Sodium Chlorate in Organic Production
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Sodium Chlorate Process Liquor De-Chromed SN
SAFETY DATA SHEET This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. 1. Identification Product identifier Sodium Chlorate Process Liquor De-chromed SN Other means of identification De-chromed blend of Crystallizer Feed Liquor and Mother Liquor, NaClO3 Recommended use For internal transfer between ERCO Worldwide sodium chlorate manufacturing facilities for process purposes Recommended restrictions None known Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name ERCO Worldwide Address 335 Carlingview Drive Unit 1 Etobicoke, M9W 5G8 Canada Telephone Information #: (416) 239-7111 (M- F: 8:00 am – 5:00pm EST) Website http://www.ercoworldwide.com E-mail [email protected] Emergency phone number Canada & USA: 1-800-424-9300 (CHEMTREC) Supplier Refer to Manufacturer 2. Hazard(s) Identification Physical hazards Oxidizing liquids Category 2 Health hazards Acute toxicity, oral Category 4 Environmental hazards Not currently regulated by OSHA, refer to Section 12 for additional information. OSHA defined hazards This mixture does not meet the classification criteria according to OSHA HazCom 2012. Label elements Signal word Danger Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Page 1 of 15 Issue Date: 11/18/2020 Sodium Chlorate Process Liquor De-chromed SN Precautionary statement Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from clothing and other combustible materials. Wear protective gloves, protective clothing, eye protection, face protection. Response IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. In case of fire: Use water to extinguish. -
Guidelines for Drinking-Water Quality, Fourth Edition
12. CHEMICAL FACT SHEETS Assessment date 1993 Principal reference WHO (2003) Chlorine in drinking-water In humans and experimental animals exposed to chlorine in drinking-water, no specific adverse treatment-related effects have been observed. IARC has classified h ypochlorite in Group 3 (not classifiable as to its carcinogenicity to humans). Chlorite and chlorate Chlorite and chlorate are disinfection by-products resulting from the use of chlorine dioxide as a disinfectant and for odour and taste control in water. Chlorine dioxide is also used as a bleaching agent for cellulose, paper pulp, flour and oils. Sodium chlorite and sodium chlorate are both used in the production of chlorine dioxide as well as for other commercial purposes. Chlorine dioxide rapidly decomposes into chlorite, chlorate and chloride ions in treated water, chlorite being the predominant species; this reaction is favoured by alkaline conditions. The major route of environmental ex- posure to chlorine dioxide, sodium chlorite and sodium chlorate is through drinking- water. Chlorate is also formed in sodium hypochlorite solution that is stored for long periods, particularly at high ambient temperatures. Provisional guideline values Chlorite: 0.7 mg/l (700 µg/l) Chlorate: 0.7 mg/l (700 µg/l) The guideline values for chlorite and chlorate are designated as provisional because use of chlorine dioxide as a disinfectant may result in the chlorite and chlorate guideline values being exceeded, and difficulties in meeting the guideline value must never be a reason for compromising adequate disinfection. Occurrence Levels of chlorite in water reported in one study ranged from 3.2 to 7.0 mg/l; however, the combined levels will not exceed the dose of chlorine dioxide applied. -
Safety Data Sheet
SAFETY DATA SHEET According to JIS Z 7253:2019 Revision Date 18-Aug-2020 Version 3.02 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product name Sodium Metaborate Tetrahydrate Product code 198-02395 Manufacturer FUJIFILM Wako Pure Chemical Corporation 1-2 Doshomachi 3-Chome Chuo-ku, Osaka 540-8605, Japan Phone: +81-6-6203-3741 Fax: +81-6-6203-5964 Supplier FUJIFILM Wako Pure Chemical Corporation 1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan Phone: +81-6-6203-3741 Fax: +81-6-6203-2029 Emergency telephone number +81-6-6203-3741 / +81-3-3270-8571 Recommended uses and For research purposes restrictions on use Section 2: HAZARDS IDENTIFICATION GHS classification Classification of the substance or mixture Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity (single exposure) Category 3 Category 3 Respiratory tract irritation Pictograms Signal word Warning Hazard statements H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation Precautionary statements-(Prevention) • Wash face, hands and any exposed skin thoroughly after handling • Wear protective gloves/protective clothing/eye protection/face protection • Avoid breathing dust/fume/gas/mist/vapors/spray • Use only outdoors or in a well-ventilated area Precautionary statements-(Response) • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. • If eye irritation persists: Get medical advice/attention. • IF ON SKIN: Wash with plenty of soap and water • If skin irritation occurs: Get medical advice/attention • Take off contaminated clothing and wash before reuse __________________________________________________________________________________________ Page 1 / 6 W01W0119-0239 JGHEEN Sodium Metaborate Tetrahydrate Revision Date 18-Aug-2020 __________________________________________________________________________________________ • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. -
The Response of Aircraft Oxygen Generators Exposed to Elevated N Temperatures
a a c i The Response of Aircraft Oxygen Generators Exposed to Elevated n Temperatures h c e t e David Blake t o n April 2003 l DOT/FAA/AR-TN03/35 a c This document is available to the public through the National Technical Information Service (NTIS), Springfield, Virginia 22161. i n h c e U.S. Department of Transportation t Federal Aviation Administration e te technical note technic t o o NOTICE This document is disseminated under the sponsorship of the U.S. Department of Transportation in the interest of information exchange. The United States Government assumes no liability for the contents or use thereof. The United States Government does not endorse products or manufacturers. Trade or manufacturer's names appear herein solely because they are considered essential to the objective of this report. This document does not constitute FAA certification policy. Consult your local FAA aircraft certification office as to its use. This report is available at the Federal Aviation Administration William J. Hughes Technical Center’s Full-Text Technical Reports page: actlibrary.tc.faa.gov in Adobe Acrobat portable document format (PDF). Technical Report Documentation Page 1. Report No. 2. Government Accession No. 3. Recipient's Catalog No. DOT/FAA/AR-TN03/35 4. Title and Subtitle 5. Report Date THE RESPONSE OF AIRCRAFT OXYGEN GENERATORS EXPOSED TO April 2003 ELEVATED TEMPERATURES 6. Performing Organization Code 7. Author(s) 8. Performing Organization Report No. David Blake DOT/FAA/AR-TN03/35 9. Performing Organization Name and Address 10. Work Unit No. (TRAIS) Federal Aviation Administration William J. -
Toxic Action of Aqueous Sodium Chlorate on Nitella1
TOXIC ACTION OF AQUEOUS SODIUM CHLORATE ON NITELLA1 By H. R. OFFORD, Agent, and R. P. D'URBAL, Assistant Chemist, Division of Blister Rust Control, Bureau of Plant Industry, United States Department of Agriculture INTRODUCTION The experiments herein reported on the toxic action of aqueous sodium chlorate on Nitella were conducted as part of an investigative program ^ to devise economic methods for the chemical suppression of wild currant and gooseberry plants. These plants, members of the family Grossulariaceae and commonly referred to as Ribes, are the alternate hosts of the blister-rust disease of white pines, which is caused by the fungus Cronartium ribicola Fisch. Blister rust may be effectively controlled by hand eradication of currants and goose- berries within 900 feet of the white-pine stand delimited for protection, though in the case of certain highly susceptible species of Ribes this distance necessarily must be increased. Hand pulling is an effective eradication practice, but a cheaper method, such as chemical treat- ment, is needed where the plants occur in great profusion. High toxicity, low cost, and adaptability to field use are important requi- sites of a chemical for general use in plant-eradication work. In field experiments more than a hundred chemicals were tested as plant poisons during the summers of 1925, 1926, and 1927 (P).^ The results of these experiments showed that sodium chlorate is by far the best killing agent and in addition lends itself suitably to general field application. Sodium chlorate, fully effective on Ribes petiolare Dougk, is but moderately successful on other Ribes. Field experiments performed during three successive years established this difference in susceptibility very definitely and suggested that, in the mechanism of killing, specific reactions between the chlorate and the several Ribes species are involved. -
Dangers of Unspent Aircraft Oxygen Generators
Safety Advisory Dangers of Unspent Aircraft Oxygen Generators U.S. Chemical Safety and Hazard Investigation Board No. 2007-I-NC-01-SA | June 2007 Key Message This Safety Advisory is issued to alert aircraft maintenance and hazardous waste facility personnel to the hazards associated with the transportation and storage of expired, unspent aircraft chemical oxygen generators. Aircraft oxygen generators are dangerous devices that, if mishandled, can cause fires, property damage, and personal injury. Aircraft oxygen generators that have exceeded their service life should be expended before shipping by any transport mode. Introduction On October 5, 2006, at about 10 pm, a fire occurred at the EQ Industrial Services (EQ) hazardous waste treatment, storage, and disposal facility in Apex, North Carolina. The fire resulted in the evacuation of thousands of Apex residents and the complete destruction of the hazardous waste building at EQ’s Apex facility. The U.S. Chemical Safety and Hazard Investigation Board (CSB) investigation concluded that aircraft oxygen generators most likely contributed to the rapid spread of the fire to other areas in the EQ facility. The CSB issues this Safety Advisory to focus attention on the need for aircraft maintenance facilities to expend chemical oxygen generators that have exceeded their service life, and for hazardous waste facility operators and shippers to exercise due care when handling unspent chemical oxygen generators. Incident Description At about 10 pm on October 5, 2006, a citizen driving past the EQ facility in Apex, North Carolina, called 911 when he saw a plume of smoke and smelled a strong chlorine odor coming from the facility. -
Experiments with Sodium Chlorate and Other Chemicals As Herbicides for Field Bindweed»
EXPERIMENTS WITH SODIUM CHLORATE AND OTHER CHEMICALS AS HERBICIDES FOR FIELD BINDWEED» By W. L. LATSHAW, Associate Professor of Chemistry^ and J. W. ZAHNLEY, Associate Professor of Farm Crops, Kansas State Agricultural College ^ INTRODUCTION Field bindweed (Convolvulus arvensis) is regarded as the most noxious weed in several of the Western States and is widely distrib- uted in Kansas. In some cases infested farms are reduced in value more than one-half and loan companies often refuse to accept them as security. Considering the seriousness of the situation and the fact that methods now in use (5)^ in Kansas are not wholly satisfactory, further experimental work seemed desirable. The use of chemicals as herbicidal agents is not new, but so far as is known to the authors sodium chlorate had not been tried in any experiments with bind- weed previous to those herein reported. REVIEW OF LITERATURE A considerable amount of work has been done by various investi- gators relating to the eradication of bindweed. Intensive cultivation has proved effective in several States as shown by the following workers: Call and Getty (5) in Kansas; Barnum (3) and Bioletti (4) in California; Cox (6) of the United States Department of Agricul- ture; Stewart and Pittman (13) in Utah; and in Idaho (10), as reported by the direptor of the Idaho Experiment Station. Chemicals have been used more or less generally. Krauss (12) and Wilcox (15) found sodium arsenite effective. Gray (7) also found it effective within the fog belt of California, but not nearly so successful (8) in the less humid section of the State. -
Physicochemical Properties of Sodium Metaborate
ELECTROCHEMICAL RECYCLING OF SODIUM BOROHYDRTDE FOR HYDROGEN STORAGE: PHYSICOCHEMICAL PROPERTIES OF SODIUM METABORATE SOLUTIONS. by Caroline R. Cloutier B. A. Sc., The University of Ottawa, 1999 A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF APPLIED SCIENCE m THE FACULTY OF GRADUATE STUDIES (Materials Engineering) THE UNIVERSITY OF BRITISH COLUMBIA July 2006 © Caroline R. Cloutier, 2006 ABSTRACT The large-scale adoption of a "hydrogen economy" is hindered by the lack of a practical storage method and concerns associated with its safe handling. Chemical hydrides have the potential to address these concerns. Sodium borohydride (sodium tetrahydroborate, NaBH4), is the most attractive chemical hydride for H2 generation and storage in automotive fuel cell applications but recycling from sodium metaborate (NaB02) is difficult and costly. An electrochemical regeneration process could represent an economically feasible and environmentally friendly solution. In this thesis, the properties of diluted NaB02 aqueous solutions and concentrated NaB02 alkaline aqueous solutions that are necessary for the development of electrochemical recycling methods have been studied. The conductivity and viscosity of dilute aqueous solutions of NaB02 were measured as a function of concentration at 25°C. Also, the solubility, pH, density, conductivity and viscosity of the filtrate of saturated aqueous NaB02 solutions containing varying weight percentages (1, 2, 3, 5, 7.5 and 10 wt%) of alkali hydroxides (NaOH, KOH and LiOH) were evaluated at 25°C. Selected experiments were repeated at 50 and 75°C to investigate the effect of temperature on the NaB02 alkaline aqueous solution solubility and physicochemical properties. Preliminary experiments to investigate the effect of glycine (C2H5N02), the smallest amino acid, on the solubility and physicochemical properties of NaB02 alkaline aqueous solutions were conducted at 25°C. -
Buffer Replacement Considerations
Buffer Replacement Considerations John Butler NEI Buffer Replacement Replacement of buffers considered as one means to minimize precipitant impact of strainer headloss Buffer Candidates 1. Liquid Systems- a) Sodium Hydroxide (NaOH) b) NaOH at reduced concentration (2.5% vice current 10%) c) Sodium Metaborate (NaMB) 2. Granular Systems- a) Trisodium Phosphate crystalline b) Sodium Tetraborate (NaTB) crystalline Lead Replacement Strategies Three primary replacement strategies – Replace TSP with NaTB – Replace NaOH with NaTB – Replace NaOH with TSP All three buffer materials are currently installed and in use at PWRs Role of Buffers in Design Bases Radiological Dose Control – pH > 7 Inhibition of Stress Corrosion Cracking of Austenitic stainless steel – Long term environmental control – pH > 7 Functional Considerations System Design Radiological Consequences Equipment Environmental Qualification Hydrogen Generation Corrosion Control Plant Operation Plant Documentation Evaluation of Alternatives WCAP-16596-NP Identify buffer alternative and TSP, NaOH, NaTB delivery method Liquid, granular Evaluate impact Chemical Precipitant Model on chemical precipitant Containment Inventory formation pH adjustment to > 7 delivery and distribution Design/Functional corrosion inhibition Evaluation boric acid solubility environmental qualification profile Hydrogen generation Analyses to Support Buffer Replacement LAR Buffer provides pH adjustment to > 7 Comparable or better delivery and distribution Comparable or better corrosion inhibition characteristics -
Deracemization of Sodium Chlorate with Or Without the Influence of Sodium Dithionate Manon Schindler
Deracemization of sodium chlorate with or without the influence of sodium dithionate Manon Schindler To cite this version: Manon Schindler. Deracemization of sodium chlorate with or without the influence of sodium dithionate. Cristallography. Normandie Université, 2020. English. NNT : 2020NORMR004. tel- 02521046v2 HAL Id: tel-02521046 https://tel.archives-ouvertes.fr/tel-02521046v2 Submitted on 15 May 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. THÈSE Pour obtenir le diplôme de doctorat Spécialité Physique Préparée au sein de l’Université de Rouen Normandie Deracémisation du chlorate de sodium avec et sans l’influence du dithionate de sodium Présentée et soutenue par Manon SCHINDLER Thèse soutenue publiquement le 13 mars 2020 devant le jury composé de Mme. Elizabeth HILLARD Dr. Hab. Université de Bordeaux Rapporteur M. Elias VLIEG Pr. Université Radboud de Nimègue Rapporteur Mme. Sylvie MALO Pr. Université de Caen Normandie Présidente M. Woo Sik KIM Pr. Université Kyung Hee de Séoul Examinateur M. Gérard COQUEREL Pr. Université de Rouen Normandie Directeur de thèse Thèse dirigée par Gérard COQUEREL, professeur des universités au laboratoire Sciences et Méthodes Séparatives (EA3233 SMS) THÈSE Pour obtenir le diplôme de doctorat Spécialité Physique Préparée au sein de l’Université de Rouen Normandie Deracemization of sodium chlorate with or without the influence of sodium dithionate Présentée et soutenue par Manon SCHINDLER Thèse soutenue publiquement le 13 mars 2020 devant le jury composé de Mme. -
Sodium Metaborate, Tetrahydrate
SAFETY DATA SHEET Preparation Date: 3/24/2015 Revision Date: Not Applicable Revision Number: Not Applicable Product identifier Product code: S2605 Product Name: SODIUM METABORATE, TETRAHYDRATE Other means of identification Synonyms: Boric acid, monosodium salt, tetrahydrate CAS #: 10555-76-7 RTECS # ED4640000 (for Sodium metaborate CAS no. 7775-19-1) CI#: Not available Recommended use of the chemical and restrictions on use Recommended use: Fungicide. Insecticide. Uses advised against No information available Supplier: Spectrum Chemicals and Laboratory Products, Inc. 14422 South San Pedro St. Gardena, CA 90248 (310) 516-8000 Order Online At: https://www.spectrumchemical.com Emergency telephone number Chemtrec 1-800-424-9300 Contact Person: Martin LaBenz (West Coast) Contact Person: Ibad Tirmiz (East Coast) 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Reproductive toxicity Category 2 Label elements Product code: S2605 Product name: SODIUM 1 / 11 METABORATE, TETRAHYDRATE Warning Hazard statements Causes skin irritation Causes serious eye irritation Suspected of damaging fertility or the unborn child Hazards not otherwise classified (HNOC) Not Applicable Other hazards Not available Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Wear protective gloves Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see .? on this label) IF IN EYES: Rinse cautiously with water for several minutes. -
A Recycling Hydrogen Supply System of Nabh4 Based on a Facile Regeneration Process: a Review
inorganics Review A Recycling Hydrogen Supply System of NaBH4 Based on a Facile Regeneration Process: A Review Liuzhang Ouyang 1,2,3, Hao Zhong 1,2, Hai-Wen Li 4,* ID and Min Zhu 1,2,* 1 School of Materials Science and Engineering, Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, South China University of Technology, Guangzhou 510641, China; [email protected] (L.O.); [email protected] (H.Z.) 2 China-Australia Joint Laboratory for Energy & Environmental Materials, South China University of Technology, Guangzhou 510641, China 3 Key Laboratory for Fuel Cell Technology in Guangdong Province, Guangzhou 510641, China 4 Kyushu University Platform of Inter/Transdisciplinary Energy Research, International Research Center for Hydrogen Energy and International Institute for Carbon-Neutral Energy, Kyushu University, Fukuoka 819-0395, Japan * Correspondence: [email protected] (H.-W.L.); [email protected] (M.Z.) Received: 24 October 2017; Accepted: 5 January 2018; Published: 6 January 2018 Abstract: NaBH4 hydrolysis can generate pure hydrogen on demand at room temperature, but suffers from the difficult regeneration for practical application. In this work, we overview the state-of-the-art progress on the regeneration of NaBH4 from anhydrous or hydrated NaBO2 that is a byproduct of NaBH4 hydrolysis. The anhydrous NaBO2 can be regenerated effectively by MgH2, whereas the production of MgH2 from Mg requires high temperature to overcome the sluggish hydrogenation kinetics. Compared to that of anhydrous NaBO2, using the direct hydrolysis byproduct of hydrated NaBO2 as the starting material for regeneration exhibits significant advantages, i.e., omission of the high-temperature drying process to produce anhydrous NaBO2 and the water included can react with chemicals like Mg or Mg2Si to provide hydrogen.