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Safety Data Sheet SAFETY DATA SHEET Creation Date 14-Nov-2018 Revision Date 27-Dec-2020 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Antimony(III) chloride, Puratronic®, 99.999% (metals basis) Cat No. : 40372 CAS-No 10025-91-9 EC-No. 233-047-2 Molecular Formula SbCl3 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met Health hazards ______________________________________________________________________________________________ ALFAA40372 Page 1 / 11 SAFETY DATA SHEET Antimony(III) chloride, Puratronic®, 99.999% (metals basis) Revision Date 27-Dec-2020 ______________________________________________________________________________________________ Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Environmental hazards Chronic aquatic toxicity Category 2 (H411) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H314 - Causes severe skin burns and eye damage H411 - Toxic to aquatic life with long lasting effects Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower 2.3. Other hazards Decomposes in contact with water In accordance with Annex XIII of the REACH Regulation, inorganic substances do not require assessment SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Antimony trichloride 10025-91-9 EEC No. 233-047-2 <=100 Skin Corr. 1B (H314) Aquatic Chronic 2 (H411) Component Specific concentration limits M-Factor Component notes (SCL's) Antimony trichloride STOT SE 3 :: C>=5% - Note 1 Note Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation (Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of the metallic element ______________________________________________________________________________________________ ALFAA40372 Page 2 / 11 SAFETY DATA SHEET Antimony(III) chloride, Puratronic®, 99.999% (metals basis) Revision Date 27-Dec-2020 ______________________________________________________________________________________________ calculated with reference to the total weight of the mixture Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Ingestion Clean mouth with water and drink afterwards plenty of water. Inhalation Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors. Hazardous Combustion Products Hydrogen chloride, Antimony oxide. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ______________________________________________________________________________________________ ALFAA40372 Page 3 / 11 SAFETY DATA SHEET Antimony(III) chloride, Puratronic®, 99.999% (metals basis) Revision Date 27-Dec-2020 ______________________________________________________________________________________________ SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Do not allow material to contaminate ground water system. 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Ensure adequate ventilation. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Class 8B (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. Component The United Kingdom European Union Ireland Antimony trichloride STEL: 1.5 mg/m3 15 min TWA: 0.5 mg/m3 8 hr Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies ______________________________________________________________________________________________ ALFAA40372 Page 4 / 11 SAFETY DATA SHEET Antimony(III) chloride, Puratronic®, 99.999% (metals basis) Revision Date 27-Dec-2020 ______________________________________________________________________________________________ Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS 91 Metals and metalloids in workplace air by X-ray fluorescence spectrometry MDHS 99 Metals in air by ICP-AES Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Skin and body protection Long sleeved clothing Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the
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