.30e-02 PMlO T45E7 Adapter Booster 2.40e-Ol 2.70e-01 2.70e-01 2.60e-01 PMlO 40 mm HEI Cartridge 4.70e-Ol 4.SOe-01 4.50e-01 4.70e-Ol RDX Cartridge, Impulse, ARD 446-1 2.30e-03 l.20e-02 l.lOe-02 8.40e-04 l.20e-03 RDX Cartridge, Impulse, BBU-36/B O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.lOe-04 RDX Cartridge, Impulse, MK 107 l.70e-04 l.SOe-04 l.50e-04 l.70e-04 2.40e-04 RDX Detonating train l. lOe-02 7.90e-03 3.70e-03 7.40e-03 1. 20e-02 RDX flare, IR Countermeasure M206 8.70e-05 5.40e-05 3. eae.:.os 6.00e-05 6. 20e-05 RDX Fu::e. Tail Bcmb FMU-139 A/B 3.SOe-04 3.SOe-04 3.00e-04 3.40e-04 3.40e-04 RDX Fu:'P T~il Bomb FHU-54 A/B 9.70e-05 9.20e-05 8.00e-05 9.00e-05 l.30e-04

115

001079 RDX Gas Generator, GGU-2/A 2.lOe-04 1. lOe-04 l.OOe-04 1. 40e-04 l.60e-04 RDX Mine, claymore, Ml8Al 1.00e-05 6.50e-07 l.90e-05 9.90e-06 1. 20e-05 RDX Signal, Illumination, Red Star AN-M43A2 l.50e-04 2.00e-04 2.30e-04 l.90e-04 l.90e-04 RDX Signal, Illumination, Red Star M158 5.20e-05 5.40e-05 6.00e-05 5.50e-05 6.70e-05 RDX TNT (ACCl) 1. 40e-06 1. 30e-06 9.70e-07 1. 20e-06 2.lOe-06 RDX TNT (ACC2) 9.60e-06 9.60e-06 l.OOe-05 RDX T45E7 Adapter Booster 2.50e-04 2.90e-04 l.80e-04 2.40e-04 2.80e-04 RDX 20 mm HEI Cartridge l.30e-05 l.SOe-05 7. lOe-06 1.20e-05 3.00e-05 RDX 40 rran HE! Cartridge 2.60e-05 3.30e-05 5.20e-05 3.70e-05 3.20e-05 Styrene Amato! surrogate O.OOe+OO O.OOe+OO 0. OOe-4-QQ O.OOe+OO O.OOe+OO Styrene Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Cartridge, Impulse, ARD 446-1 6.70e-06 4. lOe-06 5.20e-06 5.40e-06 5.40e-06 Styrene Cartridge, Impulse, BBU-36/B 2.40e-06 2.80e-06 5.60e-06 3.60e-06 3.60e-06 Styrene Cartridge, Impulse, MK 107 9.SOe-06 9.50e-06 9.20e-06 9.40e-06 l.40e-OS Styrene Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Styrene Detonating train 4.lOe-06 3.00e-06 5.lOe-06 4.lOe-06 4.lOe-06 Styrene Flare, IR Countermeasure M206 7.60e-06 4.lOe-06 9.50e-06 7.lOe-06 7.80e-06 Styrene Fuze, Tail Bomb FMU-139 A/B 3.20e-05 2.70e-05 3.00e-05 2.90e-05 3.lOe-05 Styrene Fuze, Tail Bomb FMU-54 A/B 5.60e-06 9.80e-06 7.90e-06 7.BOe-06 1.lOe-05 Styrene Gas Generator, GGU-2/A 7.?0e-06 8.BOe-06 8.50e-06 B.30e-06 9.lOe-06 Styrene HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe-+-00 O.OOe-+-00 Styrene Mine, Claymore, M18Al 2.lOe-03 1. 40e-03 l.50e-03 l.70e-03 l.70e-03 Styrene Signal, Illumination, Red Star AN-M43A2 6.20e-06 4.90e-06 2.40e-06 4.50e-06 5.40e-06 Styrene Signal, Illumination, Red Star Ml58 2.lOe-06 3.50e-06 1. OOe-06 2.20e-06 2.60e-06 Styrene Tritonal surrogate O.OOe+OO O.OOe-+-00 O.OOe-+-00 O.OOe-+-00 O.OOe+OO Styrene Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe-+-00 O.OOe+OO O.OOe+OO Styrene Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe-+-00 Styrene TNT (ACCl) O.OOe+OO O.DDe+DO O.OOe+OO O.OOe+OO O.OOe+OO Styrene TNT (ACC2) l.50e-06 l.50e-06 l.50e-06 Styrene T45E7 Adapter Booster 2.30e-04 7.40e-05 3.70e-05 1.20e-04 l.30e-04 Styrene 20 mm HE! Cartridge O.OOe+OO 3.60e-06 O.OOe+OO 3.60e-06 3.60e-06 Styrene 40 mm HEI Cartridge 4.20e-05 D.ODe+OD O.OOe-+-00 4.20e-05 4.20e-05 S02 l~m~tol surrogate 3.20e-04 2.lOe-04 2.50e-04 2.60e-04 S02 Amato! surrogate with water l.lOe-04 l.70e-04 l. lOe-04 1.30e-04 S02 Cartridge, Impulse, ARD 446-1 2.30e-04 2.30e-04 2.60e-04 2.40e-04 S02 Cartridge, Impulse, BBU-36/B 3.BOe-04 4.00e-04 4. 20e-04 4.00e-04 S02 Cartridge, Impulse, MK 107 3.00e-04 2.40e-04 2.30e-04 2.60e-04 SD2 Composition B surrogate l.40e-04 1. 40e-04 l. lOe-04 l.30e-04 S02 Detonating train 6.70e-04 3.20e-04 3.70e-04 4.60e-04 S02 Flare. IR Ccuntermeasure M206 5.BOe-04 1.20e-03 1. 30e-03 1.00e-03 S02 Fu=e T~il Bcmb FMU-139 A/B 1. 40e-03 l.30e-03 1. 40e-03 l.40e-03

116

001080 S02 Fuze, Tail Bomb FMU-54 A/B 4.BOe-04 3.60e-04 3.BOe-04 4.lOe-04 S02 Gas Generator, GGU-2/A 3.40e-04 4.50e-04 3.90e-04 4.00e-04 S02 HBX surrogate l.OOe-04 l.lOe-03 l.90e-03 l. lOe-03 S02 Signal, Illumination, Red Star AN-M43A2 l.30e-02 l.30e-02 1. 30e-02 1. 30e-02 S02 Signal, Illtunination, Red Star Ml58 2.70e-04 2.40e-05 4.lOe-05 1. lOe-04 S02 Tritonal surrogate l.20e-04 2.BOe-04 7.BOe-05 l.60e-04 S02 Tritonal surrogate with calcium stearate l.BOe-04 6.70e-05 l.20e-04 S02 Tritonal surrogate with water 2.60e-05 5.70e-05 5.90e-05 4.70e-05 S02 TNT IACC2) l.40e-04 l.40e-04 S02 TNT (Sandia) l.90e-04 l.20e-04 l.lOe-04 1. 40e-04 Tetrachloroethylene Amato! surrogate 3.70e-07 3.70e-07 O.OOe+OO 3.70e-07 3.?0e-07 Tetrachloroethylene Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Cartridge, Impulse, ARD 446-1 2.20e-05 5.90e-05 2.BOe-05 3.60e-05 8.30e-05 Tetrachloroethylene Cartridge, Impulse, BBU-36/B 3.20e-06 1. 60e-06 O.OOe+OO 2.40e-06 6.40e-06 Tetrachloroethylene Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Tetrachloroethylene Composition B surrogate 2.lOe-05 l.90ec05 l.40e-05 1. BOe-05 3.50e-05 Tetrachloroethylene Detonating train 1.20e-05 l.20e-OS 1. OOe-05 l.lOe-05 3.40e-05 Tetrachloroethylene Flare, IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO O.OOe+DO O.OOe+OO O.OOe+OO Tetrachloroethylene Gas Generator, GGU-2/A 7.00e-06 7.00e-06 3.60e-06 5.90e-06 5.90e-06 Tetrachloroethylene HBX surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Mine, Claymore, MlBAl O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Signal, Illumination, Red Star M158 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene Tritonal surrogate l.90e-06 3.30e-06 2.90e-06 2.70e-06 4.lOe-06 Tetrachloroethylene Tritonal surrogate with calcium stearate 3.70e-07 3.60e-07 3.70e-07 7.30e-07 Tetrachloroethylene Tritonal surrogate with water O.OOe+QO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Tetrachloroethylene TNT IACC2) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene T45E7 Adapter Booster O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Tetrachloroethylene 20 rran HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Tetrachloroethylene 40 mm HEI Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO

Titanium Amato! surrogat~ O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Amato! surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Titanium Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Titanium Cartridge, Impulse, BBU-36/8 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO Titanium Cartridge, Impulse, MK 107 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO Titanium Composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Titanium Detonating train O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Titanium Flare. IR Countermeasure M206 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO

117

001081 Titanium Fuze, Tail Bomb FMU-139 A/B O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 0.00e+OO Titanium Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Gas Generator, GGU-2/A O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium HBX surrogate O.OOe+OO 0.00e+OO 0.00e+OO O.OOe+OO 0.00e+OO Titanium Mine, Cla:ymore, M18A1 1. JOe-04 1. JOe-04 O.OOe+OO Titanium Signal, Illumination, Red Star AN-M43A2 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Signal, Illumination, Red Star Ml58 O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Tritonal surrogate O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Tritonal surrogate with calcium stearate O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium Tritonal surrogate with water 0.00e+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO Titanium TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO Titanium TNT (ACC2) O.OOe+OO O.OOe+OO 0.00e+OO Titanium T45E7 Adapter Booster 8.70e-05 8.70e-05 8.70e-05 Titanium 20 mm HE! Cartridge O.OOe+OO O.OOe+OO O.OOe+OO Titanium 40 mm HE! Cartridge O.OOe+OO O.OOe+OO 0.00e+OO Toluene Arnatol surrogate 1.lOe-05 3.70e-06 5.20e-06 6.70e-06 2.00e-05 Toluene Amato! surrogate w_i th water 8.lOe-05 1.60e-04 l.20e-04 l.20e-04 1.60e-04 Toluene Cartridge, Impulse, ARD 446-1 l.50e-05 l.50e-05 2.00e-05 l.?Oe-05 5.40e-05 Toluene Cartridge, Impulse, BBU-36/B l.30e-05 7.90e-06 6.40e-06 9.lOe-06 4.70e-05 Toluene Cartridge, Impulse, MK 107 8.40e-06 9.70e-06 8.90e-06 9.00e-06 2.00e-05 Toluene Composition B surrogate 4.80e-06 3.70e-06 9.SOe-06 6.00e-06 2.lOe-05 Toluene Detonating train l.70e-06 3.60e-06 7.20e-06 4.20e-06 5.70e-05 Toluene Flare, IR Countermeasure M206 3.lOe-05 2.30e-05 3.00e-05 2.80e-05 4.lOe-05 Toluene Fuze, Tail Bomb FMU-139 A/B 2.30e-05 2.20e-05 2.50e-05 2.30e-05 3.00e-05 Toluene Fuze, Tail Bomb FMU-54 A/B 2.00e-05 4.JOe-05 3.20e-05 3.20e-05 5.70e-05 Toluene Gas Generator, GGU-2/A 5.90e-06 l.90e-05 1.30e-05 1.30e-05 5.40e-05 Toluene HBX surrogate 4.80e-06 8.20e-07 4.50e-06 3.30e-06 5.30e-05 Toluene Mine, Claymore, Ml8Al 1.90e-04 2.SOe-04 3.lOe-04 2.50e-04 2.60e-04 Toluene Signal, Illumination, Red Star AN-M43A2 2.90e-05 2.90e-OS 3.00e-05 3.00e-05 4.JOe-05 Toluene Signal, Illumination, Red Star Ml58 2.50e-05 2.40e-05 2.70e-05 2.50e-05 3.90e-05 Toluene Tritonal surrogate 1. 90e-06 O.OOe+OO 1. 80e-06 l.80e-06 6.JOe-05 Toluene Tritonal surrogate with calcium stearate O.OOe+OO 0.00e+OO O.OOe+OO 6.40e-05 Toluene Tritonal surrogate with water l.lOe-04 3.40e-05 7.90e-05 7.30e-05 l.60e-04 Toluene TNT (ACCl) 6.50e-06 3.80e-06 0.00e+OO 5.lOe-06 1. 20e-05 Toluene TNT (ACC2) l.50e-06 1. 50e-06 2.lOe-05 Toluene T45E7 Adapter Booster 5.50e-05 4.SOe-05 5.60e-05 5.20e-OS 7.40e-05 Toluene 20 rr.:n HEI Cartridge 2.80e-05 3.40e-05 2.90e-05 3.00e-05 6.40e-05 Toluene .: ,-, r:~ Hf.! ·ir t t i-i'l!? 2.60e-05 O.OOe+OO 0.00e+OO 2.60e-05 6.40e-05 ,. Total Alkanes ~Paraffin~l . . : l' ... 1 OOe-05 l.60e-05 2.lOe-05 l.60e-05 4.lOe-05

,•, ,. : • ' ... l • " Total AlkanE>s !Par.1ffin~1 .. . ~ ~ 1 1:Je- 03 l. lOe-03 l.40e-03 1.20e-03 l.40e-03 .. ;i: ~ .i' 1 S 2Je 05 lOe-05 6.lOe-05 5.lOe-05 Total Alkanoos IPnr nf f 11 .... ' " . ' l .JOe-04 118

•

001082 Total Alkanes (Paraffins) Cartridge, Impulse, BBU-36/B 3.30e-05 3.60e-05 4.60e-05 3.BOe-05 l.40e-04 Total Alkanes (Paraffins) Cartridge, Impulse, MK 107 2.90e-06 l.OOe-05 7.60e-06 6.90e-06 3.90e-05 Total Alkanes (Paraffins) Composition B surrogate 1. 30e-05 6.JOe-06 l.50e-05 l. lOe-05 4.30e-05 Total Alkanes (Paraffins) Detonating train 1. 80e-05 2.80e-05 3.80e-05 2.80e-05 l.50e-04 Total Alkanes (Paraffins) Flare, IR Countermeasure M206 8.00e-06 O.OOe+OO 1. 20e-05 9.90e-06 3.BOe-05 Total Alkanes (Paraffins) Fuze, Tail Bomb FMU-139 A/B 1. 30e-05 2.60e-05 5.30e-06 l.50e-05 4.20e-05 Total Alkanes (Paraffins) Fuze, Tail Bomb FMU-54 A/B 2.20e-05 2.JOe-05 o.OOe+OO 2.20e-05 8.90e-05 Total Alkanes (Paraffins) Gas Generator, GGU-2/A 4. SOe-05 5.BOe-05 2.70e-05 4.30e-05 1. 70e-04 Total Alkanes (Paraffins) HBX surrogate 2.50e-05 8.20e-07 l.70e-05 l.40e-05 1. 50e-04 Total Alkanes (Paraffins) Mine, Claymore, Ml8Al 6.50e-05 6.BOe-05 8.lOe-05 7.lOe-05 l.20e-04 Total Alkanes (Pciraffins) Signal, Illumination, Red Star AN-M43A2 2.30e-05 9.lOe-06 1. 20e-05 l.SOe-05 3.60e-05 Total Alkanes (Paraffins) Signal, Illumination, Red Star Ml58 J.70e-os 4.lOe-05 4.lOe-06 2.70e-05 6.70e-05 Total Alkanes {Paraffins) Tritonal surrogate 3.70e-06 O.OOe+OO 1. 60e-05 l.OOe-05 2.lOe-04 Total Alkanes (Paraffins) Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO 2.00e-04 Total Alkanes (Paraffins) Tritonal surrogate with water 1. 40e-04 l.60e-04 3.70e-04 2.20e-04 5.40e-04 Total Alkanes (Paraffins) TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 7.SOe-05 Total Alkanes (Paraffins) TNT (ACC2) 3.30.-06 3.30e-06 4.00e-05 Total Alkanes {Paraffins) 'INT (Sandia) l.2De-05 8.SOe-06 5.40e-06 8.60e-06 Total Alkanes (Paraffins) T45E7 Adapter Booster 5.60e-05 6.70e-05 l.40e-04 8.70e-05 2.lOe-04 Total Alkanes (Paraffins) 20 mm HEI Cartridge l.20e-04 l.40e-04 2.40e-04 1. 70e-04 3.90e-04 Total Alkanes (Paraffins) 40 mm HE! Cartridge l.60e-04 O.OOe+OO O.OOe+OO 1. 60e-04 4.70e-04 Total Alkenes (Olefins) Amato! surrogate 2.50e-04 7.20e-05 9.60e-05 1. 40e-04 l.40e-04 Total Alkenes (Olefins) Amato! surrogate with water l.JOe-03 l.40e-03 l.70e-03 1.SOe-03 l.50e-03 Total Alkenes (Olefins) Cartridge, Impulse, ARD 446-1 8.lOe-04 6.20e-04 6.lOe-04 6.BOe-04 l.OOe-03 Total Alkenes (Olefins) Cartridge, Impulse, BBU-36/8 5.lOe-04 5.00e-04 6.20e-04 5.40e-04 1.lOe-03 Total Alkenes tolefins) Cartridge, Impulse, MK 107 5.60e-04 4.90e-04 4.lOe-04 4.80e-04 7.lOe-04 Total Alkenes (Olefins) Composition B surrogate 2.50e-05 2.JOe-05 5.30e-05 3.40e-05 3.BOe-05 Total Alkenes (Olefins) Detonating train 7.70e-04 6.40e-04 6.60e-04 6. 90e-04 l.lOe-03 Total Alkenes (Olefins) Flare, IR Countermeasure M206 4. 40e-04 4.30e-04 4.80e-04 4.SOe-04 4.60e-04 Total Alkenes (Olefins) Fuze, Tail Bomb FMU-139 A/B 9.20e-04 l.20e-03 1. 20e-03 l. lOe-03 l. lOe-03 Total Alkenes (Olefins) Fuze, Tail Bomb FMU-54 A/B 5.40e-04 9.30e-04 7.50e-04 7.40e-04 9.90e-04 Total Alkenes (Olefins) Gas Generator, GGU-2/A l.JOe-03 l.40e-03 1. 60e-03 1. 40e-03 1.50e-03 Total Alkenes (Olefins) HBX surrogate 8.00e-05 6.?0e-05 1. 30e-04 9.40e-05 9.90e-05 Total Alkenes {Olefins) Mine, Claymore, Ml8Al 1. OOe-03 l.40e-03 l.50e-03 l.JOe-03 l.30e-03 Total Alkenes (Olefins) Signal, Illumination, Red Star AN-M43A2 5.50e-04 6.50e-04 5.90e-04 6.00e-04 6.00e-04 Total Alkenes (Olefins) Signal, Illumination, Red Star M158 6.40e-04 7.80e-04 4. 50e-04 6.20e-04 6.30e-04 Total Alkenes (Olefins) Tritonal surrogate 2.40e-04 1.SOe-04 8.30e-05 1. 60e-04 l.70e-04 Total Alkenes (Olefins) Tri tonal surrogate .with calcium stearate 7.60e-05 4.70e-05 6.lOe-05 6.90e-05 Total Alkenes {Olefins) Tritonal surrogate with water 5.90e-03 5.5Qe-03 6.lOe-03 5.90e-03 5.90e-03 Total Alkenes (Olefins) TNT IACCl) 7.70e-05 6.SOe-05 3.90e-05 6.00e-05 6.40e-05 Total Alkenes (Olefins) TNT (ACC2) 4.20e-05 4.20e-05 4.40e-05

119

001083 Total Alkenes (Olefins) TNT (Sandia) 5.ooe-06 1.70e-05 l.70e-05 1. 30e-05 Total Alkenes (Olefins) T45E7 Adapter Booster 1.BOe-03 1.30e-03 l.lOe-03 1.40e-03 1.40e-03 Total Alkenes (Olefins) 20 mm HEI Cartridge 6.BOe-04 4.60e-04 6.lOe-04 5.BOe-04 8.20e-04 Total Alkenes (Olefins) 40 mm HEI Cartridge 2.00e-04 1. 50e-04 l.lOe-04 1. 50e-04 2.40e-04 Total Aromatics Amatol surrogate 5.80e-05 2.80e-05 4.20e-05 4.30e-05 8.JOe-05 Total Aromatics Amatol surrogate with water 3.30e-04 3.70e-04 4.SOe-04 3.90e-04 4.70e-04 Total Aromatics Cartridge, Impulse, ARD 446-1 1. OOe-04 9.50e-05 1. OOe-04 1.00e-04 2.40e-04 Total Aromatics Cartridge, Impulse, BBU-36/B 7.40e-05 6.20e-05 5.70e-05 6.40e-05 2.lOe-04 Total Aromatics Composition B surrogate 1. 70e-05 l.80e-05 J.60e-05 2.40e-05 7.lOe-05 Total Aromatics Detonating train 3.40e-05 4.00e-05 4.40e-05 3.90e-05 2.00e-04 Total Aromatics Flare, IR Countermeasure M206 9.lOe-05 7.00e-05 9.?0e-05 8.60e-05 l.20e-04 Total Aromatics Fuze, Tail Bomb FMU-139 A/B l.SOe-04 l.Soe-04 2.00e-04 1. 90e-04 2.lOe-04 Total Aromatics Fuze, Tail Bomb FMU-54 A/B 9.90e-05 2.40e-04 l.70e-04 l.70e-04 2.70e-04 Total Aromatics Gas Generator, GGU-2/A l.20e-04 l.70e-04 1. 80e-04 l.60e-04 2.80e-04 Total Aromatics HBX surrogate O.OOe+OO l.lOe-05 3.lOe-05 2.lOe-05 l.50e-04 Total Aromatics Mine, Claymore. M18Al 3.lOe-03 3.00e-03 3.lOe-03 3.00e-03 3.lOe-03 Total Aromatics Signal, Illumination, Red Star AN-M43A2 7.00e-05 7.80e-05 6.80e-05 7.20e-05 l.OOe-04 Total Aromatics Signal, Illumination, Red Star M158 6. JOe-05 6. 70e-05 5.BOe-05 6.JOe-05 9.60e-05 Total Aromatics Tritonal surrogate 3.40e-05 2.20e-05 2.30e-05 2.70e-05 l.70e-04 Total Aromatics Tritonal surrogate with calcium stearate O.OOe+OO 1.40e-05 1. 40e-05 l.60e-04 Total Aromatics T~itonal surrogate with water 4.70e-04 1.BOe-04 3.60e-04 3.40e-04 5.20e-04 Total Aromatics TNT (ACCll 1. 70e-05 l.50e-05 O.OOe+OO l.60e-05 6.lOe-05 Total Aromatics TNT (ACC2) 3.00e-06 3.00e-06 6.00e-05 Total Aromatics TNT (Sandia) 2.70e-06 9.90e-06 l.20e-05 8.20e-06 Total Aromatics T45E7 Adapter Booster 5.lOe-04 3.20e-04 2.50e-04 3.60e-04 4.20e-04 Total Aromatics 20 mm HEI Cartridge 2.lOe-04 2.lOe-04 2.30e-04 2.lOe-04 3.80e-04 Total Aromatics 40 mm HEI Cartridge 1.00e-04 O.OOe+OO O.OOe+OO l.OOe-04 2.60e-04 Total HpCDD Signal, Illumination, Red Star AN-M43A2 2.60e-10 5.70e-10 l.OOe-09 6.lOe-10 6.lOe-10 Total Non-methane Hydrocarbons Amato! surrogate 7.50e-04 3.40e-04 2.60e-04 4.50e-04 5.90e-04 Total Non-methane Hydrocarbons Amato! surrogate with water 3.60e-03 3.80e-03 4.00e-03 3.BOe-03 4.20e-03 Total Non-methane Hydrocarbons Cartridge, Impulse, ARD 446-1 1. lOe-03 9.lOe-04 9.lOe-04 9.BOe-04 l.70e-03 Total Non-methane Hydrocarbons Cartridge, Impulse, BBU-36/B 7.50e-04 7.lOe-04 8.40e-04 7.70e-04 l.?Oe-03 Total Non-methane Hydrocarbons Cartridge, Impulse, MK 107 7.30e-04 6.50e-04 5.60e-04 6.40e-04 l.OOe-03 Total Non-methane Hydrocarbons Composition B surrogate 5.50e-05 l.30e-04 l.50e-04 l.lOe-04 3.00e-04 Total Non-methane Hydrocarbons Detonating train 9.20e-04 8.lOe-04 8.30e-04 8.50e-04 l.60e-03 Total Non-methane Hydrocarbons Flare, IR Countermeasure M206 5.Soe-04 5.60e-04 6.90e-04 6.lOe-04 7.lOe-04 Total Non-methane Hydrocarbons Fuze, Tail Bomb FMU-139 A/B 1. 20e-03 l.50e-03 l.SOe-03 1. 40e-03 l.50e-03 Total Non-methane Hydrocarbons Fuze, Tail Bomb FMU-54 A/B 7.lOe-04 l.30e-03 9.80e-04 9.90e-04 l.50e-03 Total Non-methane Hydrocarbons Gas Generator, GGU-2/A 1. 60e-03 l.70e-03 2.00e-03 l.80e-03 2.lOe-03 Total Non-methane Hydrocarbons HBX surrogate 2.00e-04 7.70e-05 2.70e-04 l.80e-04 5.aoe-04 Total Non methane Hvdrocarbons Mine Claumore, Ml8Al 4.70e-03 4. aoe-03 5.20e-03 4.90e-03 5.lOe-03

120

001084 Total Non-methane Hydrocarbons Signal, Illumination, Red Star AN-M43A2 6.80e-04 8.SOe-04 7.lOe-04 7.40e-04 8.40e-04 Total Non methane Hydrocarbons Signal, Illumination, Red star M158 7.90e-04 9.50e-04 5.70e-04 7.70e-04 8.SOe-04 Total Non-methane Hydrocarbons Tritonal surrogate 3.90e-04 2.60e-04 l.80e-04 2.80e-04 7.50e-04 Total Non-methane Hydrocarbons Tritonal surrogate with calcium stearate 2.80e-05 5.lOe-05 4.00e-05 5.40e-04 Total Non-methane Hydrocarbons Tritonal surrogate with water 7.00e-03 6.50e-03 7. 90e-03 7.lOe-03 7.BOe-03 Total Non-methane Hydrocarbons TNT (ACCl) O.OOe+OO 2.80e-05 O.OOe+OO 2.SOe-05 5.50e-04 Total Non-methane Hydrocarbons TNT (ACC2) 4.00e-05 4.00e-05 2.lOe-04 Total Non-methane Hydrocarbons T45E7 Adapter Booster 2.?0e-03 l.60e-03 l.40e-03 1. 90e-03 2.60e-03 Total Non-methane Hydrocarbons 20 mm HEI Cartridge 1. 30e-03 9.20e-04 1. 30e-03 l.20e-03 2.60e-03 Total Non-methane Hydrocarbons 40 mm HEI Cartridge 6.50e-04 O.OOe+OO 9.00e-06 3.30e-04 2.40e-03 Total Unidentified Hydrocarbons Amatol surrogate 4.40e-04 2.30e-04 l.OOe-04 2.50e-04 3.30e-04 Total Unidentified Hydrocarbons Amato! surrogate with water 8.lOe-04 8.50e-04 4.30e-04 7.00e-04 8.00e-04 Total Unidentified Hydrocarbons Cartridge, Impulse, ARD 446-1 l.50e-04 l.50e-04 1. 30e-04 1. 40e-04 2.SOe-04 Total Unidentified Hydrocarbons Cartridge, Impulse, BBU-36/B 1. 30e-04 1. 20e-04 1.20e-04 l.20e-04 3.lOe-04 Total Unidentified Hydrocarbons Cartridge, Impulse, MK 107 7 .20e-05 6.00e-05 6.50e-05 6.60e-05 1. 30e-04 Total Unidentified Hydrocarbons Composition B surrogate 3.?0e-07 8.60e-05 5.00e-05 4.50e-05 l.50e-04 Total Unidentified Hydrocarbons Detonating train l.OOe-04 1.00e-04 8.20e-05 9.60e-05 2.40e-04 Total Unidentified Hydrocarbons Flare, IR Countermeasure M206 3.BOe-05 6. SOe-05 9.50e-05 6.60e-05 9.00e-05 Total Unidentified Hydrocarbons Fuze, Tail Bomb FMU-139 A/B 9.60e-05 l.30e-04 8. 3 Oe-05 l.OOe-04 l.40e-04 Total Unidentified Hydrocarbons Fuze, Tail Bomb FMU-54 A/B 5.lOe-05 8.00e-05 7.00e-05 6.?0e-05 l.20e-04 Total Unidentified Hydrocarbons Gas Generator, GGU-2/A l.40e-04 l.20e-04 l.SOe-04 l.50e-04 2.lOe-04 Total Unidentified Hydrocarbons HBX surrogate 7.30e-05 O.OOe+OO 8.40e-05 7.90e-05 l.80e-04 Total Unidentified Hydrocarbons Mine, Claymore, M18Al 5.lOe-04 4.00e-04 5.60e-04 4.90e-04 6.30e-04 Total Unidentified Hydrocarbons Signal, Illumination, Red Star AN-M43A2 3 .30e-05 l.lOe-04 4.20e-05 6.lOe-05 l.OOe-04 Total Unidentified Hydrocarbons Signal, Illumination, Red Star M158 4.lOe-05 6.BOe-05 5.80e-05 5.60e-05 9.lOe-05 Total Unidentified Hydrocarbons Tritonal surrogate l.20e-04 9.60e-05 S.40e-05 9.00e-05 2.00e-04 Total Unidentified Hydrocarbons Tritonal surrogate with calcium stearate O.OOe+OO 3.60e-06 3.60e-06 1.20e-04 Total Unidentified Hydrocarbons Tritonal surrogate with water 4.70e-04 6.00e-04 l.lOe-03 7.lOe-04 8.70e-04 Total Unidentified Hydrocarbons TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 3.50e-04 Total Unidentified Hydrocarbons T45E7 Adapter Booster 3.lOe-04 O.OOe+OO O.OOe+OO 3.lOe-04 5.?0e-04 Total Unidentified Hydrocarbons 20 mm HEI Cartridge 3.00e-04 1.20e-04 2.40e-04 2.20e-04 1. OOe-03 Total Unidentified Hydrocarbons 40 mm HEI Cartridge l.SOe-04 0.00e+OO 2.00e-04 l.90e-04 1. 40e-03 Vinyl chloride Aina.tel surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Amatol surrogate with water O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Cartridge, Impulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Cartridge, Impulse, BBU-36/B 6.lOe-07 2.SOe-06 1. 90e-06 l.70e-06 1. 70e-06 Vinyl chloride Cartridge, Impulse, MK 107 2.40e-06 O.OOe+OO O.OOe+OO 2.40e-06 2.40e-06 • Vinyl chloride Composition B surrogate O.OOe+QO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Detonating train l.30e-06 O.OOe+OO O.OOe+OO 1. 30e-06 l.30e-06 Vinyl chloride Flare, IR Countermeasure M206 l.50e-06 1. 50e-06 l.SOe-06 1. 50e-06 l.SOe-06 Vinvl chloride Fuze, Tail Bomb FMU-139 A/B 2.20e-06 2.20e-06 1. lOe-06 1. 80e-06 l.SOe-06

I 2 I

001085 Vinyl chloride Fuze, Tail Bomb FMU-54 A/B 0.00e+OO 6. 70e-07 6.90e-07 6.80e-07 6.80e-07 Vinyl chloride Gas Generator, GGU-2/A 2.50e-05 2.BOe-05 7. 70e-05 4.40e-05 4.40e-05 Vinyl chloride HBX surrogate 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Vinyl chloride Mine, Claymore, MlBAl l.lOe-06 l.lOe-06 l.lOe-06 Vinyl chloride Signal, Illumination, Red Star AN-M43A2 2.30e-06 2.30e-06 2.30e-06 2.30e-06 2.30e-06 Vinyl chloride Signal, Illumination, Red Star Ml58 8.00e-07 l.60e-06 7.SOe-07 l.lOe-06 l.lOe-06 Vinyl chloride Tritonal surrogate 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Tritonal surrogate with calcium stearate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride Tritonal surrogate with water O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Vinyl chloride TNT (ACCl) O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Vinyl chloride TNT IACC2) 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride T45E7 Adapter Booster 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Vinyl chloride 20 mm HE! Cartridge O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Vinyl chloride 40 mm HEI Cartridge 0.00e+OD O.OOe+-00 O.OOe+OO O.OOe+OO O.OOe+OO Zinc Amato! surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Amato! surrogate with water 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Cartridge, Impulse, ARD 446-1 0. OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Zinc cartridge, Impulse, BBU-36/B 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Cartridge, Impulse, MK 107 O.OOe+OO D.DDe+OO O.OOe+OO 0.00e+OO O.OOe+OO Zinc Composition B surrogate 0.00e+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Zinc Detonating train O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO zinc Flare, IR Countermeasure M206 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Fuze, Tail Bomb FMU-139 A/B 8.20e-03 5.40e-03 5.00e-03 6.20e-03 6.30e-03 Zinc Fuze, Tail Bomb FMU-54 A/B O.OOe+OO O.ODe+OO O.OOe+OO 0.00e+OO 8.20e-05 Zinc Gas Generator, GGU-2/A 1. 60e-04 2.40e-04 1. 50e-04 l.80e-04 2.lOe-04 Zinc HBX surrogate O.OOe+OO 2.lOe-04 2.60e-04 1. 40e-04 l.40e-04 Zinc Mine, Claymore, MlBAl l.60e-03 O.OOe+OO O.OOe+OO l.60e-03 8.00e-05 Zinc Signal, Illumination, Red Star AN-M43A2 5.80e-04 2.70e-04 l.SOe-04 3.40e-04 3.50e-04 Zinc Signal, Illumination, Red Star M158 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc Tritonal surrogate O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO Zinc Tritonal surrogate with calcium stearate l.60e-04 O.OOe+OO 7.00e-05 7.70e-05 Zinc Tritonal surrogate with water 0.00e+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO Zinc TNT (ACCl) 0.00e+OO O.OOe+OO O.OOe+OO Zinc TNT (ACC2) 1. OOe-05 l.OOe-05 2.00e-05 Zinc T45E7 Adapter Booster 2.90e-03 2.90e-03 4.20e-04 Zinc 20 mm HEI Cartridge l.60e-02 l.60e-02 7.40e-03 Zinc 40 mm HEI Cartridge l.lOe-03 l. lOe-03 2.SOe-04 !-Butene Amato! surrogate l.90e-06 O.OOe+OO l.50e-06 l.70e-06 l.70e-06 !-Butene Amato! surrogate with water 8.lOe-05 1. 50e-04 7.90e-05 l.OOe-04 l.OOe-04 !-Butene Cartridge, 1ropulse, ARD 446-1 O.OOe+OO O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO 1-Butene cartridae Imoulse BBU-36/B 6.00e-06 6.40e-06 9.40e-06 7.30e-06 7.30e-06

122

001086 1-Butene Cartridge, Impulse, MK 107 l.lOe-05 l.OOe-05 8.60e-06 l.OOe-05 l.OOe-05 1-Butene Composition B surrogate 7.40e-07 O.OOe+OO l.80e-06 l.30e-06 l.lOe-06 1-Butene Detonating train 3.lOe-05 O.OOe+OO O.OOe+OO 3. lOe-05 3.lOe-05 1-Butene Flare, IR Countermeasure M206 7.30e-06 6.20e-06 l.lOe-05 8.lOe-06 8.lOe-06 1-Butene Fuze, Tail Bomb FMU-139 A/B l.?Oe-05 1. We-05 l.60e-05 1.60e-05 1.60e-05 1-Butene Fuze, Tail Bomb FMU-54 A/B 9.80e-06 1. 3De-05 9.50e-06 1. lOe-0.5 l.lOe-05 1-Butene Gas Generator, GGU-2/A 4.lOe-05 3.9De-05 4.60e-05 4.20e-05 4.20e-05 1-Butene HBX surrogate 8.00e-06 4.50e-06 6.30e-06 6.30e-06 6.30e-06 1-Butene Mine, Claymore, Ml8Al 5.90e-06 9.80e-06 7.lOe-06 7. 60e-06 7.60e-06 1-Butene Signal, Illumination, Red Star AN-M43A2 l.30e-05 1. 20e-05 1. OOe-05 1.20e-05 1.20e-05 1-Butene Signal, Illumination, Red Star Ml58 2.40e-05 2.60e-05 1. 90e-05 2.30e-05 2.30e-05 1-Butene Tritonal surrogate 0.00e+OO l.SOe-06 2.50e-06 2.00e-06 2.00e-06 1-Butene Tritonal surrogate with calcium stearate 5.50e-06 1.80e-06 3.?0e-06 3.70e-06 1-Butene Tritonal surrogate with water 2.80e-05 l.90e-05 2.70e-05 2.SOe-05 2.50e-05 1-Butene TNT (ACCl) 1.80e-06 l.90e-06 1. 90e-06 l.90e-06 1.90e-06 1-Butene TNT (ACC2) l.50e-06 1. 50e-06 1.SOe-06 1-Butene T45E7 Adapter Booster O.OOe+OO 4.SOe-05 5. 40e-05 4.90e-05 4.90e-05 1-Butene 20 mm HE! cartridge 0.00e+OO 2.20e-05 2.70e-05 2.40e-05 2.40e-05 1-Butene 40 mm HEI Cartridge 6.60e-06 5.00e-06 3.30e-06 5.00e-06 5.00e-06 1-Hexene Amato! surrogate 2.60e-06 1. 50e-06 l.90e-06 2.00e-06 2.00e-06 1-Hexene Amato! surrogate with water 3. 50e-05 7.40e-05 4.SOe-05 5.lOe-05 5.20e-05 1-Hexene Cartridge, Impulse, ARD 446-1 l.90e-05 l.80e-05 l.70e-05 l.80e-05 1.80e-05 1-Hexene Cartridge, Impulse, BBU-36/B 1.60e-05 1.80e-05 2.JOe-05 l.90e-05 1.90e-05 1-Hexene Cartridge, Impulse, MK 107 7.JOe-06 6.60e-06 7.30e-06 7.lOe-06 7.lOe-06 1-Hexene Composition B surrogate l.SOe-06 l.90e-06 l .50e-06 l.60e-06 l.60e-06 1-Hexene Detonating train 2.30e-05 2.20e-05 2.80e-05 2.40e-05 2.40e-05 1-Hexene Flare, IR Countermeasure M206 5.60e-06 5.SOe-06 6.80e-06 6.00e-06 6.00e-06 1-Hexene Fuze, Tail Bomb FMU-139 A/B 8.80e-06 9.20e-06 8.20e-06 8.IOe-06 8.?0e-06 1-Hexene Fuze, Tail Bomb FMU-54 A/B 6.50e-06 8.60e-06 6.40e-06 7.20e-06 7.20e-06 1-Hexene Gas Generator, GGU-2/A l.20e-05 l.lOe-05 l.20e-05 1. 20e-05 1. 20e-05 1-Hexene HBX surrogate 2.20e-06 2.50e-06 3.30e-06 2.70e-06 3.00e-06 1-Hexene Mine, claymore, Ml8Al 2.40e-06 2.50e-06 2.40e-06 2.40e-06 2.40e-06 1-Hexene Signal, Illumination, Red Star AN-M43A2 9.00e-06 l.lOe-05 8.60e-06 9.50e-06 9.50e-06 1-Hexene Signal, Illumination, Red Star Ml58 l.90e-05 1. BOe-05 l.60e-05 1. ?Oe-05 l.70e-05 1-Hexene Tritonal surrogate 2.60e-06 1.lOe-06 2.50e-06 2.lOe-06 2.50e-06 1-Hexene Tritonal surrogate with calcium stearate 2.90e-06 2.60e-06 2.BOe-06 3.lOe-06 1-Hexene Tritonal surrogate with water l.BOe-05 l.90e-05 2.60e-05 2.lOe-05 2.20e-05 1-Hexene TNT (ACCl) 2.30e-06 2.40e-06 l.90e-06 2.20e-06 2.20e-06 1-Hexene TNT (ACC2) l.50e-06 1.SOe-06 l.50e-06 1-Hexene T45E7 Adapter Booster 3.40e-05 2.BOe-05 2.30e-05 2.BOe-05 2.BOe-05 1-Hexene 20 mm HEI cartridae 4.90e-06 4.30e-06 4.lOe-06 4.40e-06 4.40e-06

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001087 1-Hexene 40 mm HEI Cartridge l.70e-06 8.20e-07 l.60e-06 1. 40e-06 4.lOe-06 1-Pentene Amato! surrogate 1. lOe-06 1.90e-06 7.40e-07 1.20e-06 l.20e-06 1-Pentene Amato! surrogate with water 3.30e-05 6.80e-05 4. 80e-05 4.90e-05 5.00e-05 1-Pentene Cartridge, Impulse, ARD 446-1 9.50e-06 8. 70e-06 8.20e-06 8.90e-06 1. 30e-05 1-Pentene Cartridge, Impulse, BBU-36/B 9.00e-06 9.80e-06 1. 20e-05 1.00e-05 l.OOe-05 1-Pentene Cartridge, Impulse,· MK 107 4.50e-06 4.20e-06 4.SOe-06 4.40e-06 4.40e-06 1-Pentene Composition B surrogate O.Ooe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1-Pentene Detonating train l.20e-05 1. 40e-05 l.60e-05 1. 40e-05 2.20e-05 1-Pentene Flare, IR Countermeasure M206 4.00e-06 2.70e-06 3.70e-06 3.50e-06 3.50e-06 1-Pentene Fuze, Tail Bomb FMU-139 A/B 5.BOe-06 7.30e-06 5.30e-06 6.lOe-06 6.lOe-06 1-Pentene Fuze, Tail Bomb FMU-54 A/B 5.30e-06 6.20e-06 3.60e-06 5.lOe-06 7.00e-06 1-Pentene Gas Generator, GGU-2/A 5.90e-06 5.30e-06 6.70e-06 6.00e-06 6.00e-06 1-Pentene HBX surrogate l.lOe-06 l.60e-06 l.90e-06 1.50e-06 1.70e-06 1-Pentene Mine, Claymore, MlBAl 9.70e-07 1. 50e-06 l.90e-06 l.40e-06 1.40e-06 1-Pentene Signal, Illumination, Red Star AN-M43A2 O.OOe+OO 5.90e-06 5.20e-06 5.60e-06 5.60e-06 1-Pentene Signal, Illumination, Red Star Ml58 9.BOe-06 1.20e-05 B.60e-06 1.00e-05 1.00e-05 1-Pentene Tritonal surrogate l.50e-06 l.50e-06 l.50e-06 l.50e-06 l.70e-06 1-Pentene Tritonal surrogate with calcium stearate 3.70e-07 1. 50e-06 9.lOe-07 9.lOe-07 1-Pentene Tritonal surrogate with water 1. 50e-05 l.50e-05 2.40e-05 1. BOe-05 l.80e-05 1-Pentene TNT (ACCl) 1. BOe-06 l.40e-06 9.60e-07 1.40e-06 1. 40e-06 1-Pentene TNT (ACC2) 7.40e-07 7.40e-07 7.40e-07 1-Pentene T45E7 Adapter Booster 2.40e-05 1.90e-05 1.SOe-05 1. 90e-05 1.90e-05 1-Pentene 20 mm HEI Cartridge 2.80e-06 5.BOe-06 2.00e-06 3.50e-06 5.90e-06 1-Pentene 40 mm HEI Cartridge 1.70e-06 O.OOe+OO B.20e-07 1.20e-06 3.30e-06 1,3-Butadiene Amato! surrogate O.OOe+OO O.OOe+OO 0.00e+OO O.OOe+OO O.OOe+OO 1,3-Butadiene ~matol surrogate with water 3.70e-06 8. 90e-06 6.30e-06 6.30e-06 6.30e-06 l, 3-Butadiene cartridge, Impulse, ARD 446-1 8.BOe-06 6.70e-06 4.70e-06 6. 70e-06 6.70e-06 1,3-Butadiene Cartridge, Impulse, BBU-36/B 2.70e-06 2.50e-06 3.lOe-06 2.BOe-06 6.30e-06 1,3-Butadiene Cartridge, Impulse, MK 107 2.lOe-06 2.lOe-06 1.BOe-06 2.00e-06 2.00e-06 1,3-Butadiene composition B surrogate O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO O.OOe+OO 1,3-Butadiene Detonating train 5.50e-06 8.70e-06 1.30e-05 9.00e-06 9.00e-06 1,3-Butadiene Flare, IR Countermeasure M206 3.70e-06 2.70e-06 2.70e-06 3.00e-06 3.00e-06 l, 3-Butadiene Fuze, Tail Bomb FMU-139 A/B 2.70e-05 1.70e-05 l.90e-05 2. lOe-05 2. lOe-05 1,3-Butadiene Fuze, Tail Bomb FMU-54 A/B 3.30e-06 4.70e-06 5.50e-06 4.50e-06 4.50e-06 l, 3-Butadiene Gas Generator, GGU-2/A 2.20e-05 2.60e-05 3.30e-05 2.70e-05 2.70e-05 l, 3-Butadiene HBX surrogate 1.50e-06 B.20e-07 1. 90e-06 1.40e-06 1.40e-06 1,3-Butadiene Mine, Claymore, MlBAl 3.90e-06 2.50e-06 1.90e-06 2.70e-06 2.70e-06 1,3-Butadiene Signal, Illumination, Red Star AN-M43A2 2.40e-06 2.lOe-06 l.OOe-06 l.90e-06 1.90e-06 1,3-Butadiene Signal, Illumina.tion, Red Star Ml58 1. 30e-05 l.30e-05 1.lOe-05 1. 20e-05 1.20e-05 l, 3-Butadiene Tritonal surrogate 3.70e-07 O.OOe+OO l.50e-06 9.lOe-07 9.lOe-07 1,3-Butadiene Tritonal surroaate with calcium stearate 1.80e-06 7.30e-07 1. 30e-06 1.30e-06

124

001088 1,3-Butadiene Tritonal surrogate with water 1. ?Oe..:05 3.90e-05 3.30e-OS 3.00e-05 3.00e-05 1,3-Butadiene TNT (ACCl) 3.20e-06 9.60e-07 9.60e-07 l.70e-06 l.?Oe-06 1,3-Butadiene TNT (ACC2) 3.?0e-07 3.?0e-07 3.?0e-07 1,3-Butadiene T45E7 Adapter Booster 4.30e-05 1.SOe-05 l.JOe-05 2.30e-05 2.30e-05 l,3-Butadiene 20 mm HEI Cartridge 5.60e-06 4.30e-06 5 .40e-06 5. lOe-06 5.lOe-06 1,3-Butadiene 40 mm HEI Cartridge 4.20e-06 8.20e-07 8.20e-07 l.90e-06 1.90e-06

125

001089