有限公司 Inorganic Fluorides
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Safety Data Sheet Modified: 2016-02-12 1: Identification of Substance / Mixture 1
According to Regulation (EC) No. 1272/2008 Revision: 1.06 Language : English Safety Data Sheet Modified: 2016-02-12 1: Identification of substance / mixture 1. Product Identifier Substance Product Name Silver hexafluorophosphate Product Code 002864 CAS Number 26042-63-7 Other Names IUPAC MFCD Number MFCD00003415 EC/EINECS 247-428-6 REACH Number 2. Relevant identified uses of the substance or mixture and uses advised against Research and Development 3. Details of the supplier of the safety data sheet Fluorochem Ltd Unit 14,Graphite Way Hadfield Derbyshire Telephone: +44(0)1457 860111 SK13 1QH Fax: +44(0)1457 892799 UK Email: [email protected] 4. Emergency telephone number +44(0)7855 268577 - 2. Hazards Identification 1. Classification of the substance or mixture H314 Skin Corr. 1B R34, R23/34/35 H318 Eye Dam. 1 R41 H400 Aquatic Acute 1 R50, R50/53 No Resource File 2. Label elements Signal Word Danger Hazard Statements H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H400 Very toxic to aquatic life. Precautionary Phrases P273 Avoid release to the environment. P301 + P330 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. + P331 P303 + P361 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with + P353 water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and + P338 easy to do. Continue rinsing. P501 Dispose of contents/container to local regulations 3. -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
Acutely / Extremely Hazardous Waste List
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extemely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extemely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extemely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extemely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extemely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extemely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extemely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extemely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extemely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
Potassium Hydrogen Difluoride Product Information Cas № 7789-29
POTASSIUM HYDROGEN DIFLUORIDE PRODUCT INFORMATION CAS № 7789-29 POTASSIUM HYDROGEN DIFLUORIDE A TOXIC SUBSTANCE. Fire- and explosion-safe. Hygroscopic. Please refer to manufacturer’s SDS for further information POTASSIUM HYDROGEN DIFLUORIDE CAS № 7789-29-9 APPLICATIONS: PACKAGING: NUCLEAR INDUSTRY Polyethylene bags AIRCRAFT ENGINES inserted in convolute drums. FLUORINE CHEMISTRY Net weight 35 Kg. FERROUS AND NON- FERROUS METALLURGY Guaranteed shelf-life GLASS INDUSTRY 3 years following the date of manufacture provided that the storage Technology: reaction of an excess of concentrated hydrofluoric acid with conditions are met. concemtrated solution of potassium hydroxide KOH + 2 HF 2 KHF2 + CO2 ELEMENT Standard COMPONENT Standard as per (GOST 10067-80) TU 95-183-90 LU Mass fraction of potassium bifluoride (KF•HF), % 98-102 Mass fraction of hydrogen fluoride, %, within 25.0-26.0 the range of Mass fraction of clorides (Cl), %, max. 0,005 Mass fraction of silicon (Si), %, max. 0.1 Mass fraction of sulfates (SO4), %, max. 0,01 Mass fraction of sulfates (SO4), %, max. 0.1 Mass fraction of iron (Fe), %, max. 0,001 Mass fraction of iron (Fe), %, max. 0.10 Mass fraction of silicon (Si), %, max. 0,01 Mass fraction of insoluble sediment, %, max. 0.5 Mass fraction of lead, copper and manganese 0,001 (Pb+Cu+Mn), %, max. Appearance: white or grey powder. Lumps of various forms and sizes in the powder are acceptable. Manufactured in accordance with GOST 10067-80 “Potassium Hydrogen Difluoride” or TU 95-183-90 LU Production capacity: up to 180 tpa AECC is a ROSATOM Fuel Company «TVEL» Enterprise The plant is deemed to be one of the most state-of-the-art hi-tech companies of Russia’s nuclear industry with 60-year experience in manufacturing hi-quality products, and it is continuously expanding its presence on the domestic and international markets. -
United States Patent Office Patented June 15, 1971
3,584,999 United States Patent Office Patented June 15, 1971 Alternatively, the POF may be pumped into a reactor 3,584,999 containing the hydrogen fluoride and the reaction carried MANUFACTURE OF PHOSPHORUS out at 10-100° C. or higher. PENTAFLUORIDE Robert A. Wiesboeck, Atlanta, Ga., assignor to United The mole ratio of the reactants is not critical; however, States Steel Corporation, Pittsburgh, Pa. best results were obtained when 2-4 (preferably 3) moles No Drawing. Filed Jan. 16, 1968, Ser. No. 698,128 of hydrogen fluoride are employed per mole of phos Int, C. C01b. 25/10 phoryl fluoride. U.S. C. 23-205 10 Claims Approximately one-half of the POF is converted to PFs of high purity. If the product is removed from the O reactor at temperatures above 20° C., some hydrogen. ABSTRACT OF THE DISCLOSURE fluoride and a trace of phosphoryl fluoride are also ob Phosphoryl fluoride is reacted with hydrogen fluoride tained. These impurities can be separated by fractional to form phosphorus pentafluoride and hexafluorophos condensation at -40° C. phoric acid, and the hexafluorophosphoric acid may be The remaining liquid phase of the reaction mixture is reacted with sulfur trioxide, pyrosulfuric acid or fluoro essentially 60-65 percent hexafluorophosphoric acid. The sulfonic acid to form additional phosphorus pentafluoride. yield of phosphorus pentafluoride can be increased by The hexafluorophosphoric acid from any source may be reaction of the remaining liquid with sulfur trioxide, as reacted with the sulfur trioxide and/or pyrosulfuric acid described hereinafter. Total conversion of POF to PFs, to liberate phosphorus pentafluoride. -
XCEL NF Flux, 09-NF-00
JOHNSON MANUFACTURING COMPANY Safety Data Sheet To comply with 29CFR 1910.1200 OSHA's Hazard Communication Standard XCEL NF Flux, 09-NF-00 1. PRODUCT AND COMPANY INFORMATION Johnson Manufacturing Company Emergency Telephone 1-(563)-289-5123 114 Lost Grove Road CHEMTREC AFTER HOURS 1-(800)-424-9300 Princeton IA 52768 Revised 1/1/2021 by JMC Product Safety 2. HAZARD IDENTIFICATION GHS Classification: Acute Tox. 3 Chronic tox 3 Skin corr 3 Eye corr 3 GHS Label Elements: POTASSIUM BIFLUORIDE & BORIC ACID DANGER H Codes: H301, H314, H331, H360 Toxic if swallowed Toxic if inhaled Causes severe skin burns & eye damage May damage fertility or the unborn child P Codes: P264, 270, 201, 202, 281, 308+313, 280, 301+312, 330, 501, 271, 311, $03+233, 302, 352, 308+313, 363, 304+340, 321, 405, Do not breath dust/mist/vapors/fumes/spray. Do not get in eyes, on skin, or on clothing. Use in a well ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation use respiratory protection. Do not eat, drink or smoke when using this product. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Immediately call a POISON CENTER/Doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Wash with soap & water. If skin irritation occurs, get medical advise/attention. IF INHALED: Remove victim to to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/Doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. -
Chemical Names and CAS Numbers Final
Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride -
By T. E. THORPE, F.R.S., and J. W. RODGER
View Article Online / Journal Homepage / Table of Contents for this issue 306 XXX1V.- On Thiophosp hory 1 Fluoride. By T. E. THORPE,F.R.S., and J. W. RODGER,Associate of the Normal School of Science, S. Kensington. INa short paper bearing the above title, published in the Transac- tions of the Society during the summer vacation of last yeir (Trans., 1888, 53, 766), we announced the existence OF a new gaseous sub- stance of the formula PSE',, to which we gave the name of thio- phosphory ZJluoride. The present communication contains the results of the experiments which have served to establish the nature and composition of the new compound. Arsenic trifluoride acts with great violence on phosphorus penta- chloride, wit'h the formation of phosphorus pentafluoride and arsenic trichloride (Thorpe, Proc. Boy. Xoc., 25,122). Phosphorus trichloride mixes with arsenic trifluoride, and on gently warming, the mixture evolves the gaseous phosphorus trifluoride (Moissan, Ann. Chim. Phys. [S], 6,433). The behaviour of thiophosphoryl chloride with arsenic trifluoride is however very different. If amenic trifluoride is dropped into phos- phorus thiochloride in the cold, or if a mixture of the two compouiids is boiled under ordinary pressures, no action takes place. When, however, the mixture is heated in a sealed glass tube at 150", arsenious sulphide separates, and on cooling and opening the tc;be considerable quantities of gas are evolved. The nature of tthe gaseous product varies with the relative proportions of the arsenic fluoride and phosphorus thiochloride. If the reacting substances are heated in the proportions demanded by the equation- Published on 01 January 1889. -
Potassium Bifluoride Material Safety Data Sheet
Potassium Bifluoride Material Safety Data Sheet Chemical: Potassium Bifluoride NFPA: H=3 F=0 I=0 S=None HMIS: H=3 F=0 R=0 PPE= Supplied by user; dependent on conditions MSDS Number: KBF-1103 Effective Date: 14 November 2003 Issued by: Solvay Chemicals, Inc. Regulatory Affairs Department Not valid three years after effective date or after issuance of superseding MSDS, whichever is earlier. French or Spanish translations of this MSDS may be available. Check www.solvaychemicals.us or call Solvay Fluorides, LLC to verify the latest version or translation availability. Material Safety Data Sheets contain country specific regulatory information. Therefore, the MSDS’s provided are for use only by customers of Solvay Fluorides, LLC in North America. If you are located in a country other than Canada, Mexico or the United States, please contact the Solvay Group company in your country for MSDS information applicable to your location. 1. Company and Product Identification 1.1 Product Name: Potassium Bifluoride Chemical Name: Potassium bifluoride Synonyms: Potassium hydrogen fluoride Chemical Formula: KF•HF Molecular Weight: 78 CAS Number: 7789-29-9 EINECS Number: 232-156-2 Grade/Trade Names: None Potassium Bifluoride 1.2 Recommended Uses: Chemical industry; metal treatment; welding and soldering agents; Intermediates 1.3 Supplier: Solvay Fluorides, LLC PO BOX 27328 Houston, TX 77227-7328 3333 Richmond Ave. Houston, Texas 77098 1.4 Emergency Telephone Numbers Emergencies (USA): 1-800-424-9300 (CHEMTREC®) Transportation Emergencies (INTERNATIONAL/MARITIME): 1-703-527-3887 (CHEMTREC®) Transportation Emergencies (CANADA): 1-613-996-6666 (CANUTEC) Transportation Emergencies (MEXICO-SETIQ): 01-800-00-214-00 (MEX. -
Parameters for the Evaluation of the Fate, Transport, and Environmental Impacts of Chemical Agents in Marine Environments July 2007
Parameters for the Evaluation of the Fate, Transport, and Environmental Impacts of Chemical Agents in Marine Environments July 2007 3150 Fairview Park Drive South Falls Church, VA 22042-4519 Tel 703.610.2002 noblis.org 2007 Noblis, Inc. Company Confidential/ Parameters for the Evaluation of the Fate, Transport, and Environmental Impacts of Chemical Agents in Marine Environments July 2007 George O. Bizzigotti, Ph. D. Harry Castelly Ahmed M. Hafez, Ph. D. Wade H. B. Smith, Ph. D. Mark T. Whitmire Abstract 313 references were reviewed to obtain data relevant to the fate, transport, and environmental impacts of chemical agents in marine environments. The review covers the chemical agents phosgene, cyanogen chloride, hydrogen cyanide, sulfur mustard, Lewisite, nitrogen mustard (HN1), Tabun, Sarin, and VX. Parameters covered in the review are boiling point, melting point, density, vapor pressure, solubility, Henry’s Law constant, partition coefficients, dissociation constants, and hydrolysis rate constants and products. Recent ecotoxicity data are also discussed. Data gaps for these parameters and agents are identified and prioritized. In addition to the specific data gaps, the authors have identified several general issues that extend beyond single compounds or types of data. Given the available data and what they suggest will be the dominant fate and transport mechanisms, there are no data gaps that leave one unable to conduct a reasonable assessment for any agent. The primary source of uncertainty in the evaluation of the fate, transport, and environmental impacts of these agents remains the rate at which they are released into the environment. The data gaps identified in this work appear to cause a significantly smaller level of uncertainty. -
Hazardous Waste List (California Code of Regulations, Title 22 Section 66261.126)
Hazardous Waste List (California Code of Regulations, Title 22 Section 66261.126) Appendix X - List of Chemical Names and Common Names for Hazardous Wastes and Hazardous Materials (a) This subdivision sets forth a list of chemicals which create a presumption that a waste is a hazardous waste. If a waste consists of or contains a chemical listed in this subdivision, the waste is presumed to be a hazardous waste Environmental Regulations of CALIFORNIA unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristics which serve as a basis for listing the chemicals are indicated in the list as follows: (X) toxic (C) corrosive (I) ignitable (R) reactive * =Extremely Hazardous A chemical denoted with an asterisk is presumed to be an extremely hazardous waste unless it does not exhibit any of the criteria set forth in section 66261.110 and section 66261.113. Trademark chemical names are indicated by all capital letters. 1. Acetaldehyde (X,I) 2. Acetic acid (X,C,I) 3. Acetone, Propanone (I) 4. *Acetone cyanohydrin (X) 5. Acetonitrile (X,I) 6. *2-Acetylaminofluorene, 2-AAF (X) 7. Acetyl benzoyl peroxide (X,I,R) 8. *Acetyl chloride (X,C,R) 9. Acetyl peroxide (X,I,R) 10. Acridine (X) 11. *Acrolein, Aqualin (X,I) 12. *Acrylonitrile (X,I) 13. *Adiponitrile (X) 14. *Aldrin; 1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4,5,8-endo-exodimethanonaphthlene (X) 15. *Alkyl aluminum chloride (C,I,R) 16. *Alkyl aluminum compounds (C,I,R) 17. -
Topics in Phosphorus-Flij Orine Chemistry
TOPICS IN PHOSPHORUS-FLIJ ORINE CHEMISTRY ProQuest Number: 11011943 All rights reserved INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted. In the unlikely event that the author did not send a com plete manuscript and there are missing pages, these will be noted. Also, if material had to be removed, a note will indicate the deletion. uest ProQuest 11011943 Published by ProQuest LLC(2018). Copyright of the Dissertation is held by the Author. All rights reserved. This work is protected against unauthorized copying under Title 17, United States C ode Microform Edition © ProQuest LLC. ProQuest LLC. 789 East Eisenhower Parkway P.O. Box 1346 Ann Arbor, Ml 48106- 1346 THESIS submitted to the UNIVERSITY OF GLASGOW in fulfilment of the requirements for the DEGREE OF DOCTOR OF PHILOSOPHY *>y JOHN SIDNEY HARMAN B.A. Department of Chemistry, University of Glasgow, GLASGOW August 1970* DEDICATED TO THE PARENTS THAT HAVE TOLERATED ME. “Everything*s got a moral, if only you can find it.11 - Lewis Carroll ACKNOWLEDGEMENTS I am especially grateful to Professor D.W.A. Sharp for his encouragement and advice during the course of this work. My thanks is also expressed to my postgraduate colleagues both past and present, for many informative discussions. I am indebted to Dr. R. Keat for the supply of some starting materials and the prior communication of some of his results. I should also like to acknowledge the assistance of Mary McCartney in obtaining some results as part of her ij-th year project.