April 28-30, 2003

K FF.FFF"y~FF~F FFFF i - ' 0 0 "~~~~~~~~~~~~~~~~~~~:ili~ ,' 'r~~3SI:' 9 ·jE'i'B:~~~':·I.BiS·:~~l6 4 ~FF[F~F .e~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~FFF1~~~ * 4F FFF ~~~~~~~~~~~~ I ~~~~~~~.r 1 ,i~s~ 4 ~FF LA " 4F~F F~t 1 4 ,F~~~~~~~~~~,FFF j·'F,'i* F1F1.FF i> F, 4F 2 4 FF~~:'i ~~'.~K-wF*I F'"' [K 'F ,r F ,.FVFF ' F " .. '4 F F F' ir Q' 1 .~~iF44~~~.1FF&F'F.'IF' ' FFF~~~~~~~F14FF~~~I 1~~FF'~~ -:i~, '~~~~"~'F~~ >F'F1FK F 4 i!'~~~~ ~~FFFFFFF.FFF.FFFFF'F* * g FF ::i~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~F I -F ; F *:-~~~~~~~~~~~~~~~' ~A'F:~ .· ~'F . j'F.~'F~*· F1r I ''F'.' ~ 1"FF, Fr F ii::~~~~~~~~~~ ;4 FFIS: Fi *FI~ F' p'F'II ,~pF' F 1 F; · ::': · Fi,. FF~ig: F ''FF' i;Fi:FF'''FF 4 Jii *''F~ ; ;r~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ F~ ~ ~ ~~L I[ .; 'F ~ [F Program and Abstracts Contractors' Meeting Heavy Element Chemistry Program Separations Program Hilton of Santa Fe 100 Sandoval Street Santa Fe, New Mexico April 28 - 30, 2003 Chemical Sciences, Geosciences and Biosciences Division Office of Basic Energy Sciences Office of Science Department of Energy FOREWORD This abstract booklet provides a record of the fifth U.S. Department of Energy (DOE) contractors' meeting in separations sciences and the second in heavy element chemistry. The Chemical Sciences, Geosciences and Biosciences Division of the Office of Basic Energy Sciences and its predecessors have sponsored research in heavy element chemistry and separations sciences for over fifty years. Although these are distinct disciplines, they have much in common for many reasons, in particular because (1) separations research is needed to produce pure heavy-element samples and (2) heavy element chemistry provides the basis for many separations processes. Therefore, this year it was decided to hold these meetings jointly. There is wide agreement that a gathering of researchers with common interests and sponsorship provides a fruitful environment to present and to exchange information about researchers' activities, to build collaborations among research groups with mutually reinforcing strengths, to identify needs of the research community, and to focus on areas for future research directions. The primary means of communicating research achievements and perspectives at this meeting is via posters and the discussions that illuminate the poster sessions. Groups of brief oral presentations serve to highlight the corresponding posters that follow each oral session. We have organized the agenda so that papers in related disciplines - such as spectroscopy, theory, and coordination chemistry - are loosely clustered together. We emphasize the informal nature of this meeting - it is not a review of researchers' achievements or future directions. We are pleased to have the privilege of organizing this joint meeting and of serving as the managers of our respective research programs. In carrying out these tasks, we learn from the achievements, and share the excitement, of the research of the many sponsored scientists and students whose names appear on the papers in the following pages. We also hope that this meeting will enhance your research efforts and will nurture future collaborations and initiatives. We thank all of the researchers whose dedication and innovation have advanced our research and made this meeting possible and, we hope, productive. We hope that all of you will build on your successes and that we will assemble in a very few years for our next joint meeting. We thank Karen Talamini of the Chemical Sciences, Geosciences and Biosciences Division, and Sophia Kitts and Rachel Smith of the Oak Ridge Institute for Science and Education for assisting in the technical and logistical aspects of this meeting. John C. Miller Lester R. Morss Norman Edelstein Heavy Element Chemistry and Separations Contractors' Meeting Program Sunday, April 27, 2003; 1800 - 2000 Registration, Cash Bar Reception, and Poster Setup Monday Morning, April 28, 2003 700 - 800 Continental Breakfast at the hotel, provided by DOE. Poster Setup 800 Start of meeting - Introductory Remarks and Plenary Lecture I Department of Energy, Office of 800 Morss, Lester Welcome and Introductions Science, Chemical Sciences, Geosciences and Biosciences Division, SC-14 Department of Energy, Office of 810 Miller, John C. Welcome and Introductions Science, Cheical Sciences, Geosciences and Biosciences Division, SC-14 820 - Sattlberge A PL-I Heavy Element Chemistry in the 21st Century: Chemistry Division, Los Alamos 900 Challenges and Opportunities National Laboratory, Los Alamos 905 Short presentations - Oral session I 905 Yeung, Edward S. Pl-1 Single Molecule Studies of Chromatographic Events University 915Lukens Wae P2 X-ray Absorption Fine Structure Studies of Actinide Chemistry Group, Lawrence 915 Lukens, Wayne P1-2 Organoactinide Complexes Berkeley National Laboratory 925Ass~efa, Z. Intra-molecular energy transfer studies from oxo- and 925 Assefa, Z. P1-3 . .. .... Oak Ridge National Laboratory nitrogen ligating hetero-cyclic ligands to actinide ions 935 Pronko, Peter P. P -4 Isotopically Enriched Films and Nanostructures by Center for Ultrafast Optical Science 935 Pronko, Peter P. P1-4 Ultrafast Pulsed Laser Deposition (CUOS), University of Michigan 945 Heaven, Michael 5 Spectroscopic Studies of Prototype Actinide Department of Chemistry, Emory C. Conpounds University 955lE. Gy Multinuclear Magnetic Resonance Study of Silica and Department of Chemistry, Colorado Modified Silicas State University, Fort Collins Page 1 Heavy Element Chemistry and Separations Contractors' Meeting Program „1005Liu-,G . P Electronic Properties of Heavy Elements in Chemistry Division, Argonne Nalional 1005 Liu, Guokui P1-7 Condensed Phases Laboratory Spectroscopic Methods to Characterize Interfacial ~~~~~~~~~~~~~~~~1015 HrioeM. Departmnent of Chemistry, University of 1015 Harris, Joel M. P1-8 Electric Fields and Metal-Ion Binding to Immobilized U Ligands Synthesis of New Actinide Main-Group Metal Colorado 1025 Dorhout, Peter K. P1-9 Materials: Structures and XANES Spectroscopic Departmentatet of Chemistry,e r University Studies of Plutonium Polyselenides State 1035 - 1125 Coffee break and Poster Session I 1125 Short presentations - Oral session II Gregorich, Kenneth E., Nitsche, Heino, Nuclear Science Division. Lawrence 1125 ' ' ' P2-1 Chemistry of Elements 108 and 112 L and Hoffman, Berkeley National Laboratory Darleane C. Chemistry Division-Advanced 1135 P2-2.-Wilkerson,2 The First Observation of 5f-5f Luminescence from a Diagnostics and Instrumentation, Los Marianne P. Transuranic Actinyl Complex Alaos National Laboratory Alamos National Laboratory Raman Spectroscopy of Chromatographic Stationary Pemberton, Jeanne Rama Spectroscopy of Chroatographic Statinar Department of Chemistry, University of 1145 P2-3 Phases: Towards a Molecular Description of E. ReiArizona Retention 5 Chiarizia, R., Chemistry Division, Argonne National 1155 P2-4 Heavy Element AggregationPhenomena Beitz, J. V., Nash, Laboratory and Gas Binding in Chemistry Department, SUNY Stony 12051205 Grey, C~lareClare P.JP. Pz-jrP2-5P2-5 NMR Studies of Structure Molecular Sieves Brook Nitsche, Heino, Gregorich, Kenneth The Chemistry of Rutherfordium and Dubnium Nuclear Science Division, Lawrence E., and Hoffian, (Elements 104 and 105) Berkeley National Laboratory Darleane C. Page 2 Heavy Element Chemistry and Separations Contractors' Meeting Program 5 Sepaniak, Michael Advancing the Capabilities of Surfaced Enhanced Department of Chemistry, University of J. Raman Scattering in Chemical Analysis Tennessee, Knoxville Creating Isotopes of Elements 114, 116, and 118 - Analytical and Nuclear Chemistry Laue, Carola A P2-8 The Essential First Step to Their Chemical Division, Lawrence Livermore Characterization National Laboratory 1235 Lunch - Provided by DOE 1310 - 1410 Poster Session II 1410 Short presentations - Oral session III Details of Ion Hydration and Ion-Pair Structure from Fl S s D , Fundamental Sciences Division, Pacific 1410 Fulton, John L. P3-1 X-ray Absorption Spectroscopy and Molecular N t N l Northwest National Laboratory Dynamics Simulations Department of Chemistry and Center for Multiphase Enviromnental Clark, Sue B. and Actinide Incorporation and Radiation Effects in U(VI) Research, Washington State 1420 P3-2 Ewing, Rodney C. Solids University; Department of Nuclear Engineering and Radiological Sciences, University of Michigan Lindle, Dennis W. Molecular Environmental Science Using Synchrotron Department of Chemistry, University of 1430 and Shuh, David P3-3 Radiation: Chemistry and Physics of Waste Form Nevada, Las Vegas, and Chemical K. Materials Sciences Division, LBNL Soderholm, L. and Chemistry Division, Argonne National 1440 Jensn Mk P3-4 The Actinide Facility Lab Jensen, Mark Laboratory Sorption, Catalytic and Ion-Exchange Properties of Materials Research Laboratory, 1450 Cheetllam, Anthony P3-5 . Nanoporous Nickel Phosphates University of California, Santa Barbara Nuclear Science and Technology Felker L.. , Advanced Fuel Cycle Initiative Support at the . 1500 Felker,~1500 L. K. P3-6 Division, Oak Ridge National Radiochemical Engineering Development Center Laboratory Page 3 Heavy Element Chemistry and Separations Contractors' Meeting Program Materials Science and Technology Heterogeneity and Collective Phenomena in Division, Nuclear Materials and 1510 Conradson, Steven P3-11 Crystalline Solids Technology Division, Chemistry Division Glenn T. Seaborg Center, Chemical 1520 Booth, Corwin H. P3-12 Hybridization,

Load more