Guidelines on Determining and Reporting Significant Figures
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Guidelines on Determining and Reporting Significant Figures Guidelines on Determining and Reporting Significant Figures in Chemical Measurements (Handbook) Ephraim Muchada Govere Environmental and Soil Chemistry Laboratory Department of Crop and Soil Sciences 116 Agricultural Sciences and Industries Buidling College of Agricultural Sciences The Pennsylvania State University, PA 16802 [email protected] About The Author Ephraim M. Govere, Ph.D., MBA., M.Ed., M.S., B.S., Grad. Cert. Ed., Cert. Ed. (CPAg, CPSSc). Dr. Ephraim Muchada Govere is certified both as a professional soil scientist and professional agronomist by A Federa- tion of Certifying Boards in Agriculture, Biology, Earth and Environmental Sciences (USA). He did his undergraduate studies at Oregon State University and graduate studies at the University of North Alabama, University of Zimbabwe, and the Pennsylvania State University. Dr. Govere’s experience includes: (1) education and extension officer for the Zimbabwe Forestry Commission, (2) visiting research associate at the International Fertilizer Development Center in Alabama, (3) scientist and lecturer in soil chemistry at the University of Zimbabwe, (4) chemist with Dynamac Interna- tional (Environmental Services) at the USA Environmental Protection Agency’s Western Ecology Division in Corvallis, Oregon, and (5) senior research technologist at The Pennsylvania State University. [email protected] I dedicate this handbook with love to my beautiful, understanding, and caring wife, Linda “Mai Nkosi” Govere; our two lovely deep-thinking daughters, Alexandra Shungudzo and Saunsuray Muchadei; and their ever calculating and determined brother, Nkosilathi Tendaishe. E.M.G. Disclaimer Mention or citation of trade names or commercial products and/or names of manufacturers or distributors in this pub- lication does not constitute an endorsement of the commercial products or services referenced herein. Registered www.JCE.DivCHED.org • Journal of Chemical Education Online 1 Guidelines on Determining and Reporting Significant Figures names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. www.JCE.DivCHED.org • Journal of Chemical Education Online 2 Guidelines on Determining and Reporting Significant Figures Preface The five basic factors that affect the quality of chemical measurements are sample collection, preservation, process- ing, analysis, and data reporting. Improper actions on any of the five factors may result in poor data from which poor judgments or decisions could be made. To improve quality of sample data there ought to be clear guidelines for performing all the five factors. This handbook is aimed at addressing one of the five factors, namely data report- ing. The main purpose of this handbook is to provide the theory and practice of determining, and intelligently re- porting and interpreting significant figures in chemical measurements. From a review of literature, it appears that many authors have forgotten or simply pay little attention to the importance of assigning proper significant figures to multi-digit, computer-generated results. Such ignorance or carelessness tends to result in misinforming the end us- ers of the reported results and may lead to incorrect data-based decisions. Thus this handbook serves as a quality assurance and quality control tool on significant figures. In preparing this handbook, an attempt was made to detail general and specific aspects of significant figures. A practical rather than a theoretical approach was followed. Even though computations are nowadays done using calculators and computers, the guidelines in this handbook are pre- sented as an explanation of how those numbers are determined rather than how one should do the calculations. De- tailed guidelines that can be carried out with minimum of difficulty by mathematically less sophisticated clients are presented. Because of the way the information is presented, this handbook is a valuable resource for teaching in schools and colleges, for training at research and extension support science laboratories, and as a reference for scien- tists and publishers. www.JCE.DivCHED.org • Journal of Chemical Education Online 3 Guidelines on Determining and Reporting Significant Figures Acknowledgements I would like to thank the American Chemical Society for the permission to use a number of examples from the Jour- nal of Chemical Education to illustrate guidelines on significant figures. My gratitude goes to Professor John W. Moore, Editor of the Journal of Chemical Education, for embracing the idea that fundamental handbooks like this one play a key role in promoting teaching and learning. Special thanks go to Reviewer # 1 who showed great atten- tion to detail and provided invaluable technical advice that substantially improved this handbook, and to Reviewer # 3 who urged me to add more examples to illustrate the guidelines presented in the handbook. To Professor Dan- iel D. Fritton, thank you for reading the final draft of the manuscript and offering helpful suggestions. Lastly, I would like to thank my former employer, Dynamac International (Environmental Services) at the USA Environ- mental Protection Agency’s Western Ecology Division in Corvallis, Oregon, for cultivating my interest in envi- ronmental analytical methods. www.JCE.DivCHED.org • Journal of Chemical Education Online 4 Guidelines on Determining and Reporting Significant Figures Contents About The Author-------------------------------------------------------------------------------------------------------------------1 Disclaimer ----------------------------------------------------------------------------------------------------------------------------2 Preface ---------------------------------------------------------------------------------------------------------------------------------3 Acknowledgements ------------------------------------------------------------------------------------------------------------------4 Contents ------------------------------------------------------------------------------------------------------------------------------5 List of Figures------------------------------------------------------------------------------------------------------------------------6 List of Tables ------------------------------------------------------------------------------------------------------------------------6 Unit 1: Introduction -----------------------------------------------------------------------------------------------------------------7 Unit 2: Learning Objectives--------------------------------------------------------------------------------------------------------9 Unit 3: The Definition of Significant Figures---------------------------------------------------------------------------------- 10 Unit 4: Importance of Determining Significant Figures ---------------------------------------------------------------------- 11 Unit 5: Guidelines on Determining Significant Figures in Chemical Measurements ------------------------------------ 15 Unit 6: Guidelines on Determining Significant Figures in Mathematical Calculations---------------------------------- 20 Unit 7: Guidelines on Rounding Off Chemical Measurements and Their Calculated Results -------------------------- 31 QA/QC Results for Environmental Samples -------------------------------------------------------------------- 38 Unit 8: Guidelines on Reporting a Value and Its Estimated Uncertainty -------------------------------------------------- 42 Unit 9: Guidelines on Reporting Significant Figures in Graph Interpretation--------------------------------------------- 54 Unit 10: Use of Significant Figures as a Quality Control Objective------------------------------------------------------- 63 Unit 11: Summary ---------------------------------------------------------------------------------------------------------------- 71 Literature Cited -------------------------------------------------------------------------------------------------------------------- 74 Appendix A: Practice Questions------------------------------------------------------------------------------------------------- 76 Appendix B: The Main Number System Used In Reporting Chemical Measurements---------------------------------- 81 Appendix C: Tolerances Of Measuring Devices------------------------------------------------------------------------------- 83 TOLERANCES ON CLASS A VOLUMETRIC FLASKS-------------------------------------------------------------------------- 83 TOLERANCES ON CLASS A VOLUMETRIC PIPETS (TRANSFER PIPETS) --------------------------------------------------- 83 TOLERANCES ON MEASURING GRADUATED PIPETS ----------------------------------------------------------------------- 84 TOLERANCES ON MEASURING SERIALIZED (GRADUATED) CLASS A CYLINDERS------------------------------------- 84 TOLERANCES ON MICROPIPETTORS ------------------------------------------------------------------------------------------ 84 TOLERANCES ON BOTTLE-TOP DISPENSERS -------------------------------------------------------------------------------- 86 TOLERANCES ON CLASS A BURETS------------------------------------------------------------------------------------------ 86 TOLERANCES ON ANALYTICAL BALANCES--------------------------------------------------------------------------------- 86 Appendix D – Answers To Problems In Appendix A. ----------------------------------------------------------------------- 87 www.JCE.DivCHED.org • Journal of Chemical Education Online 5