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Nickel-Bearing Laterite Deposits in Accretionary Context and the Case of New Caledonia: From the Large- Scale Structure of Earth to Our Everyday Appliances Circum Arctic Structural Events: Tectonic Evolution of the Arctic Margins and Trans Arctic in s ith Ad acent Orogens Edited by Karsten Piepjohn, Justin V. Strauss, Lutz Reinhardt, and William C. McClelland The circum-Arctic region has received considerable attention over the past several decades with vigor- ous debate focused on topics such as mechanisms for opening the Eurasian and Amerasian basins, the importance of plume-related magmatism in the devel- Special Paper 541 opment of the Arctic Ocean, and mechanisms for ancient terrane translation along the Arctic mar- gins. In recognition of the 25th anniversary of the Circum-Arctic Structural Events (CASE) program, an international polar research effort organized ectonic Evolution of the Arctic argins and rans-Arctic Links with Ad acent Orogens and led by the Bundesanstalt für Geowissen- schaften und Rohstoffe (BGR) of Germany, this Circum-Arctic Structural Events volume presents results from 18 major field expeditions involving over 100 international Circum-Arctic Structural Events: with Ad acent Orogens ectonic Evolution of the Arctic argins and rans-Arctic Links geoscientists from a broad spectrum of disci- plines. The resulting publication focuses on the Proterozoic to Cenozoic tectonic evolution of the circum-Arctic region with correlations to adjacent orogens.
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toll-free 1.888.443.4472 | +1.303.357.1000, option 3 | [email protected] MAY 2019 | VOLUME 29, NUMBER 5 SCIENCE 4 Nickel-Bearing Laterite Deposits in Accretionary Context and the Case of New Caledonia: From GSA TODAY (ISSN 1052-5173 USPS 0456-530) prints news the Large-Scale Structure of Earth to Our and information for more than 22,000 GSA member readers Everyday Appliances and subscribing libraries, with 11 monthly issues (March- April is a combined issue). GSA TODAY is published by The Pierre Maurizot et al. Geological Society of America® Inc. (GSA) with offices at 3300 Penrose Place, Boulder, Colorado, USA, and a mail- Cover: A typical hydrous Mg-Ni silicate ore with green garnierite veins ing address of P.O. Box 9140, Boulder, CO 80301-9140, USA. (>2 wt% Ni) (Poro mine, New Caledonia). See related article, p. 4–10. GSA provides this and other forums for the presentation of diverse opinions and positions by scientists worldwide, regardless of race, citizenship, gender, sexual orientation, religion, or political viewpoint. Opinions presented in this publication do not reflect official positions of the Society. © 2019 The Geological Society of America Inc. All rights reserved. Copyright not claimed on content prepared wholly by U.S. government employees within the scope of GSA 2019 Annual Meeting & Exposition their employment. Individual scientists are hereby granted permission, without fees or request to GSA, to use a single 12 Important Dates 52 Hotel Rates figure, table, and/or brief paragraph of text in subsequent work and to make/print unlimited copies of items in GSA 12 2019 Organizing Committee 52 Travel & Transportation TODAY for noncommercial use in classrooms to further education and science. In addition, an author has the right to use his or her article or a portion of the article in a thesis 13 The Grand Canyon State 53 Discover Phoenix or dissertation without requesting permission from GSA, Welcomes You provided the bibliographic citation and the GSA copyright 54 Guest Program credit line are given on the appropriate pages. For any 14 Call for Papers other use, contact [email protected]. 55 Local Tours Subscriptions: GSA members: Contact GSA Sales & Service, 46 GSA’s Associated Societies +1-888-443-4472; +1-303-357-1000 option 3; gsaservice@ 56 GeoCareers geosociety.org for information and/or to place a claim for non-receipt or damaged copies. Nonmembers and institutions: 46 Media Coverage GSA TODAY is US$102/yr; to subscribe, or for claims for 57 On To the Future non-receipt and damaged copies, contact gsaservice@ 47 Schedule at-a-Glance geosociety.org. Claims are honored for one year; please 57 GSA Minority Student allow sufficient delivery time for overseas copies. Peri- 48 Registration Scholarships odicals postage paid at Boulder, Colorado, USA, and at additional mailing offices. Postmaster: Send address changes to GSA Sales & Service, P.O. Box 9140, Boulder, 49 Event Space & Event 59 Scientific Field Trips CO 80301-9140. Listing Requests GSA TODAY STAFF 61 Short Courses 49 Childcare Executive Director and Publisher: Vicki S. McConnell 61 GSA Meetings RISE to the Top Science Editors: Mihai N. Ducea, University of Arizona, 50 Hotels Dept. of Geosciences, Gould-Simpson Building, 1040 E 4th Street, Tucson, Arizona 85721, USA, [email protected] 61 GSA Events Code of Conduct .edu; Peter Copeland, University of Houston, Department 51 Hotel Map of Earth and Atmospheric Sciences, Science & Research Building 1, 3507 Cullen Blvd., Room 314, Houston, Texas 77204-5008, USA, [email protected]. Member Communications Manager: Matt Hudson, 62 Rock Stars: Mary Anning: She Sold (Fossil) Sea Shells by the Seashore [email protected] Managing Editor: Kristen “Kea” Giles, [email protected], 64 Penrose Conference: Climatic Controls on Continental Erosion and Sediment [email protected] Transport: CLAST2019 Graphics Production: Emily Levine, [email protected] Advertising Manager: Ann Crawford, 66 Call for Committee Service +1-800-472-1988 ext. 1053; +1-303-357-1053; Fax: +1-303-357-1070; [email protected] 69 GSA Foundation Update GSA Online: www.geosociety.org GSA TODAY: www.geosociety.org/gsatoday 71 GSA GeoCorpsTM America Program Printed in the USA using pure soy inks. 71 National Park Service Geoscientists-in-the-Parks Opportunities Nickel-Bearing Laterite Deposits in Accretionary Context and the Case of New Caledonia: From the Large-Scale Structure of Earth to Our Everyday Appliances
Pierre Maurizot*, Brice Sevin, Marion Iseppi, Geological Survey of New Caledonia (SGNC/DIMENC), BP 465, 98845, Noumea, New Caledonia; Tanguy Giband, Mineral Authority (SMC/DIMENC), BP M2, 98849, Noumea, New Caledonia
ABSTRACT control nickel deposits is therefore crucial Ultramafic rocks are composed of silicate Nickel production is vital to modern to industrial development. minerals, notably olivine, which are, economic development. Of the different If one excludes polymetallic nodules of under wet and warm intertropical cli- ore types, supergene Ni-laterite produc- the ocean floor, for which mining tech- mates, unstable and rapidly weathered tion, as open-cast mining exploitation, nology and jurisdictional issues are still (Thorne et al., 2012; Wilson, 2004). Mg is on the rise and surpassing the more not solved (Volkmann and Lehnen, 2017), and Si are released, whereas Fe, Al, Ni, conventional hypogene sulfide type. This two main types of nickel deposits are and Co stay in situ. Consequently, a thick, trend will likely continue. Assessing the known on land worldwide (Mudd and soft, residual cover of typical red- to global resource of Ni laterite is therefore Jowitt, 2014): (i) hypogene magmatic yellow-colored Fe oxy-hydroxides accu- of crucial importance. Compilation of nickel-sulfide deposits are found as lodes mulates, at times capped with ferricrete scientific publications shows that the or layered complexes in ancient cratons (Fig. 2). Nickel is then concentrated up to main producers and occurrences are and are mostly mined underground; and a grade of 1%–2% or even more (Butt, concentrated in a few countries in South- (ii) supergene Ni-laterite deposits, which 2007; Freyssinet et al., 2005; Gleeson et east Asia (New Caledonia, Indonesia, are formed by weathering of exposed al., 2003). This natural supergene process the Philippines) and the Caribbean region ultramafic units, and as such are exploited of enrichment is very efficient with a (Cuba and the Dominican Republic). In in open pits. second-enrichment factor of 10 times Supergene mineral deposits are low- compared to the initial ultramafic proto- these regions a common geological back- grade, large-tonnage resources, exploited lith and 200 times the average Earth crust ground appears, characterized by large in easy surface conditions (ICMM, 2012). composition. Grades of Ni-laterite depos- obducted ophiolites in tectonically active In the last decade, global production of Ni its (0.8–15 wt% Ni) exceed that of mag- settings, subject to weathering during the laterite has overtaken Ni sulfide (60% vs. matic Ni-sulfide deposits (0.5–5 wt% Ni; Neogene. The neoformed mineralogy 40% according to Mudd and Jowitt, 2014), Arndt and Ganino, 2012). Cobalt is, in of such surficial deposits is well docu- and the laterite proportion is still growing. some deposits, enriched in the same mented. A model is proposed, based on Nickel-laterite deposits require ultra- proportion, but its initial and final con- the knowledge gained on Ni-laterite mafic protoliths, such as Precambrian centrations are roughly 10 times lower. deposits in New Caledonia, that could komatiites and layered complexes or In addition, recent studies about scan- be applied to similar geological settings Phanerozoic ophiolites. Ophiolites corre- dium enrichment within Ni-Co laterites worldwide. This model states that in spond to remnants of oceanic mantle and of New Caledonia show that Sc-bearing accretionary terranes, vertical motions crust emplaced on land in collision zones goethites contain about 10 times the Sc during weathering control both ore involving oceanic plates (Coleman, 1977). content of the parent rock (up to 100 ppm; type and location. Mantle rocks are not commonly exposed Teitler et al., 2018). at Earth’s surface and hence are restricted Scientific research on Ni-Co laterites, INTRODUCTION to a few countries (Fig. 1). which present in essence a strong hetero- Nickel-based alloys are used in many Typical mantle rocks have been geneity, is still low globally. New applications, from modern information enriched, through repeated partial melt- Caledonia, a small French overseas and communication technologies to large- ing and extraction episodes, in nickel up territory in the southwest Pacific, holds scale industrial infrastructures, including to 0.18 wt%; i.e., 20 times the average ~25% of the global Ni-laterite resource stainless-steel products used in our every- Earth crust concentration (Palme and (Berger et al., 2011; Mudd and Jowitt, day life, such as coins, beer kegs, coffee O’Neill, 2014). However, economically, 2014). In terms of surface (18,500 km2) spoons, and much more. Improving this is not significant, and a secondary and population (~300,000), the archipel- knowledge about geological factors that enrichment process has to take place. ago is certainly the smallest among the
GSA Today, v. 29, doi: 10.1130/GSATG364A.1. Copyright 2019, The Geological Society of America. CC-BY-NC.
*Email: [email protected]
4 GSA Today | May 2019 0° A 30°S 60°S 60°N 30°N 0° w 30°S C km Go ro C Ne niambo Caledonia Isabela Island a 1 000 Ko 150°E Tiébaghi PNG New Caledonia alia Philippines Indonesia tr le E 150° E 150° E va Aus 120° een Ram u pua New Guine Gr s Pa anma r cloop alia Cy My tr s Aus 90°E n Bulong an s India ro a Pujada Philippine ascar Casigur y Russia Murrin Murri oa ko 60°E Mindo e Sor da Ba Madag ong Acoje/Zambale We Caws hiopia Indonesi Ber 120° E 120° E Et e 0° 30°S Burundi eec s e Gr 30°E oon Camer t type deposit te ous Mg-Ni silicat e 0° 0° ri y dr te Hy Oxid Cla o Ivory Coas 60°W 60°W Ni La a 30°W 30°W Loma de Hierr nezuel azil lcondo public Ve ones Br Fa Re Dominican a o Matoso Mo a 60°W 60°W a Cerr ro e subducon z ginal basins Cuba Cuba Colombi Go rd Nica Acv Mar e ta y lip Pun Fe 90°W San Camague a pa z B ra A Baja Ve Philippines US s New Caledoni d t ce 90°W 90°W Indonesia leocen e Pa esen sour km mala Re Cuba te
ic of W zo < 10 10 - 20 20 - 30 azi l st Gua 150° W etaceous to Br Re alia 1 000 e of the weathering Meso Miocene to Pr Cr tr the world Ag Aus Mt Ni metal containe B 30° N 0° Figure (A) 1. to Global sensitive highly being profiles resource Weathering 1993). of Ni Tardy, metal (after zones lateritic contained main world’s the of in envelope laterite the represent areas dashed Orange highlighted. type is located, deposits by country (after Berger et al., The 2011). intertropicalerosion, zone, where most of the most preserved of the deposits nickel are laterite deposits are (geologically)and older deposits young formed and are during found in the past intertropical warm climate periods. belt. Insets:and Higher-latitude deposit (B) the types. Caribbean PNG—Papua occurrences and New (C) SW Guinea. Asia–Oceania correspond to regions, minor showing individual and mostly known deposits
www.geosociety.org/gsatoday 5 major Ni-producing countries, but it is Lithology OreTerminology recognized by metallogenists (Laznicka, 2006) as one of the largest and richest Ni-providing areas in the world. Many scientific aspects are addressed by 0 m Duricrust
Ni-laterite deposits, including resources, La
processes, environment, and societal te ri impact (CNRT, 2017). In this paper, we te re 10 Plasmic present some recent advances in knowl- horizon siduum edge of geological controls and Ni specia- Figure 2. Weathering pro- tion of these deposits in some emblematic files on ultramafic proto- regions of the world and the contribution lith. Lithology: common 20 terminology of the differ- of New Caledonia in this respect. ent horizons of the weath- ering profile and reaction fronts (after Eggleton, enrichment
ORE TYPOLOGY Re 2001; Freyssinet et al., Oxide Three types of Ni-laterite ore types, sidua Ferruginous 2005; Butt and Cluzel, 30 saprolite 2013). Ore: enrichment and hence deposits, are known worldwide l and ore types. (Brand et al., 1998; Freyssinet et al., 2005; Sapr
Golightly, 2010; Butt and Cluzel, 2013), olit
although mixed-type deposits are frequent: 440 Mg e disconnuiy
(i) hydrous Mg-Ni silicate (garnieritic) ore Mg-Ni silicat enrichment Saprolite Absolut has the highest Ni grade, commonly ≥2 Hy dr
wt% Ni with very low Co; (ii) oxide ore is ous Saprock 505 e
dominated by iron oxy-hydroxides, with e 1.5 wt% Ni on average and generally Weathering recoverable Co up to 0.3 wt%; (iii) clay front deposits are dominated by Ni-bearing Bedrock swelling clays (nontronite), containing 606 Ni in the same range as oxide deposits. Garnierite was first discovered by Jules Garnier in New Caledonia (Garnier, 1867). where the topographic gradient is low, Southeast Asia, and the Caribbean region, Garnierite is actually a field term not internal drainage is weak, the water table all within ~25° of the equator (Fig. 1). recognized by the International Mineral is high, leaching and precipitation are lim- These countries hold more than 50% of Association (IMA), referring to a rather ited, and Ni enrichment is mainly residual, the global Ni laterite and were in the top complex mixture of poorly crystalized located in the saprolite horizon; con- five Ni producers for the past decade. phyllosilicate phases composed mainly of versely, hydrous Mg-Ni silicate dominant They present a similar geological setting, serpentinite-like, talc-like, chlorite-like, ore deposits are formed where the topo- as islands emerging from a series of sinu- and clay-like phases (Fritsch et al., 2016). graphic gradient is important, internal ous eastern-facing belts, corresponding to The appended “-like” refers to a certain drainage is free, the water table is low, complex ocean-ocean or continent-ocean weakness in the crystallinity of these leaching and precipitation are optimal, convergence zones, distributed along the phases and stacking disorder. Most of the and Ni enrichment is mainly absolute and western parts of the Pacific and Atlantic types individualized so far belong to a located deeper in the saprock. Oceans. They are separated from the con- continuous solid-solution from Mg to Ni Theoretically, calculated as purely tinent to the west by marginal basins and end-members. These highly variable, “residual enrichment,” a simple removal from the ocean to the east by island arcs poorly crystallized minerals can have up of mobile elements would result in 0.6–1 and active subduction or transcurrent to 27% Ni (Freyssinet et al., 2005). wt% Ni (Brand and Butt, 2001). Therefore, fault zones. On land, most of these belts Clay deposits are typical of large, stable higher grades recorded in saprock of include one or several ultramafic terranes, continental, or cratonic, areas, formed on hydrous Mg-Ni deposits must be explained remnants of short-lived (~50 m.y.) mar- Archean to Proterozoic ultramafic layered by other factors and are referred to as ginal basins opened above successive intrusions or komatiite, further weathered “absolute enrichment.” The total mass loss subduction planes and then accreted dur- in the Mesozoic, continuing to the present and dissolved phase may reach 80% of the ing repeated convergence periods. Most (e.g., in Australia, Brazil, and Africa), fresh rock (Trescases, 1975; Brand and of these ophiolites were emplaced during whereas hydrous Mg-Ni silicate formed Butt, 2001; Freyssinet et al., 2005). the (Late) Cretaceous to Paleogene peri- mostly on ophiolites, eventually weathered ods. In this accretionary context, lying in in the Late Mesozoic to Cenozoic. Oxide GEOLOGY AND METALLOGENY the intertropical zone, weathering started deposits are present in both contexts. For The four highest-ranked countries by as soon as the Oligocene. Hydrous Mg-Ni many authors (Elias, 2002; Freyssinet et Ni-laterite resource (New Caledonia, silicate deposits are dominant, and oxide al., 2005; Golightly, 1981; Trescases, 1975), Philippines, Indonesia, and Cuba) are or clay deposits are subordinate. A major- oxide-dominant ore deposits are formed located in the Southwest Pacific, ity of these countries are tectonically still
6 GSA Today | May 2019 active, in the sense that they are under the (Collot et al., 1987), which was emplaced erosion, a deep weathering profile may influence of an active plate boundary. onto the continental Norfolk Ridge at the be preserved. Conversely, it is destroyed. The striking asymmetrical distribution end of the Eocene (Cluzel et al., 2012) Mantle rocks (dunite, harzburgite, of the marginal basins-arc-trench system and was mentioned as a typical example lherzolite), which have a very low at Earth’s surface, which was remarked of the obduction concept defined by hydraulic conductivity, are, however, upon by some authors in the early stages Coleman (1971). densely fractured as a result of their long of global tectonic theory (e.g., Uyeda and The terrane was exposed to emergence, evolution in oceanic domains and their Kanamori, 1979), is out of the scope of dismantling, weathering, and erosion eventual obduction. Serpentinization of this paper, but the coincidence of (i) the during the Neogene post-obduction the protolith, diffuse or closely associ- large-scale structure of the Earth, where period. Early Miocene conglomerate of ated with fracturing, is a common altera- important portions of oceanic crust and the Népoui area reworks abundant weath- tion, which, on the whole, corresponds to mantle have been thrusted on land, and of ered products of the peridotite, including hydration and cooling of the lithospheric (ii) a warm and wet intertropical climate supergene nickel ore (Coudray, 1971; mantle rocks. Once exposed on land, belt, illustrates perfectly how the overlap- Maurizot et al., 2016). The oldest weath- above sea level, the fracture network ping of two independent factors may be ering profiles have been dated indirectly allows pervasive underground water cir- determinant in the formation and location by paleomagnetism methods at 25 Ma culation and setting up of a water table. of a mineral resource. (Sevin et al., 2012). The nickel ore– Through internal water fluctuations and In a comparable accretionary context, forming process was therefore already circulation, fluids in the ultramafic pro- New Caledonia is the emerged part of active at the end of Oligocene, ~10 m.y. tolith propagate weathering, leading to a the Norfolk Ridge in the northern part of after obduction, and is likely ongoing, general saprolitization, karstification what has been recently referred to as as attested to by dissolution activity and with sinkholes, underground conduits, Zealandia, a mostly submerged continent youngest paleomagnetic ages. and lapies. A complete and differentiated (Mortimer et al., 2017). In this area of weathering profile may reach 50 m in interaction between the Australian and THE NICKEL FACTORY thickness. The youngest and active front Pacific plates, the Eastern Gondwana Worldwide, Ni-Co–laterite deposits is at the base, the oldest at the top. It margin has been fragmented into several are controlled by a wide range of inter- comprises, from top to base (Eggleton, thinned continental ribbons and exten- acting factors (Freyssinet et al., 2005; 2001; Fig. 2): sional basins, some of which are oceanic Butt and Cluzel, 2013): lithology (includ- • Lateritic residuum divided into: (e.g., the Tasman Sea and Loyalty ing serpentinization) of the ultramafic - The topmost duricrust (or ferricrete basins). The most emblematic and prom- rock, fracturing, permeability, climate or iron cap), which corresponds to inent geological unit of Grande Terre, change, tectonic activity, and morpho- the zone of oscillation of the sub- the “main island” of New Caledonia, is logic evolution. Weathering tends to surface water table, where alternat- the Peridotite Nappe (Avias, 1967; Fig. accumulate laterite and thus nickel; ing saturated and unsaturated condi- 3), which covers about a third of the sur- tectonic activity or eustatic variations tions allow precipitating of massive face area of the country. The ultramafic tend to erode and destroy, or cover up iron oxy-hydroxides; terrane is interpreted as the lithospheric and conceal, these accumulations. If the - A plasmic zone (or red limonite), mantle of the Late Cretaceous to Paleo- rate of chemical weathering of a perido- in which all primary structures gene South Loyalty Marginal Basin tite is greater than the rate of physical are erased;
Figure 3. Simplified geological map of Grande Terre and section along Grande Terre showing the general shape of the ultramafic terrane.
www.geosociety.org/gsatoday 7 - Ferruginous saprolite (or yellow A MODEL FOR Ni-LATERITE that this uplift, which started as soon as limonite), where the inherited bed- DEPOSITS IN ACCRETIONARY 25 Ma (Sevin et al., 2014), is still active as rock structure is retained but trans- TERRANES recorded in the construction of the formation to a soft material is almost Owing to its importance regarding ore Pleistocene and Holocene reef barrier that complete, correlative of an important processing, detailed publications on the rims Grande Terre (Cabioch, 2003). mass loss. mineralogy and geochemistry of deposits In New Caledonia, mining geologists • Saprolite divided into: worldwide are generally available. commonly distinguish deposit types - Saprolite (more than 20% of weath- However, the shape of deposits and distri- according to their geomorphological ered rock), in which concentric sphe- bution of ore grades are rarely docu- context (Fig. 4); namely, basin, plateau, roidal weathering preserves blocks or mented. The strategy of exploration for and mountain (crest or slope) deposits boulders of fresh rocks (corestones); many mining companies is commonly (Trotet et al., 2015). Basin deposits host - Saprock (less than 20% of weathered very basic, consisting of expensive and large areas of dominant oxide ore (e.g., rock). Saprock may be the Ni-richest environmentally harmful systematic grid Goro, Prony). Mountain deposits typically horizon. drillings with a mesh adapted to the high host smaller-sized deposits, with typical • Protolith fresh peridotite. variability of the Ni content (Ni semi- high-grade hydrous Mg-Ni silicate ore. The highest concentration of nickel is variogram ranges are commonly <20 m). Plateau deposits are intermediate with at the base of the weathering profile, in The experience and knowledge gained both types of ore, including even clay the typical high-grade hydrous Mg-Ni from research on deposits in New mineralogy (e.g., Tiébaghi). This typol- silicate ore type, where its concentration Caledonia can be applied to exploration ogy of deposit and geomorphological may reach several tenths of a percent of in accretionary terranes elsewhere. features can be associated in a consistent Ni. In the saprock and above, early- At a large scale, the regolith surfaces model (Maurizot et al., 2019). Basins, formed serpentinite can be secondarily topping the Peridotite Nappe are enclosed plateaus (which are inverted basins), and enriched up to 3–6 wt% by Ni-Mg sub- in a broad, shallow-dipping envelope, mountainous areas (which are dissected stitution. The degree of serpentinization delineating a conspicuous longitudinal up plateaus) may be considered as different of the protolith is therefore an important warp (Fig. 3; Sevin et al., 2012). At both steps of a continuum of geomorphological factor of mineralization, which greatly ends of Grande Terre (Iles Béleps to the evolution on which the nickel factory has contributes to Ni grade, more than the north and Ile des Pins to the south), the evolved through time (Fig. 4). degree of weathering (Orloff, 1968; major duricrust surfaces plunge under sea The rate of chemical weathering versus Pelletier, 1996; Trotet et al., 2015). When level, whereas in the middle of the island, the rate of physical erosion (driven by early serpentine is saturated in Ni, the dismantled regolith surfaces culminate at post-obduction deformation) is therefore typical green-colored garnierite precipi- more than 1000 m. Although disrupted at crucial in the constitution of Ni resources. tates commonly as a stockwork of veins. smaller scale by many discontinuities and Where subsidence prevails and internal Garnierite occurrences are generally associated with complex sets of stepped drainage is impeded, Ni concentrations associated with other supergene precipi- benches, this bulge shape is interpreted as will cease to increase and will be buried tates, including variously crystalized the result of the long-term post-obduction under sediments (e.g., Fluvio-lacustrine silica (chalcedony, quartz), as brecciated isostatic re-equilibrium. It is worth noting Formation, near the Goro deposit; Folcher veins, sigmoidal fillings, and slickenside coating on serpentinite fault planes, indi- cating a complex supergene syn-tectonic Economic window
evolution (Cluzel and Vigier, 2008; Size Large size (world class) Small size Genna et al., 2005; Iseppi et al., 2018). Grade Low grade (Ni <= 1 wt %) High grade (Ni > 1.5 wt %) Ore main Higher in the profile, the Mg disconti- regolith Laterite>saprock Saprock>laterite horizon Oxide Hydrous Mg-Ni nuity is characterized by a drastic change Deposit Ore type Co by-product silicate Enrichment ResidualAbsolute in the Mg, Si, and Fe proportion. A num- 1 000 m ber of dark Mn- and Co-rich concretions
appear that include phyllomanganate fam- Low Altude ily minerals, which are the main Co (and Water table Ni) carriers (Llorca, 1993; Freyssinet et Sea level High al., 2005; Roqué-Rosell et al., 2010; 0 Fritsch et al., 2014). In the rest of the profile, Ni is mainly hosted by iron oxy-
hydroxides (dominant goethite, subordi- Morphology Drowned offshore Basin Plateau Mountain nate hematite) in the typical low-grade Dominant external Subsidence Weathering Upli oxide ore type. Nickel content is corre- forcing factor Burial Erosion lated with goethite crystallinity and anti- Tectonics Weak structural control High structural control correlated with hematite proportion. Nickel content thus decreases, while Figure 4. A model for Ni-laterite deposits in New Caledonia. Typology, based upon geomorphology, hematite increases upward (Dublet et al., geology, and economic factors of Ni deposits, is a function of altitude, which in turn is a function 2015, 2012). of time.
8 GSA Today | May 2019 et al., 2015) or drowned below sea level Implication for nickel sulphide exploration: Geochimica et Cosmochimica Acta, v. 160, (e.g., at both ends of Grande Terre). When Geochemistry: Exploration, Environment, p. 1–15, https://doi.org/10.1016/j.gca.2015.03.015. the rate of uplift compensates for the rate Analysis, v. 1, p. 391–407, https://doi.org/ Eggleton, R.A., 2001, The regolith glossary: 10.1144/geochem.1.4.391. Cooperative Centre for Landscape Evolution of weathering, large contiguous basin Brand, N.W., Butt, C.R.M., and Elias, M., 1998, and Mineral Exploration, Canberra, National deposits can form, with dominant residual Exploration model: The Cawse shear-controlled Capital Printing, 144 p. enrichment and oxide type ore (e.g., Ni-oxide and associated Mn-Co-Ni deposit, Elias, M., 2002, Nickel laterite deposits— Goro). Where the rate of uplift is higher Western Australia AGSO: Journal of Australian Geological overview, resources and explora- than the rate of weathering, basins are Geology and Geophysics, v. 17, p. 81–88. tion: Hobart, University of Tasmania, CODES Butt, C.R.M., 2007, Nickel laterites: Characteris- Special Publication, v. 4, p. 205–220. inverted to plateaus, and absolute enrich- tics, classification and processing options, Folcher, N., Sevin, B., Quesnel, F., Lignier, V., ment prevails, forming the typical high- in Proceedings 2007 Minerals Exploration Allenbach, M., Maurizot, P., and Cluzel, D., grade hydrous Mg-Ni ore deeper in the Seminar Abstracts: Cooperative Research 2015, Neogene terrestrial sediments: A record of profile (e.g., Tiébaghi, Koniambo). Centre for Landscape Environments and the post-obduction history of New Caledonia: Mineral Exploration, p. 10. Australian Journal of Earth Sciences: An Beyond that, in mountainous areas, the Butt, C.R.M., and Cluzel, D., 2013, Nickel laterite International Geoscience Journal of the trend of enrichment is enforced by more ore deposits: Weathered serpentinites: Geological Society of Australia, p. 379–492. uplift, to the expense, however, of a par- Elements, v. 9, p. 123–128, https://doi.org/ Freyssinet, P., Butt, C.R.M., and Morris, R.C., tial destruction and fragmentation of the 10.2113/gselements.9.2.123. 2005, Ore-forming processes related to deposits, which are dissected by erosion. Cabioch, G., 2003, Postglacial reef development lateritic weathering: Economic Geology, 100th in the South-West Pacific: Case studies from Anniversary Volume, p. 681–722. This last stage before complete destruc- New Caledonia and Vanuatu: Sedimentary Fritsch, E., Juillot, F., Dublet, G., Fandeur, D., tion of deposits is exemplified by many Geology, v. 159, no. 1–2, p. 43–59, https://doi Fonteneau, L., Martin, E., Auzente, A.L., small high-grade deposits disseminated in .org/10.1016/S0037-0738(03)00094-0. Morin, G., Robert, J.L., Galoisy, L., Calas, G., New Caledonia, which were mined in the Cluzel, D., and Vigier, B., 2008, Syntectonic Grauby, O., Boulvais, P., and Cathelineau, M., mobility of supergene nickel ores of New 2014, Analyse fine de minerais latéritiques early time of Ni exploitation. Caledonia (southwest Pacific). Evidence from (approches pétrographique, minéralogique, garnierite veins and faulted regolith: Resource géochimique et isotopique): CNRT, Rapport CONCLUSIONS Geology, v. 58, p. 161–170, https://doi.org/ final, 131 p. World Ni consumption is growing, and 10.1111/j.1751-3928.2008.00053.x. 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10 GSA Today | May 2019 Field Guide 52 Exploring Extreme and Unusual Geology in the Stable Midcontinent
Field Excursions for the 2019 GSA South-Central, North-Central, and Rocky Mountain Sections Joint Meeting
Edited by Marcia K. Schulmeister and James S. Aber
The at-lying sedimentary strata of the North American midconti-
nent are typically thought of as uniform and predictable. However, Edited by M.K. Schulmeister and J.S. Aber Aber J.S. and Schulmeister M.K. by Edited midcontinent geology contains a record of exciting geologic events and processes. The papers in this volume examine four geologic Field Guide 52 phenomena associated with the continental interior: Pennsylva- Exploring Extreme and Unusual Geology nian and Permian cyclothems, the origin of a massive Permian salt deposit, Cretaceous kimberlite intrusions, and Quaternary in the Stable Midcontinent
glacial geology. The guides cover processes and events that are Field Excursions for the 2019 GSA South-Central, North-Central,
| Exploring Extreme and nusual eology in the Sta le idcontinent Sta le the in eology nusual and Extreme Exploring unique to the geology of Kansas and highlight important eco- and Rocky Mountain Sections Joint Meeting nomic and rich historical in uences of these geologic features.
Edited by Marcia K. Schulmeister and James S. Aber FLD052, 70 p., ISBN 9780813700526 list price $38.00 | mem er price