What Is the Difference Between Enthalpy and Energy?
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Thermodynamics Notes
Thermodynamics Notes Steven K. Krueger Department of Atmospheric Sciences, University of Utah August 2020 Contents 1 Introduction 1 1.1 What is thermodynamics? . .1 1.2 The atmosphere . .1 2 The Equation of State 1 2.1 State variables . .1 2.2 Charles' Law and absolute temperature . .2 2.3 Boyle's Law . .3 2.4 Equation of state of an ideal gas . .3 2.5 Mixtures of gases . .4 2.6 Ideal gas law: molecular viewpoint . .6 3 Conservation of Energy 8 3.1 Conservation of energy in mechanics . .8 3.2 Conservation of energy: A system of point masses . .8 3.3 Kinetic energy exchange in molecular collisions . .9 3.4 Working and Heating . .9 4 The Principles of Thermodynamics 11 4.1 Conservation of energy and the first law of thermodynamics . 11 4.1.1 Conservation of energy . 11 4.1.2 The first law of thermodynamics . 11 4.1.3 Work . 12 4.1.4 Energy transferred by heating . 13 4.2 Quantity of energy transferred by heating . 14 4.3 The first law of thermodynamics for an ideal gas . 15 4.4 Applications of the first law . 16 4.4.1 Isothermal process . 16 4.4.2 Isobaric process . 17 4.4.3 Isosteric process . 18 4.5 Adiabatic processes . 18 5 The Thermodynamics of Water Vapor and Moist Air 21 5.1 Thermal properties of water substance . 21 5.2 Equation of state of moist air . 21 5.3 Mixing ratio . 22 5.4 Moisture variables . 22 5.5 Changes of phase and latent heats . -
Thermodynamics of Solar Energy Conversion in to Work
Sri Lanka Journal of Physics, Vol. 9 (2008) 47-60 Institute of Physics - Sri Lanka Research Article Thermodynamic investigation of solar energy conversion into work W.T.T. Dayanga and K.A.I.L.W. Gamalath Department of Physics, University of Colombo, Colombo 03, Sri Lanka Abstract Using a simple thermodynamic upper bound efficiency model for the conversion of solar energy into work, the best material for a converter was obtained. Modifying the existing detailed terrestrial application model of direct solar radiation to include an atmospheric transmission coefficient with cloud factors and a maximum concentration ratio, the best shape for a solar concentrator was derived. Using a Carnot engine in detailed space application model, the best shape for the mirror of a concentrator was obtained. A new conversion model was introduced for a solar chimney power plant to obtain the efficiency of the power plant and power output. 1. INTRODUCTION A system that collects and converts solar energy in to mechanical or electrical power is important from various aspects. There are two major types of solar power systems at present, one using photovoltaic cells for direct conversion of solar radiation energy in to electrical energy in combination with electrochemical storage and the other based on thermodynamic cycles. The efficiency of a solar thermal power plant is significantly higher [1] compared to the maximum efficiency of twenty percent of a solar cell. Although the initial cost of a solar thermal power plant is very high, the running cost is lower compared to the other power plants. Therefore most countries tend to build solar thermal power plants. -
Lecture 4: 09.16.05 Temperature, Heat, and Entropy
3.012 Fundamentals of Materials Science Fall 2005 Lecture 4: 09.16.05 Temperature, heat, and entropy Today: LAST TIME .........................................................................................................................................................................................2� State functions ..............................................................................................................................................................................2� Path dependent variables: heat and work..................................................................................................................................2� DEFINING TEMPERATURE ...................................................................................................................................................................4� The zeroth law of thermodynamics .............................................................................................................................................4� The absolute temperature scale ..................................................................................................................................................5� CONSEQUENCES OF THE RELATION BETWEEN TEMPERATURE, HEAT, AND ENTROPY: HEAT CAPACITY .......................................6� The difference between heat and temperature ...........................................................................................................................6� Defining heat capacity.................................................................................................................................................................6� -
Vapour Absorption Refrigeration Systems Based on Ammonia- Water Pair
Lesson 17 Vapour Absorption Refrigeration Systems Based On Ammonia- Water Pair Version 1 ME, IIT Kharagpur 1 The specific objectives of this lesson are to: 1. Introduce ammonia-water systems (Section 17.1) 2. Explain the working principle of vapour absorption refrigeration systems based on ammonia-water (Section 17.2) 3. Explain the principle of rectification column and dephlegmator (Section 17.3) 4. Present the steady flow analysis of ammonia-water systems (Section 17.4) 5. Discuss the working principle of pumpless absorption refrigeration systems (Section 17.5) 6. Discuss briefly solar energy based sorption refrigeration systems (Section 17.6) 7. Compare compression systems with absorption systems (Section 17.7) At the end of the lecture, the student should be able to: 1. Draw the schematic of a ammonia-water based vapour absorption refrigeration system and explain its working principle 2. Explain the principle of rectification column and dephlegmator using temperature-concentration diagrams 3. Carry out steady flow analysis of absorption systems based on ammonia- water 4. Explain the working principle of Platen-Munter’s system 5. List solar energy driven sorption refrigeration systems 6. Compare vapour compression systems with vapour absorption systems 17.1. Introduction Vapour absorption refrigeration system based on ammonia-water is one of the oldest refrigeration systems. As mentioned earlier, in this system ammonia is used as refrigerant and water is used as absorbent. Since the boiling point temperature difference between ammonia and water is not very high, both ammonia and water are generated from the solution in the generator. Since presence of large amount of water in refrigerant circuit is detrimental to system performance, rectification of the generated vapour is carried out using a rectification column and a dephlegmator. -
Chapter 8 and 9 – Energy Balances
CBE2124, Levicky Chapter 8 and 9 – Energy Balances Reference States . Recall that enthalpy and internal energy are always defined relative to a reference state (Chapter 7). When solving energy balance problems, it is therefore necessary to define a reference state for each chemical species in the energy balance (the reference state may be predefined if a tabulated set of data is used such as the steam tables). Example . Suppose water vapor at 300 oC and 5 bar is chosen as a reference state at which Hˆ is defined to be zero. Relative to this state, what is the specific enthalpy of liquid water at 75 oC and 1 bar? What is the specific internal energy of liquid water at 75 oC and 1 bar? (Use Table B. 7). Calculating changes in enthalpy and internal energy. Hˆ and Uˆ are state functions , meaning that their values only depend on the state of the system, and not on the path taken to arrive at that state. IMPORTANT : Given a state A (as characterized by a set of variables such as pressure, temperature, composition) and a state B, the change in enthalpy of the system as it passes from A to B can be calculated along any path that leads from A to B, whether or not the path is the one actually followed. Example . 18 g of liquid water freezes to 18 g of ice while the temperature is held constant at 0 oC and the pressure is held constant at 1 atm. The enthalpy change for the process is measured to be ∆ Hˆ = - 6.01 kJ. -
HEAT and TEMPERATURE Heat Is a Type of ENERGY. When Absorbed
HEAT AND TEMPERATURE Heat is a type of ENERGY. When absorbed by a substance, heat causes inter-particle bonds to weaken and break which leads to a change of state (solid to liquid for example). Heat causing a phase change is NOT sufficient to cause an increase in temperature. Heat also causes an increase of kinetic energy (motion, friction) of the particles in a substance. This WILL cause an increase in TEMPERATURE. Temperature is NOT energy, only a measure of KINETIC ENERGY The reason why there is no change in temperature at a phase change is because the substance is using the heat only to change the way the particles interact (“stick together”). There is no increase in the particle motion and hence no rise in temperature. THERMAL ENERGY is one type of INTERNAL ENERGY possessed by an object. It is the KINETIC ENERGY component of the object’s internal energy. When thermal energy is transferred from a hot to a cold body, the term HEAT is used to describe the transferred energy. The hot body will decrease in temperature and hence in thermal energy. The cold body will increase in temperature and hence in thermal energy. Temperature Scales: The K scale is the absolute temperature scale. The lowest K temperature, 0 K, is absolute zero, the temperature at which an object possesses no thermal energy. The Celsius scale is based upon the melting point and boiling point of water at 1 atm pressure (0, 100o C) K = oC + 273.13 UNITS OF HEAT ENERGY The unit of heat energy we will use in this lesson is called the JOULE (J). -
Solar Thermal Energy
22 Solar Thermal Energy Solar thermal energy is an application of solar energy that is very different from photovol- taics. In contrast to photovoltaics, where we used electrodynamics and solid state physics for explaining the underlying principles, solar thermal energy is mainly based on the laws of thermodynamics. In this chapter we give a brief introduction to that field. After intro- ducing some basics in Section 22.1, we will discuss Solar Thermal Heating in Section 22.2 and Concentrated Solar (electric) Power (CSP) in Section 22.3. 22.1 Solar thermal basics We start this section with the definition of heat, which sometimes also is called thermal energy . The molecules of a body with a temperature different from 0 K exhibit a disordered movement. The kinetic energy of this movement is called heat. The average of this kinetic energy is related linearly to the temperature of the body. 1 Usually, we denote heat with the symbol Q. As it is a form of energy, its unit is Joule (J). If two bodies with different temperatures are brought together, heat will flow from the hotter to the cooler body and as a result the cooler body will be heated. Dependent on its physical properties and temperature, this heat can be absorbed in the cooler body in two forms, sensible heat and latent heat. Sensible heat is that form of heat that results in changes in temperature. It is given as − Q = mC p(T2 T1), (22.1) where Q is the amount of heat that is absorbed by the body, m is its mass, Cp is its heat − capacity and (T2 T1) is the temperature difference. -
Thermodynamic State Variables Gunt
Fundamentals of thermodynamics 1 Thermodynamic state variables gunt Basic knowledge Thermodynamic state variables Thermodynamic systems and principles Change of state of gases In physics, an idealised model of a real gas was introduced to Equation of state for ideal gases: State variables are the measurable properties of a system. To make it easier to explain the behaviour of gases. This model is a p × V = m × Rs × T describe the state of a system at least two independent state system boundaries highly simplifi ed representation of the real states and is known · m: mass variables must be given. surroundings as an “ideal gas”. Many thermodynamic processes in gases in · Rs: spec. gas constant of the corresponding gas particular can be explained and described mathematically with State variables are e.g.: the help of this model. system • pressure (p) state process • temperature (T) • volume (V) Changes of state of an ideal gas • amount of substance (n) Change of state isochoric isobaric isothermal isentropic Condition V = constant p = constant T = constant S = constant The state functions can be derived from the state variables: Result dV = 0 dp = 0 dT = 0 dS = 0 • internal energy (U): the thermal energy of a static, closed Law p/T = constant V/T = constant p×V = constant p×Vκ = constant system. When external energy is added, processes result κ =isentropic in a change of the internal energy. exponent ∆U = Q+W · Q: thermal energy added to the system · W: mechanical work done on the system that results in an addition of heat An increase in the internal energy of the system using a pressure cooker as an example. -
A Comparative Energy and Economic Analysis Between a Low Enthalpy Geothermal Design and Gas, Diesel and Biomass Technologies for a HVAC System Installed in an Office Building
energies Article A Comparative Energy and Economic Analysis between a Low Enthalpy Geothermal Design and Gas, Diesel and Biomass Technologies for a HVAC System Installed in an Office Building José Ignacio Villarino 1, Alberto Villarino 1,* , I. de Arteaga 2 , Roberto Quinteros 2 and Alejandro Alañón 1 1 Department of Construction and Agronomy, Construction Engineering Area, High Polytechnic School of Ávila, University of Salamanca, Hornos Caleros, 50, 05003 Ávila, Spain; [email protected] (J.I.V.); [email protected] (A.A.) 2 Facultad de Ingeniería, Escuela de Ingeniería Mecánica, Pontificia Universidad Católica de Valparaíso, Av. Los Carrera 01567, Quilpué 2430000, Chile; [email protected] (I.d.A.); [email protected] (R.Q.) * Correspondence: [email protected]; Tel.: +34-920-353-500; Fax: +34-920-353-501 Received: 3 January 2019; Accepted: 25 February 2019; Published: 6 March 2019 Abstract: This paper presents an analysis of economic and energy between a ground-coupled heat pump system and other available technologies, such as natural gas, biomass, and diesel, providing heating, ventilation, and air conditioning to an office building. All the proposed systems are capable of reaching temperatures of 22 ◦C/25 ◦C in heating and cooling modes. EnergyPlus software was used to develop a simulation model and carry out the validation process. The first objective of the paper is the validation of the numerical model developed in EnergyPlus with the experimental results collected from the monitored building to evaluate the system in other operating conditions and to compare it with other available technologies. The second aim of the study is the assessment of the position of the low enthalpy geothermal system proposed versus the rest of the systems, from energy, economic, and environmental aspects. -
Work and Energy Summary Sheet Chapter 6
Work and Energy Summary Sheet Chapter 6 Work: work is done when a force is applied to a mass through a displacement or W=Fd. The force and the displacement must be parallel to one another in order for work to be done. F (N) W =(Fcosθ)d F If the force is not parallel to The area of a force vs. the displacement, then the displacement graph + W component of the force that represents the work θ d (m) is parallel must be found. done by the varying - W d force. Signs and Units for Work Work is a scalar but it can be positive or negative. Units of Work F d W = + (Ex: pitcher throwing ball) 1 N•m = 1 J (Joule) F d W = - (Ex. catcher catching ball) Note: N = kg m/s2 • Work – Energy Principle Hooke’s Law x The work done on an object is equal to its change F = kx in kinetic energy. F F is the applied force. 2 2 x W = ΔEk = ½ mvf – ½ mvi x is the change in length. k is the spring constant. F Energy Defined Units Energy is the ability to do work. Same as work: 1 N•m = 1 J (Joule) Kinetic Energy Potential Energy Potential energy is stored energy due to a system’s shape, position, or Kinetic energy is the energy of state. motion. If a mass has velocity, Gravitational PE Elastic (Spring) PE then it has KE 2 Mass with height Stretch/compress elastic material Ek = ½ mv 2 EG = mgh EE = ½ kx To measure the change in KE Change in E use: G Change in ES 2 2 2 2 ΔEk = ½ mvf – ½ mvi ΔEG = mghf – mghi ΔEE = ½ kxf – ½ kxi Conservation of Energy “The total energy is neither increased nor decreased in any process. -
Heat Energy a Science A–Z Physical Series Word Count: 1,324 Heat Energy
Heat Energy A Science A–Z Physical Series Word Count: 1,324 Heat Energy Written by Felicia Brown Visit www.sciencea-z.com www.sciencea-z.com KEY ELEMENTS USED IN THIS BOOK The Big Idea: One of the most important types of energy on Earth is heat energy. A great deal of heat energy comes from the Sun’s light Heat Energy hitting Earth. Other sources include geothermal energy, friction, and even living things. Heat energy is the driving force behind everything we do. This energy gives us the ability to run, dance, sing, and play. We also use heat energy to warm our homes, cook our food, power our vehicles, and create electricity. Key words: cold, conduction, conductor, convection, energy, evaporate, fire, friction, fuel, gas, geothermal heat, geyser, heat energy, hot, insulation, insulator, lightning, liquid, matter, particles, radiate, radiant energy, solid, Sun, temperature, thermometer, transfer, volcano Key comprehension skill: Cause and effect Other suitable comprehension skills: Compare and contrast; classify information; main idea and details; identify facts; elements of a genre; interpret graphs, charts, and diagram Key reading strategy: Connect to prior knowledge Other suitable reading strategies: Ask and answer questions; summarize; visualize; using a table of contents and headings; using a glossary and bold terms Photo Credits: Front cover: © iStockphoto.com/Julien Grondin; back cover, page 5: © iStockphoto.com/ Arpad Benedek; title page, page 20 (top): © iStockphoto.com/Anna Ziska; pages 3, 9, 20 (bottom): © Jupiterimages Corporation; -
CHEM 109A Organic Chemistry
2/23/18 CHEM 109A Organic Chemistry https://labs.chem.ucsb.edu/zakarian/armen/courses.html Chapter 5 Alkene: Introduction Thermodynamics and Kinetics Midterm 2..... Grades will be posted on Tuesday, Feb. 27th . Tests can be picked up outside room CHEM 2138 starting Tuesday, Feb. 27th 1 2/23/18 A Reaction Coordinate Diagram time A reaction coordinate diagram shows the energy changes that take place in each step of a reaction. Thermodynamics and Kinetics Thermodynamics: • are products more stable than starting materials? • overall, are new bonds in products stronger than the old in starting materials? • deals with equilibria Kinetics: • which reaction is faster? Reaction rates • How high is the energy of the transition state? • deals with mechanism of reactions or is Z more stable than Y? 2 2/23/18 The Equilibrium Constant (thermodynamics) The equilibrium constant gives the relative concentration of reactants and products at equilibrium. Exergonic and Endergonic Reactions ∆G° = free energy of the products - free energy of the reactants the relationship between ∆G° and Keq : 3 2/23/18 Exergonic and Endergonic Reactions ∆G° = free energy of the products - free energy of the reactants the relationship between ∆G° and Keq : ∆G° negative: exergonic reaction, products more stable ∆G° positive: endergonic reaction, products less stable Gibbs Free-Energy Change (∆G°) (thermodynamics) 4 2/23/18 Increasing the Amount of a Product Formed in a Reaction (thermodynamics) Le Chatelier’s Principle: if an equilibrium is disturbed, the system will adjust