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Safety Data Sheet
1/6 Sodium iodate,KISHIDA CHEMICAL CO., LTD.,7183E-1,10/04/2019 Date of issue: 10/04/2019 Safety Data Sheet 1. Identification of the substance/mixture and of the company/undertaking Product identifier: Product name: Sodium iodate Product code (SDS NO): 7183E-1 Details of the supplier of the safety data sheet Manufacturer/Supplier: KISHIDA CHEMICAL CO., LTD. Address: 3-1, Honmachibashi, Chuo-ku,Osaka 540-0029,JAPAN Division: Safety Management Dept. of Chemicals Telephone number: +81-6-6946-8061 FAX: +81-6-6946-1607 e-mail address: [email protected] 2. Hazards identification GHS classification and label elements of the product Classification of the substance or mixture PHYSICAL AND CHEMICAL HAZARDS Oxidizing solids: Category 2 HEALTH HAZARDS Acute toxicity (Oral): Category 4 ENVIRONMENT HAZARDS Hazardous to the aquatic environment (Acute): Category 3 Hazardous to the aquatic environment (Long-term): Category 3 (Note) GHS classification without description: Not applicable/Out of classification/Not classifiable Label elements Signal word: Danger HAZARD STATEMENT May intensify fire; oxidizer Harmful if swallowed Harmful to aquatic life Harmful to aquatic life with long lasting effects PRECAUTIONARY STATEMENT Prevention Avoid release to the environment. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles and/or other incompatible materials. Wash contaminated parts thoroughly after handling. Wear protective gloves and face protection. Do not eat, drink or smoke when using this product. Response In case of fire: Use appropriate media other than water for extinction. Rinse mouth. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. -
Production of Dialdehyde Cellulose and Periodate Regeneration: Towards Feasible Oxidation Processes
Production of Dialdehyde Cellulose and Periodate Regeneration: Towards feasible oxidation processes Produktion av dialdehydcellulosa och återgenerering av perjodat: Mot möjliga oxidationsprocesser Elisabeth Höglund Department of Engineering and Chemical Sciences Chemistry 30 hp Supervisors: Susanne Hansson, Stora Enso & Gunilla Carlsson, Karlstad University Examinator: Thomas Nilsson 2015-09-25 ABSTRACT Cellulose is an attractive raw material that has lately become more interesting thanks to its degradability and renewability and the environmental awareness of our society. With the intention to find new material properties and applications, studies on cellulose derivatization have increased. Dialdehyde cellulose (DAC) is a derivative that is produced by selective cleavage of the C2-C3 bond in an anhydroglucose unit in the cellulose chain, utilizing sodium periodate (NaIO4) that works as a strong oxidant. At a fixed temperature, the reaction time as well as the amount of added periodate affect the resulting aldehyde content. DAC has shown to have promising properties, and by disintegrating the dialdehyde fibers into fibrils, thin films with extraordinary oxygen barrier at high humidity can be achieved. Normally, barrier properties of polysccharide films deteriorate at higher humidity due to their hygroscopic character. This DAC barrier could therefore be a potential environmentally-friendly replacement for aluminum which is utilized in many food packages today. The aim of this study was to investigate the possibilities to produce dialdehyde cellulose at an industrial level, where the regeneration of consumed periodate plays a significant role to obtain a feasible process. A screening of the periodate oxidation of cellulose containing seven experiments was conducted by employing the program MODDE for experimental design. -
Safety Data Sheet Chloride
UNIVAR USA INC. SDS NO:DW79537 ISSUE DATE:2015-06-08 VERSION:014 2015-08-04 Annotation: SAFETY DATA SHEET M48005 - ANSI - EN _____________________________________________________________________________________________________ CHLORIDE SDS No.: M48005 SDS Revision Date: 08-Jun-2015 _____________________________________________________________________________________________________ _____________________________________________________________________________________________________ 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION _____________________________________________________________________________________________________ Company Identification: Occidental Chemical Corporation 5005 LBJ Freeway P.O. Box 809050 Dallas, TX 75380-9050 1-800-752-5151 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228 (USA); CHEMTREC (within USA and Number: Canada): 1-800-424-9300; CHEMTREC (outside USA and Canada): +1 703-527-3887; CHEMTREC Contract No: CCN16186 To Request an SDS: [email protected] or 1-972-404-3245 Customer Service: 1-800-752-5151 or 1-972-404-3700 Product Identifier: Synonyms: Calcium Dichloride, Calcium Chloride, Peladow, Calcium Chloride Pellets Product Use: Ice Melting Uses Advised Against: None identified. Additional Information: CONSUMER PRODUCTS: When packaged in quantities of 50 lbs. or less, and used in a manner and frequency typical of consumer use, OxyChem considers this product a consumer use product which is regulated by the Consumer Product Safety Commission (CPSC). Because CPSC labeling requirements differ from the -
Solvent Variations of the Briggs-Rauscher Reaction Chelsea Trost1, Ana Figuereo1, Marie Roche1, Leonardo Albertini2, Luis C
MOL2NET, 2016 (2), http://sciforum.net/conference/mol2net-02/stureus-01 1 Solvent Variations of the Briggs-Rauscher Reaction Chelsea Trost1, Ana Figuereo1, Marie Roche1, Leonardo Albertini2, Luis C. Fernandez-Torres1,* 1School of Science, St. Thomas University, Miami Gardens, FL 33054, USA 2Miami Dade College, North Campus, Miami, FL, USA *Author to whom correspondence should be addressed; E-Mail: [email protected] Tel.: +1-305-474-6014; Fax: +1-305-628-6706. Received: / Accepted: / Published: Abstract: The Briggs-Rauscher (BR) oscillatory reaction is one of the more interesting and colorful oscillatory reactions. It has surpassed the demonstration realm, as it has found use as a method to assess antioxidant capacity. However, this application as an antioxidant assay is limited to water-soluble samples. In the constant search for different, novel applications, we report the effects of various sample solvents on the behavior of the BR reaction. Our investigation looked at how changes in the solvent used to dissolve samples altered the time intervals of BR reaction’s oscillations. The solvents used were ethanol, isopropanol, 1- propanol, acetone, and acetonitrile. Addition of ethanol had no effect on the BR oscillations. Isopropanol, 1- propanol, and acetone shorten the oscillation time. A test using acetonitrile discarded solvent polarity effects. Our results suggest that solvents that accelerate the enol pathway rate affect the oscillations of the BR reaction. Finally, samples can be safely dissolved in ethanol and used in the BR reaction. Keywords: oscillatory reaction, Briggs-Rauscher reaction, solvent variation, and enol pathway. Introduction The Briggs-Rauscher (BR) reaction is an oscillating reaction that changes between two cycles back and forth until it reaches equilibrium. -
Potential Biocides: Iodine-Producing Pyrotechnics Full Paper
Full Paper 1 DOI: 10.1002/prep.201700037 2 3 4 Potential Biocides: Iodine-Producing Pyrotechnics 5 Jimmie C. Oxley,*[a] James L. Smith,[a] Matthew M. Porter,[a] Maxwell J. Yekel,[a] and Jeffrey A. Canaria[a] 6 7 8 9 Abstract: Currently there is a need for specialized py- measured with bomb calorimetry and extraction and analy- 10 rotechnic materials to combat the threat of biological sis of I2 by UV-Vis. Of the mixtures analyzed, calcium iodate 11 weapons. Materials have been characterized based on their and aluminum was found to be the highest producer of I2. 12 potential to produce heat and molecular iodine gas (I2)to The heat output of this mixture and others can be tuned by 13 kill spore-forming bacteria (e.g. anthrax). One formulation, adding more fuel, with the cost of some iodine. Products of 14 already proven to kill anthrax simulants, is diiodine pent- combustion were analyzed by thermal analysis (SDT), XPS, 15 oxide with aluminum; however, it suffers from poor stability XRD, and LC/MS. Evidence for various metal iodides and 16 and storage problems. The heat and iodine gas output from metal oxides was collected with these methods. 17 this mixture and candidate replacement mixtures were 18 Keywords: Keywords missing!!! 19 20 21 22 1 Introduction The pyrotechnic mixtures were mixed as dry loose pow- 23 ders using a Resodyne Lab Ram Acoustic Mixer (acceleration 24 Previously we examined a series of oxidizers and fuels to 35–40 G). Heat released from the ignition of the pyrotechnic 25 determine their potential as explosive threats [1]. -
Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
WO 2017/162668 Al 28 September 2017 (28.09.2017) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2017/162668 Al 28 September 2017 (28.09.2017) P O P C T (51) International Patent Classification: (74) Agent: SIEBER, Frank; K 703, c/o Sanofi-Aventis C07D 307/77 (2006.01) A61K 31/343 (2006.01) Deutschland GmbH, Global Intellectual Property Depart ment, Industriepark Hochst, Geb. K 703, 65926 Frankfurt (21) Number: International Application am Main (DE). PCT/EP2017/056690 (81) Designated States (unless otherwise indicated, for every (22) Date: International Filing kind of national protection available): AE, AG, AL, AM, 2 1 March 2017 (21 .03.2017) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (25) Filing Language: English BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (26) Publication Language: English HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, (30) Priority Data: KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, P160021 1 23 March 2016 (23.03.2016) HU MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, (71) Applicant: CHINOIN GYOGYSZER ES VEGYESZ- RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, ETI TERMEKEK GYARA ZRT. [HU/HU]; 1045 Bud TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, apest To u. -
Consideration of Mandatory Fortification with Iodine for Australia and New Zealand Food Technology Report
CONSIDERATION OF MANDATORY FORTIFICATION WITH IODINE FOR AUSTRALIA AND NEW ZEALAND FOOD TECHNOLOGY REPORT December 2007 1 Introduction Food Standards Australia New Zealand is considering mandatory fortification of the food supply in Australia and New Zealand with iodine. Generally, the addition of iodine to foods is technologically feasible. However, in some instances the addition of iodine can lead to quality changes in food products such as appearance, taste, odour, texture and shelf life. These changes will depend on the chemical form of iodine used as a fortificant, the chemistry of the food that is being fortified, the food processes involved in manufacture and possible processing interactions that could occur during distribution and storage. Many foods have been fortified with iodine and the potassium salts of iodine compounds have been used as the preferred form. 2 Forms of Iodine Iodine is normally introduced, or supplemented, as the iodide or iodate of potassium, calcium or sodium. The following table lists different chemical forms of iodine along with their important physical properties. Table 1: Physical Properties of Iodine and its Compounds Name Chemical Formula % Iodine Solubility in water (g/L) 0°C 20°C 30°C 40°C 60°C Iodine I2 100 - - 0.3 0.4 0.6 Calcium iodide CaI2 86.5 646 676 690 708 740 Calcium iodate Ca(IO3)2.6H2O 65.0 - 1.0 4.2 6.1 13.6 Potassium iodide KI 76.5 1280 1440 1520 1600 1760 Potassium iodate KIO3 59.5 47.3 81.3 117 128 185 Sodium iodide NaI.2H20 85.0 1590 1790 1900 2050 2570 Sodium iodate NaIO3 64.0 - 25.0 90.0 150 210 Adapted from Mannar and Dunn (1995) 2.1 Potassium Iodide Potassium iodide (KI) is highly soluble in water. -
Calcium Chloride
Iodine Livestock 1 2 Identification of Petitioned Substance 3 4 Chemical Names: 7553-56-2 (Iodine) 5 Iodine 11096-42-7 (Nonylphenoxypolyethoxyethanol– 6 iodine complex) 7 Other Name: 8 Iodophor Other Codes: 9 231-442-4 (EINECS, Iodine) 10 Trade Names: CAS Numbers: 11 FS-102 Sanitizer & Udderwash 12 Udder-San Sanitizer and Udderwash 13 14 Summary of Petitioned Use 15 The National Organic Program (NOP) final rule currently allows the use of iodine in organic livestock 16 production under 7 CFR §205.603(a)(14) as a disinfectant, sanitizer and medical treatment, as well as 7 CFR 17 §205.603(b)(3) for use as a topical treatment (i.e., teat cleanser for milk producing animals). In this report, 18 updated and targeted technical information is compiled to augment the 1994 Technical Advisory Panel 19 (TAP) Report on iodine in support of the National Organic Standard’s Board’s sunset review of iodine teat 20 dips in organic livestock production. 21 Characterization of Petitioned Substance 22 23 Composition of the Substance: 24 A variety of substances containing iodine are used for antisepsis and disinfection. The observed activity of 25 these commercial disinfectants is based on the antimicrobial properties of molecular iodine (I2), which 26 consists of two covalently bonded atoms of elemental iodine (I). For industrial uses, I2 is commonly mixed 27 with surface-active agents (surfactants) to enhance the water solubility of I2 and also to sequester the 28 available I2 for extended release in disinfectant products. Generally referred to as iodophors, these 29 “complexes” consist of up to 20% I2 by weight in loose combination with nonionic surfactants such as 30 nonylphenol polyethylene glycol ether (Lauterbach & Uber, 2011). -
Estimation of DL-Glyceraldehyde, Dihy Droxyacetone, Methylglyoxal, and Their Mixtures by Oxidation with Sodium Periodate
Estimation of DL-glyceraldehyde, dihy droxyacetone, methylglyoxal, and their mixtures by oxidation with sodium periodate M. FEDOROŇKO, E. FÜLEOVÄ, and W. DANIELISZYN Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava Received 17 May 1971 Dedicated to the 65th Anniversary of Professor S. Stankovianslcy An anatytical method for the estimation of DL-glyceraldehyde, dihydroxy- acetone, methylglyoxal, and their binary and ternary mixtures by oxidation with sodium periodate in unbuffered aqueous media was worked out. Oxi dations proceeded at 70°C during 1 hour. On the basis of chemical equations of oxidation of the individual compounds studied, of the unchanged sodium periodate as well as the produced acids and formaldehyde, mathematical relations were derived for calculation of the concentrations of individual compounds also in the mentioned types of mixtures. The error of estimation of individual compounds in the concentration range 5 — 20 mg did not exceed zz2%. In the case of binary and ternary mixtures for 20 mg sample, when the concentration range of individual compounds was 20—80%, the relative error of their estimation did not exceed ±10%. In this work, also mechanisms of oxidations with sodium periodate of the estimated compounds are dis cussed. In our studies of acid-base catalyzed isomerizations of trioses and their dehydration to methylglyoxal [1], we worked out a quick and fairly precise analytical method for the estimation of the mentioned compounds mainly in their mixtures [2]. This Polaro graphie method was based on different reactivity of the studied compounds with primary amines. Because the mentioned compounds are significant and frequently occur in mixtures, we looked for another, purely chemical method of their determination side by side. -
Hematoxylin Formulae
Hematoxylin Formulae Bryan D Llewellyn Produced for distribution through StainsFile The Internet Resource For Histotechnologists http://stainsfile.info This document includes formulae for the alum and iron hematoxylin solutions included on the StainsFile Internet site. Some of these are no longer in use, and others are variations of other, more common, formulae. I have included a dis- cussion of the relationship between the dye and the mordant, and how the rela- tionship between them affects the staining character of a formula. The formulae have been collected from several sources, including older reference texts and the Internet. If any reader knows of a hematoxylin formula not listed in this document, I would most appreciate receiving details so that it may be included in the future. I may be contacted by e-mail through the StainsFile Internet site. Bryan D. Llewellyn October, 2013 October 2013 1.0 Initial document This document may be freely reproduced and distributed for educational pur- poses provided that the text is unchanged and no charge is made. Commercial distribution is not permitted. October, 2013. © 2013, Bryan D. Llewellyn. Table of Contents Hematoxylin and Hematein ............... 4 Oxidation ........................................... 6 Mordant ............................................. 9 Reactions With Tissue ...................... 12 Staining Mucin ................................... 13 Dye:Mordant Ratio ............................ 14 Acids ................................................. 19 Differentiation ................................... -
1. Give the Correct Names for Each of the Compounds Listed Below. A
1. Give the correct names for each of the compounds listed below. a) NaCl sodium chloride n) ZrS2 zirconium sulfide b) FrBr francium bromide o) AgI silver iodide c) KF potassium fluoride p) BaSe barium selenide d) RaS radium sulfide q) MgO magnesium oxide e) LiI lithium iodide r) LaBr3 lanthanum bromide f) Li3N lithium nitride s) Sr3N2 strontium nitride g) AlBr3 aluminum bromide t) Cd3As2 cadmium arsenide h) CdCl2 cadmium chloride u) Rb2Se rubidium selenide i) K2O potassium oxide v) Rb3N rubidium nitride j) InF3 indium fluoride w) BaF2 barium fluoride k) ZnO zinc oxide x) ZrTe2 zirconium telluride l) Y2O3 yttrium oxide y) Cs3P cesium phosphide m) CaTe calcium telluride z) Y2O3 yttrium oxide 2. Write the correct chemical formula for each of the following compounds. a) potassium bromide KBr n) potassium nitride K3N b) zinc bromide ZnBr2 o) aluminum bromide AlBr3 c) lithium iodide LiI p) zinc phosphide Zn3P2 d) scandium chloride ScCl3 q) magnesium sulfide MgS e) magnesium chloride MgCl2 r) hafnium chloride HfCl4 f) magnesium oxide MgO s) barium sulfide BaS g) hydrogen sulfide H2S t) tantalum oxide Ta2O5 h) gallium iodide GaI3 u) zirconium nitride Zr3N4 i) sodium oxide Na2O v) potassium selenide K2Se j) magnesium selenide MgSe w) germanium fluoride GeF4 k) calcium fluoride CaF2 x) francium phosphide Fr3P l) aluminum oxide Al2O3 y) zinc arsenide Zn3As2 m) beryllium chloride BeCl2 z) scandium telluride Sc2Te3 L. h. s. – Chemistry – Nomenclature – Answers – Page 1 3. Give the correct names for each of the compounds listed below. a) CaSO4 calcium