□ Introduction □ Geology of the area □ Detailed geology □ Intrusives □ Flow structures □ Quaternary deposits □ Tufas □ Petrography □ Chemistry □ X-ray diffraction

Geology Chapter 2 CHAPTER II

GEOLOGY

Introduction A major part o f the state is covered with plateau basalts - the Deccan flood basalts (DFB). These flood basalts are also known commonly as the Deccan Traps. The Deccan traps are an eruptive sequence of flows which formed during the Cretaceous Tertiary period. They occur as a blanket of sub-horizontal flows over the older rocks and cover an area of over 500,000 sq. kms.

These flood basalts consist dominantly of low K-tholeitic lavas. Though the Deccan Volcanic Province (DVP) is not the largest flood basalt province in the world, it has evinced keen interest. This may be because they were erupted close to or possibly at the Cretaceous Tertiary boundary and also due to the possibilities of mass extinction and meteoric impact around the time of its eruption (Cox, 1988).

16 The total thickness of the Deccan basalts varies from few metres along the eastern fringe areas to over thousands of metres in the west. Krishnan (1968) has recorded 2120 - 3030 mts thick traps in Western Maharashtra, while in northern part of Thane district. Raja Rao (1984) has reported a 2380m thick trap.

Based on the chemical fingerprinting, Cox and Hawkesworth (1985), Beane et al. (1986), Devey and Lightfoot( 1986), Hooper etal. (1988) and others have established a stratigr^hic sequence of the Deccan Basalts of . They have divided the basalt flow sequence into ten different formations, which fall in three subgroups; the subgroup at the base with five formations, the subgroup in the middle with two formations and the topmost Wai subgroup with three formations. They have recognised six Giant phenocryst basalts (GPB’s) in the lower part of the sequence and have used these GPB's as markers. The simplified stratigr^hic sequence after Hooper is given in Table 2.1. Subbarao and Hooper (1988) have prepared a map showing the distribution of the various formations in western Maharashtra.

Ghodke et al. (1985) had proposed a preliminary lithostratigraphy of parts of western Maharashtra. Subsequently, Godbole et al. (1996) have modified the lava stratigraphy for sequence of the Deccan basalt flows of entire western Maharashtra. They have recognised four megacryst marker horizons (Ml - M4) occurring at different stratigraphic levels for and used these for correlation of the flows. The basalt pile consisting of an older sequence of compound flows and a younger sequence of simple flows have been divided into eight formations, which have been included in the North Sahyadri Group. Godbole et al. (1996) have given a map showing the distribution of various formations. The generalised stratigraphic sequence is given in Table 2.2.

17 TABLE 2.1

Generalised Stratigraphic column of the Deccan Volcanic province in Western Ghats based on chemical characteristics ( after Hooper, 1988)

GROUP SUB-GROUP FORMATION MEMBER

Deccan basalts Wai Desur Panhala Ambenali Poladpur Lonavala Bushe Monkey Hill GPB GiravaUi GPB Kalsubai Bhimashankar Manchar GPB Thakurwadi Tunnel -5 GPB Neral KasheleGPB Igatpuri Talghat GPB Jawahar

TABLE 2.2

Generalised Litbostratigraphic succession of the Deccan Volcanic Province in Western Maharashtra ( after Godbole et al, 1996)

SUPERGROUP GROUP SUB-GROUP FORMATION Deccan Traps North Sahyadri Mahableshwar Mahabal^war —M4 ( Marker) Dive Ghat Purandargad Dive Ghat Karla Lonavala Indrayani —M3 (Marker) Kalsubai Upper Ratangarh —M2 (Marker) Lower Ratangarh —Ml (Marker) Salher

18 The lava flows are not horizontal, but exhibit gentle gradients in varied directions. The disposition of the lava flows is important to understand the overall structure. In Nasik, Dhulia & Jalgaon districts the lava flows exhibit north easterly & easterly gradients. In parts of Pune, Ahmednagar, Satara and Kolhapur districts, the flows exhibit southerly and south easterly gradients. In parts of Ratnagiri and Kolhapur district the flows dip towards SW. In the coastal districts of Raigad and Thane and in Bombay, the flows dip steeply to the west.

The basalt lava pile is intruded by dykes at numerous places. Dykes occur as clusters and swarms along two tectonic belts, the West coast and Narmada Tapi lineaments (Deshmukh and Sehgal, 1988). The dyke swarms in the Satpura range and adjoining Dhulia district, trend ENE - WSW, while the dykes in the coastal areas & the Westem districts of Maharashtra trend N - S, NNE - SSW & NNW - SSW. Numerous multiple intrusives of Nepheline-syenite, lamprophyre etc. are reported from the coastal areas near Bombay, Ahbag and Murud-Janjira (Dessai, 1987; Godbole, 1987).

Acid and intermediate differentiates like rhyolites, trachytes, dacites, pitchstone and syenites have been reported from the westem pari: of Maharashtra and Saurashtra. Pyroclastics, welded tuffs and agglomerates have also been reported from the area around Bombay. Olivine rich flows occur near Bhiwandi and Igatpuri.

Intertrappean beds are seen only in the fringe areas. In the eastern part of Deccan Traps a few patches of intertrappean beds are also seen in Malabar hill and Worli hills of Bombay. These beds which contain plant and animal fossils are upto 35 m thick.

' i - 19 V. ; Faults have been reported in Deccan basalts from the northern districts (Dhulia, Jalgaon) and along the coast in Thane district & near Bombay. The Kondaibari fault and Gawilgarh fault in the northern districts exhibit maximum lateral displacement of 200mts and throw to the order of 160mts. In the western part, an arcuate fault runs from south of S^hula upto Bombay, separating a sequence of pahoehoe flows to the east of fault from the volcanic and plutonic rocks exposed to the west. This arcuate fault with a subsidence of 600mts has been recognised as cauldron subsidence (Godbole, 1987). Besides this N - S and NW - SE trending faults have also been inferred along the course of Surya and Vaitama rivers.

The Deccan Basalts are capped by laterite and bauxite in a number of places, especially in the western and southern districts. Alluvial and coUuvial sediments which constitute the Quaternary deposits are found as discontinuous patches mostly restricted to river valleys.

Geology of the Area The area taken for study falls partly in Pune & Ahmednagar districts. The area is predominantly covered by Deccan basalt flows in a 480-500 meter thick lava pile. A very systematic study of the lava flows covering the entire area on a 1:50,000 scale was carried out and a generalised geological map on 1: 250,000 scale was prepared (Fig: 2.1). Besides this detailed studies were carried out in selected localities, like Bote, Gurewadi, Chilewadi, Kotul etc. The studies were aimed at understanding the influence of lithology (type of flow) and structure in the formation of various anomalous geomorphological features.

20

The lava flows in the area have been classified as compound/pahoehoe and simple/ aa flows since they bear resemblance to the Hawaiian types, though they may differ slightly from the ones seen in Hawaii (Walker, 1969). The same terminology is followed by the Geological Survey of . During the present study, the terminology aa, simple and pahoehoe/compound flows was used for identification of flows in the field.

The general characteristics of the aa and pahoehoe flows, on the basis of which the field identification has been done is given below. The aa flows have a fragmented top or a zone of irregular vesicles towards the top of dense basalt. The fragmentary material varies in thickness from hn to a maximum of 5mts and may be absent at places. The fragmentary material consists of angular to subangular blocks ranging in size from a few centimetres to as much as a metre. Size stratification is not generally observed. Fragments are made up mostly of scoraceous basalt, which are often found immediately below the fragmentary layer. Small fragments of zeolites, calcite, and silica occupy the intervening space between the fragments. The top and the bottom of fragmentary layer are undulatory. At a few places, a thin impersistent fragmentary layer termed basal clinker is seen at the base of the flow. This can be distinguished from the fragmentary top of a lower aa flow, only where red bole separates the two flows.

The pahoehoe flows unlike aa flows are constituted of numerous flow units and may also be referred to as compound flows. The individual unit varies in thickness from a few centimetres to as much as 5mts. Occassionally units may even be 10 - 15mts thick. Each small unit has pipe vesicles or amygdules at the base. A reddened and glassy crust envelops the unit tops and separates one unit from the other. Ropy

21 structure, squeeze ups, toes etc. can be seen on the glassy crust of the flow units. The middle of a pahoehoe flow comprises of massive basalt which grades into vesicular, scoraceous and amygdular varieties towards the top.

The pahoehoe flows occur as thin units of limited extent and thickness and therefore several units are grouped into a single compound flow, while the aa flows represent a single volcanic surge (Walker, 1969). The thickness of the individual flows varies from 15-350 mts.

The middle part of the aa flows and pahoehoe flow unit is compact, dark grey to greenish grey, non porphyritic to porphyritic and often jointed. The porphyritic basalts of the area have been classified into highly porphyritic to sparsely porphyritic on the basis of frequency of phenocrysts. Based on the size of the phenocryst they are termed megaphenocryst basalt (2 - 3.5cm long plagioclase laths), coarse phenocryst basalt (1 - 1.5cm long plagioclase laths) medium phenocryst basalt (lesser than 1cm). The mega phenocryst basalt because of its striking megascopic ^pearance has been used as a marker horizon. Such flows have been termed variedly as megacryst flows. (Ghodke et al., 1985; Godbole et al. 1996) and Giant Plagioclase basalts or GPB’s (Beane et al., 1986; Hooper et al., 1988; Bodas, 1985; Thorat and Subbarao, 1996).

The vesicular portion of flows is usually ash grey, purplish to reddish in colour. The vesicles are mostly rounded in pahoehoe flows and irregular and elongated in aa flows. The vesicles may be empty or filled and the fillings are mostly altered glass, zeolite, calcite and silica.

22 Red bole usually occurs as impersistent horizons at the top of flows but may occur even on flow units. It ranges in thickness from 10cm to a maximum of l-1.5mts. Where red bole horizons do not occur at the contact of flows, geomorphic break in slope has been used as criteria along with the change in petrography to separate the flows. To understand their spatial behaviour, the flow contacts were traced laterally at each successive section. Based on this systematic study of distribution of the flows in the entire area, a generalised stratigraphic succession for the area under investigation was prepared. This is shown in Table 2.3.

Twenty flows were identified in the area. Based on their field characteristics these flows were then grouped into four categories. Group I consists of flows 1 to 7, Group II is shown separately and consists of flow number 8. Flows 9 to 18 and 19 to 20 constitute Group III & Group IV respectively. A brief description of each of the four different groiq)s of flows is given below.

Group I The flow numbers 1 to 7 have been grouped together, since they are dominantly pahoehoe in nature with only thin aa and simple flows (flow numbers 4 & 6) which pinch off towards the east. Most of the flows are moderately to sparsely porphyritic varying in thickness from 15-lOOmts. The lower flows are non porphyritic. The flow No. 6 has been termed simple, because at places, it exhibits mixed characters (of both pahoehoe & aa) i.e. pipes at the base and fragmentary material towards the top as seen north of Khamundi.

This flow contains megaphenocrysts of plagioclase, ranging in size from 1.5 - 3.5cm. The thickness of this flow is maximum in the SE part of the area, attaining a maximum

23 TABLE23

STRAHGRAPHICSUCCESSIONOFIAVAFLOWS IN THE AREA STUDIED.

Flow Flow Characters Thickness No. type

20 Aa Topmost flow. Exposed only in the 20 mts. + western and South eastern most part Grey, Sparsely porphyritic, highly jointed a. 3 £ 19 Cph Exposed only in the western and 60mts. South Eastern part. Greenish grey. Highly porphyritic with medium size phenocrysts in medium grained ground mass

18 Aa Dk. Grey, Sparsely to moderately porphyritic. with fine to medium size phenocrysts 15 -40 mts. in a fine grained matrix.

17 Cph Greenish grey. Moderately porphyritic with medium size phenocrysts. Pinches west of 0-25 mts. Kanhur.

16 Aa Grey. Moderately to sparsely porphyritic with 10 -16 mts. phenocrysts in a fine garined ground mass

15 Cph Greenish grey. Mod. porphyritic with medium size phenocrysts. Exposed only in the 0-16 mts. south eastern part of the area.

B 14 Aa Dk. Grey. Mod. porphyritic with medium 15-45 mts. a, a to the size phenocrysts set in fine grained 2 ground mass. Highly jointed with crude O vertical joints.

13 Aa Dk. Grey. Mod. porphyritic with medium 15 -60 mts. size phenocrysts. Crude colimmar joints seen.

12 Cph. Grey. Moderately porphyritic medium grained. 0-35 mts. Pinches in hill section. 903 & south South west of Kaijule Harye in upgradient direction. Thickness increases in the east.

11 Aa Dk. grey. Mod. porphyritic with coarse size 0-40 mts. phenocrysts. Bouldery outcrop. Pinches east of Takli

24 Flow Flow Characters Thickness No. type

10 Aa Dk. Grey. Moderately porphyritic coarse size phenocryst. Bouldery outcrop. Pinches 0-20 mts. e in theAne ghat. s s 9 Cph. Grey. Moderately to sparsely porphyritic 0-20 mts. o Pinches ESE of Ane. Can be traced only upto West of Takli

8 Cph Grey to brownish grey. Mod. to highly M porphyritic Upper units are contain mega 5-50 mts. cus phenocrysts of plagioclase. ( M3 megacryst 2 marker flow of Godbole et al, 1996 & o Beane et al, 1986). Giravali GPB. Pinches in the South eastern part of the area

7 Cph Grey. Non porphyritic to highly porphyritic, glomeroporphyritic with 50- 100 mts. coarse phenocrysts of plagioclase.

6 Aa/ Bm. grey. Mod.to highly porphyritic with 0-50 mts. Simfde coarse and megaphenocrysts of plagioclase. In the western part it is tMn and shows mixed characters. The porphyritic nature and thickness increases to the east. ( Manchar GPB of beane et al, 1996) Pinches towards the east near Bokharwadi

5 Cph Greenish grey. Non to sparsely porphyritic 20 - 45 mts. with medium size phenocrysts. eu s Grey. Moderately porphyritic. Medium to fine 0-40 mts. 2 4 Aa O sized phenocrysts. Mafic phenocrysts also seea Pinches towards the South eastern part

3 Cph Greenish grey Non to sparsely porphyritic 35 - 100 mts.

2 Cph Grey. Moderately porphyritic. Exposed 10 mts. only in E part of the area in Mandohal Odha

1 Cph Dk. grey. Non porphyritic to sparsely 10 mts. + porphyritic. Base not seen

Abbreviations Aa : Aa flow Simp : Simple flow Cph : Compound palioehoe flow Pig : Plagioclase.

25 thickness of 50mts. The frequency distribution of the phenociysts, is sparse in the southern part, around Nagapur with reduction in size of phenocrysts giving rise to massive flow with bouldery outcrop. This flow his been used as a local marker. The flow pinches at Boknakwadi which is NNW of Takli. In the present study, this flow has been separated (hatched portion in Fig. 2.1) mainly because it helps as a marker to a certain extent, specially in the central & South eastern portion. This flow can be equated with the Manchar GPB of Beane et al. (1986) and Alkuti flow of Thorat & Subbarao (1996). This group can be correlated with Up. Ratangarh formation of Godbole (et al. 1996) & Thakurwadi & Bhimashankar formation of Beane et al. (1986) and Hooper (1988).

Group II The flow No. 8, a compound pahoehoe flow also contains meg^henocrysts of plagioclase ranging in size from 2 cm to a maximum of 3.5 to 4 cm. (Photo 2.1). The upper few units of this flow exhibit very large sized phenocrysts. The vesicularity, jointing & frequency distribution of the plagioclase laths is variable. In most sections this flow is capped by a 0.50 to 1 metre thick red bole or green bole, followed by a massive dark grey aa flow. Hence, this contact forms a prominent marker. This flow has therefore been used as a marker horizon, separating the dominantly aa flows above from the dominantly pahoehoe flows below. Ghodke et al. (1985) & Godbole et al. (1996) have designated this flow as M3 marker, separating the Up. Ratangarh formation below from the Indrayani formation above. Hooper (1988) has called this flow as Giravili GPB, separating the Bhimashankar formation from the upper Khandala formation.

26 Group III Flows 9 to 18 have been grouped together (Group III) due to the predominance of aa flows. The flows are moderately porphyritic and vary in thickness from 15 to a maximum of 60mts. Thin inter fingering compound pahoehoe flows 9,12,15,17 pinch towards the west in the upgradient direction and become thicker towards the east Flow nos 10 and 11 are aa flows and they pinch towards the east in the direction of the gradient. The aa flows have a bouldery appearance and are moderately to sparsely porphyritic and also exhibit crude columnar jointing. Within a single flow itself, 2 to 3 collanade and entabulature zones are seen, giving ^>pearance of different tiers. The pahoehoe flow No. 17 exposed in the areas north of Padli darya, Kanhur etc. has an extensive horizontal spread. This flow is fine grained, porphyritic with medium size phenocrysts and shows extensive weathering. This group of dominantly aa flows can be correlated with the Indrayani formation of Godbole et al. (1996) and Hooper et al. (1988)

Group IV Flow numbers 19 and 20 have been grouped together due to their limited exposure in the area. They are confined to die hill ranges in the north west and south eastern parts and occur above 950 -1000 ASL.The flows are porphyritic and exhibit crude jointing.

Detailed Geology As mentioned earlier the generalised geology & stratigr^hic succession in the area was arrived at by carrying out systematic geological mjqjping at different sections

27 in the area. Four localities with prominent geomorphic features were selected for detailed studies. These were; i near Bote, Kas nadi. ii near Gurewadi, Mandohal odha iii near Chilewadi, Mandvi nadi iv near Kotul, Mula nadi At each of this location, wherever possible, the flows/flow units on either side of the river, forming the gorge were studied with tq)e & brunton and supplemented with geological maps on 1:50,000 scale wherever necessary. The details of the geology in these localities are enumerated in brief in the following paragraphs.

Geology off the area around Bote The basalt flows e?q)osed at Kas Nadi SE & E of Bote (Fig 2.2) are dominantly of pahoehoe type with a single aa flow exposed almost at the base which is close to the present stream bed level. These flows form part of flow No. 3 of Group I (Table 2.3). The lowermost con^und pahoehoe flow is moderately poiphyritic and medium graiued with 2 to 3 units. The overlying aa flow is greyish in colour and has a 1 metre thick fragmentary material towards its top. The fragmentary material being softer is easily removed resulting in caving in at this junction (Fig. 2.2).

The aa flow is overlain by a thick sequence of compound pahoehoe flows. The lowest flow of this group of flows is 12 -13 mts thick, with non-porphyritic to sparsely porphyritic units. This flow is less vesicular and more compact. Close spaced sheet jointing is seen towards the top and bottom of the flow. Vertical joints, coupled with the compact nature of the flow must have resulted in the near vertical

28 LEGEND

Silt with gravel/pebble lenses & calcareous noduies/kankar Squeeze ups

Sheet joints Simple flow / aa flow

Vertical joints How brcceia

*- *- Porphyritic flow unit with coarse VesicJes / Amygdules phenocrysts

Red bole / Reddened erust Porphyritic flow unit with medium size phenocry sts

Ropy structure Non-porphyritie basalt flow unit

\ >, Pipe vesicles / Amygdules

Fig 2.2 : SECTION ACROSS KAS NADI NEAR BOTE walls. The pahoehoe flow sequence that overlies this jointed flow is composed of highly vesicular and amygdular flows, with abundant pipes, squeeze ups, ropes etc. The units vary in texture from non-porphyritic to highly porphyritic. These flows are more weathered as compared to lower ones and hence form a smooth concave slope. Spheroidal weathering is more common in these flows. Potholes are formed in this compound flow sequence. The different flows shown in the section across Kas nadi constitute one single flow on 1:50,000 scale (Fig 2.3). This flow is the lowermost one in the area . The flat planar surface at 720 mts is composed of pahoehoe flows.

A basic dyke intrudes the lava pile north of Kelwadi and south of Bote, trending N85°E - S 85°W. This is parallel to the fracture trending N80®E - S80°W and to the direction of the knick point SE of Bote present on a tributary of Kas Nadi. The cfyke is fine to medium grained and doleritic in composition (Photo 2.2). East and southeast of Bote, Quaternary alluvial deposits rest on the basalt on the 680 - 700m surface on either banks of the Kas nadi. Alluvium is also seen filling the gorge from the bend north of Kelwadi to its confluence with Mula. The quaternary deposits are described in detail in the later part of this chapter.

Geology of the area around Gurewadi In the section e?qx)sed at Mandohal odha, a sequence of eight flows have been delineated (Fig 2.4). Flows 1 to 5 are of pahoehoe nature, varying in texture from non-porphyritic to moderately porphyritic. The lower four flows are highly vesicular and amygdular. Ropes and squeeze ups are abundant on the flow unit tops. Sheet

29 u y y Cl b. CL 3 -C ^ C. Q. JZ >> C l sz C - i g .^ e- a - a f, c)l CL t/5 > CL ctf ^« —c 0 « o >. 2 ^•SPo c y) !/) C -C z : = C g 3: c u S-C O i» o 8- '2C3 —"O o O. . JZ cz o ;; ' 3 Cl o. i t c: o 04 , UJ ■— soa t_ n . j E 0 b I- o n o o , o 0 . ^ f E 1) o O.E It > 3 ^ O D. 3 o is J=

O a : < QL <

< O O o

o UJ 0 CO 01 O)

..Of .90 tL jointing/horizontal jointing is seen in flow No.4, mainly in the lower units, which are non-porphyritic in texture.

Flow number five is a simple flow and has been designated so because it does not show typical characters of either pahoehoe or aa but has an almost uniform texture. This flow also exhibits numerous vertical joints, which along with the uniform texture has partly resulted in the vertical valley walls (Photo 2.3).

The top most pahoehoe flow has a large areal spread. The lower units are non- porphyritic with porphyricity increasing towards the top. The aa flow, which contains megaphenocrysts of plagioclase is the top most flow in the area and it occurs as isolated patches. All these flows cannot be indicated on map of 1:50,000 scale. Hence flows 1 to 5, stratigr^hically below the simple flow are grouped together as a single flow. The upper 3 flows have been shown as separate entities (Fig 2.5). All the flows form part of Group I (Table 2.3). The lower five flows correspond to flow numbers 1,2,3. The upper three flows which have been shown sq>arately correspond to flow no; 4, 5,6.

To the west of the area, parallel to the gorge, a set of five dykes intrudes the lava pile. The dykes trending NE-S W are medium to fine grained, doleritic and basaltic in composition. Remnants of the floor of lava channel/tube is seen trending in a general NW-SE & WNW-ESE direction ahnost parallel to the knick points downstream of the fall. Lava channels and tubes are considered as distributary channels supplying lava to the advancing front.

At the confluence of this nala with Mula, 6 to 7m thick alluvium is seen on both the

30 mIOOO S» 0 1

LEGEND

Pahoehoe flow with megaphenocrysts of Road \ plagioclase, 2.5 - 3 cm [Marker Flowl Pahoehoe flow, highly porphyritic, coarse phenocrysts, Stream Medium grained ground mass, gtomeroporphyritic

Aa flow, group of three flows with mega­ Lineaments / Fractures phenocrysts of plagioclase, 1 - 2 cm [Marker Flow]

Post trappean basic dykes Pahoehoe flow, non to moderately porphyritic, medium / with xenoliths sized phenocrysts, medium grained ground mass Aa flow, moderately porphyritic. medium to fine rx Lava lubes I channels grained ground mass Group of four aa flows Pahoehoe flow / intermittent pahoehoe flows

Fig 2.5 : GEOLOGICAL MAP AROUND GUREWADI banks. The alluvium is silty in texture, with intermittent lenses of pebbles. Detailed description is given in Quaternary deposits.

Geology of the area around Chilewadi Near Chilewadi, the Mandvi nadi cuts a deep gorge in the basalt, forming 70 to 80m steep valley sides. The lava flow sequence exposed on the hills on both banks was studied. This sequence exposes seven flows mappable on 1; 50,000 scale. The litho-sequence (Fig 2.6) shows a sequence of compound pahoehoe flows with one simple flow at the base and two aa flows to the top. The simple and aa flows are rather thin and there is an overall dominance of compound pahoehoe flows. Flows 1 to 4 correspond to flow no: 4, 5, 6, 7 of Flow Group I (Table 2.3). Flow number three has a more or less uniform texture and is highly porphyritic with medium to coarse size phenocrysts of plagioclase. These plagioclase phenocrysts impart a speckled q)pearance to the flow. The frequency of phenocrysts is almost uniform. Sheet jointing is also common. The uniform texture and verticaljoints have resulted in a vertical scarp. (Photo2.4). Flow number five contains meg^henocrysts of plagioclase, 2 to 3cm long. The honey yellow coloured phenocrysts occur as glomero-porphyritic aggregates. This flow has been used as marker and corresponds to flow Group II (Table 2.3). In this section, flow number 6 does not show distinct aa characters. The simple flow shows mixed characters with pipes at the base & a fragmentary top. The uppermost aa flows are well ejqwsed in the Bhamberi dongar, south of Chilewadi. These flows are hard, compact sparsely porphyritic, medium to fine grained and exhibit crude columnar joints and have a bouldery appearance. These flows belong to flow Group III (Table 2.3).

31 + + + Moderately porphyritic, Compact flow. -140 m A Zi ^ Breccia o 0 Aa flow, compact. + + + Moderately porphyritic, Jointed, Bouldery outcrop. -120 Breccia ------Red Bole ------Compound flow. 6 - 7 units. Megaphenocrysts bearing flow. -100 Vesicular top. Compound flow. 3 - 4 units. Moderately porphyritic. Vesicular top. Upper units, Highly porphyritic.

-60 Compound flow. 13-14 units. Highly porphyritic. Coarse to medium phenocrysts. Jointed. Speckled appearance

-40

Compound flow, Non porphyritic, Amygdaloidal, Vesicular. £ • RB --I -20 A . ,o A A <’1+0 + o 4 Breccia and vesicular top. + -t- Simple flow, Moderately porphyritic. Jointed. > X Pipes. -0 RC ------Reddened C r u s t ------

Fig 2.6: LITHOLOGICAL SECTION, SW OF CHILEWADI Ill-sorted alluvial material 10 - 15mts thick is seen on the right bank forming a relatively large expanse near Chilewadi and Pachgarwadi. On the left bank 8 -1 Omts thick alluvium rests unconformably on the basalts. (Fig 2.7). Detailed description is given in section on Quaternary deposits.

Geology of the area around Kohii The river Mula at Kotul exposes five compound pahoehoe flow units, with alluvium on both the banks (Photo 2.5). These flow units form part of flow number 5 of Group I (Table 2.3). The compound flow units at the base exhibit pipe vesicles towards the top. Megascopically the flows are non-porphyritic to sparsely porphyritic with medium sized phenocrysts of plagioclase. The flows are highly jointed, with sub-vertical to vertical joints. Ropes, squeeze ups etc. typical of pahoehoe flows are common on the surface, which also shows pot holes. The pothole bearing strath at the modem pool level is weathered. Alluvium is seen on both the banks of the river (Fig 2.8). On the right bank above the pothole bearing strata, calcareous tufa is seen associated with pebbly gravel and silt. Detailed description is given in section on Quaternary deposits.

Intnisives The lava flows in the area are intruded by 19 basic dykes, which are of doleritic and basaltic composition. Out of this, the majority of dykes trend NE - SW to ENE - WS W and a few trend NW - SE and E - W. The dykes usually occupy fractures. In some cases south of Chilewadi, SW of Belhe and near Takli, these dykes occur discontinously along the fi^ctures. The most prominent dyke swarm seen in the

32

area trends NE - SW and can be traced for a distance of 61 km and much beyond the study area. This dyke swarm is composed of 6 ahnost parallel dykes varying in trend from NNE - SS W, NE - S W to ENE - WS W which show pinching and swelling. The width of the dykes varies from 5 - 9 mts and are doleritic and basaltic in composition. Most of the dykes have a positive relief and occur as linear ridges and can be easily identified in the field. However, where the dyke is fine grained and weathered, they exhibit a negative relief One of the dykes near Kanherwadi is occupied by the stream Kanherodha.

Two of the fine grained basaltic dykes north east of Ane contain xenohth of quartzo- felsphatic material. Xenoliths have been collected from Vakunjhap, Kanherwadi and Kamatwadi. They vary in size from 3mts to a maximum of 27mts in length. The dyke in which the xenoliths are found is highly fractured and weathered with the result that the xenoliths stand out in relief (Photo 2.6). The xenoliths shows a lot of textural variation (Photo: 2.7 & 2.8). The quartzo-felsphathic material is highly fractured and partially assimilated by basaltic material. These xenoliths could represent products of crustal fusion related to Deccan volcanism (Vaddadi & Sharma, 1996).

Flow structures Ropy structure is one of the most impressive flow structures seen in the basalt flows (Photo 2.9). They occur in the pahoehoe flows and indicate the local direction of lava flow. The structures which reflect large scale flow movements are lava tubes. Lava tubes may be hollow or filled and are feeders of lava to the advancing lava front (Greeley, 1987). In the area under study, Lava tubes /channels have been

33 found near Nagapur, Kanhenvadi and Ane within compound pahoehoe flows. They have a linear disposition with a sinuous course and form low ridge like outcrops. The one at Nagapur has a southerly gradient and is parallel to the NE - S W trending dyke swarms. This tube and the dyke swarm cut across Mina river, near Ranjani. The one at Kanherwadi has a east south easterly gradient and cuts across Mandohal odha. At Ane only a small portion of the tube is seen. The reddened and brecciated roof and margins of the lava tubes are seen in the ghat section. The floors and margins of these tubes are highly indurated & baked and therefore hard and resistant compared to the surrounding pahoehoe flows (Photo 2.10). Intense fracturing and fragmentation is also seen along the margins, which is different from the breccia seen towards the top of aa flows. The lava tubes and channels in the area are filled. The channel fill material is basaltic in composition and shows coarse porphyritic texture, with phenocrysts of plagioclase, augite and olivine. These were reported for the first time from the area by Sharma and Warrier (1991) Sharma and Vaddadi (1996). Similar lava tubes have also been reported from the adjacent area by Punj and Mujtaba (1991) and Ravikumar (1991).

Squeeze ups also occur ia a number of places in the pahoehoe flows (Photo 2.11). They occur as small dyke like intrusions which protrude out from small pahoehoe unit tops. These according to Davis (1984) are formed as a result of differential sfresses built up due to surge of new lava.

Quaternaiy deposits The Deccan basalts are unconformably overlain by surfacial Quaternary sediments. The Early Tertiary laterites (Schmidt et al. 1983) found on the planation surface at

34 1200 -1500mts are not found in the area under study. The Quaternary deposits of the region under study are thin as compared to the extra peninsular area and they occur as discontinous patches within the river valleys. They also occur at the foot hilk of escarpments of major water divides. These sediments have been laid down primarily by fluvial agencies with subordinate contributions fix)m coUuvial processes. These deposits have been traditionally described as alluvial deposits in geological literature (Pascoe, 1965). Generally they are divided into two categories: older & younger alluvium. The older alluvium is usually calcretised and has yielded stone age artefacts and animal fossils in Upland Maharashtra in general and particularly in the region under study.

In the last decade attenq)ts have been made to date these deposits by geochronological methods like C*'*, Th - Ur series, K -Ar, Ar^®- Ar*’, fission track and paleomagnetism. On the basis of these studies some efforts have been made to categorise the older alluvial deposits into various 'Formations' (Rajaguru et.al., 1993; Mishra, 1995; Sadakata et al., 1995).

The younger alluvial fill is generally characterised by non-calcareous brownish silt interlayered with sand and gravel and has an inset relationship with older alluvial fill. These deposits have also been given the status of a 'Formation'. Kajale et, al. (1976) have identified two major formations in the Ghod valley; the Upper Bhima formation composed of sandy pebbly gravel followed by yellowish brown calcareous silt and the Post Black Soil formation composed of non laminated, non kankary brownish silt Corvinus (1981) had identified three litho units in Pravara valley; the Lower F^avara beds. Upper Pravara beds and the Late Holocene beds. The Upper

35 Bhima formation (UBF) of Kajale et al. (1976) and the Lower Pravara beds of Corvinus (1981) contain early Acheulian artefacts. Both these workers had assigned a Late Mid Pleistocene age for the sediments. The litho and biostratigr^hy of the Quaternary deposits of western Maharashtra by Rajaguru and Badam (1984) is in concurrence with that of Kajale et al. (1976). Kale and Rajaguru (1987) had subsequently identified two members in the UBF, the lower comprising of bouldery pebbly gravel and the upper consisting of silt Rajaguru et al. (1993) based on detailed sedimentological, archaeological, paleontological and geochronological work divided the Quaternary deposits into five major formations; the Bori Formation, the Godavari Formation, the Upper Bhima Formation, the Chandanapuri Formation and the Post Black Formation. These formations were placed in the time bracket of Early Middle Pleistocene to Mid Holocene.

The Bori formation rests unconformably on the Deccan traps and is composed of fine textured clays which is associated with volcanic ash. The Godavari formation consists of bouldery, pebbly gravels. Mishra et al. (1998) have shown the this formation occuring as high as 15-20 mts above the present bed levels of the Pravara and the Godavari may belong to Late Tertiary and not to Early Middle Pleistocene as suggested by Rajaguru et al. (1993). The iq)per Bhima formation has two members. The lower one is composed of pebbly sandy gravels. These have been dated between 30 to > 350ky. The upper member which consists of sandy silt, has yielded upper palaeolithic and microlithic artefacts, fossil bones, drift wood and molluscan shells which have been dated between 9 to 17ky by conventional method. The Chandanapuri formation consists mainly of colluvio-alluvial deposits occurring at the foot slopes of escarpments of hills fimctioning as water divides. It has been dated to the Late Quaternary (Joshi, 1992; Rajaguru et al., 1993).

36 The Post Black Soil formation is represented primarily by non calcareous brownish silt and clay with gravelly and sandy lenses. It forms an inset alluvial terrace (5 to 6mts high above the modem bed of the rivers) resting against the older alluvial fill terrace of Late Pliestocene age. The alluvial fill consists primarily of overbank silts and sands and probably has been laid down subsequent to stream entrenchment. Recently, Mishra et al. (1998) have discovered microliths, rudimentary hearths, pottery, bones etc. firom these deposits and have succeeded in sub dividing the PBF into members ranging in age fi-om 9000y BP to 300y BP.

As stated earlier several attempts have been made to date these deposits by 14 39 40 geochronological methods like C , Th - Ur series, K - A r, Ar - Ar , fission track and paleomagnetism. However no consensus has yet evolved on the absolute ages of these formations. Eg. Volcanic ash at Bori has been dated to 1.2my by K- 10 4ft Ar(Korrisettaret al., 1989),0.66mybyAr -Ar ( Mishra et al., 1995) and 75ky by chemostratigraphy ( Acharya et al., 1993; Westgate et al., 1998).

In the present study, therefore the traditional term alluvium has been used to describe these deposits. This term covers and includes both alluvial and colluvial deposits arising as a consequence of various depositional processes.

The alluvial deposits found in the river valleys and gorges were studied only in an attempt to understand the relative ages of the landforms and the geomorphic evolutionary history of the area. As such detailed sedimentological studies of these deposits were not carried out. The alluvial deposits occurring at different localities along the Mula and Kukdi valleys are described here.

37 Mula Valley In the Mula valley, the alluvial deposits were studied at Kotul, around Bote, Kelwadi, and at Mandve. These are decribed below.

Kotul At Kotul, alluvium is exposed on both the banks of Mula river. On the left bank, a 10-12 metre thick yellowish brown silt rests on the basalts with a thin veneer of black soil above (Photo 2.12). Overall the silt is associated with coarse sand and is coarser towards the base. Thin coarse sandy pebbly lenses occur within the silt. Toward the top the silt is fine grained, with abundant calcareous nodules and tubular concretions. Few microliths have been recovered from the coarse sandy pebbly layers in the silt. Microliths are mostly made up of varieties of chalcedony group of minerals such as agate, chert and jasper.

On the right bank the sequence of sediments consist of gravel at the base followed by silt and black soil. Calcareous spring tufa is seen associated with the gravel and silt ( Photo 2.13 and 2.14). The gravel is 3 to 3.5mts thick and rests unconformably on the basalt (pahoehoe flows). It is cobbly pebbly in texture, poorly sorted, consolidated with subrounded pebbles ranging in size from 0.5cm to about 8cms. The gravel lithology consists of vesicular and amygdular basalt. The space between the pebbles is filled with sandy material but the cementing material is calcareous. The gravel is overlain by 3 - 4mts of yellow brown calcareous silt, which is in turn covered by a 30 - 40cms thick black soil. Calc tufa, 4 - 5mts thick is associated with the gravel and silt. This occurs at an elevation of 5m from the present channel level. Calc tufa is also seen at the present channel level.

38 Bote and Keiwadi

The deq)ly entrenched valley of Kas nadi has preserved a sequence of alluvial deposits. Remnants of sediments which have escaped erosion are seen near Bote, as discontinuous patches on the 700 - 720mts level on both the banks of the river. The alluvium is only 2 - 3mts thick here, but near Keiwadi in the stream joining Kas nadi from south, a 15 - 25mts thick sequence is seen. From the elbow (Fig 4.3) upto its confluence with Mula river, the Kas nadi is completely filled with alluvium and the present stream cuts through these sediments. At Ghaddavloni, where the gorge widens into a narrow valley, renmant of alluvium which must have once filled the entire valley is seen on the left bank at an elevation of 16 to 18mts above the present channel level (Photo 2.15).

These valley fill sediments are ill sorted. At the base the sequence is composed of fine brown silt with abundant calcrete nodules and occasional thin lenses of sandy pebbly gravel ( Photo 2.16). Towards the top of the fill sequence the silt gets coarser with and becomes more gravelly. Black soil about 2m thick is developed on the sediments. The brown silt is fine grained, shows crude lamination, and contains abundant calcrete concretions and pedotubxiles. An overall coarsening upwards was observed. The gravel occurs as lenses, within the silt. It is poorly consolidated, ill sorted with subangular and angular fragments of weathered basalt varying in size from a few mm to 5cm. Microliths or other stone age artefacts have not been recovered from these deposits during the present study.

Gurewadi and Mandve At the confluence of Mandohal Odha with Mula river, the gorge widens into a narrow valley, where 6 - 7mts thick sequence of sediments is e?q)osed (Photo 2.17).

39 The dqx)sit consists of silt with lenses of sandy pebbly or pebbly sandy gravel. The silt rests unconformably on the bedrock (basalt). It is yellowish brown, fine grained compact, highly calcareous with abundant calcrete concretions. This silt is overlain by 1 to 1.5mts thick gravel. The pebbly gravel is poorly sorted, partially consolidated containing sub-rounded and rounded fragments varying in size from 1 to 12cms. Lithologically, the fragments are composed of vesicular and non porphyritic basalt, chalcedony and zeolite. The gravel is overlain by 2 - 2.5mts thick reddish brown clayey silt with thin sandy pebbly lenses. The upper silt does not contain calcrete concretions and is overlain by a Imetre thick black soil. Overall the lower layer is more calcareous and the upper layer is more reddish brown. Microliths have not been found in this section. However, near Gurewadi, on the left bank of Mandohal odha, on the rocky surface of 720-730mts, microlithic artefacts were recovered from the weathered surface of the basalt layer. Microliths are made up of agate, moss agate and blood stone. The lava flows in and around the area do not contain any vein of moss agate or bloodstone.

Ih /0'33 Chandanapuri ft Ghargaon Thick exposures of alluvial material are seen at Chandanapuri in Pravara valley and also at Ghargaon in the Mula vaUey. The material is ill sorted, coarse sUty with pebbly gravel lenses which show cross bedding. These deposits have not been studied in detail during the present work. As stated earlier, these deposits range in age from the Late Quaternary (Joshi, 1992) to Late Neogene (Mishra et al., 1998).

Kukadi Valley In the Kukadi valley, alluvium occurs as discontinuous patches all along the river

40 channel from Yedgaon to Renwadi. Gupte and Rajaguru (1970) had studied the sediments upstream of Yedgaon during the excavation for the dam site and the thickness of alluvium is not more than 25mts. The alluvium exposed at Chilewadi (in Mandvi nadi), at Otur (confluence of Mandvi and Pushpavati) and the ones at Bori, Shiroli, Jadhavwadi, Chombut along Kukadi were also examined during the present study.

The sediments exposed along the Kukadi river from Vadgaon to Jadhavwadi are associated with volcanic ash. This was reported for the first time by Korisettar et al. (1989). In the composite lithosequence given by them (Fig 2.9) the compact brown silt, fissured clays, channel lag, gravel and pebbly rubble constitute the older deposits in which the volcanic ash is preserved. This is overlain by sandy pebbly gravel which contains Acheulian artefacts. The yellow brown silt which constitutes the upper part contains bedded calcrete, lenses of sandy gravel and fissured clays. The ash bed has been dated by Ar^^ - Ar^ method to 670ky and is associated with acheulian industry (Mishra et al., 1995). However this age has been doubted by Westgate et al. (1998) based on their detailed chemo-stratigraphic studies. According to Kale (1990) the channel at Bori is one of the oldest knownhighly sinuous,low energy paleo-channel.

ChHeivadi Chilewadi is situated on the right bank of Mandvi nadi. Down stream of the knick point, huge assorted angular boulders/fragments of basalt are seen in the channel. These vary in size from 4 - 6mts. On the right bank blocky rubbly gravel with coarse sandy matrix (Photo 2.18) is preserved in the cave like feature which is formed at the flow contact above the present day channel. The gravel rests on the bed rock and

41 Early historic habitatbn

Yellow brown sandy silt

Sandy gravel with Epipalaeollthic tools

Fissured clay

Bedded carbonate

Ash lens

O .

■ O ® \ pebbley gravel wfth ■ 9...... ■ Acheulian tools and fcfossils

>— h- H-

Ash bed

' “ V Brown silt

Rubble with few artefacts

Fig 2.9 : COMPOSITE QUATERNARY LITHOSTRATIGRAPHIC COLUMN, KUKDI VALLEY (after KORISETTAR ET AL. 1989a) is 3 - 4mts thick, ill-sorted, less compact with angular to sub-angular fragments of vesicular, amygdular and compact basalt, zeolite (1 to 25cms) held together in a sandy matrix.

On the left bank, a sequence of 9-lOmts thick sediments are exposed. These are composed of gravel and silt. The pebbly gravel bed rests directly on the bed rock and is overlain by silt. The gravel is partially cemented and sorted, with subangular and subrounded pebbles of weathered vesicular and compact basalt, varying in size from 0.5 to 15cms. The reddish brown sandy silt which overlies the gravel, is on the whole compact, but shows psuedo lamination ( Photo 2.19 and 2.20). This is due to interlayering of gravel and sand with silt. The silt is more clayey towards the top and contains abundant calcrete nodules. Microliths were not found in these deposits.

Ohir and Udhampur The village Otur is at the confluence of Mandvi nadi and Pushpavati which is a tributary of Kukadi. The deep gorge of Mandvi gradually widens into a narrow valley at Otur. A 10-15mts thick pile of alluvium is seen at this place. The villages Otur and Udampur rest on this alluvium. In well cuttings along the banks of the channel, sediments with a thickness of 15 to 20mts were seen. The sediments are constituted of yellowish brown, fine sandy silt with lenses of sandy pebbly gravel. Calcrete concretions and pedotubules are abundant. The silt is finer towards the top, and more clayey. Black soil of l-1.5mts thickness is developed on the silt.

Boriand Shiroli A 6m thick sequence of silt is exposed in the area. The silt rests on the basalt and is overlain by black soil. At the base, 30-40cms, pebbly gravel occurs as lenses within

42 the brown compact silt The gravel is coarse grained, compact with subangular and sub-rounded pebbles of compact, vesicular and megaphenocryst basalt. The silt is overlain by black fissured clays which contain lenses of ash beds ranging in thickness fi'om 0.26 to 1. 5mts. The volcanic ash is buff coloured and gritty. Chemical analysis of this ash shows that it contains more than 70% silica.

Jadhavwadi The sediments exposed at Jadhavwadi are quite similar to the one at Bori and ShiroU. The ash bed is seen in the stream bed towards the right bank. The sandy silt horizon shows cross bedding. The sandy pebbly gravel lenses show graded bedding. Overall the silt is finer towards the top which is highly calcretised.

Chombut On the left bank of Kukadi between Shinq)ur and Chombut, a 3 - 4mts thick sequence of sediments is exposed. A 2 metre thick gravel bed at the base rests on the basalts. This gravel is highly consolidated, well roimded with assorted pebbles of basalt and agate, varying in size fi"om 2mm to 7cm. A fossil tooth was recovered fi'om this bed and was identified as part of a molar of Bos Namadicus (Badam, personal communication).

Tufas Tufas and travertines in a wide range of fi-esh water environments have been studied by various workers like Emeis et al. (1987), Chafetz & Folk (1984) and Viles & Goudie (1990). Though there is a terminological confusion between travertines and tufas, most surficial deposits have been termed tufas (Ford & Williams, 1989). These

43 are mostly granular, accreting to algal filaments, plant roots and stems at springs, along riverbanks, lake edges etc.

Since tufa deposits are mostly associated with springs their occurrence may be related to local or regional water table levels. Such deposits are datable radiometrically, or by means of their fossil flora and fauna assemblage and their occurrence on river terraces assumes particular importance, both in terms of chronology and palaeo- climatology (Ford & Williams, 1989).

Tufa deposits were found at Kotul and these were studied in detail. The waterfall tufas at Wadgaon darya, Kelwadi and cliff drapes at Vambori (Photo 2.21) were also studied for comparison.

Calcareous tufa is seen south of Wadgaon Darya, on the right bank of Padli nadi, which is a small tributary of Kukadi river. The tufa occurs at the edge of the Kanhur plateau as spring deposits (also forming roof pendants). The tufa is brownish white in colour, laminated and porous at places. Branches of wood and root casts are present which form the nuclei for calcium carbonate deposition. The tufa at Kotul is brownish white, hard and compact with fine laminations and contains leaf impressions and root casts. Small subangular and subrounded pebbles from the gravel occur as nuclei for carbonate deposition.

Simple laboratory studies as indicated by Viles and Goudie (1990) were carried out to obtain the basic geological and geochemical information. The studies carried out included water absorption capacity (WAC). Insoluble residence (IR) tests, chemical analyses for determining major oxide weight percentages, thin section study and X- ray diffraction studies.

44 Petrography

BasaKs The lava flows in the area under study vary in texture from non porphyritic to highly porphyritic. The porphyritic varieties contain phenocrysts of size varying from mediimi to coarse. Megaphenocrysts are also seen. In order to understand the petrographic characteristics of the flows, thin sections of representative flows from each group were studied.

The flows belonging to the Group I are mostly pahoehoe flows, except for flow numbers 4 and 6. The lower flows, flow number 1 to 5 exhibit ahnost similar petrogr^hy. These flows are compact, non-porphyritic to sparsely porphyritic. The non-porphyritic varieties consist of plagioclase laths and subhedral clinopyroxene grains exhibiting subophitic and intersertal texture. The clinopyroxene is augite and pegionite which are at times completely pseudomorphed. Opaque iron ore occurs as an accessory. Irregular vesicles and cavities are lined with greenish and yellowish glass. Glass also occupies the inter granular spaces.

Flow number 7 is a highly porphyritic flow and contains medium to coarse grained phenocrysts of plagioclase set in a medium grained ground mass. The plagioclase phenocrysts occur as glomeroporphyritic aggregates and also contain inclusions of opaque iron ore. The phenocryst plagioclase laths show normal zoning. The ground mass is made up of fine needles of plagioclase, irregular grains of augite, opaque iron ore and glass. The ground mass minerals exhibit subophitic intergrowth and intergranular and intersertal texture.

45 Flow number 6 of Group I and flow number 8 of Group II are megaphenocryst bearing flows. The plagioclase phenocrysts are large and sometimes cover the entire thin section. Besides these phenocrysts, a few phenocrysts of augite and olivine are also seen. The augite and olivine grains are partly or completely altered to iddingsite. The ground mass is fine to medium grained and is made up of fine needles of plagioclase, augite, opaque iron and glass exhibiting intergranular & intersertal texture. The plagioclase phenocrysts also exhibit pillow taxitic texture.

Flows of Group III are dominantly aa flows, medium grained and highly jointed. These flows show more or less similar petrogr^hy. They are moderately porphyritic with phenocrysts of plagioclase and augite set in a fine grained ground mass.

In a single compound flow the various units show petrographic variation. This according to Deshmukh (1988)is due to combination of several factors like gravitational sinking of phenocrysts aided with low viscosity both before and after extrusion and slow rate of effusion.

Calcareous tufas The calcareous tufas in general have a very complex fabric. The clasts and cement are not very clear. Overall they are light brown to dark brown in color and micritic to microsparitic in texture ( Photo 2.22). Randomly oriented elongated microsparite encrusted filaments are also seen. Banding is seen in Kotul A and Kan-H. The color difference makes the banding more conspicuous. This is clear in Kan-H, where more greyish and brownish bands alternate (Photo 2.23). Small rounded globular aggregates of darker tone are also seen (Photo 2.24). These could be similar to the clumps and diffuse masses of bacteria described by Chafetz and Folk (1984).

46 A few equant and prismatic grains, clouded, dirty white to grey in colour are seen.

Along the margins of these grains show golden brown hue. Relict grains of quartz and augite could also be identified. Kotul B shows more porosity as compared to Kotul A . This could be due to the fact that the pore spaces have been sealed. The textural characteristics are summarised in Table 2.4.

TABLE 2.4

Petrographic characteristics of Calc, tufas

Sample Ponosity Sparite Micrite Banding Filaments

Kotul A L PDPP Kotul B H - D - P K an-H LP D D P

L^end L - low, H-high, P - Present, D - Dominant.

Chemistry

Laboratory studies of tufas were mainly undertaken to understand the chemical and petrological characteristics of tufas. One of the objectives was also to investigate whether the calc tufas occuring at two levels at Kotul differ from each other in mineralogical and chemical characters. The results of the tests are summarised in Table 2.5. Samples from Kotul B and Kan-H have higher values of WAC (23.98 - 25.52 %) as compared to Kotul A (8.16 -12.52 %). This could be due to the fact that tufa occuring at a higher level has less porosity. Viles and Goudie (1990) have

47 00 r~ 8 00 Os s 1 m 1 m

2 - 1 1

on o o O s 98^ in z d 1 d 1 d VO m U o

a 0 O fS u M) VO o oe s (N 1 rn 1 !2 ‘S* I 1 -5 Q I o " ON VO ON o o at © ON K uS o\ d ea 'oT /-V >,

48 observed low WAC values ( mean 6.3 -11.28 %) in the old tufa cones and stalagmites and moderate values (mean 20.26, 22.3 %) for active and eroding drapes and stalagtites. The IR values for Kotul A are also low (17.70,19.14 %) when compared to Kotul B and Kan-H samples. Overall, the IR values obtained for these tufas are much higher than that reported by Viles & Goudie (1990) for the Napier range. This could be due to the fact that the present tufas are associated with alluvium, silt and gravel deposits which in turn are composed of pebbles of basalt, fragments of silica and zeolites.

X- Ray diffraction X - Ray diffraction is one of the oldest tools for determining the mineralogy of fine grained sedimentary rocks. A finely powdered sample was used for diffractometry. The diffraction was carried out at the Deccan Collie, Pune by using CuKa radiation The diffraction characteristics were recorded from 20 °to 50 ° 2 0 ( Fig 2.10). The 20 corresponding to the reflections were noted. Since each angle is related to a set of planes with characteristic ‘d’ spacing, this was calculated according to Bragg’s equation n X, - 2d Sin0. The relative intensity I/I^j was calculated and the results were then compared with the standards. The values of 20, ‘d’ and I/I^ are shown in Table 2.6.

The diffractograms of both the samples, Kotul A and Kotul B are identical. The samples are ahnost pure since all the major reflections are comparable with calcite. Quartz occurs as a very small constituent.

49 TABLE 2.6

Results of X-ray diffraction of Calcareous tufas from Kotul.

Sample 26 d spacing 1/1. Identification (A»)

Kotul A 23.2 3.83 16 Calcite 27 3.30 5 Quartz 29.5 3.03 100 Calcite 31.9 2.80 4 Calcite 36 2.49 20 Calcite 39.5 2.28 27 Calcite 43.1 2.10 21 Calcite 47 1.93 8 Calcite 47.5 1.91 20 Calcite 48.5 1.88 22 Calcite

Kotul B 23.5 3.78 18 Calcite 28 3.19 6 Quartz 29.6 3.02 100 Calcite 32 2.8 4 Calcite 36.05 2.49 19 Calcite 39.75 2.27 23 Calcite 43.5 2.08 20 Calcite 47 1.93 8 Calcite 47.5 1.91 19 Calcite 48.75 1.87 22 Calcite

50

PHOTO 2.1

Flow # 8 with megaphenocrysts of plagioclase (2 .4 cm long). Loc Qtion: Ane Ghat

PHOTO 2.2

Finegrained dolerite dyke trending N80°E -S80 W, cutting across the stream. White lines show dyke margins. Location; Near Kelwadi PHOTO 2.3

Simple flow with steep scarp in Mondohal odha. Location - Gurewodi

PHOTO 2.4

Porphyritic pahoehoe flows with uniform texture & sheet jointing forming a vertical scorp in Mandvi valley. Locotion - near Chilewadi. PHOTO 2.5

Pahoehoe flow units exposed on the Right Bank of Mulo river. Calc tufa associated with the alluvium. Location - near Kotuleshwar temple, KotuI

PHOTO 2.6

Large xenoliths of quartzofelsphatic material occcuring in fine grained basaltic dyke. Location :Vakun|hap • 4# '' ^ '41, •^J'.sC-M .-t .d

PHOTO 2.7

Photomicrograph of xenolith showing glassy texture with perlitic cracks typical of volcanic rocks (3 .5 x 10, PPL)

PHOTO 2.8

Photomicrograph of xenolith : fractured quartz phenocrysts in a fine grained cryptocrystalline ground mass (10x10, PPL) PHOTO 2.9

Ropy structure seen on the unit top of pohoehoe flows. Location - West of Chilewodi (right bank of Mandvi nodi)

PHOTO 2.10

View of lava tube showing gentle ESE'ly gradient. The baked & reddened margins (above the white lines) can be recognized from a distance. Location - Kanherwadi PHOTO 2.11

Squeeze ups in pahohoe flows, exposed in Kas nodi. Location : near Bote.

PHOTO 2.12

Yellow brown silt exposed on the left bank of Mulo river ( near KotuI) PHOTO 2.13

Calcareous Spring tufa associated with gravel and silt, seen on the right bank of Mula river, below the Kotuleshwar temple.

PHOTO 2.14

Closer view of the Calcareous Spring tufa. PHOTO 2.15

Vast expanse of alluvium on the left bank of Kas nadi Locotion : Gadhavloni

fk''. (»• ii i l ’- ■••».- L

'^1 , 7 i'*

^ '■ ■ w ^ ‘. i ■ .V

PHOTO 2.16 ■- 4 •• '

Closer view of the alluvium on the left bank Location: Gadhavloni Calcretised Basal Portion

PHOTO 2.17

Alluvium exposed on the right bank of Mondohol odha showing highly calcretised basal portion Location. Mandwe

Photo 2.18

Blocky rubbly gravel preserved on the right bank of Mandvi nodi Location : Chilewadi PHOTO 2.19

Alluviol fills plastered against the steep scarp of the gorge - left bank of Mandvi nadi. Location: Chilewadi

PHOTO 2.20 *~S,A ■- - i. f

=. ^ .. Closer view of the alluvium showing grovel resting on basalts - left bank of Mandvi nadi. Location - Chilewadi PHOTO 2.21

Calcareous tufa occuring os cliff drapes. Location -Vombori

PHOTO 2.22

Photomicrograph of Colcoreous tufa showing fine groined micritic texture. (KotulA) (4x10,BXN) PHOTO 2.23

Photomicrograph of Calcareous tufa showing fine grained texture and banding. (Kan-H) (4x10,PPL)

PHOTO 2.24

Photomicrograph of Calcareous tufa showing microsparitic texture with aggregates of organic matter. (KotulB) (10x10, BXN)