Pb2+ Uptake by Magnesite: the Competition Between Thermodynamic Driving Force and Reaction Kinetics
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Paralaurionite Pbcl(OH) C 2001-2005 Mineral Data Publishing, Version 1
Paralaurionite PbCl(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals are thin to thick tabular k{100}, or elongated along [001], to 3 cm; {100} is usually dominant, but may show many other forms. Twinning: Almost all crystals are twinned by contact on {100}. Physical Properties: Cleavage: {001}, perfect. Tenacity: Flexible, due to twin gliding, but not elastic. Hardness = Soft. D(meas.) = 6.05–6.15 D(calc.) = 6.28 Optical Properties: Transparent to translucent. Color: Colorless, white, pale greenish, yellowish, yellow-orange, rarely violet; colorless in transmitted light. Luster: Subadamantine. Optical Class: Biaxial (–). Pleochroism: Noted in violet material. Orientation: Y = b; Z ∧ c =25◦. Dispersion: r< v,strong. Absorption: Y > X = Z. α = 2.05(1) β = 2.15(1) γ = 2.20(1) 2V(meas.) = Medium to large. Cell Data: Space Group: C2/m. a = 10.865(4) b = 4.006(2) c = 7.233(3) β = 117.24(4)◦ Z=4 X-ray Powder Pattern: Laurium, Greece. 5.14 (10), 3.21 (10), 2.51 (9), 2.98 (7), 3.49 (6), 2.44 (6), 2.01 (6) Chemistry: (1) (2) (3) Pb 78.1 77.75 79.80 O [3.6] 6.00 3.08 Cl 14.9 12.84 13.65 H2O 3.4 3.51 3.47 insol. 0.09 Total [100.0] 100.19 100.00 (1) Laurium, Greece. (2) Tiger, Arizona, USA. (3) PbCl(OH). Polymorphism & Series: Dimorphous with laurionite. Occurrence: A secondary mineral formed through alteration of lead-bearing slag by sea water or in hydrothermal polymetallic mineral deposits. -
Download PDF About Minerals Sorted by Mineral Name
MINERALS SORTED BY NAME Here is an alphabetical list of minerals discussed on this site. More information on and photographs of these minerals in Kentucky is available in the book “Rocks and Minerals of Kentucky” (Anderson, 1994). APATITE Crystal system: hexagonal. Fracture: conchoidal. Color: red, brown, white. Hardness: 5.0. Luster: opaque or semitransparent. Specific gravity: 3.1. Apatite, also called cellophane, occurs in peridotites in eastern and western Kentucky. A microcrystalline variety of collophane found in northern Woodford County is dark reddish brown, porous, and occurs in phosphatic beds, lenses, and nodules in the Tanglewood Member of the Lexington Limestone. Some fossils in the Tanglewood Member are coated with phosphate. Beds are generally very thin, but occasionally several feet thick. The Woodford County phosphate beds were mined during the early 1900s near Wallace, Ky. BARITE Crystal system: orthorhombic. Cleavage: often in groups of platy or tabular crystals. Color: usually white, but may be light shades of blue, brown, yellow, or red. Hardness: 3.0 to 3.5. Streak: white. Luster: vitreous to pearly. Specific gravity: 4.5. Tenacity: brittle. Uses: in heavy muds in oil-well drilling, to increase brilliance in the glass-making industry, as filler for paper, cosmetics, textiles, linoleum, rubber goods, paints. Barite generally occurs in a white massive variety (often appearing earthy when weathered), although some clear to bluish, bladed barite crystals have been observed in several vein deposits in central Kentucky, and commonly occurs as a solid solution series with celestite where barium and strontium can substitute for each other. Various nodular zones have been observed in Silurian–Devonian rocks in east-central Kentucky. -
Neutron Single-Crystal Refinement of Cerussite, Pbc03, and Comparison with Other Aragonite-Type Carbonates
Zeitschrift fur Kristallographie 199, 67 -74 (1992) cg by R. Oldenbourg Verlag, Munchen 1992 - 0044-2968/92 $3.00+0.00 Neutron single-crystal refinement of cerussite, PbC03, and comparison with other aragonite-type carbonates G. Chevrier1, G. Giester2, G. Heger 1, D. Jarosch2, M. Wildner2 and J. Zemann 2 1 Laboratoire Leon Brillouin (laboratoire commun CEA-CNRS), C.E.N. Saclay, F-91191 Gif-sur-Yvette cedex, France 2 Institut fUr Mineralogie und Kristallographie, Universitiit Wien, Dr. Karl Lueger-Ring 1, A-I0I0 Wien, Austria Dedicated to Prof Dr. Hans Wondratschek Received: January 10, 1991; in final form: June 6,1991. Cerussite / PbC03 / Neutron structure refinement / Aragonite-type carbonates Abstract. The crystal structure of cerussite, PbC03, was refined with 669 merged single-crystal neutron data [Fo > 3G(Fo)]to R = 0.032, Rw = 0.Of5 (space group Pmcn; a = 5.179(1), b = 8.492(3), c = 6.141(2); Z = 4). - Cerussite belongs to the aragonite-type compounds. The weak aplanarity of the carbonate group, d = 0.026(1) A, is of the same order of magnitude as in aragonite, CaC03, and strontianite, SrC03, and the direction of the deviation from planarity is the same. The minor details of the stereochemistry differ slightly from the expectations to be drawn from the structures of the alkaline earth carbonates on the basis of the effective ionic radii of the twovalent metals. Introduction It is well known from the old days of morphological crystallography that cerussite, PbC03, is isomorphous with aragonite, CaC03, strontianite, SrC03, and witherite, BaC03. Zachariasen (1928) confirmed this by X-ray methods and derived coordinates of the Pb atom for this mineral. -
Descloizite Pbzn(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1
Descloizite PbZn(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or pyramidal {111}, prismatic [001] or [100], or tabular {100}, with {101}, {201}, many others, rarely skeletal, to 5 cm, commonly in drusy crusts, stalactitic or botryoidal, coarsely fibrous, granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼6.2 D(calc.) = 6.202 Optical Properties: Transparent to nearly opaque. Color: Brownish red, red-orange, reddish brown to blackish brown, nearly black. Streak: Orange to brownish red. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.185(10) β = 2.265(10) γ = 2.35(10) 2V(meas.) = ∼90◦ Cell Data: Space Group: P nma. a = 7.593 b = 6.057 c = 9.416 Z = 4 X-ray Powder Pattern: Venus mine, [El Guaico district, C´ordobaProvince,] Argentina; close to mottramite. 3.23 (vvs), 5.12 (vs), 2.90 (vs), 2.69 (vsb), 2.62 (vsb), 1.652 (vs), 4.25 (s) Chemistry: (1) (2) (1) (2) SiO2 0.02 ZnO 19.21 10.08 As2O5 0.00 PbO 55.47 55.30 +350◦ V2O5 22.76 22.53 H2O 2.17 −350◦ FeO trace H2O 0.02 MnO trace H2O 2.23 CuO 0.56 9.86 Total 100.21 100.00 (1) Abenab, Namibia. -
Theoretical Study of the Dissolution Kinetics of Galena and Cerussite in an Abandoned Mining Area (Zaida Mine, Morocco)
E3S Web of Conferences 37, 01007 (2018) https://doi.org/10.1051/e3sconf/20183701007 EDE6-2017 Theoretical study of the dissolution kinetics of galena and cerussite in an abandoned mining area (Zaida mine, Morocco) LamiaeEl Alaoui, AbdelilahDekayir* UR Geotech, Département de Géologie, Université Moulay Ismail, Meknès, Maroc Abstract. In the abandoned mine in Zaida, the pit lakes filled with water constitute significant water reserves. In these lakes, the waters are permanently in contact with ore deposit (cerussite and galena). The modelling of the interaction of waters with this mineralization shows that cerussite dissolves more rapidly than galena. This dissolution is controlled by the pH and dissolved oxygen concentration in solution. The lead concentrations recorded in these lakes come largely from the dissolution of cerussite. Introduction In the worldwide, abandoned mine sites are known by significant degradation of water quality and contamination of aquatic systems by heavy metals, which are known to be very harmful to human health due to the acid mine drainage phenomena causes by the oxidation of the sulphides, in particular pyrite and arsenopyrite. The oxidation of the sulphides causes a significant decrease in the pH, which causes the dissolution of the mineral phases and the release of metals in solution. In the upper Moulouya, water is a rare commodity. In fact, the aridity of the climate and the low rate of precipitation require the preservation of lakes waters which represent important reservoirs for the irrigation of the crops and the watering of the livestock. In the Zaida mine, primary mineralization consists mainly of cerussite (70%) and galena [7]. -
Bulletin 65, the Minerals of Franklin and Sterling Hill, New Jersey, 1962
THEMINERALSOF FRANKLINAND STERLINGHILL NEWJERSEY BULLETIN 65 NEW JERSEYGEOLOGICALSURVEY DEPARTMENTOF CONSERVATIONAND ECONOMICDEVELOPMENT NEW JERSEY GEOLOGICAL SURVEY BULLETIN 65 THE MINERALS OF FRANKLIN AND STERLING HILL, NEW JERSEY bY ALBERT S. WILKERSON Professor of Geology Rutgers, The State University of New Jersey STATE OF NEw JERSEY Department of Conservation and Economic Development H. MAT ADAMS, Commissioner Division of Resource Development KE_rr_ H. CR_V_LINCDirector, Bureau of Geology and Topography KEMBLEWIDX_, State Geologist TRENTON, NEW JERSEY --1962-- NEW JERSEY GEOLOGICAL SURVEY NEW JERSEY GEOLOGICAL SURVEY CONTENTS PAGE Introduction ......................................... 5 History of Area ................................... 7 General Geology ................................... 9 Origin of the Ore Deposits .......................... 10 The Rowe Collection ................................ 11 List of 42 Mineral Species and Varieties First Found at Franklin or Sterling Hill .......................... 13 Other Mineral Species and Varieties at Franklin or Sterling Hill ............................................ 14 Tabular Summary of Mineral Discoveries ................. 17 The Luminescent Minerals ............................ 22 Corrections to Franklln-Sterling Hill Mineral List of Dis- credited Species, Incorrect Names, Usages, Spelling and Identification .................................... 23 Description of Minerals: Bementite ......................................... 25 Cahnite .......................................... -
Contaminant Bioavailability in Soils, Sediments, and Aquatic Environments
Proc. Natl. Acad. Sci. USA Vol. 96, pp. 3365–3371, March 1999 Colloquium Paper This paper was presented at the National Academy of Sciences colloquium ‘‘Geology, Mineralogy, and Human Welfare,’’ held November 8–9, 1998 at the Arnold and Mabel Beckman Center in Irvine, CA. Contaminant bioavailability in soils, sediments, and aquatic environments SAMUEL J. TRAINA* AND VALE´RIE LAPERCHE School of Natural Resources, The Ohio State University, 2021 Coffey Road, Columbus, OH 43210 ABSTRACT The aqueous concentrations of heavy metals ion, or a molecule typically is controlled by its chemical and in soils, sediments, and aquatic environments frequently are physical state, or speciation (2–10). Thus, regulations based on controlled by the dissolution and precipitation of discrete absolute concentration may be convenient, but their scientific mineral phases. Contaminant uptake by organisms as well as validity may be in question. contaminant transport in natural systems typically occurs Knowledge of the link between chemical speciation and through the solution phase. Thus, the thermodynamic solu- bioavailability is not new, nor did it originate with concerns of bility of contaminant-containing minerals in these environ- contaminant toxicity or environmental pollution. The fields of ments can directly influence the chemical reactivity, trans- soil chemistry and soil fertility were, in part, created by the port, and ecotoxicity of their constituent ions. In many cases, recognition that total soil concentration is a poor predictor of Pb-contaminated soils and sediments contain the minerals the bioavailability of essential nutrients required for plant anglesite (PbSO4), cerussite (PbCO3), and various lead oxides growth and food production. This recognition has led to (e.g., litharge, PbO) as well as Pb21 adsorbed to Fe and Mn extensive research on the identity and form of nutrient ele- (hydr)oxides. -
Download PDF About Minerals Sorted by Mineral Group
MINERALS SORTED BY MINERAL GROUP Most minerals are chemically classified as native elements, sulfides, sulfates, oxides, silicates, carbonates, phosphates, halides, nitrates, tungstates, molybdates, arsenates, or vanadates. More information on and photographs of these minerals in Kentucky is available in the book “Rocks and Minerals of Kentucky” (Anderson, 1994). NATIVE ELEMENTS (DIAMOND, SULFUR, GOLD) Native elements are minerals composed of only one element, such as copper, sulfur, gold, silver, and diamond. They are not common in Kentucky, but are mentioned because of their appeal to collectors. DIAMOND Crystal system: isometric. Cleavage: perfect octahedral. Color: colorless, pale shades of yellow, orange, or blue. Hardness: 10. Specific gravity: 3.5. Uses: jewelry, saws, polishing equipment. Diamond, the hardest of any naturally formed mineral, is also highly refractive, causing light to be split into a spectrum of colors commonly called play of colors. Because of its high specific gravity, it is easily concentrated in alluvial gravels, where it can be mined. This is one of the main mining methods used in South Africa, where most of the world's diamonds originate. The source rock of diamonds is the igneous rock kimberlite, also referred to as diamond pipe. A nongem variety of diamond is called bort. Kentucky has kimberlites in Elliott County in eastern Kentucky and Crittenden and Livingston Counties in western Kentucky, but no diamonds have ever been discovered in or authenticated from these rocks. A diamond was found in Adair County, but it was determined to have been brought in from somewhere else. SULFUR Crystal system: orthorhombic. Fracture: uneven. Color: yellow. Hardness 1 to 2. -
Lanarkite Pb2o(SO4) C 2001-2005 Mineral Data Publishing, Version 1
Lanarkite Pb2O(SO4) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals, to 5 cm, are elongated along [010], showing {001}, {110}, with many {h0l} forms, may form radial aggregates; massive. Twinning: Rare, along the [010] zone. Physical Properties: Cleavage: On {201}, perfect; on {401}, {201}, {010}, imperfect. Tenacity: Flexible in thin laminae. Hardness = 2–2.5 D(meas.) = 6.92 D(calc.) = 7.08 Fluoresces yellow under X-rays and LW UV. Optical Properties: Transparent to translucent. Color: Gray, pale green, pale yellow; colorless in transmitted light. Streak: White. Luster: Adamantine to resinous, pearly on cleavage surfaces. Optical Class: Biaxial (–). Orientation: Y = b; Z ∧ c =30◦. Dispersion: r> v,strong, inclined. α = 1.928(3) β = 2.007(3) γ = 2.036(3) 2V(meas.) = 60(2)◦ Cell Data: Space Group: C2/m (synthetic). a = 13.769(5) b = 5.698(3) c = 7.079(2) β = 115◦56(10)0 Z=4 X-ray Powder Pattern: [Scotland?] (ICDD 18-702). 2.95 (100), 3.33 (80), 2.85 (30), 2.048 (20), 1.841 (20), 2.260 (16), 4.42 (10) Chemistry: (1) (2) SO3 15.37 15.21 PbO 84.63 84.79 Total [100.00] 100.00 (1) Leadhills, Scotland; recalculated to 100% after deduction of ignition loss 0.83% from an original total of 98.66%. (2) Pb2O(SO4). Occurrence: A rare secondary mineral in the oxidized zone of lead sulfide deposits. Association: Cerussite, leadhillite, susannite, hydrocerussite, caledonite. Distribution: In Scotland, large crystals from the Susanna mine, Leadhills, Lanarkshire; at the Meadowfoot smelter, near Wanlockhead, Dumfriesshire, in slag. -
The Vibrational Spectroscopy of Minerals
THE VIBRATIONAL SPECTROSCOPY OF MINERALS WAYDE NEIL MARTENS B. APPL. SCI. (APPL. CHEM.) M.SC. (APPL. SCI.) Inorganic Materials Research Program, School of Physical and Chemical Science, Queensland University of Technology A THESIS SUBMITED FOR THE DEGREE OF DOCTOR OF PHILOSOPHY OF THE QUEENSLAND UNIVERSITY OF TECHNOLOGY 2004 2 Toss another rock on the Raman… 3 KEYWORDS Annabergite Aragonite Arupite Baricite Cerussite Erythrite Hörnesite Infrared Spectroscopy Köttigite Minerals Parasymplesite Raman Spectroscopy Solid Solutions Strontianite Vibrational Spectroscopy Vivianite Witherite 4 ABSTRACT This thesis focuses on the vibrational spectroscopy of the aragonite and vivianite arsenate minerals (erythrite, annabergite and hörnesite), specifically the assignment of the spectra. The infrared and Raman spectra of cerussite have been assigned according to the vibrational symmetry species. The assignment of satellite bands to 18O isotopes has been discussed with respect to the use of these bands to the quantification of the isotopes. Overtone and combination bands have been assigned according to symmetry species and their corresponding fundamental vibrations. The vibrational spectra of cerussite have been compared with other aragonite group minerals and the differences explained on the basis of differing chemistry and crystal structures of these minerals. The single crystal spectra of natural erythrite has been reported and compared with the synthetic equivalent. The symmetry species of the vibrations have been assigned according to single crystal and factor group considerations. Deuteration experiments have allowed the assignment of water vibrational frequencies to discrete water molecules in the crystal structure. Differences in the spectra of other vivianite arsenates, namely annabergite and hörnesite, have been explained by consideration of their differing chemistry and crystal structures. -
Topotaxy Relationships in the Transformation Phosgenite-Cerussite
Topotaxy relationships in the transformation phosgenite-cerussite a, a C.M. Pina * , L. Femandez-Diaz , M. Prieto b a Departamento de Cristalografiay Mineralogia, Universidad Complutense de Madrid, £-28040 Madrid, Spain b Departamento de Geologia, Uniuersidad de Oviedo (JUQOM), £-33005 Oviedo, Spain Abstract The crystallization of phosgenite (Pb2CI2C03) and cerussite (PbC03) has been carried out by counter diffusion in a silica hydrogel at 25°C. The crystallization of both phases is strongly controlled by the pH of the medium. Under certain conditions the physicochemical evolution of the system determines that phosgenite crystals become unstable and transform into cerussite. The transformation is structurally controlled and provides an interesting example of topotaxy. The orientational relationships are (I JO)ph 11 [001 ter. ( I JO)ph 11 [IOO]cer' and (OOi)Ph 11 (0I0)cer' In this paper. a study of the topotactic transformation and the crystal morphology is worked out. The topotactic relationships are interpreted on the ground of geometrical and structural considerations. 1. Introduction for some polymorphic transformations. Crystal growth experiments in a porous silica gel transport Phosgenite (Pb2CI2C03) and cerussite (PbC03) medium allows us to reproduce the conditions of are two secondary lead minerals that form in super phosgenite and cerussite crystallization in nature and genic deposits as an alteration product of galene and monitor the transformation process. The develop anglesite. The crystallization of phosgenite and ment of the transformation is strongly controlled by cerussite is strongly controlled by the pH of the the structural elements that both phases have in medium. Phosgenite crystallizes at pH values around common, providing an interesting example of 5, while cerussite nucleation requires a basic pH [I]. -
6 Lead and Zinc
Energy and Environmental Profile of the U.S. Mining Industry 6 Lead and Zinc Lead and zinc ores are usually found together with gold and silver. A lead-zinc ore may also contain lead sulfide, zinc sulfide, iron sulfide, iron carbonate, and quartz. When zinc and lead sulfides are present in profitable amounts they are regarded as ore minerals. The remaining rock and minerals are called gangue. Forms of Lead and Zinc Ore The two principal minerals containing lead and zinc are galena and sphalerite. These two minerals are frequently found together along with other sulfide minerals, but one or the other may be predominant. Galena may contain small amounts of impurities including the precious metal silver, usually in the form of a sulfide. When silver is present in sufficient quantities, galena is regarded as a silver ore and called argentiferous galena. Sphalerite is zinc sulfide, but may contain iron. Black sphalerite may contain as much as 18 percent iron. Lead Ore The lead produced from lead ore is a soft, flexible and ductile metal. It is bluish-white, very dense, and has a low melting point. Lead is found in veins and masses in limestone and dolomite. It is also found with deposits of other metals, such as zinc, silver, copper, and gold. Lead is essentially a co-product of zinc mining or a byproduct of copper and/or gold and silver mining. Complex ores are also the source of byproduct metals such as bismuth, antimony, silver, copper, and gold. The most common lead-ore mineral is galena, or lead sulfide (PbS).