GORDON RESEARCH CONFERENCES frontiers of science 512 Liberty Lane, West Kingston, RI 02892 Phone: 401783-4011 Fax: 401783-7644 E-Mail: grc(a),grc.org % World Wide Web: http://www.grc.org founded in 1931

Nancy Ryan Gray, Ph.D. Director

2007 GORDON RESEARCH CONFERENCE on Inorganic Reaction Mechanisms FINAL PROGRESS REPORT DEPARTMENT OF ENERGY GRANT NO. DE-FG02-07ER15849 The Gordon Research Conference (GRC) on Inorganic Reaction Mechanisms was held at Four Points Sheraton, Ventura, CA from 2/18/2007 thru 2/23/2007. The Conference was well-attended with 100 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students.

In designing the formal speakers program, emphasis was placed on current unpublished research and discussion of the future target areas in this field. There was a conscious effort to stimulate lively discussion about the key issues in the field today. Time for formal presentations was limited in the interest of group discussions. In order that more scientists could communicate their most recent results, poster presentation time was scheduled. Attached is a copy of the formal schedule and speaker program and the poster program. In addition to these formal interactions, "free time" was scheduled to allow informal discussions. Such discussions are fostering new collaborations and joint efforts in the field.

I want to personally thank you for your support of this Conference. As you know, in the interest of promoting the presentation of unpublished and frontier-breaking research, Gordon Research Conferences does not permit publication of meeting proceedings. If you wish any further details, please feel free to contact me. Thank you.

Sincerely, Andreja Bakac Iowa State University Inorganic Reaction Mechanisms

Four Points Sheraton / Holiday Inn Express Feb 18-23, 2007

Organization Participation Status MAHOI M ABU-OMAR PURDUE UNIVERSITY Speaker Registered DONDE R ANDERSON CALIFORNIA INSTITUTE OF TECHNOLOGY Poster Presenter Registered ANDREJA BAKAC IOWA STATE UNIVERSITY Chair Registered R. TOM BAKER LOS ALAMOS NATIONAL LABORATORY Speaker Registered KEVIN BARNESE UNIVERSITY OF CALIFORNIA, LOS ANGELES Poster Presenter Registered JOHN E BERCAW CALIFORNIA INSTITUTE OF TECHNOLOGY Attendee Registered LISA M BERREAU UTAH STATE UNIVERSITY Speaker Registered SUZANNE A BLUM UNIV CALIFORNIA - IRVINE Attendee Registered SETH N BROWN UNIVERSITY OF NOTRE DAME Poster Presenter Registered WILLIAM H CASEY UNIVERSITY OF CALIFORNIA, DAVIS Speaker Registered MICHAEL CHEN OFFICE OF BASIC ENERGY SCIENCES/DOE Attendee Registered MINGMING CHENG IOWA STATE UNIVERSITY Poster Presenter Registered PAUL J CHIRIK Speaker Registered MALCOLM H CHISHOLM OHIO STATE UNIVERSITY Speaker Registered SUNHEE CHOI MIDDLEBURY COLLEGE Poster Presenter Registered MATTHEW D UNIVERSITY OF WISCONSIN-MADISON Poster Presenter Registered CHRISTIANSON CAROL CREUTZ BNL Poster Presenter Registered ALVIN L CRUMBLISS DUKE UNIVERSITY Discussion Registered Leader CHRISTOPHER C MASSACHUSETTS INSTITUTE OF TECHNOLOGY Speaker Registered CUMMINS FABIO DOCTOROVICH UNIVERSITY OF BUENOS AIRES Poster Presenter Registered LINDA H DOERRER BOSTON UNIVERSITY Poster Presenter Registered DANIEL L DUBOIS PACIFIC NORTHWEST NATIONAL LABORATORY Speaker Registered MARY R DUBOIS UNIVERSITY OF COLORADO Attendee Registered VINCENT A DURANTE W.L. GORE AND ASSOCIATES, INC Attendee Registered JAMES H ESPENSON IOWA STATE UNIVERSITY, EMERITUS Attendee Registered PATRICK J FARMER UNIVERSITY OF CALIFORNIA, IRVINE Poster Presenter Registered ULRICH FEKL UNIVERSITY OF TORONTO Poster Presenter Registered G. FERRAUDI UNIVERSITY OF NOTRE DAME Poster Presenter Registered RICHARD G FINKE COLORADO STATE UNIVERSITY Speaker Registered SAM FLEISCHMAN UNIVERSITY OF CALIFORNIA SANTA BARBARA Poster Presenter Registered MICHAEL D FRYZUK UNIVERSITY OF BRITISH COLUMBIA Attendee Registered SHUNICHI FUKUZUMI OSAKA UNIVERSITY Speaker Registered DAVID P GOLDBERG JOHNS HOPKINS UNIVERSITY Poster Presenter Registered WILLIAM H GONG BP Speaker Registered HARRY B GRAY CALIFORNIA INSTITUTE OF TECHNOLOGY Speaker Registered HAIRONG GUAN UNIVERSITY OF CINCINNATI Poster Presenter Registered MICHAEL B HALL TEXAS A&M UNIVERSITY Speaker Registered DANIEL J HARRISON UNIVERSITY OF TORONTO AT MISSISSAUGA Poster Presenter Registered JEREMY HARVEY UNIVERSITY OF BRISTOL Speaker Registered CORINNA R HESS UNIVERSITY OF CALIFORNIA, BERKELEY Poster Presenter Registered CRAIG L HILL EMORY UNIVERSITY Speaker Registered PATRICK HOLLAND UNIVERSITY OF ROCHESTER Poster Presenter Registered KUO-WEI HUANG BROOKHAVEN NATIONAL LABORATORY Poster Presenter Registered ELON AISON NORTH CAROLINA STATE UNIVERSITY Poster Presenter Registered BRIAN L JAMES UNIVERSITY OF BRITISH COLUMBIA Speaker Registered MICHAEL P JENSEN OHIO UNIVERSITY Poster Presenter Registered JASON M KEITH CALIFORNIA INSTITUTE OF TECHNOLOGY Poster Presenter Registered JOHN A KEITH CALTECH Poster Presenter Registered RHETTKEMPE UNIVERSITY OF BAYREUTH Poster Presenter Registered ILDIKO KEREZSI JUSTUS LIEBIG UNIVERSITY Poster Presenter Registered ALEXANDER M KHENKIN WEIZMANN INSTITUTE OF SCIENCE Poster Presenter Registered CHOSU KHIN UC SANTA BARBARA Poster Presenter Registered KARL KIRCHNER VIENNA UNIVERSITY OF TECHNOLOGY Poster Presenter Registered WILLEM H KOPPENOL ETH ZURICH Poster Presenter Registered CHANDRIKA P BARUCH COLLEGE-THE CITY UNIVERSITY OF NEW Poster Presenter Registered KULATILLEKE YORK MICHAEL LANCI JOHNS HOPKINS UNIVERSITY Poster Presenter Registered CLARK R LANDIS UNIVERSITY OF WISCONSIN Vice Chair Registered ANNA S LARSEN ITHACA COLLEGE Poster Presenter Registered GABOR LENTE UNIVERSITY OF DEBRECEN Poster Presenter Registered STEPHEN J. LIPPARD MASSACHUSETTS INSTITUTE OF TECHNOLOGY Speaker Registered DALE W MARGERUM PURDUE UNIVERSITY Discussion Registered Leader MANUEL MARTINEZ UNIVERSITAT DE BARCELONA Attendee Registered JAMES M MAYER UNIVERSITY OF WASHINGTON Speaker Registered DAN MEYERSTEIN COLLEGE OF JUDEA AND SAMARIA Poster Presenter Registered DANIEL J MINDIOLA INDIANA UNIVERSITY Poster Presenter Registered LESLIE J MURRAY MASSACHUSETTS INSTITUTE OF TECHNOLOGY Poster Presenter Registered WONWOO NAM EWHA WOMANS UNIVERSITY Speaker Registered RONNY NEUMANN WEIZMANN INSTITUTE OF SCIENCE Discussion Registered Leader JACK R NORTON COLUMBIA UNIVERSITY Discussion Registered Leader KATALIN OSZ UNIVERSITY OF DEBRECEN Poster Presenter Registered ANDREW A PACHECO UNIVERSITY OF WISCONSIN-MILWAUKEE Poster Presenter Registered OLEG E PESTOVSKY IOWA STATE UNIVERSITY Poster Presenter Registered JONAS C PETERS MIT Speaker Registered DAVID RICHENS UNIVERSITY OF ST ANDREWS Poster Presenter Registered JUSTINE ROTH JOHNS HOPKINS UNIVERSITY Speaker Registered MIRTARUBCIC UNIVERSITY OF ZAGREB Poster Presenter Registered ELENA V RYBAK-AKIMOVA TUFTS UNIVERSITY Poster Presenter Registered MELANIE SANFORD Speaker Registered RICHARD SCHULTZ BAR-ILAN UNIVERSITY Poster Presenter Registered FRANKLIN A SCHULTZ INDIANA UNIV PURDUE UNIV INDIANAPOLIS Poster Presenter Registered SUSANNAH L SCOTT UNIVERSITY OF CALIFORNIA, SANTA BARBARA Speaker Registered AYUSMAN SEN PENNSYLVANIA STATE UNIVERSITY Discussion Registered Leader KEVIN H SHAUGHNESSY UNIVESITY OF ALABAMA Speaker Registered LAWRENCE R SITA UNIVERSITY OF MARYLAND Poster Presenter Registered JEREMY M SMITH NEW MEXICO STATE UNIVERSITY Poster Presenter Registered WENJING SONG IOWA STATE UNIVERSITY Poster Presenter Registered SHANNON STAHL UNIVERSITY OF WISCONSIN-MADISON Discussion Registered Leader DAVID M STANBURY AUBURN UNIVERSITY Discussion Registered Leader THOMAS STRASSNER TU DRESDEN Poster Presenter Registered CHARLES E SUMNER EASTMAN CHEMICAL CO Poster Presenter Registered EWASZAJNA-FULLER IOWA STATE UNIVERSITY Poster Presenter Registered KLAUS H THEOPOLD UNIVERSITY OF DELAWARE Poster Presenter Registered RUDI VAN ELDIK UNIVERSITY OF ERLANGEN-NURNBERG Discussion Registered Leader DAVID VAN HORN UNIVERSITY OF MISSOURI-KANSAS CITY Poster Presenter Registered MICHAEL J VASBINDER IOWA STATE UNIVERSITY AND AMES LAB Poster Presenter Registered AVERY L WATKINS UNIVERSITY OF WISCONSIN-MADISON Poster Presenter Registered TIMOTHY T WENZEL DOW CHEMICAL Poster Presenter Registered YONG YANG BATTELLE, PNL Poster Presenter Registered TIMOTHY H ZAUCHE UNIVERSITY OF WISCONSIN- PLATTEVILLE Poster Presenter Registered MICHAEL J ZDILLA PURDUE UNIVERSITY Poster Presenter Registered

This conference focuses on kinetic, mechanistic, and thermodynamic studies of reactions that play a role in fields as diverse as catalysis, energy, bioinorganic chemistry, green chemistry, organometallics, and activation of small molecules (oxygen, nitrogen, carbon monoxide, carbon dioxide, alkanes). Participants from universities, industry, and national laboratories present results and engage in discussions of pathways, intermediates, and outcome of various reactions of inorganic, organic, coordination, organometallic, and biological species. This knowledge is essential for rational development and design of novel reactions, compounds, and catalysts.

The program has nine open slots for short poster talks. Everybody is welcome to apply for one of these by simply dropping a message to the Chair. The speakers will be selected by a committee shortly before the beginning of the conference. It is anticipated that the Chair will be able to provide financial aid toward travel expenses of those selected to speak.

SUNDAY 4:00 pm - 9:00 pm Arrival and Check-in 6:00 pm Dinner 7:30 pm - 7:40 pm Welcome / Introductory Comments by GRC Site Staff 7:40 pm-9:10pm METAL-MEDIATED OXIDATIONS Discussion Leader: Jack Norton (Columbia University) 7:40 pm-8:10pm Jim Mayer (University of Washington) "Metal-Mediated Oxidations of C-H and O-H Bonds: Moving Protons and Electrons" 8:10 pm-8:25 pm Discussion 8:25 pm- 8:55 pm Steve Lippard (MIT) "Dioxygen Activation and Hydrocarbon Oxidation at Carboxylate-Bridged Diiron Centers" 8:55 pm-9:10 pm Discussion 9:10 pm Chair's Reception MONDAY 7:30 am - 8:30 am Breakfast 8:3 0 am Group Photo 9:00 am -12:30 pm OXYGEN ACTIVATION AND ELECTRON TRANSFER Discussion Leader: David Stanbury (Auburn University) 9:00 am - 9:30 am Justine Roth (Johns Hopkins) "Towards a Predictive Understanding of Oxygen Activation in Chemical and Biological Systems" 9:30 am - 9:45 am Discussion 9:45 am - 10:15 am Mahdi Abu-Omar (Purdue) "New Vistas in High Valent Rhenium and Manganese Chemistry: Catalytic Reductions, Group Transfer, and Some Unexpected Mechanisms" 10:15 am - 10:30 am Discussion 10:30 am - 11:00 am Coffee Break 11:00 am - 11:30 am Bill Gong (BP Amoco) "The Catalytic Mechanism of the BP Mid-Century Oxidation for PTA Production" 11:30 am - 11:45 am Discussion 11:45 am - 12:15 pm Shunichi Fukuzumi (Osaka University) "Electron-Transfer Catalytic Systems of Metalloporphyrins" 12:15 pm- 12:30 pm Discussion 12:30 pm Lunch 1:30 pm - 4:00 pm Free Time 4:00 pm - 6:00 pm Poster Session 6:00 pm Dinner 7:30 pm-9:30 pm IRON Discussion leader: Rudi van Eldik (University of Erlangen) 7:30 pm - 8:00 pm Jonas Peters (Caltech) "A Mechanistic Basis for Multi-Electron Redox Reactions at Pseudotetrahedral Iron and Other First Row Ions" 8:00 pm -8:15 pm Discussion 8:15 pm - 8:45 pm Wonwoo Nam (Ewha Womans University) "Iron(IV)-Oxo Complexes of Heme and Nonheme Ligands" 8:45 pm - 9:00 pm Discussion 9:00 pm - 9:10 pm Poster Talk 1 9:10 pm -9:15 pm Discussion 9:15 pm - 9:25 pm Poster Talk 2 9:25 pm - 9:30 pm Discussion 9:30 pm Poster Session TUESDAY 7:30 am-8:30 am Breakfast 9:00 am- 12:30 pm HYDROGEN AND CARBON MONOXIDE Discussion leader: Ayusman Sen (Pennsylvania State University) 9:00 am - 9:30 am Michael Hall (Texas A&M University) "Activating Hydrogen in Enzymes and Model Complexes" 9:30 am - 9:45 am Discussion 9:45 am- 10:15 am Brian James (University of British Columbia) "The Latest on Catalyzed Imine Hydrogenations" 10:15am- 10:30 am Discussion 10:30 am- 11:00 am Coffee Break 11:00 am- 11:30 am Tom Baker (Los Alamos National Laboratory) "Chemical Hydrogen Storage: Mechanistic Studies Of Catalyzed Dehydrocoupling Of Amine-Boranes" 11:30 am- 11:45 am Discussion 11:45 am- 12:15pm Dan DuBois (Pacific Northwest National Laboratory) "Combining Transition-Metal Hydride Thermodynamics and Proton Relays in Catalysis" 12:15 pm- 12:30 pm Discussion 12:30 pm Lunch 1:30 pm-4:00 pm Free Time 4:00 pm - 6:00 pm Poster Session 6:00 pm Dinner 7:30 pm-9:30 pm BIOINORGANIC Discussion leader: Al Crumbliss (Duke University) 7:30 pm-8:00 pm Jeremy Harvey (University of Bristol) "Spin-State Changes In Bioinorganic Chemistry. Minor Mechanistic Footnotes Or Key Factors?" 8:00 pm-8:15pm Discussion 8:15 pm- 8:45pm Lisa Berreau (Utah State University)

8:45 pm-9:00 pm "Dioxygen Reactivity of Ni(II) Cis-beta-Keto-Enolate Complexes" 9:00 pm-9:10pm Discussion 9:10 pm-9:15 pm Poster Talk 3 9:15 pm-9:25 pm Discussion 9:25 pm-9:30 pm Poster Talk 4 9:30 pm Discussion Poster Session WEDNESDAY 7:30 am - 8:30 am Breakfast 9:00 am -12:30 pm ORGANOMETALLICS Discussion leader: Clark Landis (University of Wisconsin - Madison) 9:00 am - 9:30 am Susannah Scott (UC Santa Barbara) "Activation Of Polymerization Catalysts By Interaction With Oxide Surfaces" 9:30 am - 9:45 am Discussion 9:45 am - 10:15 am Kevin Shaughnessy (University of Alabama) "Organometallic Reaction Mechanisms in Non-Traditional Solvents: Fundamental Studies and Applications to Catalysis" 10:15 am - 10:30 am Discussion 10:30 am - 11:00 am Coffee Break 11:00 am - 11:30 am Melanie Sanford (University of Michigan) "Mechanistic Studies of Reductive Elimination Reactions from Palladium(TV) and Platinum(IV) Centers" 11:30 am - 11:45 am Discussion 11:45 am - 12:15 pm Malcolm Chisholm (Ohio State University) "Metal-Catalyzed Synthesis Of Cyclic Esters And Cyclodepsipeptides From Lactides And 2,5-Morpholinediones" 12:15 pm - 12:30 pm Discussion 12:30 pm Lunch 1:30 pm - 4:00 pm Free Time 4:00 pm - 6:00 pm Poster Session 6:00 pm Dinner 7:00 pm - 7:30 pm Business Meeting (Nominations for the next Vice Chair; Fill out Conference Evaluation Forms; Discuss future Site & Scheduling preferences; Election of the next Vice Chair) 7:30 pm 9:30 pm NITROGEN AND PHOSPHORUS Discussion leader: Shannon Stahl (University of Wisconsin - Madison) 7:30 pm - 8:00 pm Paul Chirik (Cornell) "Dinitrogen Functionalization with Group 4 Metallocenes: Kinetics, Mechanisms and Other Good Stuff 8:00 pm -8:15 pm Discussion 8:15 pm - 8:45 pm Christopher Cummins (MIT) "Experiments Aimed at the Generation and Trapping of the Diphosphorus Molecule" 8:45 pm - 9:00 pm Discussion 9:00 pm - 9:10 pm Poster Talk 5 9:10 pm - 9:15 pm Discussion 9:15 pm - 9:25 pm Poster Talk 6 9:25 pm - 9:30 pm Discussion 9:30 pm Poster Session TIUKSDAY 7:30 am-8:30 am Breakfast 9:00 am- 12:30 pm POLYOXOMETALATES AND OTHER CLUSTERS Discussion leader: Ronny Neumann (Weizmann Institute of Science) 9:00 am - 9:30 am Craig Hill (Emory) "Noble Metal-Oxo Complexes Realized. New Catalysts for Selective 02- Only Oxidations" 9:30 am - 9:45 am Discussion 9:45 am-10:15 am William Casey (UC Davis) "Why Small? Nanometer-Size Aqueous Metal-Oxo Clusters as Minerals" 10:15 am- 10:30 am Discussion 10:30 am- 11:00 am Coffee Break 11:00 am- 11:30 am Richard Finke (Colorado State University) "Nanocluster Self-Assembly Formation and Agglomeration: Kinetic and Mechanistic Studies" 11:30 am- 11:45 am Discussion 11:45 am - 11:55 am Poster Talk 7 11:55 am- 12:00 pm Discussion 12:00 pm- 12:10 pm Poster Talk 8 12:10pm- 12:15 pm Discussion 12:15 pm - 12:25 pm Poster Talk 9 12:25 pm- 12:30 pm Discussion 12:30 pm Lunch 1:30 pm - 4:00 pm Free Time 4:00 pm - 6:00 pm Poster Session 6:00 pm Dinner 7:30 pm - 9:00 pm SPECIAL LECTURE Discussion leader: Dale Margerum (Purdue) 7:30 pm-8:30 pm Harry Gray (Caltech) "Solar Photochemistry" 9:30 pm - 9:00 pm Discussion 9:00 pm Poster Session FRIDAY 7:30 am - 8:30 am Breakfast 9:00 am Depart

Last Updated FINANCIAL ASSISTANCE PROPERTY CERTIFICATION

AWARDEE Gordon Research Conferences AWARD NO DE-FG02-07ER15849 2007 Inorganic Reaction Mechanisms

The DOE Assistance Rules, 10 CFR 600, define property acquired under the terms of the award as either exempt (purchased with DOE operating dollars) or non-exempt (acquired with DOE capital equipment dollars, Government- furnished or acquired from the Government excess property lists) Non-exempt property is normally identified in the award document as Government-owned and requires a Semi-Annual Summary Report of DOE-Owned Plant and Capital Equipment to be submitted annually pursuant to DOE regulations

In order to facilitate grant closeout, please review your property records and complete the applicable Item I, for exempt property, or Item II, for non-exempt property, of this certificate and return it to the Contractmg Officer as soon as possible

I There was no reportable residual exempt property of any description at the completion of this award

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TITLE Director

II A final inventory of residual non-exempt property is enclosed for the category (or categories) checked below

( ) A NONEXPENDABLE PERSONAL PROPERTY, Federally-Owned (acquired with Capital Equipment funds, Government-furnished equipment, or through excess)

( ) B EXPENDABLE PERSONAL PROPERTY (SUPPLIES), if fair market value exceeds $5,000

Except for the category (categories) checked above, no other reportable residual property Of any description remained on this award at its completion

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TITLE Director DATE 04/15/08

AA-88 01/03 PATENT CERTIFICATION

Gordon Research Conferences Awardee I I Interim Certification

DE-FGQ2-07ER15849 DOE Prime and/or Subcontract Nos. Final Certification

Awardee hereby certifies unless indicated to the contrary, that:

1. All procedures for identifying and disclosing subject inventions as required by the patent clause of the contract have been followed throughout the reporting period.

2. There were no subcontracts or purchase orders involving research, development, and demonstration except as follows: (a separate certification must be provided to DOE for each subcontract or purchase order awarded.)

3. No inventions or discoveries were made or conceived in the course of or under this contract other than the following (Certification includes O, does not include Q all subcontracts):

TITLE INVENTOR DATE REPORTED DOE "S" NO.*

NONE

4. The completion date of this contract is as follows: February 14, 2008

5. The following period is covered by this certification:

02/15/2007 to 02/14/2008

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West Kingston. RI02892 04/15/08 Address Date of Certification

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NOTE: A positive certification for this Item 3 does not negate the requirement for furnishing to DOE a fully executed Patent Certification from each subawardee identified in Item 2. FINANCIAL STATUS REPORT (Follow instructions on the back )

1 FEDERAL AGENCY AND ORGANIZATIONAL 2 FEDERAL GRANT OR OTHER OMB Approved ELEMENT TO WHICH REPORT IS SUBMITTED IDENTIFYING NUMBER No 80-R0180 DOE DE-FG02-07ER15849

3 RECIPIENT ORGANIZATION (Name and complete 4 EMPLOYER IDENTIFICATION NUMBER address, including ZIP code) 050300482

5 RECIPIENT ACCOUNT NUMER OR IDENTIFYING NO Gordon Research Conferences 512 Liberty Lane West Kingston, RI 02892-0984 5 FINAL REPORT 7 BASIS X YES NO X CASH ACCRUAL PROJECT/GRANT PERIOD (See instructions) 9 PERIOD COVERED BY THIS REPORT FROM (Month, day, year) TO (Month, day, year) FROM (Month, day, year) TO (Month, day, year) 02/15/2007 02/14/2008 02/15/2007 02/14/2008 10 STATUS OF FUNDS a Net outlays previously reported 0 00 b Total outlays this report period 5,000 c Less Program income credits 0 00 d Net outlays this report period (Line a minus line c) 5,000 e Net outlays to date (Line a plus line d) 5,000 f Less Non-Federal share of outlays 0 g Total Federal share of outlays (Line e minus line f) 5,000 h Total unliquidated obligations 0 00 Less Non-Federal share of unliquidated obligations shown on line h 0 00 j Federal share of unliquidated obligations (Line h minus line I) 0 00 k Total Federal share of outlays and unliquidated obligations (Line g plus j) 5,000 Total cumulative amount of Federal funds authorized 5,000 m Unobligated balance of Federal funds (Line 1 minus line k) 0 00 11 a TYPE OF RATE INDIRECT (Place "X" m appropriate box) PROVISIONAL PREDETERMINED X FINAL EXPENSE FIXED NONE b RATE c BASE d TOTAL AMOUNT e FEDERAL SHARE 12 REMARKS (Attach any explanations deemed necessary or information required by Federal sponsonng agency m compliance with governing legislation)

2007 Inorganic Reaction Mechanisms

13 CERTIFICATION SIGNATURE OF AUTHORIZED CERTIFYING DATE REPORT SUBMITTED I certify to the best of my knowledge OFFICIAL and belief that this report is correct 04/15/08 and complete and that all outlays and unliquidated obligations are for the TELEPHONE (Area code, number, and extension) purposes set forth in the award documents Nancy Ryan Gray, 401-360-1519 DISTRIBUTION Copy 1 - Official Grant File STANDARD FORM 269 (7-76) Copy 2 - Grants Section, FAAB Prescribed by Office of Management and Budget Copy 3 - Grantee Cir No A-110 Form Approved OMB No. 1902-0121