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TROMA02_A07-A15hr.qxd 18-11-2009 14:48 Page A-12 A-12 APPENDIX II Useful Data # # Substance ≤H° (kJ mol) ≤G° (kJ mol) S° (J mol K) Substance ≤H° (kJ mol) ≤G° (kJ mol) S° (J mol K) f > f > > f > f > > Uranium Zinc U(s) 0 0 50.2 Zn(s) 0 0 41.6 U(g) 533.0 488.4 199.8 Zn(g) 130.4 94.8 161.0 2+ UF6(s) -2197.0 -2068.5 227.6 Zn (aq) -153.39 -147.1 -109.8 UF6(g) -2147.4 -2063.7 377.9 ZnCl2(s) -415.1 -369.4 111.5 UO2(s) -1085.0 -1031.8 77.0 ZnO(s)-350.5 -320.5 43.7 Vanadium ZnS (s, zinc blende)-206.0 -201.3 57.7 V(s) 0 0 28.9 ZnSO (s) -982.8 -871.5 110.5 V(g) 514.2 754.4 182.3 4 C. Aqueous Equilibrium Constants 1. Dissociation Constants for Acids at 25 °C Name Formula Ka1 Ka2 Ka3 Name Formula Ka1 Ka2 Ka3 -5 -9 Acetic HC2H3O2 1.8 * 10 Hypobromous HBrO 2.8 * 10 -4 -8 Acetylsalicylic HC9H7O4 3.3 * 10 Hypochlorous HClO 2.9 * 10 -5 -6 -11 Adipic H2C6H8O4 3.9 * 10 3.9 * 10 Hypoiodous HIO 2.3 * 10 -3 -7 -12 -1 Arsenic H3AsO4 5.5 * 10 1.7 * 10 5.1 * 10 Iodic HIO3 1.7 * 10 -10 -4 Arsenous H3AsO3 5.1 * 10 Lactic HC3H5O3 1.4 * 10 -5 -12 -2 -7 Ascorbic H2C6H6O6 8.0 * 10 1.6 * 10 Maleic H2C4H2O4 1.2 * 10 5.9 * 10 -5 -3 -6 Benzoic HC7H5O2 6.5 * 10 Malonic H2C3H2O4 1.5 * 10 2.0 * 10 -10 -4 Boric H3BO3 5.4 * 10 Nitrous HNO2 4.6 * 10 -5 -2 -5 Butanoic HC4H7O2 1.5 * 10 Oxalic H2C2O4 6.0 * 10 6.1 * 10 -7 -11 -2 -9 Carbonic H2CO3 4.3 * 10 5.6 * 10 Paraperiodic H5IO6 2.8 * 10 5.3 * 10 -3 -10 Chloroacetic HC2H2O2Cl 1.4 * 10 Phenol HC6H5O 1.3 * 10 -2 -3 -8 -13 Chlorous HClO2 1.1 * 10 Phosphoric H3PO4 7.5 * 10 6.2 * 10 4.2 * 10 -4 -5 -7 -2 -7 Citric H3C6H5O7 7.4 * 10 1.7 * 10 4.0 * 10 Phosphorous H3PO3 5 * 10 2.0 * 10 -4 -5 Cyanic HCNO 2 * 10 Propanoic HC3H5O2 1.3 * 10 -4 -3 Formic HCHO2 1.8 * 10 Pyruvic HC3H3O3 4.1 * 10 -5 -1 -3 -7 Hydrazoic HN3 2.5 * 10 Pyrophosphoric H4P2O7 1.2 * 10 7.9 * 10 2.0 * 10 -10 -3 -9 Hydrocyanic HCN 4.9 * 10 Selenous H2SeO3 2.4 * 10 4.8 * 10 -4 -5 -6 Hydrofluoric HF 3.5 * 10 Succinic H2C4H4O4 6.2 * 10 2.3 * 10 -2 Hydrogen SulfuricH2SO4 Strong acid 1.2 * 10 - - * 7 -2 -8 chromate ion HCrO4 3.0 10 Sulfurous H2SO3 1.6 * 10 6.4 * 10 -3 -5 Hydrogen Tartaric H2C4H4O6 1.0 * 10 4.6 * 10 -12 peroxide H2O2 2.4 * 10 -1 Trichloroacetic HC2Cl3O2 2.2 * 10 Hydrogen - -2 Trifluoroacetic selenate ion HSeO4 2.2 * 10 -1 acid HC2F3O2 3.0 * 10 -8 -19 Hydrosulfuric H2S 8.9 * 10 1 * 10 -3 -11 HydrotelluricH2Te 2.3 * 10 1.6 * 10 2. Dissociation Constants for Hydrated Metal Ions at 25 °C Cation Hydrated Ion Ka Cation Hydrated Ion Ka 3+ 3+ -5 3+ 3+ -3 Al Al(H2O)6 1.4 * 10 Fe Fe(H2O)6 6.3 * 10 2+ 2+ -7 2+ 2+ -11 Be Be(H2O)6 3 * 10 Ni Ni(H2O)6 2.5 * 10 2+ 2+ -9 2+ 2+ -8 Co Co(H2O)6 1.3 * 10 Pb Pb(H2O)6 3 * 10 3+ 3+ -4 2+ 2+ -4 Cr Cr(H2O)6 1.6 * 10 Sn Sn(H2O)6 4 * 10 2+ 2+ -8 2+ 2+ -10 Cu Cu(H2O)6 3 * 10 Zn Zn(H2O)6 2.5 * 10 2+ 2+ -10 Fe Fe(H2O)6 3.2 * 10 TROMA02_A07-A15hr.qxd 18-11-2009 14:48 Page A-13 APPENDIX II Useful Data A-13 3. Dissociation Constants for Bases at 25 °C Name Formula Kb Name Formula Kb -5 -7 Ammonia NH3 1.76 * 10 Ketamine C13H16ClNO 3 * 10 -10 -4 Aniline C6H5NH2 3.9 * 10 Methylamine CH3NH2 4.4 * 10 - -8 -6 Bicarbonate ion HCO3 2.3 * 10 Morphine C17H19NO3 1.6 * 10 2- -4 -6 Carbonate ion CO3 1.8 * 10 Nicotine C10H14N2 1.0 * 10 -6 -3 Codeine C18H21NO3 1.6 * 10 Piperidine C5H10NH 1.33 * 10 -4 -4 Diethylamine (C2H5)2NH 6.9 * 10 Propylamine C3H7NH2 3.5 * 10 -4 -9 Dimethylamine (CH3)2NH 5.4 * 10 Pyridine C5H5N 1.7 * 10 -4 -6 Ethylamine C2H5NH2 5.6 * 10 Strychnine C21H22N2O2 1.8 * 10 -5 -4 Ethylenediamine C2H8N2 8.3 * 10 Triethylamine (C2H5)3N 5.6 * 10 -6 -5 Hydrazine H2NNH2 1.3 * 10 Trimethylamine(CH3)3N 6.4 * 10 -8 HydroxylamineHONH2 1.1 * 10 4. Solubility Product Constants for Compounds at 25 °C Compound Formula Ksp Compound Formula Ksp -33 -39 Aluminum hydroxide Al(OH)3 1.3 * 10 Iron(III) hydroxide Fe(OH)3 2.79 * 10 -21 -19 Aluminum phosphate AlPO4 9.84 * 10 Lanthanum fluoride LaF3 2 * 10 -9 -12 Barium carbonate BaCO3 2.58 * 10 Lanthanum iodate La(IO3)3 7.50 * 10 -10 -6 Barium chromate BaCrO4 1.17 * 10 Lead(II) bromide PbBr2 4.67 * 10 -5 -14 Barium fluoride BaF2 2.45 * 10 Lead(II) carbonate PbCO3 7.40 * 10 -3 -5 Barium hydroxide Ba(OH)2 5.0 * 10 Lead(II) chloride PbCl2 1.17 * 10 -6 -13 Barium oxalate BaC2O4 1.6 * 10 Lead(II) chromate PbCrO4 2.8 * 10 -39 -8 Barium phosphate Ba3(PO4)2 6 * 10 Lead(II) fluoride PbF2 3.3 * 10 -10 -20 Barium sulfate BaSO4 1.07 * 10 Lead(II) hydroxide Pb(OH)2 1.43 * 10 -12 -9 Cadmium carbonate CdCO3 1.0 * 10 Lead(II) iodide PbI2 9.8 * 10 -15 -54 Cadmium hydroxide Cd(OH)2 7.2 * 10 Lead(II) phosphate Pb3(PO4)2 1 * 10 -28 -8 Cadmium sulfide CdS 8 * 10 Lead(II) sulfate PbSO4 1.82 * 10 -9 -29 Calcium carbonate CaCO3 4.96 * 10 Lead(II) sulfide PbS 9.04 * 10 -4 -6 Calcium chromate CaCrO4 7.1 * 10 Magnesium carbonate MgCO3 6.82 * 10 -10 -11 Calcium fluoride CaF2 1.46 * 10 Magnesium fluoride MgF2 5.16 * 10 -6 -13 Calcium hydroxide Ca(OH)2 4.68 * 10 Magnesium hydroxide Mg(OH)2 2.06 * 10 -6 Calcium hydrogen Magnesium oxalate MgC2O4 4.83 * 10 - * 7 -11 phosphate CaHPO4 1 10 Manganese(II) carbonate MnCO3 2.24 * 10 - * 9 -13 Calcium oxalate CaC2O4 2.32 10 Manganese(II) hydroxide Mn(OH)2 1.6 * 10 - * 33 -13 Calcium phosphate Ca3(PO4)2 2.07 10 Manganese(II) sulfide MnS 2.3 * 10 - * 5 -23 Calcium sulfate CaSO4 7.10 10 Mercury(I) bromide Hg2Br2 6.40 * 10 - * 31 -17 Chromium(III) hydroxide Cr(OH)3 6.3 10 Mercury(I) carbonate Hg2CO3 3.6 * 10 - * 10 -18 Cobalt(II) carbonate CoCO3 1.0 10 Mercury(I) chloride Hg2Cl2 1.43 * 10 - * 15 -9 Cobalt(II) hydroxide Co(OH)2 5.92 10 Mercury(I) chromate Hg2CrO4 2 * 10 - * 22 -40 Cobalt(II) sulfide CoS 5 10 Mercury(I) cyanide Hg2(CN)2 5 * 10 - * 9 -29 Copper(I) bromide CuBr 6.27 10 Mercury(I) iodide Hg2I2 5.2 * 10 - * 7 -26 Copper(I) chloride CuCl 1.72 10 Mercury(II) hydroxide Hg(OH)2 3.1 * 10 -20 Copper(I) cyanide CuCN 3.47 * 10 Mercury(II) sulfide HgS 1.6 * 10-54 - * 10 -7 Copper(II) carbonate CuCO3 2.4 10 Nickel(II) carbonate NiCO3 1.42 * 10 - * 20 -16 Copper(II) hydroxide Cu(OH)2 2.2 10 Nickel(II) hydroxide Ni(OH)2 5.48 * 10 - * 37 -20 Copper(II) phosphate Cu3(PO4)2 1.40 10 Nickel(II) sulfide NiS 3 * 10 - * 36 -5 Copper(II) sulfide CuS 1.27 10 Silver bromate AgBrO3 5.38 * 10 - * 11 -13 Iron(II) carbonate FeCO3 3.07 10 Silver bromide AgBr 5.35 * 10 - * 17 -12 Iron(II) hydroxide Fe(OH)2 4.87 10 Silver carbonate Ag2CO3 8.46 * 10 -19 Iron(II) sulfide FeS 3.72 * 10 (continued on the next page) TROMA02_A07-A15hr.qxd 18-11-2009 14:48 Page A-14 A-14 APPENDIX II Useful Data Compound Formula Ksp Compound Formula Ksp -10 -31 Silver chloride AgCl 1.77 * 10 Strontium phosphate Sr3(PO4)2 1 * 10 -12 -7 Silver chromate Ag2CrO4 1.12 * 10 Strontium sulfate SrSO4 3.44 * 10 -17 -27 Silver cyanide AgCN 5.97 * 10 Tin(II) hydroxide Sn(OH)2 5.45 * 10 Silver iodide AgI 8.51 * 10-17 Tin(II) sulfide SnS 1 * 10-26 -17 -10 Silver phosphate Ag3PO4 8.89 * 10 Zinc carbonate ZnCO3 1.46 * 10 -5 -15 Silver sulfate Ag2SO4 1.20 * 10 Zinc hydroxide Zn(OH)2 3 * 10 -51 -8 Silver sulfide Ag2S 6 * 10 Zinc oxalate ZnC2O4 2.7 * 10 -10 -25 Strontium carbonate SrCO3 5.60 * 10 Zinc sulfide ZnS 2 * 10 -5 Strontium chromateSrCrO4 3.6 * 10 5. Complex Ion Formation Constants in Water at 25 °C Complex Ion Kf Complex Ion Kf - 21 3- 43 [Ag(CN)2] 1 * 10 [Fe(CN)6] 2 * 10 [Ag(EDTA)]3- 2.1 * 107 [Fe(EDTA)]2- 2.1 * 1014 + 7 - 24 [Ag(en)2] 5.0 * 10 [Fe(EDTA)] 1.7 * 10 + 7 2+ 9 [Ag(NH3)2] 1.7 * 10 [Fe(en)3] 5.0 * 10 3- 10 4- 5 [Ag(SCN)4] 1.2 * 10 [Fe(ox)3] 1.7 * 10 - 13 3- 20 [Ag(S2O3)2] 2.8 * 10 [Fe(ox)3] 2 * 10 [Al(EDTA)]- 1.3 * 1016 [Fe(SCN)]2+ 8.9 * 102 3- 19 2- 41 [AlF6] 7 * 10 [Hg(CN)4] 1.8 * 10 - 33 2- 16 [Al(OH)4] 3 * 10 [HgCl4] 1.1 * 10 3- 16 2- 21 [Al(ox)3] 2 * 10 [Hg(EDTA)] 6.3 * 10 2- 3 2+ 23 [CdBr4] 5.5 * 10 [Hg(en)2] 2 * 10 2- 18 2- 30 [Cd(CN)4] 3 * 10 [HgI4] 2 * 10 2- 2 2- 6 [CdCl4] 6.3 * 10 [Hg(ox)2] 9.5 * 10 2+ 12 2- 31 [Cd(en)3] 1.2 * 10 [Ni(CN)4] 2 * 10 2- 6 2- 18 [CdI4] 2 * 10 [Ni(EDTA)] 3.6 * 10 2- 16 2+ 18 [Co(EDTA)] 2.0 * 10 [Ni(en)3] 2.1 * 10 - 36 2+ 8 [Co(EDTA)] 1 * 10 [Ni(NH3)6] 2.0 * 10 2+ 13 4- 8 [Co(en)3] 8.7 * 10 [Ni(ox)3] 3 * 10 3+ 48 - 1 [Co(en)3] 4.9 * 10 [PbCl3] 2.4 * 10 2+ 5 2- 18 [Co(NH3)6] 1.3 * 10 [Pb(EDTA)] 2 * 10 3+ 33 2- 4 [Co(NH3)6] 2.3 * 10 [PbI4] 3.0 * 10 2- 9 - 13 [Co(OH)4] 5 * 10 [Pb(OH)3] 8 * 10 4- 9 2- 6 [Co(ox)3] 5 * 10 [Pb(ox)2] 3.5 * 10 3- 20 4- 6 [Co(ox)3] 1 * 10 [Pb(S2O3)3] 2.2 * 10 2- 3 2- 16 [Co(SCN)4] 1 * 10 [PtCl4] 1 * 10 - 23 2+ 35 [Cr(EDTA)] 1 * 10 [Pt(NH3)6] 2 * 10 - 29 - 25 [Cr(OH)4] 8.0 * 10 [Sn(OH)3] 3 * 10 2- 5 2- 19 [CuCl3] 5 * 10 [Zn(CN)4] 2.1 * 10 2- 25 2- 16 [Cu(CN)4] 1.0 * 10 [Zn(EDTA)] 3 * 10 2- 18 2+ 14 [Cu(EDTA)] 5 * 10 [Zn(en)3] 1.3 * 10 2+ 20 2+ 9 [Cu(en)2] 1 * 10 [Zn(NH3)4] 2.8 * 10 2+ 13 2- 15 [Cu(NH3)4] 1.7 * 10 [Zn(OH)4] 2 * 10 2- 8 4- 8 [Cu(ox)2] 3 * 10 [Zn(ox)3] 1.4 * 10 4- 35 [Fe(CN)6] 1.5 * 10.
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  • Xanthan Gum Capped Zno Microstars As a Promising Dietary Zinc Supplementation

    Xanthan Gum Capped Zno Microstars As a Promising Dietary Zinc Supplementation

    foods Article Xanthan Gum Capped ZnO Microstars as a Promising Dietary Zinc Supplementation Alireza Ebrahiminezhad 1,2, Fatemeh Moeeni 2, Seyedeh-Masoumeh Taghizadeh 2, Mostafa Seifan 3, Christine Bautista 3, Donya Novin 3, Younes Ghasemi 2,* and Aydin Berenjian 3,* 1 Department of Medical Nanotechnology, School of Advanced Medical Sciences and Technologies, Shiraz University of Medical Sciences, Shiraz 71348, Iran; [email protected] 2 Department of Pharmaceutical Biotechnology, School of Pharmacy and Pharmaceutical Sciences Research Center, Shiraz University of Medical Sciences, Shiraz 71348, Iran; [email protected] (F.M.); [email protected] (S.-M.T.) 3 School of Engineering, Faculty of Sciences and Engineering, University of Waikato, Hamilton 3216, New Zealand; [email protected] (M.S.); [email protected] (C.B.); [email protected] (D.N.) * Correspondence: [email protected] (Y.G.); [email protected] (A.B.) Received: 7 February 2019; Accepted: 26 February 2019; Published: 2 March 2019 Abstract: Zinc is one of the essential trace elements, and plays an important role in human health. Severe zinc deficiency can negatively affect organs such as the epidermal, immune, central nervous, gastrointestinal, skeletal, and reproductive systems. In this study, we offered a novel biocompatible xanthan gum capped zinc oxide (ZnO) microstar as a potential dietary zinc supplementation for food fortification. Xanthan gum (XG) is a commercially important extracellular polysaccharide that is widely used in diverse fields such as the food, cosmetic, and pharmaceutical industries, due to its nontoxic and biocompatible properties. In this work, for the first time, we reported a green procedure for the synthesis of ZnO microstars using XG, as the stabilizing agent, without using any synthetic or toxic reagent.
  • Chemical Names and CAS Numbers Final

    Chemical Names and CAS Numbers Final

    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
  • The Chlorination of Certain Purinones with Phosphorus Oxychloride in the Presence of Tertiary Amines

    The Chlorination of Certain Purinones with Phosphorus Oxychloride in the Presence of Tertiary Amines

    THE CHLORINATION OF CERTAIN PURINONES WI'fH PHOSPHORUS OXYCHLORIDE IN THE PRESENCE OF TERTIARY AMINES by ROLAND KENITH ROBINS \ ·' A THESIS subnltted to OREGON STATE, COLLEGE 1n partial fulfillment of the requirements tor the degree or DOCTOR OF PHILOSOPHY June 1952 lPlROYlEr Redacted for Privacy lrcfsor ff fmfrtrf In fir;r cf Ltr Redacted for Privacy Redacted for Privacy Uril5! of ofuArlr orltil.t Redacted for Privacy lha f 0mftrtr ililErof ftr ltbrrt, lr nrrrrrrlril ItDr0 try feltrrat fr Bct0nr AOKNO LEOOEMENT The author wishes to express his deepest gratitude to his wife, Lesaa, for her personal sacrifice and efforts ·which have contri buted greatly to the sucoeas of this work. The author wishes also to express thanks to Dr. Bert E. Christensen for h1s valuable assistance throughout the course of this research. TABLE OF CONTENTS Page Discussion • • • • • • • • • • • • • • • • • • • 1 Experimental • • • • • • • • • • • • • • • • • .. 13 Summary • • • • • • ., • • • • • • • • • • ,. • ., 28 Bibliography • • • • • • • • • • • • • • • • • • 29 LIST OF FIGURES Figure 1 • • • • • • • • • • • • • • • • • • • • 5 • Figure 2 • • • • • • ,. • • • • • • • •••••• 9 THE CHLORINATION OF CERTAIN PURINONES WITH PHOSPHORUS OXYCHLORIDE IN THE PRESENCE OF TERTIARY AMINES Since Baddiley and Topham (2, p.678) first re• ported using dimethylaniline in the chlorination or barbituric acid with phosphorus oxychloride, the use or a mixture or this tertiary amine and phosphorus oxy­ chloride has found extensive application in the prep­ aration ot numerous chloropyrimidinea . Because of the close chemical relationship of pyrimidine and purine derivatives, it aeemed quite logical that thia ·reaction could well be extended to the preparation of the rather inaooeaaible chloropur1nes. These chloropurinea could then serve as valuable inter­ mediates in the preparation or synthetic nucleoaidea I (7, pp.833-838).
  • Synthesis and Exfoliation of Layered Hydroxide Zinc Aminobenzoate Compounds

    Synthesis and Exfoliation of Layered Hydroxide Zinc Aminobenzoate Compounds

    Journal of the Ceramic Society of Japan 117 [10] 1115-1119 2009 Paper Synthesis and exfoliation of layered hydroxide zinc aminobenzoate compounds Lifang ZHAO,*,** Jianyjing MIAO,* Hongshe WANG,* Yoshie ISHIKAWA** and Qi FENG**,† *Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji, Shanxi, 721007 P. R. China **Department of Advanced Materials Science, Faculty of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu-shi, 761- 0396 Two types of layered hydroxide zinc o-aminobenzoate compounds with structures of layered basic metal salt (LBMS) were prepared by reacting of zinc hydroxide and o-aminobenzoic acid solution in a temperature range of 40–110°C. The formation reactions, structures, chemical compositions, and exfoliation behavior in alcohol solvents of the layered compounds were inves- tigated by using XRD, TG–DTA, SEM, and TEM. The layered phase with a basal spacing of 1.33 nm has an α-Ni(OH)2-like structure, and its chemical formula can be written as Zn(OH)1.27(o-NH2C6H4COO)0.73·nH2O. The 1.33 nm layered phase shows plate-like particle morphology. The plate-like crystals can be exfoliated into nanosheet-like particles in alcohol solvents. ©2009 The Ceramic Society of Japan. All rights reserved. Key-words : Layered hydroxide zinc aminobenzoate compound, Layered basic metal salt, Exfoliation reaction, Nanosheet [Received June 1, 2009; Accepted August 20, 2009] Another type of anion-exchangeable brucite-like layered metal 1. Introduction hydroxide compounds is known as layered basic metal salts Low-dimensional nanomaterials, such as zero-dimensional (LBMSs), and can be represented by a general formula of II m– 13) – nanoparticles, one-dimensional nanofibers and nanotubes, and [M (OH)2–x](A )x/m·nH2O.