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GL121-Hazcard-Index GL 121 Hazcard Index (CLP Hazcards, 2016 Edition, and later updates) Version 11: November 2018 update Note: This is a working document and will be subject to frequent updates. Check the latest version at www.cleapss.org.uk Hazcard Index • Please use this index, or the search facility on the website, to find information on a particular chemical before contacting CLEAPSS. • This Index covers the chemicals included in the 2016 Edition of Hazcards (and later updates). • When each new version of this Index is published, a shaded box is used to highlight the latest updates or amendments to Hazcards; the date of the update/amendment is also indicated. • Amendments made to Hazcards since September 2016 are summarised on pages 2 and 3 (overleaf). • Chemicals are listed in the Index by their systematic names and/or by commonly-used alternative (or familiar) names as appropriate. • The Hazcard number is given for each chemical. References to other information (eg, a Recipe) may also be included. • Some chemicals occasionally used in school science activities do not, currently, appear on Hazcards but may be included in later versions. Contact CLEAPSS for information if necessary. Banned chemicals Very few chemicals are banned nationally. These are indicated in the Hazcard Index by ‘B’ and are also emphasised by being in bold print. Chemicals that are not recommended Chemicals that are not recommended or are not suitable for general use in schools are indicated in the Hazcard Index by ‘NR’ and are also emphasised by being in bold print. It may still be possible to use ‘NR’ chemicals under certain circumstances – contact CLEAPSS to discuss. MRATs For several entries in this Index, ‘See MRATs’ is stated in the Notes column. This refers to Model Risk Assessments for Design and Technology in Secondary Schools. These can be found on the CLEAPSS Design and Technology website: dt.cleapss.org.uk. Read Hazcards in conjunction with About Hazcards (Guide GL120). GL 121 11/2018 ©CLEAPSS®, The Gardiner Building, Brunel Science Park, Kingston Lane, Uxbridge UB8 3PQ Tel: 01895 251496; Fax: 01895 814372; E-mail: [email protected]; Web site: www.cleapss.org.uk Updates 2018 Summary of amendments and updates made to the 2016 Edition Hazcards since 1st November 2017, up to and including 1st November 2018 (see page 3 for 2017 changes) Hazcard Amendment/update note 3D Hazard classification information updated for nicotine. No change to general guidance. 15A Storage/Emergencies sections amended to remove references to sodium thiosulfate. WEL values* introduced for calcium oxide and calcium hydroxide as respirable dusts. 18 No change to general guidance. 21 WEL values* lowered for carbon monoxide. No change to general guidance. 23 WEL values* lowered for 1,4-dichlorobenzene. No change to general guidance. 28 WEL values* updated for dichloromethane (lower STEL). No change to general guidance. 38A WEL values* introduced for ethanoic acid. No change to general guidance. 40A On reverse: amendment to note on evaporation/cooling activity. 40B Typo in 4th ‘Dangerous in contact with …’ bullet point: ‘ethanol’ corrected to ‘methanol’. Information added about propene (front and reverse). EUH006 replaced by H230 for ethyne 45C (acetylene). Hazard classification information corrected for limonene (front and reverse). Hazcard rearranged (front and reverse). No change to general guidance. 55C Disposal information for iron(III) chloride amended to cover both solid and solutions. 58A Storage note (first bullet point) re-worded for clarification. New (lower) WEL values* for manganese and its compounds. Note about manganese(IV) 60 oxide and hydrogen peroxide moved to reverse of Hazcard. No change to general guidance. 65B Typo in H codes for nickel(II) chloride: H332 corrected to H331. WEL values* introduced for nitrogen monoxide and nitrogen dioxide. 68B Front of Hazcard rearranged plus minor rewording. No change to general guidance. 76 Storage note (first bullet point) re-worded for clarification. 87 Disposal information (reverse): deleted reference to recycle/re-use (W3) for silver solutions. 88 Storage note (first bullet point) re-worded for clarification. 95C WEL values* lowered for sodium and potassium cyanides. No change to general guidance. WEL values* introduced for sulfur dioxide. 97 Minor rewording on front of Hazcard. No change to general guidance. 99 WEL values* lowered for tetrachloroethene. No change to general guidance. 100 WEL values* lowered for tetrachloromethane. No change to general guidance. *EH40/2005 Workplace Exposure Limits, Third Edition, 2018, HSE (Health and Safety Executive) GL 121 11/2018 2 Updates 2017 Summary of amendments and updates made to the 2016 Edition Hazcards since September 2016, up to and including 1st November 2017 Hazcard Amendment/update note 2B Formula for aluminium ammonium sulfate corrected to AlNH4(SO4)2.12H2O. References to Recipe 6B (for amine solutions) corrected to Recipe 6. 3A/3B [Note: Recipe 6 will be amended/updated to also include amine solutions.] 10A Reference to ‘calcium’ (Other notes section, on reverse) corrected to ‘barium’. 17 Pictogram error on reverse corrected from GHS02 to GHS03. Copper(II) chromate: Info in storage section reworded. ‘Keep damp’ is deleted and replaced 27B by ‘Dispose after use’. Note: “Keep damp” referred to (i) the use of the substance for the migration of ions activity and (ii) minimising the risk of dust inhalation. Storage information for 2,4-dinitrophenylhydrazine re-worded for clarification. 30 Acronym amended to 2,4-DNPH. Printed (purchased) sets of the 2016 Edition included a pictogram error on the front: GHS07 40A appeared twice; one should have been GHS02. Online version (09/2016) was correct. 41 Storage information corrected to include decanedioyl dichloride. 47B Minor typos/missing H code corrected. 55C Formula mass of iron(III) nitrate(V) corrected to 403.99. 64 Formula mass of dibutyl phthalate corrected to 278.34. Nickel(II) sulfate(VI) salts: formulae/formula masses corrected and given for both the hexa- 65B and hepta- hydrates. Added supplemental hazard statement: Corrosive to the respiratory tract [EUH071]. 67 References to nitrogen oxides amended to Hazcard 68B. 78C Title line (front & back) corrected to read: Risk assessment (also 78A, 78B). 79 Recipe reference for rust indicator (ferroxyl solution) corrected to Recipe 101. 85B Hazard classification information added for 1,2-diphenylethanedione (benzil). 96A Added clarification for disposal of sulfur waste: W2 and W8. 106 Minor typo (on reverse) corrected: silicon dioxide. 108A Information added for zinc nitrate solutions ≥ 0.7 M. GL 121 11/2018 3 Hazcard Index Hazcard Chemical Hazcard Recipe Notes updated Acenaphthene 46B – Sept 2016 Acetaldehyde 34 – Sept 2016 Acetamide 35A – Sept 2016 Acetanilide 35A – Sept 2016 Acetic acid 38A 39 Nov 2018 Acetic anhydride 39 – Sept 2016 Acetone 85A 2 Sept 2016 Acetonitrile – – – Acetophenone 85B – Nov 2017 Acetyl chloride 41 – Nov 2017 Acetylcholine chloride 3D – Nov 2018 di acetyl-dioxime 53 – Sept 2016 Acetylene 45C – Nov 2018 2- acetyloxybenzoic acid 52 – Sept 2016 o- acetylsalicylic acid 52 – Sept 2016 Acid blue 40 32 – Sept 2016 Acid chlorides/acyl chlorides 41 – Nov 2017 Acridine orange 32 – Sept 2016 Acrylamide NR, 35B – Sept 2016 Acrylic cement – – – Refer to MRATs Acrylics – – – Refer to MRATs Activated carbon (activated charcoal) 21 – Nov 2018 Adenosine triphosphate (sodium/potassium salt) 72 – Sept 2016 Adhesives – – – Refer to MRATs Adipoyl chloride 41 – Nov 2017 L- adrenaline 3D – Nov 2018 Agar & agar recipes – 1 – Alcohols (see under specific names) – – – Alcohol/water solutions – 2 – Aldehydes (see under specific names) – – – Alginate gels 95A 3 Sept 2016 Alizarin 32 101 Sept 2016 Alum (potash alum) 2B 4 Nov 2017 Alumina 2B – Nov 2017 Aluminium metal (various: foil, powder) 1 – Sept 2016 Aluminium acetate 2B – Nov 2017 Aluminium ammonium sulfate(VI)-12-water 2B – Nov 2017 Aluminium bromide (anhydrous) 2A – Sept 2016 Aluminium chloride (anhydrous) 2A – Sept 2016 Aluminium chloride-6-water 2A 4 Sept 2016 Aluminium ethanoate 2B – Nov 2017 Aluminium nitrate(V)-9-water 2B – Nov 2017 Aluminium oxide 2B – Nov 2017 Aluminium potassium sulfate(VI)-12-water 2B 4 Nov 2017 Aluminium sulfate(VI)-16-water 2B – Nov 2017 Aluminon 32 – Sept 2016 Amalgam (mercury) 61 – Sept 2016 AMG (see Enzymes) 33 – Sept 2016 Amidosulfonic acid 98B – Sept 2016 © CLEAPSS 2018 Chemicals in bold print are banned (‘B’) or not recommended (‘NR’) for general use in schools 4 Hazcard Index Hazcard Chemical Hazcard Recipe Notes updated Amines (see under specific names) – – – Amino acids 38D – Sept 2016 Aminobenzene (and its salts) 4A – Sept 2016 3- aminobenzene-1,2-dicarboxylic hydrazide 4B 23 Sept 2016 2- aminobenzenecarboxylic acid 13C – Sept 2016 3- aminobenzenecarboxylic acid – – – 4- aminobenzenecarboxylic acid 13C – Sept 2016 4- aminobenzenesulfonic acid 4B – Sept 2016 2- aminobenzoic acid 13C – Sept 2016 3- aminobenzoic acid – – – 4- aminobenzoic acid 13C – Sept 2016 o- aminobenzoic acid 13C – Sept 2016 m- aminobenzoic acid – – – p- aminobenzoic acid 13C – Sept 2016 4- aminobiphenyl B – – 1- aminobutane 3A 6 Nov 2017 Aminoethane 3A 6 Nov 2017 1,2-di aminoethane 3B 6 Nov 2017 1,6-di aminohexane 3B 62 Nov 2017 Aminomethane 3A 6 Nov 2017 4- aminophenol (p-aminophenol) 70B – Sept 2016 3- aminophthalhydrazide (luminol) 4B 23 Sept 2016 880 Ammonia 6 6 Sept 2016 Ammonia gas 5 5 Sept 2016 Ammonia solution 6 6 Sept 2016 Ammoniacal silver nitrate(V) (Tollen’s reagent) 87 77, 102 Nov 2018 Ammonium acetate
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