polymers Article Environmentally-Friendly Synthesis of Carbonate-Type Macrodiols and Preparation of Transparent Self-Healable Thermoplastic Polyurethanes Seon-Mi Kim 1,†, Seul-A Park 1,†, Sung Yeon Hwang 1,2, Eun Seon Kim 1, Jonggeon Jegal 1, Changgyu Im 3, Hyeonyeol Jeon 1,*, Dongyeop X. Oh 1,2,* ID and Jeyoung Park 1,2,* ID 1 Research Center for Bio-Based Chemistry, Korea Research Institute of Chemical Technology (KRICT), Ulsan 44429, Korea;
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[email protected] (J.J.) 2 Advanced Materials and Chemical Engineering, University of Science and Technology (UST), Daejeon 34113, Korea 3 Department of Chemical Engineering, Hanyang University, Ansan 15588, Korea;
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[email protected] (J.P.); Tel.: +82-52-241-6324 (H.J.); +82-52-241-6316 (D.X.O.); +82-52-241-6315 (J.P.) † These authors contributed equally to this work. Received: 16 October 2017; Accepted: 29 November 2017; Published: 30 November 2017 Abstract: Carbonate-type macrodiols synthesized by base-catalyzed polycondensation of co-diols and dimethyl carbonate as an environmentally-friendly route were subsequently utilized for the preparation of transparent and self-healable thermoplastic polyurethanes (TPUs) containing a carbonate-type soft segment. Three types of macrodiols, obtained from mono, dual and triple diol-monomers for target molecular weights of 1 and 1.5 kg mol−1, were analyzed by 1H NMR integration and the OH titration value.