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Geochemical and Rheological Constraints on the Dynamics of the Oceanic Upper Mantle by Jessica Mendelsohn Warren M.ScL, Earth Sciences, University of Cambridge, 2000 B.A., Natural Sciences, University of Cambridge, 1999 Submitted to the MIT/WHOI Joint Program in Marine Geology and Geophysics in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the MASSACHUSETIS INSTITUTE OF TECHNOLOGY and the WOODS HOLE OCEANOGRAPIDC INSTITUTION September 2007 © Jessica Mendelsohn Warren, MMVII. All rights reserved. The author hereby grants to MIT and WHOI permission to reproduce and distribute publicly paper and electronic copies of this thesis document in whole or in part in any medium now known or hereafter created. r"---------------_"'" Author. V _. -.---- -.--~ .~ ~ , -----..... , MIT/WHOI Join~ro~ram in Marine Geology and Geophysics August 30, 2007 Certified by ..... v' r L/ Nobumichi Shimizu Senior Scientist, Woods Hole Oceanographic Institution , Thesis Supervisor Certified by ;::;r--r . v Gregory Hirth Associate Scientist, Woods Hole Oceanographic Institution Thesis Supervisor Certified by _ _/ . ., ...• ~ ,... __ ~(.. Henry J. B. Dick Senior Scientist, Woods Hole Oceanographic Institution / " Thesis Supervisor ~:~~: :i;:~~i~ ;~: ~~~~ .~;~~~. ~~i:i~~: Aocep<ed by . r MIT/WHOI Joint Program 2 Geochemical and Rheological Constraints on the Dynamics of the Oceanic Upper Mantle by Jessica Mendelsohn Warren Submitted to the MIT/WHOI Joint Program in Marine Geology and Geophysics on August 30, 2007, in partial fulfillment of the requirements for the degree of Doctor of Philosophy Abstract I provide constraints on mantle convection through observations of the rheology and composition of the oceanic upper mantle. Convection cannot be directly observed, yet is a fundamental part of the plate tectonic cycle. Relative motion among plates is accommo- dated by localized deformation at their boundaries. I demonstrate that in the ductile regime, strain localization occurs when different mineral phases are mixed together, limiting grain annealing. Upper mantle flow is by dislocation creep, resulting in seismic anisotropy due to mineral alignment. I use a shear zone in the Josephine Peridotite to quantify the rela- tionship between mineral orientation and shear strain, providing an improved framework for the interpretation of seismic anisotropy. The upper mantle is generally assumed to be homogeneous in composition. From detailed isotopic and chemical analyses of abyssal peridotites from the Southwest Indian Ridge, I show that the mantle is heterogeneous at a range of length-scales. Abyssal peridotites recovered at ocean ridges are generally inter- preted as the depleted residues of melt extraction. I find that melt-rock reaction is a sig- nificant part of the melt extraction process, modifying the composition of the lithospheric mantle. The generation of heterogeneous lithosphere provides a source for asthenospheric heterogeneity, via subduction and mantle convection. Thesis Supervisors: Nobumichi Shimizu, Senior Scientist, Woods Hole Oceanographic Institution Gregory Hirth, Associate Scientist, Woods Hole Oceanographic Institution Henry J. B. Dick, Senior Scientist, Woods Hole Oceanographic Institution 3 4 Acknowledgments I have been fortunate at WHOI to have three wonderful advisors: Nobu Shimizu, Greg Hirth, and Henry Dick. They have each provided unique insights into the upper mantle while demonstrating unique styles of advising. Henry introduced me to abyssal peridotites, took me out on three research cruises and spent hours expounding on ultra-slow spreading, dredging techniques and right-wing politics. Nobu gave me free reign on the ion probe, a solid background in geochemistry, 26 hand-picked mineral separates and much-needed left-wing literature. Greg successfully diverted my attention towards rheology and rock me- chanics, though not the Red Sox, explaining everything from collecting oriented samples to the intricacies of deformation mechanisms to the broader contexts of mantle rheology. All three have been extremely supportive and generous in their time and funding. My committee has been an invaluable source of knowledge and patience, particularly during the last 6 months of writing. Wenlu Zhu, as committee chair, has provided guidance throughout. As a committee and as individuals, Fred Frey, Glenn Gaetani, Stan Hart and Peter Kelemen have always made themselves available to answer questions, provide ideas and strengthen my understanding of mantle processes. Fred kept me on track with trace elements, Glenn gave clear explanations of thermodynamics, Stan combed through my iso- tope data and Peter expanded my view of the physical mantle. I have benefited from interactions with a variety of scientists and professors at WHOI and MIT. Marc Kurz improved my education in helium isotopes. Jurek Blusztajn attempted to improve my understanding of osmium while actually improving my knowledge of gen- eral isotope analytical techniques. Tim Grove has always been willing to discuss thermo- dynamics and obscure minerals. Jeff McGuire pushed me to place rock deformation in a context relevant to seismologists. Mark Behn and Laurent Montesi´ patiently explained mantle flow modeling while making available their own model results. Susan Humphris chaired my generals committee and has not stopped providing advice and support since then. Karen Hanghøj, Jian Lin, Jerry McManus, Brian Tucholke, Ken Sims, Adam Soule, and Jack Whitehead have always been willing to answer questions and share their research. The isotope and trace element work in Chapter 4 of this thesis would not have been com- pleted without the generosity of Eizo Nakamura, who invited me to spend over 4 months in his lab at the Institute for Study of the Earth’s Interior in Misasa, Japan. I am indebted to Chie Sakaguchi, who trained me in the clean room, shared her extensive knowledge of isotope separation techniques and was both a patient teacher and a friend. Yoshiko Nakano facilitated the coordination of my visits and made sure that I learnt to play badminton. The members of the Pheasant Memorial Lab were all extremely helpful and hospitable. In particular, my visits would have been much less fun without Maria Marin, Lucy Lu and Masako Uyama. Three chapters of this thesis relied on samples collected by the hard work of the captain 5 and crew of eight research cruises. In addition, I have benefitted from free access to the WHOI rock archive, which, with samples collected over the past 40 years, represents the work of innumerable captains, crews and scientists on many ships and expeditions. The analytical work in Chapters 2 and 3 of my thesis would not have been completed without Louie Kerr at MBL, who kept the SEM running and replaced numerous filaments. Chapter 5 of my thesis required the WHOI 3f ion probe to run smoothly, which in turn required the collective expertise of Nobu, Graham Layne and Pete Landry. Finally, collection of the microprobe data in Chapters 4 and 5 was aided by Nilanjan Chatterjee at MIT. The MIT/WHOI Joint Program provides fabulous support for its graduate students in the form of the Academic Programs Office. Julia Westwater and Marsha Gomes solved any problem I encountered, always while making me laugh. I was fortunate to interact with two deans while at WHOI, Jim Yoder and John Farrington. In addition, the Joint Program experience would not have been complete without Ronni Schwartz at MIT. Finally, the Geology and Geophysics administrative staff − in particular Fran Halbrooks, Pam Foster, Lynn Stellrecht and Maryanne F. Ferreira − are always willing to help students. Outside of the Joint Program, I have been fortunate to interact with a variety of scien- tists. I met Ian MacGregor before I understood the meaning of the word geology. He has been a source of encouragement, advice and mentoring over the past 13 years. My early science training was the result of four teachers, Mrs. Goshko, Mrs. Katbab, Mr. Hoare and Mr. Buck. I have a deep respect and appreciation for their skills at and commitment to teaching. As an undergraduate at the Department of Earth Sciences at Cambridge Univer- sity, I benefited from supervision by David Pyle and Marion Holness. My first experience of research was an undergraduate summer spent at the Smithsonian Department of Mineral Sciences, working with Tom Simkin and Sorena Sorensen. During my first research cruise, I met Bobbie John and Mike Cheadle from the University of Wyoming and ever since they have been a counterbalance to my WHOI view of life-as-a-scientist. The students who have been with me in graduate school have been a continual source of knowledge, ideas, support, laughter, and good food. Clare Williams has been a great friend, classmate, flat-mate, and true Brit. Jeff Standish and Margaret Boettcher, as elder students who shared their advisors with me, have always been willing to share their own knowledge and time. Matt Jackson is forgiven for never not talking about geochemistry because of all the insight he shares. Rachel Stanley, Anna Michel, Greg Gerbi, Elke Hodson, Mea Cook, Cara Santelli, Linda Kalnejais, Luc Mehl, Nick Austin, Emily Van Ark, Brian deMartin, Melanie Fewings, Andrew Mosedale, Carolyn Walker, Petra Klepac, Rhea Workman, Amy Draut, Seth John, Stephen Licht, Trish Gregg, Janelle Homburg, Kay Achenbach, Elena Miranda, and Graham Baines have all provided cheerful camaraderie over the years. Fi- nally, the support of the WGals has been invaluable this past year and I hope it continues for