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Influence of Hydrothermal Pretreatment Temperature processes Article Influence of Hydrothermal Pretreatment Temperature on the Hydration Properties and Direct Carbonation Efficiency of Al-Rich Ladle Furnace Refining Slag Yi Huang 1,* and Guo Xiong 2 1 School of Materials and Chemical Engineering, Hunan City University, Yiyang 413002, China 2 Hunan Hualin Xiangtan Iron and Steel Co., Ltd., Xiangtan 411101, China; [email protected] * Correspondence: [email protected] Abstract: The influence of hydrothermal pretreatment temperature on the hydration products and carbonation efficiency of Al-rich LF slag was investigated. The results showed that the carbonation efficiency was strongly dependent on the morphology of hydration products and the hydration extent of the raw slag. Hydrothermal pretreatment at 20 ◦C or 80 ◦C favored the formation of flake- shaped products with a higher specific surface area and therefore resulted in a higher CO2 uptake of 20 ◦C and 80 ◦C-pretreated slags (13.66 wt% and 10.82 wt%, respectively). However, hydrothermal pretreatment at 40 ◦C, 60 ◦C or 100 ◦C led to the rhombohedral-shaped calcite layer surrounding the unreacted core of the raw slag and the formation of fewer flake-shaped products, resulting in ◦ ◦ ◦ a lower CO2 uptake of 40 C, 60 C and 100 C-pretreated slags (9.21 wt%, 9.83 wt%, and 6.84 wt%, respectively). Keywords: LF slag; hydrothermal pretreatment; temperature; hydration products; CO2 uptake Citation: Huang, Y.; Xiong, G. Influence of Hydrothermal Pretreatment Temperature on the Hydration Properties and Direct Carbonation Efficiency of Al-Rich 1. Introduction Ladle Furnace Refining Slag. Processes The growth of global greenhouse gas emissions was 2.0% in 2018 and there is no 2021, 9, 1458. https://doi.org/ sign that any of these emissions are peaking yet. The six largest emitters of greenhouse 10.3390/pr9081458 gases, together accounting for 62% globally, are China (26%), the United States (13%), the European Union (more than 8%), India (7%), the Russian Federation (5%), and Japan Academic Editor: Federica Raganati (almost 3%) [1]. China’s carbon emission peak is a matter of international focus. Recently, China made a solemn promise to peak its carbon dioxide emission by 2030 and achieve Received: 29 July 2021 carbon neutrality by 2060. Some of the main measures China will use to reduce CO2 Accepted: 19 August 2021 emissions over next 10 years are: changing energy and industrial structures, transforming Published: 21 August 2021 the development mode, promoting clean energy, and appropriately increasing carbon sequestration ability. Among the current CO2 sequestration routes, mineral carbonation is Publisher’s Note: MDPI stays neutral regarded as a potential technology because of its advantages; it is environmentally benign, with regard to jurisdictional claims in it enables the permanent trapping of CO2 in the form of carbonate, and it does not require published maps and institutional affil- post-storage surveillance for CO leakage [2]. In general, mineral carbonation can be iations. 2 divided into two categories, namely direct carbonation and indirect carbonation. Direct mineral carbonation is accomplished through the reaction of a solid alkaline mineral with CO2, either in gaseous or in aqueous phase [3]. Alkaline solid wastes such as red mud, steel slag, blast furnace slag, fly ash, etc., are Copyright: © 2021 by the authors. used for direct mineral carbonation as efficient and economically available capturers of Licensee MDPI, Basel, Switzerland. CO2 [4–9]. For the direct mineral carbonation of steel slag, the formation of an increasingly This article is an open access article thick and dense carbonate layer surrounding the unreacted core of the solid particle hinders distributed under the terms and further carbonation and results in the lower CO capture capacity [10]. In our previous conditions of the Creative Commons 2 study [11], the improvement in the direct carbonation efficiency of Al-rich ladle furnace Attribution (CC BY) license (https:// refining slag (LF slag) by hydrothermal pretreatment was investigated. The results showed creativecommons.org/licenses/by/ ◦ 4.0/). that after hydrothermal pretreatment at 80 C, the morphology of Ca12Al14O33(C12A7) in Processes 2021, 9, 1458. https://doi.org/10.3390/pr9081458 https://www.mdpi.com/journal/processes Processes 2021, 9, 1458 2 of 12 the slag transformed from separated particles to the flake-shaped Ca3Al2O6·xH2O(C3AHx), resulting in an increased reaction surface area and carbonation efficiency. However, this study did not discuss the effect of hydrothermal temperature on the carbonation effi- ciency. In fact, the hydration product of C12A7 is dependent on the hydration temperature. ◦ Koplík et al. [12] reported that at 20 C the major hydration products of C12A7 were ◦ Ca2Al2O5·8H2O(C2AH8) and CaAl2O4·10H2O(CAH10); at 30 C CAH10 disappeared and ◦ only C2AH8 remained; at 60 C the only stable hydrates–Ca3Al2O6·6H2O(C3AH6) and Al(OH)3(AH) were formed. Edmonds et al. [13] stated that both C2AH8 and CAH10 can ◦ be produced during the hydration of C12A7 at 4 C, while no trace of CAH10 was spotted ◦ when C12A7 was hydrated at 20 or 40 C. Given that the morphology of the hydration product of C12A7 has a significant effect on the carbonation efficiency of LF slag and the type of hydration product produced is related to temperature, the aim of this study was to investigate the influence of hydrothermal pre-treatment temperature on the hydration properties and the carbonation efficiency of Al-rich LF slag at ambient temperature and pressure. Moreover, the relation between the morphology of the hydration product and the carbonation efficiency was clarified in this work. 2. Materials and Methods 2.1. Materials The Al-rich LF slag used in this study was collected from the Xiangtan steel plant in Hunan province, China. The chemical composition of the slag determined by X-ray Fluorescence (XRF) is listed in Table1. Before pretreatment, the raw slag was crushed and ground into a powder <20 mesh particle size. Distilled water was used in this study for slag suspension preparation. Table 1. Chemical composition of raw slag as determined by XRF analysis. Component CaO Al2O3 SiO2 MgO TiO2 SO3 Fe2O3 Others wt% 52.0056 23.66 15.83 4.05 0.90 2.45 0.54 0.57 2.2. Hydrothermal Pretreatment of LF Slag at Different Temperatures At first, the raw slag was fully mixed with water at a solid/water (S/W) ratio of 1:10 in a beaker. Then, the suspension was stirred for 30 min at 20, 40, 60, 80 and 100 ◦C (designated as 20H, 40H, 60H, 80H and 100H-slag, respectively). Next, the suspension was filtered and the obtained solid was sufficiently washed and dried to a constant weight at 105 ◦C for further characterization and for the following carbonation experiment. 2.3. Direct Aqueous Carbonation Process The schematic diagram of the aqueous carbonation experimental system is shown in Figure1. The pretreated slag suspension with a solid/water ratio of 1:10 was placed in a conical flask into an electric-heated thermostatic water bath equipped with a mechanical ◦ stirrer. The temperature of the water bath was kept at 40 C. Then, 99.99% pure CO2 from the CO2 cylinder was injected into the suspension at a flow rate of 5 L/min controlled by a flowmeter, and was simultaneously stirred for carbonation. The suspension underwent the carbonation process for 60 min and was then filtered. The obtained solid was dried to a constant weight at 105 ◦C for further characterization. Processes 2021, 9, 1458 3 of 12 Processes 2021, 9, 1458 3 of 12 FigureFigure 1. 1. SchematicSchematic diagram diagram of of the the aqueous aqueous carbonation carbonation experimental experimental system system.. 2.4.2.4. Characterization Characterization of of Slag Slag X-rayX-ray diffraction (XRD,(XRD, BrukerBruker AXS AXS company company D8 D8 Advance, Advance, Karlsruhe, Germany) Germany) was con- was ductedconducted on the on slags the slags to identify to identify their theirmain main mineral mineral phases. phases. The scanning The scanning range rangewas from was ◦ ◦ ◦ 5°from to 70° 5 to2θ 70 at 2°/min.2θ at 2 TG-DSC/min. TG-DSC analysis analysis was performed was performed using a using METTLER a METTLER TOLEDO TOLEDO 1600 LF1600 thermal LF thermal gravimetric gravimetric analyzer. analyzer. A field-emis A field-emissionsion scanning scanning electron microscope electron microscope (FESEM, Hitachi(FESEM, company Hitachi companySU8010, Japan) SU8010, was Tokyo, used Japan)to characterize was used the to morphology characterize theof the morphology slag. The specificof the slag. surface The area specific of the surface slags areawas ofmeasured the slags by was the measured N2 gas adsorption by the N2 Brunauer–Em-gas adsorption met–TellerBrunauer–Emmet–Teller (BET) method (ASAP (BET) method 2020, Micromeritics, (ASAP 2020, USA). Micromeritics, The pH value Norcross, of the GA, slag USA). sus- pensionThe pH was value determined of the slag by suspension a PHS-3C was pH determinedmeter. by a PHS-3C pH meter. 2.5. Analysis of Carbonation Efficiency 2.5. Analysis of Carbonation Efficiency In order to compare the carbonation efficiency of Al-rich LF slags under the hydrother- In order to compare the carbonation efficiency of Al-rich LF slags under the hydro- mal pretreatment at different temperatures, the CO2 uptake of the slags was measured thermal pretreatment at different temperatures, the CO2 uptake of the slags was measured based on the weight fraction of the TG curve (Dm600–800 ◦C) and the dry weight (m) [14] based on the weight fraction of the TG curve (Δm600–800 °C) and the dry weight (m) [14] expressed in terms of CO2 (wt%), Equation (1): expressed in terms of CO2 (wt%), Equation (1): Dm ◦ Δm600–800600–800°CC COCO2(wt%(wt%)=) = ×100×100 (1) (1) 2 mm 3. Results and Discussion 3.3.1.
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