The Charcoal Transition
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Capture and Reuse of Carbon Dioxide (CO2) for a Plastics Circular Economy: a Review
processes Review Capture and Reuse of Carbon Dioxide (CO2) for a Plastics Circular Economy: A Review Laura Pires da Mata Costa 1 ,Débora Micheline Vaz de Miranda 1, Ana Carolina Couto de Oliveira 2, Luiz Falcon 3, Marina Stella Silva Pimenta 3, Ivan Guilherme Bessa 3,Sílvio Juarez Wouters 3,Márcio Henrique S. Andrade 3 and José Carlos Pinto 1,* 1 Programa de Engenharia Química/COPPE, Universidade Federal do Rio de Janeiro, Cidade Universitária, CP 68502, Rio de Janeiro 21941-972, Brazil; [email protected] (L.P.d.M.C.); [email protected] (D.M.V.d.M.) 2 Escola de Química, Universidade Federal do Rio de Janeiro, Cidade Universitária, CP 68525, Rio de Janeiro 21941-598, Brazil; [email protected] 3 Braskem S.A., Rua Marumbi, 1400, Campos Elíseos, Duque de Caxias 25221-000, Brazil; [email protected] (L.F.); [email protected] (M.S.S.P.); [email protected] (I.G.B.); [email protected] (S.J.W.); [email protected] (M.H.S.A.) * Correspondence: [email protected]; Tel.: +55-21-3938-8709 Abstract: Plastic production has been increasing at enormous rates. Particularly, the socioenvi- ronmental problems resulting from the linear economy model have been widely discussed, espe- cially regarding plastic pieces intended for single use and disposed improperly in the environment. Nonetheless, greenhouse gas emissions caused by inappropriate disposal or recycling and by the Citation: Pires da Mata Costa, L.; many production stages have not been discussed thoroughly. Regarding the manufacturing pro- Micheline Vaz de Miranda, D.; Couto cesses, carbon dioxide is produced mainly through heating of process streams and intrinsic chemical de Oliveira, A.C.; Falcon, L.; Stella transformations, explaining why first-generation petrochemical industries are among the top five Silva Pimenta, M.; Guilherme Bessa, most greenhouse gas (GHG)-polluting businesses. -
Wood and Charcoal Anatomy of Eight Charcoal- Producing Wood Species in Central Sudan
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by KhartoumSpace Wood and Charcoal Anatomy of Eight Charcoal- producing Wood Species in Central Sudan By Hiat Mohammedain Mustafa Hagar B.Sc. (Honours-2002) Forestry, Faculty of Natural Resources and Environmental Studies University of Sinnar A Thesis Submitted in Fulfillment of the Requirement for the Degree of Master of Science in Forestry (Wood Science) at University of Khartoum Supervisor Dr. Abdelazim Yassin Abdelgadir Department of Forest Products and Industries Faculty of Forestry April 2010 اﻵﻳﺔ اﻵﻳﺔ ﭧ ﭨ ﮋ ﻬ ے ﮯ ۓ ﮱ ڭ ﯔ ﯕ ﯖ ۇ ﯘ ژ ﺻﺪق اﷲ اﻟﻌﻈﻴﻢ ﺳﻮرة (ﻳﺲ: اﻵﻳﺔ 80) i DEDICATION To the Soul of my Father ii ACKNOWLEDGEMENT Praise and thanks are due to Allah who had given me the power and support till completing this study. I am grateful and indebted to my supervisor Dr. Abdelazim Yassin Abdelgadir for his valuable guidance and advice throughout this study and deep thanks are due to Dr. Abdelatif Altyib and Dr. Ashraf Mohamed Ahmed for their supportive comments that led to a successful completion of the research. I would like to express my gratitude to El fasher University that give me this chance and my Department in the forestry of Environment and Natural Resource. I am greatly to Agriculture Engineer. Ali Alnour for his assistance in the sample collection at Alnoor Forest. Also I am grateful to technician Gamil Alla Gumaa for helping me in slide preparation, I am also very thankful to my friend Entisar Abdelrahman Ali who help me typing this work and finally thanks to my family Mother, brother, sister and all members of my family. -
Final Report Coal Project
2011 Coal Electrolysis for the Production of Hydrogen and Liquid Fuels Dr. Gerardine Botte OHIO UNIVERSITY Center for Electrochemical Engineering Research CEER-Ohio University Final Executive Summary Report Clean technologies for the production of high value chemicals, such as hydrogen, liquid fuels, and refined organic and inorganic compounds, with significant impact in the different business spheres (e.g., petrochemical, polymers, and plastics) are very important for national security purposes and for preservation of the environment. Power is traditionally generated from coal by the complete combustion (oxidation) of coal. When hydrogen is desired as a product, coal gasification (partial oxidation) is employed. Most overall coal gasification schemes use a series of reactions ranging from combustion (for heat generation) to partial oxidation (for hydrogen generation), to the water-gas shift reaction and others to produce a fuel gas product stream. In order to produce a hydrogen (H2) product from this fuel gas stream, the hydrogen must be removed from a mixture that includes carbon monoxide (CO), carbon dioxide (CO2), hydrogen sulfide (H2S), particulates, and other gases (perhaps including nitrogen, if an oxygen plant is not used). In addition, CO2 needs to be captured and sequestered from the stream to reduce the emissions of this gas to the environment. These separations become an extremely complex and costly consideration. In order for CO2 to be captured, it either must be separated from other gases in a mixture (say, CO2 from N2), or O2 must be separated from air in order to be used as combustion feed to create “pure” CO2 product. In either case, significant capital and operating expenses, as well as significant power consumption, are incurred for either kind of separation. -
Activated Carbon, Biochar and Charcoal: Linkages and Synergies Across Pyrogenic Carbon’S Abcs
water Review Activated Carbon, Biochar and Charcoal: Linkages and Synergies across Pyrogenic Carbon’s ABCs Nikolas Hagemann 1,* ID , Kurt Spokas 2 ID , Hans-Peter Schmidt 3 ID , Ralf Kägi 4, Marc Anton Böhler 5 and Thomas D. Bucheli 1 1 Agroscope, Environmental Analytics, Reckenholzstrasse 191, CH-8046 Zurich, Switzerland; [email protected] 2 United States Department of Agriculture, Agricultural Research Service, Soil and Water Management Unit, St. Paul, MN 55108, USA; [email protected] 3 Ithaka Institute, Ancienne Eglise 9, CH-1974 Arbaz, Switzerland; [email protected] 4 Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department Process Engineering, Überlandstrasse 133, CH-8600 Dübendorf, Switzerland; [email protected] 5 Eawag, Swiss Federal Institute of Aquatic Science and Technology, Application and Development, Department Process Engineering, Überlandstrasse 133, CH-8600 Dübendorf, Switzerland; [email protected] * Correspondence: [email protected]; Tel.: +41-58-462-1074 Received: 11 January 2018; Accepted: 1 February 2018; Published: 9 February 2018 Abstract: Biochar and activated carbon, both carbonaceous pyrogenic materials, are important products for environmental technology and intensively studied for a multitude of purposes. A strict distinction between these materials is not always possible, and also a generally accepted terminology is lacking. However, research on both materials is increasingly overlapping: sorption and remediation are the domain of activated carbon, which nowadays is also addressed by studies on biochar. Thus, awareness of both fields of research and knowledge about the distinction of biochar and activated carbon is necessary for designing novel research on pyrogenic carbonaceous materials. Here, we describe the dividing ranges and common grounds of biochar, activated carbon and other pyrogenic carbonaceous materials such as charcoal based on their history, definition and production technologies. -
Polycyclic Aromatic Hydrocarbon Migration from Creosote-Treated Railway Ties Into Ballast and Adjacent Wetlands
United States In cooperation Department of with the Agriculture Polycyclic Aromatic United States Forest Service Department of Transportation Hydrocarbon Migration Forest Products Federal Laboratory Highway Administration From Creosote-Treated Research Paper FPL−RP−617 Railway Ties Into Ballast and Adjacent Wetlands Kenneth M. Brooks Abstract from the weathered ties at this time. No significant PAH loss was observed from ties during the second summer. A Occasionally, creosote-treated railroad ties need to be small portion of PAH appeared to move vertically down into replaced, sometimes in sensitive environments such as the ballast to approximately 60 cm. Small amounts of PAH wetlands. To help determine if this is detrimental to the may have migrated from the ballast into adjacent wetlands surrounding environment, more information is needed on during the second summer, but these amounts were not the extent and pattern of creosote, or more specifically poly- statistically significant. These results suggest that it is rea- cyclic aromatic hydrocarbon (PAH), migration from railroad sonable to expect a detectable migration of creosote-derived ties and what effects this would have on the surrounding PAH from newly treated railway ties into supporting ballast environment. This study is a report on PAH level testing during their first exposure to hot summer weather. The PAH done in a simulated wetland mesocosm. Both newly treated rapidly disappeared from the ballast during the fall and and weathered creosote-treated railroad ties were placed in winter following this initial loss. Then statistically insignifi- the simulated wetland. As a control, untreated ties were also cant vertical and horizontal migration of these PAH suggests placed in the mesocosm. -
Structural Transformation of Nascent Char During the Fast Pyrolysis Of
Structural transformation of nascent char during the fast pyrolysis of mallee wood and low-rank coals 5 Lei Zhang1, Tingting Li1, Dimple Quyn1, Li Dong1, Penghua Qiu1,2, Chun-Zhu Li1,* 1Fuels and Energy Technology Institute, Curtin University of Technology, GPO Box U1987, Perth, WA 6845, Australia 10 2School of Energy Science and Engineering, Harbin Institute of Technology, 92 West Dazhi Street, Harbin, Heilongjiang 150001, People’s Republic of China 15 * Corresponding author: E-mail address: [email protected] (Chun-Zhu Li) Phone: +61 8 9266 1131 Fax: +61 8 9266 1138 20 February 2015 1 25 Abstract The changes in char structure during the fast pyrolysis of three different feedstocks from 600 °C to 1200 °C were investigated. Western Australian Collie sub-bituminous coal, Victorian Loy Yang brown coal and Australian mallee wood were pyrolysed in a wire-mesh 30 reactor at a heating rate of 1000 K s-1 with holding time ranging from 0 s to 50 s. FT- Raman/IR spectroscopy was used to characterise the structural features of the chars obtained at different temperatures. The combined use of a wire-mesh reactor and a FT-Raman/IR spectrometer has provided significant insights into the rapid changes in the chemical structure of nascent char during fast pyrolysis. Our results indicate that the three fuels began 35 significant ring condensation at different temperatures. Mallee wood showed significant growth of large rings within 1 s holding at 600 °C; however Loy Yang and Collie coals showed significant ring condensation at 800 °C and 900 °C respectively. -
Coal Characteristics
CCTR Indiana Center for Coal Technology Research COAL CHARACTERISTICS CCTR Basic Facts File # 8 Brian H. Bowen, Marty W. Irwin The Energy Center at Discovery Park Purdue University CCTR, Potter Center, 500 Central Drive West Lafayette, IN 47907-2022 http://www.purdue.edu/dp/energy/CCTR/ Email: [email protected] October 2008 1 Indiana Center for Coal Technology Research CCTR COAL FORMATION As geological processes apply pressure to peat over time, it is transformed successively into different types of coal Source: Kentucky Geological Survey http://images.google.com/imgres?imgurl=http://www.uky.edu/KGS/coal/images/peatcoal.gif&imgrefurl=http://www.uky.edu/KGS/coal/coalform.htm&h=354&w=579&sz= 20&hl=en&start=5&um=1&tbnid=NavOy9_5HD07pM:&tbnh=82&tbnw=134&prev=/images%3Fq%3Dcoal%2Bphotos%26svnum%3D10%26um%3D1%26hl%3Den%26sa%3DX 2 Indiana Center for Coal Technology Research CCTR COAL ANALYSIS Elemental analysis of coal gives empirical formulas such as: C137H97O9NS for Bituminous Coal C240H90O4NS for high-grade Anthracite Coal is divided into 4 ranks: (1) Anthracite (2) Bituminous (3) Sub-bituminous (4) Lignite Source: http://cc.msnscache.com/cache.aspx?q=4929705428518&lang=en-US&mkt=en-US&FORM=CVRE8 3 Indiana Center for Coal Technology Research CCTR BITUMINOUS COAL Bituminous Coal: Great pressure results in the creation of bituminous, or “soft” coal. This is the type most commonly used for electric power generation in the U.S. It has a higher heating value than either lignite or sub-bituminous, but less than that of anthracite. Bituminous coal -
Characterization of Activated Carbon Produced from Coffee Residues by Chemical and Physical Activation
Activated carbon Characterization of activated carbon produced from coffee residues by chemical and physical activation JAVIER SÁNCHEZ AZNAR KTH Chemical Science and Engineering Master Thesis in Chemical Engineering Stockholm, Sweden, March 2011 - 1 - Activated carbon List of figures PART 1 Fig 1.1 Representation of the structure of activated carbons (H. Fritzst Oeckli 1990)(47).7 Fig 1.2 The six isotherm types according to IUPAC……………………………………...8 Fig 1.3 Representation of the three types of pores according to the IUPAC………….....14 Fig 1.4 Texture of dust activated carbon………………………………………………...19 Fig 1.5 Texture of granular activated carbon…………………………………………….19 Fig 1.6 Structure of a coffee bean………………………………………………………..23 PART 2 Fig 2.1 Furnace employed for carbonization…………………………………………….31 Fig 2.2 Magnetic stirrer during HCL washing…………………………………………..32 Fig 2.3 Steam activation system…………………………………………………………33 Fig 2.4 ASAP instrument………………………………………………………………...34 PART 3 Fig 3.1 Results of yields for 30%, 40% and 50% samples by chemical activation at different temperatures…………………………………………………………………....38 Fig 3. 2. Results of yields for samples activated by steam at different temperatures……39 Fig 3.3 Results of volatile and ash content by chemical and steam activation…………..40 Fig 3.4 Results of BET surface area (m 2/g)……………………………………………...42 Fig 3. 5 Isotherm of the sample CA_3_500……………………………………………...44 Fig 3.6 Isotherm of the sample CA_3_600……………………………….……………...44 Fig 3.7 Isotherm of the sample CA_3_700……………………………….……………...44 Fig 3.8 Isotherm of the -
Hardwood-Distillation Industry
HARDWOOD-DISTILLATION INDUSTRY No. 738 Revised February 1956 41. /0111111 110 111111111111111111 t I 1, UNITED STATES DEPARTMENT OF AGRICULTURE FOREST PRODUCTS LABORATORY FOREST SERVICE MADISON 5, WISCONSIN. In Cooperation with the University of Wisconsin 1 HARDWOOD-DISTILLATION INDUSTRY— By EDWARD BEGLINGER, Chemical Engineer 2 Forest Products Laboratory, — Forest Service U. S. Department of Agriculture The major portion of wood distillation products in the United States is obtained from forest and mill residues, chiefly beech, birch, maple, oak, and ash. Marketing of the natural byproducts recovered has been concerned traditionally with outlets for acetic acid, methanol, and charcoal. Large and lower cost production of acetic acid and methanol from other sources has severely curtailed markets formerly available to the distillation in- dustry, and has in turn created operational conditions generally unfavor- able to many of the smaller and more marginal plants. Increased demand for charcoal, which is recovered in the largest amount as a plant product, now provides a compensating factor for more favorable plant operation. The present hardwood-distillation industry includes six byproduct-recovery plants. With the exception of one smaller plant manufacturing primarily a specialty product, all have modern facilities for direct byproduct re- covery. Changing economic conditions during the past 25 years, including such factors as progressively increasing raw material, equipment, and labor costs, and lack of adequate markets for methanol and acetic acid, have caused the number of plants to be reduced from about 50 in the mid- thirties to the 6 now operating. In addition to this group, a few oven plants formerly practicing full recovery have retained the carbonizing equipment and produce only charcoal. -
Bibliography of Wood Distillation
Bibliography of WoodDistillation T.CL[). Compiled by Gerald A.Walls Arranged by Morrie Craig BibliographY 5 October 1966 For.stProductsResearch FOREST RESEARCHLABORATORY OREGON STATEUNIVERSITY Corvallis PROGRAM AND PURPOSE The Forest Research Laboratoryof the School of Forestry combines a well-equipped laboratory witha staff of forest and wood scientists in program designed to improve the forestresource and promote full uti- lization of forest products. Theextensive research done by the Labora tory is supported by the forest industryand by state and federal funds. The current report results fromstudies in forest products, where wood scientists and technologists,chemists, and engineers are con- cerned with properties, processing,utilization, and marketing of wood and of timber by-products. The PROGRAM of research includes identifying and developing chemicals fromwood, improving pulping of wood and woodresidues, investigating and improving manufacturingtechniques, extending life of wood by treating, developing better methods ofseasoning wood for higher quality and reduced costs, cooperating with forest scientists to determineeffects of growing conditionson wood properties, and evaluating engineering properties ofwood and wood- based materials and structures. The PURPOSE of researchon forest products is to expand markets, create new jobs, and bringmore dollar returns, thus advancing the interests of forestry and forestindustries, by > developing products from residuesand timber now wasted, and > improving treatment and designof present wood products. Table of Contents INTRODUCTION 3 BOOKS 4 ARTICLES AND BULLETINS 5 PATENTS 46 Australia 46 Austria 46 Be1giun 46 Canada 47 Czechoslovakia 47 Denmark 47 France 47 Germany 51 Great Britain 52 India 55 Italy 55 Japan 55 Netherlands 56 Norway 56 Poland 56 Russia 56 Spain 57 Sweden 57 Switzerland 58 United States 59 Bibliography of Wood Distillation INTRODUCTION This bibliography is a revision and extension to1964 of Bibli- ography of Wood Distillation, 1907-1953published in 1955. -
Impact of Char Properties and Reaction Parameters on Naphthalene Conversion in a Macro-TGA Fixed Char Bed Reactor
Article Impact of Char Properties and Reaction Parameters on Naphthalene Conversion in a Macro-TGA Fixed Char Bed Reactor Ziad Abu El-Rub 1,*, Eddy Bramer 2, Samer Al-Gharabli 1 and Gerrit Brem 2 1 Pharmaceutical and Chemical Engineering Department, German Jordanian University, Amman 11180, Jordan; [email protected] 2 Laboratory of Thermal Engineering; University of Twente, P. O. Box 217, 7500 AE Enschede, The Netherlands; [email protected] (E.B.); [email protected] (G.B) * Correspondence: [email protected]; Tel.: +962-6-429-4412 Received: 18 February 2019; Accepted: 28 March 2019; Published: 28 March 2019 Abstract: Catalytic tar removal is one of the main challenges restricting the successful commercialization of biomass gasification. Hot gas cleaning using a heterogeneous catalyst is one of the methods used to remove tar. In order to economically remove tar, an efficient low-cost catalyst should be applied. Biomass char has the potential to be such a catalyst. In this work, the reactor parameters that affect the conversion of a model tar component “naphthalene” were investigated employing an in situ thermogravimetric analysis of a fixed bed of biomass char. The following reactor and catalyst parameters were investigated: bed temperature (750 to 900 °C), gas residence time in the char bed (0.4 to 2.4 s), char particle size (500 to 1700 μm), feed naphthalene concentration, feed gas composition (CO, CO2, H2O, H2, CH4, naphthalene, and N2), char properties, and char precursor. It was found that the biomass char has a high activity for naphthalene conversion. -
Biomass Briquette Production: a Propagation of Non-Convention Technology and Future of Pollution Free Thermal Energy Sources
American Journal of Engineering Research (AJER) 2015 American Journal of Engineering Research (AJER) e-ISSN: 2320-0847 p-ISSN: 2320-0936 Volume-04, Issue-02, pp-44-50 www.ajer.org Research Paper Open Access Biomass Briquette Production: A Propagation of Non-Convention Technology and Future of Pollution Free Thermal Energy Sources Manoj Kumar Sharma, Gohil Priyank, Nikita Sharma M.Tech. Scholar, Truba Institute of Engineering & Information Technology, Bhopal (M.P.) India M.Tech. Student, Truba Institute of Engineering & Information Technology, Bhopal (M.P.) India B.Sc. (Biotech), Student, Govt. P.G. College, BHEL, Bhopal (M.P.) India Abstract: Biomass briquettes are a biofuel substitute to coal and charcoal. Briquettes are mostly used in the developing world where cooking fuels are not as easily available. Briquettes are used to heat industrial boilers in order to produce electricity from steam. The briquettes are con-fired with coal in order to create the heat supplied to the boiler. People have been using biomass briquettes since before recorded history. Biomass briquettes are made from agriculture waste and are a replacement for fossils fuels such as oil or coal, and can be used to heat boiler in manufacturing plants. Biomass briquettes are a renewable source of energy and avoid adding fossils carbon to the atmosphere. The extrusion production technology of briquettes is the process of extrusion screw wastes (straw, sunflower husks, buckwheat, etc.) or finely shredded wood waste (sawdust) under high pressure. There is a tremendous scope to bring down the waste of convention energy sources to a considerable level through the development, propagation of non-convention briquettes technology i.e.