Authigenic Analcite in the Golden Valley Formation Southwestern North Dakota Marvin J
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University of North Dakota UND Scholarly Commons Theses and Dissertations Theses, Dissertations, and Senior Projects 1970 Authigenic analcite in the Golden Valley Formation southwestern North Dakota Marvin J. Furman University of North Dakota Follow this and additional works at: https://commons.und.edu/theses Part of the Geology Commons Recommended Citation Furman, Marvin J., "Authigenic analcite in the Golden Valley Formation southwestern North Dakota" (1970). Theses and Dissertations. 103. https://commons.und.edu/theses/103 This Thesis is brought to you for free and open access by the Theses, Dissertations, and Senior Projects at UND Scholarly Commons. It has been accepted for inclusion in Theses and Dissertations by an authorized administrator of UND Scholarly Commons. For more information, please contact [email protected]. Authentic Analcite in the Golden Valley Formation (?), SouthWestern North Dakota by Marvin J. Furman Bachelor of Science, St. Lawrence University 1965 A Thesis Submitted to the Faculty of the University of North Dakota in partial fulfillment of the requirements for the degree of Master of Science Grand Forks, North Dakota July 1970 /~ \ ..,;,, .. ..:. .. _. .,· ,,,,:;, / I I t ·-----·- t ,-~~·__: ............. ;.... "":."' b ..:;.:::.:,o~ I•, -·.- .. ~ ... ,., ' . -.JV·-'"'.••- I:.Ao.m. t!"'.. e ·u:;::vcrsity v:: gree that the Libr-.'.l.ry of this University shall m::::.:{o it f1~00:y available i'"ol,... ir:.spoct,ion. I further agreo th~t permission for 0xtensiv8 cor,yi~g in r-.is ~bso:-.. ce )' by tho of the Dcp::..rtmcnt or othc:..,, Ol~ tt.a.s or It is c2..lso . · given to rri.e the University of :.:.:r.y schol~~ly uze which m.ay c~ of a.,y material The field Tho writer is ir.debted to his fellow g:i.~aduatc st"..l.d0r:.ts whc acted. as a sounding board for many of the ideas eh-pressed hero .. Spccia.1 th~:1.}:s are extended to W. J. ·stone for the use of his samples and to H. C. Ziebarth for his inv.11.uable assistance and suggestions on photogr~phic . :rep;r-od:uct ion .. .:, I l iv 1 ·~ .i~:..DL~~ c_~ '""' -·~·~~·~.~~~"\ s ?::..;:/3 .li.CKl\O~·~·LWGl·:Z\J?S . • . .. • .. .. .:;_ ',/ LIST 01~ TABL:SS 0 . .. .. • . .. .. .. .. .. .. " . vii 7" -ell" ;..;..LvJ. OF ILLUSTRP.TI Ol'JS . • • . .. .. • . • . .. • • • . viii :_r-~~ ..'.BS '.:'.R.ACT . • • .. .. • . • • • . 0 • . • . • . .. ~ INTRODUCTION • . • • . .. " . .. • . • . .!. Modes of Cccurrcnce of P.,:,-.alcits • .. • .. • • l Scope ar.d Pc.r-_pose of Study • • • • • • • • . 2 Previous Investigations • . • . • . • .. • . J Description o.f Study Area • . .. • . .. • • • . 3 METHODS Ob, INVESTIGATIONS • • • .. .. .. • . • .. • . 7 Sarnplir,3 .. .. " • . .. • • " .. .. .. • .. • • ? .Analyti::::::.l Procedures .. • .. • .. " . • .. .. • .. • • • 7 G;:;::.G :.'\?.l ~ 0 Q .. • " .. .. .. • .. .. .. 7 ?ct:..... ~;~:.*"r.. :~hic PrGpara. tio:c. • • .. • . • • . 8 ..... ::-·o g:...'\s.:Jhic a:.11d C·;,tic~l ~:c:.::.suramen ts • . 8 Q 8 X-?..~}" Diff~'\action )11talysis .. " . • . P-t'occdures for X-R2.y Diff:i.'"'actio:'1 }_YJ.a.lysis . • .. g . .. .. • .. .. .8 Precision and Accuracy of "SGrni- Q.1antit.ative X-Ray Diffraction ll .c:.r-.tlysis .. • .. • • .. .. • . • .. " • • . .. D::;·:,,:;~... rninatio~ of Ana.lcite Corrrposition .. .. • • 13 Clu)'" l"line~tl Analysis • • • . • .. • .. • .. • 15 j c:. G~~i:1. Size ,Analysis . .. .. • • . .. .. • . -.-1 STPJ~'I:IGl'::ii.J;...-;;~.i 0 0 l? • .. • " . • .. " • • .. • . .. • .. • G0nartl Discussion .. .. ~ " • .. .. .. .. .. • .. .. l? fuscz-i i:;~~i.:>i'lS oi' Formatic~s E:;cposed :L."l the A;:0;;.. o:f .A.nalcite-ba~~ing Sedimenta:.:-y Rock::, .. • .. l'? 'I·c:... ~"::..G Rivel"' :£i'ormatio11 .. • .. .. .. • .. .. • • . .. f $ S.:/.~.-::i:-1el. Fo:c-m.:ition 0 Butte . .. • • . • • 19 ~ " ...-,r- C,.::;~::.,:;n Valley F o~rr.. c. ti en .. .. .. .. .. .. .. ~v l.t . " • " ~' .:;-__ .. d:."'on Formation .. • .. .. • . .. 2.2. 3:.~ulo 2-::· Fom.ation .. .. .. " . ...\: .. il{aree Formation . .. • • . • 22 Stl.~c;.tic~:r~~phic and Litholc;c;ic Distrioutic.n o:f .An:.:..lcito .. • .. • • . .. • • . • . • . V c,,.,,.....,,..... ~ ............ , ?.) ................. ..,i..;. ....... Dizctt!i~ion . iL~n.lc:i.tc ~~ ·c.ho Sontinol B:~:.to Itc:c-:r:.::.:tion . ?.h I !.J.1alcitc in +·...,ne Golden V::..lloy Forr.-1~t:l.on . 2L;.. I ,.'i; ? BT!\OGR.J\.P h"'Y o·'.t' ANA:CITE-BEJ._q=:; G RCCKS • . 29 j: !1inern.ls .. .. • . .. • • • "' .. .. .. 29 Quar-;;.z . .. • . .. .. .. .. • 29 Feldspar .. .. .. g .. .. .. • .. • . 2.9 Chert . • .. .. • .. • • " . 32 1~1~lcitc .. • .. • . • . • • • • . • • 32 ,:,f,:.., Cl.:1~r l"1inoral~ .. .. .. • • . .,, j • l!. ', j~ Rock TIJr,os • . • • . • . • . • ,J ( • • • ~ .Arkoso . • • . • • . .. 43 ][ lmalcimolite • . • • . • . • • • • 53 DISCUSSION . • • . • . • • • . • • • . • • 64 J:,Iineral Associations • • .. • . • . • • . • . • . 6l~ ll Analcite-Pyroclastic Association • • • • . • • . 64 I .Analcite-Quarlz Association . .. .. .. • • . 66 lu~alcite-Feldsp~~ Association • . • • . • 66 Analcite-Sericitc Association .. • . 79 . I 80 Fok~mn.tion of Sphcrulites • • .. .. • • • .;'ii Ii Relationship of L-rialcite Occurrences i·r... t!"'.. e . A11' Arkose and Analcimolite • • . • • • • .. 82 ~1nr1 Relation snip of .balcita Pistributiori to the 85 Post-Eocene Unco:nf ormity • . .. • " • .. • • • • r ! l SC/.:Y.i".:"li.Y OF CONCLUSIONS .. .. .. 86 j .. • • • • • • . • • . • • • \ .li.l~P~"\JDIX . • . .. .. • .. .. • . • . • • • • • • • • • • 88 B?ERE:i.'JCES 0 103 . • .. " • • . • .. .. • • • • • • • • • • • . • Ii, 1,t1i : ,:ti:1 ·1111 'ii ,1 '.,r•·I 1·:1:J:1 ·.1U:I 'f;li'li' (111111 1111!1 ,1111111 _1 1m11 vi LIST OF T.A3LEs Table Page 1 Vru.uos Used for the Calcula-::.ion o:f N"cd.'.?.l Compositions • • • • • • • • • • • • • • • • . • • • • • 11 2 Standard Deviations of the Weight Fractions of: Minor.:ils Obtained by Direct Scrd.-Quar.ti tati ve X-Ray tiffraction .!L"l.:i.lysis • • • • • . lJ J I'linimum level o:f Detoct. ...1.bili ty of' Y1inor.:1ls by Semi-Quantitative X-Ray Diff~action .Analysis • • • • • • • • • • • • • • • • • • • • . 14 4 Goneral.izcd Section of Formations Exposeq in the Arca ot· A:.-'lalcite-boa:ring Sedimentary Rocks in Southwestern North Dakota ••••• • • • • • • 18 5 Minerals Identified in Samples Taken in Reconnaissance Study •••••••••• /' • • • • • • • • 25. ·O X-Ray Dii'.fraction Powder: Data for ..A.na.lcite • • • • • • • 41 7 Cox.position of J.na.lci te • ·• • • • • • • • • • • • • • . 42 8 Grc.in-Size Data for Analcite-bearing .!h~kcse •• '>•••••9•o••••• " .. 9 l'icda.l Comyosi tion of L"la.lci te-beari..ng .Rocks on S(mtinel Butte • • • • • • • • . 59 .. 10 lfod.al Co:npcsition of .l\..i-:talcite-bearing Rocks en Flat Top Butte.·· ••••••••••• • •• 61 11 Modal Composition of 1:...'1alcita-bea:i:-ing Rocks on Bullion Butte .. • · • • • • .. • • • • • • • • • • 12 :Kodal Corc:oosi tion of }:n.alcite-be~ring Rocks c::i Slide and Cru:i.JJ~J Buttes • • • • • • • • • • •.• 63 13 Confider.ca Levels at which the Hypothesis 'x;,::::0 :.! X,.;::;.,can be Accepted. a.s Significant • • • • 0 • • • 71 J.::-eal. Locations :...'1d Stratig-~aphic Positions of Specimens Cited i."1 'i'axt • • • • • 0 • .. • . .. 89 vii ,. C, :tcfcror.. cu }X..::i • z cr~:i..:... .. .. ., . 4 .A.il~lcit0 Si)i'.to:'"""~litc wi~h ;5 R.:.::.di.:µ. St~~ct~~0 • • . Analcitc Sphorulite with .:.. lVia.ssive )5 5 Center .::ind Peripheral Radial Sti:"Uc~ure •••• 6 Distorted, Coalesced, ~~~alcite • .. .. • • • • • " • • • • Coarso-Grained IJ.litic Katrix 7 • • • • • 37 (Sericite) .... • • .. • .. • • • 8 SG~icite L~clusions in J.nalcite .40 .. .. • .. • .. Sphe!"Ulite • • • • • ... " .. • • C;; }fodtl Co.:nposi tion of A."l.alci te- 45 bearing 1.rkose ••• o. v o ••••• • • • ~ ,... Y.d.ne~alogic Classification of .J.U .. • .. • • 48 }.nalcite-bearing Arkose • ~ • • " • • • • G~ain-Size Distribution of .P..nalcite-beari.."lg Al."'kose " .................. • • 52 Coa1.,se Sc~icite Fl~kes Or·i.ented Ta:.~gantial to the Periphe~"Y o~ 55 Sphe!'Ulites. • .. • • • It • • o • .. • • • • • • • • • a • .. 55 Texture of Analcimolite • • • • • • • • .. • .. • 58 Modal Composition of :..nalcimolite • • • • • ,.. _ l5 Classification of Analcite Based O) 0 • .. .. • on Composition ...... C •••• • ... • • • - ., ...LO Sc.s.tt'er- Dia.gra."ll of Analcite 68 Dat:.~it.ll Plagicclase .. • • • • • • • • • • • • • • Scat.tar Diagram of J... "1.alcite 70 Datrital. Potassium Feldspar • • • • • • • • viii -· ,.., •' . ..... _..., .... _._...,, .. r- .• ~. 19 VA 77 20 Cc:rr:::,a:.."'":~o~r: of .: ¥--~:1 rs:: o:: ...:..:.1tlci~::.o i:: ~·...:.:~:_ci:.:c:...::..!..:.~ ,., ,.,..r,.., ,., ·,.- ,- w,,-,,,.. ~,,.,,. ~ t-..Jv,....,.v .J' .,,.. ..__ ' ... ,,,, .-... ,.,_., ...J,.-.vv1/'..,., ....... ," .,..,_n,,.-,y,"- Tb.e ~~lei "~o ., ..................... v ' . r,:--,·,..._ .,-:\ occ.:. .............. cc~~rs as spherulitos i:r: the interstic0s cf ..~: .. 0 ~:.~!{osG ~:':.Q £.:.S lJ. cc:r.:cn.t :'.L.:"i the c-r,.. ~-..- Three types of sptcr~litos a~e recog~iz0~: (:.) - J,.. .. 1!,,; _ _ uli~es with an internal radial str-~cture; (2) sptc~~lite~ with a ~.as- si.ve center a.-rid a peripheral radial st::c-u.cture; c:,.;r.d (3) spherulites an i:.ternal ht:vi:-.g OCC'i.1::.-' ir.d:. v:..c:c...::..:.iy K-feldspa~, and i:.lite~ arkose ur.it ,.#0 ...:.:t.::~io~-.:. feldspa~... s. It ·oronos.ad that &nalcite ;. ... b }.:'1~lci te ::.~ cl.:1ssified chemistry~ .:::.nd tics ,;.iith the foldspathoids (Deer, 1963). .'..J"a~:cite is gene~ally expressed as varLJ.tions in composition, in which potassium substitutes for sodiu...'11,