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L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Raman and Infrared Spectroscopy of Arsenates of the Roselite and Fairfeldite Mineral Subgroups
This may be the author’s version of a work that was submitted/accepted for publication in the following source: Frost, Ray (2009) Raman and infrared spectroscopy of arsenates of the roselite and fair- feldite mineral subgroups. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71(5), pp. 1788-1794. This file was downloaded from: https://eprints.qut.edu.au/17596/ c Copyright 2009 Elsevier Reproduced in accordance with the copyright policy of the publisher. Notice: Please note that this document may not be the Version of Record (i.e. published version) of the work. Author manuscript versions (as Sub- mitted for peer review or as Accepted for publication after peer review) can be identified by an absence of publisher branding and/or typeset appear- ance. If there is any doubt, please refer to the published source. https://doi.org/10.1016/j.saa.2008.06.039 QUT Digital Repository: http://eprints.qut.edu.au/ Frost, Ray L. (2009) Raman and infrared spectroscopy of arsenates of the roselite and fairfieldite mineral subgroups. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71(5). pp. 1788-1794. © Copyright 2009 Elsevier Raman and infrared spectroscopy of arsenates of the roselite and fairfieldite mineral subgroups Ray L. Frost• Inorganic Materials Research Program, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, Australia. Abstract Raman spectroscopy complimented with infrared spectroscopy has been used to determine the molecular structure of the roselite arsenate minerals of the roselite and 2+ fairfieldite subgroups of formula Ca2B(AsO4)2.2H2O (where B may be Co, Fe , Mg, 2- Mn, Ni, Zn). -
New Mineral Names*,†
American Mineralogist, Volume 106, pages 1360–1364, 2021 New Mineral Names*,† Dmitriy I. Belakovskiy1, and Yulia Uvarova2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2CSIRO Mineral Resources, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia In this issue This New Mineral Names has entries for 11 new species, including 7 minerals of jahnsite group: jahnsite- (NaMnMg), jahnsite-(NaMnMn), jahnsite-(CaMnZn), jahnsite-(MnMnFe), jahnsite-(MnMnMg), jahnsite- (MnMnZn), and whiteite-(MnMnMg); lasnierite, manganflurlite (with a new data for flurlite), tewite, and wumuite. Lasnierite* the LA-ICP-MS analysis, but their concentrations were below detec- B. Rondeau, B. Devouard, D. Jacob, P. Roussel, N. Stephant, C. Boulet, tion limits. The empirical formula is (Ca0.59Sr0.37)Ʃ0.96(Mg1.42Fe0.54)Ʃ1.96 V. Mollé, M. Corre, E. Fritsch, C. Ferraris, and G.C. Parodi (2019) Al0.87(P2.99Si0.01)Ʃ3.00(O11.41F0.59)Ʃ12 based on 12 (O+F) pfu. The strongest lines of the calculated powder X-ray diffraction pattern are [dcalc Å (I%calc; Lasnierite, (Ca,Sr)(Mg,Fe)2Al(PO4)3, a new phosphate accompany- ing lazulite from Mt. Ibity, Madagascar: an example of structural hkl)]: 4.421 (83; 040), 3.802 (63, 131), 3.706 (100; 022), 3.305 (99; 141), characterization from dynamic refinement of precession electron 2.890 (90; 211), 2.781 (69; 221), 2.772 (67; 061), 2.601 (97; 023). It diffraction data on submicrometer sample. European Journal of was not possible to perform powder nor single-crystal X-ray diffraction Mineralogy, 31(2), 379–388. -
Collinsite in Hydrothermal Assemblages Related to Carbonatites in the Kovdor Complex, Northwestern Russia
1081 The Canadian Mineralogist Vol. 39, pp. 1081-1094 (2001) COLLINSITE IN HYDROTHERMAL ASSEMBLAGES RELATED TO CARBONATITES IN THE KOVDOR COMPLEX, NORTHWESTERN RUSSIA RUSLAN P. LIFEROVICH§ Institute of Geosciences, University of Oulu, PL-3000, FIN-90014 Oulu, Finland YAKOV A. PAKHOMOVSKY, ALLA N. BOGDANOVA AND ELENA G. BALAGANSKAYA Geological Institute, Kola Science Centre, Russian Academy of Sciences, 14 Fersmana Street, 184200-RU Apatity, Russia KAUKO V.O. LAAJOKI AND SEPPO GEHÖR Institute of Geosciences, University of Oulu, PL-3000, FIN-90014 Oulu, Finland NIKITA V. CHUKANOV Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia ABSTRACT Several generations of collinsite were formed during the hydrothermal alteration of phoscorite and dolomite carbonatite in the Kovdor alkaline-ultramafic complex, northwestern Russia. The collinsite at this locality shows isomorphic substitution of Sr for Ca at the A crystallographic site, which is atypical both for this species and for the entire fairfieldite group. The Sr content reaches 0.74 atoms per formula unit and shows an inverse correlation with Ca. Sr is found to account for no more than 37% of the total occupancy of the A site, a proportion that fits the Lewis acidity of interstitial cations, a value of 0.25 valence units (assuming a disordered distribution of Sr), which in turn matches the Lewis basicity of the structural unit in collinsite, the chain [Mg(PO4)2(H2O)2]. The collinsite-bearing assemblages were formed by juvenile hydrothermal solutions derived from phoscorites and carbonatites that had been cooling in a tectonically active environment. Textural evidence and strontium isotopic character- istics show that the assemblages were superimposed upon the host rocks after the cataclasis of the dolomite carbonatite and selective leaching of its primary minerals. -
A Specific Gravity Index for Minerats
A SPECIFICGRAVITY INDEX FOR MINERATS c. A. MURSKyI ern R. M. THOMPSON, Un'fuersityof Bri.ti,sh Col,umb,in,Voncouver, Canad,a This work was undertaken in order to provide a practical, and as far as possible,a complete list of specific gravities of minerals. An accurate speciflc cravity determination can usually be made quickly and this information when combined with other physical properties commonly leads to rapid mineral identification. Early complete but now outdated specific gravity lists are those of Miers given in his mineralogy textbook (1902),and Spencer(M,i,n. Mag.,2!, pp. 382-865,I}ZZ). A more recent list by Hurlbut (Dana's Manuatr of M,i,neral,ogy,LgE2) is incomplete and others are limited to rock forming minerals,Trdger (Tabel,l,enntr-optischen Best'i,mmungd,er geste,i,nsb.ildend,en M,ineral,e, 1952) and Morey (Encycto- ped,iaof Cherni,cal,Technol,ogy, Vol. 12, 19b4). In his mineral identification tables, smith (rd,entifi,cati,onand. qual,itatioe cherai,cal,anal,ys'i,s of mineral,s,second edition, New york, 19bB) groups minerals on the basis of specificgravity but in each of the twelve groups the minerals are listed in order of decreasinghardness. The present work should not be regarded as an index of all known minerals as the specificgravities of many minerals are unknown or known only approximately and are omitted from the current list. The list, in order of increasing specific gravity, includes all minerals without regard to other physical properties or to chemical composition. The designation I or II after the name indicates that the mineral falls in the classesof minerals describedin Dana Systemof M'ineralogyEdition 7, volume I (Native elements, sulphides, oxides, etc.) or II (Halides, carbonates, etc.) (L944 and 1951). -
The Crystal Structure of the Mineral Scholzite and a Study of the Crystal
\ I 7'1,71 ¡1 :), THE CRYSTAL STRUCTURE OF THE MINERAL SCHOLZITE AND A STUDY OF THE CRYSTAL CHEMISTRY OF SOME RELATED PHOSPHATE AND ARSENATE MINERALS A thesis submitted for the Degree of Doctor of PhilosoPhY at the University of Adelaide in April, 1975 by R0DERICK JEFFREY HILL, B.Sc. (Hons.) Department of Geology and Mineralogy Au/¿tr¡'t ,,! /'/,".'','-'"' ' TABLE OF CONTENTS Page SUMMARY (i) STATEMENT OF ORIGINATITY (ii) ACKNOWLEDGEMENTS (iii) GENERAL INTRODUCTION I CHAPTER 1 TIIE GEOI.OGY AbID MINERALOGY OF REAPHOOK HILL, SOUTTI AUSTR.ALIA 2 1.1 ABSTR,ACT 2 r.2 INTRODUCTTON 2 1.3 GEOIÐGICAL SETTING 3 I.4 EXPERTMENTAI TECHNIQT ES 5 1.5 THE MAJOR PHOSPHATE MTNERALS 6 1.5.1 Tarbuttite - Znr(po4) (OH) 6 1.5.2 Parahopeite ZnrZn(pOn) - Z.4HZo 9 I.5.3 Scholzite CaZnU(pO4) - 2.2H2O 9 1.5.4 Zincian Collinsite Car(Mg,Zn) (pO4) - 2.2H2O 15 1.6 ASPECTS OF EHE CRYSTA¡ CHEMISTRY OF THE MAJOR PHOSPHATE MINERALS 19 L.7 PARAGENESIS 23 1.7.1 Major Minerals 23 L.7.2 Other lvlinerals 26 1.7.3 Conclusions 27 CHAPTER 2 TIIE CRYSTAI STRUCTURE OF SCHOLZITE 30 2.L ABSTRACT 30 2.2 INTRODUCTION 32 2.3 DATA COLLECTION AND ÐATA REDUCTION 32 2.4 DISCUSSION OF TITE INTENSITY DISTRIBUTION 35 2.4.L Subcell Structure and pseudosynunetry 35 2.4.2 Dete::mination of the True Syrnmetry 4L 2.4.3 Structural Disorder 4l 2.5 STRUqrURE SOLUTION AND REFINEMENT OF THE AVER.AGE ST'BCELL 52 2.6 DESCRIPTION AND DISCUSSION OF THE AVERAGE ST]BCELL STRUCTURE 60 2.6.I Topology 60 2.6.2 Disorder 65 2.6.3'iThermal" parameters 67 2.7 STRUCTURE SOLUTION AND REFTNEMENT OF TITE },IAIN CELL -
Description and Unique Crystal-Structure of Waterhouseite, a New Hydroxy Manganese Phosphate Species from the Iron Monarch Deposit, Middleback Ranges, South Australia
1401 The Canadian Mineralogist Vol. 43, pp. 1401-1410 (2005) DESCRIPTION AND UNIQUE CRYSTAL-STRUCTURE OF WATERHOUSEITE, A NEW HYDROXY MANGANESE PHOSPHATE SPECIES FROM THE IRON MONARCH DEPOSIT, MIDDLEBACK RANGES, SOUTH AUSTRALIA ALLAN PRING§ Department of Mineralogy, South Australian Museum, North Terrace, Adelaide, South Australia 5000, and School of Earth & Environmental Science, University of Adelaide, Adelaide, S.A. 5005, Australia UWE KOLITSCH Institut für Mineralogie und Kristallographie, Geozentrum, Universität Wien, Althanstr. 14, A–1090 Wien, Austria WILLIAM D. BIRCH Department of Mineralogy, Museum of Victoria, GPO Box 666E, Melbourne, Victoria, 3000, Australia ABSTRACT Waterhouseite from the Iron Monarch mine, Iron Knob, South Australia, is a new hydroxy manganese phosphate species that has a unique crystal-structure. The mineral was found in a carbonate-rich zone with gatehouseite, seamanite, rhodochrosite, shigaite, barite, hausmannite and hematite. It occurs as divergent sprays of orange-brown to dark brown bladed crystals up to 1 mm in length but only up to 20 m in thickness. The crystals are transparent with a pearly luster on cleavages, but it is vitreous to pearly on the tabular faces. The mineral is brittle, with a conchoidal fracture and a yellowish brown streak. There is a perfect cleavage on (100) and a probable cleavage on (001). The crystals show the principal forms {100} (dominant), {010}, {011} and {001}. All crystals are twinned on (100) by non-merohedry. The Mohs hardness is estimated to be ~4, and the measured density is 3.55(5) g/cm3 (calculated density is 3.591 g/cm3). Crystals are biaxial negative and length-slow, with ␣ 1.730(3),  ~1.738 and ␥ 1.738(4), but 2V could not be measured. -
Hillite, a New Member of the Fairfieldite Group: Its Description and Crystal Structure
981 The Canadian Mineralogist Vol. 41, pp. 981-988 (2003) HILLITE, A NEW MEMBER OF THE FAIRFIELDITE GROUP: ITS DESCRIPTION AND CRYSTAL STRUCTURE OLGA V. YAKUBOVICH§ Department of Crystallography, Moscow Lomonosov State University, Vorob’evy Gory, 119899 Moscow, Russia WERNER MASSA Fachbereich Chemie der Philipps-Universität und Wiss. Zentrum f. Materialwissenschaften, Hans-Meerwein-Straße, D-35043 Marburg, Germany § RUSLAN P. LIFEROVICH Department of Geology, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario P7B 5E1, Canada POLINA G. GAVRILENKO Department of Crystallography, Moscow Lomonosov State University, Vorob’evy Gory, 119899 Moscow, Russia ALLA N. BOGDANOVA Geological Institute, Kola Science Center, Russian Academy of Sciences, 184200 Apatity, Russia PEKKA TUISKU Institute of Geosciences, University of Oulu, PL-3000, FIN-90014 Oulu, Finland ABSTRACT Hillite (X in Russian), ideally Ca2(Zn,Mg)[PO4]2•2H2O, is a new zinc-dominant analogue of collinsite, isostructural with fairfieldite. It occurs in unmetamorphosed sediments of the Lower Cambrian Parachilna Formation, Reaphook Hill, South Australia, Australia, in association with zincian collinsite and scholzite. Hillite is triclinic, a 5.736(1), b 6.767(2), c 5.462(1) Å, ␣ 97.41(2),  108.59(2), ␥ 107.19(2)°, V 186.05(8) Å3, space group P1,¯ Z = 1. The average result of fifteen electron-microprobe analyses of relatively homogeneous crystals of the latest generation is: Na2O 0.11, CaO 30.36, MgO 4.34, ZnO 14.79, FeO 0.04, P2O5 40.85, H2Ocalc 10.23 (calculated to give 2 H2O), total 100.72 wt.%. The single crystals of hillite do not exceed 50 m in length; larger aggregates are rather inhomogeneous in terms of Zn:Mg ratio. -