Hazardous Materials Descriptions and Proper Shipping Names PSN UN/NA
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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
University of Groningen Reduction of Aldehydes and Ketones by Sodium Dithionite Vries, Johannes G. De
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by University of Groningen University of Groningen Reduction of Aldehydes and Ketones by Sodium Dithionite Vries, Johannes G. de; Kellogg, Richard M. Published in: Journal of Organic Chemistry DOI: 10.1021/jo01309a011 IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below. Document Version Publisher's PDF, also known as Version of record Publication date: 1980 Link to publication in University of Groningen/UMCG research database Citation for published version (APA): Vries, J. G. D., & Kellogg, R. M. (1980). Reduction of Aldehydes and Ketones by Sodium Dithionite. Journal of Organic Chemistry, 45(21), 4126-4129. https://doi.org/10.1021/jo01309a011 Copyright Other than for strictly personal use, it is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license (like Creative Commons). Take-down policy If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. Downloaded from the University of Groningen/UMCG research database (Pure): http://www.rug.nl/research/portal. For technical reasons the number of authors shown on this cover page is limited to 10 maximum. Download date: 12-11-2019 4126 J. Org. Chem. 1980,45,4126-4129 Reduction of Aldehydes and Ketones by Sodium Dithionite Johannes G. -
The Journal of Organic Chemistry 1959 Volume 24 No.8
THE JOURNAL OF Organic Chemistry © Copyright 1959 Volume 24, Number 8 by the American Chemical Society August 31, 1959 [Contribution from th e C hem istry D epartm ent of Syracuse U n iversity ] Condensation of Thiophenols and Formaldehyde with Some Aromatic Amines GERALD F. GRILLOT and ROBERT E. SCHAFFRATH Received September 85, 1958 N-Arylaminomethyl aryl sulfides and l,3,5-triaryl-l,5-dithia-3-azapentanes have been prepared by condensing primary aromatic amines with formaldehyde and thiophenols. A-Methylanilines condense with formaldehyde and thiophenols to form Ar-methyl-Ar-arylaminomethyl aryl sulfides. Two arylaminoethy 1 aryl sulfides were prepared by condensing 0-chloroethylaniline with the sodium salt of the thiophenol. Basicities of these arylaminoalkyl aryl sulfides have been related to (a) the presence of electrophilic substituents attached to the aryl groups and (b) the number of carbon atoms separating the nitrogen and sulfur atoms. Recently Grillot et a l.1 have demonstrated that Whereas primary aliphatic amines generally the thiophenols condense with secondary aliphatic give a mixture of secondary and tertiary amines in amines and formaldehyde to form dialkylamino- the Mannich reaction, primary aromatic amines methyl aryl sulfides similar in structure to the can be condensed with thiophenols and formalde dialkylaminomethyl alkyl sulfides prepared by hyde in a 1:1:1 mole ratio to give almost exclusively McLeod and Robinson2 3by condensing aliphatic moderately stable usually crystalline W-arylamino- mercaptans with aliphatic -
Pepper Spray Evaluation Project
If you have issues viewing or accessing this file, please contact us at NCJRS.gov. L~ Pepper Spray Evaluation Project Results of the Introduction of Oleoresin Capsicum (OC) into the Baltimore County, MD, Police Department ~QCIATIONose ' I ~ S~NCF.~s93 I June 21, 1995 I Final Report Prepared for: i National Institute of Justice i ! U.S. Department Of Justice I F IACP PROJECT STAFF I r"" Daniel N. Rosenblatt Executive Director I pRINCIP/~L PROJECT STAFF Jerome A. Needle Director, Programs and Research I John Firman Report Coordinator Charles E. I-Iigginbotham Director, Information and Services John Granfield Project Manager I Steven M. Edwards Research Consultant Jami Long-Onnen On-Site Research Coordinator I! Lynne Hargest Project Specialist i PROJECT SUPPORT Dawn Phoubandith Report Editor I Katherine Spivey Assistant Editor Carolyn Cockroft Staff Specialist Edmund J. Kelly Support Specialist I: Tony Occhiuzzo Staff Specialist Lt. Roger Gross Visiting Fellow Lara Walker Editorial Assistant I David Bright Research Assistant I I I.... I r-- TABLE OF CONTENTS I' " Page Acknowledgments i Executive Summary i I Introduction 1 L Literature Review 2 i Chloroacetophenone (CN) 2 Ochlorobenzylidene-Malononitrile (CS) 4 I Oleoresin Capsicum 6 IL Research Setting 10 1 BCPD Interest in a Force Alternative 11 I IIL Project Methodology 12 Process Evaluation 12 I Outcome Methodology 12 Development of the Measurement Instruments 13 ! Data Limitations 16 ! IV. Findings: Outcome Evaluation 18 Overview Analysis 18 Reasons/Use of Spray 21 ! Application of OC on Animals 44 Summary of Outcome Data 44 Findings Regarding the Five Principle Questions 48 I v. Findings: Process Evaluation 51 I Training Issues 51 BCPD Training 53 Decontamination/First Aid 54 I Standard Operating Procedure 54 Use-of-Force Issues 55 Reporting the Use of OC as a Use of Force 56 I Police Use of Deadly Force in Defense of OC Spray Attack 57 I VI. -
Florida State Emergency Response Commission
Florida State Emergency Response Commission Sub-Committee on Training (SOT) HAZARDOUS MATERIALS MEDICAL TREATMENT PROTOCOLS Version 3.3 TOXIDROMES Toxidromes are clinical syndromes that the patient presents with. These patterns of signs and symptoms are essential for the successful recognition of chemical exposure. The toxidromes identified in this protocol are chemical exposure based while others such as the opioids are found within general medical protocol. These chemical toxidromes are identified clinically into five syndromes: Irritant Gas Toxidrome Asphyxiant Toxidrome Corrosive Toxidrome Hydrocarbon and Halogenated Hydrocarbons Toxidrome Cholinergic Toxidrome Each can present as a clinical manifestation of the chemical/poisoning involved with some cross-over between toxidromes. This list combines the toxic syndromes found within NFPA 473 (A.5.4.1(2) and traditional syndromes. Toxidrome Correlation to NFPA Standard 473 and Traditional Syndromes Toxidrome NFPA 473 A.5.4.1(2) Hazardous Materials Protocol Correlation Irritant Gas (j) Irritants Bronchospasm OC Pepper spray & lacrimants Asphyxiant (c) Chemical asphyxiants Carbon Monoxide (d) Simple asphyxiants Aniline dyes, Nitriles, Nitrares (h) Blood Agents Cyanide & Hydrogen Sulfide (n) Nitrogen Compounds Closed Space Fires Simple Asphyxants Corrosive (a) Corrosives Hydrofluroic Acid (g) Vesicants Chemical burns to the eye Choramine and Chlorine Hydrocarbon (e) Organic solvents Phenol and (q) Phenolic Compounds Halogenated Hydrocarbons Halogenated Hydrocarbons Cholinergic (b) Pesticides -
Nerve Agent - Lntellipedia Page 1 Of9 Doc ID : 6637155 (U) Nerve Agent
This document is made available through the declassification efforts and research of John Greenewald, Jr., creator of: The Black Vault The Black Vault is the largest online Freedom of Information Act (FOIA) document clearinghouse in the world. The research efforts here are responsible for the declassification of MILLIONS of pages released by the U.S. Government & Military. Discover the Truth at: http://www.theblackvault.com Nerve Agent - lntellipedia Page 1 of9 Doc ID : 6637155 (U) Nerve Agent UNCLASSIFIED From lntellipedia Nerve Agents (also known as nerve gases, though these chemicals are liquid at room temperature) are a class of phosphorus-containing organic chemicals (organophosphates) that disrupt the mechanism by which nerves transfer messages to organs. The disruption is caused by blocking acetylcholinesterase, an enzyme that normally relaxes the activity of acetylcholine, a neurotransmitter. ...--------- --- -·---- - --- -·-- --- --- Contents • 1 Overview • 2 Biological Effects • 2.1 Mechanism of Action • 2.2 Antidotes • 3 Classes • 3.1 G-Series • 3.2 V-Series • 3.3 Novichok Agents • 3.4 Insecticides • 4 History • 4.1 The Discovery ofNerve Agents • 4.2 The Nazi Mass Production ofTabun • 4.3 Nerve Agents in Nazi Germany • 4.4 The Secret Gets Out • 4.5 Since World War II • 4.6 Ocean Disposal of Chemical Weapons • 5 Popular Culture • 6 References and External Links --------------- ----·-- - Overview As chemical weapons, they are classified as weapons of mass destruction by the United Nations according to UN Resolution 687, and their production and stockpiling was outlawed by the Chemical Weapons Convention of 1993; the Chemical Weapons Convention officially took effect on April 291997. Poisoning by a nerve agent leads to contraction of pupils, profuse salivation, convulsions, involuntary urination and defecation, and eventual death by asphyxiation as control is lost over respiratory muscles. -
Decision-Making in Chemical Warfare Agent (CWA) Response There Is a Lot of Fear Associated with Chemical Will Act Accordingly
Application Note: 102 Decision-Making in Chemical Warfare Agent (CWA) Response There is a lot of fear associated with Chemical will act accordingly. If the first responders Warfare Agents (CWAs). The misnomer over-react and immediately jump into full “Nerve Gas” quickly brings horrible images to encapsulation protection it could panic the the minds of many civilians. But if we lay aside public and cause unnecessary worry and the politics and fear, CWA detection should even injury. treated like other gas/vapor detection challenges. It should be a collaborative Over Protection Can Be Dangerous process encompassing physical clues, threat to the Responder scenario, biological clues, and a variety of Heat stress is the number one injury in sensing technologies. No one clue or HazMat response and immediately jumping technology is always correct. Experience and into full Level A encapsulation is a good way the use of multiple clues and technologies are of overheating oneself. Level A the keys to successful CWA response. encapsulation also makes one much more Understanding what the clues are and how to susceptible to slip, trip and fall injuries. layer them to make a decision is critical to Finally, over protection makes it harder to get successful CWA response. things done. When properly used, detection allows responders to respond at lower levels Why is Gas Detection Important? of Personal Protective Equipment (PPE) to Responders cannot rely on their senses for provide the highest levels of safety to decision-making. Without effectively knowing themselves and to the community that they how to use detection techniques responders protect. -
Alphabetical Index of Substances and Articles
ALPHABETICAL INDEX OF SUBSTANCES AND ARTICLES - 355 - NOTES TO THE INDEX 1. This index is an alphabetical list of the substances and articles which are listed in numerical order in the Dangerous Goods List in Chapter 3.2. 2. For the purpose of determining the alphabetical order the following information has been ignored even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations “sec” and “tert”; and the letters “N” (nitrogen), “n” (normal), “o” (ortho) “m” (meta), “p” (para) and “N.O.S.” (not otherwise specified). 3. The name of a substance or article in block capital letters indicates a proper shipping name. 4. The name of a substance or article in block capital letters followed by the word “see” indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs). 5. An entry in lower case letters followed by the word “see” indicates that the entry is not a proper shipping name; it is a synonym. 6. Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name. 7. A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking. - 356 - INDEX Name and description Class UN No. Name and description Class UN No. Accumulators, electric, see 4.3 3292 Acid mixture, nitrating acid, see 8 1796 8 2794 8 2795 Acid mixture, spent, nitrating acid, see 8 1826 8 2800 8 3028 Acraldehyde, inhibited, see 6.1 1092 ACETAL 3 1088 -
Pepper Spray: What Do We Have to Expect?
Pepper Spray: What Do We Have to Expect? Assoc. Prof. Mehmet Akif KARAMERCAN, MD Gazi University School of Medicine Department of Emergency Medicine Presentation Plan • History • Pepper Spray • Tear Gas • Symptoms • Medical Treatment • If you are the victim ??? History • PEPPER SPRAY ▫ OC (oleoresin of capsicum) (Most Commonly Used Compound) • TEAR GAS ▫ CN (chloroacetophenone) (German scientists 1870 World War I and II) ▫ CS (orthochlorobenzalmalononitrile) (US Army adopted in 1959) ▫ CR (dibenzoxazepine) (British Ministry of Defence 1950-1960) History of Pepper Spray • Red Chili Pepper was being used for self defense in ancient India - China - Japan (Ninjas). ▫ Throw it at the faces of their enemies, opponents, or intruders. • Japan Tukagawa Empire police used a weapon called the "metsubishi." • Accepted as a weapon ▫ incapacitate a person temporarily. • Pepper as a weapon 14th and 15th century for slavery rampant and became a popular method for torturing people (criminals, slaves). History of Pepper Spray • 1980's The USA Postal Workers started using pepper sprays against dogs, bears and other pets and became a legalized non-lethal weapon ▫ Pepper spray is also known as oleoresin of capsicum (OC) spray • The FBI in 1987 endorse it as an official chemical agent and it took 4 years it could be legally accepted by law enforcement agency. Pepper Spray • The active ingredient in pepper spray is capsaicin, which is a chemical derived from the fruit of plants of chilis. • Extraction of Oleoresin Capsicum from peppers ▫ capsicum to be finely ground, capsaicin is then extracted using an organic solvent (ethanol). The solvent is then evaporated, remaining waxlike resin is the Oleoresin Capsicum • Propylene Glycol is used to suspend the OC in water, pressurized to make it aerosol in Pepper Spray. -
Hazardous Material Inventory Statement
City of Brooklyn Park FIRE DEPARTMENT 5200 - 85th Avenue North Brooklyn Park MN 55443 Phone: (763)493-8020 Fax: (763) 493-8391 Hazardous Materials Inventory Statement Users Guide A separate inventory statement shall be provided for each building. An amended inventory statement shall be provided within 30 days of the storage of any hazardous materials or plastics that changes or adds a hazard class or which is sufficient in quantity to cause an increase in the quantity which exceeds 5 percent for any hazard class. The hazardous materials inventory statement shall list by hazard class categories. Each grouping shall provide the following information for each hazardous material listed for that group including a total quantity for each group of hazard class. 1. Hazard class. (See attached Hazardous Materials Categories Listing) 2. Common or trade name. 3. Chemical Abstract Service Number (CAS number) found in 29 Code of Federal Regulations (C.F.R.). 4. Whether the material is pure or a mixture, and whether the material is a solid, liquid or gas 5. Maximum aggregate quantity stored at any one time. 6. Maximum aggregate quantity In-Use (Open to atmosphere) at any one time. 7. Maximum aggregate quantity In-Use (Closed to atmosphere) at any one time. 8. Storage conditions related to the storage type, high-pile, encapsulated, non-encapsulated. Attached is a listing of categories that all materials need to be organized to. Definitions of these categories are also attached for your use. At the end of this packet are blank forms for completing this project. For questions regarding Hazardous Materials Inventory Statement contact the Fire Department at 763-493-8020. -
UPS Chemical Table - 49 CFR Version (Ground and Air Packages)
UPS Chemical Table - 49 CFR Version (Ground and Air Packages) GROUND AND AIR BASIC DESCRIPTION FOR GROUND AND AIR GROUND SHIPMENTS AIR SHIPMENTS SHIPMENTS Symbols: "‡" Requires a Technical Name / "*" For Ltd Qty see 49 CFR Part 173.*** / "**" See 49 CFR 173.27 for inner receptacle requirements / "▲" Additional CAO Contract Required for all non-Class 9 CAO / "#" Sub-risk may be omitted from shipping papers if 49 CFR 172.400a(c) criteria met. (ref 172.202(a)(3)) CARGO HAZARD PASSENGER AIRCRAFT CLASS OR GROUND LTD QTY AIRCRAFT MAX NET HAZARDOUS MATERIALS DESCRIPTIONS DIVISION I.D. NUMBER SPECIAL SERVICE TO MAX NET MAX NET PER SPECIAL NON-BULK AND PROPER SHIPPING NAME (Subsidiary if (ALSO MARK PACKING LABEL(S) REQUIRED OR PERMIT CANADA LABEL(S) REQUIRED OR PER PER PACKAGE** PERMIT SPECIAL EXCEPTIONS PACKAGING (ALSO MARK ON PACKAGE) applicable) ON PACKAGE) GROUP SPECIAL PERMIT OR EXCEPTION OR 173.13 PERMITTED SPECIAL PERMIT OR EXCEPTION PACKAGE** PACKAGE** ▲ OR 173.13 PROVISIONS §173.*** §173.*** (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) (14) (15) Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flamable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flamable gas) Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) FLAMMABLE FLAMMABLE Acetal 3 UN1088 II LIQUID * YES LIQUID 1 L 5 L 30 L 150 -
Basic Description for Ground and Air Hazardous
BASIC DESCRIPTION FOR GROUND AND AIR GROUND AND AIR HAZARDOUS MATERIALS SHIPMENTS GROUND SHIPMENTS AIR SHIPMENTS SHIPMENTS HAZARD DOT DOT CLASS OR MAXIMUM EXEMPTION, GROUND EXEMPTION, HAZARDOUS MATERIALS DESCRIPTIONS DIVISION I.D. NUMBER LABEL(S) REQUIRED OR QUANTITY PER SPECIAL SERVICE TO LABEL(S) REQUIRED OR MAXIMUM NET CARGO SPECIAL NON-BULK AND PROPER SHIPPING NAME (Subsidiary if (ALSO MARK PACKING EXEMPTION, SPECIAL PERMIT INNER PERMIT CANADA EXEMPTION, SPECIAL PERMIT QUANTITY PER AIRCRAFT PERMIT SPECIAL EXCEPTIONS PACKAGING (ALSO MARK ON PACKAGE) applicable) ON PACKAGE) GROUP OR EXCEPTION RECEPTACLE OR 173.13 PERMITTED OR EXCEPTION PACKAGE** QUANTITY OR 173.13 PROVISIONS §173.*** §173.*** (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) (14) (15) Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) FLAMMABLE FLAMMABLE Acetal 3 UN1088 II LIQUID * YES LIQUID * 5 L 150 202 FLAMMABLE Acetaldehyde 3 UN1089 I LIQUID YES Forbidden None 201 May not be regulated when shipped via UPS Acetaldehyde ammonia 9 UN1841 III ground YES CLASS 9 * 30 kg 30 kg 155 204 FLAMMABLE FLAMMABLE Acetaldehyde oxime 3 UN2332 III LIQUID * YES LIQUID * 25 L 150 203 CORROSIVE, CORROSIVE, Acetic acid, glacial or Acetic acid solution, FLAMMABLE FLAMMABLE A3, A6, with more than 80 percent acid, by mass 8 (3) UN2789 II LIQUID * YES LIQUID * 1 L A7, A10 154 202 Acetic