Amperometric Fill 1N Kcl W Agcl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 04/14/2015 Date of issue: 04/14/2015 Version: 1.0
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: 4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Part Number: 905-4787; 9210263; 9210431; 9210435; 921043; 9210432; 9210072; 9210356; 9210434; 9210264 1.2. Intended Use of the Product Use of the Substance/Mixture: No use is specified. 1.3. Name, Address, and Telephone of the Responsible Party
Company Rosemount Analytical Inc. 2400 Barranca Parkway Irvine, CA 92606 USA 949-757-8500 1.4. Emergency Telephone Number Emergency Number : 949-757-8500
SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Full text of H-phrases: see section 16 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) :
GHS09 Signal Word (GHS-US) : Warning Hazard Statements (GHS-US) : H400 - Very toxic to aquatic life. H410 - Very toxic to aquatic life with long lasting effects. Precautionary Statements (GHS-US) : P273 - Avoid release to the environment. P391 - Collect spillage. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. 2.3. Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions.
2.4. Unknown Acute Toxicity (GHS-US) No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier % (w/w) Classification (GHS-US) Water (CAS No) 7732-18-5 71 - 92.5 Not classified
04/14/2015 EN (English US) 1/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Potassium chloride (CAS No) 7447-40-7 7 - 10; 10 – 30* Not classified Silver chloride (AgCl) (CAS No) 7783-90-6 0.05 - 0.7 Met. Corr. 1, H290 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 *More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary, due to varying composition. Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Rinse affected area with water for at least 5 minutes. Wash contaminated clothing before reuse. Obtain medical attention if irritation develops or persists.
Eye Contact: Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if redness, pain, or irritation occurs.
Ingestion: Do not induce vomiting. Rinse mouth. Obtain medical attention.
4.2. Most Important Symptoms and Effects Both Acute and Delayed General: Not expected to present a significant hazard under anticipated conditions of normal use.
Inhalation: May cause respiratory irritation.
Skin Contact: May cause skin irritation.
Eye Contact: May cause eye irritation.
Ingestion: May be harmful if ingested in large quantities.
Chronic Symptoms: None expected under normal conditions of use.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice (show the label where possible).
SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions are not expected to occur under normal conditions. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides (CO, CO2). Metal oxides. Halogenated compounds. Hydrogen chloride (HCl). Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all unnecessary exposure. Avoid breathing (vapor, mist, spray). 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE).
04/14/2015 EN (English US) 2/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Stop leak if safe to do so. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and when leaving work. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures, and incompatible materials. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Light. Ammonia. Water reactive materials. 7.3. Specific End Use(s) No use is specified.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government.
8.2. Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed.
Personal Protective Equipment: Protective goggles. Gloves. Protective clothing.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Chemically resistant protective gloves.
Eye Protection: Chemical goggles.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH approved respiratory protection should be worn.
Environmental Exposure Controls: Do not allow the product to be released into the environment. Consumer Exposure Controls: Do not eat, drink, or smoke during use
04/14/2015 EN (English US) 3/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid
Appearance : Clear,Colorless. May change color slightly if exposed to light
Odor : Odorless
Odor Threshold : Not available
pH : ≈ 7
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : ≈ 212 - 220 °F (≈ 100 - 104 °C)
Flash Point : Non-flammable
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not available
Relative Vapor Density at 20 °C : Not available
Specific Gravity : 1
Solubility : Soluble
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : Not available
Explosive Properties : Product is not explosive
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge.
SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions are not expected to occur under normal conditions.
10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, incompatible materials.
10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Light. Ammonia. Water reactive materials.
10.6. Hazardous Decomposition Products: Thermal decomposition generates: Carbon oxides (CO, CO2). Hydrogen chloride. Metal oxides.
SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects - Product Acute Toxicity: Not classified LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified pH: ≈ 7
Serious Eye Damage/Irritation: Not classified pH: ≈ 7
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: Not classified 04/14/2015 EN (English US) 4/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: May cause skin irritation. Symptoms/Injuries After Eye Contact: May cause eye irritation. Symptoms/Injuries After Ingestion: May be harmful if ingested in large quantities. Chronic Symptoms: None expected under normal conditions of use. 11.2. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:
Potassium chloride (7447-40-7) LD50 Oral Rat 2600 mg/kg
Silver chloride (AgCl) (7783-90-6) LD50 Oral Rat > 5110 mg/kg
SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - General: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
Potassium chloride (7447-40-7) LC50 Fish 1 1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 1 825 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 750 - 1020 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Silver chloride (AgCl) (7783-90-6) LC50 Fish 1 1.2 μg/l (Exposure Time : 96 hours, Species : Pimephales promelas [semi-static]) NOEC chronic fish 0.00079 mg/l (Exposure Time : 64 Days, Species : Oncorhynchus mykiss [flow-through])
12.2. Persistence and Degradability Not available
12.3. Bioaccumulative Potential Not available
12.4. Mobility in Soil Not available
12.5. Other Adverse Effects Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Sewage Disposal Recommendations:. Do not empty into drains; dispose of this material and its container in a safe way. Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial, and international regulations. Ecology – Waste Materials: This material is hazardous to the aquatic environment. Keep out of sewers and waterways.
SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.(Silver Chloride) Hazard Class : 9 Identification Number : UN3082 Label Codes : 9
Packing Group : III
Marine Pollutant : Marine pollutant
ERG Number : 171
04/14/2015 EN (English US) 5/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
14.2. In Accordance with IMDG
Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver Chloride)
Hazard Class : 9
Identification Number : UN3082
Packing Group : III
Label Codes : 9
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Marine pollutant : Marine pollutant 14.3. In Accordance with IATA
Proper Shipping Name : Environmentally hazardous substance, liquid, n.o.s. (Silver Chloride) Packing Group : III Identification Number : UN3082
Hazard Class : 9 Label Codes : 9
ERG Code (IATA) : 9L 14.4. In Accordance with TDG Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S.
Packing Group : III
Hazard Class : 9
Identification Number : UN3082
Label Codes : 9
Marine Pollutant (TDG) : Marine pollutant
SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations
Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory
Potassium chloride (7447-40-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. US State Regulations Neither this product nor its chemical components appear on any US state lists.
15.3. Canadian Regulations 4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Potassium chloride (7447-40-7) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Silver chloride (AgCl) (7783-90-6) WHMIS Classification Class E - Corrosive Material
04/14/2015 EN (English US) 6/7
4M Reference Fill Solution; Amperometric Fill 1N KCl w AgCl; Biofilm,Metal, Oil, Poison, and Scaling Resistant Soaking Solutions; Reference Fill Solution; Amperometric Fill #1 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 04/14/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: ------Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 ------Met. Corr. 1 Corrosive to metals Category 1 ------H290 May be corrosive to metals ------H400 Very toxic to aquatic life ------H410 Very toxic to aquatic life with long lasting effects
Party Responsible for the Preparation of This Document Rosemount Analytical Inc. 2400 Barranca Parkway Irvine, CA 92606
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
North America GHS US 2012 & WHMIS 2
04/14/2015 EN (English US) 7/7
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl
Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 04/10/2015 Date of issue: 11/17/2014 Version: 1.0
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: 4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Part Number: 905-576, 905-135761, 192580, 05000705464, 05000709672, 05010782147, 05010782026, 050010781899, 05010797875, 05010782468, 05010783002, SS1, SS1A, SS5, SS5A, SS7, SS7A, 9160500, 9210004, SS6, SS6A, 92100457, 9210098, 9210459, 9210440, 9210364 1.2. Intended Use of the Product None specified 1.3. Name, Address, and Telephone of the Responsible Party
Company Rosemount Analytical Inc. 2400 Barranca Pkwy Irvine, CA 92606 USA 949-757-8500 1.4. Emergency Telephone Number Emergency Number : 949-757-8500
SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified 2.2. Label Elements GHS-US Labeling No labeling applicable 2.3. Other Hazards No additional information available
2.4. Unknown Acute Toxicity (GHS-US) No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier % (w/w) Classification (GHS-US) Water (CAS No) 7732-18-5 73.5 - 100 Not classified Potassium chloride (CAS No) 7447-40-7 < 0.1, 0.1 - 1, 1 - 5, Not classified 5 - 10, 10 - 26.5
04/10/2015 EN (English US) 1/6
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Alcohols, C11-15-secondary, ethoxylated (CAS No) 68131-40-8 < 0.1 Skin Sens. 1B, H317 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 Multiple WHMIS ranges have been utilized to account for varying concentration. Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. Skin Contact: Rinse immediately with plenty of water. Obtain medical attention if irritation develops or persists.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists.
Ingestion: Rinse mouth. Do not induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell.
4.2. Most Important Symptoms and Effects Both Acute and Delayed General: Not expected to present a significant hazard under anticipated conditions of normal use.
Inhalation: None expected under normal conditions of use.
Skin Contact: None expected under normal conditions of use.
Eye Contact: None expected under normal conditions of use.
Ingestion: May be harmful if ingested in large quantities.
Chronic Symptoms: None expected under normal conditions of use.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice (show the label where possible).
SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not flammable. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Halogenated compounds. Metal oxides. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray). 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel.
04/10/2015 EN (English US) 2/6
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Heading 8. Exposure controls and personal protection. Concerning disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials: strong acids. Strong oxidizers. Strong bases. Water reactive materials. 7.3. Specific End Use(s) None specified
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government.
8.2. Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure but are not required. Ensure all national/local regulations are observed.
Personal Protective Equipment: Protective goggles. Gloves.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Environmental Exposure Controls: Do not allow the product to be released into the environment. Consumer Exposure Controls: Do not eat, drink or smoke during use
04/10/2015 EN (English US) 3/6
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid
Appearance : Colorless
Odor : Odorless
Odor Threshold : Not available
pH : ≈ 7 - 9 (2.7 [0.1 molar solution])
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : ≈ 100 - 235 °C (212 - 455 °F)
Flash Point : Not combustible
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not available
Relative Vapor Density at 20 °C : Not available
Specific Gravity : 1 - 1.57
Solubility : Soluble
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : Not available
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact.
Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge.
SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions will not occur under normal conditions.
10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Incompatible materials.
10.5. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Water reactive materials.
10.6. Hazardous Decomposition Products: Thermal decomposition generates: Halogenated compounds. Metal oxides.
SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects - Product Acute Toxicity: Not classified LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified pH: ≈ 7 - 9 (2.7 [0.1 molar solution])
Serious Eye Damage/Irritation: Not classified pH: ≈ 7 - 9 (2.7 [0.1 molar solution])
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
04/10/2015 EN (English US) 4/6
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: None expected under normal conditions of use. Symptoms/Injuries After Skin Contact: None expected under normal conditions of use. Symptoms/Injuries After Eye Contact: None expected under normal conditions of use. Symptoms/Injuries After Ingestion: May be harmful if ingested in large quantities. Chronic Symptoms: None expected under normal conditions of use. 11.2. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:
Potassium chloride (7447-40-7) LD50 Oral Rat 2600 mg/kg
Alcohols, C11-15-secondary, ethoxylated (68131-40-8) LD50 Oral Rat 2100 mg/kg
LD50 Dermal Rabbit 2 ml/kg
SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No additional information available
Potassium chloride (7447-40-7) LC50 Fish 1 1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 1 825 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 750 - 1020 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Alcohols, C11-15-secondary, ethoxylated (68131-40-8) LC50 Fish 1 1.53 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
12.2 Persistence and Degradability Not available
12.3. Bioaccumulative Potential Not available
12.4. Mobility in Soil Not available
12.5. Other Adverse Effects Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. Ecology – Waste Materials: Avoid release to the environment.
SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Not regulated for transport. 14.2. In Accordance with IMDG Not regulated for transport. 14.3. In Accordance with IATA Not regulated for transport. 14.4. In Accordance with TDG Not regulated for transport.
SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations
Potassium chloride (7447-40-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory
04/10/2015 EN (English US) 5/6
4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory
Alcohols, C11-15-secondary, ethoxylated (68131-40-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. US State Regulations Neither this product nor its chemical components appear on any US state lists.
15.3. Canadian Regulations 4M POTASSIUM CHLORIDE; Oxygen Sensor Electrolyte; Potassium Chloride; SS-5 SS-5A -Potassium Chloride; CONDUCTIVITY SOLUTION; ELECTROLYTE SOLUTION; 0.01M KCl- Conductivity Standard Calibrated; 0.1M KCl- Conductivity Standard Calibrated; 2.5 M Saturated KCl Solution (Sensor Booting Solution); 3 M Saturated KCl Solution; SENSOR SOAKING SOLUTION WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Potassium chloride (7447-40-7) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Alcohols, C11-15-secondary, ethoxylated (68131-40-8) Listed on the Canadian DSL (Domestic Substances List)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 04/10/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: ------Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2 ------Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 ------Skin Sens. 1B Skin sensitization Category 1B ------H317 May cause an allergic skin reaction ------H401 Toxic to aquatic life ------H411 Toxic to aquatic life with long lasting effects
Party Responsible for the Preparation of This Document Rosemount Analytical Inc. 2400 Barranca Parkway Irvine, CA 92606 949-757-8500
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
North America GHS US 2012 & WHMIS 2
04/10/2015 EN (English US) 6/6