CONTENTS SUBJECT

INTRODUCTION 1

MANGANESE COMPOUNDS 3 Cyclopentadienyl Tricarbonyl-Processes 3 Basic Process 3 Dianiline Manganese Tricarbonyl Bromide 8 Manganese Pentacarbonyl . 9 Manganous Salts of Organic Acids 11 Ammonia Manganese Carbonyl Halides 13 Tris(Cyclopentadienyl) Aluminum Compounds 15 Ionic Aromatic Compounds of Transitior; Metals 16 Freshly Reduced Manganese for Vapor Phase Reaction 19 Carbon Monoxide Reaction in the Presence of Hydrogen 21 .1 -- Bis(Cyclopentadienyl) Manganese-CO Reaction at High Temperature 23 Concurrent Reaction of Magnesium, Cyclopentadiene and CO 23 Transition Metal Carbonyls as Catalyst 26 Sodium Metal as Reducing Agent 26 Natural Gas Fuel 28 Molybdenum Naphthenate as Antifoulant Compound 29 lsovaleryl Acetone Coadditive 31 Cyclopentadienyl Tricarbonyl-Derivatives 34 Mercurated Products 34 (p-Toly Isulfamoy1) -Substituted Compounds 36 Alkali Metal Salts of Carboxylic Acids 37 I Tridentate Ether Coordinated Compound 38 Silylorgarrocyclopentadieny l Manganese Tricarbony Is 40 Di(Cyclopentadieny1 Manganese Tricarbonyl) Ketone 42 Acy lcyclopentadieny I Tricarbony Is 44 Bromoacety lcyclopentadieny l Manganese Tricarbony l 44 Monoacetylmethylcyclopentadienyl Manganese Tricarbonyl 46 Vinylcyclopentadienyl Manganese Tricarbonyl 49 Ester Condensation Products 50 lndole Compounds Using Phenyl Hydrazone Derivatives 52

?' X Contents and Subject Index $ Contenl, Other Carbonyl Compounds 54 I Hydropentalenyl Tricarbonyl 54 Diaromatic lron Complexes Pentaleny l Tricarbony l 56 Ferrous Picrate and Picric Aci Cyclohexadienyl Tricarbonyl 57 Polycyclic Fused Ring Cornpc, Tricarbonyl Chloride Bis(Tripheny1phosphine) 58 I Fuel Compositions Mercaptomanganese Tricarbonyl 59 I Dicyclopentadienyl Iron Polytertiary Phosphite Tricarbonyl 61 I Dicyclopentadienyl Iron and 1 Organophosphorus, Arsenic and Antimony Derivatives 62 Stable lron Carbonyl Solutior, Aromatic Cyanomanganese Dicarbonyl 63 , Wear Inhibitor Coadditives Dimanganese Decacarbonyl 64 I Cyclohexylamine Acetylmanganese Tetracarbonyl 65 J NICKEL AND COBALT COMPOL Alkyl and Aralkyl Pentacarbonyl 66 Nickel Bimetallic Compounds 68 Bis(Cyclomatic Nickel) Acety Triphenyltin Manganese Pentacarbonyl 68 DicyclopentadienylNickel ' Triphenyltin Manganese Tetracarbonyl Triphenylphosphine 70 Dicyclopentadienyl Dinickel I Triphenyltin Manganese Tricarbonyl Tetraphenylcyclopentadienone 72 Cyclopentadienyl Nickel Cycl Trichlorotin Manganese Tetracarbonyl Triphenylphosphine 73 Cyclopentadienyl Nickel Nitr; Tin Manganese Carbonyl Halides 7 4 Cyclopentadienyl Nickel Trip Other Manganese Compounds 75 Phosphorus and Arsenic Triin Cyclopentadienyl Manganese Diphenyl 75 Cobalt Bis(Cyclopentadienyl) Manganese 78 Cyclopentadienyl Cobalt Cyc, Cyclopentadienyl Group I I Metal Halides 8 1 Cyclopentadienyl Cobalt 1,3- Azulene 82 Propargyl Alcohol Dicobalt H Coba It Complexes of Phosphc IRON COMPOUNDS General Processes I Dicyclopentadienyl Compounds Reduction of Bis(Cyclopenta~ Maleic Anhydride and Cyclic Ether Adducts Bis(Trifluoromethyl)-l,2-Ditt' Bridged Bicyclic Ethers Heavy Metal Diketonates a-Hydroxy-a-Phenyl-1,l'-Trimethyleneferrocene Dimers of Trimethy leneferrocene I MOLYBDENUM, VANADIUM A9 Alkyl Substituted Compounds Molybdenum Aminoalkyl Substituted Compounds I 2,5,8-Trioxanonane Molybder Hydroxyalkyl Substituted Compounds ,I Dicyclooctatetraene Molybdq Carboxy Su stituted Compounds Tris(Dimethy1formamide)Mi Acetoacetyl Derivatives Cycloheptatriene Cornpoundj Formaldehyde Reaction Products Fu lvene-MolybdenumCarb~fl Bis(Cyclopentadienyl Iron)-Aldehyde Condensation Products Vanadium i Hydrogenation of Aromatic lron Cyclopentadienyl Compounds Cyclopentadienyl Vanadiu Dicyclopentadienyl Cyanocyclopentadienyl lron ' Nitrosy l Vanadium Tetracar Sily lorganometallocenes Titanium Bis(Silylmetallocene) Organic Materials Cyclopentadienyl Hydrocar Carbony l Compounds Dicyclopentadienyl Tita Cyclopentadiene lron Tricarbonyls General Processes-Several - Cyclopentadienyl lron Carbony l i Cyclopentadienyl Cornp Iron Carbonyl-Cyclopentadiene Complexes Norbornadiene Cyclopentadienyl Dicarbony l Acyls Metallo Derivatives of Acet Cyclopentadienyl lron Dicarbonyl Triphenyl Tin Metal H ydride-Unsaturated Allyl lron Tricarbonyl Halides Fluorinated Monoolefin Ca Cyclooctadiene lron Tricarbonyls Metal Carbonyl-Tet Cyclooctatetraene lron Tricarbonyl Heterolinear Tetrap lron Tetracarbonyl Complexes with Benzo(c)cinnoline OTHER METALS Other lron Compounds 7 Boron Borated Monoalkyl Dihyd

b Contents and Subject Index

Diaromatic Iron Complexes Ferrous Picrate and Picric Acid Polycyclic Fused Ring Compounds Fuel Compositions Dicyclopentadienyl lron Dicyclopentadienyl lron and Cyclopentadienyl Nickel Nitrosy Stable lron Carbonyl Solutions Wear Inhibitor Coadditives

NICKEL AND COBALT COMPOUNDS Nickel Bis(Cyclomatic Nickel) Acetylenic Compounds Dicyclopentadienyl Nickel Dicyclopentadienyl Dinickel Dicarbonyl Cyclopentadienyl Nickel Cyclopentyl Compounds Cyclopentadienyl Nickel Nitrosyl Compounds Cyclopentadienyl Nickel Triphenylphosphine Chloride Phosphorus and Arsenic Triimide Metal Compounds Cobalt Cyclopentadienyl Cobalt Cyclopentadiene Compounds Cyclopentadienyl Cobalt 1,3-Butadiene Propargyl Alcohol Dicobalt Hexacarbonyl Cobalt Complexes of Phosphorus Esters General Processes Reduction of Bis(Cyclopentadieny1)Compounds Bis(Trifluoromethyl)-1,2-Dithiolato Metal Chelates Heavy Metal Diketonates

MOLYBDENUM; VANADIUM AND TITANIUM COMPOUNDS Molybdenum 2,5,8-Trioxanonane Molybdenum Tricarbonyl Dicyclooctatetraene Molybdenum Tetracarbonyl Tris(Dimethy1formamide) Molybdenum Tricarbonyl Cycloheptatriene Compounds Fulvene-Molybdenum Carbonyl Reaction Products Vanadium Cyclopentadienyl Vanadium Tetracarbonyl Compounds Nitrosyl Vanadium Tetracarbonyl Compounds Titanium Cyclopentadienyl Hydrocarbosiloxy Titanium Compounds Dicyclopentadienyl Titanium Bromide General P,rocesses--Several Metals Cyclopentadienyl Compounds Norbornadiene Metallo Derivatives of Acetoacetic Acid Esters Metal Hydride-Unsaturated Fluorocarbon Reaction Products Fluorinated Monoolefin Carbonyl Compounds Metal Carbonyl-Tetracyclone Reaction Products Heterolinear Tetraphenylbutadiene Compounds

OTHER METALS Boron Borated Monoalky l Dihydroxybenzenes xii Contents and Subject Index Mesityl Oxide, 4~eth~l-4~e: Sodium Hexylene Glycol Monoborate Propionic and Butyric Acids Alky lboronic Acids Carbon Suboxides and Graph Alkanediol Esters of Alkylboronic Acids Dialkanolamine Boronic Acid Diesters Aminodiboron Compounds COMPANY INDEX Tris(Alkylamino)Boranes INVENTOR INDEX Poly(Pheny1phosphino-Phenylborane) Compounds U.S. PATENT NUMBER INDEX I Bis(Triphenylsily1) Phenylboronate Carbollyl Metal Complexes Lithium Lithium Alkenyl Succinates Lithium Salts of Alkoxy-Substituted Propionic and Butyric Acids Lithium 3-(Dibuty1amino)Propionate Lithium Salts of Alkylaminoalkylphenols Addition of Free Carboxylic Acid to Improve Solubility Amino-Amide Induction Assistant Alkali Metal Salts of Diarylcarbamates Selenium Diisobutyl Selenite Amine Salts of Selenic Acid Amine Salts of Selenious Acid Tin Octaphenyl-1,l '-Spirobistannole Hexamethyltin Tetrakis(P-Cyanoethy1)Tin (4-Bromo-l,3-cis,cis-Butadieny1)DimethyltinBromide Aromatic Chromium Tricarbonyl Compounds Rhodium Complexes Rare Earth Ketoenolate Compounds Cyclic Arsenic and Phosphorus Compounds

NONMETALLIC ADDITIVES Nitrogen-Containing Compounds Aminofulvenes Hydrogenated Quinolines and Indoles 4-Phosphinyl-4-Hydroxypiperidines N-Methyl-p-Fluoroaniline Methyl N-Methylanthranilate 1,3-Diimino-2-Hydroxypropanes N-Sulfinylamine Compounds N,N1-Dimethyl-p-Phenylenediamine Cyclic Nitroxides Substituted Phenols - Cresol and Branched Ethers Liquid Alkylphenols N-Methyl-p-Aminophenol Other Additives and Processes Peroxide-Free tert-Butyl Alcohol Methyl, lsopropyl and tert-Butyl Alcohols with Alkylate Thallium Formate-Alcohol-Water Compositions lsobutane Oxidation Diisopropyl Ether 2-Methyl-2-Methoxypropane from Mixed C, Stream Contents and Subject Index xiii

Mesityl Oxide, 4Methyl-4Penten-2-one and 2.4-Dimethylfuran Propionic and Butyric Acids Carbon Suboxides and Graphitic Oxide

COMPANY INDEX INVENTOR INDEX U.S. PATENT NUMBER INDEX