Titanium -Manaccan, Cornwall, England
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Rediscovery ol the Elements Titanium -Manaccan, CornWall, England James L. Marshall, Beta Eta '71 and Virginia R. Marshall , Department of Chemistry, University of North Texas, Denton, TX 76203-5070; [email protected] About 500 B.C., according to legend the sea faring Phoenicians of Carthage traveled as far west and north as the Cassiterides, the present Isles of Scilly, beyond the southwestern tip of Cornwall, to obtain tin'. Certainly by half a mil lennium later, tin mining by the Romans was commonplace throughout Cornwall (Figure 1), and tin was extracted in prodigious quantities through the eighteenth century. The tin was obtained from "cassiterite;' tin dioxide (SnOi), still today the most common ore for this ele ment .' It was in this region two hundred years ago that a new element"titanium"was discov ered by a parson in a stream by his church. Our guide to this region was Dr. Simon Camm, of the Camborne School of Mines, University of Exeter in Redruth, Cornwall. An hour automobile ride from Redruth through rolling hills brought us to the Goonhilly region of Lizard Peninsula (Figure 2). Situated in the Figure 5. Dr. Simon Camm of the Camborne School of Mines, University of Exeter, illustrates haw to obtain center of Manaccan (from the Comish word for the black ilmenite sand by a classic panning procedure. The a11Cient Victorian miners used this same proce "monk") was the church (Figure 3). Inside the dure for gold in this region. The ilmenite, being magnetic, can be lifted easily from the grit at the bottom of 5 church were neat wooden pews nestled the pan. beneath Gothic arches and beautiful stained glass windows. On the wall hung a copy of the process in Gillan creek (Figure 5). This Lord's Prayer {in Comish) and in the comer of black material is not as strongly magnetic London one window lay a plaque dedicated to as iron, but can be easily identified by its Reverend William Gregor, the "Scientific magnetism using a neodymium-iron Cornwal • Parson." Gregor had excelled at a young age in boron magnet.5 painting, music, and science, and at Cambridge Reverend Gregor's laboratoiy contained lOO km he had won academic honors in classics and such chemicals as "phlogistic alkali,""gall- Scilly,....- ~ / mathematics. He took holy orders but was also nut tincture" and 0 microcosmic salt" (proba- islands L ' d p- keenly interested in chemistry and mineralogy. bly potassium ferrocyanide, t.annic acid, and 1zar During walks by the nearby Gillan Creek sodium ammonium hydrogen phosphate, peninsula (Figure 4) he discovered in 1790 a black powder respectively).3 He did not have the sophisti which he thought appeared like gunpowder cated facilities of some chemists on the con Figure 1. Cornwall is the extreme southwest portion of but which"followed the compass,"that is, was tinent, but through his skills and persistent F.ngland. This region has been actively mined for tin for magnetic. He took the substance home and labors he was recognized by scientists more than two millennia. analyzed it, deciding that it held a new "earth." there, including Berzelius in Sweden. By a He named the new mineral "menachanite" complex series of experiments he was able it was dear that he had something new, and he now known as ilmenite, FeT!03.' to recogni7.e and characterize a new earth. presented his findings in 1791.' "Menachanite"washes down &om the west, Mixing the black menachanite with spiritus It remained for Martin Klaproth. the famous originating &om gabbro (Note 1). This black salus (hydrochloric acid), he dissoMd the*mar Berlin chemist who discovered uranium and sand was well know by Victorian gold miners, tial portion" and destroyed its black color, leav zittonium. to establish unequivocally the ele because it would collect and mix with the pre ing a reddish-brown calx, previously unknown. mental nature of Gregor's new earth (m 1794). cious metals during panning of the streams After over 100 experiments, including melting a Even though Klaproth pedonned the definitiye (Note 2). Dr. Camm illustrated this panning pattide in bomx that rendered the flux greenish, work and gave the modem name of"titanium* 4 TI-IE HEXAGON Figure 2. Lizard Peninsula of Cornwall. This region is sometimes called "Meneage" - Manaccan Monkish Land. The village of Manaccan, where titanium was discovered, may be reached by traveling to Helston 011 A394 (west from Falmouth or east from Penzance); intersecting A3a83 (sa· aS.S1 ' N, as· 1S.8S' \IV); proceeding 3.S km and then turning left on 83293 (sa· 04.39' N, as· 14.41 ', identified by'/'\"). From 83293 there are a multitude of nan-ow, winding roads which can reach Manacam, and exact, detailed instructions are laborious to delineate and probably even nwre difficult to follow-but if one turns left at the intersection identified by "8" (Sa' Helston a2.19' N, as· a7.S7' W, which is 10 km from'/'\'') and proceeds generally northward 7 km further, one will reach Manaccan and the church (Sa' as.al' N, as· a7.63' \IV). • Figure 4. The Manaccan region. The Manaccan church is in the center of the village, and the "black sand" can be procured by spading up sediments from the muddy lowlands of Gillan Creek, either upstream or downstream from the church. _... Figure 6. Portrait of William Gregor, by john Ilmenite washes dowr Hoppner, which hangs in Huntsman Tzoxide of from the Goon hilly - watershed ,._- London. (John Hoppnerwas appointed portrait 300 m painter of the Prince of Wales, later King George IV). / .. to the clement, he graciously extended to Notes Gregor the credit of the original discovery. It is to be recalled from the previous issue of The 1. Gabbro is a dark igneous rock related to HEXAGON that Klaproth likewise gave the granite, but richer in calcium and lacking creclit of the discovery of tellurium to Muller quartz. This particular formation was formed von Reichenstein of Romania. (The story of during the Devonian era, about 400 million Klaproth "undoubtedly the greatest German years ago. The ilmenite crystallized out in the analytical chemist of the day, but modest and gabbro in microcrystalline form, and as the benevolent" is a story that must wait until a gabbro eroded, the ilmenite "sand" was future issue of The HEXAGON). released. Truly a Renaissance man, Gregor's passions 2. Samples of ilmenite sand from Manaccan encompassed many arenas, particularly affairs are exhibited at the element/mineral collection of the British Navy and science. Self-taught, his of the author at University of North Texas.5 "love of science was voted a great nuisance in Photographs are available in Walking Tour of the his youth by the females of the establishment Elements, J. L. and V. R. MarshalL JMC Services, who were bothered by Master William's mess Denton, TX 76207. es," notably one Madam who washed her"fine 3. Huntsman Tioxide, Lincoln House, 137-143 laces in what she conceived to be fair water, but Hammersmith Road, London W14 OQI (51° which alas contained unseen qualities very 29.64' N, 00° 12.83' W). No portrait of Gregor detrimental to the precious net work ... ,"' In was available for Weeks' classic, definitive work later years Reverend Gregor was remembered on the elements.• Figure 3. Manaccan Church, Lizard Peninsula, as "kind and gentle, brave as a lion, truly reli Cornwall. This is originally a twelfth-century gious by nature and zealous in everything he Literature Cited Norman churr:h, and much of the original remains undertook."' His portrait, by John Hoppner 1. H. G. Wells, Tht OutUne of History, \bl. 1, p today. Tht first mention of Manaccan occurs in a (Figure 6), is proudly exhibited by Huntsman 155, Doubleday & Company, New\brlc.1920. charter of King f.adgar; diJted 967, where it was Tioxide of London (Note 3). 2. Dana's New Mineralogy, 8th Ed., John Wiley & Sons, N.Y. 1997. called "Usmanoc-Plaa ofthe Monks."' 3. Victor Gordon,, "The Titanic Pmon. • Ref1ino Acknowledgments Magazine, 1999, No. 50(Jwle),pp17-19, Rio 6. Crttl's Annalen, 1791, L 55. Gratitude is extended to Dr. Simon Camm of Tinto Publications, London. 7. L. S. Gregor, •Francis Gregor M.P. and the the University of Eiceter of Redruth, Cornwall, 4. Rev. H. H. Dixon, "TM Slory of the Parish Rev.~ Gregor M.A Notes by Mrs. L. S. who furnished transportation to Manacxan and Clam:h of Mmtamln," printed by the Brewers Gregor in her Recollections, 1853," letter much geological and historical information; of Helston, UM, and available from the dated October, 1853. Available at Huntsman and to Hany Cowling ol Huntsman Tioxide of Manaccan Owrd\. Th»dde, London. London (Note 3), who shared Gregor family 5. Marshall, J. L., /. C1rtm. &INC., 2000, 77, & Weeks, M. E., Diwoery of the Elements, 7th information and the portrait ol Gregor. 919-9&. ed..Jotmtal ofCMmiad 'Education, 1968. SPRING2001 5 .