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Page 1/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 * 1 Identification ∙ Product identifier ∙ Trade name: PerkinElmer Advanced Filter System ∙ Article number N9303963 ∙ Application of the substance / the mixture Laboratory chemicals ∙ Details of the supplier of the safety data sheet ∙ Manufacturer/Supplier: PerkinElmer, Inc. 710 Bridgeport Avenue Shelton, Connecticut 06484 USA [email protected] 203-925-4600 ∙ Emergency telephone number: CHEMTREC (within US) 800-424-9300 CHEMTREC (from outside US) +1 703-527-3887 (call collect) CHEMTREC (within AU) +(61)-290372994 * 2 Hazard(s) identification ∙ Classification of the substance or mixture Flame Self-heat. 1 H251 Self-heating: may catch fire. Health hazard Carc. 1A H350 May cause cancer. Corrosion Eye Dam. 1 H318 Causes serious eye damage. Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. ∙ Label elements ∙ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ∙ Hazard pictograms GHS02, GHS05, GHS08, GHS09 ∙ Signal word Danger ∙ Hazard-determining components of labeling: calcium oxide Quartz (SiO2) (Contd. on page 2) USA 49.0.10 Page 2/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 Trade name: PerkinElmer Advanced Filter System (Contd. of page 1) ∙ Hazard statements H251 Self-heating: may catch fire. H318 Causes serious eye damage. H350 May cause cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. ∙ Precautionary statements P220 Keep away from water. P222 Do not allow contact with air. P235+P410 Keep cool. Protect from sunlight. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. P391 Collect spillage. P407 Maintain air gap between stacks/pallets. P420 Store away from other materials. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ∙ Classification system: ∙ NFPA ratings (scale 0 - 4) Health = 3 4 Fire = 4 3 0 Reactivity = 0 ∙ HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 4 Fire = 4 REACTIVITY 0 Reactivity = 0 ∙ Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes. ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable. * 3 Composition/information on ingredients ∙ Chemical characterization: Mixtures ∙ Description: Mixture of the substances listed below with nonhazardous additions. ∙ Hazardous components: 7440-44-0 carbon Flam. Sol. 1, H228 29.2% 1344-28-1 aluminium oxide 16.0% (Contd. on page 3) USA 49.0.10 Page 3/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 Trade name: PerkinElmer Advanced Filter System (Contd. of page 2) 1313-13-9 manganese dioxide Acute Tox. 4, H302; Acute Tox. 4, H332 11.5% 1305-78-8 calcium oxide Eye Dam. 1, H318 10.0% 1317-38-0 copper(II) oxide Aquatic Acute 1, H400; Aquatic Chronic 1, H410 5.1% 14808-60-7 Quartz (SiO2) Carc. 1A, H350 1.0% ∙ Additional Components 7631-86-9 silicon dioxide, chemically prepared 16.89% 1313-59-3 SODIUM OXIDE 10.0% 10034-96-5 Mangan(II)-sulfat-Monohydrat 0.31% * 4 First-aid measures ∙ Description of first aid measures ∙ After inhalation: Supply fresh air; consult doctor in case of complaints. ∙ After skin contact: Generally the product does not irritate the skin. ∙ After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. ∙ After swallowing: If symptoms persist consult doctor. ∙ Most important symptoms and effects, both acute and delayed No further relevant information available. ∙ Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures ∙ Extinguishing media ∙ Suitable extinguishing agents: Use fire fighting measures that suit the environment. ∙ Special hazards arising from the substance or mixture No further relevant information available. ∙ Advice for firefighters ∙ Protective equipment: No special measures required. * 6 Accidental release measures ∙ Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. ∙ Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. ∙ Methods and material for containment and cleaning up: Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. ∙ Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. ∙ Protective Action Criteria for Chemicals ∙ PAC-1: 7440-44-0 carbon 6 mg/m³ (Contd. on page 4) USA 49.0.10 Page 4/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 Trade name: PerkinElmer Advanced Filter System (Contd. of page 3) 7631-86-9 silicon dioxide, chemically prepared 18 mg/m³ 1344-28-1 aluminium oxide 15 mg/m³ 1313-13-9 manganese dioxide 4.7 mg/m³ 1305-78-8 calcium oxide 6 mg/m³ 1313-59-3 SODIUM OXIDE 0.5 mg/m³ 1317-38-0 copper(II) oxide 0.75 mg/m³ 14808-60-7 Quartz (SiO2) 0.075 mg/m³ 10034-96-5 Mangan(II)-sulfat-Monohydrat 9.2 mg/m³ ∙ PAC-2: 7440-44-0 carbon 330 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 740 mg/m³ 1344-28-1 aluminium oxide 170 mg/m³ 1313-13-9 manganese dioxide 7.9 mg/m³ 1305-78-8 calcium oxide 110 mg/m³ 1313-59-3 SODIUM OXIDE 5 mg/m³ 1317-38-0 copper(II) oxide 11 mg/m³ 14808-60-7 Quartz (SiO2) 33 mg/m³ 10034-96-5 Mangan(II)-sulfat-Monohydrat 15 mg/m³ ∙ PAC-3: 7440-44-0 carbon 2,000 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 4,500 mg/m³ 1344-28-1 aluminium oxide 990 mg/m³ 1313-13-9 manganese dioxide 690 mg/m³ 1305-78-8 calcium oxide 660 mg/m³ 1313-59-3 SODIUM OXIDE 50 mg/m³ 1317-38-0 copper(II) oxide 93 mg/m³ 14808-60-7 Quartz (SiO2) 200 mg/m³ 10034-96-5 Mangan(II)-sulfat-Monohydrat 90 mg/m³ * 7 Handling and storage ∙ Handling: ∙ Precautions for safe handling Thorough dedusting. Ensure good ventilation/exhaustion at the workplace. Do not open cartridge ∙ Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. ∙ Conditions for safe storage, including any incompatibilities ∙ Storage: ∙ Requirements to be met by storerooms and receptacles: No special requirements. ∙ Information about storage in one common storage facility: Not required. (Contd. on page 5) USA 49.0.10 Page 5/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 Trade name: PerkinElmer Advanced Filter System (Contd. of page 4) ∙ Further information about storage conditions: Keep receptacle tightly sealed. ∙ Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection ∙ Additional information about design of technical systems: No further data; see item 7. ∙ Control parameters ∙ Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 1344-28-1 aluminium oxide PEL Long-term value: 15*; 5** mg/m³ *Total dust; ** Respirable fraction REL Long-term value: 10* 5** mg/m³ as Al*Total dust**Respirable/pyro powd./welding f. TLV Long-term value: 1* mg/m³ as Al; *as respirable fraction 1313-13-9 manganese dioxide PEL Ceiling limit value: 5 mg/m³ as Mn REL Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ as Mn TLV Long-term value: 0.02* 0.1** mg/m³ as Mn; *respirable **inhalable fraction 1305-78-8 calcium oxide PEL Long-term value: 5 mg/m³ REL Long-term value: 2 mg/m³ TLV Long-term value: 2 mg/m³ 14808-60-7 Quartz (SiO2) PEL Long-term value: 0.05* mg/m³ *resp. dust; 30mg/m3/%SiO2+2 REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *as respirable fraction ∙ Additional information: The lists that were valid during the creation were used as basis. ∙ Exposure controls ∙ Personal protective equipment: ∙ General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. (Contd. on page 6) USA 49.0.10 Page 6/12 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019 Trade name: PerkinElmer Advanced Filter System (Contd. of page 5) Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. ∙ Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. ∙ Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ∙ Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
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  • Interaction of Water with the Cao(001) Surface † ‡ † § ‡ † ∥ Yuichi Fujimori, Xunhua Zhao, Xiang Shao, , Sergey V

    Interaction of Water with the Cao(001) Surface † ‡ † § ‡ † ∥ Yuichi Fujimori, Xunhua Zhao, Xiang Shao, , Sergey V

    Article pubs.acs.org/JPCC Interaction of Water with the CaO(001) Surface † ‡ † § ‡ † ∥ Yuichi Fujimori, Xunhua Zhao, Xiang Shao, , Sergey V. Levchenko, Niklas Nilius, , † ⊥ † Martin Sterrer,*, , and Hans-Joachim Freund † ‡ Department of Chemical Physics and Theory Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany ∥ Institute of Physics, Carl-von-Ossietzky University, 26111 Oldenburg, Germany ⊥ Institute of Physics, University of Graz, Universitatsplatz̈ 5, 8010 Graz, Austria *S Supporting Information ABSTRACT: The interaction of water with the CaO(001) surface has been studied from ultrahigh-vacuum to submillibar water vapor pressures and at temperatures of 100 and 300 K using well-structured CaO(001)/Mo(001) thin-film model systems. Infrared reflection absorption spectroscopy (IRAS), X-ray photoelectron spectroscopy (XPS), and scanning tunneling microscopy (STM) in combination with density functional theory (DFT) calculations have been employed to reveal the correlation between the vibrational frequencies of the hydroxyl groups and the distinct hydroxylated surface phases that develop as a function of water exposure. In the low-coverage regime, water monomers, small water clusters, and one-dimensional water chains are formed on the CaO(001) surface. At increasing water coverages, water-induced structural disorder is observed, indicating 2+ partial solvation of Ca ions. Partial transformation of CaO(001) into a Ca(OH)2-like phase occurs upon dosing of water at submillibar water pressure. In addition, it was found that interfacial hydroxyl groups formed on the CaO(001) surface during water exposure at temperatures as low as 100 K shift the temperatures for ice desorption and for the transition from amorphous solid water to crystalline ice by 10 K as compared to those for the nonhydroxylated MgO surface.