Revision 4 High-Pressure Behavior of Cuprospinel Cufe2o4: Influence Of
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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
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INDEX,VOLUME 59* Absorption coefficients Albite, continued attapulgite 1113 1ow-, comparison with ussingite 347 clay ninerals 11r3 nelting in nultispecies fluid 598 dickite 274 Alexandrite, chrorniumIII centers in 159 hal loysite 274 hectorite I 113 ALLAN, DAVID illite 1113 with V. Brown, and J. Stark, Rocke kaolinite 274 and Minez,als of Califowi,a; reviewed metabentonite 1113 by J. Murdoch 387 nontronite 1113 Allemontite, see stibarsen 1331 srnectite 1113 ALLMAN,MICHAEL Absorption spectra with D.F. Lawrence, Geological alexandrite, synthetic 159 Labonatony Techni.ques reviewed apophyllite 62I ; by F.H. Manley and W.R. Powers IL42 garnet 565 olivine 244 A1lophane rhodonite.. shocked t77 dehydration, DTA, infrared spectra 1094 Acmite, Ti-, phase relations of 536 Almandine Actinolite overgrowth by grossularite- spessartine 558 coexisting with hoinblende 529 in netamorphic rocks, optical Arnerican Crystallographic Association, properties 22 abstracts, Spring neeting,1974 1L27 Activity coefficients Amphiboles of coexisting pyroxenes 204 actinolite 2? 529 Al -Ca-anphibole ADMS, HERBERTG. 22 compositions 22 with L.H. Cohen, and W. Klenent, Jr.; coordination polyhedra M High-low quartz inversion : Thermal of site atons in I 083 analysis studies to 7 kbar I 099 hornblende L, 22, 529, 604 ADAMS,JOHN W. magnesioarfvedsonite (authigenic) 830 with T. Botinelly, W.N. Sharp, and refraction indices 22 K. Robinson; Murataite, a new richterite, Mg-Fe- 518 conplex oxide from E1 Paso County, AMSTUTZ,G.C. Colorado L72 with A.J. Bernard, Eds., )nes in Errata 640 Sediments; reviewed by P.B. Barton 881 Aenigmatite ANDERSEN,C.A. in volcanic conplex, composition, and X-ray data Micz,opnobeAnalysis; reviewed by A.E. -
Design of Large Space Structures Derived from Line Geometry Principles
DESIGN OF LARGE SPACE STRUCTURES DERIVED FROM LINE GEOMETRY PRINCIPLES By PATRICK J. MCGINLEY A THESIS PRESENTED TO THE GRADUATE SCHOOL OF THE UNIVERSITY OF FLORIDA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE UNIVERSITY OF FLORIDA 2002 Copyright 2002 by Patrick J. McGinley I would like to dedicate this work to Dr. Joseph Duffy - mentor, friend, and inspiration. My thanks also go out to my parents, Thomas and Lorraine, for everything they have taught me, and my friends, especially Byron, Connie, and Richard, for all their support. ACKNOWLEDGMENTS I would like to thank my advisor, Dr. Carl D. Crane, III, the members of my advisory committee, Dr. John Schueller and Dr. John Ziegert, as well as Dr. Joseph Rooney, for their help and guidance during my time at UF, and especially their understanding during a difficult last semester. iv TABLE OF CONTENTS page ACKNOWLEDGMENTS ................................................................................................. iv LIST OF TABLES............................................................................................................ vii LIST OF FIGURES ......................................................................................................... viii ABSTRACT...................................................................................................................... xii CHAPTER 1 INTRODUCTION ............................................................................................................1 2 BACKGROUND ..............................................................................................................5 -
An,4B Tnitt{:} Mûleculaã.Orbital .A-Pproact{
T}IE STEREÛC}{E}4ISTRY ÛF CUg- ÛXYSALT MNNERALS AN,4B TNITT{:} MÛLECULAÃ.ORBITAL .A-PPROACT{ Þ\¡ PETER C. EL-RNS A Thesis Subrnitted to the Faculty of Graduate Studies in Pa-rtial Fulfilment, of the Requireraents for the Ðegree of ÐOCT'OR OF THiLOSOPHY Ðepartment of Geological Sciences University of Manitoba Winnipeg, Manitoba @ Copyright by Peter Carman Bu¡¡rs, 1994 WWW National Library B¡bliothèqLre naiioftale W'r @ of Canada du Canâda Acquisitions and Direction des acquisitions et B¡bf iographic Seruices Branch des servìces bibl¡ographiques 395 Wellington Slreet 395, rue WeJlingron Otlawa, Onta¡io Onawa (Oniar¡o) K1A ON4 K1A ON4 aùtLle Na¡e èlùerce T'he at¡th@ü' has graü-lted aãx Ë*'au¡tec¡r a aaaondé s"!ne licemce írrevoeabIe nÕrÌ-ex6t¿.Esive ¡¡eemcc inr¡ávoaab[e et ntm exc[usíve allowing t['re F,Iationat Lihrany of penmrettant à $a Eihliothèque Camada tÕ reprtdL¡ce, åoana, natiomale du Canada de distribute Õr sell copíes of reprods.rãre, prêter, distribuer ou his/hen thesís by any sneams arsd vendre des aopies de sa thèse in any fonm or fonnlat, rnaking de quelque rna¡rière et sous tÍ'lis tl'lesis available to E¡'¡terested qt¡elque forrne que ce soit poun persons. rnettre des exenarplaires de cette thèse à [a disposition des personnes intéressées. T'[re a¡.¡t['ror retains ownershíp of E-'a¡.¡teun conserve la propriété du the eopyrig[et im hrislher tÍresis" droit d'auteun quri protège sa Ê.deít[rer ttre thesís sror substantåa[ t['rèse. hdå 8a thèse ni des extnaits extnacts fnonn it may be pnin-lted or substantiels de celle-ci ne otlrerwíse neproduced wãtå'¡or¡t doívent être ãrrrpria'nés oL¡ [rüs/her pernnlssiom. -
Copper-Nickel Mixed Oxide Catalysts from Layered Double Hydroxides For
Copper-nickel mixed oxide catalysts from layered double hydroxides for the hydrogen-transfer valorisation of lignin in organosolv pulping Iqra Zubair Awan, Giada Beltrami, Danilo Bonincontro, Olinda Gimello, Thomas Cacciaguerra, Nathalie Tanchoux, Annalisa Martucci, Stefania Albonetti, Fabrizio Cavani, Francesco Di Renzo To cite this version: Iqra Zubair Awan, Giada Beltrami, Danilo Bonincontro, Olinda Gimello, Thomas Cacciaguerra, et al.. Copper-nickel mixed oxide catalysts from layered double hydroxides for the hydrogen-transfer valori- sation of lignin in organosolv pulping. Applied Catalysis A : General, Elsevier, 2021, 609, pp.117929. 10.1016/j.apcata.2020.117929. hal-03080770 HAL Id: hal-03080770 https://hal.archives-ouvertes.fr/hal-03080770 Submitted on 17 Dec 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Copper-nickel mixed oxide catalysts from layered double hydroxides for the hydrogen-transfer valorisation of lignin in organosolv pulping. Iqra Zubair AWAN,a,b,1 Giada BELTRAMI,c Danilo BONINCONTRO,a,2 Olinda GIMELLO,b Thomas CACCIAGUERRA,b -
Thermaerogenite Cual2o4 - Crystal Data: Cubic
Thermaerogenite CuAl2O4 - Crystal Data: Cubic. Point Group: 4/m 3 2/m. As octahedral crystals to 0.02 mm displaying {111} modified by {110}, sometimes skeletal. Physical Properties: Cleavage: None. Fracture: Conchoidal. Tenacity: Brittle. Hardness = ~7 D(calc.) = 4.870 Optical Properties: Transparent to translucent. Color: Brown, yellow-brown, red-brown, brown- yellow, or brown-red; gray with yellowish internal reflections in reflected light. Streak: Yellow. Luster: Vitreous. Optical Class: Isotropic. R1-R2: (400) 16.4, (420) 16.0, (440) 15.7, (460) 15.4, (470) 15.2, (480) 15.1, (500) 14.8, (520) 14.5, (540) 14.2, (546) 14.2, (560) 14.0, (580) 13.7, (589) 13.6, (600) 13.2, (620) 13.2, (640) 13.0, (650) 12.9, (660) 12.8, (680) 12.5, (700) 12.3 - Cell Data: Space Group: Fd 3 m. a = 8.093(9) Z = [8] X-ray Powder Pattern: Arsenatnaya fumarole, Tolbachik volcano, Kamchatka Peninsula, Russia. 2.451 (100), 2.873 (65), 1.438 (30), 1.565 (28), 1.660 (16), 2.033 (10), 1.865 (6) Chemistry: (1) (2) CuO 25.01 43.83 ZnO 17.45 Al2O3 39.43 56.17 Cr2O3 0.27 Fe2O3 17.96 . Total 100.12 100.00 (1) Arsenatnaya fumarole, Tolbachik volcano, Kamchatka Peninsula, Russia; average of 4 electron microprobe analyses supplemented by Raman spectroscopy; corresponds to (Cu0.62Zn0.42)Σ=1.04 3+ (Al1.52Fe 0.44Cr0.01)Σ=1.97O4. (2) CuAl2O4. Polymorphism & Series: Continuous series with gahnite, discontinuous with cuprospinel. Mineral Group: Spinel supergroup. Occurrence: In cavities and overgrown on earlier oxide minerals, often epitaxially, as sublimates around a volcanic fumarole. -
New Mineral Species and Their Crystal Structures"
Title: Editorial for Special Issue "New Mineral Species and Their Crystal Structures" Author: Irina O. Galuskina, Igor V. Pekov Citation style: Galuskina Irina O., Pekov Igor V. (2019). Editorial for Special Issue "New Mineral Species and Their Crystal Structures". "Minerals" (Vol. 9, iss. 2 (2019), art. no 106), doi 10.3390/min9020106 minerals Editorial Editorial for Special Issue “New Mineral Species and Their Crystal Structures” Irina O. Galuskina 1,* and Igor V. Pekov 2 1 Faculty of Earth Sciences, University of Silesia, B˛edzi´nska60, 41-200 Sosnowiec, Poland 2 Faculty of Geology, Moscow State University, Vorobievy Gory, Moscow 119991, Russia; [email protected] * Correspondence: [email protected] Received: 17 January 2019; Accepted: 1 February 2019; Published: 13 February 2019 Mineralogy is the oldest and one of the most important sciences of the geological cycle. Minerals, the basis of overwhelming mass of solid matter in the universe, are direct subjects of investigation in mineralogy. Minerals, or mineral species, are generally solid crystalline substances. Their definition indicates that, they are: (1) naturally occurring; (2) belonging to the distinct structural type; (3) stable, varying merely in the relatively small limits of chemical composition. If a given mineral differs from other known species in its structure (2) and/or composition (3) then it can be considered as a new mineral species. According to the data of the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association (IMA) (http://nrmima.nrm.se/), there are currently about 5600 known mineral species. The number of minerals increases steadily year by year. -
A Review of the Structural Architecture of Tellurium Oxycompounds
Mineralogical Magazine, May 2016, Vol. 80(3), pp. 415–545 REVIEW OPEN ACCESS A review of the structural architecture of tellurium oxycompounds 1 2,* 3 A. G. CHRISTY ,S.J.MILLS AND A. R. KAMPF 1 Research School of Earth Sciences and Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 3 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA [Received 24 November 2015; Accepted 23 February 2016; Associate Editor: Mark Welch] ABSTRACT Relative to its extremely low abundance in the Earth’s crust, tellurium is the most mineralogically diverse chemical element, with over 160 mineral species known that contain essential Te, many of them with unique crystal structures. We review the crystal structures of 703 tellurium oxysalts for which good refinements exist, including 55 that are known to occur as minerals. The dataset is restricted to compounds where oxygen is the only ligand that is strongly bound to Te, but most of the Periodic Table is represented in the compounds that are reviewed. The dataset contains 375 structures that contain only Te4+ cations and 302 with only Te6+, with 26 of the compounds containing Te in both valence states. Te6+ was almost exclusively in rather regular octahedral coordination by oxygen ligands, with only two instances each of 4- and 5-coordination. Conversely, the lone-pair cation Te4+ displayed irregular coordination, with a broad range of coordination numbers and bond distances. -
INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France August 2019
IGC 2019 - Nantes IGC 2019 INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France www.igc-gemmology.org August 2019 36th IGC 2019 – Nantes, France Introduction 36th International Gemmological Conference IGC August 2019 Nantes, France Dear colleagues of IGC, It is our great pleasure and pride to welcome you to the 36th International Gemmological Conference in Nantes, France. Nantes has progressively gained a reputation in the science of gemmology since Prof. Bernard Lasnier created the Diplôme d’Université de Gemmologie (DUG) in the early 1980s. Several DUGs or PhDs have since made a name for themselves in international gemmology. In addition, the town of Nantes has been on several occasions recognized as a very attractive, green town, with a high quality of life. This regional capital is also an important hub for the industry (e.g. agriculture, aeronautics), education and high-tech. It has only recently developed tourism even if has much to offer, with its historical downtown, the beginning of the Loire river estuary, and the ocean close by. The organizers of 36th International Gemmological Conference wish you a pleasant and rewarding conference Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. The organizers of the 36th International Gemmological Conference in Nantes, France From left to right Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. 3 36th IGC 2019 – Nantes, France Introduction Organization of the 36th International Gemmological Conference Organizing Committee Dr. Emmanuel Fritsch (University of Nantes) Dr. Nathalie Barreau (IMN-CNRS) Feodor Blumentritt Dr. Jayshree Panjikar (IGC Executive Secretary) IGC Executive Committee Excursions Sophie Joubert, Richou, Cholet Hervé Renoux, Richou, Cholet Guest Programme Sophie Joubert, Richou, Cholet Homepage Dr. -
Compositional Effects on the Solubility of Minor and Trace Elements In
American Mineralogist, Volume 101, pages 1360–1372, 2016 SPINELS RENAISSANCE: THE PAST, PRESENT, AND FUTURE OF THOSE UBIQUITOUS MINERALS AND MATERIALS Compositional effects on the solubility of minor and trace elements in oxide spinel minerals: Insights from crystal-crystal partition coefficients in chromite exsolution VANESSA COLÁS1,2,*, JOSÉ ALBERTO PADRÓN-NAVARTA3, JOSÉ MARÍA GONZÁLEZ-JIMÉNEZ4, WILLIAM L. GRIFFIN5, ISABEL FANLO2, SUZANNE Y. O’REILLY5, FERNANDO GERVILLA6, JOAQUÍN A. PROENZA7, NORMAN J. PEARSON5, AND MONICA P. ESCAYOLA8 1Instituto de Geología, Universidad Nacional Autónoma de México, Ciudad Universitaria, 04510 Ciudad de México, México 2Universidad de Zaragoza, Departamento de Ciencias de la Tierra, Pedro Cerbuna 12, 50009 Zaragoza, Spain 3Géosciences Montpellier, CNRS and University of Montpellier (UMR5243), 34095 Montpellier, France 4Department of Geology and Andean Geothermal Center of Excellence (CEGA), Universidad de Chile, Plaza Ercilla no. 803, Santiago, Chile 5ARC Centre of Excellence for Core to Crust Fluid Systems (CCFS) and GEMOC National Key Centre, Department of Earth and Planetary Sciences, Macquarie University, Sydney, New South Wales 2109, Australia 6Departamento de Mineralogía y Petrología and Instituto Andaluz de Ciencias de la Tierra (Universidad de Granada-CSIC), Facultad de Ciencias, Avda. Fuentenueva s/n, 18002 Granada, Spain 7Departament de Cristal·lografia, Mineralogia i Dipòsits Minerals, Facultat de Geologia, Universitat de Barcelona, Martí i Franquès s/n, 08028 Barcelona, Spain 8IDEAN-CONICET, Departamento de Ciencias Geológicas, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2160, Ciudad Universitaria, Pabellón II-1° EP, Office 29, (1428), Buenos Aires, Argentina ABSTRACT Chromite from Los Congos and Los Guanacos in the Eastern Pampean Ranges of Córdoba (Argentin- ian Central Andes) shows homogenous and exsolution textures. -
Outline of Crystal Field Theory Bums, R
6 1 Introduction 1.3 Background reading 2 Bethe, H. (1929) Splitting of terms in crystals. (Termsaufspaltung in Kristallen.) Ann. Phys., 3, 133-206. [Trans[.: Cons]lltants Bureau, New York.] Outline of crystal field theory Bums, R. G., Clark, R. H. & Fyfe, W. S. (1964) Crystal field theory and applications to problems in geochemistry. In Chemistry of the Earth's Crust, Proceedings of the Vemadsky Centennial Symposium. (A. P. Vinogradov, ed.; Science Press, Moscow), 2, 88-106. [Trans/.: Israel Progr. Sci. Transl., Jerusalem, pp. 93-112 (1967).] Bums, R. .~· & Fyfe, W. S. (1967a) Crystal field theory and the geochemistry of transition elements. In Researches in Geochemistry. (P. H. Abelson, ed.; J. Wiley & Son, New York), 2, 259-85. Bums, R. G. (1985) Thermodynamic data from crystal field spectra. In Macroscopic to Microscopic. Atomic Environments to Mineral Thermodynamics. (S. W. Kieffer & A. Navrotsky, eds; Mineral. Soc. Amer. Publ.), Rev. Mineral., 14, 277-316. Orgel, L. E. (1952) The effects of crystal fields on the properties of transition metal Crystal field theory gives a survey of the effects of electric fields of ions. J. Chern. Soc., pp. 4756-61. definite symmetries on an atom in a crystal structure. Williams, R. J.P. (1959) Deposition of trace elements in a basic magma. Nature, 184, - -A direct physical confirmation should be obtainable by 44. analysis of the spectra of crystals. H. A. Bethe, Annalen der Physik, 3, 206 (1929) 2.1 Introduction Crystal field theory describes the origins and consequences of interactions of the surroundings on the orbital energy levels of a transition metal ion. -
Recovery of Copper and Magnetite from Copper Slag Using Concentrated Solar Power (CSP)
metals Article Recovery of Copper and Magnetite from Copper Slag Using Concentrated Solar Power (CSP) Daniel Fernández-González 1,* , Janusz Prazuch 2 , Íñigo Ruiz-Bustinza 3 , Carmen González-Gasca 4, Cristian Gómez-Rodríguez 5 and Luis Felipe Verdeja 6 1 Nanomaterials and Nanotechnology Research Center (CINN-CSIC), Universidad de Oviedo (UO), Principado de Asturias (PA), Avda. de la Vega, 4-6, 33940 El Entrego, Spain 2 Department of Physical Chemistry and Modelling, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, 30-059 Krakow, Poland; [email protected] 3 Departamento de Ingeniería Geológica y Minera, Escuela Técnica Superior de Ingenieros de Minas y Energía, Universidad Politécnica de Madrid, 28003 Madrid, Spain; [email protected] 4 Vice-Rector’s Office, Universidad Internacional de Valencia, 46002 Valencia, Spain; [email protected] 5 Departamento de Mecánica, Facultad de Ingeniería, Campus Coatzacoalcos, Universidad Veracruzana, Av. Universidad km 7.5 Col. Santa Isabel, Coatzacoalcos 6535, Veracruz, Mexico; [email protected] 6 Department of Materials Science and Metallurgical Engineering, Oviedo School of Mines, Energy and Materials, University of Oviedo, 33004 Oviedo/Uviéu, Spain; [email protected] * Correspondence: [email protected] Abstract: On the one hand, copper slag is nowadays a waste in copper pyrometallurgy despite the significant quantities of iron (>40 wt. %) and copper (1 to 2 wt. %). On the other hand, solar energy, when properly concentrated, offers great potential in high-temperature processes. Therefore, Citation: Fernández-González, D.; concentrated solar power (CSP) could be used in the treatment of copper slag to transform fayalite Prazuch, J.; Ruiz-Bustinza, Í.; into magnetite and copper sulfides and oxides into copper nodules.