NEW MINERAL NAMES* JOHN L. JAMBOR,Jacekpuziewicz

Total Page:16

File Type:pdf, Size:1020Kb

NEW MINERAL NAMES* JOHN L. JAMBOR,Jacekpuziewicz American Mineralogist. Volume 71, pages 1277-1282. 1986 NEW MINERAL NAMES* FRANK C. HAWTHORNE, MICHAEL FLEISCHER, EDWARD S. GREW, JOEL D. GRICE, JOHN L. JAMBOR, JACEK PuZIEWICZ, ANDREWC. ROBERTS, DAVIDA. VANKO,JANET A. ZILCZER Bastnaesite group minerals mineralization within alluvial deposits, found in the Aldan shield and in Kamchatka, eastern USSR. Other associated mineral in- Z. Maksimovic, Gy. Panto (1983) Mineralogy of yttrium and clusions are cuprorhodsite, malanite, native Os, iridosmine, lau- lanthanide elements in karstic bauxite deposits. Trav. Comite rite, erlichmanite, cooperite, sperrylite, chalcopyrite, and bornite. Internatl. Etude Bauxites, Alumine, et Aluminum, 13, 191- 200 (in English). No cleavage. Color is iron black, metallic luster, gray in reflected light. Microhardness is 578 ::t 140 kglmm2, with 30-g load. Very Electron-microprobe analyses are given of secondary phos- brittle. Reflectancesare [nm(%)] 460(35.0-37.5), 480(34.4-37.2), phates from the lower parts of karstic bauxites from Hungary 500(34.0-37.1), 520(34.0-37.1), 540(33.6-37.2), 560(33.4-37.2), and Yugoslavia, including bastnaesite-(Ce), bastnaesite-(La), syn- 580(33.1-37.5), 600(32.8-37.7), 620(32.6-37.8), 640(32.4-37.8), chysite-(Nd), monazite-(Nd) (see Am. Mineral., 68, 849), neo- 660(32.2-37.8), 680(32.1-38.1), 700(32.0-38.4), 720(32.0-38.7), dymian goyazite, and two new members of the bastnaesite group. 740(32.0-38.8). The minerals occur as fine-grained fracture fillings. The analyses The name is for the chemical composition. Polished thin sec- ofhydroxyl-bastnaesite-(La) and hydroxyl-bastnaesite-(Nd), yield tions containing the mineral are at the Mining Museum, Len- the following calculated formulas (C02 and H20 calculated, not ingrad Mining Institute. D.A.V. determined). (LaO.51 Ceo.ol Pr o.ION do.37Smo.06EUo.02Gdo.03Cao.06) 1.12(C03) 1.00- (Fo.ll(OH)o.,,), Cuprorhodsite* (Lao..,Pro.12Ndo.49Smo.07EUo.03Gdo.02),.o.(C03), (Fo.I.(O H)0.57)' N.S. Rudashevskii, YU.P. Men'shikov, A.G. Mochalov, N.V. (Lao.30Ceo.osPro.08N do.37Smo.07Euo.03Gdo.osDy 0.01Er 0.01Y 0.08Cao.05)1.10- (CO 3)I.OO(F0.28(0 H)0.38)' Trubkin, N.!. Shumskaia, V.V. Zhdanov(1985)Cuprorhodsite CuRh2S. and cuproiridsite CuIr2S.-New natural thiospinels (Lao.2SCeO.03Pr 0.08N do.sl Smo.09Euo.02Gdo.05 Y 0.0.Cao.03) I.IO(C03) 1.00- of platinum elements. Zapiski Vses. Mineralog. Obshch., 114, (F0.17(OH)0.S2)' Discussion. The new varieties are referred to as bastnaesite- 187-195 (in Russian). (Nd), and bastnaesite-(La) in one place, and as hydroxyl-bast- Analysis of the mineral (one of ten given) by electron micro- naesite in another, within the paper. With the calculated values probe gave Rh 39.6, Ir 10.3, Pt 6.8, Cu 7.55, Fe 5.31, S 29.8, of C02 and H20, the first-given formula corresponds to hydroxyl- sum 99.36%, corresponding to (Cuo.51Feo.4I)(RhI.66Iro.23Pto.15)S., bastnaesite-(La), and the remaining three to hydroxyl-bastnaes- Ideally, CuRh2S.. The mineral is not corroded by warm aqua ite-(Nd). Complete analyses, X-ray data, and physical properties regia. are needed to validate these as species. M.F. X-ray study (powder method) shows the mineral to be cubic, space group Fd3m, a = 9.88(1) A, Z = 8, = 6.74. The strongest lines (18 given) are 3.00(100)(311); D"""2.480(70)(400); Cuproiridsite* 1.904(80)(333,511); 1.758(100)(440); 1.009(90)(844). N.S. Rudashevskii, YU.P. Men'shikov, A.G. Mochalov, N.V. The mineral occurs as small (to 300 ILm) inclusions in angular Trubkin, NJ. Shumskaia, V.V. Zhdanov (1985) Cuprorhodsite isoferroplatinum host grains that are, in turn, the result of Pt CuRh2S. and cuproiridsite CuIr 2S.- New natural thiospinels mineralization within alluvial deposits, found in the Aldan shield of platinum elements. Zapiski Vses. Mineralog. Obshch., 114, and in Kamchatka, eastern USSR. Other associated mineral in- 187-195 (in Russian). clusions are cuproiridsite, malanite, native Os, iridosmine, lau- rite, erlichmanite, cooperite, sperrylite, chalcopyrite, and bornite. Analysis of the mineral (one of 26 given) by electron micro- No cleavage. Color is iron black, metallic luster, gray in reflected probe gave Rh 6.05, Ir 48.9, Pt 10.5, Cu 7.41, Fe 3.17, Ni 0.27, light. Microhardness is 498 ::t 30 kglmm2, with a 50-g load. Very S 24.6, sum 100.9%, corresponding to (CUo.6IFeo.30Nio.02)(Rho31" brittle. Reflectances are [nm(%)] 460(35.6-39.5), 480(35.8-39.3), IrL33Pto.28)S., Ideally, CuIr2S.. The mineral is not corroded by 500(36.4-39.3), 520(36.6-39.2), 540(36.7-39.2), 560(36.8-39.1), warm aqua regia. 580(36.9-39.1), 600(37.0-39.1), 620(37.0-39.0), 640(37.0-38.9), X-ray study (powder method) shows the mineral to be cubic, 660(36.9-38.8), 680(36.8-38.8), 700(36.7-38.7), 720(36.6-38.6), space group Fd3m, a = 9.92(1) A, Z 8, 7.24. The 740(36.6-38.5). = D""" = strongest lines (20 given) are 3.00(100)(311); 2.489(90)(400); The name is for the chemical composition. Polished thin sec- 1.912(70)(333,511); 1.760(100)(440); 1.011(70)(844). tions containing the mineral are at the Mining Museum, Len- The mineral occurs as small (to 300 ILm) inclusions in angular ingrad Mining Institute. D.A.V. isoferroplatinum host grains that are, in turn, the result of Pt Imiterite* Minerals marked with asterisks were approved before pub- * lication by the Commission on New Minerals and Mineral Names J.-J. Guillou, J. Monthel, P. Picot, F. Pillard, J. Protas, J.-C. of the International Mineralogical Association. Samama (1985) Imiterite, Ag2HgS2,a new mineral species: 0003-004X/86/0910-1277$02.00 1277 1278 NEW MINERAL NAMES Properties and crystal structure. Bull. Mineral., 108, 457-464 540,76.1,76.1; 560,75.3,77.4; 580,74.3,78.4; 600,73.2,79.2; (in French). 620,72.0,79.7; 640,70.7,79.8; 660,69.5,79.9; 680,68.5,79.8; The average of20 electron-microprobe analyses gave Ag 42.89, 700,67.5,79.5; 720,66.5,79.2; 740,65.9,78.7%. Hg 42.64, S 13.34, total 98.87%, which yields the empirical for- The mineral forms prismatic crystals from 100 x 100-120 up mula AgI.91Hgl.02SZ.00' to 200 x 300 or 60 x 400 ILm,with cleavage parallel to {100}. A single-crystal, X-ray diffraction structure analysis shows the The name is for the locality. mineral to be monoclinic, space group P2/e, a = 4.039(1), b = Cupalite 8.0052(6), e = 6.580(1) A, (3 = 107.11(2), V = 203.3(1) A3, Z = 2, 7.85g1cm3. The refined structure (R Microprobe analyses (nine grains) gave Cu 59.9-61.7, AI 29.3- D"'le = = 0.035 for 552 independent observed reflections) shows S atoms having a dis- 30.4, Zn 7.66-9.35, sum 98.61-100.45%, with negative corre- torted hexagonal close packing with Hg linearly co-ordinated and lation between Cu and Zn, corresponding to (Cu,Zn)Al. Ag trigonal-planar co-ordinated. The strongest X-ray diffraction X-ray study (Debye-Scherrer method) showed the mineral to lines (23 given) are 4.88(30)(011), 3.466(50)(110,111), be orthorhombic, a = 6.95(1), b = 4.16(1), e = 10.04(1) A, Z = 3.138(30)(002), 2.768(100)(102,121), 2.746(100)(111), 10, D,,"c = 5.12. The X-ray pattern is similar to that of synthetic 2.461 (80)(022,031), 1.959(30)(132,21 I), 1.467(35)(142,202,024). CuAlz, which has a centered orthorhombic cell. The strongest Imiterite occurs as anhedral grains up to I mm, with VHNlOo X-ray reflections (seven given) are 5.07(10)(002), 4.12(8)(010), 3.59(2)(110). = 86. In reflected light, it is light gray, pleochroic from bluish to pinkish and strongly anisotropic from blue to red-brown. The Cupalite is opaque, steel yellow. Luster metallic. Hardness 272- 318 kglmmz (20- and 50-g load). reflectance values range from 38.3 and 33.4 for A = 440 nm to 27.4 and 25.3 for A = 800 nm. In reflected light, the mineral has very weak bireflectance from The new mineral is associated with chalcopyrite, sphalerite, light gray to gray; under crossed nichols, it is weakly anisotropic polybasite, galena, and arsenopyrite in the Imiter mine, Jbel from gray to dark gray. Reflectance measurements (Rm, %, 20 Sarhro, Anti-Atlas, Morocco. It derives its name from the mine nm steps from 440 to 740 nm): 66.8, 66.1, 65.3, 64.5, 63.7, 62.9, locality; type material, consisting of polished sections, is at the 62.1,61.3,60.4,59.7,58.9,58.2,57.7,57.2,56.9,56.5. Ecole des Mines de Paris and at the Bureau de Recherches Geo- The mineral occurs as myrmekitic and dendritic droplike grains logiques et Minieres a Orleans-la-Source. J.D.G. from I x 4 to 5 x 35 ILm within khatyrkite (first generation) and as rounded or irregular grains from I x 5 to lOx 20 ILm in cracks and interstices in khatyrkite (second generation; this is usually intergrown with unnamed zinc aluminides).
Recommended publications
  • Thirty-Fourth List of New Mineral Names
    MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given.
    [Show full text]
  • Aperiodic Mineral Structures
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Infoscience - École polytechnique fédérale de Lausanne EMU Notes in Mineralogy, Vol. 19 (2017), Chapter 5, 213–254 Aperiodic mineral structures L. BINDI1 and G. CHAPUIS2 1 Dipartimento di Scienze della Terra, Universita` di Firenze, Via La Pira 4, I-50121 Firenze, Italy 2 Laboratoire de Cristallographie, E´cole Polytechnique Fe´de´rale de Lausanne, CH-1015 Lausanne, Switzerland The three-dimensional periodic nature of crystalline structures was so strongly anchored in the minds of scientists that the numerous indications that seemed to question this model struggled to acquire the status of validity. The discovery of aperiodic crystals, a generic term including modulated, composite and quasicrystal structures, started in the 1970s with the discovery of incommensurately modulated structures and the presence of satellite reflections surrounding the main reflections in the diffraction patterns. The need to use additional integers to index such diffractograms was soon adopted and theoretical considerations showed that any crystal structure requiring more than three integers to index its diffraction pattern could be described as a periodic object in a higher dimensional space, i.e. superspace, with dimension equal to the number of required integers. The structure observed in physical space is thus a three-dimensional intersection of the structure described as periodic in superspace. Once the symmetry properties of aperiodic crystals were established, the superspace theory was soon adopted in order to describe numerous examples of incommensurate crystal structures from natural and synthetic organic and inorganic compounds even to proteins. Aperiodic crystals thus exhibit perfect atomic structures with long-range order, but without any three-dimensional translational symmetry.
    [Show full text]
  • Previously Unknown Quasicrystal Periodic Approximant Found in Space Received: 13 August 2018 Luca Bindi 1, Joyce Pham 2 & Paul J
    www.nature.com/scientificreports OPEN Previously unknown quasicrystal periodic approximant found in space Received: 13 August 2018 Luca Bindi 1, Joyce Pham 2 & Paul J. Steinhardt3,4 Accepted: 16 October 2018 We report the discovery of Al Ni Fe , the frst natural known periodic crystalline approximant Published: xx xx xxxx 34 9 2 to decagonite (Al71Ni24Fe5), a natural quasicrystal composed of a periodic stack of planes with quasiperiodic atomic order and ten-fold symmetry. The new mineral has been approved by the International Mineralogical Association (IMA 2018-038) and ofcially named proxidecagonite, which derives from its identity to periodic approximant of decagonite. Both decagonite and proxidecagonite were found in fragments from the Khatyrka meteorite. Proxidecagonite is the frst natural quasicrystal approximant to be found in the Al-Ni-Fe system. Within this system, the decagonal quasicrystal phase has been reported to transform at ~940 °C to Al13(Fe,Ni)4, Al3(Fe,Ni)2 and the liquid phase, and between 800 and 850 °C to Al13(Fe,Ni)4, Al3(Fe,Ni) and Al3(Fe,Ni)2. The fact that proxidecagonite has not been observed in the laboratory before and formed in a meteorite exposed to high pressures and temperatures during impact-induced shocks suggests that it might be a thermodynamically stable compound at high pressure. The most prominent structural motifs are pseudo-pentagonal symmetry subunits, such as pentagonal bipyramids, that share edges and corners with trigonal bipyramids and which maximize shortest Ni–Al over Ni–Ni contacts. 1,2 Te frst decagonal quasicrystalline (QC) phase found in nature, decagonite Al71Ni24Fe5 , was discovered in the Khatyrka meteorite, a CV3 carbonaceous chondrite3–8.
    [Show full text]
  • 79Th Annual Meeting of the Meteoritical Society (2016) 6017.Pdf
    79th Annual Meeting of the Meteoritical Society (2016) 6017.pdf DISCOVERY OF NEW Al-Cu-Fe MINERALS IN THE KHATYRKA CV3 METEORITE. Chi Ma1,*, Chaney Lin2, Luca Bindi3, Paul J. Steinhardt2. 1Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA; 2Department of Physics, Princeton University, Princeton, NJ 08544, USA; 3Dipartimento di Scienze della Terra, Università di Firenze, Via La Pira 4, I-50121 Florence, Italy; *Email: [email protected]. Introduction: During a nanomineralogy investigation of the Khatyrka CV3 carbonaceous chondrite, we have identified two new alloy minerals (AlCu with a Pm-3m CsCl structure and Al3Fe with a C2/m structure) and associ- ated icosahedrite (quasicrystal Al63Cu26Fe11 with a five-fold symmetry) at micron scales in section 126A of USNM 7908. The section belongs to the larger Grain 126, which is one of the fragments recovered from an expedition to the Koryak Mountains in far eastern Russia in 2011 [1] as a result of a search for samples that would provide infor- mation on the origin of the quasicrystal mineral icosahedrite [2,3,4]. The recovered fragments have meteoritic (CV3- like) oxygen isotopic compositions and are identified collectively as coming from the Khatyrka meteorite [5], which formed 4.5 billion years ago during the earliest stages of the solar system. Khatyrka is unique, so far being the only meteorite to host metallic Al component. Field-emission scanning electron microscope with energy-dispersive X-ray spectrometer and electron back- scatter diffraction (EBSD), and electron probe microanalyzer (EPMA) were used to characterize chemical composi- tions and structures of the minerals in section 126A.
    [Show full text]
  • Cosmic History and a Candidate Parent Asteroid for the Quasicrystal-Bearing Meteorite Khatyrka
    COSMIC HISTORY AND A CANDIDATE PARENT ASTEROID FOR THE QUASICRYSTAL-BEARING METEORITE KHATYRKA Matthias M. M. Meier1*, Luca Bindi2,3, Philipp R. Heck4, April I. Neander5, Nicole H. Spring6,7, My E. I. Riebe1,8, Colin Maden1, Heinrich Baur1, Paul J. Steinhardt9, Rainer Wieler1 and Henner Busemann1 1Institute of Geochemistry and Petrology, ETH Zurich, Zurich, Switzerland. 2Dipartimento di Scienze della Terra, Università di Firenze, Florence, Italy. 3CNR-Istituto di Geoscienze e Georisorse, Sezione di Firenze, Florence, Italy. 4Robert A. Pritzker Center for Meteoritics and Polar Studies, Field Museum of Natural History, Chicago, USA. 5De- partment of Organismal Biology and Anatomy, University of Chicago, Chicago, USA. 6School of Earth and Environ- mental Sciences, University of Manchester, Manchester, UK. 7Department of Earth and Atmospheric Sciences, Uni- versity of Alberta, Edmonton, Canada. 8Current address: Department of Terrestrial Magnetism, Carnegie Institution of Washington, Washington, USA. 9Department of Physics, and Princeton Center for Theoretical Science, Princeton University, Princeton, USA. *corresponding author: [email protected]; (office phone: +41 44 632 64 53) Submitted to Earth and Planetary Science Letters. Abstract The unique CV-type meteorite Khatyrka is the only natural sample in which “quasicrystals” and associated crystalline Cu,Al-alloys, including khatyrkite and cupalite, have been found. They are suspected to have formed in the early Solar System. To better understand the origin of these ex- otic phases, and the relationship of Khatyrka to other CV chondrites, we have measured He and Ne in six individual, ~40-μm-sized olivine grains from Khatyrka. We find a cosmic-ray exposure age of about 2-4 Ma (if the meteoroid was <3 m in diameter, more if it was larger).
    [Show full text]
  • EXPERIMENTAL IMPACTS of ALUMINUM PROJECTILES INTO QUARTZ SAND: FORMATION 1,2 1,3 of KHATYRKITE (Cual2) and REDUCTION of QUARTZ to SILICON
    Bridging the Gap III (2015) 1071.pdf EXPERIMENTAL IMPACTS OF ALUMINUM PROJECTILES INTO QUARTZ SAND: FORMATION 1,2 1,3 OF KHATYRKITE (CuAl2) AND REDUCTION OF QUARTZ TO SILICON. C. Hamann , D. Stöffler , and W. U. Reimold1,3. 1Museum für Naturkunde, Leibniz-Institut für Evolutions- und Biodiversitätsforschung, In- validenstraße 43, 10115 Berlin, Germany ([email protected]; dieter.stö[email protected]; [email protected]); 2Institut für Geologische Wissenschaften, Freie Universität Berlin, Malteserstraße 74– 100, 12249 Berlin, Germany, 3Humboldt-Universität zu Berlin, Unter der Linden 6, 10099 Berlin, Germany. Introduction and Rationale: Impact cratering is a melt particles, shock-lithified sand with and without basic geologic process in the solar system, which was distinct shock effects (PDF, diaplectic glass), and frac- predominant over endogenic geologic processes in the tured quartz grains (for details, see the companion early evolution of geologically active planetary bodies. abstract by Wünnemann et al. [10]). Since this study Since most planetary surfaces are highly porous and/or focuses on chemical projectile–target interaction, we composed of non-cohesive materials (e.g., the lunar will only consider impact melt particles that obviously regolith), understanding the influence of pore space show a crust of projectile melt on their top sides. and non-cohesiveness of materials on the impact pro- The bulk compositions of projectile and target were cess is crucial for gaining insights into the evolution of determined with EMPA and XRF, respectively. Impact planetary regoliths. To this end, numerous theoretical melt particles were studied with optical microscopy, and experimental studies have been conducted (e.g., SEM-EDX, and EMPA.
    [Show full text]
  • Design Rules for Discovering 2D Materials from 3D Crystals
    Design Rules for Discovering 2D Materials from 3D Crystals by Eleanor Lyons Brightbill Collaborators: Tyler W. Farnsworth, Adam H. Woomer, Patrick C. O'Brien, Kaci L. Kuntz Senior Honors Thesis Chemistry University of North Carolina at Chapel Hill April 7th, 2016 Approved: ___________________________ Dr Scott Warren, Thesis Advisor Dr Wei You, Reader Dr. Todd Austell, Reader Abstract Two-dimensional (2D) materials are championed as potential components for novel technologies due to the extreme change in properties that often accompanies a transition from the bulk to a quantum-confined state. While the incredible properties of existing 2D materials have been investigated for numerous applications, the current library of stable 2D materials is limited to a relatively small number of material systems, and attempts to identify novel 2D materials have found only a small subset of potential 2D material precursors. Here I present a rigorous, yet simple, set of criteria to identify 3D crystals that may be exfoliated into stable 2D sheets and apply these criteria to a database of naturally occurring layered minerals. These design rules harness two fundamental properties of crystals—Mohs hardness and melting point—to enable a rapid and effective approach to identify candidates for exfoliation. It is shown that, in layered systems, Mohs hardness is a predictor of inter-layer (out-of-plane) bond strength while melting point is a measure of intra-layer (in-plane) bond strength. This concept is demonstrated by using liquid exfoliation to produce novel 2D materials from layered minerals that have a Mohs hardness less than 3, with relative success of exfoliation (such as yield and flake size) dependent on melting point.
    [Show full text]
  • Evidence of Cross-Cutting and Redox Reaction in Khatyrka Meteorite
    www.nature.com/scientificreports OPEN Evidence of cross-cutting and redox reaction in Khatyrka meteorite reveals metallic-Al minerals formed Received: 5 December 2016 Accepted: 22 March 2017 in outer space Published: xx xx xxxx Chaney Lin1, Lincoln S. Hollister2, Glenn J. MacPherson3, Luca Bindi4,5, Chi Ma6, Christopher L. Andronicos7 & Paul J. Steinhardt1,8 We report on a fragment of the quasicrystal-bearing CV3 carbonaceous chondrite Khatyrka recovered from fine-grained, clay-rich sediments in the Koryak Mountains, Chukotka (Russia). We show higher melting-point silicate glass cross-cutting lower melting-point Al-Cu-Fe alloys, as well as unambiguous evidence of a reduction-oxidation reaction history between Al-Cu-Fe alloys and silicate melt. The redox reactions involve reduction of FeO and SiO2 to Fe and Fe-Si metal, and oxidation of metallic Al to Al2O3, occurring where silicate melt was in contact with Al-Cu-Fe alloys. In the reaction zone, there are metallic Fe and Fe-Si beads, aluminous spinel rinds on the Al-Cu-Fe alloys, and Al2O3 enrichment in the silicate melt surrounding the alloys. From this and other evidence, we demonstrate that Khatyrka must have experienced at least two distinct events: first, an event as early as 4.564 Ga in which the first Al-Cu-Fe alloys formed; and, second, a more recent impact-induced shock in space that led to transformations of and reactions between the alloys and the meteorite matrix. The new evidence firmly establishes that the Al-Cu-Fe alloys (including quasicrystals) formed in outer space in a complex, multi-stage process.
    [Show full text]
  • New Mineral Names*
    American Mineralogist, Yolume 65, pages 205-210, 1980 NEW MINERAL NAMES* MTCH,q'EI.FrEIscrren. J. A. MANDARINo AND ADoLF Passr Adnontite* Analysisby H. V. (spectrophotometricfor Cu, Al, SO3,Cl; H2O by Penfield)gave SO, 28.30,Cl 6.70,Cu I1.80,Al2O3 9.16, Na2O K. Walenta (1979)Admontite, a new boratemineral from the gyp- 0.13,K2O 0.05,CaO 0.18,H2O 45.40,sum 101.72(-O = Clr) sum deposit Schildmauer near Admont in Styria (Austria). l00.2l%o,corresponding to Cut ' 28.1 H2O, or TschermaksMineral. Petrogr.Mitt., 26,69-77 (n German). urAlr(SO)c"aClz 1e CuAl(SOa)2Cl' 14 H2O. The DTA curve shows large endo- Admontite is a magnesium borate found in the gypsum deposit thermic breaksat 92" and l43o and small onesat 308o,730o, and of Schildmauer near Admont in Styria (Austria) in association 1047o,ttre last correspondingto the reduction of CuO to Cu2O. with gypsum, anhydrite, hexahydrite, kiweite, quartz, and pyrite. The TGA curve showsa loss(of H2O) of 35.6Voto 100' and 9.8% Chemicalanalysis gave MgO lO.20Vo,B2O354.50Vo (by difference), more from l00o to 300". Lossof SO3occurs at about 530oto 650o. H2O 35.30Vo,corresponding closely to 2MgO . B2O3. 15HrO. The Aubertite is soluble in water. mineral occurs in poorly developed colorless crystals of mono- X-ray study shows aubertite to be triclinic, Pl, a : 6.288x. clinic symmetry, elongatedparallel to c and flattened on {100}. 0.003,D: 13.239+0.006,c:6.284+O.003,{, a :91'52', B: Cell dirnensionsare: rl : 12.68,b : 10.07,c : 11.32(all +0.024), 94"40',y : 82"27'(alltl0'), Z: I, G calc 1.83,meas 1.815.
    [Show full text]
  • Generalized Crystallography of Diamond-Like Structures: II
    Crystallography Reports, Vol. 47, No. 5, 2002, pp. 709–719. Translated from Kristallografiya, Vol. 47, No. 5, 2002, pp. 775–784. Original Russian Text Copyright © 2002 by Talis. CRYSTAL SYMMETRY Generalized Crystallography of Diamond-Like Structures: II. Diamond Packing in the Space of a Three-Dimensional Sphere, Subconfiguration of Finite Projective Planes, and Generating Clusters of Diamond-Like Structures A. L. Talis Institute of Synthesis of Mineral Raw Materials, Aleksandrov, Vladimir oblast, Russia e-mail: ofi@vniisims.elcom.ru Received April 24, 2001 Abstract—An enantiomorphous 240-vertex “diamond structure” is considered in the space of a three-dimen- sional sphere S3, whose highly symmetric clusters determined by the subconfigurations of finite projective planes PG(2, q), q = 2, 3, 4 are the specific clusters of diamond-like structures. The classification of the gener- ating clusters forming diamond-like structures is introduced. It is shown that the symmetry of the configuration, in which the configuration setting the generating clusters is embedded, determines the symmetry of diamond- like structures. The sequence of diamond-like structures (from a diamond to a BC8 structure) is also considered. On an example of the construction of PG(2, 3), it is shown with the aid of the summation and multiplication tables of the Galois field GF(3) that the generalized crystallography of diamond-like structures provides more possibilities than classical crystallography because of the transition from groups to algebraic constructions in which at least two operations are defined. © 2002 MAIK “Nauka/Interperiodica”. INTRODUCTION the diamond-like structures themselves are constructed from a certain set of generating clusters in a way similar Earlier [1], it was shown that the adequate mapping to the construction of a three-dimensional Penrose divi- of the symmetry of diamond-like structures requires a sion from four types of tetrahedra [7].
    [Show full text]
  • ISBN 5 900395 50 2 UDK 549 New Data on Minerals. Moscow
    #00_firstPpages_en_0727:#00_firstPpages_en_0727.qxd 21.05.2009 19:38 Page 2 ISBN 5900395502 UDK 549 New Data on Minerals. Moscow.: Ocean Pictures, 2003. volume 38, 172 pages, 66 color photos. Articles of the volume are devoted to mineralogy, including descriptions of new mineral species (telyushenkoite – a new caesium mineral of the leifite group, neskevaaraite-Fe – a new mineral of the labuntsovite group) and new finds of min- erals (pabstite from the moraine of the Dara-i-Pioz glacier, Tadjikistan, germanocolusite from Kipushi, Katanga, min- erals of the hilairite group from Khibiny and Lovozero massifs). Results of study of mineral associations in gold-sulfide- tellyride ore of the Kairagach deposit, Uzbekistan are presented. Features of rare germanite structure are revealed. The cavitation model is proposed for the formation of mineral microspherulas. Problems of isomorphism in the stannite family minerals and additivity of optical properties in minerals of the humite series are considered. The section Mineralogical Museums and Collections includes articles devoted to the description and history of Museum collections (article of the Kolyvan grinding factory, P.A.Kochubey's collection, new acquisitions) and the geographical location of mineral type localities is discussed in this section. The section Mineralogical Notes includes the article about photo- graphing minerals and Reminiscences of the veteran research worker of the Fersman Mineralogical Museum, Doctor in Science M.D. Dorfman about meetings with known mineralogists and geochemists – N.A. Smoltaninov, P.P. Pilipenko, Yu.A. Bilibin. The volume is of interest for mineralogists, geochemists, geologists, and to museum curators, collectors and amateurs of minerals. EditorinChief Margarita I .Novgorodova, Doctor in Science, Professor EditorinChief of the volume: Elena A.Borisova, Ph.D Editorial Board Moisei D.
    [Show full text]
  • Evidence for the Extraterrestrial Origin of a Natural Quasicrystal
    Evidence for the extraterrestrial origin of a natural quasicrystal Luca Bindia,b, John M. Eilerc, Yunbin Guanc, Lincoln S. Hollisterd, Glenn MacPhersone, Paul J. Steinhardtf,g,1, and Nan Yaoh aMuseo di Storia Naturale, Sezione di Mineralogia, Università degli Studi di Firenze, Via La Pira 4, I-50121 Florence, Italy; bDipartimento di Scienze della Terra, Università di Firenze, Via La Pira 4, I-50121 Florence, Italy; cDivision of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125; dDepartment of Geosciences, Princeton University, Guyot Hall, Princeton, NJ 08544; eDepartment of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, Washington, DC 20013; fPrinceton Center for Theoretical Science, Princeton University, Princeton, NJ 08544; gDepartment of Physics, Princeton University, Jadwin Hall, Princeton, NJ 08544; and hPrinceton Institute for the Science and Technology of Materials, Princeton University, Princeton, NJ 08544 Edited by* Paul M. Chaikin, New York University, New York, NY, and approved November 21, 2011 (received for review July 9, 2011) We present evidence that a rock sample found in the Koryak The rock sample was first identified for study as a result of Mountains in Russia and containing icosahedrite, an icosahedral a decade-long systematic search for a natural quasicrystal (4). quasicrystalline phase with composition Al63Cu24Fe13, is part of a Quasicrystals are solids whose atomic arrangement exhibits qua- meteorite, likely formed in the early solar system about 4.5 Gya. siperiodic rather than periodic translational order and rotational The quasicrystal grains are intergrown with diopside, forsterite, symmetries that are impossible for ordinary crystals (5) such as stishovite, and additional metallic phases [khatyrkite (CuAl2), cupa- fivefold symmetry in two-dimensions and icosahedral symmetry lite (CuAl), and β-phase (AlCuFe)].
    [Show full text]