Catalog of GOO Chemical Cosmetics Materials

Personal Care Product Catalogue For Cosmetics

Head Oﬃce 58, Ijiri, Iseda-cho, Uji-shi, Kyoto, Japan 611-0043 TEL：+81-774-46-7777（General） FAX：+81-774-43-3552

Performance Chemicals Division TEL：+81-774-44-8408（Direct Line） FAX：+81-0774-44-0497

この印刷製品は、環境に配慮した工場で製造されています。 17-05-2000 P-D10004 ©May, 2017 This publication was produced May, 2017. Speciﬁcations are subject to change without prior notice. 本社・本社工場 From Classic to Advance Innovative Cosmetic Ingredients for All １．Polymers for Hair Styling

１．１．Polymers for Aerosol Sprays and Mists (Anionic Acrylic Polymers)

Plascize L-9909

Features ：Ultra hard, long lasting and easy wash-oﬀ INCI Name ：AMP-ACRYLATES/C1-18 ALKYL ACRYLATE/C1-8 ALKYL ACRYLAMIDE COPOLYMER

Plascize L-9900

Features ：Ultra hard, long lasting, easy wash-oﬀ and strong hair-cohesion INCI Name ：AMP-ACRYLATES/C1-18 ALKYL ACRYLATE/C1-8 ALKYL ACRYLAMIDE COPOLYMER

Plascize L-9540 GOO Chemical’s Polymers for Personal Care Features ：Ultra hard, long lasting and strong hair-cohesion INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER CONTENTS Plascize L-9600U

Page No. Features ：Ultra hard and strong hair-cohesion 1．Polymers for Hair Styling 2 INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER

Evaluation of Hair Spray ■ 1． 1 Polymers for Aerosol Sprays and Mists 2 Plascize L-9715 ■ 1．2 Non-Neutralized Polymer 2 Features ：Hard but ﬂexible and long lasting ■ 1．3 Polymers for Mousses and Mists 3 INCI Name ：AMP-ACRYLATES/C1-18 ALKYL ACRYLATE/C1-8 ALKYL ACRYLAMIDE COPOLYMER, TRIETHYLHEXANOIN, HYDROGENATED POLYISOBUTENE, POLYSILICONE-13 2．Adhesive Polymers 4 ■Example Formulation

Hair Spray Hair Mist 3．Polymers for Personal Cleansing Agents 5 (Hard Type) (Hard Type)

Plascize L-9000 Series 10 10 4．Polymer for Hair Treatment 7 Plascize L-301 0.05 － CETRIMONIUM CHLORIDE － 0.1

ALCOHOL 44.95 74.9 5．Polymers for Temporary Hair Coloring 8 WATER － 15

LPG 45 － 6．Acrylic Oligomers 8 Total 100 100 Curl Retention

7．Oily Agents for Cosmetics 8

(Anionic Acrylic Polymer) 8．Products Summary and Suitable Applications 9 １．2．Non-Neutralized Polymer

Plascize L-53

Features ：Amazing water-resistant but water-soluble after neutralization INCI Name ：ACRYLATES/DIACETONEACRYLAMIDE COPOLYME

1 2 １．Polymers for Hair Styling

１．１．Polymers for Aerosol Sprays and Mists (Anionic Acrylic Polymers)

Plascize L-9909

Features ：Ultra hard, long lasting and easy wash-oﬀ INCI Name ：AMP-ACRYLATES/C1-18 ALKYL ACRYLATE/C1-8 ALKYL ACRYLAMIDE COPOLYMER

Plascize L-9900

Features ：Ultra hard, long lasting, easy wash-oﬀ and strong hair-cohesion INCI Name ：AMP-ACRYLATES/C1-18 ALKYL ACRYLATE/C1-8 ALKYL ACRYLAMIDE COPOLYMER

Page No. Features ：Ultra hard and strong hair-cohesion 1．Polymers for Hair Styling 2 INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER

Hair Spray Hair Mist 3．Polymers for Personal Cleansing Agents 5 (Hard Type) (Hard Type)

Plascize L-9000 Series 10 10 4．Polymer for Hair Treatment 7 Plascize L-301 0.05 － CETRIMONIUM CHLORIDE － 0.1

ALCOHOL 44.95 74.9 5．Polymers for Temporary Hair Coloring 8 WATER － 15

LPG 45 － 6．Acrylic Oligomers 8 Total 100 100 Curl Retention

7．Oily Agents for Cosmetics 8

(Anionic Acrylic Polymer) 8．Products Summary and Suitable Applications 9 １．2．Non-Neutralized Polymer

Plascize L-53

Features ：Amazing water-resistant but water-soluble after neutralization INCI Name ：ACRYLATES/DIACETONEACRYLAMIDE COPOLYME

1 2 １．Polymers for Hair Styling 2．Adhesive Polymers (Non-Ionic Acrylic Polymers) １．3．Polymers for Mousses and Mists (Anionic Acrylic Polymers) Plascize L-2700 Features ：Forms soft film, suitable for re-styling hair products without plasticizers Features ：Ultra Hard, dry finishing and long lasting Plascize L-6330 INCI Name ：DIMETHYLACRYL AMIDE/HYDROXYETHYL INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER ACRYLATE/METHOXYETHYL ACRYLATE COPOLYMER Plascize L-6466 Features ：Hard, strong hair-cohesion INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER Plascize L-2714 Features ：Forms softer and more sticky film than Plascize L-2700 INCI Name ：DIMETHYLACRYL AMIDE/HYDROXYETHYL ACRYLATE/METHOXYETHYL ACRYLATE COPOLYMER Plascize L-6740 Features ：Relatively soft and natural finishing INCI Name ：AMP-ACRYLATES/C1-18 ALKYL Features ：Forms sticky film of moderate tack. The degree of ACRYLATE/C1-8 ALKYL ACRYLAMIDE Plascize L-2200 film stickiness is between L-2700 and L-2714 COPOLYMER INCI Name ：HYDROXYETHYL/METHOXYETHYL ACRYLATE COPOLYMER

Styling Products with Plascize L-2000 Series Oligomer Stickiness Oily Base

4 Anionic Hair-setting Polymer

Hard Plascize L-2700

3 Plascize L-2200 Styling Products with Plascize L-2714

Polymer and Plasticizer 2 Re-styling Ability Load(N)

Evaluation of Hair Mist Curl Retention 1 Soft Type Hard Type Styling Products Styling Products ■Example Formulations 0 0 50 100 150 200 Styling Mist Hair Mist Styling Styling Mousse Hair Mousse Ratio of Distorsion(%) (Regular Type) (Hard Type) Mousse (Soft Type) (Treatment Type) Initial Setting Ability Load-following Plascize L-6330 15 12 12 Plascize L-6740 7.5 2.5

Plascize L-301 － 0.3 － POLYSORBATE 60 0.3 0.2 Schematic of Concept CETRIMONIUM CHLORIDE 0.15 － 0.225 DIMETHICONE 0.2 － Bending Test of Hair Bundles Coated with Each Polymer

POLYSORBATE 60 －－ 0.225 PEG-9 DIMETHICONE 0.6 0.2 ■Example Formulations ALCOHOL 69.35 72.4 9.0 HYDROLYZED COLLAGEN － 1 Hair Spray Styling Hair Spray Styling Styling Mist Styling Gel DIGLYCERIN 0.5 －－ ALCOHOL 10 10 (Re-Stylable) Mousse (Re-Stylable) Mousse (Re-Stylable)

DIPHENYL DIMETHICONE － 0.3 － WATER 73.4 78.1 Plascize Plascize L-2200 7.5 9 12.5 4.29 5.14 2.86 L-2700／L-2714 WATER 15 15 68.55 LPG 8 8 POLYSORBATE 60 － 0.225 － POLYSORBATE 60 － 0.225 － LPG －－ 10 Total 100 100 ALCOHOL 52.5 5.4 50 ALCOHOL 55.71 9 10 Total 100 100 100 BUTYLENE GLYCOL －－ 1 ACRYLATES/C10-30 ALKYL －－ 0.5 ACRYLATE CROSSPOLYMER WATER － 75.375 36.5 Spray (VOC 55%) TRIETHANOLAMINE －－ 1 LPG － 10 － Plascize L-6330 16.7 BUTYLENE GLYCOL －－ 5 DME 40 －－ ALCOHOL 17.4 WATER － 75.635 80.64 Total 100 100 100 WATER 35.9 LPG 40 10 － DME 30 Total 100 100 100 Total 100

3 4 １．Polymers for Hair Styling 2．Adhesive Polymers (Non-Ionic Acrylic Polymers) １．3．Polymers for Mousses and Mists (Anionic Acrylic Polymers) Plascize L-2700 Features ：Forms soft film, suitable for re-styling hair products without plasticizers Features ：Ultra Hard, dry finishing and long lasting Plascize L-6330 INCI Name ：DIMETHYLACRYL AMIDE/HYDROXYETHYL INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER ACRYLATE/METHOXYETHYL ACRYLATE COPOLYMER Plascize L-6466 Features ：Hard, strong hair-cohesion INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER Plascize L-2714 Features ：Forms softer and more sticky film than Plascize L-2700 INCI Name ：DIMETHYLACRYL AMIDE/HYDROXYETHYL ACRYLATE/METHOXYETHYL ACRYLATE COPOLYMER Plascize L-6740 Features ：Relatively soft and natural finishing INCI Name ：AMP-ACRYLATES/C1-18 ALKYL Features ：Forms sticky film of moderate tack. The degree of ACRYLATE/C1-8 ALKYL ACRYLAMIDE Plascize L-2200 film stickiness is between L-2700 and L-2714 COPOLYMER INCI Name ：HYDROXYETHYL/METHOXYETHYL ACRYLATE COPOLYMER

Styling Products with Plascize L-2000 Series Oligomer Stickiness Oily Base

4 Anionic Hair-setting Polymer

Hard Plascize L-2700

3 Plascize L-2200 Styling Products with Plascize L-2714

Polymer and Plasticizer 2 Re-styling Ability Load(N)

Plascize L-301 － 0.3 － POLYSORBATE 60 0.3 0.2 Schematic of Concept CETRIMONIUM CHLORIDE 0.15 － 0.225 DIMETHICONE 0.2 － Bending Test of Hair Bundles Coated with Each Polymer

3 4 3．Polymers for Personal Cleansing Agents（Amphoteric and Cationic Polymers） Hair Shampoo Conditioner ■Features ■Features

： Performances Performances Plascize L-410W Features Gives ﬁneness and resilience to foams of various cleansing Property of Smoothness Smoothness Feeling after formulations, fast rinsing and refreshing ﬁnish Gloss Smoothness Feeling Foam in foaming in Rinsing Finishing INCI Name ：POLYQUATERNIUM-50 Plascize Fast Foaming Plascize Fair Fair Refreshed Excellent Excellent Supple L-410W Extremely Fine L-402W

Plascize Slightly Plascize Very Fine Fair Fair Good Fair Stiﬀ L-402W Moistured L-450／L-450W Features ：Gives softness, smoothness and excellent gloss to Plascize L-402W Plascize Soft Excellent Excellent Moisturized treated hair L-440 ／ L-440W

INCI Name ：POLYQUATERNIUM-50 Plascize Bouncy and Fine Fair Fair L-450 ／ L-450W Firm

Plascize L-440 Features ：Gives amazing smoothness to Shower Gel silicone-free shampoos both in ■Features washing and in rinsing Performances INCI Name ：POLYQUATERNIUM-49 Property of Ease of Feeling after Foam Rinsing Finishing

Plascize Resilient Excellent Refreshed L-410W Creamy and Fine Plascize L-440W Features ：Water-based Plascize L-440 Plascize Resilient Good Moisturized INCI Name ：POLYQUATERNIUM-49 L-440 ／ L-440W

Plascize Soft Excellent Fair L-450 ／ L-450W Hair Bundles Treated with Conditioners （Left: No Additive; Right: Containing L-450） Plascize L-450 Features ：Gives body and strength to treated hairs, so-called ridgide-effect which ■Compatibility of Plascize L-440 with Anionic Surfactants leads to volumizing effect Plascize L-440（1.5%） Anionic INCI Name ： Sodium Laureth Sulfate Sodium Laureth-4 Carboxylate Sodium C14-16 Olefin Sulfonate POLYQUATERNIUM-48 Surfactant (10%)

Cocamidopropyl 0% 3% 5% 7% 0% 3% 5% 7% 0% 3% 5% 7% Betaine

Appearance C C C B C A A A A B A A Plascize L-450W Features ：Water-based Plascize L-450 INCI Name ：POLYQUATERNIUM-48 Plascize L-440（1.5%）

Anionic TEA-Lauroyl Sarcosinate Sodium Lauroyl Aspartate Sodium Cocoyl Glutamate Surfactant (10%) Features Cocamidopropyl 0% 3% 5% 7% 0% 3% 5% 7% 0% 3% 5% 7% Hair Shampoo Conditioner Shower Gel Betaine

◎ ◎ Appearance C A A A A A A A B A A A Plascize L-410W ○ Fine Foam Fine Foam A: Transparent B: Translucent C: Aggregation ◎ Plascize L-402W ○ ○ Softness Gloss

Plascize ◎ ○ ○ L-440／L-440W Smoothness

Plascize ◎ ◎ ○ L-450／L-450W Ridge Eﬀect Ridge Eﬀect

After 10 minutes Load(mN)

Foams of Potassium Soap

No additives Additives(0.5% solid) (Left: No Additive; Right: Containing L-410W)

Load Test in Squashing Foams (Index of Resilience of Foams) (Potassium Soap, at 25℃)

5 6 3．Polymers for Personal Cleansing Agents（Amphoteric and Cationic Polymers） Hair Shampoo Conditioner ■Features ■Features

INCI Name ：POLYQUATERNIUM-50 Plascize Bouncy and Fine Fair Fair L-450 ／ L-450W Firm

Cocamidopropyl 0% 3% 5% 7% 0% 3% 5% 7% 0% 3% 5% 7% Betaine

Appearance C C C B C A A A A B A A Plascize L-450W Features ：Water-based Plascize L-450 INCI Name ：POLYQUATERNIUM-48 Plascize L-440（1.5%）

◎ ◎ Appearance C A A A A A A A B A A A Plascize L-410W ○ Fine Foam Fine Foam A: Transparent B: Translucent C: Aggregation ◎ Plascize L-402W ○ ○ Softness Gloss

Plascize ◎ ○ ○ L-440／L-440W Smoothness

Plascize ◎ ◎ ○ L-450／L-450W Ridge Eﬀect Ridge Eﬀect

After 10 minutes Load(mN)

Foams of Potassium Soap

No additives Additives(0.5% solid) (Left: No Additive; Right: Containing L-410W)

Load Test in Squashing Foams (Index of Resilience of Foams) (Potassium Soap, at 25℃)

5 6 4．Polymer for Hair Treatment (Cationic Acrylic Polymer) 5．Polymers for Temporary Hair Coloring (Anionic Acrylic Polymers)

Plascize L-514 Features ：Plascize L-514 gives moderate strength Plascize L-53DCU Features ：Binder polymer for pigment dispersions, excellent rub- and water-resistance and volumizing effect to hair, tames cuticles INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER and makes damaged hair smoother. It also helps to protect the coloured hair from Plascize L-75CBU Features ：Binder polymer for pigment dispersions, excellent flexibility decolouration. INCI Name ：AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER INCI Name ：POLYQUATERNIUM-99 Plascize L-53/L-75 Color Pastes (Ready-Mix of Binder polymer and Color Pigments) ■Sample Formulation Plascize L-53/L-75 BLACK, BROWN, UMBER, RED, YELLOW and BLUE (Six colors available) After Bath Treatment Comment (Mist Type) Finishing Touch* Slightly hard and supple Plascize L-514 10 Flaking* Very Good Color Pastes EU Grade (Made from Color Pigments Suitable for the EU regulations) ALCOHOL 78.5 Wash Ability* Withstands 20 wash cycles Plascize L-53 BLACK F, UMBER EUR, RED EU WATER 10 Film Hardness** On the soft side, durable GLYCERIN 1 Water Resistance** Excellent CYCLOPENTASILOXANE 0.5 * Evaluation is based on sensory test after the example Total 100 mist is dried ** The film test is done on film of approx.100 μm 6．Acrylic Oligomers (Non-Ionic Acrylic Oligomers)

Plascize L-301 Features ：Liquid polymer which does not form ﬁlm. Uses as a plasticizer or base ingredient for hair liquid (light ﬁnishing in hair styling). INCI Name ：HYDROXYETHYL/METHOXYETHYL ACRYLATE/BUTYL ACRYLATE COPOLYMER

Plascize L-222 Features ：Liquid polymer which does not form film. Uses as a plasticizer or base ingredient Hair without Treatment for hair cares (light finishing in hair styling and easy wash-off). Non-coated L-514-coated INCI Name ：HYDROXYETHYL/METHOXYETHYL Original Hair Dyed After Immersion ACRYLATE COPOLYMER in De-coloring Agent

De-coloring Test: Hair bundles non-treated and treated with the L-514-containing mist were immersed in de-coloring agent for 12 hors. Improvement in cuticle (Phosphatic Polymers) peelings 7．Oily Agents for Cosmetics

Parlon EP-77 Features ：Base ingredient for hair liquid or oily agents for hair cares, provides glossy ﬁnish to hair INCI Name ：PPG-25 BUTYL ETHER PHOSPHATE Hair Treated with L-514

Gelasol E-50 Features ：Provides smoothness and glossy ﬁnish, oily gelling agent for O/W formulations INCI Name ：OLETH-20 PHOSPHATE

7 8 4．Polymer for Hair Treatment (Cationic Acrylic Polymer) 5．Polymers for Temporary Hair Coloring (Anionic Acrylic Polymers)

Parlon EP-77 Features ：Base ingredient for hair liquid or oily agents for hair cares, provides glossy ﬁnish to hair INCI Name ：PPG-25 BUTYL ETHER PHOSPHATE Hair Treated with L-514

Gelasol E-50 Features ：Provides smoothness and glossy ﬁnish, oily gelling agent for O/W formulations INCI Name ：OLETH-20 PHOSPHATE

7 8 8．Products Summary and Suitable Applications

Applications Applications

Active Active Category Product Name Ionicity Ingredient Solvent Category Product Name Ionicity Ingredient Solvent (wt%) (wt%) Aerosol Spray Mousse Mist Gel Hair Wax Shampoo Shower Gel Treatment Conditioner Make-Up Skin Care Aerosol Spray Mousse Mist Gel Hair Wax Shampoo Shower Gel Treatment Conditioner Make-Up Skin Care

Plascize Polymer for Plascize Anionic 40 Ethanol ● ● ● ● ● ● Cationic 30 Ethanol ● ● ● L-9909 Hair Treatment L-514

Plascize Plascize Anionic 40 Ethanol ● ● ● Anionic 50 Ethanol L-9900 Polymers for L-53DCU ● ● ● ● Temporary Plascize Anionic 40 Ethanol ● ● ● ● ● ● ● Hair Coloring Plascize L-9540B Anionic 50 Ethanol L-75CBU ● ● ●

Plascize Anionic 40 Ethanol ● ● ● Plascize L-9600U Non-ionic 90 Ethanol L-301 ● ● ● ● Polymers for Acrylic Plascize Hair Styling Anionic 40 Ethanol Oligomers L-9715 ● ● ● Plascize Non-ionic 90 Ethanol L-222 ● ● ● ● ● Plascize Anionic 50 Ethanol ● ● ● ● ● L-53 Parlon Anionic 100 － EP-77 ● ● ● ● ● ● Plascize Oily Agents Anionic 30 Ethanol/Water ● ● ● ● ● ● for Cosmetics L-6330 Gelasol Anionic 100 － E-50 ● ● ● ● Plascize Anionic 40 Ethanol/Water L-6466 ● ● ● ● Acrylic Oligomers that do not contain ethanol are available as trial products upon request. Plascize For details, please contact our sales representatives. Anionic 40 Ethanol L-6740 ● ● ● ●

Plascize Non-ionic 70 Ethanol ● ● ● ● ● ● ● L-2700 Color Pastes ■Plascize L-53/L-75 Color Pastes Adhesive Plascize Non-ionic 70 Ethanol ● ● ● ● ● Polymers L-2714 Binder CARBON Grade ALCOHOL CI 12315 CI 21090 CI 74160 polymer BLACK Plascize Non-ionic 40 Ethanol/Water L-2200 ● ● ● ● ● BLACK CA 22% 70% 8% －－－

Plascize BROWN A 21% 69% 1% 6% 3% － Amphoteric 30 Water * L-410W ● ● ● ● ● ● ● UMBER A 21% 69% 1% 3% 6% － Plascize Amphoteric 30 Water * L-402W ● ● ● ● ● ● ● RED A 21% 69% － 10% －－

Plascize Amphoteric/ YELLOW A 21% 69% －－ 10% － Polymers for 30 Ethanol/Water L-440 Cationic ● ● ● ● ● ● ● Personal BLUE A 21% 69% －－－ 10% Cleansing Plascize Amphoteric/ Agents 30 Water * L-440W Cationic ● ● ● ● ● ● ● ■Plascize L-53 Color Pastes EU Grade Plascize Amphoteric/ 40 Ethanol/Water ● ● ● ● ● ● ● ● Binder BLACK 2 RED 30 YELLOW 5 LAKE L-450 Cationic Grade ALCOHOL polymer CI 77266 CI 73360 CI 19140 Plascize Amphoteric/ 40 Water * BLACK F 22% 70% 8% －－ L-450W Cationic ● ● ● ● ● ● ● ●

UMBER EUR 21% 69% 1% 3% 6% ＊Containing phenoxyethanol as preservatives

Water-based products of Polymers for Hair Styling and Adhesive Polymers are available RED EU 21% 69% － 10% － upon requests. For details, please contact our sales representatives.

9 10 8．Products Summary and Suitable Applications

Applications Applications

Plascize Polymer for Plascize Anionic 40 Ethanol ● ● ● ● ● ● Cationic 30 Ethanol ● ● ● L-9909 Hair Treatment L-514

UMBER EUR 21% 69% 1% 3% 6% ＊Containing phenoxyethanol as preservatives

Water-based products of Polymers for Hair Styling and Adhesive Polymers are available RED EU 21% 69% － 10% － upon requests. For details, please contact our sales representatives.

9 10 Personal Care Product Catalogue For Cosmetics

Head Oﬃce 58, Ijiri, Iseda-cho, Uji-shi, Kyoto, Japan 611-0043 TEL：+81-774-46-7777（General） FAX：+81-774-43-3552

Performance Chemicals Division TEL：+81-774-44-8408（Direct Line） FAX：+81-0774-44-0497

To Whom May It Concern:

Revision for “Product Catalogue for Cosmetics” published at May 2017

Revised Part

Composition Lists of Color Pastes at page 10

Revised Contents

Plascize L-53/L-75 Color Pastes Binder Carbon Red 30 Yellow 12 Blue 404 Grade Alcohol polymer Black CI 73360 CI 21090 CI 74160 BLACK CA 22% 70% 8% - - - YELLOW A 21% 69% - - 10% - BLUE A 21% 69% - - - 10% 226 BROWN 21% 69% 1% 6% 3% - 226 UMBER 21% 69% 1% 3% 6% -

Plascize L-53 Color Pastes EU Grade Binder Black 2 Red 30 Yellow 5 Lake Grade Alcohol Polymer CI 77266 CI 73360 CI 19140 BLACK F 22% 70% 8% - - UMBER EUR 21% 69% 1% 3% 6% RED EUK 21% 69% - 10% -

Plascize L-75 Color Paste EU Grade Binder Black 2 Red 30 Grade Alcohol Polymer CI 77266 CI 73360 BLACK F 22% 70% 8% - RED EUK 21% 69% - 10%