Dr. Davit Hayrapetyan Nazarbayev University Kabanbay Batyr Ave 53, Nur-Sultan 010000 Kazakhstan Personal Address: Kabanbay Batyr Ave 53, 38/1102 Nur-Sultan 010000 Kazakhstan Phone: +7 717 270 58 92 (office) +7 705 440 29 44 (mobile) E-mail: [email protected] (preferred contact) Date of birth: April 1, 1987 Place of birth: Yerevan, Armenia Citizenship: Republic of Armenia Languages: Armenian (mother tongue), Russian (near-native), English (fluent), German (beginner), Japanese (beginner) Education 2009 – 2012 M.V. Lomonosov Moscow State University, Moscow, Russia Ph.D. in Chemestry Specialization: Organometallic Chemistry, Organic Chemistry Thesis: Organogermanium and Organotin Complexes With Extended Coordination Sphere: Synthesis, Structure and Properties Advisor: Prof. Dr. Valeriy Petrosyan 2004 – 2009 M.V. Lomonosov Moscow State University, Moscow, Russia Diploma Chemist (M.Sc. equivalent) Specialization: Organometallic Chemistry Thesis: Novel O,O-Chelate Complexes of Penta- and Hexacoordinated Germanium and Tin Based on Amides of 2- Hydroxycarboxylic acids Advisor: Dr. Sergey Gruener Jun 2004 Anania Shirakatsy Armenian National Lyceum, Yerevan, Armenia Postdoctoral experience Jan 2019 – present Nazarbayev university Postdoctoral Scholar Diversity oriented synthesis of spirocyclic heterocycles Electrochemical oxidative C-H functionalization reactions Nov 2016 – Nov 2018 Ruhr-Universität Bochum Postdoctoral Fellow, Group of Prof. Lukas Gooßen Electrochemical oxidative C-H functionalization reactions

Jul 2015 – Oct 2016 Nazarbayev University Postdoctoral Fellow, Group of Prof. Kevin Lam Organometallic anticancer drugs; Electrochemical transformations of aromatic and aliphatic carboxylic acid derivatives May 2014 – May 2015 University of Tokyo Postdoctoral Fellow, Group of Prof. Shu Kobayashi Hydrogen autotransfer processes catalyzed by Polymer Incarcerated (PI) metal nanoparticles; Organic polymers with aluminum and scandium as heterogeneous water-compatible Lewis acid catalysts Teaching experience 2019 General chemistry II laboratory, Nazarbayev University 2018 Organic chemistry laboratory, Ruhr Universtät Bochum 2009 – 2012 Teaching assistant in organic chemistry laboratory (laboratory, colloquia), Moscow State University 2009 – 2012, 2015 – 2018 Supervision of undergraduate students in research laboratory 2009 – 2012 Individual training of High school students in Chemistry Industry experience Oct 2017 – Nov 2018 Collaborative project with Evonik Research in the field of preparative organic electrochemistry Feb 2013 – Dec 2013 ChemDiv Research Institute (CDRI), Khimki, Russia Research Scientist Multiple research programs on synthesis of diverse saturated heterocyclic compounds, medium- and large ring systems, spiro- and bridged heterocycles. Modification of natural products.

Publications 13. K. A. Gudun, A. Slamova, D. Hayrapetyan, A.Y. Khalimon, Efficient Co‐catalyzed Double Hydroboration of Nitriles: Application to One‐Pot Conversion of Nitriles to Aldimines. Chem. Eur. J. Accepted Manuscript. doi:10.1002/chem.202000753 12. A. Y. Khalimon, K. A. Gudun, D. Hayrapetyan, Base Metal Catalysts for Deoxygenative Reduction of Amides to Amines, Catalysts 2019, 9(6), 490-516 11. Marco Dyga, Davit Hayrapetyan, Raja K. Rit, Lukas J. Gooßen, Electrochemical ipso- Thiocyanation of Arylboron Compounds, Adv. Synth. Catal. 2019, 361, 3548–3553  Very Important Publication 10. D. Hayrapetyan, R. K. Rit, M. Kratz, K. Tschulik, L. J. Gooßen, Electrochemical C–H Cyanation of Electron-Rich (Hetero)Arenes, Chem. Eur. J., 2018, 24, 11288 – 11291  Hot Paper 9. E. A. Hall, J. E. Ramsey, Z. Peng, D. Hayrapetyan, V. Shkepu, B. O'Rourke, W. Geiger, K. Lam, C. F. Verschraegen, Novel organometallic chloroquine derivative inhibits tumor growth, J Cell Biochem. 2018; 119, 5921-5933 8. D. Hayrapetyan, V. Shkepu, O. T. Seilkhanov, Z. Zhanabil, K. Lam, Electrochemical synthesis of phthalides via anodic activation of aromatic carboxylic acids, Chem. Commun., 2017, 53, 8451-8454 7. H.Miyamura, A. Sonoyama, D. Hayrapetyan, S. Kobayashi, Self-Assembled Nanocomposite Organic Polymers with Aluminum and Scandium as Heterogeneous Water-Compatible Lewis Acid Catalysts, Angew. Chem. Int. Ed. 2015, 54, 10559 –10563  Highlighted in Synfacts (Synfacts 2015, 11(12), 1331) 6. A. Zherebker, D. Airapetyan, A. I. Konstantinov, Y. Kostyukevich, A. Kononikhin, I. Popov, K. V. Zaitsev, E. Nikolaev, I. V. Perminova, Synthesis of Model Humic Substances by Oxidative Coupling of Phenylpropanoic Monomer and Hydroquinone: Mechanistic Study Using Controllable H/D Exchange and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Analyst, 2015, 140, 4708-4719 5. D. V. Airapetyan, V. S. Petrosyan, S. V. Gruener, A. A. Korlyukov, D. E. Arkhipov, A. A. Bowden, K. V. Zaitsev, Structure of hypercoordinatedmonoorganodihalostannanes in solutions and in the solid state: the halogen effect, Inorg. Chim. Acta, 2015, 432,142-148 4. D.V. Airapetyan, V.S. Petrosyan, S.V. Gruener, K.V. Zaitsev, D.E. Arkhipov, A.A. Korlyukov, Disproportionation reactions within the series of coordinated monoorganostannanes, J. Organomet. Chem., 2013, 747, 241-248. 3. D. V. Airapetyan, T. P. Murasheva, S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, S. V. Gruner, E. P. Kramarova, Vad. V. Negrebetsky, S. A. Pogozhykh, G. Ya. Zueva, M. Yu. Antipin. Yu. I. Baukov, Trichloro- and methyldichlorogermylmonochelates and dibromo- and dichlorogermylbischelates derived from N,N-disubstituted amides of 2-hydroxycarboxylic acids, Russ. Chem. Bull., 2012, 61, 642-651. 2. S. V. Gruener, D. V. Airapetyan, A. A. Korlyukov, A. G. Shipov, Y. I. Baukov, V. S. Petrosyan, Interaction of ethyltrichlorostannane with N,N-dimethylamides of O-trimethylsilyl-α- hydroxyacids, Appl. Organomet. Chem., 2010, 24, 888-896. 1. A. G. Shipov, S. V. Gruner, A. A. Korlyukov, E. P. Kramarova, T. P. Murasheva, S. Yu. Bylikin, Vad. V. Negrebetsky, F. A. Ivaschenko, D. V. Airapetyan, G. Ya. Zueva, M. Yu. Antipin. Yu. I. Baukov, Tribromogermylmonochelates — derivatives of N,N-disubstituted 2-hydroxycarboxylic amides, Russ. Chem. Bull., 2010, 59, 761-770.

Selected talks 2018 Saint Petersburg State University (invited lecture) 2015 Annual Meeting of the Chemical Society of Japan. Skills  Deep knowledge of organic and organometallic chemistry. Research experience in synthetic organic chemistry, synthetic organometallic chemistry, synthesis of building blocks, multistep synthesis, modification of natural products, homogenous and heterogeneous catalysis, Lewis acid catalysis, reaction optimization and screening, autoclave experiments, preparative organic electrochemistry, design and construction of electrochemical cells for synthesis  Knowledge of analytical instruments and techniques: NMR, Ft-IR, GC, GC/MS, HPLC, LC/MS, MPLC, ICP etc. Maintenance of instruments: GC, GC/MS, MPLC, HPLC  Advanced user of ChemDraw, BioviaDraw, ACDlabs, ISIS/draw, ISIS/Base, MestreNova, SciFinder, Reaxys etc.  Self-motivated, hard-working, ability to meet deadlines, ability to work independently and in a team, responsible, creative

Scientific interests  Synthetic methodology, Catalysis, Organic electrochemistry, Medicinal chemistry, Building block development, Natural products, Total synthesis, Pharmaceuticals References Prof. Lukas Gooßen Ruhr-Universität Bochum, Bochum, Germany Phone: +49 234 32 19075 E-mail: [email protected] Prof. Kevin Lam Nazarbayev University, Astana, Kazakhstan (currently at University of Greenwich) Phone: +7 7172 709110 E-mail: [email protected], [email protected] Prof. Shu Kobayashi University of Tokyo, Tokyo, Japan Phone: +81 3 5841 4790 E-mail: [email protected] Dr. Volodymyr Kysil Director of Chemistry at ChemDiv, Inc., San Diego, CA, USA E-mail: [email protected] Prof. Valery S. Petrosyan Moscow State University, Moscow, Russia Phone: +7 495 939 56 43 E-mail: [email protected], [email protected]