<<

Number 104

compiled by Veronica M. Cornel

Department of , Reedley College, 995 Reed Avenue, Reedley, California 93654

[email protected]

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index.

Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted.

This installment of Recent Reviews covers principally the latter part of the 2011 literature. Previous installment: J. Org. Chem. 2012, 71(1).

Additional Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in plain text that can be imported into Endnote (using Refer style) and Reference Manager databases.

Regularly Issued Journals and Series Volumes

Accounts of Chemical Research Santos, M. Zeolites and Other -Based Promoters in Carbohydrate Chemistry. 2010, 63, 29–99 1. Yu, J.; Shi, F.; Gong, L.-Z. Bronsted-Acid- 7. Seibel, J.; Buchholz, K. Tools in Oligo- Catalyzed Asymmetric Multicomponent Reactions for the saccharide Synthesis: Current Research and Appli- Facile Synthesis of Highly Enantioenriched Structurally cation. 2010, 63, 101–38. Diverse Nitrogenous Heterocycles. 2011, 44(11), 1156– 8. Chabre, Y. M.; Roy, R. Design and Creativity in 71. Synthesis of Multivalent Neoglycoconjugates. 2010, 63, 2. Biju, A. T.; Kuhl, N.; Glorius, F. Extending 165–393. NHC-: Coupling with Unconven- 9. Mischnick, P.; Momcilovic, D. Chemical Struct- tional Reaction Partners. 2011, 44(11), 1182–95. ure Analysis of Starch and Cellulose Derivatives. 2010, 3. Wang, B.; Tu, Y. Q. Stereoselective Con- 64, 117–210. struction of Quaternary Stereocenters via a 10. Marradi, M.; Martin-Lomas, M.; Penades, S. Semipinacol Rearrangement Strategy. 2011, 44(11), Glyconanoparticles: Polyvalent Tools to Study Carbo- 1207–22. hydrate-Based Interactions. 2010, 64, 211–90. 4. Li, N.-S.; Frederiksen, J. K.; Piccirilli, J. A. 11. Mossine, V. V.; Mawhinney, T. P. 1-Amino-1- Synthesis, Properties, and Applications of Oligo- deoxy-D-fructose (“Fructosamine”) and its Derivatives. nucleotides Containing an RNA Dinucleotide Phos- 2010, 64, 291–402. phorothiolate Linkage. 2011, 44(12), 1257–69. 5. Asmis, K. R.; Neumark, D. M. Vibrational Spectroscopy of Microhydrated Conjugate Base Aldrichimica Acta Anions. 2012, 45(1), 43–52. 12. Uyanik, M.; Ishihara, K. 2-Iodoxybenzene- Advances in Carbohydrate Chemistry and sulfonic Acid (IBS) Catalyzed Oxidation of Alco- hols. 2010, 43(3), 83–91. 13. Vora, H. U.; Rovis, T. Asymmetric N-Hetero- 6. Rauter, A. P.; Xavier, N. M.; Lucas, S. D.; cyclic (NHC) Catalyzed Acyl Anion Reactions. 2011, 44(1), 3–11. 30. Inoue, M. Total Synthesis and Functional 14. Michel, B. W.; Sigman, M. S. Peroxide- Analysis of Non-Ribosomal Peptides. 2011, 11(5), 284– Mediated Wacker Oxidations for . 94. 2011, 44(3), 55–62. 31. Alcaide, B.; Almendros, P. Allenyl-β-Lactams. 15. Al-Maharik, N.; O'Hagan, D. Organofluorine Versatile Scaffolds for the Synthesis of Heterocycles. Chemistry. Deoxyfluorination Reagents for C–F Bond 2011, 11(6), 311–30. Synthesis. 2011, 44(3), 65–75. 32. Chang, J. W. W.; Ton, T. M. U.; Chan, P. W. H. Transition-Metal-Catalyzed Aminations and Aziridin- Angewandte Chemie, International Edition in ations of C–H and C–C Bonds with English Iminoiodinanes. 2011, 11(6), 331–57.

16. Kushner, A. M.; Guan, Z. Modular Design in Chemical Reviews Natural and Biomimetic Soft Materials. 2011, 50(39), 9026–57. 33. Turner, N. J. Enantioselective Oxidation of C–O 17. Canevet, D.; Perez, E. M.; Martin, N. Wrap- and C–N Bonds Using Oxidases. 2011, 111(7), 4073–87. around Hosts for Fullerenes: Tailored Macrocycles and 34. Forgan, R. S.; Sauvage, J.-P.; Stoddart, J. F. Cages. 2011, 50(40), 9248–59. Chemical Topology: Complex Molecular Knots, Links, 18. Haag, B.; Mosrin, M.; Ila, H.; Malakhov, V.; and Entanglements. 2011, 111(9), 5434–64. Knochel, P. Regio- and Chemoselective Metalation of 35. Gilmore, K.; Alabugin, I. V. Cyclizations of Arenes and Heteroarenes Using Hindered Metal Amide : Revisiting Baldwin's Rules for Ring Closure. Bases. 2011, 50(42), 9794–824. 2011, 111(11), 6513–56. 19. Schwarz, H. Chemistry with : Concepts 36. Majumdar, K. C.; Mondal, S. Recent Develop- Rather than Recipes. 2011, 50(43), 10096–115. ments in the Synthesis of Fused Sultams. 2011, 111(12), 20. Curran, D. P.; Solovyev, A.; Brahmi, M. M.; 7749–73. Fensterbank, L.; Malacria, M.; Lacote, E. Synthesis and 37. Yus, M.; Gonzalez-Gomez, J. C.; Foubelo, F. Reactions of N-Heterocyclic Carbene Boranes. 2011, Catalytic Enantioselective Allylation of Carbonyl Com- 50(44), 10294–317. pounds and . 2011, 111(12), 7774–854. 21. Liu, Q.; Zhang, H.; Lei, A. Oxidative 38. Hitt, D. M.; O'Connor, J. M. Acceleration of Carbonylation Reactions: Organometallic (R–M) or Conjugated Dienyne Cycloaromatization. 2011, 111(12), Hydrocarbons (R–H) as Nucleophiles. 2011, 50(46), 7904–22. 10788–99. 39. Demmer, C. S.; Krogsgaard-Larsen, N.; Bunch, 22. Wendlandt, A. E.; Suess, A. M.; Stahl, S. S. L. Review on Modern Advances of Chemical Methods Copper-Catalyzed Aerobic Oxidative C–H Functional- for the Introduction of a Phosphonic Acid Group. 2011, izations: Trends and Mechanistic Insights. 2011, 50(47), 111(12), 7981–8006. 11062-87. 40. Yoon, M.; Srirambalaji, R.; Kim, K. Homochiral 23. Zimmer, L. E.; Sparr, C.; Gilmour, R. Metal–Organic Frameworks for Asymmetric Conformational Effects in Organocatalysis: an Emerging Heterogeneous Catalysis. 2012, 112(2), 1196–231. Strategy for Molecular Design. 2011, 50(50), 11860–71. 24. Hsu, C.-H.; Hung, S.-C.; Wu, C.-Y.; Wong, C.- Chemical Society Reviews H. Toward Automated Oligosaccharide Synthesis. 2011, 50(50), 11872–923. 41. Kambe, N.; Iwasaki, T.; Terao, J. Pd-Catalyzed Cross-Coupling Reactions of Alkyl Halides. 2011, The Chemical Record 40(10), 4937–47. 42. Delgado, J. L.; Martin, N.; de la Cruz, P.; Langa, 25. Itami, K. Molecular Catalysis for Fullerene F. Pyrazolinofullerenes: A Less Known Type of Highly Functionalization. 2011, 11(5), 226–35. Versatile Fullerene Derivatives. 2011, 40(11), 5232–41. 26. Hashizume, S.; Oisaki, K.; Kanai, M. Catalytic 43. Chisholm, M. H.; Lear, B. J. M2δ to Ligand π- Migratory Oxidative Coupling of Nitrones Through an Conjugation: Test-Beds for Current Theories of Mixed 3 Outer-Sphere C(sp )–H Activation Process. 2011, 11(5), in Ground and Photoexcited States of Molecular 236–41. Systems. 2011, 40(11), 5254–65. 27. Nakao, Y. Hydroarylation of Alkynes Catalyzed 44. Nair, V.; Menon, R. S.; Biju, A. T.; Sinu, C. R.; by Nickel. 2011, 11(5), 242–51. Paul, R. R.; Jose, A.; Sreekumar, V. Employing Homo- 28. Ohmori, K. Synthetic Challenge to Ubiquitous enolates Generated by NHC Catalysis in Carbon–Carbon Natural Products from Plant Origin: Flavan-Derived Bond-Forming Reactions: State of the Art. 2011, 40(11), Polyphenols. 2011, 11(5), 252–9. 5336–46. 29. Matsunaga, S.; Yoshino, T. Construction of 45. Cabeza, J. A.; Garcia-Alvarez, P. The N- Contiguous Tetrasubstituted Chiral Carbon Stereocenters Heterocyclic Carbene Chemistry of Transition-Metal via Direct Catalytic Asymmetric Aldol and Mannich- Carbonyl Clusters. 2011, 40(11), 5389–405. Type Reactions. 2011, 11(5), 260–8. 46. Dondoni, A.; Marra, A. Recent Applications of Thiol–Ene Coupling as a Click Process for Glycoconju- 63. Ninomiya, M.; Garud, D. R.; Koketsu, M. gation. 2012, 41(2), 573–86. Biologically Significant Selenium-Containing 47. Mlynarski, J.; Gut, B. Organocatalytic Synthesis Heterocycles. 2011, 255(23-24), 2968–90. of Carbohydrates. 2012, 41(2), 587–96. 64. Postigo, A.; Nudelman, N. S. Synthetically 48. Nising, C. F.; Braese, S. Recent Developments Useful Metal-Mediated Radical Transformations in Water in the Field of Oxa-Michael Reactions. 2012, 41(3), 988– and Aqueous Media. 2011, 255(23–24), 2991–3030. 99. 49. Rios, R. Enantioselective Methodologies for the Current Synthesis of Spiro Compounds. 2012, 41(3), 1060–74. 65. Wan, J.-P.; Liu, Y. Multicomponent Reactions Chemistry of Heterocyclic Compounds Promoted by Reagents. 2011, 15(16), 2758–73. 50. Kalinin, A. A.; Mamedov, V. A. Pyrrolo[1,2-a]- 66. Luo, F.; Pan, C.; Cheng, J. The Application of quinoxalines Based on Pyrroles. 2011, 46(12), 1423–42. Trialkoxysilane as Transmetallation Reagent in Organic 51. Aleksandrova, E. V.; Kravchenko, A. N.; Koch- Synthesis. 2011, 15(16), 2816–29. ergin, P. M. Properties of Haloimidazoles (Review). 67. Turner, C. D.; Liang, H. S. Recent Advances in 2011, 47(3), 261–89. the Assembly of Tri-Substituted Oxazoles. 2011, 15(16), 52. Lozinskii, O. A.; Shokol, T. V.; Khilya, V. P. 2846–70. Synthesis and Biological Activity of Chromones 68. Schmidt, A.; Dreger, A. Recent Advances in the Annelated at the C(7) –C(8) Bond with Heterocycles. Chemistry of Pyrazoles. Part 2. Reactions and N-Hetero- 2011, 47(9), 1055–77. cyclic of Pyrazole. 2011, 15(16), 2897–920. 53. Bukhryakov, K. V.; Kurkin, A. V.; Yurovskaya, 69. Simkova, L.; Liska, F.; Ludvik, J. 2,2-Dinitro- M. A. Synthetic Approaches to Imidazo[4,5-b]Pyridine ethene-1,1-Diamine. 2011, 15(17), 2983–95. Derivatives. 2011, 47(5), 533–57. 70. Baghernejad, B. Application of p-Toluene- 54. Rudenko, D. A.; Shurov, S. N.; Stepanyan, Y. G. sulfonic Acid (PTSA) in Organic Synthesis. 2011, 15(17), 3-Amino-5,5-Dimethylcyclohex-2-Enone in the Synthesis 3091–7. of Heterocyclic Compounds (Review). 2011, 47(6), 661– 71. Hierso, J.-C. Palladium Complexes of 83. Constrained Polyphosphines – Discovery and 55. Popov, V. V.; Konstantinova, L. S.; Rakitin, O. Investigation of "Through-Space" NMR Spin-Spin A. Synthesis and Reactivity of 1,3,2-Dithiazoles Couplings in Organometallic Compounds. 2011, 15(18), (Review). 2011, 47(7), 789–806. 3197–213. 56. Shyshkina, O. O.; Popov, K. S.; Gordivska, O. 72. Gu, S.; Chen, C.; Qiu, H.; Chen, W. Potentially O.; Tkachuk, T. M.; Kovalenko, N. V.; Volovnenko, T. Hemilabile N-Heterocyclic Carbene Palladium Com- A.; Volovenko, Y. M. Synthesis and Chemical Properties plexes: Synthesis and Catalytic Applications. 2011, of Cyclic β-Keto Sulfones. 2011, 47(8), 923–45. 15(18), 3291–308. 57. Garkushenko, A. K.; Sagitullina, G. P. Synthesis 73. Poulain, A.; Iglesias, M.; Albrecht, M. Abnormal of β-Nitropyrroles Based on Nitro Compounds. 2012, NHC Palladium Complexes: Synthesis, Structure, and 47(10), 1189–205. Reactivity. 2011, 15(18), 3325–36. 74. Dunina, V. V. Chiral Cyclopalladated Com- Coordination Chemistry Reviews pounds: New Structures, Methodologies and Appli- cations. A Personal Account. 2011, 15(18), 3415–40. 58. Diez, A.; Lalinde, E.; Moreno, M. T. Hetero- 75. Guenin, E.; Meziane, D. Microwave Assisted polynuclear Cycloplatinated Complexes: Structural and Phosphorus Organic Chemistry: A Review. 2011, 15(19), Photophysical Properties. 2011, 255(21–22), 2426–47. 3465–85. 59. Budagumpi, S.; Kim, K.-H.; Kim, I. Catalytic 76. Al-Mousawi, S. M.; Moustafa, M. S.; Abdel- and Coordination Facets of Single-Site Non-Metallocene hamid, I. A.; Elnagdi, M. H. Optimizing Scale Up Yield Organometallic Catalysts with N-Heterocyclic Scaffolds to Pyridazines and Fused Pyridazines. 2011, 15(19), Employed in Olefin Polymerization. 2011, 255(23–24), 3503–13. 2785–809. 77. Silvi, B.; Reinhardt, P. Localization and Loca- 60. Costas, M. Selective C-H Oxidation Catalyzed lizability in Quantum Organic Chemistry: Localized by Metalloporphyrins. 2011, 255(23–24), 2912–32. Orbitals and Localization Functions. 2011, 15(20), 3555– 61. Liang, L.; Astruc, D. The Copper(I)-Catalyzed 65. -Azide Cycloaddition (CuAAC) “Click” Reaction 78. Lopez, C. S.; de Lera, A. R. Bond Ellipticity as a and Its Applications. An Overview. 2011, 255(23–24), Measure of Electron Delocalization in Structure and 2933–45. Reactivity. 2011, 15(20), 3576–93. 62. Bokach, N. A.; Kuznetsov, M. L.; Kukushkin, V. 79. Arrieta, A.; de Cozar, A.; Cossio, F. P. Cyclic Y. 1,3-Dipolar Cycloaddition of Nitrone-Type Dipoles to Electron Delocalization in Pericyclic Reactions. 2011, Uncomplexed and Metal-Bound Substrates Bearing the 15(20), 3594–608. C≡N Triple Bond. 2011, 255(23–24), 2946–67. 80. Fuentealba, P.; Santos, J. C. Electron Local- ization Function as a Measure of Electron Delocalization 2011, 8(6), 777–86. and Aromaticity. 2011, 15(20), 3619–26. 98. Yadav, J. S.; Antony, A.; Reddy, B. V. S. Recent 81. Garcia-Revilla, M.; Rocha-Rinza, T. Application Advances in the Applications of Ionic Liquids for the of Electron Delocalization Indicators in the Study of Synthesis of Bioactive Six-Membered N-Heterocycles. Electrophilic Aromatic Substitution Reactions. 2011, 2011, 8(6), 787–809. 15(20), 3627–51. 99. Bica, K.; Leder, S.; Gaertner, P. From Solvent to 82. Sheng, W.; Yang, Q.; Weng, J. Application of Sustainable Catalysis. Chloroferrate Ionic Liquids in Noble Metal Nanoparticles in Organic Reactions. 2011, Synthesis. 2011, 8(6), 824–39. 15(21), 3692–705. 100. Rosatella, A. A.; Frade, R. F. M.; Afonso, C. A. 83. Perdih, A.; Dolenc, M. S. Recent Advances in M. Dissolution and Transformation of Carbohydrates in the Synthesis of Unnatural α-Amino Acids – An Updated Ionic Liquids. 2011, 8(6), 840–60. Version. 2011, 15(22), 3750–99. 101. Sydnes, M. O. Recent Developments in the Use 84. Mo, L.-P.; Zhang, Z.-H. Recent Applications of of Palladium on Solid Support in Organic Synthesis. Zirconium Compounds as Catalysts or Reagents in 2011, 8(6), 881–91. Organic Synthesis. 2011, 15(22), 3800–23. 102. Al-Mousawi, S. M.; Moustafa, M. S.; Abdel- 85. Keglevich, G.; Grun, A.; Hermecz, I.; Odinets, I. hamid, I. A.; Elnagdi, M. H. Functionally Substituted L. Quaternary Phosphonium Salt and 1,3-Dialkylimidaz- Nitriles as Versatile Reagents in Organic Synthesis. olium Hexafluorophosphate Ionic Liquids as Green Recent Developments in Our Laboratories. 2011, 8(6), Chemical Tools in Organic Syntheses. 2011, 15(22), 892–900. 3824–48. 103. Cruz, A.; Ramirez, M. E. B. Ephedrines and 86. Basu, B.; Mandal, B. KF/Alumina, A Potential Their Acyclic Derivatives. 2011, 8(6), 901–28. Heterogeneous Base for Organic Reactions. 2011, 15(22), 3870–93. Heterocycles 87. Waser, M.; Falk, H. Progress in the Chemistry of Second Generation Hypericin Based Photosensitizers. 104. Srinivasan, K. V.; Chaskar, P. K.; Dighe, S. N.; 2011, 15(23), 3894–907. Rane, D. S.; Khade, P. V.; Jain, K. S. Microwave 88. Bonet, A.; Gulyas, H.; Fernandez, E. The Boron Assisted Synthesis of Fused Heterocyclic Compounds. Imprint into Combined Catalytic Organic Reactions. 2011, 83(11), 2451–88. 2011, 15(23), 3908–27. 105. Kim, I. S.; Jung, Y. H. Recent Advances in the 89. Patil, M. K.; Prasad, A. N.; Reddy, B. M. Total Synthesis of Indolizidine Iminosugars. 2011, 83 Zirconia-Based Solid Acids: Green and Heterogeneous (11), 2489–507. Catalysts for Organic Synthesis. 2011, 15(23), 3961–85. 106. Abdel-Wahab, B. F.; Mohamed, H. A.; Farahat, 90. Ramazani, A.; Kazemizadeh, A. R. Preparation A. A.; Dawood, K. M. Synthetic Accesses to Azolyl- of Stabilized Phosphorus Ylides via Multicomponent thiazoles. 2011, 83(12), 2731–67. Reactions and Their Synthetic Applications. 2011, 107. Merino, P.; Tejero, T.; Greco, G.; Marca, E.; 15(23), 3986–4020. Delso, I.; Gomez-Sanjuan, A.; Matute, R. Recent 91. Lu, H.-H.; Tan, F.; Xiao, W.-J. Enantioselective Advances on the Synthesis of Piperidines through Organocatalytic Friedel–Crafts Alkylations. 2011, 15(24), Ruthenium-Catalyzed Ring-Closing Metathesis (RCM) 4022–45. Reactions. 2012, 84(1), 75–100. 92. Vesely, J.; Rios, R. Enantioselective Organo- 108. Nugroho, A. E.; Morita, H. Absolute Config- catalytic Synthesis of 5 and 6 Membered Heterocycles. urational Elucidation of Monoterpene Indole Alkaloids by 2011, 15(24), 4046–82. Circular Dichroism. 2012, 84(1), 101–13. 93. Zhou, Z.; Wang, Y.; Tang, C. Nucleophilic 109. Nishiwaki, N.; Hirao, S.; Sawayama, J.; Saigo, Tertiary Phosphine Organocatalysts in Asymmetric K. Practically Usable C3 Building Blocks for the Reactions. 2011, 15(24), 4083–107. Syntheses of Nitro Heterocycles. 2012, 84(1), 115–34. 94. Lalli, C.; Brioche, J.; Bernadat, G.; Masson, G. 110. Wang, F.; Zhao, P.; Xi, C. Copper-Catalyzed Catalytic Enantioselective Cycloaddition with Chiral Domino Reaction of Heteroallenes Towards Benzo– Lewis Bases. 2011, 15(24), 4108–27. Heterocycle Compounds. 2012, 84(1), 209–21. 95. Han, B.; Li, J.-L.; Xiao, Y.-C.; Zhou, S.-L.; 111. Bott, T. M.; West, F. G. Preparation and Synth- Chen, Y.-C. Thiourea-Catalyzed Asymmetric Mannich- etic Applications of Azetidines. 2012, 84(1), 223–64. Type Reactions. 2011, 15(24), 4128–43. 112. Satoh, T. Recent Advances in the Chemistry and 96. Peng, F.-Z.; Shao, Z.-H. Asymmetric Synthetic Uses of Magnesium . 2012, 85(1), Organocatalytic Cascade Reactions Catalyzed by Chiral 1–33. Bronsted Acids. 2011, 15(24), 4144–60. Journal of Current Organic Synthesis 113. Omae, I. Agostic Bonds in Cyclometalation. 97. Kumar, V.; Parmar, V. S.; Malhotra, S. V. Ionic 2011, 696(6), 1128–45. Liquids: Neoteric Solvents for Nucleoside Chemistry. 114. Kochina, T. A.; Vrazhnov, D. V.; Ignatyev, I. S.; Sinotova, E. N.; Voronkov, M. G. Nucleogenic on a Catalyst Surface. 2011, 334(6057), 776–80. Silylium Cations and Their Analogs. 2011, 696(7), 1331– 129. McNally, A.; Prier, C. K.; Macmillan, D. W. C. 40. Discovery of an α-Amino C-H Arylation Reaction Using 115. Bolano, T.; Esteruelas, M. A.; Onate, E. the Strategy of Accelerated Serendipity. 2011, 334(6059), Osmium-Carbon Multiple Bonds: Reduction and C–C 1114–7. Coupling Reactions. 2011, 696(25), 3911–23. 116. Xue, Z.-L.; Morton, L. A. Transition Metal Synlett Alkylidene Complexes. Pathways in Their Formation and Tautomerization between Bis-Alkylidenes and Alkyl 130. Herzon, S. B. Enantioselective Syntheses of (–)- Alkylidynes. 2011, 696(25), 3924–34. Kinamycin F and (–)-Lomaiviticin Aglycon. 2011, (15), 117. Nomura, M.; Fujita-Takayama, C.; Sugiyama, 2105–14. T.; Kajitani, M. Diverse Reactivities of Aromaticity– 131. Ito, S.; Shoji, T.; Morita, N. Recent Advances in Unsaturation Coexisted Metalladithiolene Rings. 2011, the Development of Methods for the Preparation of Func- 696(25), 4018–38. tionalized Azulenes for Electrochromic Applications. 118. Rascon, F.; Coperet, C. Alkylidene and Alkyl- 2011, (16), 2279–98. idyne Surface Complexes: Precursors and Intermediates 132. Zefirov, N.; Kuznetsova, T. S. The in Alkane Conversion Processes on Supported Single-Site Dihalotriangulane Rearrangement: A Mechanistic Catalysts. 2011, 696(25), 4121–31. Mystery. 2011, (16), 2299–306. 133. Reisman, S. E.; Nani, R. R.; Levin, S. Buchner Russian Chemical Reviews and Beyond: Arene Cyclopropanation as Applied to Natural Product Total Synthesis. 2011, (17), 2437–42. 119. Chepaikin, E. G. Homogeneous Catalysis in the 134. Lundgren, R. J.; Hesp, K. D.; Stradiotto, M. Oxidative Functionalization of Alkanes in Protic Media Design of New “Dalphos” P,N-Ligands: Applications in 2011, 80(4), 363–96. Transition-Metal Catalysis. 2011, (17), 2443–58. 120. Uzhinov, B. M.; Khimich, M. N. Conform- 135. Chen, D. Y.-K. Adventures in Total Synthesis: ational Effects in Excited State Intramolecular Proton A Personal Account. 2011, (17), 2459–81. Transfer of Organic Compounds. 2011, 80(6), 553–77. 136. Bronner, S. M.; Goetz, A. E.; Garg, N. K. 121. Ignat'eva, D. V.; Ioffe, I. N.; Troyanov, S. I.; Understanding and Modulating Indolyne Regioselec- Sidorov, L. N. Exohedral and Skeletal Rearrangements in tivities. 2011, (18), 2599–604. the Molecules of Fullerene Derivatives. 2011, 80(7), 631– 137. Chain, W. J. Synthetic Strategies Toward the 45. Guaiane Sesquiterpene Englerin A. 2011, (18), 2605–8. 122. Rakitin, O. A. Stable Heterocyclic Radicals. 138. Dang, T. T.; Dang, T. T.; Langer, P. Synthesis 2011, 80(7), 647–59. of Functionalized Heterocycles by Cyclization Reactions 123. Zavarzin, I. V.; Chertkova, V. V.; Levina, I. S.; of Oxime and Hydrazone 1,4-Dianions. 2011, (18), 2633– Chernoburova, E. I. Steroids Fused to Heterocycles at 42. Positions 16,17 of the D-Ring. 2011, 80(7), 661–82. 139. Taylor, B. L. H.; Jarvo, E. R. Construction of 124. Shokova, E. A.; Kovalev, V. V. Ketoesters and Enantioenriched Tertiary Stereogenic Centers by Nickel- Ketoacids of the Adamantane Series. Synthesis and and Palladium-Catalyzed Cross-Coupling Reactions of Transformations. 2011, 80(10), 927–51. Alkyl Electrophiles. 2011, (19), 2761–5. 140. Wang, S.-X.; Han, X.; Zhong, F.; Wang, Y.; Lu, Science Y. Novel Amino Acid Based Bifunctional Chiral Phos- phines. 2011, (19), 2766–78. 125. Harper, K. C.; Sigman, M. S. Three-Dimen- 141. Guinchard, X.; Roulland, E. Various Entries to sional Correlation of Steric and Electronic Free Energy Vinyl Chloride Derivatives and Their Applications in Relationships Guides Asymmetric Propargylation. 2011, Total Synthesis of Natural Products. 2011, (19), 2779–88. 333(6051), 1875–8. 126. Zhong, D.; Franke, J.-H.; Podiyanachari, S. K.; Synthesis–Stuttgart Bloemker, T.; Zhang, H.; Kehr, G.; Erker, G.; Fuchs, H.; Chi, L. Linear Alkane Polymerization on a Gold Surface. 142. Mikami, K.; Fustero, S.; Sanchez-Rosello, M.; 2011, 334(6053), 213–6. Acena, J. L.; Soloshonok, V.; Sorochinsky, A. Synthesis 127. Xu, Y.; Masuko, S.; Takieddin, M.; Xu, H.; Liu, of Fluorinated β-Amino Acids. 2011, (19), 3045–79. R.; Jing, J.; Mousa, S. A.; Linhardt, R. J.; Liu, J. Chemo- 143. Nakao, Y. Transition-Metal-Catalyzed C–H enzymic Synthesis of Homogeneous Ultralow Molecular Functionalization for the Synthesis of Substituted Weight Heparins. 2011, 334(6055), 498–501. Pyridines. 2011, (20), 3209–19. 128. Demers-Carpentier, V.; Goubert, G.; Masini, F.; 144. Zhang, M. Advances in the Direct Amination of Lafleur-Lambert, R.; Dong, Y.; Lavoie, S.; Mahieu, G.; Azole C-H Bonds. 2011, (21), 3408–17. Boukouvalas, J.; Gao, H.; Rasmussen, A. M. H.; Ferrighi, 145. Sperry, J. The Oxidation of Amides to Imides: L.; Pan, Y.; Hammer, B.; McBreen, P. H. Direct Observ- A Powerful Synthetic Transformation. 2011, (22), 3569– ation of Molecular Preorganization for Chirality Transfer 80. 146. Le Bras, J.; Muzart, J. Heck Arylations of Synthesis of γ-Nitrocarbonyl Compounds Through Baylis–Hillman Adducts. 2011, (22), 3581–91. Michael and Domino Reactions. 2010, 21(21–22), 2561– 147. Paradies, J. [2.2]Paracyclophane Derivatives: 601. Synthesis and Application in Catalysis. 2011, (23), 3749– 162. Guenay, M. E.; Ilyashenko, G.; Richards, C. J. 66. Models for the Basis of Enantioselection in Palladium 148. Boldon, S.; Stenhagen, I. S. R.; Moore, J. E.; Mediated C-H Activation Reactions. 2010, 21(23), 2782– Luthra, S. K.; Gouverneur, V. Supported Synthesis of 7. Halogenated Organic Compounds. 2011, (24), 3929–53. 163. Panday, S. K. Advances in the Chemistry of 149. Barker, T. J.; Jarvo, E. R. Developments in Proline and Its Derivatives: An Excellent Amino Acid Transition-Metal-Catalyzed Reactions Using Electro- with Versatile Applications in Asymmetric philic Nitrogen Sources. 2011, (24), 3954–64. Synthesis. 2011, 22(20–22), 1817–47. 164. Bhowmick, S.; Bhowmick, K. C. Catalytic Tetrahedron Asymmetric Carbon–Carbon Bond-forming Reactions in Aqueous Media. 2011, 22(23), 1945–79. 150. Monrad, R. N.; Madsen, R. Modern Methods for Shortening and Extending the Carbon Chain in Topics in Current Chemistry Carbohydrates at the Anomeric Center. 2011, 67(46), 8825–50. 165. Mori, T.; Inoue, Y. Recent Theoretical and 151. Nag, S.; Batra, S. Applications of Allylamines Experimental Advances in the Electronic Circular for the Syntheses of Aza-Heterocycles. 2011, 67(47), Dichroisms of Planar Chiral Cyclophanes. 2011, 8959–9061. 298(Electronic and Magnetic Properties of Chiral 152. Jacobs, J.; Abbaspour Tehrani, K.; de Kimpe, N. Molecules and Supramolecular Architectures), 99–128. A Survey of Synthetic Routes Towards 2-Azaanthraquin- 166. Fraser-Reid, B.; Lopez, J. C. Armed-Disarmed ones. 2011, 67(49), 9459–71. Effects in Carbohydrate Chemistry. History, Synthetic 153. O'Brien, A. G. Recent Advances in Acyclic and Mechanistic Studies. 2011, 301(Reactivity Tuning in Stereocontrol. 2011, 67(50), 9639–67. Oligosaccharide Assembly), 1–29. 154. Chaturvedi, D. Perspectives on the Synthesis of 167. Gomez, A. M. A Survey of Ley's Reactivity Organic Carbamates. 2012, 68(1), 15–45. Tuning in Oligosaccharide Synthesis. 2011, 301, 31–68. 155. Kotha, S.; Dipak, M. K. Strategies and Tactics 168. Shiao, T. C.; Roy, R. Active-Latent Thioglyco- in Olefin Metathesis. 2012, 68(2), 397–421. syl Donors and Acceptors in Oligosaccharide Syntheses. 156. Panigrahi, M.; Dash, S.; Patel, S.; Mishra, B. K. 2011, 301, 69–108. Syntheses of Cyanines: A Review. 2012, 68(3), 781–805. 169. Premathilake, H. D.; Demchenko, A. V. Super- 157. Simsek Kus, N. Organic Reactions in armed and Superdisarmed Building Blocks in Expeditious Subcritical and Supercritical Water. 2012, 68(4), 949–58. Oligosaccharide Synthesis. 2011, 301, 189–221. 158. Raju, R.; Prasad, K. Synthetic Applications of 170. Wu, C.-Y.; Wong, C.-H. Programmable One- 2-Ethylhexanoic Acid Derived Reagents. 2012, 68(5), Pot Glycosylation. 2011, 301, 223–52. 1341–9. 171. Codee, J. D. C.; Christina, A. E.; Walvoort, M. 159. Mekheimer, R. A.; Ahmed, E. A.; Sadek, K. U. T. C.; Overkleeft, H. S.; van der Marel, G. A. Uronic Recent Developments in the Chemistry of Pyrazolo[4,3- Acids in Oligosaccharide and Glycoconjugate c]quinolines. 2012, 68(6), 1637–67. Synthesis. 2011, 301, 253–89. 172. Toullec, P. Y.; Michelet, V. Cycloisomerization Tetrahedron: Asymmetry of 1,N-Enynes via Carbophilic Activation. 2011, 302 (Computational Mechanisms of Au and Pt Catalyzed 160. Han, J. W.; Hayashi, T. Palladium-Catalyzed Reactions), 31–80. Asymmetric of 1,3-Dienes. 2010, 21(18), 173. Correa, A.; Nolan, S. P.; Cavallo, L. N-Hetero- 2193–7. cyclic Carbene Complexes of Au, Pd, and Pt as Effective 161. Roca-Lopez, D.; Sadaba, D.; Delso, I.; Herrera, Catalyst in Organic Synthesis. 2011, 302, 131–55. R. P.; Tejero, T.; Merino, P. Asymmetric Organocatalytic

Contributed Volumes

Alkaloids: Chemistry and Biology. Volume 68. Related Alkaloids. Cordell, G. A., Ed., Elsevier: San Diego, CA, 2010. 176. Perez, E., G. ; Cassels, B., K. Alkaloids from the Genus Duguetia. 174. Cedron, J., C. ; Del Arco-Agular, M.; Estevez- 177. Heinrich, M. Galanthamine from Galanthus and Braun, A.; Ravelo, A., G. Chemistry and Biology of Other Amaryllidacea – Chemistry and Biology Based on Pancratium Alkaloids. Traditional Use. 175. Parsons, A., F. ; Palframan, M., J. Erythrina and

Monographs

178. Allen, D. W.; Tebby, J. C.; Loakes, D. Organo- 191. Gale, P. A., Dehaen, W., Eds. Anion phosphorus Chemistry. Vol. 39. Royal Society of Chem- Recognition in Supramolecular Chemistry. [In: Top. istry: Cambridge, U.K., 2010. Heterocycl. Chem., 2010, 24]. Springer: Berlin, Germany, 179. Alvarez-Builla, J.; Vaquero, J. J.; Barluenga, J.; 2010. Eds. Modern Heterocyclic Chemistry. Vol. 1. Wiley- 192. Gribble, G. W., Joule, J. A., Eds. Progress in VCH: Chichester, Germany, 2011. Heterocyclic Chemistry. Vol. 21. Elsevier: Oxford, U.K., 180. Banik, B. K.; Ed. Heterocyclic Scaffolds I: β- 2009. Lactams. [In: Top. Heterocycl. Chem., 2010, 22]. 193. Gribble, G. W., Ed. Heterocyclic Scaffolds II: Springer: Berlin, Germany, 2010. Reactions and Applications of Indoles. [In: Top. Hetero- 181. Bansal, R. K., Ed. Phosphorus Heterocycles I. cycl. Chem., 2010, 26]. Springer: Berlin, Germany: 2010. [In: Top. Heterocycl. Chem., 2010, 20]. Springer: Berlin, 194. Krygowski, T. M., Cyranski, M. K., Eds. Germany, 2009. Aromaticity in Heterocyclic Compounds. [In: Top. 182. Bansal, R. K., Ed. Phosphorus Heterocycles II. Heterocycl. Chem., 2009, 19]. Springer: Berlin, Germany, [In: Top. Heterocylic Chem., 2010, 21]. Springer: Berlin, 2009. Germany, 2010. 195. Margetic, D.; Vianello, R. From Conceptual to 183. Basset, J.-M., Psaro, R., Roberto, D., Ugo, R., Computational Chemistry and Back. [In: Croat. Chem. Eds. Modern Surface Organometallic Chemistry. Wiley- Acta, 2009, 82(1)]. Croatian Chemical Society: Zagreb, VCH: Weinheim, Germany, 2009. Croatia, 2009. 184. Canty, A. J., Ed. Higher 196. Molander, G. A., Ed. Science of Synthesis, and Chemistry. [In: Top. Stereoselective Synthesis 2: Stereoselective Reactions of Organomet. Chem., 2011, 35]. Springer: Berlin, Carbonyl and Imino Groups. Georg Thieme Verlag: Germany, 2011. Stuttgart, Germany, 2011. 185. Chauhan, B., Gielen, M., Eds. Applied Organo- 197. Nylund, K., Johansson, P., Eds. Heterocyclic silicon and Silicon-Organic Chemistry. [In: Appl. Org- Compounds: Synthesis, Properties and Applications. anomet. Chem., 2010, 24(3)]. John Wiley: Chichester, Nova Science: Hauppauge, NY, 2010. U.K., 2010. 198. Orru, R. V. A., Ruijter, E., Eds. Synthesis of 186. Chauvin, R., Canac, Y., Eds. Transition Metal Heterocycles via Multicomponent Reactions I. [In: Top. Complexes of Neutral ν1-Carbon Ligands. [In: Top. Heterocycl. Chem., 2010, 23]. Springer: Berlin, Germany: Organomet. Chem.; 2010, 30]. Springer: Berlin, 2010. Germany, 2010. 199. Orru, R. V. A., Ruijter, E., Eds. Synthesis of 187. Chin, H. F., Ed. Organometallic Compounds: Heterocycles via Multicomponent Reactions II. [In: Top. Preparation, Structure and Properties. Nova Science: Heterocycl. Chem., 2010, 25]. Springer: Berlin, Germany, Hauppauge, NY, 2010. 2010. 188. Dai, L.-X., Hou, X.-L., Eds. Chiral Ferrocenes 200. Pihko, P. M., Ed. Hydrogen Bonding in Organic in Asymmetric Catalysis: Synthesis and Applications. Synthesis. Wiley-VCH: Weinheim, Germany, 2009. Wiley-VCH: Weinheim, Germany, 2010. 201. Wang, F.-P.; Chen, Q.-H. The C19 Diterpen- 189. Diez-Gonzalez, S., Ed. N-Heterocyclic oids. [In: Alkaloids: Chemistry and Biology. 2010, 69]. Carbenes: From Laboratory Curiosities to Efficient Elsevier: San Diego, CA, 2010. Synthetic Tools. [In: RSC Catal. Ser.; 2011; 6]. Royal 202. Wyman, E. B., Skief, M. C., Eds. Society of Chemistry: Cambridge, U.K., 2011. Organosilanes: Properties, Performance and Applications. 190. Fourmigue, M., Ouahab, L., Eds. Conducting Nova Science: Hauppauge, NY, 2010. and Magnetic Organometallic Molecular Materials. [In: 203. Yudin, A. K., Ed Catalyzed Carbon–Hetero- Top. Organomet. Chem., 2009, 27]. Springer: Berlin, atom Bond Formation. Wiley-VCH: Weinheim, Germany, 2009. Germany, 2011. Index

Acyloxyborohydride, amination, 158 book, 203 enantioselective synthesis, 92 Adamantane, ketoacids, 124 Carbonylation, hydrocarbon fused to steroids, 123 ketoester, 124 nucleophiles, 21 fused, microwaves, 104 Alkaloids, C19 diterpenoids, book, 201 organometallic nucleophiles, 21 N-, from duguetia, book, 176 Carbonyls, allylation, 37 aminodimethylcyclohexenones, 54 erythrina, book, 175 stereoselective, book, 196 N-, via multicomponent reactions, galanthamine, book, 177 Cascade reactions, chiral 1 pancratium, book, 174 organocatalyst, 96 O-, synthesis, 48 Alkanes, activation, Pd, 162 Catalysts, chirality transfer, 128 radicals, 122 metathesis, 118 Cellulose derivatives, 9-10 scaffolds, lactams, book, 180 oxidative functionalization, 119 C–H activation, Cu, aerobic, 22 transition metal polymerization polymerization, Au, 126 Chloroferrate ionic liquid, 99 catalysts, 59 Alkyl electrophiles, Ni/Pd coupling, Chromones, heterocycle annelation, 52 via multicomponent reactions, 139 Click glycoconjugation, 46 book, 198-9 Alkyl halide cross coupling, Pd, 41 Computational chemistry, book, 195 Homoenolates, 44 Alkylidene tungsten complexes, 116 Cyanine dyes, 156 Hydrazone dianion heterocyclization, Alkylidynes, alkyl- and bis-, 116 Cycloaddition, chiral Lewis Base 138 Alkyne–azide click cycloaddition, 61 catalysts, 94 Hydrogen bonding, synthesis, book, Alkynes, cyclization, Baldwin rules, 35 Cycloheptatriene, 133 200 hydroarylation, Ni, 27 Cyclometalation, agostic products, 113 Hypericin photosensitizers, 87 Allenylsilane, 160 Cyclopalladated chiral compounds, 74 Imidazolines, asymmetric synthesis, 29 Allylamines, aza-heterocycle synthesis, Cyclopalladation, 162 Imidazolium hexafluorophosphate 151 Cyclophanes, chiral, circular ionic liquid, 85 Allylsilane, 160 dichroism, 165 Imidazopyridine, synthesis, 53 Alumina, potassium fluorine basic Dalphos ligands, 134 Imides, from amides, 145 surface, 86 Deoxyfluorination, 15 Imines, allylation, 37 Amines, with cyanoaromatics, 129 Dienes, hydrosilylation, Pd, 160 Imino group, stereoselective, book, 196 Amino acids, unnatural, synthesis, 83 Dienynes, conjugated, Iminoiodinane, aminations, 32 vicinal tetrasubstitution, 29 cycloaromatization, 38 aziridination, 32 β-, fluorinated, 142 Dihalotriangulane, rearrangement, 132 Indole alkaloids, absolute Aminodeoxyfructose, 11 Dinitroethenediamine, 69 configuration, 108 Aminohydroxyesters, synthesis, 29 Dinucleotide phosphorothiolate Indolizidine imino sugars, 105 Aminomethylcyclohexenone, 54 linkage, 4 Indoles, heterocyclic scaffolds, book, Antillatoxin, synthesis, 30 Dithiazoles, 55 193 Antitumor agent, englerin A, 137 Electrocyclizations, 79 Indolyne regioselectivity, 136 Aqueous C-C bond formation, 164 Electron delocalization, 78-81 Iodoxybenzenesulfonic acid, Aqueous reactions, subcritical, 157 Electrophilic nitrogen sources, 149 oxidation, 12 supercritical, 157 Enolates, from unsaturated aldehydes, Ionic liquids, carbohydrates, 100 Arenes, cyclopropanation, 133 44 chloroferrate, 99 metalation, 18 Enynes, cycloisomerization, 172 N-heterocycles, 98 Aromatic electrophilic substitution, 81 Ephedrine, acyclic, 103 nucleoside solvents, 97 Arylation, photoredox catalyst, 129 Ethylhexanoic acid reagents, 158 Ketamines, asymmetric Mannich Azaanthraquinone, synthesis, 152 Excited state, intramolecular proton reaction, 29 Azetidines, 111 transfer, 120 , enantioselective Azoles, amination, 144 Ferrocenes, chiral, book, 188 propargylation, 125 synthesis, 138 Friedel–Crafts alkylation, Kinamycin synthesis, 130 Azolylthiazoles, synthesis, 106 organocatalytic, 91 Lactams, allenylic, 31 Azulenes, synthesis, 131 Fructosamine, 11 Ligands, pi conjugation, Baylis–Hillman adducts, arylation, 146 Fullerenes, allylation, 25 photoexcitation, 43 Benzylic amines, synthesis, 129 cycloaddition, 25 Localizability, quantum organic Biomimetics, 135 macrocycles and cages, 17 chemistry, 77 Bond ellipticity, 78 rearrangement, 121 Lomaiviticin aglycon synthesis, 130 Boron catalysis, 88 Glyconanoparticles, 10 Magnesium carbenoids, 112 Breslow intermediates, 2 Glycosylation, one pot synthesis, 170 Merocyanines, 156 Buchner reaction, 133 Halobenzamides, synthesis, 110 Metal organic frameworks, 40 Carbamates, organic, 154 Halobenzenamines, synthesis, 110 Metallacycles, 117 Carbene ligands, book, 186 Haloimidazoles, 51 Metalladithiolene rings, 117 Carbenoids, rearrangement, 132 Halophenols, synthesis, 110 Metalloporphyrins, C-H oxidation, 60 Carbohydrates, aldol reactions, 150 Heck arylation, 146 Methane, organometallic chemistry, 19 anomeric center, 150 Heparin, chemoenzymatic synthesis, Methylketones, synthesis, 14 in ionic liquids, 100 127 Molecular knots, 34 organocatalytic synthesis, 47 Heteroallenes, domino reaction, 110 N-Chloroamines, 149 thiol-ene coupling, 46 Heteroarenes, metalation, 18 N-Heterocyclic carbenes, 44 zeolites, 6 Heterocycles, aromaticity, book, 194 acyl ion reactions, 13 Carbon–heteroatom bond formation, book, 179, 192, 197 Au, Pd, Pt, 173 boranes, 20 Osmium cyclopentapyrroles, 115 Quinoxalines, pyrrolo-, 50 organocatalysis, 2 Oxa-Michael reaction, 48 Radical transformations, with metals, Pd, 73 Oxazoles, trisubstituted, 67 64 Pd, hemilabile ligands, 72 Oxazolines, asymmetric synthesis, 29 Selenium heterocycle, biological, 63 pyrazoles, 68 Oxidases, enantioselective oxidation, Semipinacol rearrangement, 3 synthesis, book, 189 33 Sesquiterpene englerin A, 137 transition metal clusters, 45 Oxime dianion heterocyclization, 138 Silyl alkylidenes, 116 Neoglycoconjugates, synthesis, 8 Oximes, 149 Silylium cations, nucleogenic, 114 Nitriles, nitrone cycloaddition, 62 Palladacycles, 162 Spiro compounds, enantioselective substituted, 102 Palladium complexes, hemilabile NHC synthesis, 49 Nitrocarbonyls, via organocatalysis, ligands, 72 Squarine, 156 161 Palladium, solid supports, 101 Starch derivatives, 9 Nitromalonaldehydes, nitro heterocycle Paracyclophane, 147 Stereocontrol, acyclic, 153 synthesis, 109 Pericyclic aromaticity, 79 Steroids, fused to heterocyles, 123 Nitrones, coupling, 26 Phosphines, bifunctional catalysts, 140 Sulfones, keto-, cyclic, 56 Noble metal nanoparticles, 82 chiral, bifunctional, 140 Sultams, fused, 36 Norcaradiene, 133 nucleophilic, tertiary, Supramolecular chemistry, anion n-Pentenyl glycosides, 169 organocatalyst, 93 recognition, book, 191 Nucleosides, in ionic liquids, 97 Phosphonic acid group, 39 Surface organometallic chemistry, Olefins, metathesis, 155 Phosphorus, and microwaves, 75 book, 183 polymerization, non-metallocene heterocycles, book, 181-2 Tertiary stereogenic centers, 139 catalysts, 59 ylide, 90 Thioglycosides, 170 Oligosaccharides, active/latent Photoluminescence, Pt complex, 58 Thioglycosyl donors, 168 thioglycosyl donors, 168 Piperidines, vis ring closing metathesis, Thiourea, asymmetric Mannich armed-disarmed effect, 166, 169 107 condensation, 95 Ley reactivity, 167 Platinum cyclometalated complexes, 58 Toluenesulfonate catalyst, 70 one pot synthesis, 170 Polymethine dyes, 156 Topology of molecules, 34 solid phase synthesis, 24 Polypeptides, natural, 16 Trialkoxysilanes, transmetallation, 66 synthesis, 7 Polyphenols, flavan, 28 Umpolung reactions, benzoin Oocydin total synthesis, 141 Polyphosphines, Pd complex, 71 condensation, 2 Organofluorine, 15 Polytheonamide, synthesis, 30 Stetter, 2 stereoelectronic effect, 23 Proline, in asymmetric synthesis, 163 Uronic acid, glycoconjugate synthesis, Organohalogens, 148 Pyrazoles, N-Heterocyclic carbenes, 68 171 Organometallics, book, 187 Pyrazolinofullerenes, 42 oligosaccharide synthesis, 171 conducting, book, 190 Pyrazoloquinoline, 159 Vibrational spectroscopy, 5 magnetic, book, 190 Pyridazines, synthesis, 76 Vinyl chloride derivatives, 141 Organopalladium, book, 184 Pyridines, functionalization, 143 Wacker oxidation, with peroxides, 14 Organophosphorus, book, 178 Pyrroles, nitro-, 57 Ylide ligands, book, 186 , book, 184 Pyrroloquinoxalines, 50 Zirconia solid acids, 89 Organosilanes, book, 202 Quaternary carbon sterocenters, 3 Zirconium compounds, 84 Organosilicon, book, 185 Quaternary phosphonium salts, green multicomponent reactions, 65 chemistry, 85