DOCSLIB.ORG

Supporting Information

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Supporting Information Recent Advances in the Chemistry of Metal Carbamates Giulio Bresciani, Lorenzo Biancalana, Guido Pampaloni and Fabio Marchetti Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via G. Moruzzi 13, I-56124 Pisa, Italy SUPPORTING INFORMATION Table of contents Page(s) Table S1. Rate and equilibrium constants for carbamato formation and hydrolysis in S2-S3 water. Table S2. Selected X-ray bond distances (Å) and angles (°) in amidinium/guanidinium S4 CO 2 adducts. Table S3. Selected bond distances (Å) and angles (°) for carbamato ligands in metal S5-S9 complexes. Table S4. NMR and IR data related to the NCO 2 moiety in metal carbamato complexes. S10-S13 References S14-S23 S1 Table S1. Rate (k) and equilibrium (K CBM ) constants for the carbamato formation and equilibrium constant (KHYD ) for the carbamato hydrolysis at 18 °C in water. Amine pK b[a] k (M-1 min -1) KCBM KHYD Ref. NH 3 4.76 3.8 × 10 3 2.3 × 10 3 4.4 × 10 -1 [1] Primary amines NH 2Me 3.38 8.3 × 10 4 4.0 × 10 6 6.0 × 10 -3 [1] NH 2Et 3.19 1.5 × 10 5 2.0 × 10 6 1.8 × 10 -2 [1] NH 2Pr 3.41 1.6 × 10 5 1.5 × 10 6 1.3 × 10 -2 [1] NH 2iPr 3.37 6.8 × 10 4 3.6 × 10 5 6.3 × 10 -2 [1] NH 2Bn 4.74 1.1 × 10 5 8.5 × 10 4 1.2 × 10 -2 [1] NH 2Ph 9.30 ≈10 3 8.1 × 10 -3 3.6 [1] NH 2allyl 4.38 1.1 × 10 5 1.6 × 10 5 1.5 × 10 -2 [1] NH 2Bu 3.24 2.0 × 10 5 1.1 × 10 5 1.6 × 10 -2 [1] NH 2sBu 3.44 7.1 × 10 4 3.8 × 10 5 4.9 × 10 -2 [1] NH 2iBu 3.58 1.6 × 10 5 1.3 × 10 6 1.0 × 10 -2 [1] NH 2tBu 3.55 1.9 × 10 4 1.1 × 10 5 1.0 × 10 -1 [1] Secondary amines NHMe 2 3.22 6.7 × 10 5 1.6 × 10 6 2.2 × 10 -2 [1] NHEt 2 3.51 2.9 × 10 5 7.4 × 10 4 2.4 × 10 -1 [1] NHPr 2 3.09 3.0 × 10 5 3.0 × 10 5 1.5 × 10 -1 [1] NH iPr 2 3.17 − None − [1] NHBu 2 2.54 3.1 × 10 5 4.6 × 10 5 1.9 × 10 -1 [1] NH sBu 2 − − None − [1] NH iBu 2 3.41 1.3 × 10 5 1.9 × 10 5 1.2 × 10 -1 [1] Piperidine 2.95 7.8 × 10 5 7.9 × 10 5 8.1 × 10 -2 [1] 3-MPD 3.12 − 6.9 × 10 6 6.2 × 10 -3 [2] 4-MPD 3.06 − 5.9 × 10 6 8.3 × 10 -3 [2] Pyrrolidine 3.16 3.5 × 10 6 1.9 × 10 7 2.0 × 10 -3 [3,4] Substituted amines MEA 4.42 8.3 × 10 4 6.0 × 10 4 1.9 × 10 -2 [1] DEA 4.98 1.0 × 10 5 2.1 × 10 3 1.5 × 10 -1 [1] 1-AP [b] 4.75 3.2 × 10 5 9.6 × 10 3 1.1 × 10 -1 [3] 2-AP [b] 4.75 6.0 × 10 4 4.0 × 10 3 2.5 × 10 -1 [5] MPA [b] 4.18 5.4 × 10 5 2.5 × 10 5 1.5 × 10 -2 [5] S2 AMP [b] 4.73 − None − [5] 4-PIPDM [b] 3.71 1.3 × 10 6 2.7 × 10 5 4.1 × 10 -2 [3,4] 4-PIPDE [b] 3.65 − 3.0 × 10 5 4.2 × 10 -2 [4] Morpholine [b] 5.78 1.6 × 10 5 1.4 × 10 3 6.8 × 10 -2 [3,4] Thiomorpholine [b] 5.57 1.9 × 10 5 9.3 × 10 2 1.6 × 10 -1 [3,4] 4.50 − 5.5 × 10 4 3.2 × 10 -2 Piperazine [6] 8.67 − 2.6 × 10 -1 4.6 × 10 -1 MPIPZ 4.96 − 5.1 × 10 3 1.2 × 10 -1 [3] 4-AMTHP [b] 4.37 3.6 × 10 5 1.9 × 10 5 1.3 × 10 -2 [7] Taurine [b],[c] 5.19 − 7.1 × 10 3 5.1 × 10 -2 [8] Amino acids Glycine [d] 4.49 3.2 × 10 5 4.4 × 10 4 4.2 × 10 -2 [9] Sarcosine [b],[d] 4.22 1.1 × 10 6 3.3 × 10 4 1.0 × 10 -1 [10] a-Alanine [d] 4.40 6.6 × 10 4 1.8 × 10 4 1.1 × 10 -1 [11] b-Alanine [d] 3.86 1.1 × 10 5 1.9 × 10 5 3.1 × 10 -2 [11] Proline [c] 3.57 − 5.4 × 10 5 2.8 × 10 -2 [12] 4.44 [e] − 1.7 × 10 4 1.2 × 10 -1 Lysine [b],[c] [13] 3.24 [f] − 6.3 × 10 4 5.1 × 10 -1 [a] pK b values are from ref. [1–9,12,13]. For a list of pKb see ref. [14,15]. (K w = 10 -14.27 ); [b] Measured at 25°C; [c] Potassium salt; [d] Sodium Salt; [e] Deprotonation of the a-amino group; [f] Deprotonation of the amino group on the lateral chain; 3-MPD = 3-methylpiperidine, 4-MPD = 4-methylpiperidine, MEA = monoethanolamine, DEA = diethanolamine, 1-AP = 2-amino-1-propanol, 2-AP = 1-amino-2-propanol, MPA = 3-amino-1-propanol, AMP = 2-amino-2-methyl-1-propanol, 4-PIPDM = 4-piperidinemethanol, 4-PIPDE = 4-piperidineethanol, MPIPZ = 1-methylpiperazine, 4-AMTHP = 4-aminomethyltetrahydropyran S3 Table S2. Selected X-ray bond distances (Å) and angles (°) in amidinium/guanidinium CO 2 adducts. N1-C1 C1-O1 C1-O2 N1-C2 C2-N2 C2-N3 O1-C1-O2 C1-N1-C2-N2 Compound Ref. (Å) (Å) (Å) (Å) (Å) (Å) (((α(ααα)) (°) (βββ)β))) ( °))) 1.480(3) 1.257(3) 1.229(2) 1.369(3) 1.332(2) 1.338(3) 128.6(2) 4.4(2) [16] 1.513(3) 1.233(3) 1.228(3) 1.330(3) 1.322(3) - 132.2(2) 9.1(2) [17] 1.439(2) 1.248(1) 1.243(1) 1.373(1) 1.355(1) 1.349(2) 130.6(1) 88.9(2) [17] 1.432(1) 1.251(1) 1.243(1) 1.368(1) 1.338(1) 1.392(1) 129.09(9) 68.9(1) [17] S4 Table S3. Selected bond distances (Å) and angles (°) for carbamato ligands in metal complexes (2004-2020). Metal center Carbamate coordination C-O1 (Å) C-O2 (Å) C-N (Å) O-C-O (°) Ref. Al(III) B/2 1.284(2) 1.282(2) 1.347(2) 120.0(1) [18] Al(III) B/2 1.300(5) 1.282(5) 1.326(5) 122.3(4) [19] Al(III) B/2 1.280(4) 1.280(4) 1.335(4) 120.4(3) [20] Bi(III) M/1 1.295(5) 1.250(6) 1.348(4) 123.9(4) [21] B/2 1.288(4) 1.265(4) 1.360(4) 122.9(3) Bi(III) C/2 1.295(4) 1.274(4) 1.342(4) 120.5(3) [22] C/1 1.299(4) 1.260(4) 1.355(4) 119.9(3) C/1 1.28(1) 1.26(2) 1.35(2) 120(1) B/2 1.28(1) 1.26(1) 1.34(1) 121(1) Ce(III) C/2 1.28(1) 1.28(1) 1.35(1) 119(1) [23] B/3 1.34(1) 1.25(1) 1.33(1) 120.6(9) B/4 1.311(9) 1.28(1) 1.34(1) 119.7(8) M/1 1.26(1) 1.21(1) 1.44(1) 128.4(8) Ce(III) C/2 1.284(9) 1.23(1) 1.39(1) 123.5(7) B/3 1.26(1) 1.23(1) 1.44(1) 128.7(8) [24] Ce(III) M/1 1.29(3) 1.20(3) 1.42(2) 129.0(2) Ce(IV) M/1 1.293(2) 1.201(3) 1.438(3) 128.3(2) Ce(IV) B/2 1.253(4) 1.243(4) 1.421(4) 128.1(2) C/1 1.269(8) 1.254(7) 1.357(5) 118.3(5) Ce(IV) B/2 1.277(4) 1.271(5) 1.362(6) 123.8(4) [23] C/2 1.279(7) 1.270(4) 1.346(7) 119.6(4) Cu(II) M/1 1.30(3) 1.20(3) 1.39(3) 131(2) [25] Cu(II) C/2 1.35(2) 1.25(2) 1.31(2) 118(1) [26] Cu(II) B/2 1.269(6) 1.259(6) 1.375(6) 126.7(4) [27] Cu(II) C/2 1.289(4) 1.238(4) 1.375(4) 123.6(3) M/1 1.281(3) 1.236(3) 1.375(3) 125.9(2) [28] Cu(II) B/2 1.280(3) 1.280(3) 1.367(3) 125.2(2) S5 C/1 1.28(1) 1.28(1) 1.34(1) 119.0(7) Dy(III) B/2 1.275(8) 1.27(1) 1.36(1) 122.7(7) [29] B/3 1.293(9) 1.25(1) 1.372(8) 121.3(6) Dy(III) M/1 1.272(6) 1.235(7) 1.373(8) 125.0(5) [30] C/1 1.295(8) 1.260(9) 1.369(9) 120.5(6) Er(III) B/2 1.272(7) 1.263(6) 1.346(8) 123.3(5) [31] B/3 1.305(6) 1.266(7) 1.348(6) 121.0(4) Er(III) D/2 1.333(6) 1.277(6) 1.315(6) 115.6(4) [32] C/1 1.27(1) 1.26(1) 1.37(1) 120.6(8) Eu(III) B/2 1.278(8) 1.254(6) 1.336(7) 123.1(5) [31] B/3 1.300(7) 1.253(6) 1.340(8) 122.2(5) Fe(III) B/2 1.280(5) 1.269(5) 1.346(6) 125.3(4) [33] Fe(II) M/1 1.293(3) 1.204(3) 1.401(4) 128.4(2) [34] Ga(III) B/2 1.283(4) 1.281(5) 1.345(5) 122.2(3) [35] C/1 1.33(1) 1.252(8) 1.39(1) 117.1(7) Ga(III) B/2 1.30(1) 1.30(1) 1.37(1) 122.3(7) [36] Ga(III) B/2 1.283(3) 1.276(3) 1.354(3) 121.0(2) Ga(III) C/1 1.293(3) 1.290(3) 1.351(3) 114.7(2) C/1 1.32(2) 1.24(2) 1.36(2) 117(1) Hf(IV) [37] B/2 1.29(1) 1.26(2) 1.31(2) 121(1) Ir(I) M/1 1.300(9) 1.23(1) 1.36(1) 125.5(8) [38] Ir(III) M/1 1.254(5) 1.231(7) 1.391(7) 124.0(5) Ir(III) M/1 1.252(7) 1.251(6) 1.401(8) 124.8(5) [39] Ir(III) M/1 1.26(1) 1.22(1) 1.395(8) 124.2(7) Ir(III) M/1 1.275(3) 1.219(2) 1.474(3) 128.7(2) [40] Ir(III) C/1 1.290(5) 1.275(5) 1.334(6) 117.7(4) [41] Ir(III) D/1 1.366(4) 1.237(4) 1.327(4) 120.7 C/1 1.25(1) 1.25(1) 1.39(1) 122.0(9) La(III) C/2 1.29(1) 1.262(9) 1.360(9) 120.5(7) [42] C/3 1.28(1) 1.27(1) 1.35(1) 120.1(8) Li(I) B/2 1.261(2) 1.255(2) 1.401(2) 124.3((1)) B/2 1.262(4) 1.254(4) 1.391(5) 122.21(3) [18] Li(I) B/3 1.285(3) 1.245(5) 1.379(4) 121.53(3) B/4 1.273(3) 1.273(4) 1.361(5) 121.0(3) B/2 1.264(4) 1.262(4) 1.338(5) 123.1(3) Li(I) B/3 1.264(2) 1.261(3) 1.355(4) 120.9(2) [43] B/5 1.279(3) 1.272(3) 1.342(3) 120.3(2) S6 C/5 1.261(3) 1.251(4) 1.333(3) 121.2(3) Li(I) B/3 1.262(3) 1.234(3) 1.424(4) 127.8(3) C/1 1.30(1) 1.26(2) 1.33(2) 119(1) Lu(III) B/2 1.26(1) 1.25(1) 1.36(1) 124.0(9) [31] B/3 1.309(9) 1.24(1) 1.34(1) 121.6(8) Mg(II) B/2 1.267(3) 1.266(3) 1.368(3) 124.9(2) B/2 1.262(5) 1.259(5) 1.391(5) 126.5(3) [44] Mg(II) C/3 1.276(4) 1.272(4) 1.353(5) 119.8(3) B/2 1.28(2) 1.24(2) 1.41(2) 124.5(2) C/2 1.30(2) 1.22(2) 1.368 124.0(1) Mg(II) [45] B/3 1.28(2) 1.28(2) 1.32(2) 122.0(1) M/2 1.28(2) 1.28(2) 1.35(2) 124.3(1) B/2 1.261(9) 1.25(1) 1.348(9) 123.7(6) Mn(II)/Mn(III) [46] B/3 1.267(5) 1.258(4) 1.333(4) 122.6(3) C/1 1.306(6) 1.295(8) 1.323(9) 115.3(5) Nb(V) [47] B/2 1.304(7) 1.278(8) 1.33(1) 120.8(6) Nd(III) C/2 1.307(5) 1.250(6) 1.347(6) 119.1(4) [48] Ni(II) B/2 1.264(3) 1.255(3) 1.368(3) 129.0(2) [49] Ni(II) B/2 1.27(2) 1.22(2) 1.44(2) 130(1) Ni(II) M/1 1.263(8) 1.24(1) 1.37(1) 127.3(6) [50] Ni(II) M/1 1.286(4) 1.254(3) 1.361(4) 124.6(3) [51] Ni(II) D/1 1.340(2) 1.229(2) 1.360(2) 123.7(2) [52] Ni(II) B/2 1.325(7) 1.322(8) 1.291(8) 118.6(5) [53] Ni(II) M/1 1.288(2) 1.243(2) 1.372(2) 124.7(1) [54] Ni(II) M/1 1.280(3) 1.211(4) 1.388(4) 126.5(3) [55] Ni(II) M/1 1.288(2) 1.233(2) 1.387(2) 126.5(1) [56] Ni(II) C/1 1.284(4) 1.239(4) 1.385(4) 124.2(3) Pd(II) D/1 1.316(2) 1.219(2) 1.401(3) 124.2(2) [57] Pd(II) M/1 1.299(4) 1.230(5) 1.382(5) 125.0(3) [58] Pt(IV) M/1 1.326(4) 1.235(4) 1.354(4) 125.1(3) Pt(IV) M/1 1.323(3) 1.240(2) 1.346(3) 125.4(2) [59] Pt(IV) M/1 1.335(4) 1.233(4) 1.344(4) 125.0(3) Pt(IV) M/1 1.325(5) 1.219(5) 1.354(6) 126.1(4) Pt(IV) M/1 1.321(3) 1.236(3) 1.340(3) 125.8(2) [60] Pt(IV) M/1 1.310(4) 1.242(5) 1.346(5) 124.6(4) [61] Pt(IV) M/1 1.327(4) 1.249(5) 1.336(6) 125.0(3) Re(I) M/1 1.27(1) 1.25(1) 1.40(1) 125.1(7) [62] S7 Rh(III) C/1 1.281(4) 1.263(4) 1.352(4) 119.6(3) [63] Ru(II) C/1 1.28(3) 1.24(3) 1.39(4) 123(3) [64] Ru(II) M/1 1.301(5) 1.229(5) 1.457(6) 127.3(4) [65] Ru(II) M/1 1.281(2) 1.243(2) 1.390(2) 126.5(1) [66] Sc(III) M/1-c 1.318(5) 1.209(5) 1.425(5) 124.3(4) [67] C/1 1.289(6) 1.255(7) 1.364(9) 120.4(5) Sm(III) B/2 1.273(4) 1.270(6) 1.358(6) 123.4(4) [23] B/3 1.304(4) 1.262(4) 1.345(6) 121.6(3) Sn(II) M/1 1.304(3) 1.238(3) 1.366(2) 121.7(2) [68] C/1 1.280(3) 1.272(3)
Load more

Recommended publications
  • Dalton Transactions Accepted Manuscript
    Dalton Transactions Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/dalton Page 1 of 13 PleaseDalton do not Transactions adjust margins Dalton Transactions PERSPECTIVE Rare-Earth Metal πππ-Complexes of Reduced Arenes, Alkenes, and Alkynes: Bonding, Electronic Structure, and Comparison with Received 00th January 20xx, Accepted 00th January 20xx Actinides and Other Electropositive Metals a,b a,c DOI: 10.1039/x0xx00000x Wenliang Huang, and Paula L. Diaconescu www.rsc.org/ Rare-earth metal complexes of reduced π ligands are reviewed with an emphasis on their electronic structure and bonding interactions. This perspective discusses reduced carbocyclic and acyclic π ligands; in certain categories, when no example of a rare-earth metal complex is available, a closely related actinide analogue is discussed.
    [Show full text]
  • Gold(I)-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes
    Gold(I)-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes by Seong Du Lee Department of Chemistry Duke University Date:_______________________ Approved: ___________________________ Ross A. Widenhoefer, Supervisor ___________________________ Jiyong Hong ___________________________ Katherine J. Franz ___________________________ Qiu Wang Dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry in the Graduate School of Duke University 2012 i v ABSTRACT Gold(I)-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes by Seong Du Lee Department of Chemistry Duke University Date:_______________________ Approved: ___________________________ Ross A. Widenhoefer, Supervisor ___________________________ Jiyong Hong ___________________________ Katherine J. Franz ___________________________ Qiu Wang An abstract of a dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry in the Graduate School of Duke University 2012 i v Copyright by Seong Du Lee 2012 Abstract Numerous methodologies for efficient formation of carbon-nitrogen bonds have been developed over the decades due to the widespread importance of nitrogen containing compounds in pharmaceuticals and bulk commercial chemicals. Among many methods, hydroamination, in particular, has attracted considerable attention owing to its high atom economy and use of simple C-C substrates. As a result, numerous methods for hydroamination have been reported which employ a range of metal catalysts. However, the hydroamination of unactivated alkenes remains an unsolved challenge owing to the low reactivity of the C=C double bond. The recent development of gold(I) as an effective π-activation catalyst prompted us to develop efficient gold (I)-catalyzed methods for enatioselective intra- and intermolecular hydroamination of unactivated alkenes.
    [Show full text]
  • Lanthanide Chalcogenolate Complexes: Syntheses, Structures
    中国科技论文在线 http://www.paper.edu.cn Coordination Chemistry Reviews 250 (2006) 2059–2092 Review Lanthanide chalcogenolate complexes: Syntheses, structures and applications in organic chemistry Hong-Xi Li a, Yan-Jun Zhu a, Mei-Ling Cheng a, Zhi-Gang Ren a, Jian-Ping Lang a,b,∗, Qi Shen a a Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Engineering, Suzhou University, Suzhou 215123, Jiangsu, PR China b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, Jiangsu, PR China Received 18 October 2005; accepted 9 February 2006 Available online 23 February 2006 Contents 1. Introduction ........................................................................................................... 2060 2. Methods of preparation ................................................................................................. 2060 2.1. Protonolysis reaction ............................................................................................. 2060 2.2. Salt metathesis reaction........................................................................................... 2062 2.3. Oxidation–reduction reaction ..................................................................................... 2063 2.3.1. Oxidation reaction of divalent lanthanocene complexes ...................................................... 2063 2.3.2. Reaction of elemental lanthanide and REER ................................................................ 2065 2.3.3. Reaction of Ln/M amalgam with REER and trans-metallation
    [Show full text]
  • A Dissertation Entitled the Study of Lanthanides for Organometallic And
    A Dissertation entitled The Study of Lanthanides for Organometallic and Separations Chemistry by Andrew Charles Behrle Submitted to the Graduate Faculty as partial fulfillment of the requirements for the Doctor of Philosophy Degree in Chemistry _____________________________________ Dr. Joseph A. R. Schmidt, Committee Chair ____________________________________ Dr. Mark R. Mason, Committee Member ____________________________________ Dr. Steven J. Sucheck, Committee Member ____________________________________ Dr. Constance A. Schall, Committee Member ____________________________________ Dr. Patricia R. Komuniecki, Dean College of Graduate Studies The University of Toledo December 2012 Copyright 2012, Andrew Charles Behrle This document is copyrighted material. Under copyright law, no parts of this document may be reproduced without the expressed permission of the author. An Abstract of The Study of Lanthanides for Organometallic and Separations Chemistry by Andrew Charles Behrle Submitted to the Graduate Faculty as partial fulfillment of the requirements for the Doctor of Philosophy Degree in Chemistry The University of Toledo December 2012 Part 1. The effective use of f-element complexes as catalysts for reactions such as hydroamination and hydrophosphination has been demonstrated in many recent reports. Unfortunately, the homoleptic starting materials underpinning this chemistry are generally derived from only a handful of ligands. That is, of the homoleptic lanthanide complexes that exist, the majority make use of alkylsilane (-CH2SiMe3), silylamide (- N(SiMe3)2), or benzyl (-CH2C6H5) derivatives. The paucity of tri-alkyl lanthanide complexes can be attributed to the required extended coordination sphere and high Lewis acidity or electrophilicity of these metals. While these properties make lanthanum alkyl complexes very reactive, in turn they also make their synthesis and manipulation quite challenging.
    [Show full text]
  • Synthesis, Structure, and Reactivity of Early Transition Metal
    SYNTHESIS, STRUCTURE, AND REACTIVITY OF EARLY TRANSITION METAL PRECATALYSTS BEARING (N,O)-CHELATING LIGANDS by Philippa Robyn Payne B.Sc., University of Ottawa, 2008 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY in THE FACULTY OF GRADUATE AND POSTDOCTORAL STUDIES (Chemistry) THE UNIVERSITY OF BRITISH COLUMBIA (Vancouver) December 2013 © Philippa Robyn Payne, 2013 ABSTRACT The synthesis, structure, and reactivity of early transition metal complexes containing (N,O)-chelating ancillary ligands are described. The ligands investigated include ureates, pyridonates, amidates, and sulfonamidates. These related ligands generate four-membered metallacycles when bound to the metal center in a κ2-(N,O) fashion. The zirconium and tantalum complexes have been examined in terms of their activity and selectivity as precatalyst systems for hydroamination or hydroaminoalkylation. A chiral cyclic ureate ligand has been synthesized from enantiopure L-valine for application in zirconium-catalyzed asymmetric hydroamination of aminoalkenes. Chiral zirconium complexes, prepared in situ from two equivalents of the urea proligand and tetrakis(dimethylamido) zirconium, promote the formation of pyrrolidines and piperidines in up to 12% ee. Isolation of an asymmetric bimetallic zirconium complex containing three bridging ureate ligands confirms that ligand redistribution occurs in solution and is most likely responsible for the low enantioselectivities. Mechanistic investigations focusing on the hydroaminoalkylation reactivity promoted by a bis(pyridonate) bis(dimethylamido) zirconium precatalyst expose a complex catalytic system in solution. Stoichiometric investigations reveal the formation of polymetallic complexes upon addition of primary amines. The kinetic and stoichiometric investigations are most consistent with a bimetallic catalytically active species. A series of mono(amidate) tantalum amido complexes with varying steric and electronic properties have been synthesized via protonolysis.
    [Show full text]
  • 1 Michael Franz Lappert 1928 -2014 Archive of Publications This List Of
    Michael Franz Lappert 1928 -2014 Archive of Publications This list of references has been compiled from a database obtained form Mendeley and cross- checked against a list of publications made by Mike himself, and lent by Lorna Lappert. It includes a number of early book reviews, and chapters written in books edited by other authors. Patents and some contributions to Inorganic Reactions and Methods and Journal of Organometallic Chemistry Library have been omitted. Braces indicating cyclic structures have been omitted from linear typed formulae, so care should be taken if titles of papers are copied without reference to the original journals. J David Smith August 2018 (1) Gerrard, W.; Lappert, M. F. Interaction of Alcohols and Boron Trichloride. J. Chem. Soc. 1951, 2545–2550. (2) Gerrard, W.; Lappert, M. F. Interaction of Boron Trichloride with Optically Active Alcohols and Ethers. J. Chem. Soc. 1951, 1020–1024. (3) Gerrard, W.; Lappert, M. F. Preparation of Alkyl Borates by Means of Pyridine-Boron Trichloride Complex. Chem. Ind. 1952, (3), 53–55. (4) Gerrard, W.; Lappert, M. F. Fission of Mixed Ethers by Boron Trichloride. J. Chem. Soc. 1952, 1486–1490. (5) Lappert, M. F. Studies with Boron Trichloride and Organic Sulphides .1. The Preparation and Properties of Di-N-butyl Sulphide-Boron Trichloride. J. Chem. Soc. 1953, 2784–2788. (6) Lappert, M. F. Reaction Sequences in Alcohol Boron Trichloride Pyridine Systems. J. Chem. Soc. 1953, 667–673. (7) Gerrard, W.; Lappert, M. F. The Preparation and Stability of Alkyl Dichloroboronites. J. Chem. Soc. 1955, 3084–3088. (8) Colclough, T.; Gerrard, W.; Lappert, M.
    [Show full text]
  • Intramolecular Alkene Hydroaminations
    Intramolecular alkene hydroaminations mediated by simple group 3 metal complexes: the development of non-lanthanocene-based catalysts by Young Kwan Kim A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemistry Montana State University © Copyright by Young Kwan Kim (2003) Abstract: Metallocene-based Group 3 metal complexes; lanthanocenes, have intrinsic problems for use as a universal catalysis. For example, preparations of most complexes are complicated, and most lanthanocenes are extremely sensitive to air and water and have structural limitation on variation. The first application of non-metallocene-based Group 3 metal catalysts to intramolecular aminoalkene cyclizations has been achieved. Simple amido lanthanide complexes of the type Ln[N(TMS)2]3 (Ln = Y, Nd) have been found to be competent catalysts for this reaction, which have similar or superior activity in cyclization including diastereoselectivity to the lanthanocenes. Modification of the metal center in Ln [N(TMS)2]3 (Ln = Y, Nd, La) has been readily achieved by amine elimination in the presence of hindered chelating diamines, bis(thiophosphinic) amines, or bis(thioenamides) in situ, to provide new Group 3 amido chelates. These complexes have shown remarkably improved catalytic activities and stereoselectivities [e.g., 33:1 (trans/cis)\ in the cyclization of 2-aminohex-5-ene. An X-ray crystallographic structure of one of the bis(thiophosphinic amide)-based Group 3 metal complexes has been defined. Chiral lanthanide complexes have been implemented for enantioselective hydroamination reactions. The C2 symmetric catalysts exhibit good enantioselectivity in the cyclization of l-amino-2,2-dimethylpent-5-ene, as high as 66% enantiomeric excess at 10 °C.
    [Show full text]
  • Recent Developments in Enantioselective Lanthanide-Catalyzed Transformations Helene Pellissier
    Recent developments in enantioselective lanthanide-catalyzed transformations Helene Pellissier To cite this version: Helene Pellissier. Recent developments in enantioselective lanthanide-catalyzed transformations. Co- ordination Chemistry Reviews, Elsevier, 2017, 336, pp.96-151. 10.1016/j.ccr.2017.01.013. hal- 01612105 HAL Id: hal-01612105 https://hal.archives-ouvertes.fr/hal-01612105 Submitted on 16 Apr 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Coordination Chemistry Reviews 336 (2017) 96–151 Contents lists available at ScienceDirect Coordination Chemistry Reviews journal homepage: www.elsevier.com/locate/ccr Review Recent developments in enantioselective lanthanide-catalyzed transformations Hélène Pellissier Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France article info Article history: Received 22 December 2016 Ó 2017 Elsevier B.V. All rights reserved. Accepted 31 January 2017 Available online 2 February 2017 Keywords: Lanthanides Rare earth metals Asymmetric catalysis Enantioselectivity Chirality Enantioselective
    [Show full text]
  • Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging Σ- and Π‑Radical Lanthanide Dichalcogenides Conrad A
    This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. pubs.acs.org/IC Article Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π‑Radical Lanthanide Dichalcogenides Conrad A. P. Goodwin, Benjamin L. L. Reant,́ Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills,* and Stephen Sproules* Cite This: Inorg. Chem. 2020, 59, 7571−7583 Read Online ACCESS Metrics & More Article Recommendations *sı Supporting Information 3−• ABSTRACT: The introduction of (N2) radicals into multinuclear lanthanide molecular magnets raised hysteresis temperatures by stimulating strong exchange coupling between spin centers. Radical ligands with larger donor atoms could promote more efficient magnetic coupling between lanthanides to provide superior magnetic properties. Here, we show that heavy chalcogens (S, Se, Te) are primed to fulfill these criteria. The moderately reducing Sm(II) †† †† complex, [Sm(N )2], where N is the bulky bis(triisopropylsilyl)- amide ligand, can be oxidized (i) by diphenyldichalcogenides E Ph (E †† 2 2 = S, Se, Te) to form the mononuclear series [Sm(N )2(EPh)] (E = S, 1-S; Se, 1-Se, Te, 1-Te); (ii) S8 or Se8 to give dinuclear †† μ η2 η2 †† μ [{Sm(N )2}2( - : -E2)] (E = S, 2-S2; Se, 2-Se2); or (iii) with Te PEt3 to yield [{Sm(N )2}( -Te)] (3). These complexes have been characterized by single crystal X-ray diffraction, multinuclear NMR, FTIR, and electronic spectroscopy; the steric bulk of N†† α dictates the formation of mononuclear complexes with chalcogenate ligands and dinuclear species with the chalcogenides.
    [Show full text]
  • Curriculum Vitae for Narayan S. Hosmane
    CURRICULUM VITAE NARAYAN S. HOSMANE HOME ADDRESS: BUSINESS ADDRESS: 663 Teal Court Dept. of Chemistry & Biochemistry DeKalb, Illinois 60115-6201 Northern Illinois University Phone: (815) 754-1205 DeKalb, Illinois 60115-2862 E-Mail: [email protected] Tel: 815-753-3556 / Fax: 815-753-4802 PLACE OF BIRTH: CITIZENSHIP: Gokarn, Southern India U.S.A. EDUCATION B.S. 1968 Karnatak University, Dharwar, India Organic, Inorganic and Physical Chemistry M.S. 1970 Karnatak University, Dharwar, India Inorganic Chemistry Ph.D. 1974 University of Edinburgh, Edinburgh, Scotland Organometallic/Inorganic Chemistry Ph.D. Thesis: Some Reactions of Stannic Chloride with Silicon Hydrides and Some Novel Group IV Derivatives of Mercury. E.A.V. Ebsworth as Research Advisor. RECORD OF EMPLOYMENT Postdoctoral Research Assistant, Queen’s University of Belfast 1974-75. Full-time research under the supervision of Professor Frank Glockling in the areas of methylmercurials in relation to toxicology and environmental pollution. Research Scientist, Catalysis Section, Lambeg Industrial Research Institute, Northern Ireland 1975-76. Supervised a group of chemists researching on odor and pollution control. Research Associate, Auburn University, Auburn, Alabama 1976-77. Full-time research under the supervision of Professors Frederic A. Johnson and William E. Hill in the area of synthetic and -2 kinetic studies of B10H10 and C2B10-carboranes. Research Associate, University of Virginia, Charlottesville, Virginia, 1977-79. Full-time research under the supervision of Professor Russell N. Grimes in the area of carboranes and metallacarboranes. Assistant Professor, Virginia Polytechnic and State University, Blacksburg, Virginia, 1979-82. Assistant Professor (tenure track), Southern Methodist University, 1982-1986. Sabbatical Leave from SMU, Sept.
    [Show full text]
  • Ions Across the Lanthanide Series in [K(2.2.2-Cryptand)][(C5me4h)3Ln] Complexes Tener F
    Article Cite This: Organometallics 2018, 37, 3863−3873 pubs.acs.org/Organometallics Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes Tener F. Jenkins, David H. Woen, Luke N. Mohanam, Joseph W. Ziller, Filipp Furche,* and William J. Evans* Department of Chemistry, University of California, Irvine, California 92697-2025, United States *S Supporting Information ABSTRACT: Although previous studies of the stabilization of Ln(II) ions across the lanthanide series have relied on fi Me3Si-substituted cyclopentadienyl ligands, we now nd surprisingly that these ions can also exist surrounded by three tetramethylcyclopentadienyl ligands. Reduction of the n tet tet 4f Ln(III) complexes, Cp 3Ln (Cp =C5Me4H) using potassium graphite in the presence of 2.2.2-cryptand (crypt) tet produces the Ln(II) complexes, [K(crypt)][Cp 3Ln] for Ln = La, Ce, Pr, Nd, Sm, Gd, Tb, and Dy, all of which were characterized by X-ray crystallography. These complexes display intense absorptions in the UV−visible−near IR region that are red-shifted compared to those of previously ′ 1− ′ characterized (Cp 3Ln) complexes (Cp =C5H4SiMe3). The thermal stability of these new Ln(II) complexes decreases with the size of the metal. ttt 20,21 ■ INTRODUCTION C5H2(CMe3)3 (Cp ) and the tris(aryloxide) mesitylene Ad,Me 3− 22,23 In recent years, the range of oxidation states available to the ligand, [( ArO)3mes] . Extensive crystallographic, rare-earth metals in crystallographically characterizable molec- spectroscopic, magnetic, and density functional theory ular complexes available for reactivity in solution has greatly (DFT) studies showed that the new Ln(II) ions in the n 1 expanded.1,2 Up until 2001, it was thought that only six tris(cyclopentadienyl) environments adopted 4f 5d electron 1,7−12,23−26 lanthanides could form crystallographically characterizable configurations.
    [Show full text]
  • Intramolecular Enantioselective Hydroamination Catalyzed by Rare Earth Binaphthylamides
    Journal of Organometallic Chemistry 696 (2011) 255e262 Contents lists available at ScienceDirect Journal of Organometallic Chemistry journal homepage: www.elsevier.com/locate/jorganchem Intramolecular enantioselective hydroamination catalyzed by rare earth binaphthylamides Jérôme Hannedouche a,b, Jacqueline Collin a,b,*, Alexander Trifonov c, Emmanuelle Schulz a,b,* a Univ Paris-Sud, Laboratoire de Catalyse Moléculaire, ICMMO, UMR 8182, Orsay, F-91405, France b CNRS, Orsay, F-91405, France c G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia article info abstract Article history: Asymmetric intramolecular hydroamination reaction is a stately way to prepare chiral nitrogen-con- Received 26 July 2010 taining heterocyclic compounds. We report in this account our personal contribution in this field with Received in revised form the synthesis of chiral amido rare-earth complexes. A new family of structurally defined heterobimetallic 2 September 2010 rare earth lithium ate complexes based on N-substituted binaphthylamido ligands was discovered that Accepted 3 September 2010 promoted the hydroamination/cyclization of aminoolefins with up to 87% ee. Available online 21 September 2010 Neutral rare earth amido and amido alkyl complexes could also be prepared and led to very active species. A more simple and reliable synthetic procedure was discovered towards the preparation of Keywords: Asymmetric intramolecular hydroamination heterobimetallic rare earth amido alkyl
    [Show full text]