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+ A Zn-SnO2 Cd-SnO2 + 5 µm NSF 2011 NSEC Grantees Conference Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Chad A. Mirkin, Director Milan Mrksich, Associate Director Northwestern University International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Center Vision Knowledge Creation Unique Sub-100 nm Surface Patterning Capabilities NSEC for Integrated Design & Fabrication of Nanoscale Experiments, Nanopatterning and Soft Nanostructures Theory and Engineering Detection Technologies Integrated Research New Detection Technologies Nanostructure Characterization New Educational Paradigms International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Synergistic Team 10 mi NU UIUC ANL UC 80 mi International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Mission To advance discovery and knowledge within the field of nanotechnology through focused and collaborative research leading to the development of powerful new biological and chemical detection systems that have the potential to revolutionize many diverse fields. This research forms the foundation for, and is effectively integrated with, innovative and diverse educational outreach programs that seek to inform, engage, and inspire people of all ages and broaden the participation of underrepresented minorities. International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Participating PIs by Department Biochemistry Chemical and Biological Medicine Stephen Sligar, UIUC-JA Engineering Thomas Meade, JA Thomas Meade, JA Chad A. Mirkin, JA Chad Mirkin, JA Justin Notestein Stephen Sligar, UIUC-JA Biomedical Engineering Monica Olvera de la Cruz, JA Samuel Stupp, JA Chad Mirkin, JA Electrical Engineering and Medicine – Infectious Diseases Chemistry Computer Science Steven Wolinsky Franz Geiger Matthew Grayson Mark Hersam, JA Chang Liu, JA Medicine - Urology Brian Hoffman, JA C. Shad Thaxton Joseph Hupp Kellogg School of Mgmt Mercouri Kanatzidis Barry Merkin Neurobiology and Physiology Thomas Meade William Klein Materials Science and Engineering Chad Mirkin Thomas Meade, JA Michael Bedzyk Milan Mrksich, UC Vinayak Dravid Physical Science SonBinh Nguyen Mark Hersam Michael Davis, HWC Teri Odom Jiaxing Huang Monica Olvera de la Cruz, JA Physics and Astronomy Lincoln Lauhon George Schatz Michael Bedzyk, JA Chad Mirkin, JA Tamar Seideman Donald Ellis Teri Odom, JA Stephen Sligar, UIUC, JA John Ketterson Monica Olvera de la Cruz J. Fraser Stoddart David Seidman Weinberg College Writing Program Samuel Stupp, JA Samuel Stupp John Anderson Richard Van Duyne Civil and Environmental Mechanical Engineering Engineering Cate Brinson 181 FTE graduate students Kimberly Gray Horacio Espinosa 53 graduate student fellowships Chang Liu, JA Medical Humanities and Ethics 114 FTE postdocs Wing Kam Liu Laurie Zoloth Jane Wang International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Research Objectives . Develop a suite of high throughput, parallel nanolithography tools with soft matter compatibility for patterning materials on surfaces with sub-100 nm spatial resolution and evaluate their potential for building the targeted devices. Develop detection systems with novel receptors and signal transduction methods made possible through the development of these novel lithographic tools and related nanostructures. International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Strategic Framework I – Versatile Parallel Nanolithography Tool Versatile chemistry On-chip DNA and Nanolithography integration with & materials research peptide synthesis complementary fabrication techniques tool system Coupled nanotechnology Multiplexed ink research/manufacturing systems deposition for DNA and protein arrays Technology Integration DPN probes with integrated Inking channels; Integrated ink wells and stamp pads; Lithography software development Multimode lithography 1-dimensional passive and active probes Multi-valency site 2-dimensional passive and active probes recognition and assembly Alignment sensors Technology Base Development of routine chemistry and Development of inks, low wear tip coatings, methods for fabricating combinatorial and alignment strategies in the context of nanostructure libraries multiple tip arrays Development of methods for structural and spectroscopic characterization of lithographically generated nanostructures Knowledge Base 1 million pen Optimized active Fabrication of Integration of 1 million pen passive writing probe actuation: combinatorial nanolithography tool with active writing with multiplexed Pneumatics and Polyvalent recog- larger scale fabrication with multiplexed Inking piezoelectrics nition nanopatterns techniques inking Year 6 Year 7 Year 8 Year 9 Year 10 International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Strategic Framework II – Integrated Point-of-Care Device Multiplexed HIV detection AD detection panel assay based upon Sepsis detection using bio-barcodes, with using bio-barcodes in patient onboard electrophoretic capabilities samples LSPR and barcodes Multiplexed protein, Small molecule/Raman integrated detection DNA, and RNA detection with onboard sample processing Technology Integration Integrated microfluidics and electrophoresis Single particle plasmonic sensors “The breadboard” Nanomaterials for amplification Nanopatterning for electrical detection Quantification of photonic Universal probe design sensors and barcode assays Technology Base Bio-barcode detection uses nanoparticle Electrochemical detection uses polymer enhanced equilibrium to beat conventional amplification sensing limits Enhanced Raman sensing and allosteric Nanodisc receptors provide new amplification enables molecule-specific functionality to membrane bound proteins detection of small molecule targets Knowledge Base • Intracellular Raman • Dye-enhanced LSPR • Plasmon wire sensing • Plasmon-enhanced sensing • Plasmon-enhanced • Polymer-electro- SHG probes • Integrated photonic/ • Detection of 20+ different diffraction chemical probes • Detection of 10 different plasmonic sensors targets with BCA sensor • Plasmon-enhanced • Nanoporous materials targets with BCA • Single particle Raman • Semiconductor light MALDI-TOF for small-molecule • Photonic arrays for sensing sources integrated with • Multiplexing BCA sensing SERS metal plasmonics Year 6 Year 7 Year 8 Year 9 Year 10 International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Synergistic Research Groups Nanopatterning SRG Leader: Mark Hersam Co-Leader: Teri Odom Signal Transduction & Receptor Design SRG Leader: Milan Mrksich Co-Leader: George Schatz Integrated Biodetection Chip SRG Leader: Vinayak Dravid Co-Leader: Chang Liu International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Notable Research Accomplishments Fundamentals of Patterning in 2001 State-of-the-art available in 2001 . Dip-pen Nanolithography (DPN) . Microcontact Printing (μCP) . Nanoimprint Lithography . Nanosphere Lithography (NSL) Parallel DPN using two-pen cantilever and single feedback . Feedback Controlled Lithography (FCL) . Conventional (Photolithography, EBL) 93 nm Nanosphere Lithography (NSL) International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Notable Research Accomplishments Fundamentals of Patterning in 2010 New Techniques and Advanced Fabrication Methods Dip-pen Nanolithography Microcontact Printing Nanoimprint Lithography Nanosphere Lithography Feedback Controlled Lithography Photolithography Polymer Pen Lithography Liquid Phase Multi-Step FCL Electrochemical DPN Nanolithography Liquid Phase Nanolithography Field Induced Oxidation Soft Interference Lithography Cathodic Electrografting Laser-assisted Embossing Soft E-Beam Lithography PEEL (Phase-shifting photolithography, Etching, Electron-beam deposition, Lift-off) 1.3 Million Probe 2-D Passive Array International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Notable Research Accomplishments Fundamentals of Patterning in 2010 New Substrates, Surface Chemistries, and Materials 100 nm 40nm 4mm 290 nm Sol Gel Templates DNA and Protein Nanoarrays Complex Shapes ssDNA-CNT on Si(111):H 290 nm 500 nm Cylindrical Nanostructures Conducting Polymers Polymer Brushes 65 nm PZT 55 nm 1 mm 500 nm Silicon Nanostructures Single Nanoparticles Multifunctional Oxides International Institute for Nanotechnology Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies Northwestern University Notable Research Accomplishments Fundamentals
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