Contact Europe, Africa, West Asia

BASF Nederland B.V. Resins & Additives

Innovatielaan 1 We create chemistry 8466 SN Nijehaske P.O. Box 390 8440 AJ Heerenveen The Netherlands that makes coatings

Tel.: +31 51 3619-619 Fax: +31 51 3619-600love resins and additives [email protected]

BASF SE

67056 Ludwigshafen Germany www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed.

® = registered trademark of the BASF Group 2019 EDC 0115e Table of contents 2019 3

Table of contents

Market technology matrix 4 Radiation-curable systems 71 We create chemistry 8 Epoxy acrylates 82 Water-based systems 11 Polyester acrylates 84 Amine-modified polyether acrylates, Colloidals and polyether acrylates, and dual cure resins 86 non-cross-linking acrylic dispersions 20 Urethane acrylates 88 Explore our Non-cross-linking acrylic dispersions 22 Unsaturated polyesters portfolio online Self-cross-linking acrylic dispersions 24 and UV specialties 90 www.basf.com/ OH-functional dispersions 26 UV monomers 92 resin-additive-search Polyurethane dispersions Water-based UV resins 94 and PUD / acrylic hybrids 28 Amino resins 30 Formulation additives 97 Polyisocyanates 32 Epoxy resins and amine adducts 34 Rheology modifiers 106 Grinding resins, waxes, Defoamers 110 and cross-linker solutions 36 Dispersing agents 114 Wetting agents and surface modifiers 122 Solvent-based systems 39 Acrylic polyols, HPE, and catalyst 46 Performance additives 129 Amino resins and co-cross-linker 48 UV absorbers for water-based Urea resins and polyvinyl chlorides 50 and solvent-based coatings 144 Polyisocyanates and cross-linker 52 HALS for water-based and solvent-based coatings 146 Grinding resins, unsaturated polyesters, and amine 54 Light stabilizer blends 148 Soft resins 56 Antioxidants and optical brighteners 150

Renewable systems 59 BASF’s Biomass balance apporach 60 Natural oil-based polyols 62 Properties of natural oil-based polyols 68 Market technology matrix Market technology matrix 4 2019 2019 5

Our solutions for your requirements

Furniture Flooring Automotive Industrial Interior Product chemistry Brand name Page Economic Medium-quality High-quality Wood PVC / linoleum Concrete Automotive Automotive Exterior Car parts topcoats & Protective furniture furniture furniture flooring / cork flooring flooring OEM refinish topcoats primers Water-based systems

Colloidals and non-cross-linking acrylic dispersions Joncryl® / Acronal® 20 1 1 ------

Non-cross-linking acrylic dispersions Joncryl® 22 1 1 ------1 - 1 1

Self-cross-linking acrylic dispersions Joncryl® / Luhydran® 24 1 1 1 1 1 1 ------

OH-functional dispersions Basonol® / Joncryl® / Luhydran® 26 - - 1 1 1 1 - - - 1 1 1

Polyurethane acrylic hybrids / polyurethane dispersions Joncryl® / Basonol® 28 - 1 1 1 1 1 - - 1 - 1 -

Amino resins Luwipal® / Plastopal® 30 1 1 1 - - - 1 - - 1 1 -

Polyisocyanates Basonat® 32 - 1 1 1 - 1 1 1 1 1 1 1

Epoxy resins 34 - - - - - 1 - - - - 1 1 Waterpoxy® Amine adducts 34 - - - - - 1 - - - - 1 1

Grinding resins Joncryl® / Laropal® 36 1 1 1 - - 1 - 1 1 1 1 1

Waxes and cross-linker solutions Joncryl® / Zinc Oxide Solution 36 1 1 1 1 1 1 ------Solvent-based systems

Acrylic polyols Joncryl® 46 - 1 1 1 - 1 - - - 1 1 1

Hyperbranched polyesters Basonol® HPE 46 ------1 - - 1 1 1

Amino resins Luwipal® / Plastopal® / Larotact® 48 1 1 1 1 - - 1 - - 1 1 -

Polyvinyl chlorides Laroflex® 50 ------1 1

Polyisocyanates Basonat® 52 - 1 1 1 - 1 1 1 1 1 1 1

Amine Laromin® 54 ------1 1

Grinding resins Laropal® 54 1 1 1 - - 1 - 1 1 1 1 1

Unsaturated polyesters Ludopal® 54 ------1 - 1 -

Acronal® / Joncryl® / Soft resins (acrylic resins, vinyl ethers, glycoluril) 56 - 1 1 ------1 1 Lutonal® / Plastigen® G ULF Renewable systems

Natural oil-based polyols Sovermol® 64 - 1 1 1 1 1 - 1 1 1 1 1 Market technology matrix Market technology matrix 6 2019 2019 7

Our solutions for your requirements

Furniture Flooring Automotive Industrial Interior Product chemistry Brand name Page Economic Medium-quality High-quality Wood PVC / linoleum Concrete Automotive Automotive Exterior Car parts topcoats & Protective furniture furniture furniture flooring / cork flooring flooring OEM refinish topcoats primers Radiation-curable systems

Epoxy acrylates 82 1 1 1 1 1 - - - 1 - 1 1

Polyester acrylates 84 1 1 1 1 1 - - - 1 - 1 -

Amine-modified polyether acrylates 86 1 1 1 1 1 - - - 1 - 1 -

Polyether acrylates and dual cure resins 86 1 1 1 1 1 - - - 1 - 1 -

Urethane acrylates Laromer® 88 1 1 1 1 1 - 1 1 1 1 1 -

Unsaturated polyesters 90 1 1 1 1 1 - - - 1 - 1 1

UV specialties 90 1 1 1 1 1 - - 1 1 1 1 1

UV monomers 92 1 1 1 1 1 - 1 1 1 1 1 1

Water-based UV resins 94 1 1 1 1 1 1 - - 1 1 1 - Formulation additives

Solvent-based and solvent-free systems Defoamers 112 1 1 1 1 1 1 1 1 1 1 1 1

Dispersing agents 118 1 1 1 1 1 1 1 1 1 1 1 1 Efka® Rheology modifiers 108 1 1 1 - - - 1 1 1 1 1 1

Wetting agents and surface modifiers 124 1 1 1 1 1 1 1 1 1 1 1 1 Water-based systems Defoamers FoamStar® 110 1 1 1 1 1 - 1 1 1 1 1 1

Dispersing agents Dispex® / Dispex® Ultra 114 1 1 1 1 1 - 1 1 1 1 1 1

Rheology modifiers Rheovis® 106 1 1 1 1 1 - 1 1 1 1 1 1

Wetting agents and surface modifiers Hydropalat® 122 1 1 1 1 1 - 1 1 1 1 1 1 Performance additives

UV absorbers 144 1 1 1 1 1 1 1 1 1 1 - 1 Chimassorb® / Tinuvin® / HALS 146 1 1 1 1 1 1 1 1 1 1 - 1 Lignostab® Light stabilizer blends 148 1 1 1 1 1 1 ------

Hindered phenolic primary antioxidants ------1 - - 1 1 -

Thioether secondary antioxidants ------1 - - 1 1 - Irganox® / Irgafos® Phosphite secondary antioxidants 150 ------1 - - 1 1 -

Antioxidant blends ------1 - - 1 1 -

Optical brighteners Tinopal® ------1 - We create chemistry 8 2019

Find your perfect match

At BASF, we create chemistry. We offer tailor-made and sustainable solutions based on our long-term technical expertise and market knowledge. As such, we can proudly offer you a comprehensive portfolio of resins, formulation additives, light stabilizers, antioxidants, and cross-linking agents for the formulation of industrial, automotive, furniture, and flooring coating applications.

Your committed partner

Our goal is to understand the unique challenges faced by each industry as well as the impact of the respective market trends. Our dedicated team works to develop innovative, custom-made, and sustainable solutions to advance your formulations.

We constantly upgrade our assets and invest in additional capacities to fulfill the growing demand for environmentally friendly technologies. Our leading-edge competency in product safety and regulatory affairs helps you to comply with increasing legal demands.

Worldwide close to our customers

In today’s global and rapidly changing business environment, a global footprint is a key requirement in remaining competitive. With backward integrated production sites across the world, we can deliver the high-quality products you need. This also helps us to better understand your local market with an eye to research and development, product supply, environmental concerns, and technical services.

Take a look at our far-reaching portfolio. In collaboration with our experts you will surely find the perfect match of products to suit your needs. This brochure will give you an overview of the comprehensive and steadily growing portfolio. Our recent product launches are marked with NEW. Bitte Kurzversion des KapiteltitelsWater-based eintragen systems 2019 20191111 Water-based systems Water-based

Water-based systems

The growing trend towards water-based systems is based on economic factors, low-VOC demand, and health and safety requirements.

We are driving market conversion by setting new trends and industry standards in terms of cost and performance.

Performance meets sustainability Broad formulation toolbox

In our view, finding the best match means delivering We provide a broad technology toolbox consisting of high-performance for your formulation without several water-based technologies offering a variety of harming the environment. For example, our products choices to match your specific requirements – ranging make it possible to produce long-lasting and resilient from acrylic dispersions to polyurethane dispersions coatings while, at the same time, reducing the output and polyurethane acrylic hybrids. levels of volatile organic compounds (VOC). 12 § § PRO standsfor for anticorrosive metalcoatings. Acronal Acronal Acronal Resistant, long-lasting,andenvironmentally friendly for water-based systems Acrylic dispersions New developmentsintheAcronal galvanized substrates. and goodadhesiontoferrous, non-ferrous and improved corrosion protection, earlywaterresistance, barrier- andcorrosion-inhibiting properties with brushing androlling. spraying, dipping,roller, andcurtaincoating,aswellmanualapplications suchas technologies andcanbeformulatedaccording tothedesired applicationmethod: our comprehensive portfolio.Theyallowyoutochoosefrom arangeofwater-based § § Professional –althoughthe Acronal protection Protection –offering high-performancecorrosion may alsobeusedinDIYapplications professional industrialmetal market,theproducts has primarilybeendevelopedfortheanticorrosion 2019 Water-based systems ® PROisaninnovativeproduct linefrom BASF ® ® PRO,Joncryl PROacrylicdispersions ® , andLuhydran ® PROrangeoffer ® PROrange

® dispersionsare thekeyproduct lineswithin coating applicationsonmetal,plastic,andwood. These products are especiallysuitedforindustrial dispersions haveanear-Newtonian rheologyprofile. co-binders insomeexteriorapplications. for interiorwoodapplicationsandfurniture foilsandas or OH-functionaldispersions,andparticularlysuitable success. Theyare surfactant-based, self-cross-linking, These products havealong, reputable historyof Luhydran Most Joncryl Joncryl polymeric emulsionstabilizer. Therefore, mostJoncryl of alowmolecularweightacid-functionalresin asa ® acrylicdispersions ® ® dispersionsare characterized bytheuse acrylicdispersions ®

Flow Single-phase feed Homogeneous Acronal Rheology profileJoncryl Viscosity [mPa∙s] Viscosity ® , Luhydran ® , andJoncryl Sequential multifeedcompositions Core shell(inverse) ® ® –particlemorphologies composition Continuous changeinfeed Gradient Conventional acrylicdispersion(pseudoplastic) Joncryl Water-based systems ® dispersion(near-Newtonian) (or potentialsecondarynucleation) Physical blendoftwodispersions Mixtures Shear rate[s-1] Spray /brushroller 2019 13

Water-based systems Water-based systems Water-based systems 14 2019 2019 15 Water-based systems Water-based Perfect match for interior furniture and flooring applications

The interior wood furniture and flooring market is very diverse. It encompasses Selected recommendations Selected recommendations for medium-/ assembled contemporary furniture, cabinets, self-assembled flat-stock furniture for for economic flat-stock furniture high-quality furniture and flooring

home and office, as well as parquet and solid wood, ranging from factory-applied Colloidal Conventional RC industrial to on-site professional or DIY applications. Self-cross-linking PUD Acrylic / PUD hybrid

Transfer, resolubility Chemical resistance / Natural look Chemical resistance / scratch resistance scratch resistance Joncryl® 1980 E Joncryl® 661 Joncryl® 8226 Joncryl® 8331 Our goal of supporting you with our water-based No matter what the nature of your application, Joncryl® 663 Joncryl® 8322 Cost-effective Luhydran® A 875 S dispersion technologies entails finding the best we create coating raw material solutions that meet Joncryl® 670 Joncryl® 1980 E Joncryl® 8322 Luhydran® A 849 S2 match of product properties – i.e. preserving the your needs regarding cost and performance while beauty of wooden furniture and the environment conforming to the latest environmental regulations. as well. Application methods and substrates vary enormously Joncryl® 8224 Joncryl® 8330 from country to country as a result of local preferences, Our Joncryl® and Luhydran® self-cross-linking national regulations, and coating requirements. dispersions allow the appearance of wood to We thus offer individual support for your needs with Cost-effective Low VOC Fast drying / blocking resistance Abrasion resistance be modified – from a natural look to strong grain our water-based dispersions and system solutions Joncryl® 77-E Joncryl® 1915-E Joncryl® 8224 Joncryl® HYB 6336 Joncryl® 79 Joncryl® 8225 Joncryl® HYB 6430 enhancement. designed to match your targeted properties. Low VOC Joncryl® 8223 Joncryl® U 4190 Joncryl® 8225

A class of its own, Joncryl® 9500 series Newly developed dispersions based on multiphase technology, with ultrafine particle size.

Product Key properties

Excellent stain resistance in pigmented Joncryl® 9500 systems, excellent adhesion, for DIY and industrial use

Very good stain resistance in pigmented Joncryl® 9502 systems, improved blocking resistance over Joncryl® 9500

Universal self cross-linking acrylic, excellent chemical and scratch resistance, high Joncryl® 9530 wet film transparency, excellent grain enhancement 16 Multilayer coatings forprimer, direct tometal,andtopcoat products allowsthecoatings manufacturer todesign pigmented coatings.Ourportfolio’s diversityof designed toattainhigh-performanceinclearand Customer supportiswellservedwithproducts should beabletomeetyourneeds. properties andperformanceattributes.Therangeofacrylicemulsionsthatweoffer environmentally sustainableproducts thatoffer theperfectbalancebetweencoating The biggestchallengewithintheindustrialmetalcoatingsindustrytodayisproviding water-based metalcoatings Perfect matchfor 80 µm Primer 80 µm Intermediate coat 25–80 µm Topcoat 2019 Water-based systems unit topcoat+primer aggressive chemicals+buildfilmthickness Enhance barriertomoisture and weatherability +additionalbarrier Aesthetics (color, texture, gloss)+ surface +provide surfaceforadhesion oxygen, water+ions)adhesiontometal Active corrosion protection (barrieragainst Metal adhesion, andexcellentexteriordurability. and chemicalresistance, hardness, goodintercoat and dryadhesion,earlywaterresistance, corrosion optimize product performanceattributes suchaswet applications whilealsoproviding thelatitudeto Direct tometal(DTM) 25–40 µm DTM coating no anticorrosive pigments High gloss,chemical+UVresistance Metal Corrosion classification(according toDINENISO12944-1) basedondryfilmthicknessofapprox. 40μm(DTM)and80(primer) Portfolio snapshot 1K acrylicdispersionsforprotectivecoatings Acronal Acronal Acronal Acronal Acronal Acronal Product (Primer) Product maturity ® ® ® ® ® ® PRO8977 PRO780 PRO763 PRO7600(new) PRO761 PRO770(new) Joncryl 1532 PRO Joncryl 1555 PRO ® Joncryl 1537 PRO ® C2 ® Joncryl Joncryl Improved blockresistance, harder Improved corrosionresistance (>80µm) thicklayers for Universal, suited especially cost-effective; resistance, adhesiontogalvanized steel properties,application water goodearly Workhorse, benchmark, robust, good Superior performance Attributes (new) 1554 1522 PRO PRO ® ® Acronal Acronal (new) 7600 PRO PRO 761 ® ® Acronal Acronal C3 8977 PRO PRO 763 ® ® Acronal PRO 780 Joncryl Joncryl Joncryl Joncryl Joncryl Product (DTM) ®

Acronal (new) PRO 770 ® ® ® ® ® PRO1555 PRO1537 PRO1532 PRO1522 PRO1554(new) ® C4 ooot matt Primer /monocoat fast drying High anti-blocking, goodadhesion, Improved hardnessvs. Joncryl Fast drying, blockresistance resistance Good corrosionresistanceandchemical adhesion improvedwet resistance (newtechnology); Improved corrosionresistanceandchemical Attributes Water-based systems Higher corrosionprotection (250–400 PRO 763 Acronal µm) C5 ® ooot glossy DTM /monocoat Established Growing ® PRO1532 2019 New 17

Water-based systems 18 dispersion andJoncryl plastic. different coatingapplicationsonwood,metal,and variety ofuniqueproperties thatcanbetailored for and softdomains,thisproduct classexhibitsawide Due tothechemicalstructure ofphase-separatedhard NEP-free process, resulting insolvent-free products. dispersions are manufactured usinganNMP-and Joncryl Joncryl and hybriddispersions Polyurethane dispersions(PUDs) PUD hybriddispersions 2019 Water-based systems ® /Basonol ® andBasonol ® PUDandacrylic ® PUpolyurethane ® HYBacrylic / PUD hybrid /

Drying process:phaseseparation PUD (specialproperties) Advantages ofacrylics Advantages ofPUDs Mechanical properties chemical resistance development and Good hardness Fast dryingand recoating times Better-defined Film formation water phase Appearance C- O H N- Low odor O N-R- C-O-R-O H H N-C O Hybrid technology “best oftwoworlds” combination ofthe

properties control ofelastic (Mainly macrodiols) Soft phase physical cross-linker interactions: and electrostatic Rich inH-bonds Hard phase Synergistic dispersions atalowerisocyanatedemand. They cancompetewithtraditionalsecondaryacrylic especially suitedforhigh-gloss2KPUtopcoats. dispersions withverylowemulsifiercontentthatare a completelynewclassofcore-shell, OH-functional OH-functional acrylicdispersions Besides theOH-functionalprimarydispersionsJoncryl Joncryl for 2KPUsystems Your bestchoice OH andLuhydran ® OHandBasonol ® , BASF hasdevelopedBasonol , ® AC AC

® AC, ®

secondary dispersions,likePUDs. range canbeincorporatedhomogeneouslyinto The Basonat applications. opened thefieldof2KPUcoatingstowater-based Hydrophilic modificationsofaliphaticpolyisocyanates cross-linkers inwater-based coatings. Years agoitwasunthinkabletousepolyisocyanate Basonat Basonat The hydrophilic modified polyisocyanates from the close tothoseofsolvent-based2Kcoatings. life andabroad formulation latitude,withproperties water-based 2KPUcoatingswithasufficientlylongpot The lowviscositypolyisocyanatesfrom theBasonat acrylic dispersionsandPUDs. example, theycanbeusedtogetherwithOH-functional supplied, orcanbedilutedwithsuitablesolvents.For water-based systems ® HWrangeare emulsifiable inwater, as ® polyisocyanatesfor

® HWrangeallowsthemanufacturingof Water-based systems

2019 ® HA 19

Water-based systems Water-based systems Water-based systems 20 2019 2019 21

® ® Joncryl colloidals and Acronal systems Water-based non-cross-linking acrylic dispersions

1 Suited 2 Highly recommended

Solids by Viscosity Acid number on Coating layer Substrate Product Appearance pH MFT [°C] Tg [°C] Key properties and applications weight [%] [mPa·s] solids [mg KOH/g] Primer Topcoat Wood Metal Plastic Glass Concrete Colloidals

Excellent penetration, minimal grain raising, excellent clarity and sandability, Joncryl® 95-E Translucent dispersion 30.0 100 8.0 70 20 43 fast drying. Alkali-soluble dispersion for quick-drying interior stains, wood 2 - 2 - - - - sealers

High viscosity at low solids content, high transfer with roller coaters, good flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as Joncryl® 661 Semi-translucent dispersion 44.0 60 2.1 154 - 70 2 - 2 - - - - a thickener in various acrylic water-based paints, especially for roller coating applications

High viscosity at low solids content, high transfer with roller coaters, good flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as Joncryl® 663 Semi-translucent dispersion 40.0 450 6.2 131 - 30 2 - 2 - - - - a thickener in various acrylic water-based paints, especially for roller coating applications

High transfer with roller coaters, good flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as thickener in various acrylic Joncryl® 670 NEW Semi-translucent dispersion 46.0 85 4.5 - 12 - 2 - 2 - - - - water-based paints, especially for roller coating applications. Increased solids content compared to Joncryl® 663 Non-cross-linking acrylic dispersions

Anticorrosion primer, topcoat: zero add-on of APEO, ecological, good, corrosion category medium duty C2–C3, good adhesion and compatibility Acronal® PRO 761 White dispersion 50.0 325 9.3 < 20 22 ~ 20 2 1 - 2 1 - - with anticorrosive pigments, good sandability. Anticorrosion primer, topcoat, direct to metal

Silane-modified styrene acrylic dispersion. Universal, cost-effective product. Good corrosion protection, good adhesion and compatibility with anticorrosive Acronal® PRO 763 White dispersion 50.0 100–250 7–8 15 28 - pigments, corrosion category light to medium duty, C2–C3 for DFT 80 µm; 2 - - 2 - - - heavy corrosion protection (C5M) with high film built possible (240–400 µm) anticorrosion primer, topcoat, direct to metal

Superior performance, zero add-on of APEO and zinc, excellent anticorrosion protection for both glossy and matt paints (zinc phosphates not necessary for Acronal® PRO 770 NEW White dispersion 50.0 100–400 7–8 7 19 - 2 2 - 2 - - - good protection), excellent barrier to humidity, good adhesion, good early rain resistance, corrosion category medium duty, C3–C4

Zero add-on of APEO and zinc, excellent anticorrosion protection at > 80 µm Core dry film thickness, excellent barrier to humidity, good adhesion, good early rain Acronal® PRO 780 White dispersion 50.0 190 8.5 < 20 22 2 1 - 2 - - - shell resistance, high pigmentability with anticorrosive pigments, corrosion category medium duty, C3–C4. Anticorrosion primer, topcoat, direct to metal

Anticorrosion primer, topcoat: APEO-free direct plug-in of Acronal® PRO 760, ecological, good, corrosion category medium duty C2–C3, good adhesion Acronal® PRO 7600X NEW White emulsion 50.0 240 9.5 < 20 22 ~ 20 2 1 - 2 - - - and compatibility with anticorrosive pigments good sandability. Anticorrosion primer, topcoat, direct to metal

Anticorrosion primer, topcoat: zero add-on of APEO, good anticorrosion protection, excellent block resistance, high pigmentability (PVC 35 %) with Acronal® PRO 8977 White dispersion 50.0 200 9.5 - 37 ~ 36 2 1 - 2 1 - - anticorrosive pigments, corrosion category medium duty, C2–C3. Anticorrosion primer, topcoat, direct to metal 22 Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Non-cross-linking acrylicdispersions Product acrylic dispersions Joncryl ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® PRO1555 PRO1554 PRO1537 PRO1532 PRO1522 9500 8228 8227 8226 8225 8224 8223 8211 1915 79 77-E Water-based systems 2019 NEW NEW ® non-cross-linking Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion White opaquedispersion Translucent dispersion Translucent dispersion Translucent dispersion Translucent dispersion Translucent dispersion Translucent dispersion White dispersion Appearance weight [%] Solids by 41.5–44.0 51.0 40.0 48.0 40.0 42.0 30.0 44.0 46.0 45.0 46.0 45.0 45.0 45.0 44.0 50.0 250–1,750 700–1,500 Viscosity Viscosity [mPa·s] < 100 250 600 160 250 700 550 250 400 150 75 60 75 70 7.5–8.9 7.5–9.0 pH 7.9 7.6 7.8 8.5 7.9 9.0 7.8 7.7 8.2 8.5 8.1 8.4 9.0 7.6 solids [mgKOH/g] Acid numberon 100 36 53 30 27 68 12 57 53 68 23 62 49 26 - - MFT [°C] < 20 < 5 < 0 < 5 < 5 < 5 20 12 25 10 20 12 45 57 42 26 Tg [°C] Core shell < 0 14 46 21 60 43 22 35 34 7 - - - - - anticorrosion primer, topcoat resistance, excellentblockresistance, light duty, corrosioncategory C1–C2 Very fastdrying, excellentadhesion(also tonon-ferrous), water early C1–C2 anticorrosionprimer, topcoat humidity andcorrosionresistanceproperties, lightduty, corrosioncategory andUVresistance, water Good early excellentadhesionto varioussubstrates, lines resistance andclarity. onfast industrialinteriorwoodcoatings Dispersionfor resistanceandblockresistance,Excellent scratch fastdrying, goodchemical durability, mediumduty, corrosioncategory C2–C3 improvedwet adhesion,resistance (newtechnology); high gloss, exterior filmthickness)andchemical 30–40 µmdry Improved corrosionresistance(at good adhesion;application: primeron industrialandwoodcoating High Tg, goodhardnessdevelopment, andchemicalresistance, goodwater brushing enamels, timbercoatings aswellindustrialapplied reduce solventdemand, exteriorandinteriorstains, dispersionfor highgloss Low VOC, enhancement, andgrain goodappearance blendingpartnerto wood and engineered tropicalhardwoods anti-bleedingindustrialprimerfor Flexible dispersionfor woodtypes. propertiesontropicalhardwoodsandengineered Good isolating primersandtopcoats mended for Very fastdrying, excellentblockresistanceandstackability, dispersionrecom- pigment wetting, economicindustrialwoodandboardprimers dispersionfor resistance,Good water adhesionwith100%UVsystems, goodintercoat good resistance good weathering fasthardnessdevelopment,Excellent adhesiontoplasticsubstrates; very capability. coatings hardboardandotherflat-stock Dispersionfor Very goodblockresistance, excellentadhesion, low VOC, pigment-dispersing backings pigmentedprimers, dispersionsfor Excellent cost-performing furniture High pigment-bindingpower, excellentcostperformance, high-solidcontent. withcolloidaldispersions flexibility andadhesionincombination Medium-hard dispersionrecommendedasblendingpartnertoimprove Good balanceofflexibility furniture and flat-stock coatings furniture andflat-stock clearlacquersfor applied useinfastindustrially Low-VOC dispersionfor Excellent clarity, fastdrying, very goodblockresistance, goodstackability. pigments, mediumduty, corrosioncategory C2–C3topcoat, direct tometal thickness, highgloss, withanticorrosive andcompatibility exteriordurability film 30–40µmdry Corrosion protectionwithouttheuseofactivepigmentsat the DIYmarket adhesion tovarioussubstrates. andfor bothin industrialapplications Suitable Excellent stainresistanceinwhitepigmentedformulations. Providesgood Key properties andapplications / hardness, excellentpigmentwetting.

Primer 2 2 2 2 2 2 2 2 2 2 1 1 1 1 Coating layer - - Topcoat 2 2 2 2 2 2 1 1 1 1 1 - - - - - Wood 2 2 2 2 2 2 2 2 2 2 1 1 1 - - - Metal 2 2 2 2 2 1 1 ------1 Suited Water-based systems Substrate

Plastic 2 2 1 ------2 Highlyrecommended Glass ------2019 Concrete ------23

Water-based systems 24 Luhydran Joncryl Luhydran Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Joncryl Self-cross-linking acrylicdispersions Product self-cross-linking acrylicdispersions Joncryl ® ® ® ® ® ® ® ® ® ® 9530 9502 8336 8333 8331 8330 8322 8320 8310 1980-E Water-based systems 2019 ® ® A 875S A 849S2 NEW NEW ® andLuhydran Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion Semi-translucent dispersion White opaquedispersion Translucent dispersion White dispersion White dispersion White dispersion White dispersion Appearance weight [%] Solids by 40.5 44.0 44.0 40.0 38.5 38.0 41.0 39.0 45.0 42.0 42 41 Viscosity Viscosity [mPa·s] < 100 ® 200 500 150 250 100 60 75 75 80 50 85

pH 7.0 7.0 7.0 8.0 8.1 8.1 9.2 8.6 8.6 7.2 7.0 8 solids [mgKOH/g] Acid numberon 21 20 45 25 17 25 25 18 18 24 - - MFT [°C] < 5 60 39 40 59 33 46 45 30 56 58 44 Tg [°C] Core Core Core Core Core Core Core Core Core Core Core shell shell shell shell shell shell shell shell shell shell shell 37 wood coatings plasticizer, resistance. andscratch industrialinterior All-round emulsionfor Good blockresistance, clarity,forming, film sandability, excellentchemical, resistance. interior woodcoatings dispersionfor Second-generation High chemicalresistance, enhancementandscratch excellentgrain clear coat woodtypesas enhancement(“Anfeuerung”)ondifferent Provides goodgrain resistance, IKEAR2andDIN68861-1B inpigmentedformulations. enabling Excellent stainresistance, goodsolventresistanceandexcellent blocking very use inindustrialwoodcoatings quick hardnessdevelopment, excellentsandability. Dispersiondevelopedfor resistance,Excellent chemicalandscratch goodhot-blockresistance, very duty, C1–C2) light application: (corrosioncategory woodandindustrialcoatings for topcoat UVdispersions; block andhardnessdevelopment;blendingpartnerfor highclarityandchemicalresistance,Clear andpigmentedcoating; excellent blushing) resistance andchemicalresistance, excellenthumidityresistance(without highhardness,Excellent adhesiontoplasticsubstrates; goodblocking scratch resistance scratch Provides highwetfilmclarity,grain enhancement, excellent chemicaland interiorwoodcoating. dispersionfor Universal self-cross-linkingacrylic for primerandtopcoat clearandpigmentedfinishes applied solvent demand, balancedchemicalresistance. industrial Dispersionfor Fast drying, goodblockresistance, goodblendingpartnertoreducethe lightduty, (corrosioncategory wood andindustrialcoatings C1–C2) economical,resistance andsandability; goodclarity;application: for topcoat High gloss, highhardness, andUVresistance, fastdrying goodchemical look.natural interiorwoodapplications Dispersionfor Good chemicalresistance, andmarresistance, goodscratch low VOC, hand creamresistance resistance,Good scratch interiorwithsuperiorplasticizerand dispersionfor furniture and flooring applications furniture andflooring film clarity.for medium-tohigh-quality1Kand2KPU Primersandtopcoats resistance.High chemicalandscratch enhancementanddry Goodgrain clearandpigmentedsystems.Universal useas1Kand2KPUdispersionfor Key properties andapplications Primer 2 2 2 2 1 1 1 1 1 1 1 Coating layer - Topcoat 2 2 2 2 2 2 2 2 2 2 2 2 Wood 2 2 2 2 2 2 2 2 2 2 2 1 Metal 2 1 1 1 1 1 1 1 1 1 1 1 1 Suited Water-based systems Substrate

Plastic 2 2 2 1 1 ------2 Highlyrecommended Glass 1 1 1 1 1 1 1 1 1 1 - - 2019 Concrete ------25

Water-based systems 26 Luhydran Joncryl Joncryl Joncryl Luhydran Joncryl Basonol OH-functional dispersions Product stoving and2KPUapplications OH-functional acrylicdispersionsfor Basonol ® ® ® ® ® OH8312 OH8311 OH8300 8310 Water-based systems 2019 AC 1120W AC ® ® S939 T S938 T NEW NEW ® , Joncryl Semi-translucent dispersion Semi-translucent dispersion Translucent dispersion White dispersion White dispersion White dispersion White dispersion Appearance weight [%] ® Solids by 42.5 45.0 43.5 44.0 42.0 42.0 45 , andLuhydran Viscosity Viscosity [mPa·s] < 100 100 280 300 100 25 40 pH 3.0 2.0 9.6 8.2 7.6 7.0 7 Acid number [mg KOH/g] on solids 15 60 - - - - - ®

MFT [°C] < 15 > 60 < 5 60 48 50 44 [mg KOH/g] OH number on solids 120 100 100 120 42 80 29 with very goodchemicalresistance,with very resistance goodflexibilityandscratch withpolyisocyanates,compatibility excellentglossandlevelingincombination 2KPUhigh-performance,Dispersion for excellent high-glosstopcoats; with freeisocyanates (DTM), metaltopcoats, shortpotlifeincombination very andglasscoatings; solvent-based alkyd-melaminesystems. aredirecttometal Mainapplications general metalorstovingenamels. towater-reducible Goodalternative and metal andglasscoatings. dispersiontobeusedfor Thermosetting acrylic thermosetwater-based dispersionfor controlledacrylic Rheology industrial wood andindustrialcoatings gloss. furniturefoils, for Suitable melaminecoatings, curable heat and2K OH-functional dispersion, goodpigmentwetting, chemicalresistance, and ordirecttometal) (topcoat industrial coatings furniturefoils,for melaminecoatings, heat-curable and2KPUwood OH-functional dispersion, goodchemicalresistance, economicaldispersion furniture and flooring applications furniture andflooring film clarity.for medium-tohigh-quality1Kand2KPU Primersandtopcoats resistance.High chemicalandscratch enhancementanddry Goodgrain clearandpigmentedsystems.Universal useas1Kand2KPUdispersionfor resistance, andadhesion;application: industrialandwoodcoating for topcoat resistance, resistance, goodscratch goodhardnessdevelopment, block OH-functional dispersion, longpotlifeupto6hours, excellentchemical chemicals, andsolvents;application: industrialandwoodcoating for topcoat OH-functional dispersion(2KPU), excellentadhesion, resistancetowater, Key properties andapplications Primer 2 1 1 1 1 1 1 Coating layer Topcoat 2 2 2 2 2 2 2 Wood 2 2 2 2 1 1 - Metal 2 2 2 1 1 1 1 1 Suited Water-based systems Substrate

Plastic 2 2 1 1 1 - - 2 Highlyrecommended Glass 2 1 1 1 1 1 - 2019 Concrete ------27

Water-based systems 28 Joncryl Joncryl Joncryl Joncryl Basonol Polyurethane dispersions Joncryl Polyurethane acrylichybriddispersions Product Joncryl dispersions andPUD Joncryl ® ® ® ® ® ® ® U5168X U4320 U4310 U4190 HYB6340 HYB6336 Water-based systems 2019 PU1035 W NEW NEW ® andBasonol Semi-translucent dispersion Translucent dispersion Translucent dispersion Translucent dispersion White dispersion White dispersion White dispersion Appearance weight [%] Solids by ~ 43 36.0 40.0 40.0 36.5 40.0 38.0 / ® Viscosity Viscosity [mPa·s] acrylic hybrids polyurethane 15–95 < 100 ~ 78 ~ 35 80 50 50 6–8 pH 7.8 8.0 8.0 8.5 7.6 8.0 solids [mgKOH/g] OH numberon 35 ------Acid number [mg KOH/g] on solids 12 26 - - - - - MFT [°C] < 0 < 5 < 0 < 2 45 40 23 Basonol pigment-wetting properties speed; good withimproveddrying basecoats developedfor PUD especially Solvent-free, hybridwithexcellent acrylic polyurethane Taber enhancement good grain resistance,abrasion fasthardnessdevelopment, goodchemicalresistance, hybriddispersion, acrylic Polyurethane and excellentclarityaswellscratch and high-performance furnituretopcoats and high-performance high-quality water-based applications parquetflooring onwoodfor clearcoats resistance, fasthardnessdevelopment, good chemicalresistance. Hybridfor solvents dispersions;zeroadd-onofNMP, acrylic partner for NEP, andotherorganic e-coat, robustness;universalblending formulation metal);excellentflexibility; (plastic, excellentadhesiontovarioussubstrates plastic andmetalsubstrates; suitable for blend with harder dispersions; suitable for fibersizing for blendwithharderdispersions;suitable for suitable strates, excellentresistancetoboilingwater; uponadditionofpolyisocyanates high glossandgoodadhesiononwood, plastic(ABS/PC)andmetalsub- dispersion,Soft polyurethane range, overawidetemperature elasticbehavior glassfiber sizing for steam;suitable andwater to water toughness, highchemicalresistance, resistant, heat highgloss, goodbarrier Soft PUDwithgoodadhesiononmetalsubstrates, good elasticat very various plasticsubstrates resistance,chemical andwater excellentadhesiontowood, metal, e-coat, and sion resistance, goodbalanceoffilmhardness, flexibilityandtoughness, good Solvent-free, water-based aliphatic dispersion, polyurethane - goodabra very ® PU1035 for W isusedin1Kstovingand2Kprimerapplications Key properties andapplications ® abrasion abrasion Primer 2 2 1 1 1 1 Coating layer - Topcoat 2 2 2 2 1 - - Wood 2 2 2 1 1 - - Metal 2 2 2 1 1 - - 1 Suited Water-based systems Substrate

Plastic 2 2 2 2 - - - 2 Highlyrecommended Glass 2 2 2 2 1 1 - 2019 Concrete 1 1 1 1 - - - 29

Water-based systems 30 Luwipal Plastopal Luwipal Luwipal Luwipal Luwipal Luwipal Luwipal Luwipal Plastopal Carbamate resins Luwipal resins /methanol-etherified Melamine-formaldehyde Luwipal resin /methanol-butanol-mixed-etherified Melamine-formaldehyde Product amino resins Luwipal ® ® ® ® ® ® ® ® ® ® Water-based systems 2019 073LF 073 072 069 068 066ULF 066LF 066 063 052 ® ® BTW BTM Melamine resin, highiminocontent Melamine resin, highetherification Melamine resin, highetherification Mixed-etherified melamineresin, Hexa(methoxymethyl)-melamine, Hexa(methoxymethyl)-melamine, Hexa(methoxymethyl)-melamine, imino-methylolation degree imino-methylolation degree imino-methylolation degree imino-methylolation high methylolation degree high methylolation Melamine resin, balanced Melamine resin, balanced Melamine resin, balanced ® fully methyl-etherified fully methyl-etherified fully methyl-etherified fully Type ofproduct medium-etherified medium-etherified Carbamate resin / Carbamate resin / Carbamate andPlastopal degree degree 2 h, 125°C[%] Non-volatile at 78 –82 78 –82 73 –77 79 –83 81 –85 68 –72 69 –72 93 –96 93 –96 93 –96 75 –79 N / A 23 °C [mPa·s] Viscosity at Viscosity 2,500–3,700 3,000–5,000 3,000–5,000 4,000–7,000 2,500–3,500 1,600–2,400 4,000–6,500 2,000–6,000 2,000–6,000 2,000–6,000 1,000–1,500 500–800 ®

Methanol / Isobutanol Solvent Butanol ethanol Water Water Water Water Water Water - - -

Temperature reactivity Medium Medium Medium High High High High Low Low Low Low Low reactivity Medium Medium Medium Medium Acid High High High Low Low Low - - formalde- hyde [%] < 1.5 < 2.1 < 0.3 < 0.5 < 1.0 < 3.5 < 0.6 < 1.0 < 0.8 < 0.1 < 0.3 < 0.6 Free and industrialapplications For solvent-basedandwater-based coatings. Mediumtohighreactivity, furniturefoil for furniture coatings water-based resinfor Carbamate mediumtohighacidreactivity. coatings; and Forfoil content lowformaldehyde industrial applications; For water-based coatings. Highbakingreactivity, furniturefoil, for coil, automotiveand industrial applications For water-based coatings. Highbakingreactivity, furniturefoil, for coil, automotiveand coil, automotiveandindustrialapplications For solvent-basedandwater-based coatings. Highbakingreactivity, furniturefoil, for For water-based coatings. acid-curable Highreactivity, applications foil decorative for applications For water-based coatings. Very highbakingreactivity, andindustrial furniturefoil for high baking reactivity; for automotiveapplication high bakingreactivity;for for water-basedMethanol-butanol-mixed-etherified resin andsolvent-basedcoatings; furniture coatings with lower formaldehyde contentthanPlastopal withlowerformaldehyde furniture coatings water-based resinfor Carbamate mediumtohighacidreactivity. coatings; and Forfoil furniture foil and coil-coating applications; noCMR labeling applications; andcoil-coating furniture foil For solvent-basedandwater-based coatings. acid-curable Very highreactivity, for applications: andcoil-coating furniture foil content lowformaldehyde For solvent-basedandwater-based coatings. acid-curable Very highreactivity, for applications andcoil-coating furniture foil For solvent-basedandwater-based coatings. acid-curable Very highreactivity, for Key properties ® BTM Wood 1 1 1 1 1 1 1 1 1 1 1 1 Metal 2 2 2 2 2 2 2 2 2 2 2 2 Substrate 1 Suited Plastic ------Water-based systems

2 Highlyrecommended Glass 2 2 2 2 2 2 1 1 1 1 1 1 2019 Concrete ------31

Water-based systems 32 Basonat Basonat Basonat Basonat Hydrophilic (NEW: availableat<0.1%residual diisocyanate) Basonat Low-viscous (NEW: availableat<0.1%residual diisocyanate) Product Basonat Basonat Basonat Basonat Basonat Basonat ® ® ® ® ® ® ® ® ® ® Water-based systems 2019 HW4000 HW3280MBA HW2100 HW2000 HW1180PC HW1000 HI2000NG HA3000 HA2000 HA1000 Hydrophilically modified HDI /IPDI modified Hydrophilically ® HDI isocyanurate low-viscous HDI isocyanurate Hydrophilically modifiedHDI Hydrophilically modifiedHDI Hydrophilically modifiedHDI Hydrophilically modifiedHDI Hydrophilically modifiedHDI Hydrophilically polyisocyanates Type ofproduct HDI allophanate HDI allophanate HDI allophanate isocyanurate isocyanurate isocyanurate isocyanurate isocyanurate isocyanurate Solids byweight[%] 100 100 100 100 100 100 100 100 80 80 Viscosity at23°C Viscosity 3,000–3,500 2,000–3,600 1,500–3,000 2,000–6,000 800–1,400 900–1,500 900–1,500 450–850 200–400 500–900 [mPa·s] Propylene carbonate Propylene 3-Methoxy 1-butyl Solvent acetate ------11.5–12.5 13.2–14.0 18.5–19.5 16.9–17.9 17.5–18.5 16.5–17.5 22.5–23.5 19.0–20.0 18.5–21.5 21.0–23.0 NCO [%] Easy-mixing polyisocyanate for general use with improved physical-drying andhardnessdevelopmentinwater-based generalusewithimprovedphysical-drying for Easy-mixing polyisocyanate systems Diluted versionofBasonat development. Compatible with primary and secondary dispersions for use in DIY 2K PU floor coatings orhigh-qualityfurniture coatings useinDIY2KPUfloorcoatings dispersionsfor development. andsecondary withprimary Compatible withhighchemicalresistance. incombination Easy emulsification technology. stabilization Newpatented for handmixingtogetherwithfasthardness Lowsolventdemand regarding miscibility, resistance, andreactivity dispersionsinwater-basedAll-purpose, andsecondary low for 2KPUcoatings generalusewithprimary for hydrophilicpolyisocyanate VOC systems withbalancedproperties Easy-mixing versionofBasonat lent chemicalresistance Hydrophilic, dispersions. generaluseinwater-based for orsecondary polyisocyanate low comprisingprimary fast-drying Enables 2KPUcoatings VOC systemsprovidingexcel- Low-viscous trimer for high-solid 2K PU coatings without limitation inchemicalresistanceandreactivity. withoutlimitation high-solid2KPUcoatings Low-viscous trimerfor Itcanalsobecombinedwithwater-emulsifiable Basonat high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat dispersions secondary dispersions for water-based dispersionsfor secondary NG: 2KPUwoodcoatings; reducedcolordriftinformulations water-based 2KPUwoodcoatings water-based 2KPUwoodcoatings water-based 2KPUwoodcoatings ® HW 1000 for faster incorporation in water-based 2K PU systems based on primary or secondary dispersions inwater-based fasterincorporation HW1000for orsecondary 2KPUsystemsbasedonprimary ® HW 1000 providing a combination of fast drying and easy mixing for water-based 2K PU systems in combination with primary and secondary water-based andeasymixingfor andsecondary offastdrying HW1000providingacombination withprimary 2KPUsystemsincombination Key properties andapplications ® ® ® HW types and secondary dispersions for dispersionsfor HWtypesandsecondary dispersionsfor HWtypesandsecondary dispersionsfor HWtypesandsecondary Water-based systems ® HWtypesand 2019 33

Water-based systems 34 Waterpoxy Amine adducts Product Waterpoxy Epoxy resins Product Waterpoxy Waterpoxy Waterpoxy and amineadducts Waterpoxy Water-based systems 2019 ® ® ® ® ® 801 760 751 1455 1422 amine adduct amine adduct amine adduct Water-based Water-based Water-based Emulsion ofsolid Emulsion ofsolid product epoxy resinin epoxy resinin Type of product Type of water water ® Appearance epoxyresins Solution Solution Solution Milky emulsion Milky emulsion Appearance weight [%] Solids by weight [%] 60 60 59 Solids by 56 55 Viscosity Viscosity [mPa·s] 11,750 6,500 700 Viscosity Viscosity [mPa·s] 3,500 4,000 thickness High Yes Yes No thickness High No No Specific gravity [g/cm 1.08 1.09 1.09 Specific gravity 3 ] [g/cm 0.96 1.1 3 ] content [%] Free amine ~ 0.2 ~ 0.2 < 1 equivalent weight Epoxy 1,035 1,150 resistance Yellowing High High High suitable applications areautomotiveandmarinecoatings applications suitable other sandedandrecoated; canbequickly filmproperties that rapid-cure longpotlifebutwith withalowsolventcontentoffering produce formulations gloss andhardnesscomparedto Waterpoxy fast tack-freeandcuringtimesaswellgoodchemicalresistance;improved corrosion and chemical resistance; combinations with corrosion andchemicalresistance;combinations Waterpoxy excellent giving industrialandmaintenancecoatings heavy-duty resins for Water-reducible withemulsifiedepoxy combination for epoxycuringagent speed and very longpotlife speed andvery wetting properties enabling optimumpigmentdispersion wetting propertiesenabling excellent offer bothresinandcuringagent goodprotectiveperformance; very floorings); combinedwith Waterpoxy (i.e.protection formulations primers, protectivecoatings, self-leveling Excellent wetting, flow, andresistivityproperties,for concreteandmetal application andcuringbehavior application donotlimitthe of potlifeandgoodchemicalresistance;lowtemperatures withstandardliquidepoxyresin,in combination end itshowsadefinable water-based used application; epoxyself-levelingflooringwithhighthickness propertiesmakesitusefulfor lowshrinkage solution;very Curing agent with Waterpoxy incombination concrete; producesascuringagent for protective coatings water-based formulating usefulfor Particularly systems, coating primers, and combinedwith offers protection coatings; Waterpoxy ofindustrialmaintenanceandconcrete usefulintheformulation Particularly ® 751 excellent drying/curing characteristicscombinedwith 751excellentdrying/curing Key properties Key properties ® 1455 ® / 1455 1422, it offers very fast drying 1422, fastdrying very itoffers ® 751 as curing agent 751ascuringagent ® 1422 equivalent weight equivalent weight Hydrogen Hydrogen (HEW) (HEW) 225 210 91 Wood Wood - - - - - Metal Metal 2 2 2 2 - 1 Suited Water-based systems Substrates Substrate Plastic Plastic

1 - - - - 2 Highlyrecommended Glass Glass 1 1 1 1 1 2019 Concrete Concrete 2 2 2 2 1 35

Water-based systems 36 Laropal Joncryl Joncryl Joncryl Joncryl Joncryl Waxes andcross-linker solutions Product Joncryl Grinding resins Product Zinc OxideSolution#1 Joncryl waxes, andcross-linker solutions Joncryl ® ® ® ® ® ® ® ® Wax 35 Wax Strip2000 HPD496-E HPD296-E HPD96-E HPD71-E 8078 Water-based systems 2019 LR9008 ® NEW NEW andLaropal Yellowish liquid Appearance Clear liquid Clear liquid Clear liquid Clear liquid Clear liquid Type ofproduct Wax dispersion Additive Additive Solids byweight[%] 35.5 31.0 31.0 32.0 34.5 35.0 Semi-translucent dispersion Semi-translucent dispersion ® Appearance Clear solution grindingresins, Viscosity [mPa·s] Viscosity 2,000–15,000 2,000 1,750 500 200 500 Solids byweight[%] 34.5 25.0 45 7.5–8.5 pH 8.1 8.5 8.5 8.3 8.5 solids [mgKOH/g] Acid numberon Viscosity [mPa·s] Viscosity 178 141 233 221 224 < 100 - 25 5 Molecular weight 11.4 pH 9.8 3.0 [g/mol] 11,500 16,500 17,000 5,500 8,500 - Melting pointofwax [°C] 130 - - Tg [°C] 105 120 101 15 58 - Very-low pigmentdispersions concentrated highly VOC ammonia-neutralizedresinsolutionfor Excellent viscositystability, pigmentwetting, andcolordevelopment. Very-low pigmentdispersions concentrated highly VOC ammonia-neutralizedresinsolutionfor Excellent viscositystability, pigmentwetting, andcolordevelopment. Excellent viscositystability, pigmentwetting, andcolordevelopment Enables high-concentrated dispersions, high-concentrated Enables excellentcolordevelopment, lowmaintenance, pH-neutral Excellent pigmentwetting, resolubility, compatibility, pigmentpastes for stability andrheology Solution of a modified aldehyde resin for universalpigmentdispersions Solution ofamodifiedaldehyderesin Excellent pigmentwetting, broadcompatibility. Polyethylene wax to improve scratch resistance, waxtoimprovescratch Polyethylene slip, andblockresistance coatings, and2Kwoodindustrialcoatings OH-functional dispersion, goodpigmentwetting, chemicalresistance, andgloss. furniturefoils, for Suitable melamine curable heat Cross-linker for carboxy-functional acrylics to improve early resistanceproperties toimproveearly carboxy-functionalacrylics Cross-linker for Water resistance, drying, hardness.

Key properties andapplications Key properties andapplications

Water-based systems 2019 37

Water-based systems Bitte Kurzversion desSolvent-based Kapiteltitels eintragen systems 2019 39

Solvent-based systems Solvent-based systems

Solvent-based systems represent the majority of applications in the coatings industry. We offer a wide range of amino resins for high-solid performance and baking reactivity, OH-functional acrylic copolymers, hyperbranched polyesters, hardeners, and grinding resins for all solvent-based binder classes. Our high-quality products are usable for 1K and 2K systems and fulfill the current VOC regulations.

Performance, however, is preeminent: Good adhesion, resistance to weathering, yellowing, and chemicals; flexibility and economic cost in use, and especially hardness and luster are among the hallmarks of these product ranges.

Our products cover a broad application window (especially temperature, humidity, film thickness) and include applications for physical drying, low-bake systems, and high-bake processes. They are usable for a majority of substrates and for matt and high-gloss finishes. 40 Fields ofapplication–mainfocusonhigh-solid 2KPU To leveragethefullpotentialofthesesystems, and reducing theglasstransition temperature. content are reducing themolecularweightofpolyols based systems.Two optionsforachievinghigh-solid systems canbesubstitutedbyhigh-solidssolvent- coatings, low-tomedium-solidssolvent-based For environmental andworkers’ protection in2KPU Basonol Basonat With and high-solid2KPUcoatings Polyisocyanates forconventional binders for1Kand2KPUcoatings Your bestchoiceforcross-linkers and market’s highestperformancerequirements. well-established marketstandards andfulfillsthe optimization anddevelopment,BASFprovides and high-solidapplications.Thankstocontinuous It issimplytheidealhardener formostconventional hardeners forhigh-performance2KPUcoatings. Performance level 2019 Solvent-based systems Conventional 2KPU ® weoffer high-qualitypolyisocyanate ® HPEhyperbranchedpolyesters High-solid 2KPU

+HPE

5–30% (solidsonresin solids). 5–30% and polyisocyanates.Therecommended doserateis in systemsbasedonlowmolecularweightpolyacrylates a co-binderimproves curingspeed atincreased potlife and resistance ofthecured film.UsingBasonol possible drop incuringspeed andhampered hardness a complementingsolutionisneededtoaddress a which istin-free andidealforlow-temperature curing. With Basionics With HW hardeners atresidual diisocyanatelevelsof<0.1%. formulations. As of 2019 we offer all Basonat HI, HA, and performance withverylowyellowinginautomotiverefinish (Basonat Our newgenerationofisocyanurategrades ® HING)combinesthiswell-knowntechnical § § § § § § § § § § § § § § § § Minimal impactonVOC Increased potlife Improved finalhardness Improved reflow behavior Improved chemicalresistance Faster curingspeed Excellent weatherresistance Early blockresistance, earlyhandling ® KAT1 weoffer theperfectcatalyst, ® HPEas § such asBasonat used asbindersforcross-linking withpolyisocyanates copolymers forsolvent-based coatings.Theycanbe Joncryl Joncryl Daimler EtchTest–treeresinresistanceandpancreatin BASONOL the networkdensitytoincrease chemicalresistance, binder inacrylate other curingtechnologies.Basonol per­ can andcoilcoatings,ineachfieldofusetheprice/ Automotive clearcoats,pigmentedindustrialtop used curingchemistryinavarietyofcoatingsapplications. Melamine curing1Kstovingtechnologyisstillawidely close to2KPolyurethane coatings.Basonol boost chemicalandmechanicalperformancestoalevel + + + 2 + Acrylic reference + + 1 + + 1 Acrylic reference Tree resinresistance Pancreatin resistance

§ PENDULUM HARDNESS [OSC] KOENIG 2 1 1 2 2 drying time Slight increase ofsurfacehardness atlongeroven 100 120 0 0 0 0 0 0 0 0 for­ 20 40 60 80 % HPE1265B % HPE1170B % HPE1265B % HPE1170B % HPE1170B % HPE1265B % HPE1265B % HPE1170B 0 BASONOL HPE1170B mance behaviorisstillunbeatablecompared to ® polyolgradesare hydroxyfunctional acrylic reference Acrylate 10' ® HPE1170B ® / ® melamine curingsystemscanimprove OH-functional acrylicresins orincombination withotherbinder 20' 1 0 STOVING TIMEAT100 °C [MIN] % Basonol 30 30 32 32 30' Automotive stovingtimewindow ® HPE1170 34 34 36 36 ® HPE can significantly HPEcansignificantly 40' 38 38 2 0 % Basonol 40 40 ® HPEasco- 50' 42 42 ®

44 44 HPE 1170 60' 46 46 ​ 48 48 § stability andreduced sensitivitytohydrolysis. the highlybranchedpolyesterpro­ technology andtherightchoiceofmonomerstobuildup to thepure acrylatesystem.BASF’s uniquecross-linking The properties ofthefinalfilmcanbesig­ especially pancreatin, tree resin, andpetrol resis­ tem­ HPE showveryrobust performancesatun­ ester’s typicalreflow effect. Coatingscured withBasonol and surfacehardness atahighflexibilitywiththepoly­ § low-VOC systems. for producing outstandingcoatingperformancesin levels. Basonol chemistries toimprove performanceatreduced VOC § § PENDULUM HARDNESS [OSC] KOENIG 50 50 20% ofBasonol 100 – More hardness /reactivity atlowtemperatures on surfacehardness 100 120 140 160 20 40 60 80 per­ 0 BASONOL HPE1170B 52 52 atures andincreases finalchemical resis­ 120 °C 80 reference Acrylate 54 54 89 56 56 ® HPEisanespeciallyeffective co-binder 100 ® 58 58 HPE 1170 B has significant impact HPE1170Bhassignificantimpact 1 0 % Basonol STOVING TEMPERATURE[°C] 60 60 109 Solvent-based systems 62 62 ® 120 HPE1170 64 64 vides high weathering vides highweathering 132 66 66 143 68 68 nificantly superior nificantly superior 2 0 % Basonol der 70 70 157 ­­cure 72 72 2019 tances, tances.

168 ®

HPE 1170 74 74 180 41 ® °C °C

Solvent-based systems 42 Luwipal may beformulated,dependingontheresin structure. finishes. Bothsolvent-basedandwater-based systems finishes, acid-curingandphysicallydrying Applications forthisclassofproducts includebaking Luwipal for everychallenge Select therightaminoresin chemicals. is characterizedbyhighflexibilityand resistance to and lightfastnessare limited. However, Luwipal Because ofthisaromatic ring, weatherresistance raw materialbenzoguanamineinsteadofmelamine. Benzoguanamine-formaldehyde resins containthe of etherification, reactivity, andtypeofcuttingsolvent. distinguished byviscosity, molecularweight,degree formaldehyde, andanetherificationalcohol.Theyare are condensationproducts consistingofmelamine, Melamine-formaldehyde resins inthecoatingsindustry luster. yellowing, andchemicals,especiallyhardness and the paintfinishmustprovide resistance toweathering, and benzoguanamineresins Melamine-formaldehyde 2019 Solvent-based systems

® gradesare thepreferred choicewherever ® grades–

® B

Plastopal In contrasttomelamine-formaldehyderesins, based andwater-based systemscanbeformulated. finishes. Dependingon resin structure, bothsolvent- finishes, acid-curingandphysicallydrying Applications forthisclassofproducts includebaking Plastopal used wherever lastingflexibility is required. an etherificationalcohol.Plastopal group containingrawmaterial, formaldehyde,and Carbamate resins are composedofaurethane to workassolebinders. co-reactantneed anexternal andplasticizedproducts BASF’s product rangeincludesbrittlecross-linkers that of etherification, reactivity, andtypeofcuttingsolvent. distinguished byviscosity, molecularweight,degree formaldehyde, andanetherificationalcohol.Theyare are condensationproducts consistingofurea, Urea-formaldehyde resins forthecoatingsindustry cost ofuse. resistance tooverbaking,flexibility, andeconomic where thepaintfinish requires goodadhesion, Urea-formaldehyde resins ® gradesare thepreferred choiceincases

® grades–

® BTgradesare

non-volatile content(NVC)*versusreactivity** * 2g Luwipal ** Reactivityaccording tolong-termexperience (pendulumhardness, xylene resistance, etc.) 1 Methanol-etherifiedmelamine resin 100 100 40 60 40 60 20 20 80 80 0 0 / NVC (%) NVC (%) Low Low Baking reactivity withsulfonicacid Baking reactivity withoutcatalyst 2 h / 125 °C(dilutedto250 m 1 ® andPlastopal Medium Medium · Pas, ICI) 1 1 Benzoguanamineandmixed-etherifiedmelamine resins ® grades / 2 3

3 2 High High C A effect onstoragestabilityandneedsseparatelabwork. of allfunctionalgroups. Theadditionofcatalystshasan C amino resins and. enhance thebakingreactivity ofmethylolgroups in B cross-linkers. drying conditionsisachievedwithhighlyreactive baking reactivity. Superiorperformanceintermsof content apartiallyetherifiedamino resin offers higher amino resins are mostbeneficial.Atthesamesolids A 100 40 60 20 80 To achievehigh-solidcoatings,highlyetherified Weak acids(e.g.maleicacid)usedasacatalyst Strong acids(e.g.sulfonicacid)boostthereactivity 0 NVC (%) Low Baking reactivity withmaleicacid 1 1 Butanol-etherifiedmelamine resins Medium Solvent-based systems 2 2019 1 Urea resins

3 High B 43

Solvent-based systems 44 aldehyde-based resin, itis asuniversalLaropal A 81. Laropal on pigment). A 81,significantlowerVOCscanbe reached (depending Typical propertiesofLaropal Laropal Laropal Laropal Laropal The grindingresin of stability. and goodflowbehaviorcombinedwithahighdegree created: highpigmentloading, excellentcolorstrength, pigment pasteswiththefollowingproperties canbe that, compared topigment pastesbasedonLaropal When combinedwithourEfka pigment pastesalike. preferred solutionforuniversalmixingsystemsand solvents usedinindustrialcoatingsmakesitthe compatibility withallthemainbindersandorganic high-quality aldehydegrindingresin. Itsoutstanding temperature Tg Glass transition Saponification value Hydroxyl value Density at20°C Acid value Iodine colornumber Softening temperature Delivery form 2019 Solvent-based systems ® ® A-8Lisaliquidgrindingresin. Since itisan A81hasanexcellentreputation asa ® ® A-8L A81 ® A-8Lhasbeendesignedinsuchaway, ~ 57°C ~ 65mgKOH/g ~ 40mgKOH/g ~ 1.11g/cm³ ≤ 3mgKOH/g ≤ 3 80–95 °C Solid /pellets ® dispersingagents, ® A81

®

®

during processing, anditis easytopump. dilution stepcanbeskipped,nodustisreleased On topofthat,easierhandlingisguaranteedsincethe Laropal

0 1 Solubility ofLaropal BASF’s universalLaropal pastes. producing highlycompatiblesolvent-basedpigment aldehyde resin byBASFisaworld-classbinderfor time, space,andmoney. this highlyflexibleproduct reduces inventoryandsaves as increasing theefficiency ofyourmixingprocesses, standard forallstate-of-the-art mixingsystems.Aswell 1K acrylic,2KPU,orstovingsystems.Laropal that itcanbeusedforalloutdoorapplicationsin to theeffects ofhumidityandtemperature. Thismeans

Aliphatic hydrocarbons Aromatic hydrocarbons Ketones Esters Alcohols Adding 2–5%ofanaromatic solventproduces stablesolutions Solutions tendtoseparateattemperatures below15°C. Soluble ® A81doesnotyellow, andishighlyresistant ® grindingresin isthemarket ® A81 0 1 1 1 1

® A81

of Laropal Compatibility 1 Laropal One fitsall– Nitrocellulose 1 Hydrocarbon resins Epoxy resins Alkyd resins resins Melamine-formaldehyde Urea-formaldehyde resins Acrylic resins VC copolymers Chlorinated rubber Cellulose acetobutyrate Ethyl cellulose Cellulose nitrate Compatible NC 1 ® 0 , theuniversalgrindingresinformixingsystems Without Laropal

Limited compatibility ® 2 Two-component polyurethane Alkyd A81

2K PU ® 2 EP 3 3 Epoxy 0 1 1 1 1 1 1 1 1 1 1 16 pigmentpastes 4 pigments Pigment paste Binder system Pigment with Laropal One fitsall with allbindersystems Universal compatibility 4 pigmentpastes 4 pigments of Laropal Viscosity profiles Viscosity [mPa·s] 9,000 1,000 2,000 3,000 4,000 5,000 6,000 7,000 8,000 0 70 Laropal ehx rplaeae(P) MPA /Solvesso Methoxy propyl acetate(MPA) Solvesso

® ® ® A 81[%] A81invarioussolvents

® 100 NC 65 1

Solvent-based systems With Laropal Alkyd 60 2K PU ® Butyl acetate 2 55 2019 EP 3 ® 100 45 50

Solvent-based systems 46 Basonol Joncryl Joncryl Joncryl Basionics Catalyst for2KPU Basonol Hyperbranched polyesters Joncryl Acrylic polyolsforhigh-solidcoatings Joncryl Acrylic polyolsformedium-solidcoatings Joncryl Acrylic polyolsforconventionalcoatings Product Joncryl Joncryl Joncryl Basionics ® ® ® ® ® ® ® ® ® ® 507 909 552 587 581 804 963 922 Solvent-based systems 2019 HPE1265B HPE1170B ® Kat 1 Kat ® White to slightly yellow,White toslightly clear to slightly turbid clear toslightly acrylic polyols, Basonol Clear solidresin Clear solidresin Clear solidresin Appearance Clear liquid Clear liquid Clear liquid Clear liquid Clear liquid Clear liquid Clear liquid ® catalyst weight [%] Solids by > 98.5 64–66 69–71 100.0 100.0 > 97 80.0 68.0 62.0 80.0 100 500–2,000 Viscosity Viscosity [mPa·s] 4,000 6,500 5,500 2,400 4,000 5,500 7,500 Solid Solid Solid n-Butyl acetate n-Butyl acetate n-Butyl acetate n-Butyl acetate Butyl acetate Butyl acetate Solvent - - - - - Tg [°C] -63 25 49 60 62 70 38 20 7 7 - ® HPE, on solids[%] OH number 3.5 2.7 2.8 4.7 1.3 5.5 8.2 4.2 4.2 3.9 - [mg KOH/g] OH number on solids 117 155 180 270 145 145 130 90 94 45 - Basionics cal resistanceandoutstandingdurability. industrialapplications 2KPUfor Forversatile time, hardnessdevelopmentandfastdrying Excellent early excellentglossandcolorretention, goodchemi- hardness. insolvent-basedsystems high-qualityfurnitureandfloorcoatings for suitable Solidpolyol goodchemicalresistanceand offering coatings usedinboth2KPUandacid-curable 100% solidpolyol useful as a low-VOC modifier for officefurnitureandgeneralmetalcoatings useful asalow-VOCmodifier withgoodhardness, polyol Acrylic stainresistance, andpigmentdispersibility, and broadresincompatibility versatility formulator withlongpotlife,drying andexcellentUVchemicalresistance, provides costbenefitand solidform Good outdoordurability, highgloss, andglossretention. Conventional-solids workhorsepolyol, fast very be usedasamodifier economical2KPUcoatings,formulate versatility,formulator providescostbenefitand solidform canalso Fast drying, highhardness, lowOHvalue. lowNCOdemand, Highequivalentweightfor canbeusedto Hyperbranched polyester as low OH value alternative withsimilarpropertyprofileasBasonol aslowOHvaluealternative Hyperbranched polyester and2KPUhigh-solidtopcoats,PU high-solidrefinishclearcoats for conventionalsystems butalsousable hardnessdevelopment,early andcross-linking.for 2K Improved chemicalresistanceandreflowbehavior showslowimpacton that Hyperbranched polyester fasterdrying, significantly high-solidcoatings; VOC for pot life good drying time and pot life characteristics; useful as a sole binder or a modifier for higher timeandpotlifecharacteristics;usefulasasolebinderormodifier good drying Tgpolyols formulations, theadditionof Basionics andadhesives. formulations isactiveincoatings catalyst Inconventionalsolvent-basedandhigh-solid conditions. drying andforced lowtemperatures activityat highcatalytic ionic characterdisplaying The early polishing early B, higher slightly at VOC. handlingand early Itshowsfastcuringspeedwithhardnessdevelopmentfor outdoor durability. Non-HAPsapplication 4.2% OHonsolidresin, low-VOCcapability, excellentflowandleveling, andexcellent broadcompatibility Fast cureversionofJoncryl with properlightstabilization goodoutdoordurability goodadhesionondifficultsubstrates; highflexibilityandvery withextremely coating solvents, usedtoplasticizeand several goodchemicalresistanceagainst withhighOHnumbertoobtainavery Very softandreactivepolyol ® KAT reactions. polyurethane for 1isametal-freecuringcatalyst Itisalow-viscousliquidwith ® 507, withoutstandingreactivity / or toreduce arubber-like asasolebinderitforms VOC in2KPUcoatings; Key properties andapplications ® KAT alonger at lowertemperature 1enhancesthecuring speed at / pot lifebehavior. Low offering VOC polyol ® HPE1170 Wood 2 2 2 1 1 1 1 1 1 1 1 Metal 2 2 2 2 2 2 2 2 2 2 2 1 Suited Solvent-based systems Substrate

Plastic 2 2 2 2 1 1 1 1 1 1 1 2 Highlyrecommended Glass 2 2 1 1 1 1 1 1 1 1 1 2019 Concrete 1 ------47

Solvent-based systems 48 Luwipal Luwipal Luwipal Luwipal Co-cross-linker Luwipal resin /n-butanol-etherified formaldehyde Benzoguanamine Luwipal resins /methanol-etherified Melamine-formaldehyde Luwipal resins /methanol-butanol-mixed-etherified Melamine-formaldehyde Luwipal resins /butanol-etherified Melamine-formaldehyde Larotact Product Luwipal Luwipal Luwipal Luwipal Luwipal Luwipal and Larotact Luwipal ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® Solvent-based systems 2019 B017 072 066ULF 066LF 066 052 044ULF 018RF 018BX 018 016 015 014 012 150 Fully butyl-etherifiedmelamineresin Fully Triazine (melamine-based derivative Melamine resin, highmethylolation, Melamine resin, highmethylolation, Melamine resin, highmethylolation, Melamine resin, highiminocontent Melamine resin, highmethylolation Mixed-etherified melamineresin, Hexa(methoxymethyl)-melamine, Hexa(methoxymethyl)-melamine, Hexa(methoxymethyl)-melamine, imino-methylolation degree imino-methylolation Melamine resin, highMW Melamine resin, highMW high methylolation degree high methylolation degree high methylolation Melamine resin, balanced Benzoguan amineresins, ® fully methyl-etherified fully methyl-etherified fully methyl-etherified fully blocked isocyanate) Type ofproduct higher etherified higher etherified higher etherified aminoresins high imino high imino ® / /

co-cross-linker 2 h, 125°C[%] Non-volatile at 73–77 68–72 64–68 71–75 56–60 93–96 93–96 93–96 94–97 79–83 69–72 72–75 52–55 50–54 23 °C [mPa·s] 6,000–10,000 Viscosity at Viscosity 4,000–7,000 3,000–6,000 4,000–7,000 2,000–6,000 2,000–6,000 2,000–6,000 2,000–5,000 3,000–5,000 4,000–6,500 1,300–2,000 900–1,400 600–1,000 600–1,000 10–50 Isobutanol Isobutanol n-Butanol Solvent Butanol / Butanol / Butanol / Butanol Butanol Butanol Butanol Butanol xylene xylene xylene - - - - Temperature reactivity Medium Medium Medium Medium Medium Medium Medium High High High Low Low Low Low - reactivity Acid High High High High High ------formalde- hyde [%] < 0.6 < 0.5 < 0.4 < 0.6 < 1.0 < 0.1 < 0.3 < 0.6 < 0.4 < 0.1 < 1.0 < 0.7 < 1.0 < 0.5 Free - standard for automotiveclear-coatstandard for solventcutbutanol applications; For solvent-based, withmediumtohighbakingreactivity; medium-solidautomotiveorindustrialcoatings lower solidscontentthanLuwipal For solvent-based, withmediumtohighbakingreactivity; medium-solidautomotiveorindustrialcoatings coil-coating finishes coil-coating withaminoresinsoralone.in combination areautomotive,application Preferredfieldsof industrial, and itself, flexibility makingitanoptimumcross-linkeryieldingadvantageous 120°C. above temperatures at releasedduringcross-linking. Noformaldehyde Itdoesnotcross-linkwith Low-viscous andlow-molecular-mass cross-linker. blockedisocyanate Deblockingandcross-linkingstart standard for automotiveclear-coatstandard for content reducedformaldehyde applications; For solvent-based, withmediumtohighbakingreactivity; medium-solidautomotiveorindustrialcoatings automotiveclear-coatstandard for applications For solvent-based, withmediumtohighbakingreactivity; medium-solidautomotiveorindustrialcoatings industrial applications For solvent-basedandwater-based coatings. Highbakingreactivity, furniturefoil, for coil, automotiveand noCMRlabeling applications; coil-coating For solvent-basedandwater-based coatings. acid-curable Very highreactivity, and furniturefoil for applications:coil-coating content lowformaldehyde For solvent-basedandwater-based coatings. acid-curable Very highreactivity, and furniturefoil for applications coil-coating For solvent-basedandwater-based coatings. acid-curable Very highreactivity, and furniturefoil for For solvent-based, withmediumtohighbakingreactivity medium-solidautomotiveorindustrialcoatings resistance; noCMRlabeling withhighreactivityandexcellentchemical solvent-basedfurnitureandwoodfloorcoatings For acid-curable physical drying For solvent-based, highbakingreactivity;fast withvery medium-solidautomotiveorindustrialcoatings coating primers coating mediumtohighbakingreactivity. solvent-based coatings; Benzoguanamine resin;for Forcoilandcan automotiveapplication reactivity; for for water-basedMethanol-butanol-mixed-etherified resin highbaking andsolvent-basedcoatings; baking reactivity;fastphysicaldrying for solvent-based,i-Butanol-etherified resin; high withvery medium-solidautomotiveorindustrialcoatings ® 016 Key properties / xylene / hardness relation. Bestuse Wood 2 1 1 1 1 1 ------Metal 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 1 Suited Solvent-based systems Substrate

Plastic ------2 Highlyrecommended Glass 2 2 2 2 1 1 1 1 1 1 1 1 1 1 1 2019 Concrete ------49

Solvent-based systems 50 Plastopal Plastopal Plastopal Plastopal Laroflex Polyvinyl chlorides Product Plastopal Urea resins Product Laroflex Laroflex Laroflex Laroflex Plastopal Laroflex Plastopal ® ® ® ® ® Solvent-based systems 2019 ® ® ® ® ® ® MP60 MP45 MP35 MP25 MP15 RH H85EBLF H73IB EBS400I EBS400B BTB Urea resin, low-etherified ® Type ofproduct medium-etherified medium-etherified medium-etherified medium-etherified Carbamate resin, Carbamate highly etherified highly polyvinylchlorides ® Urea resin, Urea resin, Urea resin, Urea resin, urea resins and Fine whitepowder Fine whitepowder Fine whitepowder Fine whitepowder Fine whitepowder Physical form

Non-volatile at2h, 125 °C[%] 59–62 83–88 59–62 59–62 59–62 59–62

Viscosity [mPa·s](20%solution Viscosity Viscosity at23°C Viscosity 1,000–1,300 3,000–6,000 1,400–1,700 1,400–1,700 1,600–2,400 4,000–7,000 [mPa·s] in toluene,23°C) 40–50 30–40 20–26 12–18 > 50 Butanol /ethanol Butanol /xylene Isobutanol Isobutanol Solvent Butanol Butanol K value 35 35 35 35 30 Temperature reactivity Medium High Low Low Low Low temperature [°C] Vicat softening Vicat 48–52 48–52 48–52 48–52 46–48 reactivity Medium Medium Medium Medium Acid High Low additional plastification usingplasticizersorsoftresins.additional plastification Canbeblendedwithalkydsor acrylics mineral substrates, printinginksandroadmarking paints, aswellfor resistanttohydrolysis. Requires onironandsteel, coatings themanufactureofphysicaldrying binderfor Chlorinated non-ferrousmetals, or acrylics to hydrolysis. usingplasticizersorsoftresins. Requiresadditionalplastification Canbeblendedwithalkyds mineral substrates, printinginks(PVC aswellfor onironandsteel, coatings themanufactureofphysicaldrying binderfor Chlorinated non-ferrousmetals, usingplasticizersorsoftresins.additional plastification Canbeblendedwithalkydsor acrylics mineral substrates, printinginksandroadmarking paints, aswellfor resistanttohydrolysis. Requires onironandsteel, coatings themanufactureofphysicaldrying binderfor Chlorinated non-ferrousmetals, usingplasticizersorsoftresins.additional plastification Canbeblendedwithalkydsoracrylics mineral substrates, printinginksandroadmarkingpaints, aswellfor resistanttohydrolysis. Requires onironandsteel, coatings themanufactureofphysicaldrying binderfor Chlorinated non-ferrousmetals, usingplasticizersorsoftresins.additional plastification Canbeblendedwithalkydsoracrylics mineral substrates, printinginksandroadmarkingpaints, aswellfor resistanttohydrolysis. Requires onironandsteel, coatings themanufactureofphysicaldrying binderfor Chlorinated non-ferrousmetals, formalde- hyde [%] < 0.8 < 0.5 < 0.3 < 1.0 < 0.6 < 0.4 Free Universal resin with low baking reactivity; for generalwoodandindustrialapplications Universal resinwithlowbakingreactivity;for floor coatings, assolebinder suitable mediumtohighacidreactivity. solvent-based coatings; resinfor Carbamate Forwoodand coatings; low formaldehyde content lowformaldehyde coatings; furniture,Medium acidreactivity;lowsolventcontent;highgloss;for floor, andindustrial applications for general woodandindustrial i-Butanol-etherified resinwithlowbakingreactivity; Very high baking reactivity for industrialprimers Very highbakingreactivityfor i-Butanol-etherified resin; high acid reactivity; for furniture,i-Butanol-etherified resin;highacidreactivity; floor, andindustrialcoatings Key properties andapplications / acrylic gravure inks)androadmarkingpaints, gravure acrylic resistant Key properties Wood Wood 2 2 2 2 2 ------Metal Metal 2 2 2 2 2 2 2 2 2 2 1 1 Suited Solvent-based systems

Substrate Plastic Plastic 1 1 1 1 1 ------2 Highlyrecommended Glass Glass 1 1 1 1 1 1 - - - - - 2019 Concrete Concrete 2 2 2 2 1 ------51

Solvent-based systems 52 Product Basonat Allophanates (NEW: availableat<0.1%residual diisocyanate) Basonat Biurets Basonat Isocyanurates (NEW: availableat<0.1%residual diisocyanate) Larotact Blocked polyisocyanate-typeco-cross-linker Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat Basonat and Larotact Basonat ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® Solvent-based systems 2019 HA1000 HA3000 HA2000 HB175MP/X HB100 HB275B HI145BNG HI100NG HB475B/X HI290BNG HI268B/SNG HI190B/SNG HI180B/SNG HI172SNG HI152BNG HI2000NG 150 Triazine (melamine-based derivative ® HDI isocyanurate low-viscous HDI isocyanurate polyisocyanates blocked isocyanate) Type ofproduct HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI isocyanurate HDI allophanate HDI allophanate HDI allophanate HDI biuret HDI biuret HDI biuret HDI biuret ® co-cross-linker Solids byweight[%] 48–52 [105°C] 100 100 100 100 100 100 75 75 45 75 90 68 90 80 72 52 23 °C [mPa·s] Viscosity at Viscosity 2,500–4,000 2,500–4,000 900–1,500 900–1,500 500–900 130–300 100–180 100–250 400–600 450–600 130–250 200–400 70–120 10–50 39–55 6–20 < 10 22.5–23.5 21.0–23.0 19.0–20.0 18.5–21.5 16.0–17.0 22.0–23.0 16.0–17.0 21.5–22.5 16.0–17.0 15.3–16.6 19.3–20.3 14.5–15.5 19.3–20.3 16.9–18.3 NCO [%] 9.7–10.1 11–12 - Solvent-free (allowing for Solvent-free (allowingfor Methoxypropyl acetate / acetate Methoxypropyl broad rangesolvents) Solvesso Solvesso Solvesso n-Butyl acetate / n-Butyl acetate n-Butyl acetate / n-Butyl acetate / n-Butyl acetate / n-Butyl acetate n-Butyl acetate n-Butyl acetate n-Butyl acetate n-Butyl acetate Solvesso Xylene 1:1 Xylene 1:1 n-Butanol Solvent ® ® ® - - - - - 1001:1 1001:1 1001:1 ® 100 or alone. areautomotive,application Preferredfieldsof industrial, finishes andcoil-coating cross-linking. Itdoesnotcross-linkwithitself, flexibility makingitanoptimumcross-linker yieldinganadvantageous Low-viscous andlow-molecular-mass cross-linker. blockedisocyanate 120°C. above temperatures Deblocking andcross-linkingstartat releaseduring Noformaldehyde Basonat Basonat woodcoatings high-performance extendfromautomotivetopcoats, applications general usein2KPUcoatings; for knownaspolyisocyanates plasticsubstrates,Biuret grades for especially and togeneralindustry Basonat Basonat Basonat Low-viscous trimer for high-solid 2K PU coatings without limitation inchemicalresistanceandreactivity. withoutlimitation high-solid2KPUcoatings Low-viscous trimerfor Itcanalsobecombinedwithwater-emulsifiable Basonat secondary dispersions for water-based dispersionsfor secondary NG: 2KPUwoodcoatings; reducedcolordriftinformulations resins, e.g. Joncryl e.g. Joncryl e.g. Joncryl resins, e.g. Joncryl resins, e.g. Joncryl e.g. Joncryl and refinish;NG:formulations reducedcolordriftin lowinitialcolor, trimersknownfor Isocyanurate resistance, highweather high cross-linkdensity, 2KPUcoatings, high-performance andperfectfor e.g. 2KPUautomotiveOEM for water-based 2KPUwoodcoatings water-based 2KPUwoodcoatings and refinish;NG:formulations reduced color driftin lowinitialcolor, trimersknownfor Isocyanurate resistance, highweather highcross-linkdensity, 2KPUcoatings, high-performance andperfectfor e.g. 2KPUautomotiveOEM for Basonat Basonat water-based 2KPUwoodcoatings Low-viscous polyisocyanates for high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat Low-viscous polyisocyanates for high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat high-solidsolvent-based2KPUcoatings. for Low-viscous polyisocyanates Itcanalsobecombinedwithwater-emulsifiable Basonat Basonat Basonat ® ® ® ® ® ® ® ® ® HB polyisocyanates for general use 2K PU coatings suchasgeneralindustry, generaluse2KPUcoatings for HBpolyisocyanates woodcoatings, high-performance automotivetopcoats, plasticsubstrates especially HB polyisocyanates for general use 2K PU coatings suchasgeneralindustry, generaluse2KPUcoatings for HBpolyisocyanates woodcoatings, high-performance automotivetopcoats, plasticsubstrates especially suchasgeneralindustry, generaluse2KPUcoatings for HBpolyisocyanates woodcoatings, high-performance automotivetopcoats, plasticsubstrates especially HI aliphatic polyisocyanates for highly cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant 2KPUcoating. withmosthydroxy-acrylic and cross-linkable arecompatible They HI aliphatic polyisocyanates for highly cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant resins, withmosthydroxy-acrylic andcross-linkable compatible 2KPUcoatings; cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant resins, withmosthydroxy-acrylic andcross-linkable compatible 2KPUcoatings; cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant 2KPUcoating. withmosthydroxy-acrylic and cross-linkable arecompatible They cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant 2KPUcoating. withmosthydroxy-acrylic andcross-linkable arecompatible They HI aliphatic polyisocyanates for highly cross-linked, highly for polyisocyanates HIaliphatic lightfast, andweather-resistant resins, withmosthydroxy-acrylic andcross-linkable compatible 2KPUcoatings; ® ® ® grades and polyester resins containing hydroxyl groups; NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations ® ® ® grades and polyester resins containing hydroxyl groups; NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations grades and polyester resins containing hydroxyl groups; NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations grades and polyester resins containing hydroxyl groups; NG: resinscontaininghydroxylgroups; andpolyester grades reducedcolordriftinformulations Key properties andapplications / hardness relation. withaminoresins Bestuseincombination ® ® ® HW types and secondary dispersions for dispersionsfor HWtypesandsecondary dispersionsfor HWtypesandsecondary HW types and secondary dispersions for dispersionsfor HWtypesandsecondary Solvent-based systems ® HWtypesand 2019 53

Solvent-based systems 54 Laromin Amine Product Ludopal Unsaturated polyesters Product Laropal Grinding resins Product Ludopal Laropal Laropal unsaturated polyesters,Laromin Laropal ® ® ® ® ® ® Solvent-based systems 2019 A-8L 101 A 81 A U150 P6 C260 Condensation productofureawith Condensation productofureawith Condensation productofureawith Condensation ® aliphatic aldehydes aliphatic aldehydes aliphatic aldehydes aliphatic Solution instyrene Solution instyrene Physical form Physical form grindingresins,Ludopal Type ofresin Liquid Solids byweight Solids byweight Physical form 64–67 64–67 Liquid Solid Solid [%] [%] 99 Solids byweight Viscosity at23°C Viscosity at23°C Viscosity 78–83 100 100 [%] 900–1,100 900–1,200 [mPa·s] [mPa·s] 6–10 Viscosity at25°C Viscosity 7,000–15,000 [mPa·s] solids [mgKOH/g] Water content[%] Acid numberon - - ® 27–31 29–33 < 0.2 ® amine

Flash point 49.5 [°C] - - equivalent weight Refractive index 1.524–1.527 1.531–1.534 Hydrogen at 20°C (HEW) 27 Tg [°C] – 8 73 57 coatings, constructiontrade, ormarinecoatings. ofLaromin Combinations concrete topping, self-leveling concrete, repairmortars, filledwearingsurfaces aswellhighly industrialandanticorrosioncoatings.and solventsareusedashardenersfor curing Itcanalsobeusedfor Laromin and metal, dissolvedinstyrene. gelcoats for Suitable wood andsurfacersfor coatings andpolishable ofsandable theformulation resinfor polyester Unsaturated and metal, dissolvedinstyrene. gelcoats for Suitable wood andsurfacersfor coatings andpolishable ofsandable theformulation resinfor polyester Unsaturated solids [mgKOH/g] OH numberon ® C 260 is mainly used to harden low viscosity liquid epoxy resins for low-solventorsolvent-free usedtohardenlowviscosityliquidepoxyresinsfor C260ismainly 90 35 40 Iodine color number Key properties andapplications Key properties andapplications ≤ 50 ≤ 5 ≤ 3 Resistance toyellowing. resin Usedasgrinding resins. andsolubilitywithcommoncoating Excellent compatibility Goodpigmentwetting. Improvesgloss, andadhesion. adhesion. Resistancetoyellowing. resinorco-binder Usedasgrinding resins. andsolubilitywithcommoncoating Excellent compatibility Goodpigmentwetting. Improveshardness, gloss, and and adhesion. Resistancetoyellowing. resinorco-binder Used asgrinding resins. withcommoncoating Excellent compatibility Excellentsolubility. Goodpigmentwetting. Improveshardness, gloss, ® C260withsolidepoxyresins Key properties andapplications Wood Wood 2 2 - Metal Metal 2 1 1 1 Suited Solvent-based systems Substrate Substrate

Plastic Plastic 1 1 1 2 Highlyrecommended Glass Glass - - - 2019 Concrete Concrete 2 - - 55

Solvent-based systems 56 Lutonal Acronal Lutonal Lutonal Lutonal Acronal 45% ino-xylene 50% inlightnaphta 35% inwhitespirit 50% inethanol Joncryl Acronal 65%ig ino-xylene 50% inethylacetate 40% inethylacetate Acronal 50% inethylacetate Acronal Acrylic resins Product Plastigen Glycoluril Product Lutonal ethers Vinyl Product Acronal Soft resins ® ® ® ® ® ® ® ® ® ® ® ® 611 Solvent-based systems 2019 M40, I60app. I60 A 50app. 25 A LR8820 9020 700Lapprox. 500LC 4Lapprox. 4F ® GULF Poly(vinyl isobutylether) Poly(vinyl isobutylether) Poly(vinyl Poly(vinyl methylether) Poly(vinyl Poly(vinyl ethylether) Poly(vinyl ethylether) Poly(vinyl Type ofproduct Type ofresin Glycoluril resin Glycoluril Solution inethylacetate Solution inethylacetate Solution inethylacetate Solution ino-xylene Physical form Liquid Liquid Solid Physical form Non-volatile at2h, Solution Solution Solution Solution Liquid 125 °C[%] 93–96 weight [%] Solids by 99.0 98.5 99.0 65.0 51.0 40.0 50.0 weight [%] Solids by > 90 70 50 35 50 Viscosity at23°C Viscosity 20,000–50,000 (251/s) 9,000–14,000 (251/s) (50% inethylacetate) Viscosity at23°C Viscosity 150 (40%intoluene) 900–1,400 [mPa·s] 1,000–2,500 1,600–2,600 130–200 500–800 [mPa·s] Viscosity at23°C Viscosity 1.0–6.0 (Brookfield 0.3–4.5 (1001/s) 2.5–6.0 (1001/s) RV, Sp. 5, 201/s) 50–250 (251/s) 5–20 (251/s) [Pa·s] Solution inn-butanol Solvent Flash point Flash point [°C] 150 109 –4 –6 –4 34 > 55 [°C] –21 26 11 9 Flash point Tg [°C] Tg [°C] [°C] –40 –45 –40 77 –27 –27 –49 –30 –43 - - - - Iodine color Iodine color Iodine color < 400Hazen number number number 0–15 0–15 0–8 0–8 0–4 0–1 0–1 0–2 - - - - Plasticizing softresin. Italsoactsasanadhesionpromoter. 50%solutioninlightnaphta Plasticizing softresin. Italsoactsasanadhesionpromoter. 35%solutioninwhitespirit 50% solutioninethanol Plasticizing softresin, i.e. coatings. cellulosenitrate for Italsoactsasanadhesionpromoter. Used as co-binder for anti-fouling coatings. anti-fouling Used asco-binderfor 70%solutioninethanol Plasticizing softresin, i.e. coatings. cellulosenitrate for Italsoactsasanadhesionpromoter. Plasticizing softresin, i.e. coatings. cellulosenitrate for Italsoactsasanadhesionpromoter Carbamide softresin, solvent-basedcoatings asadhesionpromoterandplasticizingresinfor binders for coatings withgood flexibilityandexcellentadhesion coatings binders for resin,Soft acrylic resistanttolightandaging, andchlorine-containing plasticizingcellulosenitrate for adhesion. Productissolubleinalcohols, aldehydes, ketones, hydrocarbons andaromatic otherresinsystems, withmany Compatible usedasmodifyingresintoconferflexibilityandimproves for coilcoatings for withgoodflexibilityandexcellentadhesion. coatings binders for application: Main ofPVDF plastification resin,Soft acrylic resistanttolightandaging, andchlorine-containing plasticizingcellulosenitrate for binders for coatings withgoodflexibilityandexcellentadhesion coatings binders for resin,Soft acrylic resistanttolightandaging, andchlorine-containing plasticizingcellulosenitrate for flexibility andexcellentadhesion to lightandaging, withgood coatings andchlorine-containingbindersfor plasticizingcellulosenitrate for resin, isobutyletherandn-butylacrylate, ofvinyl Copolymer softacrylic dissolvedinethylacetate; resistant cellulose nitrate and chlorine-containing binders for coatings withgoodflexibilityandexcellentadhesion coatings andchlorine-containingbindersfor cellulose nitrate resin, ofbutylacrylate,Polymer softacrylic dissolvedinacetate; resistanttolightandaging, plasticizing for binders for coatings withgood flexibilityandexcellentadhesion coatings binders for resin,Soft acrylic resistanttolightandaging, andchlorine-containing plasticizingcellulosenitrate for Key properties andapplications Key properties andapplications Key properties Wood Wood Wood 1 1 1 1 1 1 1 1 1 1 1 1 - Metal Metal Metal 2 1 1 1 1 1 1 1 1 1 1 1 1 1 Suited Solvent-based systems Substrate Substrate Substrate

Plastic Plastic Plastic 1 1 1 1 1 1 1 1 1 1 1 1 - 2 Highlyrecommended Glass Glass Glass 1 1 1 1 1 1 ------2019 Concrete Concrete Concrete 1 1 1 1 1 1 ------57

Solvent-based systems Bitte Kurzversion des KapiteltitelsRenewable eintragen systems 2019 20195959

Renewable systems

The coatings market is at a turning point: Efficient production is meant to go hand in hand with ever better performance. At the same time, applied coatings must meet the increasing demand for health-friendly and resource-saving solutions. The paints and coatings industry can profit from these trends by delivering products that offer high- performance while consuming fewer resources and causing less emissions. Adding value with more sustainable solutions will most likely become a key growth driver. Renewable systems

We at BASF can help you meet these future demands. Discover our advanced renewable solutions to set your products apart from the competition! Renewable systems Renewable systems 60 2019 2019 61

Saving fossil resources and reducing

CO2 emissions

BASF’s biomass balance approach

Consumers are increasingly aware of sustainability, a trend that is reflected in purchase decisions. Market research shows that significant numbers of consumers favor products manufactured by companies that actively conserve resources, save costs, and safeguard human well-being and the environment. This demand can be expected to keep growing long into the future. Renewable systems The coatings industry can benefit from the trend by Surprise your customers with added delivering products that offer outstanding performance ecological benefit! while consuming fewer resources and causing less emissions. §§ Drives the use of sustainable renewable feedstock

With the biomass balance approach, BASF offers you §§ Saves fossil resources and reduces greenhouse gas more sustainable resins and additives while maintaining emissions the same product performance as ever. §§ Independently certified by third party §§ Same product quality and properties In this approach, the fossil resources are replaced by sustainable biomass such as bio-naphtha or biogas already at the beginning of the production process. If you are interested in our sustainable solutions, please In a calculatory process certified by a third party, the contact us – our experts will be glad to advise you. applied share of renewable resources is then virtually allocated to the new product line. According to this calculation, up to 100 % of the fossil resources Read more about biomass balance at can be replaced by renewable raw materials. basf.com/biomassbalance

Almost all our resins can be manufactured according to the biomass balance approach. Renewable systems Renewable systems 62 2019 2019 63

Your best choice for natural oil polyols

Sovermol® – a chemical hybrid Polyether

Hydrolysis stability Natural oil polyols are polyfunctional alcohols based on renewable raw materials like

rapeseed oil, castor oil, soybean oil, and palm kernel oil. The practical advantages of Sovermol® polyether / polyester these products include good adhesion, excellent workability, and good weathering Hydrophobic properties properties. They can also be used on a wide variety of different substrates. Hydrolysis stability

®

Polyols based on natural oils have a very pronounced The modular system of our Sovermol product group Renewable systems hydrophobic character. For this reason, oleochemical includes other important features, such as being 100% Hydrophobic properties polyols create significantly less carbon dioxide by virtue solid, good gloss development, and good pigment-​ of the side reaction of the isocyanate. In high humidity wetting characteristics. The latest generation of BASF Hydrolysis stability and high temperature conditions, these special polyols Sovermol® products combines sustainability with are able to create networks without bubbles or foam performance, thus meeting the requirements of today’s formation. Besides good hydrophobicity, polyols producers and consumers. Hardness can be regulated based on oleochemicals exhibit excellent hydrolysis without using plasticizers and the group features Hydrophobic properties resistance, chemical resistance, and UV resistance, excellent UV stability and long-term weathering as well as low viscosity. This latter characteristic is performance. Some markets where Sovermol® is being especially important in spraying applications. used include concrete flooring, wind blades, pipeline Polyester coatings, protective coatings, and adhesives. Renewable systems Renewable systems 64 2019 2019 65

Sovermol® natural oil-based polyols (1/2)

1 Suited 2 Highly recommended

Medium OH Medium Substrate Renewable raw Medium OH Product Type of product Functionality equivalent viscosity Key properties and applications material content value [weight] [mPa·s] Wood Metal Plastic Glass Concrete Natural oil-based polyols

Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve- Sovermol® 45 Branched polyether - 4.0 98 570 3,000 ment of glass transition temperature Tg; high cross-linking density; hydrophilic; improvement of chemical 1 1 1 1 2 resistance

Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve- ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical Sovermol® 100 Branched polyether - 3.0 64 880 6,000 1 2 1 1 2 resistance; drinking and potable water application possible upon product-specific confirmation according to local legislation

Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve- ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical Sovermol® 100 N NEW Branched polyether - 3.0 65 860 5,900 1 2 1 1 2 resistance; drinking and potable water application possible upon product-specific confirmation according to local legislation (N: different production site)

Branched polyether / Drinking and potable water application possible upon product-specific confirmation according to local Renewable systems Sovermol® 320 80–100% 2.8 180 310 1,000 1 2 1 1 2 polyester legislation; high shore D hardness (D ~ 80); good mechanical properties

Branched polyether / Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 80); Sovermol® 750 65–80% 3.0 178 315 1,100 [20 °C] 1 2 1 1 2 polyester hydrophobic; high saponification stability; excellent chemical resistance; hydrolysis stable; high-Tg polyol

Branched polyether / High shore D hardness (D ~ 90); hydrophobic; high saponification stability; excellent chemical resistance; Sovermol® 760 65–80% 3.5 145 390 2,300 1 1 1 1 2 polyester hydrolysis stable; extremely high-Tg polyol; high heat resistance

Branched polyether / Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 90); Sovermol® 780 50–65% 3.0 110 510 2,300 [20 °C] 1 2 1 2 2 polyester hydrophobic; excellent chemical resistance; hydrolysis stable; high-Tg polyol

Branched polyether / Sovermol® 805 65–80% 3.5 330 170 3,500 Universal polyol; excellent impact resistance; shore D hardness (D ~ 70) 2 2 2 1 2 polyester

Branched polyether / Sovermol® 810 65–80% 3.3 244 230 900 Polyol for encapsulation systems; hydrolysis stable; hydrophobic; low viscosity; high filler content possible 2 1 1 1 2 polyester

Branched polyether / Low-viscous universal polyol binder for pigment pastes and crack-bridging flooring; good chemical resis­ Sovermol® 815 80–100% 3.5 260 215 1,600 2 1 1 1 2 polyester tance, hydrophobic, good elastic, memory effect

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; excellent flexibility at Sovermol® 818 Fatty acid polyester 80–100% 2.6 238 236 750 2 2 2 1 2 temperatures below 0 °C; good bonding properties

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; good bonding Sovermol® 819 Fatty acid polyester 80–100% 2.6 234 240 850 2 2 2 1 2 properties Renewable systems Renewable systems 66 2019 2019 67

Sovermol® natural oil-based polyols (2/2)

1 Suited 2 Highly recommended

Medium OH Medium Substrate Renewable raw Medium OH Product Type of product Functionality equivalent viscosity Key properties and applications material content value [weight] [mPa·s] Wood Metal Plastic Glass Concrete Natural oil-based polyols

Low-viscous universal workhorse polyol; extremely hydrophobic; good self-leveling properties; good Branched oleochemical Sovermol® 830 80–100% 2.6 233 241 875 bonding properties; drinking and potable water application possible upon product-specific confirmation 2 2 2 2 2 polyether / polyester according to local legislation

Gel time prolonger; reactive diluent; hydrophobic; good adhesive properties on metal surfaces; contains Sovermol® 860 Aliphatic polyol 80–100% 2.5 270 210 530 [20 °C] 2 2 1 1 2 epoxy groups (Ep-O = 0.3 to 1.4%)

Sovermol® 908 Aliphatic dimer alcohol 80–100% 2.0 272 206 2,300 Crack-bridging coatings; good saponification stability; hard elastic performance; hydrophobic 1 1 1 1 2

Slightly branched Hydrophobic; plasticizer for polyol; soft elastic performance; drinking and potable water application possible Sovermol® 1005 80–100% 2.2 460 122 800 [20 °C] 2 2 1 1 2 aliphatic diol upon product-specific confirmation according to local legislation

Soft elastic performance; drinking and potable water application possible upon product-specific Sovermol® 1014 Aliphatic triol 80–100% 2.5 350 160 700 2 2 1 1 2 confirmation according to local legislation Renewable systems Fatty acid polyester Ep content Non-reactive diluent; VOC-free acc. to 2004/42/EU; UV-stable performance; plasticizer for polyols and Sovermol® 1055 80–100% - EEW = 333 15 [20 °C] 1 1 1 1 2 with epoxy groups 4.6–5.0% epoxy resins

Sovermol® 1058 Fatty acid polyester 80–100% - - - 5 [20 °C] Non-reactive diluent; VOC-free acc. to 2004/42/EU; hydrophobic; plasticizer for polyols 1 1 1 1 2

Branched polyether / High-performance polyol for coatings, putties, and adhesives, low viscosity; extremely hydrophobic; Sovermol® 1092 65–80% 2.8 198 283 800 2 2 1 1 2 polyester hardness similar to epoxy systems; hard elastic performance; good self-leveling properties

Branched polyether / Sovermol® 1093 65–80% 2.8 245 229 2,500 Polyol; high hardness; hydrophobic performance; hard elastic; water repellency 2 2 2 1 2 polyester

Slightly branched Sovermol® 1102 80–100% 2.1 245 230 400 [20 °C] Universal copolyol; gel time prolonger; reactive diluent hydrophobic; UV-stable; soft elastic performance 1 2 1 1 2 polyether / polyester

Sovermol® 1140 Fatty acid polyester 80–100% 2.7 267 210 1,000 Universal polyol for adhesives; gel time prolonger; hard flexible performance; hydrophobic 1 1 1 1 2 Renewable systems Renewable systems 68 2019 2019 69

Properties of Sovermol® natural oil-based polyols After stoichiometric cross-linking with MDI polymer (NCO = 31%, functionality = 2.4)

Gel time ASTM D Shore hardness A / D (EN ISO 868) ISO 527-3 Type 5 ISO 527-3 Type 5 ISO 34-1 DIN EN ISO 604 DIN EN ISO 178 DIN 53453 DIN 53754 Product 2471-88 (30 g mass) Tensile strength Tear resistance Compression Bending strength Impact resistance Abrasion 1st day 2nd day 14th day 28th day Elongation [%] [h:min] [MPa] [N/mm] strength [MPa] [MPa] [mJ/mm²] [mg/1,000 R] Sovermol® 100 / 0:20 100 / 77 100 / 77 100 / 80 100 / 80 n.m. n.m. n.m. n.m. 107 2 n.m. Sovermol® 100 N

Sovermol® 320 0:46 71 / 22 98 / 64 100 / 81 100 / 83 30 4 30 n.m. 36 12 n.m.

Sovermol® 750 0:38 100 / 74 100 / 80 100 / 86 100 / 87 45 3 9 36 53 6 34

Sovermol® 760 0:19 100 / 86 100 / 88 100 / 90 100 / 90 42 1 6 45 57 4 15

Sovermol® 780 0:22 100 / 89 100 / 90 100 / 91 100 / 91 58 0 4 45 85 6 61

Sovermol® 805 0:47 75 / 30 86 / 42 98 / 64 98 / 69 17 65 88 n.m. 8 121 68

Sovermol® 810 0:55 77 / 32 86 / 42 98 / 66 98 / 67 18 39 60 n.m. 10 34 79

Sovermol® 815 1:00 83 / 39 92 / 52 99 / 75 99 / 77 21 34 70 n.m. 22 24 28 Renewable systems

Sovermol® 818 1:24 60 / 18 78 / 31 94 / 50 96 / 60 18 58 64 n.m. 6 113 77

Sovermol® 819 0:59 69 / 24 85 / 39 96 / 62 97 / 64 18 66 70 n.m. 7 107 88

Sovermol® 830 0:55 70 / 25 85 / 39 96 / 63 100 / 65 19 65 73 13 6 126 42

Sovermol® 860 6:10 n.m. n.m. 85 / n.m. 97 / 62 13 17 48 n.m. 6 9 100

Sovermol® 908 0:12 66 / 24 78 / 34 84 / 40 84 / 42 14 122 38 n.m. 1 96 n.m.

Sovermol® 1005 1:47 n.m. 4 / n.m. 22 / n.m. 38 / 10 1 24 3 n.m. 0.3 n.m. n.m.

Sovermol® 1014 1:35 50 / 17 62 / 24 67 / 26 67 / 26 3 59 6 n.m. 1 3 7

Sovermol® 1092 1:09 90 / 45 97 / 65 100 / 84 100 / 86 39 3 21 31 43 34 61

Sovermol® 1093 0:59 96 / 60 n.m. 100 / 87 100 / 87 43 4 25 n.m. 54 34 n.m.

Sovermol® 1102 3:15 n.m. 39 / 10 89 / 45 94 / 56 13 52 47 n.m. 2 38 75

Sovermol® 1140 6:07 n.m. 50 / n.m. 98 / 61 99 / 69 10 1 14 9 16 10 n.m.

n.m. = not measured Bitte Kurzversion des KapiteltitelsRadiation-curable eintragen systems 2019 20197171

Radiation-curable systems

BASF is the first choice for high-performance radiation-curable resins. Our Laromer® range enables you to create coatings as well as printing formulations tailored to your needs. Your challenges are our challenges, and constantly spur us on to improve our product portfolio with innovative new solutions for your coating and printing formulations.

With our continuous high focus on research and development, investments in assets and people, and our close interaction with formulators and machine manufacturers, we are shaping the future of radiation-curable resins – for example with our water- based UV resins.

Oligomers Monomers

Our extensive portfolio of oligomers, our strong Reactive diluents are key ingredients in most UV and technical center, and our passionate team of experts EB formulations for matching the viscosity to a wide Radiation-curable systems are dedicated to fulfilling your requirements for variety of application conditions. Additionally, they state-of-the-art UV and EB formulations. We offer a influence performance properties like reactivity, broad portfolio of oligomers including UV 100% and hardness, and adhesion. BASF offers a broad portfolio UV waterborne resins. of high-quality monomers for the coating and printing industries. Radiation-curable systems Radiation-curable systems 72 2019 2019 73

Discover new possibilities

UV LED curing Corrosion protection 1 Good 2 Very good 3 Excellent

Anti- UV LED curing is continuing to make significant inroads Product Type Viscosity (23.0 °C) A high-performance UV coating needs to meet other Product Type Adhesion into traditional UV curing markets used to work with prerequisites besides adhesion to the metal, e.g. good corrosion mercury lamps as radiation source until now. UV LED Amine-modified anticorrosion properties. That’s why we offer UV resins Adhesion Laromer® PO 8996 0.05 – 0.09 Pa·s Laromer® PA 9083 3 1 radiation sources, apart from their considerably longer polyether acrylate that can be used in combination with acidic adhesion promoter service life than mercury lamps, do not emit infrared promoters and low-shrinkage, hydrophobic UV diluents.

® Amine-modified radiation evolving as heat. As a consequence, heat-​​ Laromer PO 9144 0.10 – 0.20 Pa·s Since the cross-linking of UV coatings is done at room ® polyether acrylate Laromer TBCH Diluent 3 2 sensitive substrates like plastic films in packaging or temperature, UV technology is also very economical. wood in furniture applications can be processed without Amine-modified Laromer® PO 94 F 0.45 – 0.75 Pa·s any dif­fi­culties caused by heating in contrast to mercury polyether acrylate Laromer® LR 8887 Diluent 3 3 lamps.

® Amine-modified Laromer PO 9137 0.50 – 0.90 Pa·s Anticorrosion polyether acrylate Laromer® UP 9151 2 3 However, due to the quasi-monochromatic emission resin of commercial UV LED radiation sources in the wave­ Amine-modified Laromer® PO 9067 0.50 – 0.90 Pa·s length range of 360–410 nm, the number of suitable polyether acrylate photoinitiators, absorbing this red-shifted UV radiation Amine-modified is rather limited; particularly photoinitiators with proper Laromer® PO 9139 2.0 – 6.0 Pa·s surface cure are missing. This lack of surface cure for polyether acrylate UV LED formulations triggered by oxygen inhibition requires the use of highly reactive monomer and Laromer® PE 8981 Polyester acrylate 4.0 – 14.0 Pa·s oligomer acrylates to compensate these surface cure deficiencies. A dedicated range of monomer and Modified epoxy Laromer® LR 9019 12.0 – 20.0 Pa·s oligomer acrylates with a very fast UV cure response is acrylate available, covering beyond printing and packaging markets also furniture and flooring as well as automo- tive and industrial applications. Radiation-curable systems Radiation-curable systems Radiation-curable systems 74 2019 2019 75

Enabling durable coatings

Abrasion resistance (Taber®1 Abraser) Scratch resistance Weather resistance Adhesion

Abrasion resistance is of utmost importance in the Many different applications require a highly scratch-re- The weather resistance properties of UV and EB Recently, there has been a strong interest in using UV world of high-quality flooring products. Product sistant coating to assure a long service life. Examples coatings open up a wide range of outdoor ​ and EB curable technology to coat metal and plastic selection can sometimes be test-method-dependent include high-performance automotive clear coats and applications. The key to formulating such weather-re- substrates. These non-absorbing substrates require and a close and specific match is often needed. plastics coatings as well as furniture and flooring sistant coatings is the use of aliphatic urethane careful selection of radiation-curable raw materials to For each test method, we offer the optimal solution. coatings. Highly scratch-resistant surfaces can be acrylates in combination with a suitable photoinitiator. ensure that the coatings formulation achieves the achieved via two alternative routes: through resins with To achieve the best possible weather resistance, we necessary adhesion performance. This can be either high functionality or nano-modification. offer the Tinuvin® product range (UV absorbers and achieved by employing dual cure resins, film shrinkage HALS). control, substrate wetting optimization, or an acidic adhesion promoter.

1 Good 2 Very good 3 Excellent

S 33 / Falling CS 10 / Scratch Hard- / scratch- Product Product Key features Product Flexible Product Metal Plastics Wood S 42 sand CS 17 resistance resistant

Laromer® PE 56 F - 1 3 Laromer® UA 8987 N 2 High functionality Laromer® UA 8987 N 2 - Laromer® UA 9059 - - 3

Laromer® PE 9032 - 2 2 Laromer® UA 9048 3 High functionality Laromer® UA 9048 3 - Laromer® PA 9083 3 2 -

Laromer® UA 9065 - 2 - Laromer® UA 9136 3 High functionality Laromer® UA 9050 3 - Laromer® PR 9000 1 3 2

Laromer® UA 9033 N - 3 - Laromer® UA 9050 3 High functionality Laromer® UA 19 T - 2 Laromer® UA 9033 N 2 2 2

Laromer® PR 9052 3 - - Laromer® UA 9047 3 High functionality Laromer® UA 9033 N - 3 Laromer® UA 9072 2 2 2 Radiation-curable systems

Laromer® TMPTA 3 1 3 Laromer® TMPTA 2 High functionality Laromer® UA 9089 - 3 Laromer® PR 9013 1 1 2

Laromer® DPGDA 1 3 3 Laromer® UA 9136 3 - Laromer® TBCH 3 3 -

Laromer® LR 8887 - 3 1 Laromer® UA 9134 Aqua 2 - Laromer® LR 8887 2 2 2

Laromer® PE 9123 - 3 - Laromer® UA 9147 Aqua 2 - Laromer® POEA 2 2 2

Laromer® PE 9121 - 2 - Laromer® UA 8949 Aqua - 3

1 ® = Registered trademark of Taber Acquisitions Corporation Radiation-curable systems Radiation-curable systems 2019 2019 76 PO 9139 77 130

PO 9137 120 UV resins

110 Viscosity – reactivity

100 100

UA 9112 Aqua PO 77 F UA 9050 90 90

UA 9005 Aqua 80 80 UA 9149 Aqua PO 94 F LR 9019 PE 9079

PE 55 Aqua 70 70

UA 9065

UA 9134 Aqua PO 8997 EA 9124 EA 9143 UA 9135 Aqua 60 60 UA 9147 Aqua PO 9067 LR 9023

EA 8765 R PE 56 F 50 50 PE 55 F UA 9154 Aqua PO 84 F EA 9138 PE 9084

PO 8996 UA 8983 Aqua PE 22 Aqua PE 8981 PE 9032

40 40 Radiation-curable systems UA 9095 Aqua PR 9058 UA 9136 PO 9007 EA 9082 EA 9145 PE 9074 LR 8986 UA 8949 Aqua UA 9059 Aqua PE 9004 30 30 PO 9144 UA 9033 N PE 9123 UA 9048 UA 9073 PE 9045 PE 9121 PR 9052 EA 9097 PO 83 F 20 PO 9034 UA 9047 20 UA 8987 N UP 9118 PE 46 T PE 9142 PR 9119 PO 8967 PE 9128 PE 8800 UP 35 D 10 10 UP 9151 PO 43 F UP 9096 UP 9115 EA 9101 PR 8985 UA 19 T PE 8907 PE 9126 UA 9072 LR 8863 PO 33 F GPTA PR 9013 PO 9102 UA 9089 UA 9030 Reactivity [m/min] 0 0 PPTTA 10 55 100 550 1,000 5,500 10,000 50,500 100,000 550,000 1,000,000 Viscosity at 23 °C [mPa·s]

1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone / 1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone Film thickness: 25 µm Radiation-curable systems Radiation-curable systems 78 2019 2019 79

UV resins

Hardness – flexibility

10 10 UA 9072

UA 9030

9 9 UA 9059 Aqua UA 9073 UA 9033 N

UA 9089 UA 8983 Aqua

8 8 UA 9065 UA 8949 Aqua UA 19 T UA 9154 Aqua

7 PE 55 Aqua 7 PE 9126

PE 8907 PE 9142

PE 9074 6 PE 9045 6 PE 8981 PE 56 F PE 9004 PE 55 F UA 9149 Aqua UA 9095 Aqua PE 9084 PE 46 T PE 9128 PO 9102 UP 9115 PE 22 Aqua 5 PO 77 F PE 9079 PE 9032 5 PE 9123 EA 9101 EA 9097 PE 9121 UP 35 D UA 8987 N PO 9067 EA 8765 R LR 9023 UA 9005 Aqua PO 84 F

4 4 Radiation-curable systems LR 9019 PO 9034 PO 94 F PE 8800 PO 9137 PO 8997 PO 83 F PO 9007 PR 9058 EA 9145 PO 8996 LR 8986 UA 9147 Aqua PO 9139 PO 9144 UP 9096 PO 43 F 3 EA 9138 3 UP 9151 EA 9143 EA 9082 EA 9124

UA 9047 PO 8967 UA 9134 Aqua GPTA 2 2 UA 9135 Aqua UP 9118 UA 9112 Aqua

PO 33 F LR 8863 PR 9013 PPTTA 1 PR 8985 1

UA 9048 UA 9050 PR 9119 UA 9136 PR 9052

Erichsen cupping [mm] 0 0 20 40 60 80 100 120 140 160 Pendulum hardness [oscil.]

1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone / 1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone Film thickness: 25 µm Radiation-curable systems Radiation-curable systems 80 2019 2019 81

Functional monomers in formulation

Viscosity – reactivity Hardness – flexibility

PPTTA PPTTA

LR 8863 (TMPEOTA) LR 8863 (TMPEOTA)

GPTA GPTA

TMPTA TMPTA

HDDA HDDA

TPGDA TPGDA

DPGDA DPGDA

PO 9102 PO 9102

POEA POEA Radiation-curable systems

LR 8887 LR 8887

TBCH TBCH

8,000 6,000 4,000 2,000 0 5 10 15 20 25 60 40 20 0 2 4 6 8 Viscosity at 23 °C [mPa·s] Reactivity [m/min] Pendulum hardness [oscil.] Erichsen indentation [mm]

Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1) Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1) Film thickness: 25 µm Film thickness: 25 µm 82 Laromer Laromer Laromer Laromer Laromer Laromer Epoxy acrylates Product Laromer Laromer Laromer Laromer Laromer Laromer ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 EA8765R LR9023 LR9019 LR8986 EA9145 EA9143 EA9138 EA9124 EA9101 EA9097 EA9082 Soybean oil Aromatic Aromatic Aromatic Aromatic Aromatic Aromatic Aromatic Aromatic Aromatic Type of Aliphatic acrylate resin ® epoxyacrylates Type ofthinner DPGDA [15%] DPGDA [30%] TPGDA [25%] TPGDA [40%] TPGDA [30%] HDDA [20%] GPTA [25%] [content] - - - - 23 °C[Pa·s] Viscosity at Viscosity 12.0–20.0 35.0–55.0 10.0–20.0 13.0–20.0 7.0–15.0 3.0–6.0 0.6–1.2 2.0–5.0 4.0–6.5 1.5–3.0 6.0–9.8 Functionality calculated 2.4 2.4 2.3 2.0 2.0 2.3 2.0 2.0 3.8 2.1 2.0 Hydroxy value [mg KOH/g] 175 170 175 176 330 150 159 181 157 158 3.5 Hardness 4 4 4 4 4 4 4 3 3 1 1 Elasticity 3 3 3 3 2 2 2 2 2 2 1 Reactivity 4 3 3 2 2 2 2 2 2 2 1 resistance Chemical 4 4 4 4 4 4 4 4 4 1 1 version ofLaromer reactive,Highly goodchemicalresistance;diluted curing reactive,Highly goodchemicalresistance, UVLED resistance, highhardness Low viscosityepoxyacrylate, goodchemical Standard epoxyacrylate, lowviscosity Standard epoxyacrylate, highviscosity Standard epoxyacrylate, mediumviscosity withgoodadhesion Standard epoxyacrylate chemical resistance Low viscosity, balancedmechanicalprofile, good Standard epoxyacrylate, lowviscosity water-soluble,Partially flexible, reactive highly Flexibilizing co-resin, outstandingpigmentwetting 1 Low Key properties ® LR9019, UVLEDcuring 2 Medium 3 Good REACH Europe 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan ENCS 2 2 2 2 2 2 2 2 2 - - IECSC China 1 1 1 1 1 1 1 1 1 1 1 - Currently nonotification 3 2 1 Notified  Please contactyourlocalsalesrepresentative forfurther information  Canada For furtherregulatory information,[email protected] 3 3 DSL 1 1 1 1 1 1 1 1 1 Korea 3 3 3 3 3 3 ECL 1 1 1 - - Radiation-curable systems TSCA USA 1 1 1 1 1 1 1 1 1 1 1 Australia AICS 1 1 1 1 1 1 1 1 1 - - 2019 Philippines PICCS 3 3 3 1 1 1 1 1 1 - - 83

Radiation-curable systems 84 Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Polyester acrylates Product Laromer Laromer Laromer Laromer ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 PE9142 PE9128 PE9126 PE9123 PE9121 PE9084 PE9079 PE9074 PE9045 PE9032 PE9004 PE8981 PE8907 PE8800 PE56F PE55F PE46 T ® 2.0–4.0 [60°C] 23 °C [Pa·s] Viscosity at Viscosity 10.0–30.0 16.0–26.0 15.0–25.0 20.0–50.0 20.0–40.0 25.0–45.0 8.0–16.0 7.0–13.0 7.0–13.0 4.0–14.0 2.0–5.0 2.0–5.0 2.0–7.0 0.5–2.0 4.0–8.0 2.0–2.5 polyesteracrylates Functionality calculated 3.3 3.2 4.2 2.3 2.9 2.8 1.9 3.2 3.0 2.9 2.7 2.5 2.0 2.6 2.8 2.6 2.5 Hydroxy value [mg KOH/g] 120 60 68 44 50 80 80 84 50 70 60 50 60 80 70 70 60 Hardness 3 2 2 2 2 2 2 2 2 2 2 2 1 1 1 1 1 Elasticity 4 4 3 3 3 3 3 3 3 3 3 3 3 3 2 2 2 Reactivity 4 3 3 3 3 3 3 3 3 3 2 2 2 2 2 1 1 resistance Chemical 4 4 4 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Laromer (fallingsand),applications highviscosityversionof Tough, inparquet chemical-resistant;abrasion-resistant abrasion-resistant medical stains against goodchemicalresistance withvery onto flexiblesubstrate PVCflooring: for dedicated Specially combinessuperioradhesion Low yellowing, resistance(fallingsand) goodabrasion (fallingsand),applications lowyellowing Tough, inparquet chemical-resistant;abrasion-resistant plastic substrates ontowood, formulations topcoat Can beusedfor paper, and Free ofdiluents, lowviscosity, flexible (falling sand) Balanced properties, lowyellowing, resistance goodabrasion Laromer (fallingsand),applications mediumviscosityversionof Tough, inparquet chemical-resistant;abrasion-resistant version ofLaromer Tough withgoodadhesion, goodchemicalresistance;diluted (fallingsand) Abrasion-resistant inparquetapplications resistance abrasion Tough withgoodadhesion, goodchemicalresistance, high reactiveandflexible,Highly UVLEDcuring flexible,Highly withhard, useincombination lessflexiblebinders withreactivediluents(versusLaromer compatibility Well-balanced propertieswithhightoughness. Improved Well-balanced propertieswithhightoughness Hard andgoodchemicalresistance Laromer Well-balanced propertieswithhightoughness;dilutedversionof ® ® ® PE9074 PE9074 PE56F ® LR9004 1 Key properties Low 2 Medium ® PE55F), 3 Good REACH Europe 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan ENCS 2 2 2 2 2 2 2 2 ------IECSC China 1 1 1 1 1 1 1 1 1 1 1 1 1 1 - - - - Currently nonotification 3 2 1 Notified  Please contactyourlocalsalesrepresentative forfurtherinformation  Canada For furtherregulatory information, [email protected] 3 3 3 3 3 3 3 3 3 3 3 3 DSL 1 1 1 - - Korea 3 ECL 1 1 1 1 1 ------Radiation-curable systems TSCA USA 1 1 1 1 1 1 1 1 1 1 1 1 - - - - - Australia AICS 3 3 3 3 3 1 1 1 ------2019 Philippines PICCS 3 3 1 1 1 1 1 1 1 1 1 1 1 - - - - 85

Radiation-curable systems 86 Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Dual cure resin Product Laromer Polyether acrylates Product Laromer Amine-modified polyetheracrylates Product Laromer Laromer Laromer Laromer Laromer cure resins acrylates, polyetheranddual Laromer ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 PR9000 PO9034 PO9007 PO8967 PO43F PO33F PO9144 PO9139 PO9137 PO9067 PO8997 PO8996 PO94F PO84F PO83F PO77F Aliphatic urethane Aliphatic NEW NEW NEW Alkoxylated TMP Alkoxylated Type ofresin Type ofresin triacrylate acrylate - - - - ® Type ofthinner [content] amine-modifiedpolyether None None None None None None None None None None Type ofthinner 23 °C [Pa·s] [content] Viscosity at Viscosity None None None None None 1.0–1.4 23 °C [Pa·s] Viscosity at Viscosity 0.05–0.09 0.09–0.13 0.1–0.3 2.5–8.0 0.5–0.9 0.4–0.7 0.3–0.5 0.3–0.6 0.4–0.7 1.0–3.0 23 °C [Pa·s] Viscosity at Viscosity 0.12–0.19 0.07–0.13 0.35–0.6 0.8–1.5 0.2–0.4 Functionality 2.0 +NCO calculated Amine value [mg KOH/g] Functionality 88 88 25 25 34 36 39 35 36 calculated - Hydroxy value 2.6 3.0 2.3 2.2 2.7 [mg KOH/g] - Functionality calculated Hydroxy value [mg KOH/g] 3.3 2.4 2.6 2.6 2.6 2.6 2.6 2.6 2.5 2.6 130 100 58 50 30 Hardness 2 Hardness 3 Hardness 2 2 2 2 2 2 2 2 Elasticity 1 3 3 3 3 1 1 Reactivity Elasticity Elasticity 3 3 4 2 2 2 2 2 2 2 2 2 2 2 1 1 resistance Chemical Reactivity Reactivity 4 4 4 4 3 3 3 3 3 3 3 2 2 2 2 1 molecule, goodadhesion Contains 14–15wt%NCO-andUV-reactive withinone groups resistance resistance Chemical Chemical 4 4 3 3 3 3 3 3 3 3 3 3 3 3 2 Outstanding reactivity, UVLEDapplications Outstanding reactivity, UVLEDapplications Lowest amountofextractables, scratch-resistant curing reactive,Highly lowcolorandviscosity, UVLED curing reactive,Highly goodchemicalresistance, UVLED reactiveall-roundresin,Highly UVLED curing version ofLaromer Chemical resistance, all-round resin;low-viscosity Chemical resistance, all-roundresin Reactive, lowcolorandviscosity, UVLED curing curing Good chemicalresistance, lowviscosity, UVLED Partially water-soluble,Partially viscosity tospray adjustable Reactive, wetting, goodsubstrate UVLEDcuring leveling, UVLEDcuring Reactive, excellentpigmentwetting, excellent Low yellowing, lowodor, reactivediluent Low viscositywithgoodreactivity 1 Key properties Low Key properties Key properties ® PO43F 2 Medium 3 Good REACH REACH REACH Europe Europe Europe 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan ENCS Japan Japan ENCS ENCS 2 2 2 2 2 2 2 2 2 2 2 - - - - - IECSC IECSC IECSC China China China 3 3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 - Currently nonotification 3 2 1 Notified  Please contactyourlocal salesrepresentative forfurtherinformation  Canada Canada Canada For furtherregulatory information,pleasecontact [email protected] 3 3 3 3 3 3 3 3 DSL DSL DSL 1 1 1 1 1 1 1 1 Korea Korea Korea ECL ECL ECL 1 1 1 1 1 1 1 ------Radiation-curable systems TSCA TSCA TSCA 3 3 3 USA USA USA 1 1 1 1 1 1 1 1 1 1 1 - - Australia Australia Australia AICS AICS AICS 3 1 1 1 1 1 1 1 1 1 ------2019 Philippines Philippines Philippines PICCS PICCS PICCS 3 3 3 3 1 1 1 1 1 1 1 1 1 1 1 - 87

Radiation-curable systems 88 Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Urethane acrylates Product Laromer Laromer Laromer Laromer Laromer ® ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 UA9136 UA9089 UA9073 UA9072 UA9065 UA9050 UA9048 UA9047 UA9033N UA9030 UA8987N UA19 T NEW ® Aromatic Aromatic Type of Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic resin urethane acrylates Type ofthinner DPGDA [35%] DPGDA [25%] TPGDA [35%] Laromer Laromer HDDA [20%] HDDA [30%] TBCH [30%] 8887 [30%] 8887 [30%] BuAc [20%] BuAc [30%] [content] - - ® ® LR LR 23 °C[Pa·s] Viscosity at Viscosity 80.0–150.0 10.0–20.0 10.0–30.0 14.0–32.0 8.0–21.0 2.0–15.0 2.0–15.0 3.0–6.0 7.0–9.0 1.5–5.0 2.0–7.0 4.0–6.0 [60 °C] [60 °C] Functionality calculated 7.0 2.2 2.8 2.0 3.5 8.3 7.5 3.5 2.4 2.0 2.9 2.9 Hydroxy value [mg KOH/g] 17 12 10 10 30 11 10 6 9 5 3 6 Hardness 4 4 4 3 3 2 2 2 2 1 1 1 Elasticity 4 4 4 4 3 3 3 2 2 1 1 1 Reactivity 4 3 3 3 3 2 2 2 1 1 1 1 resistance Chemical 4 4 4 4 3 2 2 2 2 2 1 1 weathering-resistant shrinkage, lowyellowing, abrasion-resistant, elastic,Highly reactive, goodadhesion, low substrates good adhesiontovariousplasticandinorganic high chemicalresistance, weathering-resistant, resistance,Excellent scratch highreactivity, very resistance good weathering high temperature, goodadhesion, lowshrinkage, Physical drying, whencuredat bestperformance behavior, highviscosity, goodadhesion very flexibleandtough,Extremely beststrain-stress Highly elastic,Highly lowyellowing, goodadhesion Flexible andtoughwithhighviscosity resistance (fallingsand) Very reactive, flexible,abrasion very good very applications, lowyellowing andweathering-resistant,Scratch- outdoor for Laromer monomer-free (solvent-based)versionof Lowest yellowing, resistance, excellentscratch weathering-resistant functional,highly highchemicalresistance, very resistance, andabrasion Excellent scratch weathering resistance,weathering lowyellowing High elasticity, excellentPVCadhesionand weathering-resistant Elastic, lowyellowing,at lowtemperatures, flexible ® 1 UA9048 Low Key properties 2 Medium 3 Good REACH Europe 1 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan ENCS 2 2 2 2 2 2 2 - - - - - IECSC China 3 3 3 3 3 3 1 1 1 1 1 - - Currently nonotification 3 2 1 Notified  Please contactyourlocalsalesrepresentative forfurtherinformation  Canada For furtherregulatory information, [email protected] 3 3 3 3 3 3 DSL 1 1 1 1 1 - Korea ECL 1 1 1 1 1 1 1 1 - - - - Radiation-curable systems TSCA USA 1 1 1 1 1 1 1 1 1 1 - - Australia AICS 1 1 1 1 ------2019 Philippines PICCS 3 3 3 3 1 1 1 - - - - - 89

Radiation-curable systems 90 Laromer Laromer Laromer Laromer Laromer UV specialties Product Laromer Unsaturated polyesters Product Laromer Laromer Laromer Laromer Laromer and UVspecialties Laromer ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 PR9119 PR9058 PR9052 PR9013 PR8985 PA 9083 UP9151 UP9118 UP9115 UP9096 UP35D NEW ® Unsaturated Unsaturated Unsaturated Unsaturated Unsaturated Unsaturated Inert resin Inert resin Aromatic; Aromatic; Adhesion Polyester Polyester Polyester promoter polyester polyester polyester polyester polyester Type of Type of modified solution solution resin resin resin resin unsaturatedpolyesters Type ofthinner Type ofthinner DPGDA DPGDA [45%] TMPTA [62%] TMPTA [60%] TPGDA [38%] Monomer mix GPTA [60%] [content] [content] [42%] [42%] - - - - / TMPTA 23 °C[Pa·s] 23 °C[Pa·s] Viscosity at Viscosity at Viscosity 30.0–65.0 13.0–19.0 26.0–31.0 5.0–10.0 1.2–3.5 5.0–8.0 4.0–8.0 3.0–6.0 3.0–6.0 45–70 60–80 Functionality Functionality calculated calculated 1.0 5.5 6.0 3.5 3.5 4.8 2.3 1.5 1.5 4.5 - Hydroxy value Hydroxy value [mg KOH/g] [mg KOH/g] 170 14 18 11 26 25 25 8 7 - - Hardness Hardness 3 3 3 3 3 3 2 2 2 2 - Elasticity Elasticity 3 3 2 2 2 1 1 1 1 1 - Reactivity Reactivity 3 3 2 2 2 2 2 1 1 1 - resistance resistance Chemical Chemical 3 3 3 3 3 3 3 2 2 2 - adhesion onmetalandplastic Acidic adhesionpromoter;co-bindertoincrease Good corrosionresistanceonmetal age; lesshydrophobicthanLaromer age; Excellent pigment-wettingproperties, lowshrink- morehydrophobicthanLaromer age; Excellent pigment-wettingproperties, lowshrink- good adhesion to matt andchemicalresistance,Very goodscratch easy S33), hard, scratch-resistant (S42,application Abrasion-resistant inflooring diluent Good leveling, goodadhesion, freeofstenomeric even at highfillercontent even at Excellent pigmentwetting, goodflowbehavior Hard, goodchemicalresistance Good adhesionandgoodsandingproperties adhesion Balanced mechanicalprofile, goodsandingand 1 Low Key properties Key properties 2 Medium ® ® PR8985, PR9013 3 Good REACH REACH Europe Europe 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan Japan ENCS ENCS 2 2 2 2 2 2 2 2 2 2 - IECSC IECSC China China 1 1 1 1 1 1 1 1 1 1 1 - Currently nonotification 3 2 1 Notified  Please contactyourlocalsalesrepresentative forfurtherinformation  Canada Canada For furtherregulatory information, [email protected] 3 3 DSL DSL 1 1 1 1 1 1 1 1 1 Korea Korea 3 3 3 3 3 ECL ECL 1 1 1 1 1 - Radiation-curable systems TSCA TSCA 3 USA USA 1 1 1 1 1 1 1 1 1 1 Australia Australia AICS AICS 3 1 1 1 1 1 1 1 1 1 1 2019 Philippines Philippines PICCS PICCS 1 1 1 1 1 1 1 1 1 - - 91

Radiation-curable systems 92 Laromer (PONPGDA) (CTFA) (TMPEOTA) Laromer UV monomers Product Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 TPGDA TMPTA TBCH PPTTA POEA PO9102 LR8887 LR8863 HDDA GPTA DPGDA Propoxylated (3.8) glycerol (3.8)glycerol Propoxylated neopentyl glycol diacrylate neopentyl glycol Ethoxylated (3.0)trimethyl Ethoxylated Trimethylolpropane formal Phenoxyethyl acrylate Hexanediol diacrylate 4-t-Butylcyclohexyl Chemical name Trimethylolpropane propane triacrylate Tripropylene glycol Dipropylene glycol glycol Dipropylene Propoxylated (2.0) Propoxylated Ethoxylated (5.0) Ethoxylated pentaerythritol pentaerythritol monoacrylate tetraacrylate ® triacrylate triacrylate diacrylate diacrylate acrylate UVmonomers Structure Viscosity Viscosity at 23°C 130–190 [mPa·s] 70–120 50–100 10–20 ~ 130 ~ 11 ~ 40 ~ 9 ~ 8 ~ 6 ~ 8 Stenomeric Yes Yes Yes Yes Yes Yes Yes No No No No Density [g/cm 1.04 1.14 1.10 0.94 1.10 1.01 1.02 1.05 1.09 1.08 1.10 3 ] Molecular [g/mol] weight 300 572 296 210 192 328 226 242 200 475 428 CAS number 42978-66-5 51728-26-8 15625-89-5 84100-23-2 48145-04-6 84170-74-1 13048-33-4 57472-68-1 66492-51-1 52408-84-1 28961-43-5 1 Notified 2 APHA color Max. 150 Max. 100 Max. 150 Max. 100 Max. 250 Max. 200 Max. 150 Max. 150 Max. 200 Max. 150 Max. 100 [Pt-Co]  representative for further information further representativefor Please contact yourlocalsales REACH Europe 1 1 1 1 1 1 1 1 1 1 1 Japan ENCS 2 2 2 2 2 2 2 2 2 - -

IECSC China 3 1 1 1 1 1 1 1 1 1 1 1  please contact [email protected] For further regulatory information, Canada 3 3 DSL 1 1 1 1 1 1 1 1 1 Korea ECL 1 1 1 1 1 1 1 1 1 1 1 Radiation-curable systems TSCA USA

1 1 1 1 1 1 1 1 1 1 1 - Currently nonotification Australia AICS 1 1 1 1 1 1 1 1 1 1 1 2019 Philippines PICCS 1 1 1 1 1 1 1 1 1 - - 93

Radiation-curable systems 94 Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Laromer Water-based UVresins Product Laromer Laromer Laromer ® ® ® ® ® ® ® ® ® ® ® ® ® Radiation-curable systems 2019 UA9154 Aqua UA9149 Aqua UA9147 Aqua UA9135 Aqua UA9134 Aqua UA9112 Aqua UA9095 Aqua UA9059 Aqua UA9005 Aqua UA8983 Aqua UA8949 Aqua PE55 Aqua PE22 Aqua NEW NEW NEW NEW NEW NEW ® Polyester acrylate acrylate Polyester acrylate Polyester Urethane acrylate Urethane acrylate Urethane acrylate Urethane acrylate Urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate urethane acrylate water-based UVresins Type ofresin dispersion dispersion dispersion dispersion dispersion dispersion dispersion dispersion dispersion dispersion emulsion emulsion Aromatic Aromatic Aromatic Aromatic Aromatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Aliphatic Solid content 38–42 38–42 38–41 37–39 38–42 48–52 48–52 35–38 37–40 38–41 38–41 68–72 ~ 40 [%] 23 °C[Pa·s] Viscosity at Viscosity 0.015–0.18 0.005–0.35 0.02–0.25 0.01–0.38 0.25–0.65 0.01–0.15 0.05–0.3 0.01–0.5 0.15–0.5 0.05–1.2 0.05–0.5 0.01–0.6 6.0–11.0 Functionality calculated 1.6 3.8 5.2 2.7 3.6 2.6 5.0 4.7 3.9 4.9 3.7 3.1 2.0 pH value 7.3–8.3 6.5–8.0 7–8.5 7–8.5 6–8 7–9 7–9 4–6 7–8 7–8 7–8 4–6 7–8 Hardness 4 4 4 4 4 4 4 2 2 2 2 2 1 Elasticity 4 4 3 3 3 2 2 2 2 2 2 2 2 Reactivity 4 4 4 3 3 2 2 2 2 2 2 2 2 resistance Chemical 4 4 4 4 4 4 4 3 3 3 2 2 1 Excellent scratch andchemicalresistance Excellent scratch ties, easytomatt Hard, chemicalresistance, goodsandingproper ency and good compatibility withotherdispersions ency andgoodcompatibility dispersionwithhighwetfilm transpar Fast-drying dispersions coatings.formulated withother Goodcompatibility in clearcoatings. in Goodviscositystability releasewithhighresistance Very fastwater basedonLaromer Coatings ing propertiesandfreeofstenomericmonomers. Very highchemicalresistance,- goodphysicaldry basedonLaromer Coatings propertiesandlowyellowing.physical drying highchemicalresistance, avery Offers good clear orwhitepigmentedsystemsisrequired wherehighresistancese.g. suitable very in coffee or whitepigmentedsystemsisrequired wherehighresistance(e.g.suitable inclear coffee) Excellent physical drying properties Excellent physicaldrying yellowing Good all-roundproperties, adhesiontoPVC, low resistance weathering enhancement,Good grain goodchemical and Tough, easytomatt, adhesiontoPVC adhesion onmelaminesubstrates and withgoodphysicaldrying coatings off-white releasewithhighresistancein Very fastwater good adhesiononvarioussubstrates ed coatings, goodresistancepriortoUVcuring, Outstanding throughcuringpropertiesinpigment- coin-test results Excellent adhesiononwood, flexible, very excellent 1 Low Key properties 2 Medium ® ® UA9135 Aqua are UA9134arevery 3 Good - - REACH Europe 1 1 1 1 1 1 1 1 1 1 1 1 1 4 Excellent Japan ENCS 2 2 2 2 ------IECSC China 3 3 3 3 1 1 ------Currently nonotification 3 2 1 Notified  Please contactyourlocalsalesrepresentative forfurtherinformation  Canada For furtherregulatory information,[email protected] 3 3 3 3 3 3 3 3 3 DSL 1 - - - Korea 3 3 3 ECL 1 ------Radiation-curable systems TSCA USA 1 1 1 1 1 1 1 1 - - - - - Australia AICS 3 1 ------2019 Philippines PICCS 3 1 1 1 ------95

Radiation-curable systems

Bitte Kurzversion des KapiteltitelsFormulation eintragen additives We createWe chemistrycreate chemistry that makes that coatingsmakes coatings love resins love and resins additives and additives9797 Water-based systems Water-based

Formulation additives Solvent-based systems

BASF is a premier provider of formulation additives for the paints and coatings industry. With a full complement of respected brands and a broad technology base of dispersing agents, wetting agents and surface modifiers, defoamers, and rheology modifiers, our unique portfolio helps to enable performance-driven products which meet the latest and most stringent environmental regulations. Bio-based systems

Efka® Hydropalat®

The Efka® brand offers a broad selection of Under the Hydropalat® brand, BASF presents a dispersing agents, wetting agents and surface selection of substrate wetting, colorant compatibilizing, modifiers, defoamers, and rheology modifiers for flow control, and slip agents for water-based industrial non-aqueous formulations. and automotive coatings.

Dispex® and Dispex® Ultra Rheovis®

® Providing a range of standard and highly efficient The long-established Rheovis range comprises Radiation-curable systems dispersing agents for aqueous systems and for a broad portfolio of synthetic rheology modifiers for universal pigment concentrates, the Dispex® and aqueous systems, including non-ionic associative Dispex® Ultra brands portfolio includes polymeric, (HEUR / HMPE), anionic associative (HASE), and oligomeric, and surfactant-based dispersing agents. non-associative thickener (ASE) technologies.

Foamaster® and FoamStar®

Offering an outstanding selection of defoamer technologies for aqueous systems, the familiar Formulation additives Foamaster® and FoamStar® brands present Formulation additives products based on mineral oils or native oils as well as specialty-emulsion defoamers and organosilicone, silicone-free, and star-polymer- based defoamers. Performance additives Formulation additives Formulation additives 98 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 99

Dispersing agents

Solid particles such as pigments and fillers are BASF’s knowledge of pigment chemistry and surface BASF offers a full range of dispersing agents for all prepared that are designed to optimally fit pigment important components of paints and coatings and treatments combined with our know-how about paints and coatings formulations containing highly and resin chemistry. need to be dispersed and stabilized well in the dispersing agents and their technology enables us efficient solutions for aqueous, solvent-based, high-​ formulations to assure consistent color, quality, to find optimum solutions for our customers and their solid, or 100% solids systems and for pigment As illustrated, dispersing agents designed with CFRP and durability. formulation challenges. concentrates. The broad technology portfolio includes consist of two defined blocks that are produced by Highly specialized additives are needed to wet, polymeric, oligomeric, and surfactant-based dispersing sequential polymerization of monomers or monomer disperse, and stabilize dry pigment powders in liquid Favored properties agents. mixtures. Typically, a longer stabilizer block is formulations. Dispersing agents represent an essential synthesized first, which has to be compatible with the component of most paint and coating formulations. BASF’s dispersing agents product range relevant paint systems. The anchoring block contains Their specialized function ensures color strength, for water-based systems functional groups which interact strongly with the gloss, viscosity stability, and prevents sedimentation of pigment surface to allow for efficient and stable Advanced  Low-molecular Oligomeric High-molecular particles. Today, high-quality coatings of high brilliance high-molecular adsorption. For demanding applications like organic weight dispersants weight weight and color strength are characterized by a perfect dispersants (FAME) dispersants pigments, the anchoring block typically contains aminic dispersants pigment dispersion, optimal pigment particle size, and Primary particles Aggregates Agglomerates groups, which can optionally be modified further. Dispex® AA Dispex® Ultra PA long-term stabilization of the dispersed particles in the Dispex® Ultra FA Dispex® Ultra FA Dispex® CX Dispex® Ultra PX formulation. Favored energy state

BASF’s dispersing agents product range A-Block is resin- and solvent-specific Higher for solvent-based systems (incl. 100% systems) Compatible with paint system, B-Block is pigment-specific e.g. resins and solvents Anchoring onto pigment Advanced  Low-molecular Oligomeric High-molecular high-molecular weight dispersants weight Structure of dispersing agents designed with CFRP technology weight dispersants (FAME) dispersants dispersants BASF recently developed a new dispersant “toolbox” ® ® ® Dispex Ultra FA Efka PA ® that was developed to formulate a complete set of Efka FA ® ® Efka PX Efka FA Efka PU label-free universal colorants. Universal pigment concentrates can be used to tint aqueous and Lower Especially, the award-winning controlled free radical solvent-based paints and coatings. This is achieved Particle size polymerization (CFRP) allows for higher efficiency and with “universal” dispersing additives, which are often Viscosity Photo stability Strength Opacity broader compatibility, which creates optimal rheology based on low molecular weight or oligomeric type and improved coloristics. Benefits are outstanding dispersing agents. §§ Optimum properties at low particle size viscosity reduction, enhanced gloss, increased color All toolbox products comply with the major ecolabel §§ Energy required to mill down pigment intensity, and hiding power. standards. Based on innovative new chemistry, §§ Stabilization required to keep particles apart a combination of amine- and acid-functional Efka® PX and Dispex® Ultra PX grades are very polymers was found that provides universal affinity

Dry pigments Need for dispersion, whereby optimum properties of a pigment are achieved versatile and powerful product groups for sol- to pigment surfaces (FAME technology). With this at low particle size vent-based and aqueous applications, respectively. set of dispersants it is possible to formulate inorganic

Although non-controlled free-radical polymerization pigments at high pigment loading while also achieving Formulation additives can lead to good dispersing agents, polymers with excellent results with organic pigments and carbon Key benefits for your formulation a highly defined architecture can be more efficient, blacks. The products carry no, or only mild, labeling, resulting in improved colorant stability and broader which allows the formulator their use in label-free §§ Shorter dispersion time §§ Improved tone development system compatibilities. colorant formulations at a maximum concentration of 10%, §§ Enhanced gloss §§ Prevention of flooding and floating This exact degree of control in polymer synthesis is provided no other components with similar labeling are created by the award-winning controlled free radical used. §§ Increased color strength and hiding power §§ Prevention of flocculation polymerization (CFRP) technology. It enables the §§ Reduced viscosities §§ Prevention of settling of pigments and fillers precise design of polymer structures. With the CFRP For all dispersing additives BASF experts have worked technology, well-defined block copolymers can be out guide formulas for a variety of pigments in order to support formulators and developers. Formulation additives Formulation additives 100 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 101

Wetting agents and surface modifiers

Wetting agents and surface modifiers are essential BASF Formulation Additives offers a broad portfolio Fluorinated polyacrylates are a very versatile class of Fluorinated polyacrylate components of modern paints and coatings. They of wetting agents and surface modifiers for water-​ interfacially active additives. They are widely used in at the liquid / air interface provide a formulation with adequate wetting properties, based and solvent-based systems based on various the coating industry as flow and leveling agents. Pure enhance different component compatibility, and chemistries. polyacrylate copolymers are highly appreciated for their Illustration of fluorinated polyacrylate at the liquid / air improve the surface of a coating. Our broad portfolio flow performance, although they do not significantly interface. The block copolymer arrangement makes of wetting agents and surface modifiers offers highly reduce the surface tension of a formulation. However, maximum use of the fluorinated side chains. Product effective products for almost every paint and coating Chemistry Characteristics a straight polyacrylate cannot solve problems like system. range cratering, poor substrate wetting, and other problems Most coating systems need good flow and leveling related to surface tension. Fluorinated polyacrylates in order to have a smooth appearance. A flat and Alkoxylated Low-foaming substrate wetting have been developed as a result. These polyacrylates Hydropalat® even surface will give a higher gloss and is therefore surfactant agents for waterborne applications with fluorinated side chains can lower the surface eye-catching. As shown, wetting agents and surface tension of a formulation. They combine excellent flow modifiers can have a strong influence on coating and leveling with anti-cratering and good wetting properties like substrate wetting, slip, flow, and leveling. behavior. Substrate wetting agents with Efka® Silicone generally very low static surface Hydropalat® surfactants In comparison to organo-modified silicones and tension Controlling coating effects straight polyacrylates, fluorocarbon-modified polyacrylates have clear advantages with respect Several coating effects such as substrate wetting, flow to flow, substrate wetting, and fish-eye resistance. Statistical copolymer and leveling, surface slip, and defoaming are controlled Cost-effective substrate wetting On the other hand, polysiloxanes can provide Hydropalat® Sulfosuccinates agents with excellent dynamic by wetting agents and surface modifiers. strong surface slip and anti-blocking effects and surface tension reduction Fluorinated side chains reduce surface tension. Defoaming / deairation Slip / hydrophobization Leveling The newest generation of fluorinated acrylates are block copolymers with fluorinated side chains. These High-performance acrylate Efka® (Fluorinated) unique products are made via controlled free radical leveling agents for waterborne Hydropalat® polyacrylates and solvent-based applications polymerization (CFRP), which allows the synthesis of block copolymer structures and to concentrate the Coating Flow fluorinated side chains in one polymer block only. Such an arrangement makes best use of the Defoaming wetting agents based on Star-shaped fluorinated side chains and guarantees maximum Hydropalat® star-shaped polymers for excellent Polyacrylate backbone polymers Substrate wetting dynamic surface tension reduction effectiveness with respect to substrate wetting and anti-cratering behavior. Substrate Block copolymer Formulation additives Formulation additives Formulation additives 102 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 103

Defoamers

For paint manufacturers and applicators, foam control All defoamers are characterized by a certain balance BASF Formulation Additives offers a broad selection A very special defoaming technology is our award- is one of the major tasks to ensure a smooth and even between compatibility and incompatibility in a given of defoamer technologies to the paint and coatings winning FoamStar® series. The FoamStar® polymer appearance of the paint film. Thus, high-performing system. On the one hand, the active ingredient in the market. The portfolio ranges from standard mineral is a hyper-branched polymer with a 3D star-shaped defoamers are needed to prevent the formation of defoamer must be almost insoluble in the paint oil defoamer technologies to aqueous emulsion structure, containing hydrophilic as well as hydrophobic bubbles in liquid paints. They reduce foam and avoid formulation. A defoamer must form small defoamer defoamers and up to our innovative FoamStar® elements. foam formation during the production, application, droplets which are able to migrate into the foam technology. Unlike conventional mineral oil and silicone defoamers, and transport of paint formulations. lamellae. In order to ensure long-term defoaming Today, most defoamers are sophisticated formulations the FoamStar® molecule defoams on a molecular level. Especially in industrial surroundings, foam is a very efficiency the defoamer droplets have to be stable designed to fit together with paint and coating formula- It acts as a unique surfactant interacting with the undesirable phenomenon that can emerge during in the system and should not dissolve upon storage. tions in the best possible way. Usually the formulations foam-stabilizing surfactants and destabilizes the foam dispersing processes, pumping, stirring operations, are based on raw materials with a low surface tension bubbles. When combined with conventional defoamer or while applying paints. This foam can, for example, On the other hand, no surface defects such as craters such as silicone, mineral oils, fatty acids, and fluorocar- types it yields faster bubble-break times and improves increase the production time, create difficulties in filling should be generated in the final paint film due to bons. the overall efficiency. Bubble-break time is the time in vessels, reduce the efficiency of many high-speed defoamer incompatibility. The defoamer must therefore seconds needed to break all macro bubbles in a paint operations, and promote surface defects like craters, be sufficiently compatible with the binder. Thus, every film; the shorter the time the better the defoamer. fish eyes, pinholes, and weak points in the dried film. defoamer is formulated on a tightrope between compatibility and targeted incompatibility. In order to explain the working mechanism of defoamers, there is no single overarching defoamer Product range Chemistry Characteristics theory in the scientific literature. However, for aqueous systems all theories have some explanations and Foamaster® prerequisites in common. It is generally accepted that a defoamer active should: MO Mineral oil Macro foam, universal §§ Possess a “controlled incompatibility” with the formulation to be defoamed. This “controlled NO Natural oil Renewable, low S-VOC

incompatibility” must remain even after long-term FDA, better odor, WO White oil storage low fogging §§ Have a low surface tension FoamStar® §§ Exhibit a de-wetting effect Universal, easy §§ Have the capability to penetrate into the foam ED Emulsion defoamers to incorporate lamellae and to spread effectively on the liquid / High efficiency, gas interface PB Polymer-based no silicone

Silicone-based High gloss, industrial, SI defoamers printing inks

Star polymer-based High efficiency, Formulation additives ST defoamers fast foam knock down Efka®

Polymer-based High efficiency, PB defoamers no silicone

Silicone-based High efficiency, SI defoamers high gloss The FoamStar® star-shaped polymer Formulation additives Formulation additives 104 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 105

Rheology modifiers

Rheological modifiers are key ingredients in paints and Rheology modifiers from BASF reduce dripping and BASF offers nearly all commercially used classes of characteristic properties. The table below highlights coatings as they help control the coating application spattering of paint during roller or brush application. synthetic rheology modifiers for water-based paints the benefits and areas of use of each product class. and the final appearance. Without these special Sag resistance of paint is improved by a rapid but and coatings. Each product class has its own additives, such media would be as “runny” as water. controlled viscosity increase after application. During application, paints would spatter in all During transport and storage of the paint, rheology directions, have little hiding power, and exhibit a modifiers prevent sedimentation of the pigments Polyurethanes, polyethers Acrylics Property / influence on much shorter shelf life. Rheology modifiers enable within a formulation. Rheology modifiers ensure (Rheovis® PU, Rheovis® PE) (Rheovis® AS, Rheovis® HS) formulators to adjust the flow behavior of paints and that the end product achieves the desired balance Low shear viscosity Medium contribution High contribution coatings. That way, painters benefit from improved between consistency, durability, and good application viscosity and application characteristics. properties. High contribution (high film thickness by roller / High shear viscosity Low contribution, less impact on film thickness brush application)

Viscosity [mPa·s] Spattering Improves spattering Low effect 105 Storage 104 Gloss Low to no effect Matting effect possible

103 Sag, leveling Influence of surfactants Low to high, must be tested in each case Hardly any (AS), moderate (HS) 102 Stirring Low to no tendency to syneresis 10 Painting Syneresis Tendency to syneresis depending on type 1 Good to moderate effect 0.01 0.1 1 102 103 104 Scrub and wash resistance Very good effect depending on type Brookfield Stormer ICI Shear rate [s-1]

Controlled stress rheometer

Viscosity profile and shear rates at different application scenarios including corresponding measurement equipment Especially our Rheovis® PU and PE series of The rheological behavior of aqueous paints and associative thickeners represent a class of coatings can be rendered either more Newtonian BASF offers six classes of The naming of our products corresponds ground-breaking materials based primarily on hydro- (brush, roll-on, curtain coating) or more pseudoplastic rheology modifiers for paints to their chemical composition and shear phobically modified polyether and polyurethane (sprayable) in nature to ensure optimized application and coatings profile derivatives. properties. With these rheology modifiers, it is possible to create §§ Alkali swellable emulsions (ASE) a wide variety of rheological profiles, imparting superb Rheology modifiers §§ Hydrophobically modified alkali swellable emulsions attributes to a broad range of water-based paints and coatings. (HASE) Rheovis® HS 1xxx Associative acrylic (HASE) §§ Hydrophobically modified polyurethanes (HEUR) Rheovis® AS 1xxx Non-associative acrylic (ASE) §§ Hydrophobically modified polyethers (HMPE) Key benefits for your formulation Formulation additives §§ Attapulgites (inorganic rheology modifiers) Rheovis® PE 1xxx Associative polyether (HMPE) §§ Broad rheology profile §§ Low impact on water uptake §§ Castor oil and wax-based thixotropes §§ Highly efficient across many resin types §§ Low impact on water whitening Rheovis® PU 1xxx Associative polyurethane (HEUR) §§ pH-independent §§ Excellent leveling Attagel® Organoclay types §§ Improved wash and scrub resistance §§ Reduced spattering

Efka® RM 1xxx Rheology modifiers for solvent-based

11xx = low shear 12xx = mid shear 13xx = high shear 19xx = solids 106 Rheovis Rheovis Rheovis Rheovis Rheovis Rheovis Rheovis Rheovis Rheovis Rheology modifiersdesignedtobeusedinwater-based systems Product name The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products exceptRheovis Rheovis ® ® ® ® ® ® ® ® ® We create chemistrythatmakescoatingsloveresins andadditives Formulation additives PU1331 PU1291 PU1191 PE1330 HS1303EB HS1212 HS1169 HS1162 1130 AS NEW ® PU1214andRheovis ® Associative thickener:Associative hydrophobically thickener:Associative hydrophobically thickener:Associative hydrophobically thickener:Associative hydrophobically modified ethoxylated urethane(HEUR) modified ethoxylated urethane(HEUR) modified ethoxylated urethane(HEUR) modified ethoxylated rheologymodifiers Non-associative thickener:Non-associative anionic hydrophobically modified(HASE) hydrophobically modified(HASE) hydrophobically modified(HASE) hydrophobically hydrophobically modified(HASE) hydrophobically Associative thickener:Associative anionic thickener:Associative anionic thickener:Associative anionic Associative thickener:Associative anionic polyacrylate copolymer (ASE) copolymer polyacrylate modified polyether (HMPE) modified polyether polyacrylate copolymer,polyacrylate copolymer,polyacrylate copolymer,polyacrylate polyacrylate copolymer,polyacrylate Description ® PU1250complywith APEO-free claims.APEO hasnotbeenintentionallyadded. Solids [%] 40 30 35 30 25 18 45 30 30 Viscosity Viscosity [mPa·s] ~ 4,500 ~ 4,500 ~ 3,000 ~ 2,800 < 50 < 50 < 50 ~ 5 ~ 5 VOC content < 0.005 < 0.005 < 0.5 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 [%] < 1 Recommended for low-VOC paints* 1 1 1 1 1 1 1 1 1 Tin-free 1 1 1 1 1 1 1 1 1 Water-based systems 1 1 1 1 1 1 1 1 1 *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Recommended for Solvent-based systems ------Solvent-free systems ------product whichcanbeusedinmostpaintsystems thickener; improvesflow;excellentefficiency;all-round thickening;mid-shear thickenerwithassociative Acrylic Excellent high-shearthickener;impartsexcellentflow brushandrollerapplications for coatings for wood suited especially Newtonian flowbehavior; systems;excellent aqueouspaintandcoating many for thickenerwithpronouncedhigh-shearbehavior Acrylic of opentime uptake;elongation lesswater applications; thickener; spray thickening;low-shear thickenerwithassociative Acrylic contact even afterlongwater uptake;noimpactonwetadhesion lowwater flow behavior; thickening;thixotropic thickenerwithassociative Acrylic best-in-class ICIperformance high-shearthickener;ultra-efficient,Next-generation excellent ICIthickeningandeasyhandling Next-generation modifierwith VOC-free mid-shearrheology andeasyhandling;strongpseudoplasticity performance stronglow-shearthickenerwithexcellent Next-generation applications spray for successfulinindustrialandautomotiveformulations highly anti-settling; usedinpigmentandfillerslurriesbutalso low-shear thickener;highshearthinning, anti-sagging, and efficient thickener;highly pureacrylic Non-associative Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 - - - - Formulation additives Industrial 1 1 1 1 1 1 - - - and flooring Furniture 1 1 1 1 1 1 - - - 107

Formulation additives 108 Efka Efka Efka Efka Rheology modifiersdesignedtobeusedinsolvent-basedsystems Product name Efka The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® RM1920 RM1900 RM1506 RM1469 RM1463 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® rheologymodifiers Modified hydrogenated castoroil Modified hydrogenated Hydrogenated castoroil Hydrogenated Polyamide wax Polyamide wax Polyamide wax Polyamide Description Solids [%] 100 100 24 20 20 Viscosity Viscosity [mPa·s] Powder Powder Paste Paste Paste VOC content < 0.1 < 0.1 [%] 76 80 80 Recommended for low-VOC paints* - - - - - Tin-free 1 1 1 1 1 Water-based systems - - - - - *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Recommended for Solvent-based systems 1 1 1 1 1 Solvent-free systems 1 1 - - - formulations; standardthixotropy formulations; non-aqueous resistancefor Provides excellentsag stability highertemperature formulations; non-aqueous resistancefor Provides excellentsag dipping, spraying, andaerosolapplications mostsolvent-basedsystemsin in xylene;wellsuitedfor waxdispersed systems; hardpastetypeofpolyethylene solvent-based for Anti-settling andanti-hard-cakingagent on colorandgloss minimumeffect for woodcoatings; and refinishaswell solvent-basedOEM andanti-settlingpropertiesfor sagging waxthickener; excellentanti- polyamide Pre-activated industrial, architectural, heavy-duty, andmarinecoatings solvent-based andanti-settlingpropertiesfor sagging waxthickener; excellentanti- polyamide Pre-activated Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 - - - - Formulation additives Industrial 1 1 1 1 1 and flooring Furniture 1 1 - - - 109

Formulation additives 110 FoamStar FoamStar FoamStar Defoamers designedtobeusedinwater-based systems Product name FoamStar FoamStar FoamStar FoamStar FoamStar FoamStar FoamStar FoamStar The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. FoamStar We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® ® ® ® ® ® ® ® ® ® ® ST2454 ST2438 ST2400 SI2299 SI2280 SI2250 SI2240 SI2216 SI2210 ED2523 ED2522 NEW NEW polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based polydimethylsiloxane-based Emulsion defoamers Emulsion defoamers Star polymer-based Star polymer-based Star polymer-based ® Description defoamers defoamers defoamers defoamers defoamers defoamers defoamers defoamers defoamers defoamers Modified Modified Modified Modified Modified Modified /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding /let-down stage Grinding Incorporation Grinding stage Grinding stage Dosage [%] 0.25–0.5 0.25–0.5 0.05–1.5 0.2 –0.6 0.1–1.0 0.1–1.5 0.1–0.5 0.2–0.7 0.1–1.0 0.1–0.3 0.1–0.5 Solids ~ 27 ~ 20 100 100 100 100 100 100 100 100 100 VOC content < 0.1 < 0.1 < 0.5 < 0.1 < 0.1 < 0.5 < 0.5 < 0.5 [%] < 1 < 1 0.5 Recommended for low-VOC systems* 1 1 1 1 1 1 1 1 1 1 1 Water-based systems 1 1 1 1 1 1 1 1 1 1 1 Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems ------Solvent-free systems 1 ------containing Silicone 1 1 1 1 1 1 1 1 1 1 - to highPVCcoatings Ultra lowSVOC, medium for emulsiondefoamer low-SVOC content extremely stability; paints, clearcoats, andinks;excellentstorage premiumwater-based for emulsion defoamer High-performance, ultralowSVOCsilicone persistency and foam knockdown persistency andfoam based paints, deliveringexcellent long-term high-quality water- for Silicone-based defoamer andcompatibility ofeffectiveness combination anoutstanding periods;offers longer storage remainspersistentover coatings; spray fromwater-basedremoves micro-foam effectively applications; coating aqueous spray for anddefoamer deaerator effective Highly content andsystemswithhighsurfactant concentrates aqueouspigment for defoamer effective Highly content andsystemswithhighsurfactant concentrates aqueouspigment for defoamer effective Highly efficient inPURemulsions outstanding long-termstability,coatings; highly aqueouswood,for industrialandautomotive Silicone-free defoamer, suitable especially andcompatibility effectiveness of anoutstandingcombination periods; offers Remains persistentoverlongerstorage pigment concentrates water-baseder; recommendedfor paintsand Easy toincorporate,- defoam high-shearstable in therange exists;mosteffective processing orapplication wherehigh-shear pigment concentrates water-based for Defoamer and coatings persistency outstanding long-termdefoaming effect; a strongspontaneousdefoaming andUV-curablecoatings systems;provides pigmented andlow-pigmentedaqueous non- for 100%-active-content defoamer Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 1 - - - - - Formulation additives Industrial 1 1 1 1 1 1 1 1 1 - - and flooring Furniture 1 1 1 1 1 1 1 1 - - - 111

Formulation additives 112 Efka Efka Efka Efka Efka Efka Efka Efka Efka Efka Efka Defoamers designedtobeusedinnon-aqueoussystems Product name The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® ® ® ® ® ® ® SI2723 SI2721 SI2040 SI2035 SI2022 SI2008 PB2744 PB2720 PB2020 PB2010 PB2001 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® defoamers Solvent-based solutionof Solvent-based solutionof Solvent-based solutionof Solvent-based solutionof Blend of foam-destroying Blend offoam-destroying of defoaming substances of defoaming substances of defoaming substances of defoaming substances of defoaming substances of defoaming substances withsilicone defoaming substances,defoaming substances,defoaming substances,defoaming substances,defoaming Solvent-free solutionof Solvent-based solution Solvent-based solution Solvent-based solution Solvent-based solution Solvent-based solution defoaming substances defoaming with modifiedsilicone with modifiedsilicone with modifiedsilicone with modifiedsilicone with modifiedsilicone with modifiedsilicone Description silicone-free silicone-free silicone-free silicone-free compounds compounds compounds compounds compounds compounds Before orafterprocessing Before orafterprocessing Before orafterprocessing Before Before orafterprocessing Before orafterprocessing Before orafterprocessing Before orafterprocessing Before Before orafterprocessing Before Prior toprocessing End ofprocessing End ofprocessing Incorporation Dosage [%] 0.1–10.0 0.05–0.5 0.5–1.0 0.1–0.7 0.5–1.0 0.1–1.0 0.3–1.0 0.1–0.7 0.1–0.7 0.5–1.5 0.2–1.5 Solids 100 26 ------VOC content < 0.1 > 95 > 95 > 95 > 90 ~ 80 ~ 80 ~ 60 < 25 [%] 99 74 Recommended for low-VOC systems* 1 ------Water-based systems ------Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 1 1 1 1 1 1 1 1 1 - Solvent-free systems 1 1 1 1 1 1 1 1 1 - - containing Silicone 1 1 1 1 1 1 1 - - - - roller, brush, applications andairlessspray Solvent-based industrialfinishes, including enamels andstoving curtaincoatings Polyurethane long-oil air-drying alkyds systemsandmedium-to drying Physically systems suchasepoxy,coatings polyurethane, orUPE withnon-aqueous with excellentcompatibility efficientair-releaseSilicone-based highly agent silicone-free defoamer broaduse andgelcoats; polyesters unsaturated systems,Acid-cured andNC-curtaincoating when comparedtoEfka systems duetotheimprovedcompatibility clear solvent-based systems;wellsuitedfor broadusein for Silicone-free defoamer systems suchasepoxy,coatings polyurethane, orUPE Silicone-free air-release non-aqueous for agent systems polyester,Unsaturated epoxy, andpolyurethane defoaming substances in2-ethylhexylacrylate defoaming systems; inclearand matted defoaming UV-curing effective andEBCsystems;highly solvent-free radiation-curing systems solvent-free radiation-curing low odor, high-solid2-packsystemsand systems,Solvent-free epoxyandpolyurethane term persistency imparts surfacesmoothness;excellentlong- excellent efficiency;improveslevelingand high-solid andsolvent-freeformulations; for andde-aerator Ultra low-VOCdefoamer Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives ® PB2020 Automotive 1 1 1 1 1 ------Formulation additives Industrial 1 1 1 1 1 1 1 1 1 1 - and flooring Furniture 1 1 1 1 1 1 1 1 - - - 113

Formulation additives 114 Dispex Dispex Dispex Dispex Dispex Dispex Dispex High molecularweightdispersingagents Dispex Low molecularweightdispersingagentsmainlydesignedforwater-based systems,surfactant-liketypes Dispex Anionic dispersingagentsbasedonpolyacrylicacid Product name The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Dispex dispersing agents ® ® ® ® ® ® ® ® ® UltraFA 4480 UltraFA 4420 UltraFA 4416 CX4240 4140 AA 4040 AA UltraPX4275 UltraPA 4550 UltraFA 4483 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® and Fatty acidmodifiedemulsi- Fatty Ammonium polyacrylate Ammonium polyacrylate Ammonium polyacrylate Mixture ofsurfactants Phosphoric acidester Modified fatty alcohol Modified fatty Modified polyacrylate Modified polyacrylate Sodium polyacrylate Sodium polyacrylate Description (co-)polymer (co-)polymer (co-)polymer fier (FAME) Copolymer ethoxylate polymer

Dispex Solids [%] 37.5 100 80 75 40 43 45 50 30 ® Ultra Amine number [mg KOH/g] 35 27 ------[mg KOH/g] Acid value 25 22 ------VOC content < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.5 [%] < 2 < 1 < 1 Recommended for low-VOC systems* 1 1 1 1 1 1 1 1 - Water-based systems 1 1 1 1 1 1 1 1 1 Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 ------Solvent-free systems 1 ------intensity, andcoloracceptance to alternative APEOs; improvesglossdevelopment, color Universal, powerful non-ionicwettinganddispersingagent; organicandinorganicpigmentspigmentconcentrates for Wetting suitable aqueousformulations; for anddispersingagent Dispex For inorganicpigmentsandextenders;morehydrophobicthan liquefying effect leadingtoefficientdispersingpropertiesand low polydispersity inorganicfillersandpigments; for Standard dispersingagent liquefying effect leadingtoefficientdispersingpropertiesand low polydispersity inorganicfillersandpigments; for Standard dispersingagent suitable for inorganicpigmentconcentrates for suitable Universal, especially anionicwettinganddispersingagent; pigment concentrates and semi-glossandhigh-glosspaintformulations designed for specifically wettinganddispersingagent; High-performance resin-containing andresin-freepigmentconcentrates pH-independent, making for suitable broadcompatibility; Water-based industrialandautomotivecoatings, acceptance ofuniversalcolorantsinbasepaints andcolor willimprovecompatibility weight dispersingagents; withhighmolecular ascodispersingagent also suitable inorganicfillersandpigments; for Universal dispersingagent ® AA 4040 AA Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 - - - - Formulation additives Industrial 1 1 1 1 1 - - - - and flooring Furniture 1 1 1 1 1 1 - - - 115

Formulation additives 116 Dispex Dispex High molecularweightdispersingagents Product name Dispex The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Dispex ® ® ® UltraPX4585 UltraPX4575 UltraPX4525 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® Ultradispersingagents acid-functional polymers made by controlledfree made by controlledfree made by Acrylic block copolymer blockcopolymer Acrylic blockcopolymer Acrylic radical polymerization radical polymerization radical polymerization Blend ofamine-and Description (CFRP) (CFRP) Solids [%] 50 40 92 Amine number [mg KOH/g] 20 32 16 [mg KOH/g] Acid value 33 - - VOC content < 0.1 < 0.1 [%] < 1 Recommended for low-VOC systems* 1 1 1 Water-based systems 1 1 1 Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems - - - Solvent-free systems - - - suitable for makingresin-freepigmentconcentrates for suitable bindersystems;pH-independent; withdifferent compatibility High-end water-based coatings, industrialandautomotive;broad intoprimers, grinds for gloss, andsemi-glosspaints colorantsbutwellsuited resinsystems;designedfor different towards organicpigments; broadcompatibility for performance ininorganicpigments;excellentoverall benchmark performance water-based for VOC-free dispersingagent systemswith development, colorintensity, andcoloracceptance improvesgloss Universal wettinganddispersingagent; Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 - Formulation additives Industrial 1 1 1 and flooring Furniture 1 1 1 117

Formulation additives 118 Efka Efka Efka Efka Efka Efka High molecularweightdispersingagents Efka Low molecularweightdispersingagentsmainlydesignedforsolvent-basedsystems,conventionaltypes Product name Efka Efka Efka Efka Efka The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® ® ® ® ® ® ® ® PU4061 PU4047 PU4046 PU4010 PA 4403 PA 4401 FA 4620 FA 4611 FA 4609 FA 4608 FA 4601 FA 4600 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® dispersingagents NEW Solution of a copolymer Solution ofacopolymer Surface-active anionic modified polyurethane modified polyurethane Modified polyurethane Modified polyurethane Modified polyurethane Copolymer withacidic Copolymer Second generation of Second generation unsaturated modified unsaturated Modified polyacrylate Modified polyacrylate Modified polyacrylate Blend of fatty alcohol Blend offatty Hydroxyl functional with acidicgroups Acidic polyether carboxylic acid Description compounds polymer polymer polymer polymer polymer polymer sulfates groups Solids [%] 35.5 100 100 100 30 35 40 51 55 50 52 47 Amine number [mg KOH/g] 17 19 35 50 85 8 6 - - - - - [mg KOH/g] Acid value 129 290 50 12 ------VOC content < 2.5 < 2.5 27.5 [%] < 1 70 65 60 45 50 48 16 49 Recommended for low-VOC systems* 1 1 ------Water-based systems 1 ------Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 1 1 1 1 1 1 1 1 1 1 1 Solvent-free systems 1 1 1 1 1 1 ------strong viscosity-depressingproperties High-quality industrial, automotive,applications, andrefinish hiding power mill baseviscosity;highpigmentandfillerloading;increased strongreductionof Solvent-free wettinganddispersingagent; industrial coatings, especially TiO alltypesof for inorganicpigments;suitable for Dispersing agent fillers in composite formulations (SMC+BMC) formulations fillers incomposite refinish High-quality industrialfinishesincludingautomotiveOEMand General industrialcoatings grinding resinssuchasLaropal grinding with For industrialcolorants(pigmentpastes)incombination resinssuchasLaropal withgrinding combination industrialcolorants(pigmentpastes)in depression) for Industrial coatings, excellent(viscosity topcoats; transportation hiding power mill baseviscosity;highpigmentandfillerloading;increased strongreductionof wettinganddispersingagent; Copolymeric Solvent-based systemsincludinglowtopolarsolvents anti-settling propertiesinpolarsystems non-aqueoussystems;providesgood for Anti-settling agent properties for medium-polarsystems properties for non-aqueoussystems;goodanti-settling for Anti-settling agent TiO General industrialcoatings, of stabilization for woodcoatings 2 , agents andmatting Features andbenefits ® A 81 A 2 ; dispersionofextendersand We create chemistrythatmakescoatingsloveresins andadditives ® A 81 A Automotive 1 1 1 1 1 1 ------Formulation additives Industrial 1 1 1 1 1 1 1 1 - - - - and flooring Furniture 1 1 1 1 1 ------119

Formulation additives 120 Efka Efka Efka Efka Efka Efka Efka Efka Efka High molecularweightdispersingagents Product name The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® ® ® ® ® PX4350 PX4340 PX4330 PX4310 PU4063 PX4780 PX4753 PX4703 PX4701 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® dispersingagents NEW NEW NEW made by controlledfree made by made by controlledfree made by controlledfree made by controlledfree made by controlledfree made by made by controlledfree made by Acrylic block copolymer blockcopolymer Acrylic Acrylic block copolymer blockcopolymer Acrylic blockcopolymer Acrylic blockcopolymer Acrylic blockcopolymer Acrylic Acrylic block copolymer blockcopolymer Acrylic Modified polyurethane Modified polyurethane radical polymerization radical polymerization radical polymerization radical polymerization radical polymerization radical polymerization radical polymerization radical polymerization radical polymerization Advanced polymer Advanced polymer Description polymer (CFRP) (CFRP) (CFRP) (CFRP) (CFRP) (CFRP) Solids [%] 100 100 100 51 55 70 50 51 45 Amine number [mg KOH/g] 56 12 28 19 20 40 12 10 4 [mg KOH/g] Acid value ------VOC content < 2.6 < 2.5 < 2.5 [%] 45 49 30 50 49 55 Recommended for low-VOC systems* 1 1 ------Water-based systems ------Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 1 1 1 1 1 1 1 1 Solvent-free systems 1 1 1 1 - - - - - (RCPC) inawiderangeofapplications resin-free (RFPC)andresin-containingpigmentconcentrates solvent-based wellsuitedfor Solvent-free dispersingagent with 2-packPURandepoxies inCAB-modifiedsystemsbutalso systems; goodperformance Solvent-based high-endapplications, industrial, automotive desired reactivedispersantis wherearesin-matrix especially coatings industrialandautomotive for low levelsofaddition;suitable very lowerpigmentpasteviscositiesat carbon-blacks; creates for organicpigmentsand agent efficient dispersing Highly solvent-based applications, bothmild-solventandstrong-solvent UVinkjets;alsofor for systems;especially energy-curable for pigmentsespecially high-performance for Dispersing agent industrial andautomotivecoatings high-qualitysolvent-based for due toexcellentcompatibility; highgloss Cu-phthalocyanine pigmentsandpigmentgreen; for ß-andε-blue agent efficientdispersing Highly resinssuchasLaropal grinding with industrialcolorants(pigmentpastes)incombination for excellent(broadcompatibility) Solvent-based industrialcoatings; highjetness extremely blacks giving carbon for anddispersingagent coilcoatings pigment pastesfor resin-free for setting newstandardsasadispersingagent High-quality solvent-basedindustrialandautomotivecoatings; due to excellent compatibility; tin-free due toexcellentcompatibility; pigments incl. α-blueCu-phthalocyaninepigments;highgloss organic high-performance for suitable automotive coatings; high-qualitysolvent-basedindustrialand for Dispersing agent pastes and organicpigmentsinhigh-qualitysolvent-basedpigment ofinorganic thedeflocculation for dispersingagent Polymeric Features andbenefits ® A 81 A We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 1 - - - Formulation additives Industrial 1 1 1 1 1 1 1 1 - and flooring Furniture 1 1 1 1 1 1 - - - 121

Formulation additives 122 Hydropalat Slip andlevelingagents Hydropalat Substrate wettingagents Product name Hydropalat Hydropalat Hydropalat Hydropalat Hydropalat Hydropalat Hydropalat Hydropalat Hydropalat and surfacemodifiers The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Hydropalat We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® ® ® ® ® ® ® ® ® ® ® SL3682 3694 WE 3650 WE 3500 WE 3475 WE 3370 WE 3322 WE 3221 WE 3220 WE 3197 WE 3120 WE Aqueous dispersionofanultra-high molecular weightsilicone Fluorinated polyacrylates Fluorinated polyacrylates Fluorinated Alkoxylated surfactants Alkoxylated surfactants Alkoxylated surfactants Alkoxylated Star-shaped polymers ® Modified alkoxylates Silicone surfactants Silicone surfactants Sulfosuccinates Description wettingagents Dosage [%] 0.05–2.0 0.1–0.75 0.2–2.0 0.1–1.0 0.5–1.5 0.5–5.0 0.5–5.0 0.1–1.0 0.2–1.0 0.1–0.5 0.5–2.0 Solids [%] > 99.5 > 85 > 97 > 96 87.5 100 65 75 60 60 45 VOC content[%] < 0.5 < 0.5 < 15 < 10 < 20 12.5 < 1 ~ 6 < 3 < 3 55 Recommended for low-VOC systems* 1 1 1 1 1 1 - - - - - Water-based systems 1 1 1 1 1 1 1 1 1 1 1 Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems ------Solvent-free systems 1 ------containing Silicone 1 1 1 ------aqueous systems; good compatibility properties aqueous systems;goodcompatibility Strong slipandanti-blockingadditivefor good recoatability additivewith andanti-crater excellent substrate surface tensioninaqueousformulations; monomethyl etherwithstrongreductionof glycol Silicone surfactantindipropylene sissing and has pronounced effect onleveling sissing andhaspronouncedeffect problem solverinwater-based systems, against wetting,substrate leveling, andanti-cratering; excellent Fluorocarbon-modified polyacrylate; surface tension foaming andlow properties;low emulsification withexcellentwettingand formulations aqueous for Non-ionic wettingagent adhesion stabilization,foam onintercoat andeffects likecratering, sideeffects avoids wetting agent; Excellent surface-levelingandsubstrate- standard productusedinoverprintvarnishes strong reductionofdynamicsurfacetension; agent; wetting efficientsulfosuccinate Highly wetting excellent substrate aqueous formulations; for wetting agent low-foaming Non-volatile surface tension excellentreductionofdynamic formulations; aqueous for wettingagent Low-foaming good recoatability additivewith andanti-crater excellent substrate surface tensioninaqueousformulations; Silicone surfactantwithstrongreductionof characteristics; excellent anti-cratering additive characteristics; excellentanti-cratering withpronounceddefoaming formulations aqueous for Non-ionic wettingagent agent for water-based for agent coatings effective,Highly low-foaming, substrate-wetting Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 1 1 1 1 - - Formulation additives Industrial 1 1 1 1 1 1 1 1 1 1 - and flooring Furniture 1 1 1 1 1 1 1 1 1 1 1 123

Formulation additives 124 Efka Flow andlevelingagents Product name Efka Efka Efka Efka and surfacemodifiers The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® FL3778 FL3777 FL3772 FL3741 FL3740 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® wettingagents Fluorinated polyacrylates Fluorinated polyacrylates Fluorinated Copolyacrylates Copolyacrylates Copolyacrylates Description Dosage [%] 0.5–2.0 0.5–2.0 0.5–2.0 0.2–1.0 0.2–1.0 Solids [%] > 95 > 95 70 70 60 VOC content[%] < 0.5 < 0.5 30 30 40 Recommended for low-VOC systems* 1 1 - - - Water-based systems 1 - - - - Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 1 1 1 1 Solvent-free systems 1 1 1 - - containing Silicone - - - - - and solvent-basedsystems canbeusedinbothwater-and anti-cratering; leveling Fluorocarbon-modified polyacrylate; wetting, andleveling oflowfoam,excellent combination substrate coil coatings, OEM, andindustrialcoatings; solvent-basedsystems, polymer; Acrylic compatibility withair-releaseagent properties;excellent Silicone- andsolvent-freeflowleveling aqueous coatings withair-releaseagent non- propertiesfor Silicone- andsolvent-freeflowleveling low foam, wetting, substrate andleveling of excellentcombination industrial coatings; based systems, coilcoatings, OEM, and solvent- Fluorocarbon-modified polyacrylate; Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 - - Formulation additives Industrial 1 1 1 1 - and flooring Furniture 1 1 - - - 125

Formulation additives 126 Efka Efka Efka Efka Efka Slip andlevelingagents Product name Efka Efka Efka Efka Efka Efka and surfacemodifiers The datain theproduct selectortable isafirst recommendation. Suitabilityofaproduct should alwaysbechecked intheactualpaint, coating,orink. Product maycompriseminortracesasubiquitously occurringimpuritiescannotbeexcluded. All products complywithAPEO-free claims.APEOhasnotbeenintentionally added. Efka ® ® ® ® ® ® ® ® ® ® ® SL3883 SL3299 SL3258 SL3239 SL3236 SL3210 SL3035 SL3034 SL3033 SL3031 SL3030 We create chemistrythatmakescoatingsloveresins andadditives Formulation additives ® wettingagents Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Modified polysiloxanes Reactive polysiloxanes Description Dosage [%] 0.05–3.0 0.05–1.0 0.05–0.5 0.04–0.4 0.05–0.2 0.2–1.0 0.1–0.3 0.1–0.5 0.1–1.0 0.1–0.3 0.1–0.3 Solids [%] > 95 100 100 100 100 70 52 15 52 52 52 VOC content[%] < 0.5 < 1 < 1 < 1 < 1 30 48 85 48 48 48 Recommended for low-VOC systems* 1 1 1 1 1 ------Water-based systems 1 1 1 1 1 1 - - - - - Recommended for *  for indoor and outdoor paints and varnishes. Forproductsfor indoorandoutdoor paintsandvarnishes. witha VOClevelabove15%thevalueisbased oncalculationaccording to recipe. Recommended forlow-VOC paintsandcoatingsifVOCcontent <1%.Measurements done according totheEUEcolabel 2014/312/EU Solvent-based systems 1 1 1 1 1 1 1 1 1 1 1 Solvent-free systems 1 1 1 1 1 1 1 - - - - containing Silicone 1 1 1 1 1 1 1 1 1 1 1 unsaturated PEincludingUV-curedunsaturated and water-based coatings, stovingenamels, solvent- modifiedpolysiloxane; Organically and marresistance, compatible very improvedslip modifiedpolysiloxane; Organically substrate wettingandanti-cratering substrate strong Fluorocarbon-modified polysiloxane; including UV-cured based metal, wood, coatings andpaper solvent- modifiedpolysiloxane; Organically plastic, coatings andpaper UV-curingterminal groups; wood, systemsfor withunsaturated Polysiloxane-modified to Efka similar Solvent-free modifiedpolysiloxane; solvent-free floorcoatings based woodfinishes, industrialcoatings, and solvent- Solvent-free modifiedpolysiloxane; coats surface flow, inclear excellentcompatibility improved modifiedpolysiloxane; Organically industrial coatings high-gloss for and surfacesmoothnesseffect strongslip modifiedpolysiloxane; Organically UV systems and non-aqueouscoatings for leveling agent solvent-freeslipadditiveand effective Highly enhancer; economicsolutions Broad spectrumandefficientflowslip properties ® SL 3236 but stronger defoaming SL3236butstrongerdefoaming Features andbenefits We create chemistrythatmakescoatingsloveresins andadditives Automotive 1 1 1 1 1 1 1 - - - - Formulation additives Industrial 1 1 1 1 1 1 1 1 1 - - and flooring Furniture 1 1 1 1 1 1 1 1 1 1 - 127

Formulation additives Bitte Kurzversion des KapiteltitelsPerformance eintragen additives We createWe chemistrycreate chemistry that makes that coatingsmakes coatings love resins love and resins additives and additives129129

Performance additives

Organic coatings and inks with aesthetical, protective, and other functional properties are exposed to a variety of environmental and artificial factors such as solar radiation, humidity, temperature change, microbiological attack, air pollutants, and many more.

In order to assure that coatings will maintain their beautiful appearance, we offer the most comprehensive portfolio of stabilizers and other performance additives: UV absorbers (UVA) and hindered amine light stabilizers (HALS) for effective stabilization against the detrimental effects of light and weathering, as well as phenolic and non-phenolic antioxidants against thermally induced degradation during production, processing, and service life. The product range is completed with optical brighteners. Performance additives Performance additives Performance additives 130 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 131

Your best choice for light stabilizers and other performance additives

UVA (UV absorbers) and HALS (hindered amine light stabilizers) products are available under the brand names Chimassorb®, Tinuvin®, and Lignostab®.

BP UVA based on 2-hydroxy-benzophenone are HALS are mainly derivatives of 2,2,6,6-tetramethyl Tinuvin® DW range Irganox® and Irgafos® mainly used in applications where low to medium piperidine (TMP). They act as radical scavengers and protection is required. inhibit the photo-oxidative degradation of polymers. The Tinuvin® DW range is based on aqueous Irganox® and Irgafos® antioxidants (AO) protect preparations of light stabilizers designed for coatings, plastics, and fibers against thermal BTZ UVA based on 2-(2-hydroxyphenyl)-benzotriazole water-based coatings and inks. degradation during processing, production, and show a broader spectral coverage combined with a service life. Irganox® comprises a complete range of better photopermanence than BP and are used in Tinuvin® blends AO based on sterically hindered phenols or thioethers, various applications such as plastics, textiles, and as well as blends of different AO classes. Irgafos® are coatings. They fulfill medium (industrial / architectural / Tinuvin® 5000 blends are liquids based on synergistic so-called secondary AO process stabilizers based on wood) to high-end (automotive) protection requirements. combinations of UVA and HALS, thereby combining phosphite chemistry. easy handling with excellent compatibility and solubility HPT UVA based on 2-hydroxyphenyl-s-triazine exhibit in most organic solvents, resins, and binder systems. Tinopal® superior photopermanence and heat stability and a higher extinction coefficient compared to BTZ and BP. Lignostab® Tinopal® optical brighteners (fluorescent whitening HPT also show excellent chemical resistance. agents) are designed to brighten coatings or to mask In contrast to BP and BTZ, mono-resorcinyl-triazines Lignostab® are lignin-stabilizing additives for wood yellowing. Tinopal® can also be used as a marker do not interact with certain metal ions (e.g. catalysts pretreatment that engender color retention and where fluorescence is employed to detect film voids or production-related impurities) or with strong alkali. improved durability. or for registration and identification purposes. HPT is the UVA class of choice for applications involving high baking temperatures and / or extreme environmental conditions. Performance additives Performance additives Performance additives 132 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 133

Background of light and heat stabilization

How UV radiation and heat promote degradation of organic substrates.

Light- or heat-induced oxidation of organic materials Photo-oxidation in the presence of light and oxygen Mechanism of light and / or thermally induced oxidation is a complex radical process involving initiation, is the prevailing mechanism under interior and ambient propagation, chain branching, and autocatalytic conditions. The main consequence is discoloration 1 chain and termination reactions. Both initiation steps of the substrate (i.e. yellowing) or fading of colorants 3 4 h·ѵ R • O generate free radicals (R•) to enter this cyclic process. (e.g. in wall paints or inks). Under exterior weathering CH CH* 2

conditions – water being the decisive factor – • ∆T P-H ROO CH P-H POO • The predominant initiation mechanism under normal photo-oxidation leads to photodegradation resulting 2 P • service life conditions of polymers is light-induced in additional surface defects of the coating including RO • + • OH PO • + • OH oxidation, so-called photo-oxidation. The initiation loss of gloss, cracking, chalking, etc. 6 reaction is photolysis whereby a chromophore ROOH 5 P-H POOH CH (= UV-absorbing molecule or moiety) absorbs Heat exposure such as that encountered during radiation energy (h•ѵ). The absorbed energy leads to processing steps like synthesis, mixing, extrusion, the formation of an excited state CH* (higher energy curing, or during the high-temperature-baking CH = chromophore = UV-absorbing molecule R• = free radicals P-H = polymer level). CH* molecules are highly reactive and can cycles of coatings is the main cause of yellowing, subsequently form free radicals (R•) through hemolytic embrittlement, or loss of other mechanical properties bond cleavage . Under high temperature conditions such as tensile strength in organic substrates. In order heat can accelerate the oxidation – so-called thermal to protect organic substrates against harmful UV Overview of existing light and heat stabilizer technologies oxidation – through radical breakdown reactions radiation and subsequent photo-oxidation followed and initiate the formation of free radicals (R•). This by photo-degradation, the use of appropriate light Mode of Usage Protects Protects Product class Prevents Chemical classes heat-induced initiation step can occur during high- stabilizers such as UV absorbers (UVA) and free-radical action area what? against temperature processing, production, and service life. scavengers such as hindered amine light stabilizers (HALS) is necessary. UV absorbers filter out harmful Deeper Photo- UV coating Yellowing, 2-hydroxyphenyl-benzophenones (BP), The free radicals (R•) generated during photo- and UV light, thereby protecting the resin, the substrate Converts UV Interior / oxidation absorbers layers, blistering, 2-(2-hydroxyphenyl)-benzotriazoles (BTZ), thermal oxidation can subsequently react with oxygen underneath, and the colorants in coatings and inks light into heat exterior and (UVA) substrate loss of adhesion 2-hydroxyphenyl-s-triazines (HPT) 4 against color changes. HALS trap free radicals once degradation (O2) to form peroxy radicals (ROO•) , which can underneath further attack the polymer (P-H) whereby unstable they are formed and are effective in preventing surface hydroperoxides (ROOH) 5 are formed. These defects such as loss of gloss, cracking, and chalking. Surface defects, loss hydroperoxides fragment due to UV radiation and / While HALS are, technically speaking, a distinct class Coating Hindered amine of mechanical or heat and form additional free radicals 6 . As the of antioxidant or free-radical scavenger, the term Deactivation Photo- surface, light stabilizers Exterior properties, loss Tetramethyl piperidine derivatives of free radicals degradation pigments process continues, more and more molecular bonds antioxidant or AO generally refers to additives that are (HALS) of water in coatings break – a process that is autocatalytic in nature and primarily used as heat stabilizers. Today, the most Radical impermeability, is known as autoxidation. commonly used AOs are based on sterically hindered scavengers pigment fading phenol, thioether, or phosphite chemistries. Yellowing, Sterically hindered phenols, Deactivation Interior / Thermal embrittlement, Antioxidants Coating phosphites, of free radicals exterior oxidation loss of mechanical thioethers properties Performance additives Performance additives Performance additives 134 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 135

UV absorbers

Tinuvin® and Chimassorb® UV absorbers (UVA) prevent the degradation of both The required concentration of UVA Mode of action of 2-(2-hydroxyphenyl)- coatings and substrates by filtering out harmful UV radiation during the photolysis for effective protection depends on benzotriazole (BTZ) and the dry film thickness of the coating 2-hydroxyphenyl-s-triazine (HPT) UV cycle before subsequent photo-oxidation can take place. and the absorption coefficient of the absorbers choosen UVA

UVA concentration based on Dry film thickness binder solids (% w/w) 1 2 HO R1 H-O- R1 Today, 2-hydroxyphenyl-benzophenones (BP), According to the Lambert Beer law, the absorbance A, + 2-(2-hydroxyphenyl)-benzotriazoles (BTZ), and i.e. the filter effect of a coating, is in linear relationship N h·ѵ N 10–20 µm 8–4 BTZ N N ΔT 2-hydroxyphenyl-s-triazines (HPT) are the most widely to the UVA concentration (c), the film thickness (= light R3 N R3 N R2 R2 used UVA for coatings and inks. UV absorbers work by path length d), and the extinction coefficientε . Thus R1 R1 converting absorbed light energy (h•ѵ) into heat. First the Lambert Beer law allows the amount of UVA the UVA chromophore CH absorbs radiation energy needed for proper light protection to be calculated for 20–40 µm 4–2 - HO O (h ) and becomes an energy-enriched excited-state a given film thickness d. Increased c or d results in HPT h·ѵ + •ѵ 2 2 H R N N R R2 N N R2 CH*, which causes an electronic rearrangement, e.g. increased filter effect and therefore increased protection ΔT N a reversible intramolecular proton transfer. The CH* against harmful UV radiation. In addition, the law also N 40–80 µm 2–1 3 3 is then deactivated by a radiationless release of heat infers that the filter effect is strongly influenced by R R R3 R3 energy (ΔT) and reverts to its original form (ground coating thickness; the thinner the coating, the more state). UVA are necessary. Hence UVA on their own are insufficient for protecting the surface of a coating itself The main criteria for selecting UVA are their specific (where thickness d approaches 0). It follows, then, that General structures of 2-hydroxyphenyl-benzophenone (BP), 2-(2-hydroxyphenyl)- photo-physical (primary) and physical (secondary) UVA cannot effectively prevent the formation of surface benzotriazole (BTZ), and 2-hydroxyphenyl-s-triazine (HPT) UV absorbers properties. Photo-physical properties of UVA are defects resulting from photo-degradation under exterior absorbance A (= measure of the filter effect of a UVA conditions. For exterior conditions the combination of at a certain wavelength) and the extinction coefficient UVA and HALS creates synergistic effects producing R1 ε, which is a molecule-specific constant that indicates excellent protection against surface defects and H O O HO R1 the efficiency of the filter effect of a chromophore. The discoloration. For interior conditions, the use of UVA HO N 2 2 absorbance A is a direct measure of the filter effect and alone is normally sufficient for preventing both the N R N N R is in inverse logarithmic relation to the transmittance T colorant fading of coatings and inks as well as the R1 R3 N N R2 (= amount of light penetrating through a coating / yellowing of resins. R3 R3 plastic). The absorbance A and the transmittance T ​ BP BTZ HPT of UVA depend both on the chemical class and the Photo-permanence (i.e. physical / chemical loss of UVA molecular weight. The UV absorption spectra of during service life) and heat stability (i.e. low volatility) Tinuvin® UV absorbers and of blends thereof, as well are basic requirements for UVA efficacy in the final of the Chimassorb® UVA are shown on pages application. 140 / 141. Lambert Beer law

Transmittance T decreases exponentially, absorbance A increases directly proportional to 1

§§ Chromophore concentration c T §§ Light path length or film thickness d

§§ Extinction coefficientε Performance additives Performance additives Performance additives 136 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 137

UV-VIS absorbance spectra of UV absorbers

2-(2-hydroxyphenyl)-benzotriazole (BTZ) 2-hydroxyphenyl-s-triazine (HPT)

1.50 2.5 Spectra were recorded with 1.0 Spectra were recorded with 20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm 1.25 Spectra were recorded with 20 mg/l in toluene, path = 1 cm 1.6 2.0 0.8 Spectra were recorded with 1.00 20 mg/l in toluene, path = 1 cm 1.2 1.5 0.6 0.75

0.8 1.0 0.4 0.50 Absorbance [AU] Absorbance [AU] Absorbance [AU] Absorbance [AU]

0.4 0.5 0.25 0.2

0 0 0 0 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430 Wavelength [nm] Wavelength [nm] Wavelength [nm] Wavelength [nm]

Tinuvin® 326 Tinuvin® Carboprotect® Tinuvin® 900 Tinuvin® 384-2 Tinuvin® 928 Tinuvin® 400 Tinuvin® 405 Tinuvin® 460 Tinuvin® 477 Tinuvin® 479

2-hydroxy-benzophenone (BP) 2-(2-hydroxyphenyl)-benzotriazole (BTZ) Tinuvin® 5000 series

1.0 1.0 1.5 1.5 Spectra were recorded with Spectra were recorded with Spectra were recorded with Spectra were recorded with 20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm 1.25 0.8 0.8 1.25

1.0 1.0 0.6 0.6

0.75 0.75

0.4 0.4 Absorbance [AU] 0.5 Absorbance [AU] 0.5 Absorbance [AU] Absorbance [AU]

0.2 0.2 0.25 0.25

0 0 0 0 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430 280 300 320 340 360 380 400 Wavelength [nm] Wavelength [nm] Wavelength [nm] Wavelength [nm]

® ® ® Chimassorb® 81 Tinuvin® 171 Tinuvin® 99-2 Tinuvin® 1130 Tinuvin® 5248 Tinuvin® 5251 Tinuvin 5050 Tinuvin 5060 Tinuvin 5151 Performance additives Performance additives Performance additives 138 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 139

Tinuvin® DW (N) Optical brighteners

The Tinuvin® DW (N) range is based on aqueous preparations of light stabilizers Tinopal® fluorescent optical brighteners (OB) are designed to brighten or enhance designed for all water-based applications. Based on novel encapsulated additive the appearance of coatings, adhesives, and sealants by producing a perceived technology (NEAT), Tinuvin® DW (N) has low viscosity, is solvent-free, storage- and “whitening” effect and also serve to mask yellowing. sedimentation-stable, and has no EUH 208 label. 1.00 Tinopal® NFW Liquid

0.80 Tinuvin® DW (N) comprises a range of selected BTZ This allows to add them at the end of the production Tinopal® and HPT UVA as well as HALS preparations. These process under normal stirring conditions without 0.60 light stabilizer preparations are based on a proprietary specific equipment and / or dispersing aids, e.g. Tinopal® can also be used where fluorescence can

encapsulation technique where active agents are emulsifiers or cosolvent. provide a mean to determine film thickness, and Rel. intensity 0.40 essentially dissolved in an acrylic copolymer matrix. After being incorporated into the liquid paint they for registration and identification purposes, e.g. The NEAT-based preparations exhibit excellent do not impair paint properties and storage stability. in adhesives and sealants as a fluorescent tracer 0.20 long-term storage stability without any sedimentation The Tinuvin® DW (N) range fully maintains dry film in in-line assurance inspections. OB are dyes that

or phase separation in their delivery form. The absence properties such as inherent color, gloss, and trans­ work by re-emitting light through the mechanism 0 of EUH 208 label and of co-solvents make them the parency. Other properties such as water permeability of fluorescence. They absorb light in the ultraviolet 275 325 375 425 475 525 575 625 ideal choice for low to zero VOC applications. They are and blocking resistance, hardness, and scratch region of the electromagnetic spectrum (usually Wavelength [nm] easy to incorporate and homogeneously disperse into resistance are not affected. 340–370 nm), and emit light in the blue region Fluorescence min / max Absorption min / max 1.00 water and / or water-based paints. (typically 420–470 nm). Tinopal® OB CO

The Tinopal® range is available in a powder form that 0.80 is soluble in solvent or water and as a solution for direct use in various applications. Due to the limited 0.60 ® photostability of optical brighteners, which can result

Tinuvin 5000 series in yellowish degradation products, their use for Rel. intensity 0.40 exterior applications is not recommended.

0.20 The Tinuvin® 5000 series and other Tinuvin® blends offer synergistic combinations 1.00 0 Tinopal® SFP of UVA and HALS against surface defects while also maintaining color and gloss 275 325 375 425 475 525 575 625 Wavelength [nm] retention in coating applications. 0.80 Fluorescence min / max Absorption min / max

1.00 Tinopal® SFP 0.60 The Tinuvin® 5000 series is attractive for its combination them particularly suitable for coatings exposed to high 0.80 of easy handling with its excellent compatibility and baking temperatures and / or extreme environmental

Rel. intensity 0.40 solubility in most solvent-based coating systems. conditions. Furthermore, they are not sensitive 0.60 The Tinuvin® 5000 family matches all performance to high pH and certain metal ions, i.e. there is no

requirements for architectural, industrial, and formation of colored complexes. Blends containing 0.20 Rel. intensity 0.40 automotive applications. The broad UV absorbance N-OR HALS are especially suitable for oxidative curing

of BTZ-based blends makes them suitable for a and acid-catalyzed systems. The non-basic character 0.20 0 wide range of coatings on wood, plastic, and metal prevents potential interactions with acidic paint 275 325 375 425 475 525 575 625 substrates. HPT-based blends show high thermal ingredients such as catalysts, biocides, and pigments. Wavelength [nm] 0 stability and superior photopermanence, which makes 275 325 375 425 475 525 575 625 Fluorescence min / max Absorption min / max Wavelength [nm]

Fluorescence min / max Absorption min / max Performance additives Performance additives Performance additives 140 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 141

Hindered Amine Light Stabilizers (HALS)

Typical HALS structures Influence of HALS basicity vs. Hindered amine light stabilizers (HALS) are mainly derivatives of 2,2,6,6-tetramethyl N-substituent piperidine (TMP). They act as radical scavengers in the autoxidation cycle and inhibit the photo-oxidative degradation of polymers. R N H pk ~ 4–5 Tinuvin® 770 DF R3 b HN

N N R1 N O (CH ) O N R1 R2 2 2 8 N N N R R N CH ® 3 pkb ~ 5–6 Tinuvin 292 The mode of action of HALS is largely independent surfactants, catalysts, or certain acid-treated pigments, O O of the applied film thickness, which in turn means which can result in limited formulation stability that they can also act at the coating surface where or the deactivation of HALS or of other additives. N N R N (CH ) OR pk ~ 7–8 Tinuvin® 622 SF only minor protection is provided by a UVA (see Furthermore, basic HALS can interfere with the R1 R1 2 2 b Lambert Beer law). In clear coats they protect against curing process of acid-catalyzed or oxidation-based A B surface defects such as loss of gloss or cracking, curing systems. Because non-basic N-OR HALS do R N OR pk ~ 8–10 Tinuvin® 123 whereas in pigmented coatings they prevent chalking not interact, they are the products of choice for all b Tinuvin® 152 and discoloration. Such surface defects eventually applications where traditional basic HALS fail. Typical structures of hindered amine light stabilizers (HALS) Tinuvin® 249 lead to substrate erosion due to increased water A: linked by diester; B: linked by triazine ring Tinuvin® 5100 permeability and the loss of physical and protective The usage amount of UVA and HALS strongly properties. Today, a large variety of HALS utilizing depends on the concentration of pigments (acting as mono-, di-, or oligo-functional TMP are available; their UV screeners) and the final thickness of the coating. wide range of physical and chemical properties enable Clear coatings require higher amounts of UVA Denisov cycle them to fulfill the multiple requirements of the coatings (and lower dose levels of HALS) whereas opaque and plastics industries. pigmented coatings require higher amounts of HALS (and lower UVA dose levels). Typical usage amounts • According to the “Denisov cycle” the mode of action are listed in the table below. The usage amount of UVA 1 2 R 3 of HALS is a cyclic regenerative process. In the in pigmented coatings depends on the pigments used. h· , O ѵ 2 • N presence of oxygen (O2) and UV radiation (h•ѵ), the The lightfastness or weather stability of some organic N R N O OR HALS compound is converted into the corresponding pigments can be improved by addition of UVA, nitroxyl radical NO• as an active species that traps free whereas for inorganic pigments the use of UVA can be

RO• radicals through the formation of an aminoether dispensed with. R'OH + R=O R'OO • N-OR structure. N-OR interacts with ROO• forming intermediates, which then decompose into harmless Typical UVA and HALS use levels decomposition products, thereby reforming the active species NO•. The cyclic nature of the stabilization Mode of action of hindered amine light stabilizers (HALS) according to the Denisov cycle process along with the regeneration of the active Pigmentation Active UVA [%]1 Active HALS [%]2 species explains the high and long-term efficiency of HALS. Clear 1–2 1 Besides solubility and compatibility, the first selection criteria for HALS is their basicity. The basicity of HALS is governed by the substitution pattern on the Semi-transparent 1–2 1–2 piperidine nitrogen: H or alkyl-substituted HALS are basic, whereas aminoether-(N-OR)-functionalized HALS are considered as non-basic. Basic HALS Opaque 0–1 1–2 are highly efficient and long-term stable; they can, however, undergo acid / base interactions with certain 1 % active UVA on binder solids (DFT ~ 40 µm) formulation components such as biocides, 2 % active HALS on binder solids (does not depend on DFT) Performance additives Performance additives Performance additives 142 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 143

Antioxidants (AO) AO structures

AO prevent thermally induced oxidation of polymers in coatings during heat exposure, Hindered phenol AO Phosphite AO Thioether AO OH R2 processing, and curing or baking at high temperatures, as well as during their service R2 R1 S(R)2 ® ® R3 O P(R) life. Irganox and Irgafos denote different primary sterically hindered phenolic AO 3-x and secondary thioether or phosphite AO, respectively. R3 R1 x

Mechanism of AO Unlike HALS, AO are a non-regenerative reaction Hindered phenol AO mechanism, which in turn means that both primary and §§ activity over broad temperature range (RT to melt) Hindered phenol AO secondary AO are essentially consumed and rendered ineffective after reaction. Conversely, HALS are usually §§ improve long-term thermal stability OH O• O O O R2 R1 R2 R1 R2 R1 R2 R1 R2 R1 not effective in preventing thermal degradation but do §§ non-regenerative mechanism, consumption during + ROO· + ROO· 3 have the advantage that the regenerative nature of reaction • - ROR R3 3 HALS allows them to function over much longer time R3 R3 R OOR O p-Benzoquinone scales. This makes them well suited as light stabilizers, although some oligo-functional HALS can also Phosphite AO be effective heat stabilizers under long-term and §§ phosphites are processing stabilizers Phosphite AO Thioether AO moderately low heat exposure conditions. §§ stable against hydrolysis R2 R2

Primary AO such as the sterically hindered phenols §§ no colored reaction products 3 3 R O P + ROOH R O P=O + ROH S(R)2 + ROOH (R)2S=O + ROH deactivate free radicals (RO•) formed during thermal 1 oxidation and interrupt breakdown reactions via a R 3 R1 3 kinetic mechanism. Primary AO work by donating Thioether AO hydrogen atoms to preferably oxygen-centered radicals §§ thiosynergists “like it hot” (RO•, ROO•), thereby interrupting the autoxidation Effective use temperatures for the different classes of stabilizers process. Phenolic AO are multipurpose products for §§ rate of ROOH decomposition increases with ΔT a broad temperature range and are mainly used to §§ designed to protect against high-temperature aging Long-term thermal stability (LTTS) Melt processing stability increase the long-term thermal stability of various coatings or plastics.

Oligomeric HALS Hindered amines Secondary phosphite AO decompose peroxides §§ HALS with AO properties (ROOH) formed during the autoxidation process Thiosynergists and extend the performance of primary AO through §§ work up to 120 °C synergistic effects. §§ stable against light, migration, and extraction Today, hydrolytically stable phosphites and divalent §§ regenerative mechanism in contrast to AO Hindered phenols sulfur compounds are the most widely used secondary AO. Applications include heat stabilization during Phosphites synthesis, processing, mixing, extrusion, and curing of coatings that are baked or cured at relatively high temperatures (e.g. coil coatings and powder coatings). 0 50 100 150 200 250 300 °C

Solid Melt Performance additives Performance additives Performance additives 144 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 145

Tinuvin® UV absorbers for water-based and solvent-based coatings

Molecular Automotive and Furniture Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications weight [g/mol] transportation and flooring Water-based UV absorbers

Tinuvin® 400-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 1 1 Blue-shifted UVA for water-based high-performance applications, excellent spectral coverage in combination with Tinuvin® 479-DW

Tinuvin® 477-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture - 1 1 1 Red-shifted UVA for high-performance water-based wood coatings

UVA with extremely high extinction coefficient, for highest durability requirements in water-based clear coats, specifically suited for thin Tinuvin® 479-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 - 1 film applications

Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)

Tinuvin® 9945-DW (N) Benzotriazole Liquid 45% active - Mixture - 1 1 1 Multipurpose UVA for medium to high durability requirements for water-based formulations Solvent-based UV absorbers

Benzophenone (BP) Chimassorb® 81 (ED) Benzophenone Solid 47–51 326 - 1 1 1 UVA for moderate durability requirements; mass stabilization of gel coats Benzotriazole (BTZ) Tinuvin® 99-2 Benzotriazole Liquid 95% in MPA** - 452 - 1 1 1 UVA for medium-performance solvent-based coatings

Tinuvin® 326 Benzotriazole Solid 138–142 316 - 1 1 1 Chlorinated red-shifted UVA, allows < 1% transmittance up to 370 nm; limited solubility in organic solvents

Tinuvin® 384-2 Benzotriazole Liquid 95% in MPA** - 452 1 1 - - Multipurpose UVA for medium to high durability requirements, minimum color impact in refinish clear coat applications

Tinuvin® 900 Benzotriazole Solid 138–142 448 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, limited solubility in organic solvents

Tinuvin® 928 Benzotriazole Solid 109–113 442 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, excellent solubility in organic solvents

Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)

Very red-shifted UVA for protection of aromatic epoxy systems, especially recommended for carbon or glass fiber reinforced composites; Tinuvin® Carboprotect® Benzotriazole Solid 132–136 560 1 1 - - allows < 1% transmittance up to 420 nm Tris-ResorcinylTriazine (TRT), high photo- and thermal-permanence Tinuvin® 460 Tris-Resorcinyltriazine Solid 97–101 630 - 1 - - Red-shifted UVA with extremely high extinction coefficient, allows ~ 1% transmittance up to 370 nm, limited solubility in organic solvents

Tinuvin® 477 Tris-Resorcinyltriazine Liquid 80% in MPA** - Mixture - 1 1 1 Red-shifted UVA with high extinction coefficient, for high durability wood coating requirements, allows < 1% transmittance up to 370 nm HydroxyPhenylTriazine (HPT), best photo- and thermal-permanence, no interaction with amines, strong alkali, or any metal catalysts Liquid 85% in Blue-shifted UVA for high durability requirements in clear coat applications including UV-curing systems, excellent spectral coverage in Tinuvin® 400 Hydroxyphenyltriazine - 647 1 1 1 1 1-methoxypropan-2-ol combination with Tinuvin® 479

Tinuvin® 405 Hydroxyphenyltriazine Solid 73–77 584 1 1 - - Blue-shifted UVA for high durability requirements in powder clear coats, excellent spectral coverage in combination with Tinuvin® 479

UVA with extremely high extinction coefficient, for highest durability requirements in clear coats, powder coatings, or UV-curing systems, Tinuvin® 479 Hydroxyphenyltriazine Solid 39–43* 678 1 1 1 1 specifically suited for thin film applications

* Tg [°C] ** 1-methoxy-2-propyl acetate Performance additives Performance additives Performance additives 146 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 147

Tinuvin® HALS for water-based and solvent-based coatings

Molecular Automotive and Furniture Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications weight [g/mol] transportation and flooring Non-basic HALS for water-based coatings

Tinuvin® 123-DW (N) N-OR HALS Liquid 30% active - - 1 1 1 1 Non-basic HALS for waterborne formulations, no interaction with sensitive dispersions Basic HALS for water-based coatings

Multipurpose basic HALS for various applications, use in water-based coatings may require addition of cosolvents, may interact with Tinuvin® 292 N-alkyl HALS Liquid - 509 / 370 1 1 1 1 sensitive dispersion binders

Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - - cosolvents, may interact with sensitive dispersion binders Basic HALS for solvent-based coatings

Tinuvin® 111 FDL N-alkyl / N-R HALS Solid - - - 1 - - HALS blend for powder-coating applications with triboelectric charging activity

Multipurpose basic HALS for various applications, use in water-based coatings may require addition of cosolvents, may interact with Tinuvin® 292 N-alkyl HALS Liquid - 509 / 370 1 1 1 1 sensitive dispersion binders

Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - - cosolvents, may interact with sensitive dispersion binders

Tinuvin® 770 DF (ED) N-H HALS Solid 81–85 480 - 1 - - HALS suitable for powder-coating applications Non-basic HALS for solvent-based coatings

Tinuvin® 123 N-OR HALS Liquid - 737 1 1 1 - Non-basic HALS for acid-catalyzed and oxidative curing coatings, improves yellowing resistance in direct-fired gas ovens

Tinuvin® 152 N-OR HALS Solid 72–76 757 1 1 - - Non-migrating, reactable low basic HALS for polar solvent-based coatings over plastic substrates (e.g. polycarbonate, ABS substrate)

Non-basic HALS, no exudation from solvent-based polar coatings, low viscosity and very low inherent color; use in water-based coatings Tinuvin® 249 Non-basic HALS Liquid - 482 1 1 1 - may require addition of cosolvents

Tinuvin® 622 SF Oligomeric N-R HALS Solid - 3,100–4,000 - 1 - - Low-basic HALS for powder-coating applications with very good antioxidant properties, limited solubility in organic solvents

Tinuvin® 5100 N-OR HALS Liquid - 737 - 1 1 1 Non-basic HALS for oxidative curing coatings

Molecular Automotive and Furniture Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications weight [g/mol] transportation and flooring HALS for wood color protection

Lignostab® 1198 Lignin stabilizer Solid 66–70 172 - - 1 1 Lignin stabilizer for wood impregnation

Lignostab® 1198 L Lignin stabilizer Liquid 20% in water - 172 - - 1 1 Lignin stabilizer solution for wood impregnation Performance additives Performance additives Performance additives 148 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 149

Tinuvin® light stabilizer blends

Molecular Automotive and Furniture Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications weight [g/mol] transportation and flooring Light stabilizer blends

Tinuvin® 111 FDL N-alkyl / N-R HALS Solid - - - 1 - - HALS blend for powder-coating applications with triboelectric charging activity

Tinuvin® 5050 BTZ / N-alkyl HALS Liquid - Mixture - 1 1 1 UVA / HALS blend for solvent-based applications

Tinuvin® 5060 BTZ / N-OR HALS Liquid - Mixture - 1 1 1 UVA / non-basic HALS blend for solvent-based oxidative curing coatings

Tinuvin® 5151 BTZ / N-alkyl HALS Liquid - Mixture 1 1 1 1 UVA / HALS blend for solvent-based coatings, use in water-based coatings may require addition of cosolvent

Tinuvin® 5248 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications

Tinuvin® 5251 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications

Tinuvin® 5333-DW (N) UVA / HALS Liquid 40% active - - - 1 1 1 High-performance UVA / non-basic HALS blend for water-based applications with broad spectral coverage

Tinuvin® B 75 (ED) AO / N-alkyl HALS / UVA Liquid - Mixture - - 1 - Stabilizer blend for furniture and flooring applications Performance additives Performance additives Performance additives 150 We create chemistry that makes coatings love resins and additives We create chemistry that makes coatings love resins and additives 151

Irgafos® and Irganox® antioxidants and Tinopal® optical brighteners

Molecular Automotive and Furniture and Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications weight [g/mol] transportation flooring Hindered phenolic (primary antioxidants)

Irganox® 245 (ED) Phenol Solid 76–79 587 1 1 - - AO for solvent-based and powder-coating applications

Irganox® 245-DW Phenol Liquid 40% active - 587 - 1 - - AO for water-based coating applications

Irganox® 1010 (ED) Phenol Solid 110–125 1,178 1 1 - - AO for solvent-based and powder-coating applications, not to be used in direct fired gas ovens

Irganox® 1035 Phenol Solid 63–78 643 - 1 - - AO for solvent-based coating applications

Irganox® 1076 (ED) Phenol Solid 50–55 531 1 1 - - AO for solvent-based and powder-coating applications

Irganox® 1135 Phenol Liquid - 390 1 1 - - AO for all solvent-based applications

Irganox® 1425 Calcium phosphonate Solid > 260 695 - 1 - - Stabilizer for synthesis of polyester resins Phosphite (secondary antioxidants)

Irgafos® 126 (ED) Phosphite Solid 160–175 604 1 1 - - AO for solvent-based and powder-coating applications, prevents yellowing in direct gas fired ovens

Irgafos® 168 (ED) Phosphite Solid 183–186 647 1 1 - - AO for solvent-based and powder-coating applications, prevents yellowing in direct gas fired ovens Thioether (secondary antioxidant)

Irganox® PS 802 Thioether Solid 50–55 683 - 1 - - Thiosynergist suitable when high-temperature aging is required, needs combination with primary AO Antioxidant blends

Irganox® B 225 (ED) Phenol / phosphite Solid > 100 - - 1 - - AO blend for powder-coating applications

Irganox® B 900 Phenol / phosphite Solid 59–61 - 1 1 - - AO blend for powder-coating applications Optical brighteners

Tinopal® NFW LIQ Biphenyl-stilbene Liquid 20% active - 563 - 1 - 1 Liquid optical brightener for water-based white and pastel-tone paints, clear coats, overprint varnishes

Tinopal® OB CO Benzoxazole Solid 196–203 431 - 1 - 1 Solid optical brightener for solvent-based white and pastel-tone paints, clear coats, overprint varnishes

Tinopal® SFP Triazine-stilbene Solid - 1,305 - 1 - 1 Water-soluble optical brightener for photographic color developer baths or as fluorescent tracers Performance additives ContactsContact WorldwideEurope, Africa, West Asia

AsiaBASF Nederland B.V. North America Resins & Additives BASF (China) Co., Ltd. BASF Corporation No.Innovatielaan 300, Jiangxinsha 1 Road, 24710 West Eleven Mile Road Pudong,8466 SN ShanghaiNijehaske 200137 Southfield, Mi 48034 P.R.P.O. ChinaBox 390 USA 8440 AJ Heerenveen Phone:The Netherlands +86-21-2039-5213 US and Canada: [email protected] Phone: +1-800-231-7868 Tel.: +31 51 3619-619 [email protected] Fax: +31 51 3619-600 Mexico: [email protected] Phone: +52-55-5325-2600 [email protected]

Europe, Africa, West Asia South America

BASF SE BASF S.A. Resins & Additives Av. das Nações Unidas 14171, E-EDE/R – J550 Cond. Rochavera 67056 Ludwigshafen T. Crystal Germany 04794-000 São Paulo, SP Brazil [email protected] Phone: +55-11-2039-2735-2735

BASF SE

67056 Ludwigshafen Germany www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed.

® = Registered trademark of the BASF Group ® = registered trademark of the BASF Group Res022019PSG EDC 0115e