PRELIMINARY ECONOMIC ASSESSMENT MARIMACA PROJECT ANTOFAGASTA, II REGION, CHILE
NI 43 101 Technical Report.
Prepared by: Robin Kalanchey (P. Eng.), Ausenco Francisco Castillo (Member of Chilean Mining Commission), Ausenco Scott Weston (P. Eng.), Ausenco Luis Oviedo (Member of Chilean Mining Commission), NCL Ingeniería y Construcción Carlos Guzman (FAusIMM), NCL Ingeniería y Construcción Marcelo Jo (Member of Chilean Mining Commission), Jo & Loyola Consultores de Procesos
Prepared for: Marimaca Copper Report Effective Date: 4 August 2020
Important Notice
This report was prepared as National Instrument 43-101 Technical Report for Marimaca Copper Corp (Marimaca Copper) by Ausenco Engineering Canada Inc., Jo & Loyola Consultores de Procesos and NCL Ingeniería y Construcción (collectively, the “Report Authors”). The quality of information, conclusions, and estimates contained herein is consistent with the level of effort involved in Report Authors’ services, based on i) information available at the time of preparation, ii) data supplied by outside sources, and iii) the assumptions, conditions, and qualifications set forth in this report. This report is intended for use by Marimaca Copper subject to terms and conditions of its contract with each of the Report Authors.
Except for the purposed legislated under Canadian provincial and territorial securities law, any other uses of this report by any third party is at that party’s sole risk.
Table of Contents
1 Summary ...... 1-1 1.1 Introduction ...... 1-1 1.2 Terms of Reference ...... 1-1 1.3 Project Setting ...... 1-1 1.4 Mineral Tenure, Surface Rights, Water Rights, Royalties and Agreements ...... 1-1 1.5 Geology and Mineralization ...... 1-2 1.6 History ...... 1-3 1.7 Drilling and Sampling ...... 1-3 1.8 Data Verification ...... 1-6 1.9 Metallurgical Testwork ...... 1-6 1.9.1 Crush Heap Leach ...... 1-6 1.9.2 ROM Leach ...... 1-7 1.10 Mineral Resource Estimation ...... 1-7 1.11 Mineral Resource Statement ...... 1-8 1.12 Mining Methods ...... 1-11 1.13 Recovery Methods ...... 1-13 1.14 Project Infrastructure...... 1-14 1.15 Environmental, Permitting and Social Considerations ...... 1-15 1.15.1 Environmental Considerations ...... 1-15 1.15.2 Closure and Reclamation Planning ...... 1-16 1.15.3 Social Considerations ...... 1-16 1.16 Markets and Contracts ...... 1-16 1.17 Capital Cost Estimates ...... 1-16 1.18 Operating Cost Estimates ...... 1-17 1.19 Economic Analysis ...... 1-18 1.19.1 Cautionary Statement ...... 1-18 1.19.2 Methodology Used ...... 1-19 1.19.3 Results ...... 1-20 1.19.4 Sensitivity Analysis ...... 1-20 1.20 Risks and Opportunities ...... 1-21 1.21 Interpretation and Conclusions ...... 1-22 1.22 Recommendations ...... 1-22 1.22.1 Geology ...... 1-22 1.22.2 Mining...... 1-22 1.22.3 Metallurgy ...... 1-23 1.22.4 Environmental ...... 1-23 2 Introduction...... 2-24 2.1 Introduction ...... 2-24 2.2 Terms of Reference ...... 2-24 2.3 Qualified Persons ...... 2-24 2.4 Site Visits and Scope of Personal Inspection ...... 2-25 2.5 Effective Dates ...... 2-26 2.6 Information Sources and References ...... 2-26 2.7 Previous Technical Reports ...... 2-26 3 Reliance on Other Experts ...... 3-27 3.1 Introduction ...... 3-27 3.2 Mineral Tenure ...... 3-27 3.3 Markets ...... 3-27 3.4 Taxation ...... 3-27 4 Property Description and Location ...... 4-28 4.1 Introduction ...... 4-28 4.2 Property and Title in Chile ...... 4-28 4.2.1 Mineral Tenure ...... 4-28
4.2.2 Mining Tax ...... 4-28 4.2.3 Surface Rights ...... 4-29 4.2.4 Rights of Way ...... 4-30 4.2.5 Water Rights ...... 4-30 4.3 Ownership ...... 4-30 4.4 Agreements and Options ...... 4-30 4.4.1 Newco Marimaca ...... 4-30 4.4.2 Inversiones Creciente Limitada ...... 4-31 4.4.3 Capax SA ...... 4-32 4.4.4 Compañía Minera Naguayán S.C.M...... 4-32 4.4.5 Proyecta S.A. and Sociedad Contractual Minera Proyecta ...... 4-33 4.4.6 Rayrock Antofagasta S.A.C. and Compañía Minera Milpo S.A.A ...... 4-33 4.5 Mineral Tenure ...... 4-33 4.6 Surface Rights ...... 4-34 4.7 Water Rights ...... 4-39 4.8 Royalties...... 4-39 4.8.1 Newco Marimaca ...... 4-39 4.8.2 Inversiones Creciente ...... 4-39 4.8.3 Capax ...... 4-39 4.8.4 Minera Naguayán ...... 4-39 4.8.5 Proyecta S.A. and Sociedad Contractual Minera Proyecta ...... 4-40 4.8.6 Rayrock ...... 4-40 4.9 Permitting Considerations ...... 4-40 4.10 Environmental Considerations ...... 4-40 4.11 Social Licence Considerations ...... 4-40 4.12 Comments on Section 4 ...... 4-40 5 Accessibility, Climate, Local Resources, Infrastructure and Physiography ...... 5-42 5.1 Accessibility ...... 5-42 5.2 Local Resources and Infrastructure ...... 5-42 5.3 Climate ...... 5-43 5.4 Physiography ...... 5-43 5.4.1 Comments on Section 5 ...... 5-44 6 History ...... 6-45 6.1 Project History ...... 6-45 6.2 Production ...... 6-45 7 Geological Setting and Mineralization ...... 7-46 7.1 Regional Geology ...... 7-46 7.2 Project Geology ...... 7-48 7.3 Deposit Description ...... 7-49 7.3.1 Lithologies ...... 7-49 7.3.2 Structure ...... 7-49 7.3.3 Alteration ...... 7-54 7.3.4 Mineralization ...... 7-55 7.4 Comments on Section 7 ...... 7-59 8 Deposit Types ...... 8-61 8.1 Overview ...... 8-61 8.2 Comments on Section 8 ...... 8-61 9 Exploration ...... 9-62 9.1 Surveying, Imagery and Topographic Base ...... 9-62 9.2 Geological Mapping ...... 9-63 9.3 Geochemical Sampling ...... 9-64 9.4 Geophysical Surveys ...... 9-66 9.5 Comments on Section 9 ...... 9-68 10 Drilling ...... 10-69
10.1 Introduction ...... 10-69 10.2 Drill Methods...... 10-69 10.3 Logging Procedures ...... 10-69 10.4 Recovery ...... 10-69 10.5 Collar Surveys ...... 10-69 10.6 Down Hole Surveys ...... 10-72 10.7 Sample Length/True Thickness ...... 10-72 10.8 Comments on Section 10 ...... 10-72 11 Sample Preparation, Analyses and Security ...... 11-73 11.1 Sampling Methods ...... 11-73 11.1.1 Geochemical Sampling ...... 11-73 11.1.2 Reverse Circulation ...... 11-73 11.1.3 Core Sampling ...... 11-73 11.2 Specific Gravity Determinations ...... 11-75 11.3 Analytical and Test Laboratories ...... 11-76 11.4 Sample Preparation and Analysis ...... 11-76 11.5 Quality Assurance and Quality Control ...... 11-77 11.5.1 Introduction ...... 11-77 11.5.2 Check Sample Analysis ...... 11-77 11.5.3 Standard Reference Material Analysis...... 11-79 11.5.4 Duplicate Sample Analysis ...... 11-80 11.5.5 Blank Sample Analysis ...... 11-81 11.6 Analysis of Core vs RC Holes (twin) ...... 11-81 11.7 Databases ...... 11-83 11.8 Sample Security...... 11-84 11.9 Comments on Section 11 ...... 11-84 12 Data Verification ...... 12-86 12.1 Internal Data Verification ...... 12-86 12.2 Data Verifications by NCL ...... 12-86 12.3 Comments on Section 12 ...... 12-86 13 Mineral Processing and Metallurgical Testing ...... 13-87 13.1 Metallurgical Testing ...... 13-87 13.1.1 Geomet I & II ...... 13-87 13.1.2 Geomet III ...... 13-96 13.2 Current and Future Tests ...... 13-98 13.2.1 Geomet IV ...... 13-98 13.2.2 Metallurgical Variability Analysis Plan ...... 13-101 13.2.3 Metallurgical Parameters Optimization ...... 13-101 13.3 Industrial Metallurgical Models ...... 13-101 13.3.1 Copper Recovery ...... 13-101 13.3.2 Acid Consumption ...... 13-106 13.5 Metallurgical Parameters ...... 13-125 13.5.1 Agglomeration ...... 13-125 13.5.2 Crushing Size ...... 13-126 13.5.3 Heap Height ...... 13-127 13.5.4 Irrigation Rate ...... 13-134 13.5.5 Leaching Cycle ...... 13-135 13.6 Conclusions and Recommendations ...... 13-136 14 Mineral Resource Estimates ...... 14-140 14.1 Introduction ...... 14-140 14.2 Geological Models ...... 14-140 14.3 Database Supporting Mineral Resource Estimate...... 14-140 14.4 Sample Coding ...... 14-140 14.5 Composites ...... 14-144 14.6 Contact Analyses ...... 14-144
14.7 Capping/Outlier Restriction ...... 14-144 14.8 Variography ...... 14-145 14.9 Block Model ...... 14-145 14.10 Density Assignment ...... 14-145 14.11 Estimation/Interpolation Methods ...... 14-145 14.12 Block Model Validation ...... 14-148 14.13 Classification of Mineral Resources...... 14-148 14.14 Reasonable Prospects of Eventual Economic Extraction ...... 14-149 14.15 Mineral Resource Statement ...... 14-151 14.16 Factors That May Affect the Mineral Resource Estimate...... 14-153 14.17 Comments on Section 14 ...... 14-154 15 Mineral Reserve Estimates ...... 15-155 16 Mining Methods ...... 16-156 16.1 Summary ...... 16-156 16.2 Throughput Rate Rationalisation Study ...... 16-156 16.3 Input Parameters ...... 16-156 16.4 Geotechnical Considerations ...... 16-157 16.5 Dilution and Mine Losses ...... 16-157 16.6 Cut-off Grades ...... 16-158 16.7 Pit Designs ...... 16-159 16.7.1 Final Pit ...... 16-159 16.7.2 Mining Phases ...... 16-159 16.8 Production Schedule ...... 16-161 16.9 Waste Rock Storage Facilities ...... 16-165 16.10 ROM Leach and Stockpile ...... 16-165 16.11 Drilling and Blasting ...... 16-166 16.12 Mining Equipment ...... 16-166 16.13 Mine Rotation Schedule ...... 16-169 17 Recovery Methods ...... 17-170 17.1 Process Description ...... 17-170 17.2 Production Plan ...... 17-171 17.3 Dry Area and Material Handling ...... 17-172 17.3.1 Crushing Plant and Stockpile Reclaim ...... 17-172 17.3.2 Agglomeration ...... 17-175 17.3.3 Heap Stacking ...... 17-175 17.3.4 Spent Material Reclaim ...... 17-175 17.4 Wet Area and Solution Management ...... 17-175 17.4.1 Heap Leaching Circuit and Irrigation System ...... 17-175 17.4.2 Solution Management and Operating Ponds ...... 17-176 17.4.3 Event Ponds ...... 17-177 17.5 Solvent Extraction ...... 17-177 17.6 Electrowinning ...... 17-178 17.7 ROM ...... 17-179 17.7.1 ROM Mine Plan ...... 17-179 17.7.2 ROM Leaching ...... 17-179 17.7.3 ROM Operating Pond ...... 17-179 17.8 Water and Power Requirements for Processing ...... 17-179 17.9 Consumables...... 17-180 17.10 Design Criteria ...... 17-180 18 Project Infrastructure ...... 18-185 18.1 On-site Infrastructure ...... 18-185 18.1.1 Existing Infrastructure ...... 18-185 18.1.2 Proposed Infrastructure...... 18-185 18.2 Process Facilities ...... 18-186 18.2.1 Crush Heap Leach Facilities ...... 18-186
18.2.2 ROM Leach Facilities ...... 18-187 18.2.3 Ripios Storage facility ...... 18-187 18.2.4 Waste Rock Storage Facility ...... 18-187 18.3 Power Supply ...... 18-188 18.4 Water Management Infrastructure ...... 18-188 18.5 Off-site Infrastructure ...... 18-189 18.5.1 Existing Infrastructure ...... 18-189 18.5.2 Other Infrastructure in the zone ...... 18-190 18.5.3 Proposed Infrastructure...... 18-190 19 Market Studies and Contracts ...... 19-191 19.1 Metal Prices ...... 19-191 19.2 Sulphuric Acid Price in Chile and Peru ...... 19-191 19.2.1 Sources of Sulphuric Acid Supply in the Vicinity of the Marimaca Project ...... 19-191 20 Environmental Studies, Permitting and Social or Community Impact ...... 20-193 20.1 Sustainability Philosophy ...... 20-193 20.2 Environmental and Socioeconomic Setting...... 20-193 20.2.1 Completed Baseline Studies during DIA ...... 20-193 20.2.2 Baseline Studies Required for next stages ...... 20-196 20.3 Environmental Permitting ...... 20-197 20.3.1 Environmental Approvals ...... 20-197 20.3.2 Environmental Sectorial Permits (PAS) ...... 20-200 20.3.3 Sectorial Permits...... 20-201 20.4 Closure Considerations ...... 20-202 20.4.1 Regulatory Considerations ...... 20-202 20.4.2 Closure Measures ...... 20-203 20.4.3 Closure Costs and Financial Assurance ...... 20-203 20.5 Summary of Potential Environmental and Socio-economic Effects ...... 20-203 21 Capital and Operating Costs ...... 21-205 21.1 Cost Estimation Methodology ...... 21-205 21.1.1 Source Data ...... 21-205 21.1.2 Basic Information ...... 21-206 21.1.3 Estimate Classification ...... 21-206 21.1.4 Market Availability ...... 21-206 21.2 Capital Costs ...... 21-206 21.2.1 Overview ...... 21-206 21.2.2 Initial Capital Cost ...... 21-207 21.2.3 Sustaining Capital Costs ...... 21-209 21.2.4 Mine Capital Cost ...... 21-209 21.3 Operating Cost ...... 21-210 21.3.1 Summary ...... 21-210 21.3.2 Mine Operating Cost ...... 21-211 21.3.3 Processing ...... 21-212 22 Economic Analyses ...... 22-220 22.1 Cautionary Statement ...... 22-220 22.2 Methodology Used ...... 22-221 22.3 Financial Model Parameters...... 22-221 22.4 Taxes ...... 22-221 22.5 Working Capital ...... 22-222 22.6 Royalty ...... 22-222 22.7 Economic Analysis ...... 22-222 22.8 Sensitivity Analysis ...... 22-226 23 Adjacent Properties ...... 23-229 24 Other Relevant Data and Information ...... 24-230
25 Interpretation and Conclusions ...... 25-231 25.1 Introduction ...... 25-231 25.2 Mineral Tenure, Surface Rights, Water Rights, Royalties and Agreements ...... 25-231 25.3 Geology and Mineralization ...... 25-231 25.4 Exploration, Drilling and Analytical Data Collection in Support of Mineral Resource Estimation ...... 25-232 25.5 Metallurgical Test Work...... 25-232 25.6 Mineral Resource Estimates ...... 25-232 25.7 Mine Plan ...... 25-232 25.8 Recovery Plan ...... 25-233 25.9 Infrastructure ...... 25-233 25.10 Environmental, Permitting and Social Considerations ...... 25-233 25.11 Markets and Contracts ...... 25-233 25.12 Capital Cost Estimate ...... 25-234 25.13 Operating Cost Estimate ...... 25-234 25.14 Economic Analysis ...... 25-234 25.15 Sensitivity Analysis ...... 25-234 25.16 Risks and Opportunities ...... 25-234 25.17 Conclusions ...... 25-236 26 Recommendations ...... 26-237 26.1 Introduction ...... 26-237 26.2 Geology ...... 26-237 26.3 Mining...... 26-237 26.4 Metallurgy ...... 26-237 26.5 Environmental ...... 26-238 27 References ...... 27-239
List of Tables Table 1-1: Pit Shell Input Parameters...... 1-8 Table 1-2: Mineral Resource Statement ...... 1-10 Table 1-3: Pit Shell Input Parameters ...... 1-12 Table 1-4: Estimated Capital Cost ...... 1-17 Table 1-5: Operating Costs ...... 1-18 Table 1-6: Copper Price Sensitivity Summary...... 1-20 Table 4-1: Mineral Title Types...... 4-29 Table 7-1: Lithology Summary ...... 7-50 Table 7-2: Structure Summary ...... 7-53 Table 7-3: Mineral Zone Summary ...... 7-57 Table 10-1: Drill Summary Table...... 10-70 Table 11-1: Samples...... 11-76 Table 11-2: Average SG values ...... 11-76 Table 11-3: Control Programs for Each Drilling Campaign...... 11-78 Table 11-4: Check Sample Analysis, MAR 01–16 Campaign ...... 11-79 Table 11-5: Average CuT and CuS, for DDG and RC drilling...... 11-83 Table 13-1: Chemical and Mineralogical Characterization...... 13-88 Table 13-2: Column Height per Sample ...... 13-89
Table 13-3: M1 to M7 Sulphation Tests Results...... 13-90 Table 13-4: Acid Addition in Agglomeration per Sample...... 13-91 Table 13-5:Column Leaching Results Summary...... 13-92 Table 13-6: Geomet I Iso-pH Test...... 13-93 Table 13-7: Iso-pH tests, CuT recovery and acid consumption ...... 13-97 Table 13-8: Total Copper Recoveries used in Block Model and PEA Mineral Feed Plan...... 13-101 Table 13-9: Summary Results CuT Rec. and Acid Consumption Geomet I and II ...... 13-101 Table 13-10: Solubility Block Model by Mineral Sub-Zone (different cut-off grades)...... 13-105 Table 13-11: Summary CuT Rec. and Acid Consumption iso-pH Test Geomet I and III...... 13-111 Table 13-12: Distribution in Mineral Weight (Samples Marimet 1 to 7)...... 13-112 Table 13-13: Head Chemical Characterization Geomet I and II Samples...... 13-113 Table 13-14: Head Chemical Characterization Geomet III Samples...... 13-114 Table 13-15: Geomet III Selected Columns Operating Conditions...... 13-116 Table 13-16: Acid Consumption Breakdown...... 13-121 Table 13-17: Calculation of Equilibrium Chloride Concentration...... 13-123 Table 13-18: Expected Dissolutions Calculations...... 13-124 Table 13-19: Sulphate Balance and Acid Make-up...... 13-124 Table 13-20: Marimaca Industrial Plant Impurities Balance...... 13-125 Table 13-21: Trade-off Analysis...... 13-133 Table 13-22: Modelled Acid Concentration in Drainage at Different Heap Height...... 13-134 Table 13-23: In pit Resources per Mineral Zone...... 13-137 Table 14-1: CuT Raw Sample Data...... 14-142 Table 14-2: CuT Sample Statistics ...... 14-143 Table 14-3: CuS Sample Statistics ...... 14-144 Table 14-4: Grade Caps ...... 14-145 Table 14-5: Correlograms, Adjusted Models CuT According Structural Domain ...... 14-146 Table 14-6: Correlograms, Adjusted Models CuS According Structural Domain...... 14-146 Table 14-7: Density by Mineralization Type ...... 14-147 Table 14-8: Kriging Plan Parameters ...... 14-147 Table 14-9:D85 Direction for Structural Domains ...... 14-147 Table 14-10: Resource Classification ...... 14-150 Table 14-11: Pit Shell Input Parameters ...... 14-150 Table 14-12: Inter Ramp and Overall Slope Angles ...... 14-151 Table 14-13: Mineral Resource Statement ...... 14-152 Table 14-14: Sensitivity of Tonnes, Grades and Contained Metal ...... 14-153 Table 16-1: Input parameters ...... 16-157 Table 16-2: Dilution and Losses (resource model versus mining model) ...... 16-158 Table 16-3: Cut-off Grades Calculation ...... 16-158
Table 16-4: Variable Cut-off Profile Forecast ...... 16-163 Table 16-5: Mine Production Schedule Forecast ...... 16-164 Table 16-6: Plant Feed Forecast ...... 16-164 Table 16-7: Copper Cathodes Production Forecast ...... 16-165 Table 16-8: Peak Fleet Requirements for Pre-Production and Commercial Production ...... 16-168 Table 16-9: Fleet Requirements by Year ...... 16-168 Table 17-1: 2020 PEA Design Criteria ...... 17-181 Table 19-1: Main acid producers in Chile ...... 19-192 Table 20-1: Additional Baseline Studies Requirements for a DIA ...... 20-197 Table 20-2: Preliminary Analysis of Applicability of EIA ...... 20-199 Table 20-3: Environmental Sectorial Permits (PAS) Approved for the Marimaca 1-23 ...... 20-200 Table 20-4: Preliminary Critical Sectorial Permits ...... 20-202 Table 21-1: Capital Cost Summary ...... 21-207 Table 21-2: Initial Capital Estimate Summary Level 1 Major Area ...... 21-207 Table 21-3: Sustaining Capital by Major Area ...... 21-209 Table 21-4: Mine Capital Cost Estimate Summary ($ M) ...... 21-210 Table 21-5: Operating Cost Estimate Summary ...... 21-211 Table 21-6: Mining Operating Cost Estimate Summary ...... 21-212 Table 21-7 Processing Costs ...... 21-213 Table 21-8 Data Sources for Processing Costs ...... 21-214 Table 21-9: Operating Costs - Power ...... 21-215 Table 21-10: Operating Costs - Consumables and Reagents ...... 21-215 Table 21-11: Main crushing and heap leach consumables ...... 21-216 Table 21-12: Reagents ...... 21-216 Table 21-13: Operating Costs - Maintenance ...... 21-217 Table 21-14: Operating Costs - Labour ...... 21-218 Table 21-15: G&A Cost Summary ...... 21-218 Table 21-16: G&A Costs – Contracts ...... 21-219 Table 22-1: Summary of Project Economics ...... 22-223 Table 22-2: Project Cash Flow on an Annualised Basis ...... 22-224 Table 22-3 Sensitivity Summary...... 22-226 Table 22-4: Pre-tax sensitivity ...... 22-227 Table 22-5 Post-tax sensitivity ...... 22-228
List of Figures Figure 1-1: Core Sampling Process ...... 1-5 Figure 1-2: Projected LOM Cash Flows...... 1-20 Figure 2-1: Project Location Plan ...... 2-25
Figure 4-1: Total Mineral Tenure Holdings ...... 4-35 Figure 4-2: Mineral Tenure, Proposed Open Pit Location ...... 4-36 Figure 4-3: Marimaca Project Provisional Easement ...... 4-37 Figure 4-4: Easement Application ...... 4-38 Figure 5-1: Key Regional Infrastructure ...... 5-43 Figure 5-2: Physiography of the General Project Area ...... 5-44 Figure 7-1: Regional Coastal Cordillera Geology ...... 7-47 Figure 7-2: Project Overview (northeast view) ...... 7-48 Figure 7-3: Project Overview (south view) ...... 7-49 Figure 7-4: Sub-Surface Interpreted Geology Plan ...... 7-51 Figure 7-5: Cross-Section NE 100, Showing Litho-Structure (a) and Mineralization (b) ...... 7-52 Figure 7-6: Structural Zones ...... 7-55 Figure 7-7: Sub-Surface Mineralization Map ...... 7-58 Figure 7-8: Cross-Section Showing Mineralization, Section NW 400 ...... 7-59 Figure 7-9: Cross-Section Showing Mineralization, Section NW 650 ...... 7-59 Figure 7-10: Deposit Model Schematic ...... 7-60 Figure 9-1: Examples of Surface Survey Control ...... 9-62 Figure 9-2: Underground Workings ...... 9-63 Figure 9-3: Example Underground Geological Mapping ...... 9-64 Figure 9-4: Surface Road-Cut Channel Chip Sample Location Plan ...... 9-65 Figure 9-5: Underground Channel Chip Sampling Location Plan ...... 9-65 Figure 9-6: Copper Geochemistry ...... 9-66 Figure 9-7: Pole Reduced Ground Magnetic Plan ...... 9-67 Figure 9-8: Cross section with Interpreted Sulphide Zone, Previously Completed Sulphide Drill Results and Vector Inversion Magnetic Anomaly > 0.03 SI ...... 9-68 Figure 10-1: Drill Hole Collar Plan ...... 10-71 Figure 10-2: Example of Drill Hole Survey and BHTV Data ...... 10-72 Figure 11-1: Core Sample Process ...... 11-75 Figure 11-2: Check Sample Regression MAR 01–16 Campaign ...... 11-79 Figure 11-3: Location of Drill Holes used in RC/Core Comparison ...... 11-82 Figure 11-4: Sequence of data entry ...... 11-84 Figure 11-5: Scatter Plot CuT vs CuS ...... 11-85 Figure 13-1: Particle Size Distribution ...... 13-88 Figure 13-2: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-1, M-3 and M-5...... 13-93 Figure 13-3: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-2 and M-4...... 13-94 Figure 13-4: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-6 and M-7...... 13-94
Figure 13-5: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-1, M-3, M-5, M-6 and M-7 ...... 13-95 Figure 13-6: Mini-columns Total Copper Recoveries...... 13-99 Figure 13-7: 1.5 meters Columns Total Copper Recoveries...... 13-100 Figure 13-8: 1.5 meters Columns Net Acid Consumption...... 13-100 Figure 13-9: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Days). .. 13-102 Figure 13-10: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Leaching Ratio)…………...... 13-102 Figure 13-11: CuT Recovery and Net Acid Consumption P90 ½” Geomet II Columns (vs Days).13-103 Figure 13-12: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Leaching Ratio)…………………...... 13-103 Figure 13-13: Total Copper Recovery and Net Acid Consumption Kinetics for a 4 meters Column (Model)……………………...... 13-104 Figure 13-14: Net Acid Consumption P90 ½” Geomet I Columns vs Added Acid...... 13-107 Figure 13-15: Net Acid Consumption P90 ½” Geomet II Columns vs Added Acid...... 13-107 Figure 13-16: Mine Plan Solubility Ratio by Mineral Subzone...... 13-108 Figure 13-17: AAC vs Solubility Ratio...... 13-109 Figure 13-18: iso-pH Geomet I, II & III Gangue Acid Consumption vs Solubility Ratio...... 13-110 Figure 13-19: Total Copper Recovery Geomet II Selected Columns...... 13-116 Figure 13-20: Total Acid Consumption Geomet II Selected Columns...... 13-117 Figure 13-21: Net Acid Consumption (Gangue) Geomet II Selected Samples...... 13-117 Figure 13-22: Evolution of FeT Concentration in Geomet II Selected Columns...... 13-118 Figure 13-23: Evolution of FeT dissolution Geomet II Selected Columns...... 13-119 Figure 13-24: Aqueous Phase Chloride Balance Diagram...... 13-121 Figure 13-25: Crushed Material Particle Size Distribution...... 13-127 Figure 13-26: ROM Particle Size Distribution...... 13-127 Figure 13-27: Effect of Height on Marimet-1 Columns...... 13-128 Figure 13-28: Effect of Height on Marimet-2 Columns...... 13-129 Figure 13-29: Effect of Height on Marimet-3 Columns...... 13-129 Figure 13-30: Effect of Height on Marimet-4 Columns...... 13-130 Figure 13-31: Effect of Height on Marimet-5 Columns...... 13-130 Figure 13-32: Effect of Height on Marimet-6 Columns...... 13-131 Figure 13-33: Effect of Height on Marimet-7 Columns...... 13-131 Figure 13-34: Total Copper Recovery Kinetics at Different Heap Heights (BROC/ATA Model). .. 13-132 Figure 13-35: Net Acid Consumption Kinetics at Different Heap Heights (BROC/ATA Model). ... 13-133 Figure 13-36: Simplified Leach Circuit Balance Years 1 to 5...... 13-135 Figure 13-37: Simplified Leach Circuit Balance Years 6 to 12...... 13-136 Figure 14-1: 3D Litho-Structural Model ...... 14-141 Figure 14-2: 3D Mineral Zones Model ...... 14-141
Figure 14-3: Details of the Copper Mineral Zones from 3D Wireframes ...... 14-142 Figure 14-4: Mineral Zones Solid (Atahualpa Domain) ...... 14-147 Figure 14-5: Block Model Cross Section ...... 14-148 Figure 14-6: Block Model Cross Section ...... 14-149 Figure 14-7: Geotechnical Zones ...... 14-150 Figure 16-1: Geotechnical Slope Domains ...... 16-157 Figure 16-2: Final Pit Design...... 16-160 Figure 16-3: Open Pit Development Phases ...... 16-161 Figure 16-4: Final Pit and Material Storage Facilities ...... 16-166 Figure 17-1: General Block Diagram ...... 17-171 Figure 17-2: Crushing Plant Flowsheet for Phase 1...... 17-173 Figure 17-3: Crushing Plant Flowsheet for Phase 2...... 17-174 Figure 17-4: ROM and Heap Leaching Diagram ...... 17-176 Figure 17-5: SX Schematic Configuration Phase 1 & 2...... 17-178 Figure 17-6: EW Diagram ...... 17-178 Figure 18-1: Proposed Infrastructure Layout Plan...... 18-186 Figure 18-2: Crush Heap Leach and Ripios Storage Facilities...... 18-187 Figure 18-3: Site Project Electrical Network ...... 18-188 Figure 18-4: Schematic Water Supply and Distribution Network ...... 18-189 Figure 18-5: Non-Paved B-240 Road with Bischofita Covering ...... 18-189 Figure 18-6: Gravel Road which leads to the Marimaca Plant Site ...... 18-190 Figure 22-1: Projected LOM Cash Flows...... 22-222
1 Summary
1.1 Introduction
Marimaca Copper Corporation (Marimaca Copper) requested Ausenco Engineering Canada Inc (Ausenco) to compile a technical report (the Report) on the results of a preliminary economic assessment (2020 PEA) on the Marimaca Copper Project (the Project), located in Antofagasta Province, Chile.
1.2 Terms of Reference
This Report supports the disclosure of the results of the PEA in the news release dated 4 August by Marimaca Copper, entitled “Exceptional PEA Results for the Marimaca Project including $524 million post-tax real NPV8 and 33.5% IRR”.
Companies who contributed to the PEA, in alphabetical order, include:
Ausenco Jo & Loyola Consultores de Procesos NCL Ingeniería y Construcción.
All measurement units used in this Report are metric unless otherwise noted. Currency is expressed in United States (US) dollars ($). The Chilean currency is the peso. The Report uses US English.
1.3 Project Setting
The Project is located in Chile’s Antofagasta Province, Region II, approximately 45 km north of the city of Antofagasta and approximately 1,250 km north of Santiago. The coastal cities of Antofagasta and Mejillones can be accessed from the Project via a well-maintained multi-lane highway. The regional Cerro Moreno airport is located 45 km from the Project. Marimaca is accessible by maintained dirt roads, either from the Cerro Moreno Airport or the Route Antofagasta–Tocopilla.
The Project is located about 39 km north of the Tropic of Capricorn. The climate is dry, and the average annual rainfall is 2–3 mm as an annual average over a 24-hour period. However, rare intense rainfall events of 12–30 mm in a short period can occur. It is expected that any future mining operations will be conducted on a year-round basis.
The Marimaca Project is situated within the Cordillera de la Costa, a mountainous area, with relief ranging from 400–1,000 m elevation. Vegetation is minimal outside of inhabited valleys where irrigation and the “Camanchaca” sea mist that comes from the nearby ocean, support vegetation that is capable of withstanding the desert environment. The Mejillones and Naguayán quebradas drain the Project area from east to west and south to north, respectively.
1.4 Mineral Tenure, Surface Rights, Water Rights, Royalties and Agreements
The Project is held 100% by Marimaca Copper. Marimaca Copper has four Chilean subsidiaries that have actual, or eventual, rights over various mining properties that make up the Project:
Compañía Minera Cielo Azul Limitada (MCAL)
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Compañía Minera NewCo Marimaca (Newco Marimaca) Compañía Ivan SpA (Compañía Ivan) Minera Rayrock Limitada (Rayrock).
There are several agreements and options in force over the mineral tenures. There are also staged payments that must be met for certain of the agreements. As at the report effective date, these had been met as they came due.
Through direct acquisition and option agreements, Marimaca Copper holds 100% of 385 granted concessions and concession applications, covering an area of 74,248 ha. These are, for convenience, divided into two packages:
Marimaca area: 265 claims (62,568 ha) held in the names of the following Marimaca Copper`s subsidiaries and/or third party companies (according to the Option Agreements): Compañía Minera Cielo Azul Limitada, Compañía Minera Naguayán SCM, Sociedad Contractual Minera NewCo, Sociedad Legal Minera Rodeada Uno, Proyecta S.A. and Sociedad Contractual Minera Proyecto Iván area: 120 claims (11,680 ha) held in the names of Minera Rayrock Limitada or Compañía Minera Cielo Azul Limitada.
The surface land in the Commune of Mejillones is owned by the State and managed and represented by the Ministerio de Bienes Nacionales. Marimaca Copper has developed a strategy to obtain the necessary surface rights to cover mine, plant, tailings storage facilities and transmission lines. Marimaca Copper holds one easement and a second has been applied for.
Marimaca Copper holds no water rights in the Project area.
The Project is subject to several NSR royalties, which range from 1–2%. Marimaca Copper has the right to buy back some of the NSR percentages for in all of the royalty agreements.
1.5 Geology and Mineralization
The Marimaca deposit appears to be a new deposit style as it does not readily conform to any of the major published geological models. It has affinities with vein-style iron ore–copper–gold (IOCG) deposits and “manto-type” mineralization styles.
The regional geology consists of Jurassic volcanic and intrusive rocks, with minor older Triassic acid volcanic occurrences, intermediate intrusive units, sediments and Palaeozoic metamorphic rocks. The main regional structure is the Atacama Fault System (AFS) which forms the eastern border of the Coastal Cordillera in the region. To the west of the AFS, the Naguayán Banded Fracture Belt (NBFZ) forms an approximately 15 km long and 3 km wide zone of sub-parallel fractures that trend north–south to north–northeast, dipping at 40–60º to the east or southeast. The rhyodacitic-composition regional dyke swarm end members are preferentially associated with the NBFZ.
The local geology consists of monzonite, diorite and monzodiorite intrusions correlated with the Naguayán Plutonic Complex, and dykes belong to the regional bimodal dyke swarm. Alteration related to mineralization consists of development of actinolite and magnetite, with lesser chlorite, sericite, and hematite, that is associated with veins, feeders, and banded rocks. The diorite unit has undergone biotite–magnetite replacement. A major alteration feature is the so-called hanging wall alteration front, which controls the mineralization toward the “top” of the parallel-fractured monzonite and diorite units and the mineralization associated with dikes. Hematite, in association with sericite and pyrite, forms band replacements and veins. The feeders that crosscut the alteration limit displays a well-developed “argillic” halo.
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Supergene oxidation has resulted in the formation of limonite, clays, and copper oxides. Goethite and hematite stain fractures or fill open fractures. Iron oxides can be associated with clay, gypsum and rock flour within fault gouge. Jarosite can occur in the halo of some of the northwest-trending faults zones in the southern part of the Project area.
The Marimaca deposit consists of a supergene copper blanket (oxides and enriched sulphides). The oxide zone is exposed on surface, and has dimensions of about 1.4 km long, 400–600 m in width, and a thickness that ranges from 150–350 m. Mineralization in the Marimaca area has formed in association with the fractures of the NBFZ, and in association with north–south to northeast-oriented “feeder” zones or vein-like structures. It consists of chalcopyrite, moderate to minor pyrite, minor bornite, covellite and primary chalcocite forming massive bodies, zones of replacement and fracture fills. The copper oxide blanket overlies the primary mineralization, which resulted from the alteration of a secondary sulphide- enriched blanket that produced a chemical zonation from brochantite to atacamite at the core of the alteration zone, with a surrounding outboard halo of predominantly chrysocolla, followed by a wad halo.
1.6 History
Small-scale artisanal mining activities were undertaken in the general Project area from the 1990s to mid-2000s. Underground workings are at maximum of 100 m deep.
No modern exploration was undertaken prior to Coro Mining Corp (Coro), a predecessor company to Marimaca Copper, began to assemble the Project ground holdings. The Marimaca deposit was identified in 2016, following a reverse circulation (RC) drill program. Coro subsequently detailed geological surface mapping and rock chip sampling, additional RC drilling, core drilling to support geotechnical and geometallurgical studies, metallurgical testwork, and mining studies. An initial resource estimate was completed in January 2017, and Mineral Reserves were first estimated in 2018.
Coro completed a feasibility study in June 2018 (the 2018 Feasibility Study). This study considered an open pit mining using conventional equipment to feed a refurbished process plant, referred to as the Ivan plant, that would have the capability of producing 10,000 t of cathode copper per year.
The 2018 Feasibility Study is not currently considered to be the preferred Project development option. Marimaca Copper is not treating the study as current, and the Mineral Reserve estimates are also not considered to be current. However, some of the baseline information generated in support of the 2018 Feasibility Study is used in the 2020 PEA.
An Environmental Impact Statement (Declaración de Impacto Ambiental, DIA in the Spanish acronym) and the Mining Safety Regulations and Environmental Qualification Resolution (RCA) was approved on 5 July 2018.
Mineral Resources were updated in late 2019, and that estimate is discussed in Section 14. Coro changed its name to Marimaca Copper in May 2020. A PEA was completed in 2020, and the results of that study are summarized in this Report.
1.7 Drilling and Sampling
A total of 346 RC holes (82,234 m) and 39 core holes (8,976 m) have been completed. The RC drilling was completed by PerfoChile Ltda, with drill hole diameters from 5¾” to 5 ⅝”. Core drilling was performed at PQ (85 mm core diameter), HQ (63.5 mm) and HQ3 (61.1 mm) sizing by Superex, a Chilean drilling contractor. Collar locations were at 100 m or 50 m spacing, as dictated by topography and the ability to construct drill platforms and pad accesses. Drill holes were typically oriented at either 220º or 310º. However, some holes were oriented at 270º to
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test high-grade zones controlled by north–south-trending feeders and veins. Drill holes were angled at -60º.
All drill holes were geologically logged using digital data capturing methods. Information logged included lithology, structure, alteration and mineralization based on drilling intervals, recoveries and analytical results. RC drill cuttings were cleaned prior to geological description. The first pass logging recorded lithology, structure and alteration. Oxide mineralogy was relogged when assay data were received. A chip tray record of the drill holes was stored. Core holes were initially logged for lithology, structure and alteration. When assay data were available, the data were correlated with the logged mineralization. Rock quality designation (RQD) data were also recorded. In addition to measuring deviations, most of the holes were surveyed using an optical televiewer (OPTV or BHTV), which continuously recorded structures and orientation measurements down the length of the drill hole.
Recovery data were recorded for the RC and core drill holes. Measured recoveries are over 95% for both types of drilling, without significant variations and recovery is unrelated to copper grades.
Local contractors carried out the supervision of the drilling operation. An experienced surveyor recorded the collar locations. Collars are marked in the field using PVC pipe and a metal plate with the name of the drill hole. Down hole surveys were completed by either Data Well Services or Comprobe. The instrumentation includes Giroscope NSG for survey and Optv, Hirat and Caliper probes for video. All readings were continuous to the end of the holes.
In the opinion of the QP, the quantity and quality of the lithological, collar and down-hole survey data collected in the drilling programs are sufficient to support Mineral Resource estimation.
Continuous rock sampling along exposures in road cuts was completed during 2018–2019. Samples consisted of continuous chip-channel samples at 2 m intervals for a total 5,120 m of sampling. Detailed and systematic rock sampling was extended to the underground mine workings, using the same criteria and methods from the surface samples. A total of 8,028 m was sampled from the artisanal mine workings. RC drill holes were sampled on a 2 m continuous basis, with all the dry samples riffle split on-site and one quarter sent to the laboratory for preparation and assaying. The description of core sampling is in the Figure 1-1.
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Figure 1-1: Core Sampling Process
Note: Figured prepared by Marimaca Copper. 2020
Specific gravity (SG) was measured systematically on core samples at approximately 20 m intervals. The core samples ranged in length from 7–26 cm. The SG was determined on wax- coated core using a water displacement method where the core was weighed in air, and then in water. Measurements were performed by the Mecánica de Rocas (Rock Mechanics) laboratory at Calama.
Initially, the primary sample preparation and assay laboratory was Geolaquim Ltda. (Geolaquim) in Copiapó. Geolaquim held ISO 9001:2000 accreditations for selected analytical techniques and was independent of Marimaca Copper. From the 2017 infill drilling campaign onward, samples were prepared in the Andes Analytical Assay Ltda (Andes Analytical) Calama laboratory and assayed by the Andes Analytical laboratory in Santiago. Andes Analytical holds ISO 9001:2008 accreditations for selected analytical techniques and is independent of Marimaca Copper. Andes Analytical acted as an umpire laboratory for the 2015 drill campaign. Marimaca Copper did not employ an umpire laboratory for the remainder of the campaigns.
Samples were prepared by drying, crushing to 85% passing 10 mesh, and pulverizing to 95% passing 150 mesh. Total copper (CuT) was analysed using a four-acid digest followed by an atomic absorption spectroscopy (AAS) finish. Soluble copper (CuS) was analysed using a single acid digest, followed by AAS. The analytical quality assurance and quality control (QA/QC) programs involved the use of pulp duplicates for precision analyses, standard reference materials (SRMs) and check samples for accuracy analyses.
To validate the use of data from the core and RC exploration campaigns, a comparison was undertaken of 11 drill holes that were within a maximum of 10 m separation. The average CuT and CuS grades from the core and RC drilling were compared. In the QP’s opinion, these averages are very similar.
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The sample preparation and analytical procedures used by the independent laboratories are in line with industry norms. Sample security practices are acceptable. The analytical data are considered acceptable to support Mineral Resource estimation.
1.8 Data Verification
The exploration and production work completed by Marimaca Copper was conducted using internally documented procedures and involved verification and validation of exploration and production data prior to use of the data in geological modelling and Mineral Resource estimation.
NCL staff performed site visits, and observed core and RC drill sites, collars, and collar monumenting. NCL examined core from several RC and DDH drill holes, finding that the logging information accurately reflected the inspected core and cuttings. The lithology and grade contacts checked by NCL matched the information reported in the core logs. The QP reviewed the drill hole database and concluded that it was adequate to support block models, and Mineral Resource estimates. NCL visually compared the block models against the informing samples on plans and sections to confirm that the estimations were generally an adequate representation of the distribution of the copper mineralization.
The QP is of the opinion that the data verification programs completed on the data collected from the Project are consistent with current industry practices and that the database is sufficiently error-free to support the geological interpretations, Mineral Resource estimation and preliminary mine planning.
1.9 Metallurgical Testwork
Metallurgical testwork was completed in three campaigns, Geomet I, II and III. Geomet IV is underway at the Report effective date. Most of the mineralized material is planned to be crush leached, using crushing, agglomeration, leaching, solvent extraction (SX) and electrowinning (EW). Low-grade mineralized material will be sent to a run-of-mine (ROM) leach.
1.9.1 Crush Heap Leach
Preliminary tests evaluated parameters such as mineral subzone, agglomeration conditions, granulometry, column height, irrigation rates and acid concentration in the irrigation solution. Five mineralization subzones were defined, listed below with their predicted leaching recoveries (calculated over the total copper content of the material that will be processed):
BROC/ATA: classified as oxide; copper in the form of brochantite and atacamite; 82% recovery CRIS: classified as oxide; copper in the form of chrysocolla; 77% WAD: classified as oxide; copper in the form of wad; 65% MIX: classified as sulphide; mixed oxide/sulphides; 62% ENR: classified as sulphide; sulphides; 49%.
The overall copper recovery prediction for the combined mineralized subzones is 76%.
Acid consumption is predicted to be 40kg/t for oxide mineralization (BROC/ATA, CRIS and WAD) and 35 kg/t for sulphide mineralization (MIX and ENR). The carbonate content is relatively low and accounts for about 30% of the expected overall acid consumption. The other major acid consumers that will be dissolved are iron and aluminium, which are estimated to represent about 30% and 20% of the overall acid consumption, respectively.
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A particle size distribution after crushing of P90 <1/2” with a content of fines of less than 12% -100# Tyler is considered applicable to the process design.
Agglomeration will be conducted with raffinate solution and concentrated sulphuric acid at the rate of 15–30 kg/t. Later in the proposed mine life, addition of NaCl in the agglomerate is assumed to be used at the rate of 15 kg/t to improve sulphide oxidation during the resting period. Resting time without salt addition is forecast at about 2–3 days. When salt is added, a resting time of 15–30 days will be required. The chloride leaching process is proposed for the later mine plan with the chloride base level defined by the use of seawater and the chloride present in the mineralized material to support the recovery of some of the copper present in the sulphide subzones.
A trade-off analysis between heap height and the area needed for a crush heap leach pad was conducted to determine the preferred combination and leaching time (residence time). The analysis suggested that a 4 m high heap pad and with a total leaching area of 500,000 m2 was the preferred configuration. This combination would result in a leach cycle of 95 days.
An irrigation rate of 12 L/hr/m 2 add by sprinklers was recommended for the crush heap leaching process.
The oxidized mineralization subzones (BROC, CRIS and WAD) are planned to have three days of resting time and 92 days of irrigation, completing a leaching cycle of 95 days. The sulphide mineralization subzones (MIX and ENR) will have 30 days of resting time and 110 days of irrigation, to complete a leaching cycle of 140 days.
For the first part of the 2020 PEA process plan (Years 0 to 5), MIX and ENR mineralization will be mixed with WAD and treated as if they were oxides without the need of salt addition. The latter part of the PEA process plan (Years 6 to 12), oxide and sulphide subzones are planned to be processed in separate leach pad modules.
It is estimated that the plant will operate with high dissolved impurity levels, including chloride (63–73 g/L), iron (40 g/L) and sulphates (200 g/L). As a result, an SX plant with two washing stages was considered for the 2020 PEA, to avoid impurities to report to electrowinning.
1.9.2 ROM Leach
The ROM feed will predominantly be WAD material, which is forecast to achieve a 40% total copper recovery.
The ROM material is recommended to be stacked in 10-m layers, with a leaching cycle of six months, 10 g/L of sulphuric acid in irrigation and a continuous application rate of 5 L/hr/m 2 using drippers.
1.10 Mineral Resource Estimation
Estimation was conducted using commercially available Leapfrog and GEMS software. The primary support for the Mineral Resource estimate is data collected from the 2016, 2017 and 2018 drill programs. All samples without a grade value in the database were eliminated prior to resource modelling. Values labelled <0.001% were changed to 0.001% for both CuT and CuS.
Lithology, structure, and mineralization were interpreted on approximately 50 m-spaced cross-sections that were oriented northeast, northwest, and east–west at 1:1,000 scale. The mineralization interpretations are used as the domains for resource estimation. The domains are brochantite, chrysocolla, enriched, wad CuT ≥0.1%, wad CuT <0.1%, and chalcopyrite. Samples from the database were coded based on the 3D solid codes, based on the solid that contained the sample centroid.
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A review of the sample lengths was conducted to determine if compositing was warranted. This check showed that only three samples within the modelled solids had a length of <1 m. All the remaining samples were 2 m in length. No compositing was conducted as a result. Review of CuT and CuS domain boundaries indicated that all contacts should be treated as hard boundaries. Grade capping was used in all domains to restrict outlier CuT and CuS assay values. In addition, a 5 m search ellipse was used during estimation to locally restrict the samples with grades above the cap value. Prior to estimation, all SG outliers were removed from the 562 SG determinations available. Average SG values were assigned to each of the estimation domains.
Correlograms were computed for five zones considered to be structurally separated (Tarso, Atahualpa, Atahualpa–La Atomica, La Atomica and Marimaca) to provide search distances to be used in estimation. A percentage model was run in GEMS for each mineralized domain. The block size was 5 m x 5 m x 5 m in size, rotated to N 40º E to match the geological section interpretations. The remaining blocks below the surface topography were coded as waste. Grade was interpolated using ordinary kriging (OK) and a series of four passes. Pass 1 resulted in Measured Mineral Resources, Pass 2 in Indicated, and Pass 3 in Inferred. All blocks estimated in the fourth pass were considered unclassified. Model validation used a combination of visual inspection, a nearest-neighbour (NN) analysis, and trend analyses.
Reasonable prospects of eventual economic extraction were addressed by applying a resource pit shell defined using Whittle software and the parameters outlined in Table 1-1. Pit slope angles were derived from a study carried out by Ingeroc S.A, (Ingeroc) in 2019.
Table 1-1: Pit Shell Input Parameters.
Item Unit Value Mining cost $/t 2.00 Heap leach process cost (including G&A and SX/EW cost) $/t 9.00 ROM process cost including G&A $/t 2.50 Selling cost $/lb Cu 0.07 Heap leach recovery % 76 ROM recovery % 40 Pit slope angle Degrees 44–46 Cu price $/lb Cu 3.00
1.11 Mineral Resource Statement
Mineral Resources and Mineral Reserves are reported in accordance with the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Definition Standards for Mineral Resources and Mineral Reserves (May 2014; the 2014 CIM Definition Standards) and the CIM Estimation of Mineral Resources and Mineral Reserves Best Practice Guidelines 2019 edition (2019 CIM Best Practice Guidelines).
Mineral Resources are reported on a 100% basis. Mineral Resources are not Mineral Reserves and do not have demonstrated economic viability. The Qualified Person for the estimate is Mr Luis Oviedo, CMC, an NCL employee. Mineral Resources are provided in Table 1-2.
Areas of uncertainty that may materially impact the Mineral Resource estimates include: changes to long-term copper price and exchange rate assumptions; changes in local interpretations of mineralization geometry and continuity of mineralized zones; changes to geological and grade shape and geological and grade continuity assumptions; changes to interpretations of the structural zones; changes to the density values applied as averages to
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the estimated domains; changes to metallurgical recovery assumptions; changes to the input assumptions used to derive the conceptual open pit used to constrain the estimate; changes to the cut-off grades applied to the estimates; variations in geotechnical, hydrogeological and mining assumptions; forecast dilution; and changes to environmental, permitting and social license assumptions.
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Table 1-2: Mineral Resource Statement
Contained Metal
Tonnes Grade CuT CuS Classification (t x 1,000s) Tonnes Tonnes CuT (%) CuS (%) (kt) (kt) Measured
Brochantite 10,890 0.76 0.55 82 60 Chrysocolla 4,918 0.59 0.45 29 22 Enriched 1,176 0.75 0.17 9 2 Mixed 475 1.02 0.26 5 1 Wad 3 0.27 0.17 0 0 Wad GT 0.1 % 3,260 0.34 0.2 11 7 Total Measured 20,721 0.66 0.44 136 92 Indicated
Brochantite 24,719 0.68 0.49 167 121 Chrysocolla 9,581 0.5 0.37 48 36 Enriched 3,468 0.69 0.14 24 5 Mixed 1,177 0.86 0.21 10 2 Wad 36 0.26 0.14 0 0 Wad GT 0.1% 10,686 0.32 0.18 34 19 Total Indicated 49,666 0.57 0.37 284 184 Measured and Indicated
Brochantite 35,609 0.7 0.51 250 181 Chrysocolla 14,499 0.53 0.4 77 58 Enriched 4,644 0.7 0.15 33 7 Mixed 1,652 0.9 0.22 15 4 Wad 38 0.26 0.14 0 0 Wad GT 0.1% 13,945 0.32 0.19 45 26 Total Measured and 70,387 0.6 0.39 420 276 Indicated Inferred
Brochantite 17,618 0.63 0.42 111 74 Chrysocolla 9,978 0.47 0.33 47 33 Enriched 2,193 0.63 0.13 14 3 Mixed 3,661 0.63 0.15 23 6 Wad 43 0.27 0.09 0 0 Wad GT 0.1% 9,521 0.31 0.17 30 16 Total Inferred 43,015 0.52 0.31 224 132
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Notes to accompany Mineral Resource Table:
1. Mineral Resources are reported using the 2014 CIM Definition Standards. The Qualified Person for the estimate is Mr Luis Oviedo, CMC, an NCL employee. Mineral Resources have an effective date of 15 January 2020 and are reported on a 100% basis.
2. Mineral Resources are not Mineral Reserves and do not have demonstrated economic viability.
3. Mineral Resources are reported within a constraining pit shell developed using Whittle™ software. Input assumptions include a copper price of $3.00/lb, mining recovery of 100%, metallurgical recoveries of 76% for CuT leaching and 40% for Cu ROM leaching, a mining cost of $ 2.00/t, processing costs of $9.0/t for leach processing and $2.50/t for the ROM process. General and administrative costs are included in the processing costs.
4. Base case Mineral Resources are reported using a 0.22% total copper (CuT) grade. Tonnages contained in the chalcopyrite subzone are not included in the tabulation.
5. Wad GT0.1% unit corresponds to the “high grade Wad”, which was separated from the low-grade Wad to refine the geological model, better reflecting the grade distribution within the deposit.
6. Mineral Resource contained copper estimates have been rounded as required by reporting guidelines.
1.12 Mining Methods
Open pit mining is contemplated, using equipment conventional to the industry.
The open pit area was divided into three geotechnical zones, with pit slope angles that range from 42–52º. Mining dilution, based on a cut-off grade of 0.2% CuT is assumed to be 2.3% for tonnes, and a contained copper loss of 4.6% will result.
Eight pit phases are planned. phase 1 targets the material with the highest grade in the central area, down to 920 masl. phases 2 and 3 are successive expansion to the north, down to 960 masl and 870 masl, respectively. phase 4 is an almost independent pit at the northern area of the deposit with an exit to the north and a connection with phase 3 for exiting to the primary crusher to the south. This phase will extend to the 890 masl. phase 5 is an expansion to the west of the main pit, to 830 masl. phases 6 and 7 are final expansions to the south and west, respectively to 890 masl and 830 masl. phase 8 corresponds to the final expansion of the north pit, to 880 masl.
A road width of 30 m was selected to accommodate trucks up to 190 t. NCL used a 10% road gradient which is common in the industry for this type of truck. The 2020 PEA mine plan is designed with 10 m benches stacked to 20 m (i.e. double benching) for the geotechnical Zone 1 (East wall). Mining costs are based on blasting 10 m benches for every material type. Additional 20 m wide safety berms were included in the design when the slope height exceeds 150 m, in accordance with geotechnical recommendations.
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Table 1-3: Pit Shell Input Parameters
Item Unit Value Copper price $/lb 3.0 Mine $/t mined 2.10 Mineralized material haulage $/t processed 0.48 Crush Heap leach $/t processed 4.33 Crush Heap leach $/lb 0.25 G&A $/t processed 2.00 ROM Dump leach $/t ROM 2.54 ROM Dump leach $/lb 0.25 Selling cost $/lb 0.07
The mine plan was tailored toward a copper cathode production rate of 40,000 t/y. An initial pre-stripping period of 4.0 Mt would be required to expose sufficient mineralised material to start commercial production in Year 1. The mineralised material mined during pre-stripping will be stockpiled in the stockpile area and will make up part of the Year 1 plant production. The total stockpiled for later re-handling during Year 1 will amount to 139 kt, plus 32 kt of low- grade material. The pre-stripping period will be approximately three months. Three separate mining rates will be used during commercial production. An initial three-year period will mine at a rate of 14.5 Mt/y. This will be followed by a two-year period that will mine at a rate of 18.54 Mt/y, which will meet the initial plant throughput capacity of 5.4 Mt/y. To meet the second plant throughput capacity rate of 9.0 Mt/y a total mining rate of 23.5 Mt/y is required for the remainder of the mine life.
Two waste rock storage facilities area (WRSFs), will be located to the west (WSFN) and south (WSFS) of the pit. A ROM pad area was designed in a flat valley, located in between the WRSFs, where the ROM leach process will take place. The leaching of this low-grade material is planned in 10 m lifts. The mine plan assumes that 42.3 Mt are placed in the facility. The life of mine (LOM) plan stockpiles low-grade material for later re-handling at the end of the LOM to the primary crusher for crush leaching. The low-grade stockpile was designed at the toe of the WSFS and will accommodate 1.3 Mt.
The drilling equipment will consist of diesel units capable of drilling 7⅞” diameter holes in all material types.
The major equipment was selected based on the mine production schedule, nine months of pre-production and approximately 12 years of commercial mining operations. The pre- production period will include an initial pioneering period estimated at six months for preparing initial roads and bench openings and storage material facilities, followed by a pre-stripping period estimated to be three months long. The total material mined during pre-stripping will be 4 Mt. Re-handling of material will be required in Year 1 for material mined during pre- stripping to meet the plant feed requirements. The mining operation will use 22 m 3 hydraulic excavators, 23 m3 front-end-loaders and trucks with a capacity of 150 t. This type of equipment can achieve the required productivity for an annual total material movement of 23.5 Mt. The fleet will be complemented with drill rigs for material delineation. Auxiliary equipment will include track dozers, wheel dozers, motor graders and a water truck. The mine fleet will also include the necessary equipment to re-handle the material from the stockpiles to the primary crusher. This operation will be carried out using a front-end loader and the same 150 t trucks used in the open pit.
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1.13 Recovery Methods
The Marimaca Project will operate a conventional salt acid leaching process consisting of a comminution circuit, crush leach (HL) and ROM leach facilities, SX and EW to produce Grade- A copper cathodes. All leaching will be performed using seawater-based process solutions, with sulphuric acid and salt addition to both acid-leach the copper oxide mineralization and chloride-leach the sulphide copper mineralization sent to crush heap leaching.
Water devoid of chloride for SX/EW requirements will be provided by a dedicated reverse osmosis (RO) plant. The brine RO plant reject stream will be recovered as process water, hence providing additional chloride to the process and making full use of all available water to meet process needs.
The SX plant was designed to operate with high levels of chloride present in the pregnant leach solution (PLS) and includes two organic washing stages that will allow for a low and manageable transfer of chloride to EW through entrainment.
As explained in the sections before the mine plan assumes two mining phases. Phase 1 will run from Year 1 to Year 5 will see primarily oxide mineralization being sent to the crush heap leach at a processing capacity of 5.4 Mt/y. This initial period is expected to see minimal mining of sulphide copper mineralization. The second mine phase will run from Year 6 to Year 12 and assumes that 9 Mt/y of mineralization will be sent to the crush heap leach. The material will still be dominated by oxide copper minerals, but there will be a higher proportion of sulphide copper mineralization, including mixed oxide-sulphide mineralization. Phase 2 of the mine plan requires an expansion of the crushing and leaching facilities. However, the other plant facilities such as the SX/EW units are sized for phase 2 capacity from the start.
The addition of salt is only considered necessary for phase 2 of the mine plan; chloride build up in the leaching solutions is considered sufficient to enhance recovery from the minor copper sulphide fractions during the first stage of the mine plan.
Facilities for copper cathode production will have a nominal capacity of 40,000 t/y Cu. Full cathode production will be achieved during the first phase of the mine plan from processing high-grade mineralized material.
The second phase will treat lower-grade mineralization, requiring a capacity increase to meet the proposed cathode production tonnage from the EW circuit. The design considers an installed power capacity of 30 MVa, with a peak power consumption of 155 GWh per year occuring at year 6, when the second phase starts.
Water requirements are 1,612,000 m³/y for phase 1 and 2,558,000 m³/y for phase 2.
The assumed mine life is 12 years. Mineralization that will be sent to the crush heap leach facility will be crushed at the crushing plant, totals 88,586 kt of copper-bearing mineralization over the LOM.
For phase 1 of the mine plan, which includes a lower capacity first year due to ramp-up considerations, an average of 5,130 kt/y of feed will be delivered during that five-year period, at an average copper grade is 0.78%. Phase 2 will average of 8,991 kt/y including a final year of slightly lower feed at an average copper grade of 0.49%. Recoveries will be about 79% for the first phase of the mine plan, reducing to approximately 74% on average during the second stage.
The crush heap leach plant is designed to process a nominal of 5,400 kt/y for phase 1 of the mine plan, equivalent to a daily balance tonnage of 14,795 t/d (with 365 d/y), consistent with the mine plan for Year 2 to Year 5 . For phase 2 (Year 6 to 12), nominal capacity will be 9,000 kt/y, equivalent to a daily balance tonnage of 24,658 t/d.
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Total copper cathode production is estimated to be approximately 430 kt of cathodes during the LOM, which includes both copper metal recovered from the heap leach and the ROM leach.
1.14 Project Infrastructure
Planned infrastructure will include:
Road network: The road network includes connections from the open pit to the WRSFs, main processing area, crush leach facilities, ROM leach facilities, maintenance complex, and administrative facilities. Processing plants: Crushing plant, agglomeration plant, and SX/EW facilities, tank farm, as well as salt and acid storage system. Conveyor systems: Overland conveyor from the agglomeration plant to the heap leach pad area, a transfer conveyor with tripper car, mobile (grasshopper) and radial stacking conveyors. Heap leach facilities: On/off acid heap, irrigation system, drainage system for pregnant leach solution (PLS) and intermediate leach solution (ILS) and process ponds. ROM leach facilities: Permanent acid heap, irrigation system and a drainage system. Solutions ponds and pumping system: PLS, ILS and raffinate ponds, emergency ponds for the spent rock (ripios) and crush leach facilities and a seawater pond WRSFs: Two facilities, north and south Administration building: Offices for mine management and supervisory staff, human resources, accounting, procurement, information technology, and safety staff. Maintenance workshop: Truck shop, warehouse, and laboratory. Electrical substation: For the main 110 kV line, Fuel storage: Tank farm with storage tanks. Process control system Communications system Water supply: potable and process.
Power will be taken from the national grid. The most convenient connection would be with the 110 kV line that follows the B240 road and is about 7 km north of the proposed plant site. For the purposes of the 2020 PEA it was assumed that a tap-off from that line will be permitted. A 7 km, 110 kV line will be built from the tap-off point to the main substation, which will be placed close to the SX/EW plant. From the main substation power will be distributed to the user centers via 23 kV overhead lines.
The water demand is assumed to be supplied by Aguas de Antofagasta S.A. (ADASA), a major Chilean water supplier, are at an expected rate of 1,612,000 m 3/y year for phase 1. phase 2 will need 2,558,000 m 3/y. The make-up water is considered to be extracted by ADASA from an existing seawater pipeline, which also follows the B-240 road. ADASA will deliver the water into Marimaca’ s seawater pond. A reverse RO plant will be required to produce the water quality needed in the SX/EW facilities, and a second RO plant will be installed for the administration building.
The installation of an operational man camp is not considered in this PEA due to the proximity of the project to Mejillones and Antofagasta, it is assumed that the majority of workforce will come from these cities.
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1.15 Environmental, Permitting and Social Considerations
1.15.1 Environmental Considerations
Marimaca Copper received an Environmental Impact Declaration (DIA in the Spanish acronym) in July 2018. The main infrastructure approved in this DIA included: mine pit, WRSF, mineralization stockpile, auxiliary installations (shops, offices, waste management, etc.), and an explosives magazine. The original Marimaca Project considered mineral extraction from the Marimaca 1-23 Claims Project (Marimaca 1-23) and the use of the existing processing plants and auxiliary installations in the Rayrock facilities (Ivan Plant).
Baseline studies for the Marimaca 1-23 DIA were completed within a surface area of 147 ha. This comprised the original Marimaca 1-23 Claims Project area, and depending on the study, additionally covered the area representing an indirect effects study area. Baseline studies included the following:
Physical environment: climate, meteorology, air quality, noise, natural hazards, soils, hydrology, hydrogeology. Biotic environment: fauna and flora Human environment: setting, heritage, archaeology; and visual landscape.
The 2020 PEA represents an expansion of the original Marimaca 1-23 Claims Project and assumes construction of a new processing plant and auxiliary facilities to be located 5 km west of the proposed open pit. This change was evaluated in a 2020 Options Study performed by GEM Gestion y Economia Minera Ltda and it was preferred over the existing Ivan Plant facilities because of the shorter distance to the mine and from Mejillones. The plant complex will include a crushing plant, leach pads, and ripios facilities and is estimated to occupy approximately 281 ha of surface area. In addition, the Project will increase the mine pit footprint, which translates into an increase in tonnage processed and a surface area of the mine of 257 ha. This new configuration will require an environmental permit via a new Environmental Impact Assessment (EIA) or DIA.
The Chilean authorities may require that existing baseline studies be updated for a new DIA or EIA; and based on the type of document, the amount of information needed will differ. Should the project require an EIA, additional studies will be needed to account for seasonal differences and the need for one year’s worth of data for air emissions monitoring.
There are uncertainties that will need to be addressed to confirm DIA or EIA. The expansion of the pit and WRSFs will need to be considered with respect to any additional impact to the surrounding environment. Traffic studies may be required to understand potential disruptions in Mejillones or Antofagasta and or increases in air and noise emissions.
The original Marimaca 1-23 Claims Project received approval for various Environmental Sectorial Permits, (PAS in the Spanish acronym) for infrastructure and activities approved in the 2018 Marimaca 1-23 DIA. The Project will also require various PAS that will have to be included in the new DIA or EIA document. The PAS will have to be amended or renewed based on the new Project areas and/or installations, and some will have to be updated with the modifications to the pit and WRSFs in the mine area.
The Project as described in the 2020 PEA will have to identify and classify the Sectorial Permits (PS in the Spanish acronym) needed along with critical path permits. Among the critical permits are those approved by the mining, water, and roads authorities that have long approval timelines, complex level of technical studies/data required or that have pre-requisites that could impact the Project schedule. To date, Marimaca Copper has not submitted applications for the approved Project installations.
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1.15.2 Closure and Reclamation Planning
The Project will require a Closure Plan, approved by the Mining Authority (Sernageomin) and regulated by Supreme Decree N°41/2012. The Closure Plan will specify closure measures defined through risk assessment and will include an estimate of the closure costs. The Closure Plan will consider all the facilities included in the approved Environmental documents as per Sernageomin’s Methodology Guide.
The Closure Plan will have to be approved before operation starts and a bond will have to be delivered to the Government of Chile during the first year of operation. The Closure Plan approval is preceded by obtaining all mining permits from Sernageomin, including those for the WRSFs, process plant, and open pits (mine operation). To date, Marimaca Copper has not obtained permits for mine operation, the process plant, or the WRSFs.
No closure and salvage costs have been considered at this stage.
1.15.3 Social Considerations
The area of influence of the Project the Antofagasta Region, and particularly the communities and cities of Mejillones and Antofagasta.
There are no indigenous lands or territories of any kind being claimed in the Project area. The closest indigenous community (Atacama La Grande) is more than 150 km from the Project area.
Formal community consultations have not occurred.
1.16 Markets and Contracts
No formal marketing studies were completed as part of this preliminary economic assessment and as of the effective date, no definitive contracts are in place for purchase of the copper produced or supply of the acid required at Marimaca.
Copper cathode is a common commodity that is traded in transparent and liquid markets. The value of the product is high in relation to their mass and volume and freight costs are not therefore a fundamental driver of expenditure.
Accordingly, for the purpose of the 2020 PEA, it is appropriate to assume that the product can be sold and at standard market rates.
1.17 Capital Cost Estimates
Capital costs were estimated from a variety of sources including derivation from first principles, equipment quotes and factoring from actual costs incurred in the construction of other similar facilities. Costs are estimated in US dollars to an accuracy of ± 25% which is equivalent to an AACE International, Class 4 Estimate.
Capital costs are summarised in Table 1-4 and show initial costs of $ 284.7 M, with sustaining costs of $66 M, for a LOM total capital cost of $350.7 M.
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Table 1-4: Estimated Capital Cost
Estimated Capital Costs Costs ($M)
Mining Equipment 14.0
Mine Development 9.2
Crushing & Agglomeration 22.7
Leaching 43.5
SX-EX Plant 81.1
Infrastructure (incl acid tanks, power supply, buildings) 14.7
Total Direct Costs 185.1
Indirect Costs 42.6
Contingency 56.9
Total Initial Capital Cost 284.7
LOM Sustaining Capital (including Indirect costs) 66.0
Total Life of Mine Capital Cost 350.7
1.18 Operating Cost Estimates
All operating costs are presented in US dollars. Operating cost estimates are accurate to within ±25%. An overall contingency was not explicitly included in the operating cost estimate, yet it does consider contingencies for specific cost contributors to allow for at-present unspecified miscellaneous details, such as electrical consumption of minor auxiliary equipment (sump pumps, dust suppression, maintenance equipment, services).
The operating costs are estimated C1 cash costs over the life of mine, at an average of $1.22/lb. C1 cash costs consist of mining costs, processing costs, site G&A and transport charges and royalties. All in sustaining costs (AISC) are estimated at an average of $1.29/lb. AISC includes cash costs plus sustaining capital.
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Table 21-5 summarizes the LOM average C1 operating costs, including mining, processing and general and administrative (G&A) costs. Average operating cost is $8.68/t of processed mineralized material (ROM and crush leach); offsite transport and royalties is $0.11/t of processed mineralized material. Operating costs consider crush leach tonnes sent to the crusher and subsequent crush leach processing, as well as ROM leaching; ROM mineralized material haulage costs to ROM facility are included in the mining haulage cost.
Table 1-5: Operating Costs
$/t mineral $/lb Cu Operating Cost Processed Processed Mining 3.19 0.44
Processing 4.95 0.69
Site G&A 0.54 0.07
Transport & Royalties 0.11 0.02 Total 8.79 1.22
1.19 Economic Analysis
1.19.1 Cautionary Statement
The 2020 PEA is preliminary in nature, and is partly based on Inferred Mineral Resources that are considered too speculative geologically to have the economic considerations applied to them that would enable them to be categorized as Mineral Reserves, and there is no certainty that the 2020 PEA based on these Mineral Resources will be realized. Mineral Resources that are not Mineral Reserves do not have demonstrated economic viability.
The results of the economic analyses discussed in this section represent forward-looking information as defined under Canadian securities law. The results depend on inputs that are subject to several known and unknown risks, uncertainties, and other factors that may cause actual results to differ materially from those presented herein. Information that is forward- looking includes the following:
Mineral resource estimates Assumed commodity prices and exchange rates Proposed mine production plan Projected mining and process recovery rates Assumptions as to mining dilution Capital cost and proposed operating cost estimates Assumptions about environmental, permitting, and social risks
Additional risks to the forward-looking information include:
Changes to costs of production from what is assumed Unrecognised environmental, permitting or social risks Unanticipated reclamation expenses Unexpected variations in quantity of mineralised material, grade or recovery rates Geotechnical considerations during mining being different from what was assumed
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Failure of mining methods to operate as anticipated Failure of plant, equipment or processes to operate as anticipated Changes to assumptions as to the availability of electrical power, and the power rates used in the operating cost estimates and financial analysis Ability to maintain the social licence to operate Accidents, labour disputes and other risks of the mining industry Changes to interest rates Changes to tax rates
Calendar years used in the financial analysis are provided for conceptual purposes only. Permits still must be obtained in support of operations; and approval to proceed is still required from Marimaca Copper’s Board of Directors.
1.19.2 Methodology Used
An economic model was developed to estimate annual pre-tax and post-tax cash flows and sensitivities of the project based on an 8% discount rate. It must be noted that tax estimates involve complex variables that can only be accurately calculated during operations and, as such, the after-tax results are approximations. A sensitivity analysis was performed to assess the impact of variations in metal prices, initial capital cost, total operating cost, discount rate and grade. The economic analysis was run on a constant dollar basis with no inflation.
A base case copper price of $3.15/lb is based on consensus analyst estimates and recently published economic studies.
The economic analysis was performed using the following assumptions:
Construction starting January 1, 2023 Construction costs capitalised by 30% and 70% in Year -2 and Year -1 respectively Commercial production starting (effectively) on January 1st, 2025, with first revenue and expensed costs in Year +1 Mine life (LOM) of 12 years Cathode premium of $100/t of copper Cost estimates in constant 2020 United States dollars with no inflation or escalation 100% ownership with 0.5% royalty payable on mineralized material mined from the Marimaca 1-23 claims and a 1% royalty payable on mineralized material mined from the La Atomica claims Capital costs funded with 100% equity (no financing costs assumed) Copper is assumed to be sold in the same year it is produced No contractual arrangements for refining currently exist
At the effective date of this Report, the project was assumed to be subject to the following tax regime:
The Chilean corporate income tax system consists of 27% income tax. Total undiscounted tax payments are estimated to be $430 M over the life of mine.
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1.19.3 Results
The economic analysis was performed assuming an 8% discount rate, with results as summarized in Figure 1-2.
The pre-tax NPV discounted at 8% is $757 M; the internal rate of return IRR is 39.9%; and payback period is 2.4 years.
On an after-tax basis, the NPV discounted at 8% is $524 M; the IRR is 33.5%; and the payback period is 2.6 years.
1.19.4 Sensitivity Analysis
A sensitivity analysis was conducted on the base case pre-tax and after-tax NPV and IRR of the project, using the following variables: metal prices, initial capital costs, total operating cost, and discount rate. The analysis revealed that the Project is most sensitive to revenue attributes such as copper price followed by operating cost and capital cost (Table 1-6).
Figure 1-2: Projected LOM Cash Flows
Projected LOM Cash Flow $210 $1,200
$140 $800
$70 $400
$- $- -2 -1 1 2 3 4 5 6 7 8 9 10111213 $(70) $(400)
$(140) $(800) Flow Cash
$(210) $(1,200)
Post-Tax Unlevered Free Cash Flow Post-Tax Unlevered Free Cash Flow Cash Free Unlevered Post-Tax Post-Tax Cumulative Unlevered Free Cash Flow Free Unlevered CumulativePost-Tax
Note: Figure prepared by Ausenco, 2020.
Table 1-6: Copper Price Sensitivity Summary.
Post-Tax Post-Tax Post-Tax Post-Tax Copper Post-Tax NPV8% NPV8% NPV8% NPV8% IRR Price NPV8% Capital Capital Operational Operational Base Case $/Lb Base Case cost cost cost cost (-10%) (+10%) (-10%) (+10%) $2.85 $408 $434 $381 $455 $360 28.6%
$3.00 $466 $492 $439 $514 $418 31.1%
$3.15 $524 $551 $498 $572 $476 33.5% $3.30 $582 $609 $556 $630 $535 35.7%
$3.45 $640 $667 $614 $688 $592 37.9%
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1.20 Risks and Opportunities
The following risks were identified
Unexpected variations in quantity of mineralised material, grade, or recovery rates
Geotechnical considerations during mining being different from what was assumed
Failure of mining methods to operate as anticipated
Failure of plant, equipment, or processes to operate as anticipated
Samples analysed in the Geomet I, II and III metallurgical programs mainly correspond to oxide materials from the Marimaca 1-23. There is a risk that not all of the sulphide materials in the deposit identified as leachable are not amenable to the acid-salt leaching process identified.
ROM leaching definition was estimated from a benchmark condition, testwork is required to confirm recoveries.
The current proposed copper recoveries used in the 2020 PEA considers average values for each type of zone mineral. There is a risk of low accuracy in the copper recoveries associated to the mine plan.
Heap leach defined operating conditions (heap leach height) needs to be confirmed with additional testwork.
Changes to assumptions as to the feasibility of electrical power connection to the existing powerline, and the power rates used in the operating cost estimates and financial analysis
Changes to assumptions as to the feasibility of Seawater pipeline connection to the existing seawater pipeline, and the power rates used in the operating cost estimates and financial analysis
Unrecognised environmental, permitting, or social risks
Unanticipated reclamation expenses
Changes to interest rates
Changes to tax rates
The following opportunities were identified
Significant increase in mineralization, as further Exploration activities are conducted adjacent the current deposit and in the District. Conduct a trade-off study for assessing a better economical option of transporting mined mineralized material by conveyor belt rather than hauling by truck from the pit. Occurrence of positive variations in quantity of mineralised material, grade or recovery rates after an infill drilling campaign is conducted. Geotechnical considerations during mining being better than what was assumed. This would be confirmed after geotechnical drilling is conducted on the property.
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Explore even higher leach pad heights after conducting further metallurgical testwork, which could lead to further reduction on the leaching area footprint, thus reducing capital costs. There is a potentially additional copper leachable material like secondary copper sulphide and mixed that need to be tested and analysed in the next experimental plan, which could lead to an overall increase in average recoveries. Investigate the potential reduction on the proposed acid consumption unit rate by adding a lower acid concentration solution to the pads. Conduct detailed topographic survey, which will lead to a better definition of cut and fill costs, as this is a major component of the construction costs. Investigate the use of alternative power sources, like the solar systems, which could possibly lower the power costs. Start on the water and power supply contract negotiations, which could lead to a unit cost reduction once a firmer agreement is made.
1.21 Interpretation and Conclusions
Under the assumptions in this Report, the 2020 PEA returns a positive economic return.
1.22 Recommendations The 2020 PEA yielded a positive result and indicates Marimaca is a project which should be advanced to the next phase of development. Given the Project is well advanced from many aspects, it is recommended that the Project progress directly to Feasibility Study, but that a detailed option trade-off study should be completed to ensure that consideration is given to alternative development strategies which may further enhance the value of the Project. The project is well advanced from a metallurgical perspective, but it is recommended to complete an additional phase of testing to further refine and optimize design parameters for the Project. Infill drilling will be required to move the material within the Mineral Resource Estimate, which is currently classified within the inferred category, to the higher confidence categories for the purposes of the Feasibility Study and the eventual declaration of Mineral Reserves.
To complete the recommended list of activities Marimaca Copper estimates that 10 to 12 $M will be required.
1.22.1 Geology
Marimaca Copper should consider generating a set of SRMs from local samples, matrix matched to the mineralization and reflecting deposit grades, for use in future drill campaigns.
It is recommended to conduct an infill drilling campaign using a 50 m grid spacing to provide additional information in the resource estimate area, and to potentially support conversion of existing Mineral Resources to higher confidence categories.
1.22.2 Mining
Geotechnical investigations should be extended to the north area of the pit to validate the recommendations. Stability analysis carried out to the final designed pit suggested some opportunities.
Results of metallurgical test works for recoveries and acid consumptions for both, crush leach and ROM leach processes, may increase the mineral inventory and the pit limits.
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The sulphide mineralisation potential may significantly extend the size of the pit; therefore, the location of the WRSFs and ROM pad should be revisited in the next stage of development of the project.
1.22.3 Metallurgy
METSIM software modelling and metallurgical optimization planning should be conducted to evaluate combinations of operational variables in support of performance optimization. Aspects to examine include granulometry, column heights, agglomeration conditions, and irrigation rates and acidity levels. Other parameters would include review of the copper balance, sulphuric acid, water, NaCl, impurities, solids in each stage of the planned process route.
Additional testwork should be completed to confirm that ROM leaching of the low-grade mineralization is potentially economic.
1.22.4 Environmental
Complete the baseline studies, some of which are underway, to support the preparation of permitting documents. Baseline studies should include fauna and flora, archeology, human component, paleontology and landscape.
Commence development of other preliminary engineering studies that will also support an early preparation of a DIA. In that regard, the following studies should be conducted to support infrastructure designs, in particular for those infrastructures that will remain post-closure:
Seismic study Hydrology and hydrogeology Geomorphology and geological risk Geotechnical studies Condemnation drilling
Additional evaluation of the potential for Potential Acid Generation (PAG), ML and groundwater mobilization of contaminants should be conducted to reflect the 2020 PEA project footprint. Such samples should be taken from exploration drill holes.
Conduct an early social perception study on the local communities to determine their perception/expectations about the future project. This will help with defining any compensation plan that should be taken into account by Marimaca Copper.
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2 Introduction
2.1 Introduction
Marimaca Copper Corporation (Marimaca Copper) requested Ausenco Engineering Canada Inc. (Ausenco) compile technical report (the Report) on the results of a preliminary economic assessment (2020 PEA) on the Marimaca Copper Project (the Project), located in Antofagasta Province, Chile (Figure 2-1).
2.2 Terms of Reference
This Report supports the disclosure of the results of the 2020 PEA in the news release dated 4 August by Marimaca Copper, entitled “Exceptional PEA Results for the Marimaca Project including $524 million post-tax real NPV at 8% and 33.5% IRR”.
Companies who contributed to the 2020 PEA, in alphabetical order, include:
Ausenco. Jo & Loyola Consultores de Procesos. NCL Ingeniería y Construcción.
All measurement units used in this Report are metric unless otherwise noted. Currency is expressed in United States (US) dollars ($). The Chilean currency is the peso. The Report uses US English.
2.3 Qualified Persons
This Report was prepared by the following Qualified Persons (QPs):
Robin Kalanchey (P. Eng.), Ausenco Francisco Castillo (Member of Chilean Mining Commission), Ausenco Scott Weston (P. Eng.), Ausenco Luis Oviedo (Member of Chilean Mining Commission), NCL Ingeniería y Construcción Carlos Guzman (FAusIMM), NCL Ingeniería y Construcción Marcelo Jo (Member of Chilean Mining Commission), Jo & Loyola Consultores de Procesos
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Figure 2-1: Project Location Plan
Note: Figure prepared by Marimaca Copper, 2020.
2.4 Site Visits and Scope of Personal Inspection
Mr. Oviedo visited the Marimaca offices and site from 28–31 August 2019. During the visit, he observed active drill sites, and undertook field verification of drill collar locations. He reviewed core logging and sampling procedures at the core storage facility in the project. Mr. Oviedo also reviewed data collection, data and database integrity, and geological model construction with Marimaca Copper staff.
Mr. Guzman visited the Marimaca site on May 23rd, 2018, He completed a personal inspection of the Marimaca Project for one day, involving all, during which he visited the existing facilities at the Ivan Plant and the Marimaca mine area, including previous mined pits, mineralized outcrops and future location of processing plant and material storage areas .
Mr. Jo visited the Marimaca site on January 22nd, 2020, during which time he inspected the exploration camp, sample warehouse, drill sample storage, and drilling zones. He also toured the project site to identify potential locations for the future process plant.
Mr. Castillo performed a site visit on July 23rd, 2020, during which time he inspected the existing infrastructure and toured the Project site to view potential locations for future infrastructure.
As of the effective date, neither Mr Robin Kalanchey nor Mr Scott Weston had visited the Marimaca site.
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2.5 Effective Dates
The Report has several effective dates as follows:
Close-out date for the database used in Mineral Resource estimation: 3 September 2019 Mineral Resource estimate: 20 January 2020 Date of supply of last information on mineral tenure, surface rights and agreements: 17 April 2020 Date of 2020 PEA economic analysis: 4 August 2020
The effective date of this Report is 4 August 2020.
2.6 Information Sources and References
This Report is based in part on internal company reports, maps, published government reports, and public information, as listed in Section 27 of this Report. It is also based on the information cited in Section 3.
Additional information was sought from Marimaca Copper employees in their areas of expertise.
2.7 Previous Technical Reports
Marimaca Copper, under its former name of Marimaca Copper Mining Corporation (Marimaca Copper Mining), filed the following technical reports on the Project:
Oviedo L., 2017: Technical report for the Marimaca Copper Project, Antofagasta Province, Region II, Chile: technical report prepared by NCL Ingeniería y Construcción SpA for Marimaca Copper Mining, effective date 24 February 2017, 99 p. Oviedo, L., 2018: Updated Resource Estimate for the Marimaca Copper Project, Antofagasta Province, Region II, Chile: technical report prepared by NCL Ingeniería y Construcción SpA for Marimaca Copper Mining, effective date 22 May 2018, 130 p. Quiroga V, E., Oviedo, L., Guzman, C., 2018: Definitive Feasibility Study for Marimaca 1-23 Claim Project, Antofagasta II Region, Chile: technical report prepared by Propipe and NCL Ingeniería y Construcción SpA for Marimaca Copper Mining, effective date 13 June 2018, 354 p. Oviedo, L., 2020: Updated and Expanded Resource Estimate for the Marimaca Copper Project, Antofagasta Province, Region II, Chile: technical report prepared by NCL Ingeniería y Construcción SpA for Marimaca Copper Mining, effective date 15 January 2020, 217 p.
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3 Reliance on Other Experts
3.1 Introduction
The QPs have relied upon the following other expert report, which provided information on mineral rights, surface rights, royalties, encumbrances, property agreements, product marketability, and taxation of this Report as noted below.
3.2 Mineral Tenure
The QPs have not reviewed the mineral tenure, surface rights, property ownership, royalties or encumbrances, nor independently verified the legal status of the Project area underlying property agreements or permits. The QPs have entirely relied upon, and disclaim responsibility for, information derived from experts retained by Marimaca through the following document:
Bofill Mir and Alvarez Jana Abogados, 2020: Marimaca Mining Project Legal Opinion: report prepared by Bofill Mir and Alvarez Jana Abogados for Coro Mining, 17 April, 2020
This information is used in Section 4 of the Report. It is also used in support of the Mineral Resource statement in Section 14, and the economic analysis in Section 22.
3.3 Markets
The QPs have fully relied on, and disclaim responsibility for marketing information derived from experts retained by Marimaca through the following document:
Jorge Jorrat, July 2020, The Sulphuric Acid Market Chile -Perúr
This information is used in Section 19 of the Report. It is also used in support of the economic analysis in Section 22.
3.4 Taxation
The QPs have fully relied on, and disclaim responsibility for taxation information derived from experts retained by Marimaca through the following document:
Ernst and Young, July 2020, Tax aspects for the financial model of the Marimaca project
This information is utilized to support of the economic analysis in Section 22.
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4 Property Description and Location
4.1 Introduction
The Marimaca Claims and surrounding Marimaca Copper-owned concessions are located in Chile’s Antofagasta Province, Region II, approximately 45 km north of the city of Antofagasta and approximately 1,250 km north of Santiago.
The Project is located at approximately 374,820 E and 7,435,132 S in WGS84 UTM coordinates.
4.2 Property and Title in Chile
Information in this subsection is based on data in the public domain and Chilean law (Chilean Civil Code, Chilean Mining Code, Chilean Tax Law), and has not been independently verified by the QPs.
The following laws regulate the mining industry:
Constitution of the Republic of Chile Constitutional Organic Law of Mining Code and Regulations governing Mining Code and Regulations governing Water Rights Laws and Regulations governing Environmental Protection as related to mining.
4.2.1 Mineral Tenure
The concessions have both rights and obligations as defined by an Organic Constitutional Law, enacted in 1982. Concessions can be mortgaged or transferred, the holder has full ownership rights, and is entitled to obtain the rights of way for exploration (pedimentos) and exploitation (mensuras).
Mining rights in Chile are acquired in the stages outlined in Table 4-1.
4.2.2 Mining Tax
A mining tax is calculated as a percentage of the Unidad Tributaria Mensual (UTM or monthly tax unit) and applies to each hectare of land included in the mining exploration or mining exploitation concessions. This tax is paid annually in a single payment before 31 March of each year.
For mining exploitation concessions, the tax rate is currently 10% of a UTM per hectare; for mining exploration concessions, the tax rate is currently 2% of a UTM per hectare. The value of the UTM is adjusted monthly according to the consumer price index (IPC) in Chile.
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Table 4-1: Mineral Title Types.
Mineral Title Size Validity Period Notes Type Minimum is Maximum period of Defined by UTM coordinates. New 100 ha, and two years. The claim pedimentos can overlap with pre-existing maximum is may be reduced in ones. However, the underlying 5,000 ha with size by at least 50% Pedimento (previously staked) claim always takes a maximum at the end of the precedent, providing the claim holder length-to- two-year period, and avoids letting the claim lapse due to a width ratio of renewed for an lack of required payments. 5:1 additional two years Before a pedimento expires, or at any stage during its two-year life, it may be converted to a manifestación. A manifestation may also be filed on any open ground without going through the pedimento filing process. Within 220 days of filing, the applicant must file a “Request for Survey” (Solicitud de Mensura) with the court of jurisdiction, including official publication Manifestación to advise the surrounding claim holders. The applicant may raise objections if they believe their pre-established rights are being encroached upon. The owner is entitled to explore and to remove materials for study only (i.e. the sale of the extracted material is forbidden). If an owner sells material from a manifestation or exploration concession, the concession will be terminated. Within nine months of the approval of the “Request for Survey” by the court, the claim must be surveyed by a government licensed surveyor. Surrounding claim owners may be present during the survey. Once surveyed, presented to the court, and reviewed by the National Mining Mensura Indefinite Service (Sernageomin), the court adjudicates the application as a permanent property right (a mensura), which is equivalent to a “patented claim” or exploitation right subject to the payment of annual fees. Once an exploitation concession has been granted, the owner can remove materials for sale.
4.2.3 Surface Rights
Ownership rights to the subsoil are governed separately from surface ownership. Articles 120 to 125 of the Chilean Mining Code regulate mining easements. The Mining Code grants to the owner of any mining exploitation or exploration concessions full rights to use the surface land provided that reasonable compensation is paid to the owner of the surface land.
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4.2.4 Rights of Way
The Mining Code also grants the holder of the mining concession general rights to establish a right of way (RoW), subject to payment of reasonable compensation to the owner of the surface land. Through a private agreement or legal decision, RoW is granted that indemnifies the owner of the surface land. A RoW must be established for a particular purpose and will expire after cessation of activities for which the right of way was obtained. The owners of mining easements are also obliged to allow owners of other mining properties the benefit of the RoW if this does not affect their exploitation activities.
4.2.5 Water Rights
Article 110 of the Chilean Mining Code establishes that the owner of the record of a mining concession is entitled, by operation of law, to use waters found in the works within the limits of the concession, as required for exploratory work, exploitation and processing, according to the type of concession in which the owner might engage. These rights are inseparable from the mining concession. Water is considered part of the public domain and is independent of land ownership. Individuals can obtain the right to use public water following the Water Code. Under the Code (updated in 1981), water rights are expressed in liters per second (L/s), and usage rights are granted based on total water reserves.
4.3 Ownership
The Project is held 100% by Marimaca Copper. Marimaca Copper has four Chilean subsidiaries that have actual, or eventual, rights over various mining properties that make up the Project:
Compañía Minera Cielo Azul Limitada (MCAL) Compañía Minera NewCo Marimaca (Newco Marimaca) Compañía Ivan SpA (Compañía Ivan) Minera Rayrock Limitada (Rayrock).
4.4 Agreements and Options
4.4.1 Newco Marimaca
Newco Marimaca owns the Marimaca 1 to 23 and Sor 1 to 16 concessions. Newco Marimaca was incorporated in September 2015 and has an initial 10-year term from the incorporation date. After the initial term, the company can be extended for two-year terms, unless the board of directors decides to wind up the company.
MCAL, and the shareholders of Newco Marimaca (referred to as the vendors), entered into an option agreement in November 2015, whereby MCAL could acquire a total 75% interest in Newco Marimaca. Under the Marimaca option agreement, the Marimaca 1 to 23 mining properties were assigned to MCAL. Newco Marimaca cannot assign or transfer royalty or mining rights to any third party. The Sor 1 to 16 concessions were not specifically stipulated as part of the Marimaca option agreement, and a second option agreement was concluded to include those claims as part of the Marimaca option package.
Under the option terms, MCAL was to acquire 51% of the total shares of Newco Marimaca for $185,000 and had to complete a feasibility study by 6 August 2018. This condition was met. To acquire the remaining 24% of the total shares of Newco Marimaca, MCAL had to pay $1,000, and either have obtained project construction financing, or have purchased a solvent extraction–electrowinning (SX/EW) plant capable of an annual production rate of no less than 1,500 t of copper cathode annually, and contributed this plant to Newco Marimaca, together
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with the surface rights over the plant location. The option contract was terminated by means of public deed dated February 14, 2020 as a consequence of the execution of the Marimaca Sales and Purchase Transaction.
The Marimaca Sales and Purchase Transaction provided for MCAL and a second Marimaca Copper subsidiary, Inversiones Cielo Azul Limitada (ICAL) to purchase the total amount of Newco Marimaca shares issued. The two-company ownership structure is a result of Chilean law that states that Contractual Mining Corporations (Sociedad Contractual Minera) such as Newco Marimaca may not have less than two shareholders.
The price to acquire the remaining 49% interest in Newco Marimaca that MCAL/ICAL did not hold was $12 M, to be paid in tranches, as follows:
First payment: $6 M on the date of signing of the Sales and Purchase Transaction; this was paid on 14 February 2020 (paid) $3 M within 20 months of the date of signing of the Sales and Purchase Transaction $3 M within 24 months of the date of signing of the Sales and Purchase Transaction.
Marimaca Copper, through its subsidiaries, currently owns 100% of Newco Marimaca.
Sociedad Contractual Minera Elenita and Newco Marimaca entered into a mining concession sales and purchase agreement for the Sello Nueve concession. MCAL paid $1,000 at the execution of the sales and purchase public deed.
4.4.2 Inversiones Creciente Limitada
MCAL entered into a 36-month option agreement during October 2017 with Inversiones Creciente Limitada (Inversiones Creciente) to purchase the La Atomica 1 to 10 concessions. The agreement will expire on 14 November 2020.
MCAL will acquire 100% of the La Atómica claims for a total of $6 M with the following payment schedule:
$20,000 before signing the agreement (paid) $80,000 at the signature of the option agreement (paid) $500,000 on November 14, 2018 (paid) $500,000 on November 14, 2019 (paid) $500,000 on March 14, 2020. There is an associated monthly interest of 0.75% between November 2019 and March 2020, approximating to $15,000 that must also be paid (paid) $1 M on November 14, 2020. $1.055.230 on May 14, 2021. $2.648.586 on November 14, 2021.
A third party, Manuel Abel Segovia Aguirre Servicios Mineros E.I.R.L., has an existing extractive agreement with Inversiones Creciente. MCAL has allowed the operations to continue with the following provisos:
Mining must not exceed 2,000 t per month Material mined must be sent to Empresa Nacional de Minería (ENAMI)
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Mining activities cannot impede Marimaca Copper’s exploration activities. When the La Atómica purchase is concluded, workers must leave, and the La Atómica 1 to 10 concessions must be delivered to Marimaca Copper free of all contracts or other encumbrances.
4.4.3 Capax SA
MCAL entered into a sales and purchase agreement on 3 August, 2018 with Capax SA (Capax) for the Anta María Uno 1 and 2, Santa María Dos 1 to 2, Vida Dos 1 to 17, Inca 1 to 2, Sorpresa 1 to 10, Sorpresa II 1 to 15, Atahualpa 1 to 2, Truska Uno 1 to 9, and Truska Dos 1 to 20 (reduced to Truska Dos 1 to 12) concessions.
The purchase price was $5.8 M, consisting of:
$100,000 payable prior to the execution of the sales and purchase agreement (paid) $5.7 M paid as at the execution date of the sales and purchase agreement (paid).
A second sales and purchase agreement was concluded with Capax on 18 March 2019, for 50 shares in Sociedad Legal Minera Rodeada Uno del Mineral de Naguayán (SLM Naguayán). SLM Naguayán is the sole owner of the Rodeada Uno to Tres concessions. Commercial considerations included $200,000 payable on execution of the agreement. The 50 SLM Naguayán shares are currently registered to MCAL.
4.4.4 Compañía Minera Naguayán S.C.M.
MCAL entered into a sales and purchase agreement on 3 January 2018, amended 28 November 2019, with Compañía Minera Naguayán S.C.M. (Minera Naguayán) for the Roble 1 1 to 10, Olimpo 1 to 20, Tarso 1 to 13, Macho 1 to 20, San Lorenzo 1 to 10, Sicilia 1 to 20, San Patrick 1 to 20, Morencia 1 to 20, Nepal 1 to 20, to 20 and Cedro I 1 to 20 concessions. The option term will expire 3 January 2022.
The option agreement was subject to $6.5 M in payments, as follows:
$200,000 on the date the option was signed (paid) $300,000 on 3 January 2019 (paid) $400,000 on 3 January 2020 (paid) $300,000 on 13 April 2020 plus an interest payment of 0.03% per month for the January to April 2020 period, equating to about $9,227 (paid) $554.639 on 1 February, 2021. $205.966 on 12 April, 2021. $1.085.660 on 5 October, 2021. $3.55 M on 3 January 2022.
Minera Naguayán had existing extraction contracts concluded with a number of third parties.
MCAL has allowed the operations to continue with the following provisos:
Mining must not exceed 2,000 t per month Material mined must be sent to ENAMI Mining activities cannot impede Marimaca Copper’s exploration activities.
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When the Minera Naguayán purchase is concluded, workers must leave, and the Roble 1 1 to 10, Olimpo 1 to 20, Tarso 1 to 13, Macho 1 to 20, San Lorenzo 1 to 10, Sicilia 1 to 20, San Patrick 1 to 20, Morencia 1 to 20, Nepal 1 to 20, to 20 and Cedro I 1 to 20 concessions must be delivered to Marimaca Copper free of all contracts or other encumbrances.
4.4.5 Proyecta S.A. and Sociedad Contractual Minera Proyecta
MCAL entered into an option to purchase agreement on 6 May, 2019, with Proyecta S.A. and Sociedad Contractual Minera Proyecta over the Mercedes Dos 1 to 6, Llano 15 1 to 15, Llano 16 1 to 15, Llano 17 1 to 35, Llano 18 1 to 36, Llano 19 1 to 40, Llano 20 1 to 46, Llano 21 1 to 50, Llano 22 1 to 50, Llano 23 1 to 50, Llano 24 1 to 10, Llano 25 1 to 10, Llano 26 1 to 2, Llano 29 1 to 10, Llano 31 1 to 5, and the Llano 33 1-20 concessions.
The commercial terms were a fixed $2 M purchase price, payable as follows:
$50,000 to meet conditions precedent (paid) $50,000 on 6 September 2020 (paid) $50,000 on 6 May 2021 $100,000 on 6 November 2021 $125,000 on 6 May 2022 $125,000 on 6 November 2022 $1.4 M on 6 May 2023.
4.4.6 Rayrock Antofagasta S.A.C. and Compañía Minera Milpo S.A.A
MCAL entered into a sales and purchase agreement on 8 June 2017 with Rayrock Antofagasta S.A.C. and Compañía Minera Milpo S.A.A to acquire the Notable Uno 1 to 30, Terrible 1 to 143, Deses V 1 to 27, and Junto 1 to 10 concessions. Under this agreement, MCAL acquired 99.9% of the interest of Minera Rayrock Limitada (Rayrock) and Pablo Mir Balmaceda acquired 0.1% of the total interest of Rayrock. The transfer of the Rayrock’ s interest was distributed as follows:
Rayrock Antofagasta S.A.C. sold 15.82% in Rayrock to MCAL for $983,748.06. Compañía Minera Milpo S.A.A. sold 84.08% in Rayrock to MCAL for $5,228,415.78
MCAL, Rayrock Antofagasta S.A.C. and Compañía Minera Milpo S.A.A. entered into a frame agreement that provided the details for the transfer of rights in Rayrock from Rayrock Antofagasta S.A.C. and Compañía Minera Milpo S.A.A. to MCAL.
The Rayrock shareholders agreed to form a spinoff company, Compañía Iván Limitada, where the shareholders were MCAL (99.9%) and Pablo Mir Balmaceda (0.1%). On 16 March 2019, Pablo Mir Balmaceda transferred his interest to MCAL, such that MCAL now holds 100% of Compañía Iván Limitada.
4.5 Mineral Tenure
Through direct acquisition and option agreements, Marimaca Copper holds 100% of 385 granted concessions and concession applications, covering an area of 74,248 ha. These are, for convenience, divided into two packages:
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Marimaca area: 265 claims (62,568 ha) held in the names of the following Marimaca Copper subsidiaries: Compañía Minera Cielo Azul Limitada, Compañía Minera Naguayán SCM, Sociedad Contractual Minera NewCo Sociedad Legal Minera Rodeada Uno, Proyecta S.A. and Sociedad Contractual Minera Proyecta Iván area: 120 claims (11,680 ha) held in the names of Minera Rayrock Limitada or Compañía Minera Cielo Azul Limitada.
A list of the claims that make up the two packages are provided in Appendix A. A summary figure of the mineral tenure holdings is included as Figure 4-1. An inset figure showing the mineral tenure in the location of the proposed pit is included as Figure 4-2
As part of the grant process, the concessions have been surveyed by a government-licensed surveyor.
Under the option terms outlined in Section 4.4, Marimaca Copper is responsible for paying any annual mining licence fees applicable under Chilean laws, and for protecting and maintaining the mining concessions. Marimaca Copper advised NCL that all concession fees were current as of 4 September 2020, and will continue to be paid regularly as due, using a formal status tracking system.
4.6 Surface Rights
The surface land in the Commune of Mejillones is owned by the State and managed and represented by the Ministerio de Bienes Nacionales.
Marimaca Copper has developed a strategy to obtain the necessary surface rights to cover mine, plant, tailings storage facilities and transmission lines.
Marimaca Copper currently has a provisional mining legal easement, and the process to formally grant the easement for a 30-year term is underway. The easement covers 4,465 ha (Figure 4-3) and includes the underlying Miranda I 1 to 146, Miranda II 1 to 30, Miranda III 1 to 130, Miranda IV 1 to 48, Chacaya 1 1 to 200, Chacaya 3 1 to 300, Chacaya 5 1 to 100, Chacaya 7 1 to 300, Chacaya 10 1 to 300, Chacaya 11 1 to 200 and Chacaya 12 1 to 300 concessions.
Marimaca Copper has applied for a second easement, shown in Figure 4-4 This easement covers Marimaca 1-23, La Atomica 1-10 and Atahualpa group.
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Figure 4-1: Total Mineral Tenure Holdings
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 4-2: Mineral Tenure, Proposed Open Pit Location
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 4-3: Marimaca Project Provisional Easement
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 4-4: Easement Application
Note: Figure prepared by Marimaca Copper, 2020. Vertices solicitud de servidumbre = vertices of the easement application; solicitud de servidumbre = easement boundary; concesiones exploitatción Marimaca Copper = exploitation licences held by Marimaca Copper; concesiones exploración Marimaca Copper = exploration licences held by Marimaca Copper; norte = north.
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4.7 Water Rights
Marimaca Copper holds no water rights in the Project area. Water assumptions for the purposes of the 2020 PEA are discussed in Section 18.
For current exploration and testworks water is taken to site as per required by trucks. For the project seawater will be provided by Aguas de Antofagasta S.A. (ADASA), a major Chilean water supplier
4.8 Royalties
As noted in Section 4.2.2, a mining tax applies to each hectare of land included in the mining exploration or mining exploitation concessions.
As a result of the various option agreements, the Project is subject to the following royalties.
4.8.1 Newco Marimaca
A 1.5% net smelter return (NSR) royalty is payable on the sale or transfer of the minerals, metals, or other mineral products (refined or not) from the Marimaca 1 to 23 and Sor 1 to 16 concessions.
MCAL has the right to purchase 1% of the royalty (leaving a 0.5% royalty payable) within 24 months of the start of commercial production from the concessions. The fee payable is $4 M. MCAL also has the right of first refusal to purchase the royalty if a third party makes an offer for the royalty and must match the third-party offer.
4.8.2 Inversiones Creciente
A 1.5% NSR royalty is payable on sale or transfer of the minerals, metals, or other mineral products (refined or not) from the La Atómica 1 to 10 concessions.
MCAL has the right to purchase 0.5% of the royalty (leaving a 1% royalty payable) at any time after the option to purchase the concessions is exercised, for $2 M.
4.8.3 Capax
A 2% NSR royalty is payable on sale or transfer of the minerals, metals or other mineral products (refined or not) from the Anta María Uno 1 and 2, Santa María Dos 1 to 2, Vida Dos 1 to 17, Inca 1 to 2, Sorpresa 1 to 10, Sorpresa II 1 to 15, Atahualpa 1 to 2, Truska Uno 1 to 9, and Truska Dos 1 to 20 (reduced to Truska Dos 1 to 12) concessions.
A 2% NSR royalty is also payable on sale or transfer of the minerals, metals or other mineral products (refined or not) from the Rodeada Uno to Tres concessions.
4.8.4 Minera Naguayán
A 1.5% NSR royalty is payable on sale or transfer of the minerals, metals or other mineral products (refined or not) from the Roble 1 1 to 10, Olimpo 1 to 20, Tarso 1 to 13, Macho 1 to 20, San Lorenzo 1 to 10, Sicilia 1 to 20, San Patrick 1 to 20, Morencia 1 to 20, Nepal 1 to 20, to 20 and Cedro I 1 to 20 concessions.
MCAL has the right to purchase 0.5% of the royalty (leaving a 1% royalty payable) after the option to purchase the concessions is exercised, and within 12 months of commercial production from the concessions, for $2 M. Minera Naguayán cannot transfer the 0.5% royalty to a third party while the MCAL right to purchase is in force.
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MCAL also has the right of first refusal to purchase the remaining 1% royalty if a third party makes an offer for the royalty and must match the third-party offer.
4.8.5 Proyecta S.A. and Sociedad Contractual Minera Proyecta
A 1% NSR royalty is payable on sale or transfer of the minerals, metals or other mineral products (refined or not) from the Mercedes Dos 1 to 6, Llano 15 1 to 15, Llano 16 1 to 15, Llano 17 1 to 35, Llano 18 1 to 36, Llano 19 1 to 40, Llano 20 1 to 46, Llano 21 1 to 50, Llano 22 1 to 50, Llano 23 1 to 50, Llano 24 1 to 10, Llano 25 1 to 10, Llano 26 1 to 2, Llano 29 1 to 10, Llano 31 1 to 5, and the Llano 33 1-20 concessions.
MCAL can purchase the entire NSR royalty within 24 months of the commencement of commercial production from the concessions for $500,000. Proyecta S.A. and Sociedad Contractual Minera Proyecta cannot transfer the royalty to a third party while the MCAL right to purchase is in effect.
4.8.6 Rayrock
The Rayrock Notable Uno 1 to 30, Terrible 1 to 143, Deses V 1 to 27, and Junto 1 to 10 concessions are subject to either a 1.5% NSR or 2% NSR royalty, payable to Compañía Minera Milpo S.A.A. Once a concession is in production, the royalty payments must be made every three months.
The 1.5% NSR royalty is payable on concessions which had an underlying royalty granted to J. Hunt on 3 January 1994, and to J. Hunt and J. Hunt Resource Associates on 1 September 1994.
The 2% NSR royalty is payable on all of the other concessions.
4.9 Permitting Considerations
The Project permitting status is discussed in Section 20.
4.10 Environmental Considerations
The Project environmental status is provided in Section 20. At current moment there is no environmental liabilities identified.
4.11 Social Licence Considerations
The current Project social licence status is outlined in Section 20.
4.12 Comments on Section 4
The QP was provided with legal opinion and information from Bofill Mir & Alvarez Jana and experts retained by Marimaca Copper that supports:
Marimaca Copper holds 100% of the Marimaca Project Marimaca Copper is the Project operator The mineral tenure held is valid and is sufficient to support the declaration of Mineral Resources Marimaca Copper currently has a provisional mining legal easement, and the process to formally grant the easement is underway. Royalties in the form of the Chilean mining tax will be payable
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The Project is subject to several third-party NSR royalties on individual claims, which range from 1–2%, depending on the claim block and applicable option agreement
The QP is not aware of any issues that may affect access, title, or the right or ability to perform work on the Project that are not discussed in this Report.
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5 Accessibility, Climate, Local Resources, Infrastructure and Physiography
5.1 Accessibility
Antofagasta and Mejillones are the closest major centres and are connected by a well- maintained multi-lane highway. The Marimaca Project is accessible by well-maintained dirt roads, one coming from the Cerro Moreno Airport in Antofagasta and the other branching off Route Antofagasta–Tocopilla.
The Antofagasta regional airport is serviced by regional and international flights from Santiago and other destinations daily. The regional Antofagasta Cerro Moreno airport is located 45 km to the south-southwest of the Project location.
High voltage lines that transport energy from the power stations located in Mejillones are also close to the main highway.
5.2 Local Resources and Infrastructure
Antofagasta and Mejillones are modern port cities with all regular services, serving a combined population of approximately 570,000. Numerous mining-related businesses are located in the cities.
Personnel employed by Marimaca Copper mainly come from the Antofagasta region.
There are power lines and water desalination plants in reasonable proximity to the Project.
Mejillones is a mega-port for larger cargo. In addition, there are five thermoelectric plants and the most important sulphuric acid terminal in the north of the country. The installed capacity of electric production currently available at Mejillones is closed to 900 MGW, while the sulphuric acid storage facilities have a capacity of more than 6 Mt/y.
Infrastructure considerations for the PEA are outlined in Section 18.
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Figure 5-1: Key Regional Infrastructure
Note: Figure prepared by Marimaca Copper, 2020.
5.3 Climate
The Project is located about 39 km north of the Tropic of Capricorn. The minimum temperatures vary between 10–15° C and the maximum temperatures between 20–29° C, while the average relative humidity oscillates between 67–70%.
The climate is dry, and the average annual rainfall is 2–3 mm as an annual average over 24 hours. However, storm events can occur, and may result in precipitation of 12–30 mm in a few hours.
5.4 Physiography
The Marimaca Project is located in the Cordillera de la Costa, a mountainous area, with relief ranging from 400–1,000 m.a.s.l. (Figure 5-2).
Vegetation is minimal outside of inhabited valleys where irrigation is used, and areas where the “Camanchaca” sea mist that comes from the nearby ocean supports vegetation that is capable of withstanding the desert environment.
The Mejillones and Naguayán quebradas drain the Project area from east to west and south to north, respectively. The Project is located in an active seismic zone.
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Figure 5-2: Physiography of the General Project Area
Note: Figure prepared by Marimaca Copper, 2020, The figure has a vertical exaggeration of 3x. View toward northeast. CCF = coastal cliff; MP = Mejillones Peninsula.
5.4.1 Comments on Section 5
The existing local infrastructure, availability of staff, and methods whereby goods could be transported to the Project area to support exploration activities are well understood by Marimaca Copper and can support the declaration of Mineral Resources.
The Project covers an area that is sufficient for infrastructure requirements to support a mining operation.
Surface rights are discussed in Section 4.7.
Mining operations in the region are conducted year-round, and it is expected that any operation conducted by Marimaca Copper would also be year-round.
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6 History
6.1 Project History
The Project is located in the “Mineral de Naguayán” district
Small-scale artisanal mining activities were undertaken in the Project area from the 1990s to the mid-2000s. Underground mining and small pits may have produced around 100,000 t of copper oxides between 1–2% of copper. The pits have dimensions of 20 by 15 m getting 20 m in depth. Underground workings are at maximum of 100 m deep. Most of the artisanal production was sold to Minera Michilla SA, ENAMI, and Minera Rayrock Ltda.
During the second half of the past century the Institute of Geological Investigations and ENAMI reported copper oxide mineralization hosted within north–south trending fracture systems. During the early 2000s, a number of junior mining companies inspected the area, but no one undertook further investigations.
The modern exploration in the area had not been conducted until Marimaca Copper Mining now Marimaca Copper, assembled the Project tenure. The Marimaca 1 to 23 claims that cover the main area were staked in 1979.
In April 2016 as result of the reverse circulation (RC) drill program Marimaca was discover. Subsequent, detailed geological surface mapping and rock chip sampling, additional RC, core drilling, geotechnical and geometallurgical studies, metallurgical testworks, and mining studies has been executed. An initial resource estimate was completed in January 2017, and Mineral Reserves were first estimated in 2018.
Coro completed a feasibility study in June 2018 (the 2018 Feasibility Study). This study considered an open pit mining using conventional equipment to feed a refurbished process plant, referred to as the Ivan plant, that would have the capability of producing 10,000 t of cathode copper per year.
The 2018 Feasibility Study is not currently considered to be the preferred Project development option. Marimaca Copper is not treating the study as current, and the Mineral Reserve estimates are also not considered to be current. However, some of the baseline information generated in support of the 2018 Feasibility Study is used in the 2020 PEA.
An Environmental Impact Statement (Declaración de Impacto Ambiental, DIA) and the Mining Safety Regulations and Environmental Qualification Resolution (RCA) was approved on 5 July 2018.
Mineral Resources were updated in late 2019, and that estimate is discussed in Section 14.
Marimaca Copper changed its name to Marimaca Copper in May 2020.
A PEA was completed in 2020, and the results of that study are summarized in this Report.
6.2 Production
No formal production has occurred from the Project area.
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7 Geological Setting and Mineralization
7.1 Regional Geology
The regional geology consists of Jurassic volcanic and intrusive rocks (Figure 7-1), with minor older Triassic acid volcanic occurrences, intermediate intrusive units, sediments and Paleozoic metamorphic rocks. The main regional structure is the Atacama Fault System (AFS) which forms the eastern border of the Coastal Cordillera in the region.
The regional metallogeny is dominated by the occurrence of Cu–Ag “manto-type” deposits that have iron oxide–gold–copper (IOGC) affinities. The classic “manto-type” deposits (e.g. Buena Esperanza, Michilla, Mantos de la Luna, Ivan and Mantos Blancos) are hosted in volcanic rocks that have similar morphologic and mineralization–alteration characteristics, although each deposit has its own particular litho-structural mineralization control. There are also examples of vein-related deposits hosted in intrusions, such as Minitas, Tocopilla, Gatico, Naguayán, Montecristo, that also have IOCG affinities.
The oldest exposed rocks are metasedimentary and intermediate intrusions of late Paleozoic and Triassic age. Early Jurassic to lower Cretaceous age diorite, monzonite and monzodiorite, with lesser gabbro, quartz monzonite and metadiorite, bodies intrude the earlier rocks. These are in turn intruded by bi-modal gabbro to rhyodacite dyke swarms. The dyke swarms have variable orientations, ranging from oldest to youngest, from northeast–southwest to north– south, to northwest–southeast. The dykes are associated with the regional IOCG mineralizing systems.
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Figure 7-1: Regional Coastal Cordillera Geology
Note: Figure prepared by Marimaca Copper, 2020. PG: Puntillas-Galenosa; MCh: Michilla; AN: Antucoya; IZ: Ivan- Zar; MB: Mantos Blancos; JM: Julia-Montecristo). The letter “M” is the location of the Marimaca Project. SudAmerica = South America, Oceano Pacifico = Pacific Ocean, Sistema De Faltas de Atacama = Atacama Fault Zone.
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Overlying all the earlier units along the coastal plain/Mejillones Peninsula are Tertiary-age marine sediments.
To the west of the AFS, the Naguayán Banded Fracture Belt (NBFZ) forms an approximately 15 km long and 3 km wide zone of sub-parallel fractures that trend north–south to north– northeast, dipping at 40–60º to the east or southeast. The rhyodacitic-composition regional dyke swarm end members are preferentially associated with the NBFZ.
A key aspect of regional metallogenesis is the post-Cretaceous geomorphological and climatic evolution that permitted the generation of deep columns of supergene enrichment and oxidation.
7.2 Project Geology
The local geology consists of monzonite, diorite and monzodiorite intrusions correlated with the Naguayán Plutonic Complex, and dykes belong to the regional bimodal dyke swarm.
Mineralization in the Marimaca area has formed in association with the fractures of the NBFZ, and in association with north–south to northeast-oriented “feeder” zones or vein-like structures. It consists of chalcopyrite, moderate to minor pyrite, minor bornite, covellite and primary chalcocite forming massive bodies, zones of replacement and fracture fills. A copper oxide blanket overlies the primary mineralization, which resulted from the alteration of a secondary sulphide-enriched blanket that produced a chemical zonation from brochantite to atacamite at the core of the alteration zone, with a surrounding outboard halo of predominantly chrysocolla, followed by a wad halo.
Figure 7-2 and Figure 7-3 are overview illustrations showing the surface extension of the copper oxide blanket, as expressed by the >0.1% Cu limit from surface mapping, and the eastern limit of alteration, referred to as the hanging wall alteration or “Red Cap”.
Figure 7-2: Project Overview (northeast view)
Note: Figure prepared by Marimaca Copper, 2020. Panoramic view looking northeast, the >0.1% Cu boundary as light-yellow dashed line, and the hanging wall alteration as the darker yellow dashed line. The highest peaks are 1,100 m elevation; the lowest is about 900 m elevation.
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Figure 7-3: Project Overview (south view)
Note: Figure prepared by Marimaca Copper, 2020. Panoramic view looking south showing the main mineralized zones, the >0.1% Cu boundary, and the hanging wall alteration front. The northern limit of mineralization corresponds to a northwest-trending fault that can be observed on the hill above the hanging wall alteration marker.
7.3 Deposit Description
7.3.1 Lithologies
The principal rock types are summarized in Table 7-1. A deposit geology plan is included as Figure 7-4 and a cross-section through the geology is provided in Figure 7-5.
7.3.2 Structure
The key structural elements in the Project area are summarized in Table 7-2.
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Table 7-1: Lithology Summary
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Figure 7-4: Sub-Surface Interpreted Geology Plan
Note: Figure prepared by Marimaca Copper, 2020, after Kovacic, 2017 and IMG, 2019.
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Figure 7-5: Cross-Section NE 100, Showing Litho-Structure (a) and Mineralization (b)
Note: Figure prepared by Marimaca Copper, 2020. Sections are oriented at 220°to the southeast.
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Table 7-2: Structure Summary
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The NBFZ is characterized by decametric sub-parallel fractures that show different types of penetration, filling, spacing and persistence. Fractures can be filled with a clay or limonite gouge.
Feeder faults range from a few centimetres to 10 m in thickness. Strong supergene alteration, limonite staining. and fracture filling as well as copper oxide mineralization are characteristics of the feeder-fault zone. The most prominent feeders close to the hanging wall alteration front, towards the east, display a white clay (albite–sericite) halo. In the central part, hematite-rich fringes and chlorite–hematite halos are common.
Veins are typically 1–3 m wide. In the supergene zone, these have iron oxide fill, and often surrounded by a chlorite halo. At depth, below the oxidation zone, the fill is magnetite. Where associated with dykes, the vein alteration halo is typically actinolite. Veins carrying tourmaline and quartz are common at Atahualpa.
Post-mineral faults are typically northwest-trending, vertical faults, and are associated with late-stage dyke emplacement. Five major zones of associated dyking and northwest-trending faults have been defined (Figure 7-6). These appear to control the supergene alteration and mineralization and influence the orientation of the oxide blanket. The faults are interpreted to divide the mineralized body into discrete panels with different structural orientations, which was used to separate structural domains for resource estimation.
7.3.3 Alteration
The hypogene background alteration consists of calcic–sodic metasomatism.
Alteration related to mineralization consists of development of actinolite and magnetite, with lesser chlorite, sericite, and hematite, that is associated with veins, feeders and banded rocks. The diorite unit has undergone biotite–magnetite replacement. Tourmaline has been observed related to the main feeder veins within the Atahualpa and La Atómica zones.
A major alteration feature is the so-called hanging wall alteration front, which controls the mineralization toward the “top” of the parallel-fractured monzonite and diorite units and the mineralization associated with dykes. Hematite, in association with sericite and pyrite, forms band replacements and veins. The feeders that crosscut the alteration limit displays a well- developed “argillic” halo.
Supergene oxidation has resulted in the formation of limonite, clays, and copper oxides. Goethite and hematite stain fractures or fill open fractures. Iron oxides can be associated with clay, gypsum and rock flour within fault gouge. Jarosite can occur in the halo of some of the northwest-trending faults zones in the southern part of the Project area.
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Figure 7-6: Structural Zones
Note: Figure prepared by Marimaca Copper, 2020. Figure shows structural zones superimposed on Project geology plan. In each zone, the figure in red is a strike rosette plot, and the sphere is a pole weighted contour plot. Black lines demarcate the zone extents.
7.3.4 Mineralization
The Marimaca deposit consists of a supergene copper blanket (oxides and enriched sulphides). Table 7-3 summarizes the characteristics of the main mineralization zones.
The oxide zone is exposed on surface, and has dimensions of about 1.4 km long, 400–600 m in width, and a thickness that ranges from 150–350 m. The shape of the oxide zone is controlled by the parallel fracture system and dikes, with the deeper zones of oxidation typically related to northwest-trending faults. However, the rhyodacitic dykes also have a role in the location of higher copper grade zones, in combination with feeders and veins.
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Figure 7-7 shows the distribution of the principal copper oxide mineralized zones, projected to surface, while Figure 7-8 is a cross-section showing the mineralization distribution. Most of the copper oxides occur as fracture staining and infill within fracture-veins and veinlets. Minerals in the upper copper oxide zone are typically zoned, extending outwards from brochantite, atacamite, chrysocolla and finally wad-rich zones. The brochantite zone contains more than 60% of the brochantite and or atacamite and 30–35% of chrysocolla, and forms high-grade cores. The chrysocolla zone borders the brochantite zone, and typically has >60% chrysocolla. The wad zone is the outermost zone, with the lowest copper grades, and typically displays about 90% non-green copper oxides.
The oxide zone grades into a mixed zone of oxide and sulphide materials. Chalcocite and covellite can occur as both primary and secondary sulphides, forming fracture stains, sulphide coatings, and massive replacement in breccias or veins (bands).
At depth, the primary mineralization is chalcopyrite in association with pyrite. The primary zones are not well defined due to the lack of drill data at depth.
The oxide blanket is better preserved in the southern part of the deposit area. Towards the north and east, it has been partially eroded, resulting in most of the wad and chrysocolla capping being removed. Brochantite that has been altered to atacamite crops out and has a more irregular distribution that is interpreted to be related to the main feeders and veins. Chrysocolla is better preserved closest to the surface at Marimaca, and within some ridges to the north.
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Table 7-3: Mineral Zone Summary
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Figure 7-7: Sub-Surface Mineralization Map
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 7-8: Cross-Section Showing Mineralization, Section NW 400
Note: Figure prepared by Marimaca Copper, 2020. Lix = Leachable
Figure 7-9: Cross-Section Showing Mineralization, Section NW 650
Note: Figure prepared by Marimaca Copper, 2020. Lix = Leachable
Wad is more consistently present towards the deposit eastern and northern margins and has been partially projected down-dip below the hanging wall alteration zone. Mixed zones are irregularly preserved in all of the oxide blanket area. The enriched zone is well preserved in the central part of the blanket.
An idealized schematic model of the deposit is provided in Figure 7-10, showing the precursor sulphide bodies in relation to the development of the oxide blanket.
7.4 Comments on Section 7
In the opinion of the QP, the geological, structural, alteration and mineralization data are sufficient to support Mineral Resource estimation.
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Figure 7-10: Deposit Model Schematic
Note: Figure prepared by Marimaca Copper, 2020. Idealized east–west section. MZD: monzodiorite; DIO: early diorite; MzdP: Monzodiorite Porphyry; PDA: dacitic dike. Sulphide mineralized bodies in red. Oxide blanket in green.
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8 Deposit Types
8.1 Overview
The Marimaca deposit appears to be a new deposit style and does not readily conform to any of the major published geological models.
The deposit occurs in a district that has a number of vein-style IOCG deposits, which have common features including regional metamorphism/metasomatism, Ca–Na alteration, the presence of magnetite and hematite, chalcopyrite as the major copper-bearing mineral, and an overall low sulphide content (Sillitoe, 2003; Richards and Mumin, 2013). The Marimaca deposit setting includes some of these elements.
However, Marimaca also has affinities with “manto-type” mineralization styles, although the monzodiorite mineralization host is unusual, since the known manto-type deposits are typically associated with volcanic piles. If the host rock issue is not taken into consideration, Marimaca is analogous to manto-type copper deposits such as Mantos Blancos (Chavez, 1983) or El Soldado (Boric et al., 2002). The critical role of structures, dykes, and alteration zoning is a common feature in these deposits. The deep and extensive development of supergene alteration and oxidation is similar to that seen at Mantos Blancos.
The sulphide and alteration mineralogy at Marimaca resemble those encountered within IOCG systems; however, the lack of iron oxides and gold and the occurrence of hypogene chalcocite and covellite are not common in IOCG deposits (Richards and Mumin, 2013). These features appear to be more frequent in the “manto-type” deposits. In alteration terms, Marimaca appears to be a hybrid of the manto-type and IOCG deposits.
8.2 Comments on Section 8
Exploration models that use features of the IOCG and manto type deposit styles, based on the information available on Marimaca to date, are likely to be applicable to future exploration activities.
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9 Exploration
Marimaca Copper is currently refining the geological interpretation and model for the Marimaca deposit with a focus on the sulphide potential below the Marimaca deposit and in the areas immediately surrounding the deposit. This work includes reassessing historical drilling data, remapping, sampling and, geophysical campaigns including drone-mounted magnetometry and induced polarization (IP) surveys, to assist with drill target identification to identify potential exploration targets for follow up drilling towards the end of 2020.
A preliminary scout drilling program was completed during the latter part of 2019,. which included 31 RC drill holes targeting the identification of new, near-surface, oxide mineralized copper zones to the north and south of the Marimaca deposit. A total of 27 out of the 31 drill holes encountered zones of oxide copper mineralization that supports additional follow up drilling. Several broad zones of copper mineralization were encountered that were higher- grade than the cut-off grade used in Section 14 for the Marimaca resource estimate.
The Marimaca alteration zone was found to extend for over 10 km across the Project area.
The Marimaca Project remains open to the north and south and at depth. Exploration potential for oxide copper deposits exists within Marimaca Copper’s extensive land holdings.
Based on a preliminary scout drilling program, the results appear to demonstrate structures carrying copper mineralization which may be an expression of Marimaca-style mineralization at depth.
The timeframe for any additional drilling campaigns is dependent on obtaining a Prospecting Environmental Impact Declaration (DIA in the Spanish acronym). The permitting process is underway and is expected to be concluded in late Q3 or early Q4 of 2020.
9.1 Surveying, Imagery and Topographic Base
The topographic base consists of a photographic and photogrammetric survey, using drone technology and digital cameras. The flight resolution was 8–13 cm per pixel, and a digital elevation model (DEM) was generated with interpolated curves at 1 m for use at a 1:1,000 scale. The topographical support is based on conventional topography, which, from official bases, generated a sufficient network of points to balance and orthorectify the image and DEM. The base uses PSAD 56 UTM coordinates. Figure 9-1 shows where the regional survey control points are located (a). It also provides examples of a registered control point (b) and the Atahualpa 1 1/154 co-ordinate base point (c).
The topographic base was updated during 2019. This was merged with the previous base and generated the topography surface used to constrain the Mineral Resource estimate in Section 14.
Underground workings were surveyed, using conventional survey instrumentation. Surveyed lines were used to generate tunnel-solids that were, in turn, used to deplete the resource estimate for the mined voids. An example of the resulting survey data showing the locations of the mined areas is provided in Figure 9-2.
Figure 9-1: Examples of Surface Survey Control
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Note: Figure prepared by Marimaca Copper, 2020.
Figure 9-2: Underground Workings
Note: Figure prepared by Marimaca Copper, 2020. Figure looks towards northeast.
9.2 Geological Mapping
A detailed surface geological map at 1:1,000 scale was completed by Investigaciones Mineras y Geológicas Ltda. (IMG) in 2017 (Kovacic, 2017), which was subsequently updated and
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extended by Marimaca Copper personnel (refer to Figure 7-4). A less detailed 1:5,000 scale was also used on occasion.
Underground workings were mapped and sampled. An example of the resulting mapping is provided in Figure 9-3.
Figure 9-3: Example Underground Geological Mapping
Note: Figure prepared by Marimaca Copper, 2020.
9.3 Geochemical Sampling
A program of road cut sampling was conducted in 2018–2019. Continuous chip samples were taken at 2 m intervals, for a total of 5,120 m of sampling. Sample locations are shown on Figure 9-4. Chip sampling, at 2 m intervals, was also conducted in the underground workings, with 8,028 m sampled. Sample locations are shown on Figure 9-5. The sampling indicated the areas of significant copper anomalism that could be further tested by drilling.
Reconnaissance rock chip sampling was conducted on an approximate 100 x 100 m grid, with sample locations recorded using a hand-held global positioning system instrument (GPS), and reported using PSAD56 UTM coordinates. The 200 ppm and 500 ppm copper contours shown in Figure 9-6 are co-incident with the oxide blanket. Other copper anomalies located above and below the hanging wall alteration zone are interpreted to be either veins or feeders.
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Figure 9-4: Surface Road-Cut Channel Chip Sample Location Plan
Note: Figure prepared by Marimaca Copper, 2020.
Figure 9-5: Underground Channel Chip Sampling Location Plan
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 9-6: Copper Geochemistry
Note: Figure prepared by Marimaca Copper, 2020. Orange line = 200 ppm copper contour; purple line = 500 ppm copper contour; dashed red outline is the outline of the copper block model.
9.4 Geophysical Surveys
Geophysics was not used as an exploration tool during the initial work program that discovered the Marimaca deposit. However, to determine if there was a relationship between mineralization at depth and high magnetite contents, a high-resolution aeromagnetic survey was carried out in 2016 using GeoMagDrone™ technology.
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Figure 9-7 shows the pole-reduced ground magnetics with the >0.1% Cu outline superimposed. A magnetic high lying adjacent to the eastern part of the deposit corresponds to the interpreted down-dip extensions of the mineralization below the hanging wall alteration zone. The easternmost drill holes in this area intercepted diorite that displayed intense magnetite–biotite alteration and disseminated sulphides, chiefly pyrite.
Figure 9-7: Pole Reduced Ground Magnetic Plan
Note: Figure prepared by Marimaca Copper, 2020. Magnetics shown in relation to (a) drill hole grid and (b) Cu block model projected to surface. Red dashed line is the 0.1% Cu outline.
Marimaca Copper completed a drone-mounted, high resolution, magnetic survey in 2020, over an area of 2 by 2 km which is directly over the Marimaca deposit and its immediate surrounding area. The results show a large magnetic anomaly adjacent to and underlying the current projection of Mineral Resource estimate continuity. The magnetic anomaly, which extends to at least 700 m depth below the mineralized area, appears to be controlled by the west–northwest-trending Manolo fault.
A representative east–west cross section is shown in Figure 9-8 demonstrating the correlation between the Marimaca deposit, the deep drilling sulphide intercepts and the projected high magnetic intensity solid, as interpreted using the Magnetic Vector Inversion modelling technique.
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Figure 9-8: Cross section with Interpreted Sulphide Zone, Previously Completed Sulphide Drill Results and Vector Inversion Magnetic Anomaly > 0.03 SI
Note: Figure prepared by Marimaca Copper, 2020.
9.5 Comments on Section 9
Exploration conducted to date has been suitable to identify areas of copper anomalism. Marimaca Copper has a large regional landholding which is prospective for additional copper mineralization.
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10 Drilling
10.1 Introduction
Table 10-1 summarizes the drilling completed to date by year. A total of 346 RC holes (82,234 m) and 39 core holes (8,976 m) have been completed. Drill collar locations are included in Figure 10-1.
10.2 Drill Methods
The RC drilling was completed by PerfoChile Ltda, with drill hole diameters from 5¾” to 5 ⅝”. Core drilling was performed at PQ (85 mm core diameter), HQ (63.5 mm) and HQ3 (61.1 mm) sizing, by Superex, a Chilean drilling contractor.
Collar locations were at 100 m or 50 m spacing, as dictated by topography, and the ability to construct drill platforms and pad accesses. Drill holes were typically oriented at either 220 º or 310 º. However, some holes were oriented at 270 º to test high-grade zones controlled by north–south-trending feeders and veins. Drill holes were angled at -60 º.
10.3 Logging Procedures
All drill holes were geologically logged using digital data capture methods. Information logged included lithology, structure, alteration and mineralization based on drilling intervals, recoveries and analytical results.
RC drill cuttings were cleaned prior to geological description. The first pass logging recorded lithology, structure and alteration. Oxide mineralogy was relogged when assay data were received. A chip tray record of the drill holes was stored.
Core holes were initially logged for lithology, structure, and alteration. When assay data were available, the data were correlated with the logged mineralization. Rock quality designation (RQD) data were also recorded.
In addition to measuring deviations, most of the holes were surveyed using an optical tele viewer (OPTV or BHTV), which continuously recorded structures and orientation measurements down the length of the drill hole (Figure 10-2).
10.4 Recovery
Recovery data were recorded for the RC and core drill holes. Measured recoveries are over 95% for both types of drilling, without significant variations. Recovery is considered to be unrelated to copper grades.
10.5 Collar Surveys
Local contractors carried out the supervision of the drilling operation. An experienced surveyor recorded the collar locations. Collars are marked in the field using PVC pipe and a metal plate with the name of the drill hole.
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Table 10-1: Drill Summary Table
Drill Number of Drill Metreage Year Location Purpose Type Holes (m) Exploration RC 15 2,710 2016 Marimaca Infill 100 x 100 m RC 39 8,910 Geometallurgy HQ core 6 2,008 Infill 50 x 50 m RC 59 11,928 Geometallurgy PQ core 4 820 2017 Marimaca HQ3 Geotechnical 6 1,230 core Marimaca Exploration RC 11 2,950 2017– Northeast 2018 La Atomica Exploration RC 14 3,220 Delineation RC 55 12,980 exploration EW exploration RC 6 1,050 La Atomica Manolo sector RC 9 2,120 exploration Geometallurgy PQ core 9 2,203 2018– Exploration RC 61 17,700 2019 Delineation RC 16 4,200 exploration Atahualpa–Tarso EW Exploration RC 32 7,266 Tarso exploration RC 29 7,200 Geometallurgy, PQ 14 2,715 Atahualpa Core Subtotal RC 346 82,234 Subtotal core 39 8,976 All drilling 385 91,210
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Figure 10-1: Drill Hole Collar Plan
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 10-2: Example of Drill Hole Survey and BHTV Data
Note: Figure prepared by Marimaca Copper, 2020.
10.6 Down Hole Surveys
Down hole surveys were completed by either Data Well Services or Comprobe. and the instrumentation included Giroscope NSG for survey and Optv, Hirat and Caliper probes for video. All readings were continuous to the end of the holes.
10.7 Sample Length/True Thickness
Drill holes are angled to best intercept the projected orientation of the mineralization. Typically, drilled widths are longer than true widths. Figure 7-8 and Figure 7-9 provides examples of the drill orientations in relation to mineralization.
10.8 Comments on Section 10
In the opinion of the QP, the quantity and quality of the lithological, collar and down-hole survey data collected in the drilling programs are sufficient to support Mineral Resource estimation:
Core and RC logging is in line with industry standards Collar surveys were performed using industry-standard instrumentation Down-hole surveys performed were performed using industry-standard instrumentation Recovery data from core drill programs are acceptable.
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11 Sample Preparation, Analyses and Security
11.1 Sampling Methods
11.1.1 Geochemical Sampling
The geochemical sampling programs are discussed in Section 9.3.
11.1.2 Reverse Circulation
Notably, no wet samples were encountered in these drill holes. RC drill holes were sampled on a 2 m continuous basis, with dry samples riffle split on-site and one quarter sent to the laboratory for preparation and assaying. A second quarter was stored on site for reference. The RC chips are stored in the field in old adits, as are coarse rejects of about 8–9 kg weight, obtained from the third riffle pass.
11.1.3 Core Sampling
11.1.3.1 Transfer of Trays to Sampler
The trays are covered using high-density foam to prevent movement in the tray. In turn, the trays are arranged in the truck with the same material to also avoid blows during transportation. The trays are tied firmly so that they will not fall out during the transfer, which must be carried out at low speed.
11.1.3.2 Core Markers
Core markers are placed at the end of each drilling run and must contain the name of the hole, depth, length of the drilled section and the recovery of the drilled section. This information is reviewed and compared with the shift reports and with the physical verification of the sample in the tray. If there are differences, these must be clarified at the time by the supervisor of the drilling company. Corrective actions are taken if necessary.
11.1.3.3 Calculation of Recovery and Regularization
The recoveries of the drilled sections are calculated and the sample actually recovered, the assignment of the sampling support is also made, for this the recovery and drilling a yellow wooden block with the name of the well and the regularized section is located. The trays are also marked, indicating the beginning and bottom of the segment.
11.1.3.4 Fracture Frequency and Rock Quality Designation Measurements
Geotechnical parameters rock quality designation (RQD) and fracture frequency (FF) are recorded, as are visual fractures and faults.
11.1.3.5 Geological Logging
Cores are logged for lithology, structures, mineralogy, and alteration. Geologists mark-up the core for sampling, respecting geological boundaries in accordance with Marimaca Copper’s sampling protocol.
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11.1.3.6 Pre-Split Photography
High definition photographs are taken of the trays, using natural light, and wet core. The photographs are reviewed and approved by Marimaca Resources personnel.
11.1.3.7 Pre-Split Weight Control
The mass of the tray is controlled and recorded before sampling, in order to be able to determine the amount of sample sent for analysis.
11.1.3.8 Splitting and Sampling
The sample is cut into two equal parts using an electro-hydraulic guillotine. One half is kept in the tray and the other half is wrapped, marked and bagged ready to be sent for sample preparation and analysis.
11.1.3.9 Post-Split Weight Control
The core remaining in the core trays is weighed, and the weights recorded. These data are used to monitor the sample weights reported by the laboratory.
11.1.3.10 Post-Split Photography
High definition visual registration of the trays already sampled, trays are placed on the lectern and the photograph is taken with the wet test media to obtain greater enhancement of colours and textures. Photographs also are reviewed and approved by Marimaca Resources.
11.1.3.11 Weight Control of Bagged Sample
All bagged samples are weighed and the weights recorded. These data are used to monitor the sample weights reported by the laboratory.
11.1.3.12 Storage
Core and RC samples are retained as follows:
RC d “B” and “C” splits are stored in adits on site RC sample pulps, initial and duplicate RC samples, and core sample pulps (drill holes MAD-07 to MAD-16) are stored in the sample warehouse. Core trays for core drill holes MAD-01 to MAD-16, ATD-01 to ATD-13, and LAD-01 to LAD-09 are stored in the sample core yard.
Figure 11-1 shows a diagram of the core sampling protocol.
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Figure 11-1: Core Sample Process
Note: Figure prepared by Marimaca Copper, 2020
11.2 Specific Gravity Determinations
Specific gravity (SG) was measured systematically on core samples at approximately 20 m intervals. The core samples ranged in length from 7–26 cm. Each selected piece of core was logged in detail and photographed.
The SG was determined on wax-coated core using a water displacement method where the core was weighed in air, and then in water. Measurements were performed by the Mecánica de Rocas (Rock Mechanics) laboratory at Calama.
Fifty-eight measurements were completed in 2016, 98 in 2017, and 427 in 2018, for a total of 562 measurements as shown in Table 11-1.
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Table 11-1: Samples
Sample Sector Number of Total Types Samples Marimaca 319 Drill hole Atomica 78 502 Atahualpa 105 Underground 30 30 Road Cuts 30 30
The average SG of each estimation unit was calculated based on each mineral zone, eliminating outliers Table 11-2 shows the SG and variance for each of the mineralized zones.
Table 11-2: Average SG values
Mean Variance SZMIN (t/m3) Brochantite 2.639 0.0778 Chalcopyrite 2.719 0.0709 Chrysocolla 2.670 0.0505 Enriched 2.649 0.1043 Waste 2.645 0.0964 Lix 2.663 0.0746 Mixed 2.688 0.0803 Pyrite 2.711 0.0366 Wad 2.642 0.0550
11.3 Analytical and Test Laboratories
Initially, the primary sample preparation and assay laboratory was Geolaquim Ltda. (Geolaquim) in Copiapó. Geolaquim held ISO 9001:2000 accreditations for selected analytical techniques and was independent of Marimaca Copper.
From the 2017 infill drilling campaign onward, samples were prepared in the Andes Analytical Assay Ltda (Andes Analytical) Calama laboratory and assayed by the Andes Analytical laboratory in Santiago. Andes Analytical holds ISO 9001:2008 accreditations for selected analytical techniques and is independent of Marimaca Copper.
Andes Analytical acted as an umpire laboratory for the 2015 drill campaign. Marimaca Copper did not employ an umpire laboratory for the remainder of the campaigns.
11.4 Sample Preparation and Analysis
Samples were transferred by laboratory personnel from the Project site to either the Copiapó or Calama facilities for sample preparation. Preparation pulps were returned to the project storage facilities to generate the analysis batches with inserts for the quality assurance and quality control (QA/QC) program.
Upon arrival at the laboratory, the RC and core samples were organized, and the sample numbers recorded. Sample preparation consisted of:
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Drying at 105°C Crushing to 85% passing 10 mesh Splitting using a rotary splitter Pulverizing a 500–700 g sample to 95% passing 150 mesh Collection of three samples, two at 125 g each, and one at 250 g Despatch of the sample envelopes to MCAL for insertion of QA/QC samples.
Total copper (CuT) was analysed using a 1 g digestion with 10 mL mixture HNO 3 + 4 mL HClO 4 + 1 mL H 2SO 4 in 20 mL dilution of 50% HCl for a 100 mL gauge flask, followed by an atomic absorption spectroscopy (AAS) finish. The detection limit was 0.01% CuT.
Soluble copper (CuS) was analysed using 1 g leaching with 50 mL H 2SO 4 in a 250 ml gauge flask, followed by shaking at 130 rpm for one hour, and AAS analysis. The detection limit was 0.01% CuS.
11.5 Quality Assurance and Quality Control
11.5.1 Introduction
The analytical QC programs involved the use of preparation and pulp duplicates for precision analyses, standard reference materials (SRMs) and check samples for accuracy analyses (Table 11-3)
Fine blanks for contamination evaluation were used from 2018 onward. Field duplicates and coarse blanks were not used in any of the analytical campaigns.
11.5.2 Check Sample Analysis
Check samples, consisting of 240 duplicate pulp pairs, were the sole quality control measure for the 2016 MAR 01–16 pilot drilling campaign and were taken at an approximate rate of one check sample for every six samples.
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Table 11-3: Control Programs for Each Drilling Campaign
Drill Check Coarse Pulp Fine Campaign Type Year Laboratory SRM Holes Sample Duplicate Duplicate Blank
Geolaquim/ MAR 01-16 16 RC 2016 Andes X — — — — Analytica
MAR 17-54 38 RC 2016 Geolaquim — X X X —
MAD 01-06 6 Core 2016 Geolaquim — - X X —
Andes MAR 55-111 59 RC 2017 — X X X — Analytica
Andes LAR 01-14 14 RC 2017 — X X X X* Analytica
Andes MAD 07-16 10 Core 2017 — - X X X* Analytica
Andes MAR 112-124 11 RC 2018 — X X X X* Analytica
Andes LAR 15-84 70 RC 2018 — X X X X Analytica
AER 01-03 Andes ATR 01-104 120 RC 2019 — X X X X Analytica TAR 01-13
ATD 01-13 Andes 22 Core 2019 — — X X X LAD 01-09 Analytica
Note: * indicates that these samples were not true blanks, but instead, were low-grade SRMs.
No other check sampling campaigns were completed.
The check samples were evaluated using reduced major axis (RMA) regression plots. In these plots, the coefficient of determination (R 2), should approximate one to be acceptable, and the slope (RMAS), allowing for a bias percentage calculation (1-RMAS), should approximate zero to be acceptable.
Table 11-4 and Figure 11-2 show the check sample evaluation results.
This campaign shows acceptable accuracy in principle, though with moderate uncertainty, due to a lack of appropriate control programs accompanying check samples to the main and especially the umpire laboratory.
However, given that the amount of check samples exceeds industry requirements by a considerable margin, and that the RMA regression shows a decisively strong assay
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correlation between laboratories, the probability of quality control issues in the dataset is mitigated to some extent in the QP’s opinion.
Table 11-4: Check Sample Analysis, MAR 01–16 Campaign
AV Duplicate Check Samples %CuT Bias R2 Pairs Original Duplicate MAR 01-16 240 0.816 0.819 0.01% 0.99
Figure 11-2: Check Sample Regression MAR 01–16 Campaign
Note: Figure prepared by Marimaca, 2020. GLQ = Geolaquim, AAA = Andes Analytica.
11.5.3 Standard Reference Material Analysis
SRMs were sourced from two companies. SRMs from Geostats Pty Ltd (Australia) were used during 2016–2018, with 832 samples of 17 materials, inserted at an approximate rate of one SRM every 16 samples.
SRMs sourced from Intem Ltd. (Chile) were used during 2018–2019, with 1,154 samples of six different SRMs, inserted at an approximate rate of one SRM every 25 samples for RC drill holes and one SRM every 15 samples for core holes.
Geostats’ SRMs come from different sources, depending on the required grade. Intem’s SRMs were prepared from pulp samples sourced from RC drill holes within the Project area, homogenized and analyzed in a round-robin program, to obtain best values (BV).
The QP reviewed the SRM data. The first step was to remove outliers, which were defined as samples with values that exceeded a window of ±3 standard deviations (SD) of each SRM dataset. Outliers should not form more than 5% of the database. The average values of the filtered dataset were compared to the best values, by calculating the bias (AV/BV-1), which should not exceed ±5% (with a tolerance of ±10%). Finally, Shewhart control charts were
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constructed, plotting a time series of the SRM values against acceptability (precision) windows of BV±2*SD / BV±3*SD (round-robin SD) in the case of Geostats SRMs, or BV±5% / BV±10% in the case of Intem SRMs. Assay values surpassing these windows are considered outliers and should remain below 5% of all samples (with an extreme tolerance of 10%), especially in the case of the outermost windows.
The analytical campaigns show acceptable accuracy (bias %) and precision (outliers %) in principle, though with moderate to high uncertainty in some cases, due to the number of different SRMs used (some with very similar copper grades) and the number of samples inserted for each SRM.
Usually, three to five SRMs of different grade values, inserted at an approximate rate of one SRM every 15 samples, are sufficient for a project with only one economically important element. Here, although the insertion rate is appropriate, there are six Intem SRMs and 17 Geostats SRMs. It is because of this that there are usually only a few assays for each SRM, which leads to uncertainty when facing unacceptable percentages, given that a single anomalous sample can take the small dataset past the acceptability windows.
The change of SRM provider and its preparation methodology allowed for better accuracy control in recent campaigns, reducing the number of SRMs used, and increasing the number of samples inserted in each campaign. This, in turn, has led to more reliable SRM analyses, although there are still instances where assays are insufficient to identify a problem with certainty.
The increased insertion rate to one every 25 samples for RC drill holes could lead to uncertainty in shorter campaigns. The number of MRC-2 samples, which is unusually high compared to other materials, probably due to availability, is a further source of uncertainty.
The two recent campaigns show acceptable accuracy (bias %) and precision (outliers %).
11.5.4 Duplicate Sample Analysis
Preparation and pulp duplicate samples were inserted in every campaign, except for the pilot program. The insertion rate for the RC programs was approximately one every 15 samples, resulting in 2,750 coarse duplicate samples and 2,822 pulp duplicate samples. The insertion rate for the core holes was one in 10 samples, resulting 477 pulp duplicate samples.
The QP’s duplicate sample review began with a relative error (RE) analysis, calculating the absolute percentage value of 2*(OA-DA)/(OA+DA), where OA refers to the original assay and DA to the duplicate assay values. Relative errors should generally remain below 20% for coarse duplicate pairs and below 10% for pulp duplicate pairs. The practical detection limit (PDL) was obtained by plotting original assay values against their corresponding relative error and identifying the approximate value where low-grade assays curve upward approaching a vertical limit near the reported detection limit (RDL). This value is the practical detection limit. Duplicate pairs were validated using the hyperbolic method. This function acts as an acceptability boundary, which compensates for higher relative errors at lower grades. Failed pairs should remain below 10% of all duplicate samples.
All campaigns show acceptable precision and insertion rates that far exceed industry requirements. Even though drilling campaign MAR 17-54 is not as good as the rest in terms of percentage of failed pairs and relative error, it is still well within acceptability boundaries. As mentioned in the check sample analysis, the pilot drilling campaign (MAR 01-16) lacks the necessary control program along with the check samples, so it cannot be analyzed for precision. However, the good assay correlation between laboratories hints at an acceptable reproducibility.
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No field duplicates were collected in any campaign, which means that the first split right after drilling is not properly controlled. The QP recommends that Marimaca Copper reduces the coarse and pulp duplicate insertion rates to one in every 25 samples each and it introduces field duplicates at the same insertion rate of one in every 25 samples.
The duplicate sample analysis shows acceptable precision with virtually no observations, other than for the lack of duplicates in the pilot drilling campaign. This issue is somewhat mitigated thanks to the strong correlation between check samples.
11.5.5 Blank Sample Analysis
Blank samples were not included in the 2016–2017 drill campaigns. Since 2018, 912 fine blanks were inserted in the form of a very low-grade SRM (MRC-1, with 0.006% CuT), at an approximate rate of one every 30 samples for RC drill holes and one every 45 samples for core holes. This SRM is technically not a blank because it does not have a copper grade below the RDL, which is usually 0.001% CuT in standard AAS tests, but in the QP’s opinion, it is sufficiently close to the RDL to treat it as such.
The sample review was undertaken by plotting a time series of blank assay values against an acceptability limit of 3–5 times the RDL. As with SRMs, outliers should remain below 5% of all samples. Since MRC-1 is a slightly higher value “blank”, it seems reasonable to use the lower factor (3*RDL) and the acceptability limit as a window of ±3*RDL (±0.003% CuT) from the best value (BV) of the SRM. If there is an unacceptable outlier percentage, blank assay values are plotted against their corresponding previous sample values in an RMA regression, to look for a correlation (high R 2 value) that would imply systematic error and thus contamination during sample preparation (coarse blanks) or assaying (fine blanks).
The campaigns show acceptable results, with no apparent contamination. The lack of blanks in previous campaigns can be relatively mitigated in the QP’s opinion by reviewing the quality controls performed and reported by the laboratory. A review was conducted of the QA/QC protocols used by Geolaquim and the Andes Analytical reports. Both laboratories appear to have well-structured quality control measures in place, including the insertion of blank samples.
Coarse blanks were not included in any campaign, which means that potential contamination during sample preparation is not properly controlled. The QP recommends that Marimaca Copper reduce the current fine blank insertion rates to one every 50 samples and introduce insertion of coarse blanks at the same insertion rate of one every 50 samples.
The blank sample analysis shows no evidence of contamination. The lack of blank samples in previous campaigns, while not irrelevant, is of moderate to low concern, especially after reviewing the quality controls performed and reported by both laboratories. Because the SRM and duplicate sample analyses performed acceptably, it seems reasonable to infer that there is a low probability for contamination in campaigns that are missing blanks.
11.6 Analysis of Core vs RC Holes (twin)
To validate the use of data from the core and RC exploration campaigns, a comparison was undertaken of 11 drill holes that were within a maximum of 10 m separation (Figure 11-3). The GSLib Getpairs routine was used for this work.
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Figure 11-3: Location of Drill Holes used in RC/Core Comparison
Note: Figured prepared by Marimaca, 2020.
The average CuT and CuS grades from the core and RC drilling were compared (Table 11-5). In NCL’s opinion, these averages are very similar. A scatterplot of the CuT and CuS grades from the core and RC drilling is provided in Figure 11-5.
To validate the use of data from the DDH and RC exploration campaigns, samples close to 10m maximum, from both exploration campaigns 11 twin holes were compared. The GSLib getpairs routine was used for this work.
When comparing the averages of CuT and CuS grade of DDH and RC drilling it is observed that these averages are very similar and there is no global error. The Table 11-5 shows the average CuT and CuS, for DDH and RC drilling.
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Table 11-5: Average CuT and CuS, for DDG and RC drilling.
Average (%) Range Pairs CUT_RC CUT_DDH 0 - 10m 0.45 0.43 20,228
Average (%) Range Pairs CUS_RC CUS_DDH 0- 10m 0.24 0.23 16,210
When comparing the scatterplot of CuT and CuS from DDH and RC drilling, it is observed that the pairs of nearby samples have a high dispersion. However, this dispersion is typical of the deposit, since when cross-validating with the nearest neighbor, the same behavior is observed therefore it was concluded that the use of DDH and RC samples together does not introduce a bias in the data. Apart from this geostatistics comparisons, the best correlation corresponds to the 220-azimuth group of drills. This direction corresponds with the most perpendicular to the NW trending fracture system controlling supergene mineralization trend. So, the direction that penetrate the mineralization trend in oblique way may not have good correlations.
11.7 Databases
Assay data were loaded directly from digital assay result files into the final database to minimize sources of error using "LogSon" program, with updates 2018 and 2019.
The mapping of alteration minerals, minerals and ganga is done independently, respecting natural breaks in the case of DDH drilling and AR boxes sampling support. Figure 11-1 shows sequence of the data entry:
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Figure 11-4: Sequence of data entry
Note: Figured prepared by Marimaca Copper, 2020.
The reviews carried out by the QP, including the data entry process to the software’s used for the revision procedure, indicated that there were no major problems, only some minor repetitions or different signs. The lithology, geotechnical parameters, alteration, mineralogy and all numeric data, worked very well in the 3D software’s and in the estimation processes.
11.8 Sample Security
All drilling assay samples were collected by Marimaca Copper personnel or under the direct supervision of Marimaca Copper personnel. Samples were shipped directly from the Project site to the laboratory.
Assay samples are catalogued by appropriately qualified staff at the laboratories. Sample security involved two aspects: maintaining the chain of custody of samples to prevent contamination or mixing of samples and rendering active tampering as difficult as possible.
During site visits, NCL found no evidence of active tampering or contamination of assay samples.
11.9 Comments on Section 11
The QP reviewed the field procedures and performed an extensive analytical quality control review of the data provided by Marimaca Copper. In the opinion of the QP, Marimaca Copper personnel used care in the collection and management of the field and assaying exploration data.
Based on reports and data available, the QP has no reason to doubt the reliability of exploration and production information provided by Marimaca Copper.
The reports and analytical results projected by the QP suggest that, apart from minor to moderate concerns noted in the 2016–2017 campaigns, analytical results delivered by the laboratories used by Marimaca Copper are free of apparent bias.
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The sample preparation and analytical procedures used by the independent laboratories are in line with industry norms. Sample security practices are acceptable.
The data generated from the analytical programs is suitable for use in Mineral Resource estimation.
Figure 11-5: Scatter Plot CuT vs CuS
Note: Figure prepared by Marimaca Copper, 2020.
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12 Data Verification
12.1 Internal Data Verification
The exploration and production work completed by Coro was conducted using internally documented procedures and involved verification and validation of exploration and production data prior to use of the data in geological modelling and Mineral Resource estimation.
During drilling, experienced geologists conducted industry-standard measures designed to ensure the consistency and reliability of the exploration data.
Quality control failures were investigated, and appropriate actions were taken when necessary, including requesting re-assaying of certain sample batches.
12.2 Data Verifications by NCL
Professionals under the supervision of NCL visited the Marimaca properties on December 6– 7, 2016, accompanied by Sergio Rivera, Marimaca Copper’s Vice President of Exploration. The team included Ricardo Palma, P. Eng. and Luis Oviedo P. Geo. NCL carried out a second site visit during 28 to 31 August 2019 to verify aspects of the drill program that was underway at the time.
During the visits, aspects that could impact the integrity of the drill hole database (e.g. core logging, sampling, and database management) were reviewed with Marimaca Copper staff. NCL was able to interview Marimaca Copper staff to ascertain exploration procedures and explanation of protocols written protocols.
NCL toured the Marimaca area and observed core and RC drill sites, collars and collar monumenting. NCL examined core from several drill holes, finding that the logging information accurately reflected the inspected core and cuttings. The lithology and grade contacts checked by NCL matched the information reported in the core logs.
The QP reviewed the drill hole database during preparation of the 2020 resource estimate update and concluded that it was adequate to support block modelling, and Mineral Resource estimation.
NCL also completed statistical comparisons of the global grade of the block model against the informing drilling data. NCL visually compared the block model against the informing samples on plans and sections to confirm that the estimations were generally an adequate representation of the distribution of the copper mineralization.
12.3 Comments on Section 12
The QP is of the opinion that the data verification programs completed on the data collected from the Project are consistent with current industry practices and that the database is sufficiently error-free to support the geological interpretations and Mineral Resource estimation, and preliminary mine planning.
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13 Mineral Processing and Metallurgical Testing
13.1 Metallurgical Testing
Marimaca Copper Corp. has completed three test programs (Geomet I, II and III) to characterize the metallurgical response to samples collected from its Marimaca copper project. Preliminary tests were performed considering parameters such as: mineral subzone, agglomeration conditions, particle size, column height, irrigation rate and acid concentration in the irrigation solution.
Additionally, during the preparation of this document (Section 13 PEA August 2020), a fourth metallurgical testing program was in progress (Geomet IV). Definition of the next steps that include analysis of the metallurgical variability of the deposit and the optimization of the metallurgical parameters is on-going. The experimental results of Geomet IV support the definitions of the current PEA and do not contradict the PEA definitions and assumptions. These results and the complete metallurgical analysis will be part of the next project stage.
The following summarizes each of these metallurgical testing programs and their results.
13.1.1 Geomet I & II
13.1.1.1 Samples
Seven (7) samples where generated for column testing from copper mineralized zones defined during the 2016 drilling campaign. These were obtained from a matrix linking the spatial location with the mineral zones.
A portion of the samples correspond to monzodiorite (diorite with potassium feldspar) affected by an albite-chlorite-actinolite alteration; a minor part to the andesitic and dacitic dikes composition that cut the monzodiorite. Oxide mineralogy is brochantite, atacamite, chrysocolla and wad. Most of the oxide mineralized material occurs as fracture impregnation and filling.
The samples used for this testing were named: Marimet 1, Marimet 2, Marimet 3, Marimet 4, Marimet 5, Marimet 6 and Marimet 7, abbreviated as M1, M2, M3, M4, M5, M6 and M7. Table 13-1 shows the chemical characterization of each sample and a simple description of its mineralogy and location.
13.1.1.2 Analytical Procedure
In April 2017, Geomet was commissioned to start phase 1 of the initial metallurgical program, which considered 7 samples from the three aforementioned metallurgical units and whose scope included the mechanical preparation of the material, its characterization, head particle size analysis, sulphation tests, iso-pH tests, leaching tests at two crush sizes in seven columns of 6” x 1 meter in duplicate including leach residue analysis.
Based on the phase 1 results, Geomet was commissioned again in September 2017 to execute phase 2 of the metallurgical program using the same samples.
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Table 13-1: Chemical and Mineralogical Characterization.
Solubility CuT CuS AAC** Mineralogical Characterization Sample Ratio (%) (%) (location) (RS)*(%) (kg/t) M1 0.88 0.71 80 49 Chrysocolla (Pit 2) Brochantite/atacamite > Supergene M2 1.47 1.17 79 32 sulphide (Pit 2) M3 0.49 0.32 65 53 Wad dominant (Pit 2) M4 0.81 0.71 87 39 Chrysocolla (Pit 1) M5 1.14 0.97 85 39 Brochantite/atacamite (Pit 1) Wad dominant > supergene sulphide M6 0.62 0.47 75 30 (Pit 1) Mixed primary Sulphides-supergene > M7 0.58 0.40 69 23 oxide (High Pit)
*Copper Solubility Ratio or RS defined as the CuS over CuT ratio.
**Analytical Acid Consumption assay: 10 g of sample in 100 mL of 1N sulphuric acid solution for 2 hours.
Crush size
The crush size for these tests was 90% below ½”. Figure 13-1 shows the particle size distribution obtained for each sample.
Figure 13-1: Particle Size Distribution
Note: Figure prepared by Marimaca, 2020.
Irrigation Rate:
The initial tests were performed with an irrigation rate close to 10 L/h/m 2, the new tests were adjusted to a lower rate, approximately 8 L/h/m 2, trying to achieve a higher copper concentration. For the case of the initial tests, 9.5 gpl acid was used, and in the new tests a sulphuric acid concentration around 10.5 gpl was used.
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Acid in Agglomeration:
In the first 1 m height tests, almost all columns reached a deficiency of acid application, with the effluent solution having too high pH to leach the copper. Consequently, a new series of sulphation tests were run to better define the amount of acid to be added to each sample in the agglomeration stage.
Each sample, M1 to M7, was subjected to sulphation tests using three different acid doses of low-, mid- and high-dose.
Column Height
As stated above, most tests were performed at different heights, between 1.6 m and 3 m. Table 13-2 shows the height for each sample in the metallurgical column test executed.
Table 13-2: Column Height per Sample
Sample M1 M2 M3 M4 M5 M6 M7 Column Height (m) 2.7 2.2 1.6 3.0 2.5 3.0 2.8
Leaching Time, Leaching Ratio and Acid Consumption:
Initially, it was determined to use a fixed leach solution ratio of at least 2.5 m 3/t to compensate for the variable column height.
However, all tests were terminated between 64 and 66 days, hence the leaching ratio varied for each one of the columns due to the varying height. Therefore the overall acid consumption, measured in kg/t, was variable for each test, not only for acid addition during the agglomeration stage, but also because of the excess volume of leaching solution passed per tonne of treated material in the lower height columns.
13.1.1.3 Main Results
Sulphation tests
Table 13-3 show the sulphation test results and graphs for the seven samples.
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Table 13-3: M1 to M7 Sulphation Tests Results.
The best sulphation results, metallurgically speaking, are highlighted in yellow and green. The goal of this test is to add sufficient acid, but not excessive, to achieve a pH of 1.8 to 2.1 in the wash water from the agglomerates.
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For samples with the same or similar CuT grade, the sulphation result, at the same particle size, is a clear indicator of the acid soluble copper content (CuS).
The acid addition for each sample to add in agglomeration, resulting from these sulphation tests, is shown in Table 13-4.
Table 13-4: Acid Addition in Agglomeration per Sample.
Sample M1 M2 M3 M4 M5 M6 M7 Added Acid (kg/t) 28 32 27 27 25 21 21
Column Leaching Tests
Table 13-5 shows the general results of each of the tests for the samples M1 to M7 with the 90% -½” particle size distribution.
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Table 13-5:Column Leaching Results Summary.
LEACHING SUMMARY
Head Grade (%) Results ) 2
ID Acid Cu Extraction (%) Account Consumption (kg/t) CuT CuS RS AQ Calc. Final Net or (%) Gross Head Tail Gangue Sample IrrigationRate (L/h/m Height (m) Leach.OFF Ratio Head
Col-29 Marimet-1 8 2.7 3.21 0.88 0.707 80.4 83.6 83.5 83.4 100.2 59.8 48.4
Col-30 Marimet-1 8 2.7 3.15 0.88 0.707 80.4 79.4 82.7 83.4 96.1 60 49.3
Col-31 Marimet-2 8 2.2 3.19 1.47 1.169 79.6 71.5 76.4 77.9 93.5 70.1 53.9 Col-32 Marimet-2 8 2.2 3.21 1.47 1.169 79.6 70.4 76.2 77.9 92.5 69.8 53.8 Col-33 Marimet-3 8 1.6 4.46 0.49 0.318 65.3 68.6 72.6 74.1 94.5 63.7 58.5 Col-34 Marimet-3 8 1.7 4.41 0.49 0.318 65.3 70.5 72.6 73.3 97.2 65.7 60.4 Col-35 Marimet-4 8 3 2.53 0.81 0.706 87.3 77 81.6 82.6 94.4 57 47.4 Col-36 Marimet-4 8 3 2.54 0.81 0.706 87.3 75.9 80.7 81.9 94.1 56.7 47.2 Col-37 Marimet-5 8 2.5 2.91 1.14 0.966 85 78.8 84.2 85.2 93.6 53.2 39.4
Col-38 Marimet-5 8 2.5 2.91 1.14 0.966 85 80.5 83.9 84.5 96 53.7 39.7 Col-39 Marimet-6 8 3 2.61 0.62 0.468 75.1 75.1 76.9 77.5 97.6 46.7 39.5 Col-40 Marimet-6 8 3 2.62 0.62 0.468 75.1 73.3 77.2 78.3 95 46.8 39.8 Col-41 Marimet-7 8 2.8 2.78 0.58 0.398 68.1 62.6 68.5 71.2 91.5 48.8 43.2 Col-42 Marimet-7 8 2.8 3.05 0.58 0.398 68.1 62.8 71.2 74.6 88.3 47.7 42.1
Columns have acceptable metallurgical accounting results with half of them achieving 100+- 5% on a CuT head assay versus CuT “calculated” head basis. The rest achieved 100+-10% or better. Head and leached residue sample pulps where sent for check-assaying with acceptable results.
Sulphuric Acid Consumption
All the Geomet II columns (Table 13-5) and some of iso-pH tests (Table 13-6) reached an acid consumption higher than the Analytic Acid Consumption (AAC) of the sample, which is usually referred as the maximum acid consumption achievable in a typical leaching process as is performed with samples below #150 Tyler mesh at a higher acid content (50 gpl acid).
This high acid consumption may be partially explained due to the fact that the leaching solution does not have any impurities present, such as Fe, Al and Mg, which, if present in the leaching solution, might reduce their dissolution from the mineral.
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Table 13-6: Geomet I Iso-pH Test.
Iso pH Test Head Grade Iso pH Test Results Conditions Sample Soluble. Gross Net H + CuS AAC Time CuT + CuT % CuS/CuT pH H Cons. Cons. % kg/t h Recovery % kg/t kg/t M1 0.937 0.732 78 49 1.5 48 85 44 32 M2 1.502 1.133 75 32 1.5 48 82 64 44 M3 0.456 0.272 60 53 1.5 48 66 42 37 M4 0.851 0.715 84 39 1.5 48 88 50 38 M5 1.157 0.977 84 39 1.5 48 86 35 19 M6 0.622 0.436 70 30 1.5 48 73 29 22 M7 0.626 0.402 64 23 1.5 48 65 44 37
Copper Extraction and Acid Consumption Profiles
The CuT extraction rate and profiles for the tested samples are typical of acid soluble oxide minerals. The initial dissolution, with most of the acid added in agglomeration, is rapid, followed by a slower leaching residual mineral.
Figure 13-2 also shows that M1, M2 and M5, the samples with the highest acid consumption, continues to consume acid almost linearly and continues beyond the 1 m 3/t target leach ratio.
Figure 13-2: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-1, M-3 and M-5.
Note: Figure prepared by Marimaca Copper, 2020.
Figure 13-3 shows that the M2 and M4 samples continue to consume acid almost linearly and continues beyond the 2 m 3/t target leach ratio.
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Figure 13-3: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-2 and M-4.
Note: Figure prepared by Marimaca Copper, 2020.
Figure 13-4 shows that the samples which have a lower consumption than the others, M6 and M7, once reaching 1 m 3/t of solution application, start showing un-reacted free acid, which is similar to samples for all mineral types.
Figure 13-4: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-6 and M-7.
Note: Figure prepared by Marimaca, 2020.
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Figure 13-5: Cu Extraction (%), Starting H+ Addition in Agglomeration and Consumption (kg/t) vs Leaching Ratio (m2/t), M-1, M-3, M-5, M-6 and M-7
Note: Figure prepared by Marimaca Copper, 2020.
13.1.1.4 Conclusions
The recoveries and the acid consumption that may be estimated from the performed tests, for the indicated copper grades, are as follows:
The M1 sample, corresponding to a CuT grade between 1.0% and 0.8% and a mineral- type description as Chrysocolla, has a recovery of 77% and a net (Gangue) acid consumption of 42 kg/t. The M3 sample, corresponding to a CuT grade between 0.4% and 0.5% and a mineral- type description as Wad -Chrysocolla – Brochantite/Atacamite, has a recovery of 62% and a net (Gangue) acid consumption of 52 kg/t. The M5 sample, corresponding to a CuT grade between 1.2% and 1% and a mineral- type of Brochantite/Atacamite, has a recovery of 76% and a net (Gangue) acid consumption of 37 kg/t. The M6 sample, corresponding to a CuT grade between 0.6% and 0.43% and a mineral-type of Wad and Supergene Sulphide, has a recovery of 70% and a net (Gangue) acid consumption of 38 kg/t. The M7 sample, corresponding to a CuT grade between 0.6% and 0.5% and a mineral- type of Mix of Primary Sulphide and Supergene-Oxides, has a recovery of 58% and a net (Gangue) acid consumption of 40 kg/t. The M2 sample, corresponding to a CuT grade between 1.5% and 1.3% and a mineral- type of mainly Brochantite/Atacamite with minor Supergene Sulphide, but which has a high sulphuric acid consumption, has a recovery of 67% and a net (Gangue) acid consumption of 50 kg/t.
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The leaching kinetics for all samples is fast, at one-third of the leaching cycle achieving 70% to 80% recovery.
The expected net (Gangue) acid consumption is estimated to be between slightly below 40 kg/t up to 60 kg/t.
13.1.2 Geomet III
13.1.2.1 Samples
In Geomet III the samples tested were of a higher proportion of brochantite/atacamite and chrysocolla mineral-type as these two mineral-types will be treated in the first years from the near-surface (5 to 10 meters) mining. Thirty-seven (37) composites where obtained from 13 drill hole locations - 10 were Reverse Circulation (RC) and 3 were from Diamond Drill Hole (DDH) core.
13.1.2.2 Test Description
This test program included the Head Chemical Characterization of the 37 composites (CuT, CuS, FeT, Al, Mg, CAA, CO3, AlS, FeTS and MgS) and the completion of 42 iso-pH 1.5 tests, 37 of them at 48hrs and 5 at 72 hrs.
13.1.2.3 Main Results
The bottle-roll test results are shown in Table 13-7. The values in red were re-assayed with similar results. The new values are shown in the table. These corrected values for samples M-21, M-25 and M-35 are not well-balanced yet according to related data.
Regarding copper recovery, except for M-21, M-22 and M-23, over 100% of the soluble copper ratio (acid soluble assay) was recovered. This is consistent with this trend in the Geomet II column testing for the oxide mineral-type.
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Table 13-7: Iso-pH tests, CuT recovery and acid consumption
Avg Acid Leach CuT Sol. Copper Recovery Head CuS .CuT Ratio Consumption Sample Time Ratio AQ Rec. Leach ID (%) A.H. C.H. F.T. Gross Net CO 3 CAA (h) (%) (%) Rec./CuS (%) (%) (%) (%) (kg/t) (kg/t) (%) (kg/t) M-4 48 1.01 0.81 80.00 83.3 85.2 85.6 84.7 1.06 35.8 22.9 0.15 28.8 M-5 48 0.74 0.48 64.73 72.7 75.4 76.2 74.8 1.16 30.4 22.1 0.15 35.5 M-6 48 0.37 0.26 70.05 79.8 82.8 83.4 82.0 1.17 44.3 39.8 1.10 48.1 M-7 48 0.87 0.55 63.35 74.6 75.0 75.2 74.9 1.18 33.3 23.3 0.05 37.8 M-8 48 1.66 1.36 81.64 83.5 85.0 85.3 84.6 1.04 40.8 19.4 0.05 40.2 M-9 48 1.13 0.87 77.10 82.4 85.6 86.1 84.7 1.10 40.3 26.0 0.45 50.3 M-10 48 0.67 0.53 79.54 83.9 87.5 88.0 86.5 1.09 39.9 31.2 0.40 37.5 M-10 72 0.67 0.53 79.54 87.0 88.0 88.2 87.7 1.10 42.3 34.0 0.40 37.5 M-11 48 0.61 0.47 76.78 82.6 84.1 84.4 83.7 1.09 39.4 31.6 0.60 34.6 M-12 48 1.05 0.96 90.93 93.4 93.3 93.3 93.3 1.03 42.2 27.0 0.10 48.2 M-13 48 0.65 0.56 86.27 87.4 89.2 89.5 88.7 1.03 33.5 24.8 0.40 52.2 M-13 72 0.65 0.56 86.27 88.4 90.6 90.8 89.9 1.04 40.4 32.4 0.40 52.2 M-1 48 0.50 0.43 85.03 83.2 83.9 84.1 83.7 0.98 45.3 39.6 0.82 36.8 M-2 48 0.46 0.37 81.08 89.8 85.8 85.2 86.9 1.07 44.7 38.8 0.86 37.5 M-3 48 0.62 0.48 77.56 81.2 83.5 84.0 82.9 1.07 47.0 40.1 1.05 35.3 M-14 48 1.77 1.63 91.90 95.3 96.0 96.1 95.8 1.04 75.9 52.7 1.90 83.0 M-15 48 1.32 1.09 82.39 93.7 90.4 90.1 91.4 1.11 71.7 54.2 2.48 69.2 M-16 48 0.83 0.63 75.55 74.6 77.4 78.2 76.7 1.02 64.7 56.4 2.62 70.7 M-17 48 0.38 0.28 74.84 78.5 81.3 81.9 80.5 1.08 81.9 77.8 3.86 75.0 M-17 72 0.38 0.28 74.84 80.5 83.8 84.4 82.9 1.11 85.3 81.0 3.86 75.0 M-18 48 0.78 0.68 87.42 87.0 89.7 90.0 88.9 1.02 39.3 29.6 0.32 61.1 M-19 48 0.54 0.45 82.54 78.6 81.8 82.5 81.0 0.98 57.7 52.2 1.65 58.1 M-20 48 1.14 0.90 78.78 78.8 80.4 80.7 80.0 1.01 78.1 65.7 2.57 68.4 M-21 48 0.82 0.72 88.46 86.0 88.1 88.3 87.5 0.99 18.5 8.8 4.34 30.5 M-22 48 1.18 1.09 92.83 88.6 91.3 91.6 90.5 0.97 66.7 52.4 2.13 44.5 M-23 48 1.65 1.58 95.62 93.4 94.1 94.1 93.9 0.98 97.7 76.9 3.96 86.5 M-23 72 1.65 1.58 95.62 91.4 95.1 95.3 93.9 0.98 104.6 83.9 3.96 86.5 M-24 48 1.62 1.41 86.82 89.4 89.9 90.0 89.8 1.03 51.9 32.0 0.31 37.3 M-25 48 0.40 0.31 77.70 85.1 82.0 81.3 82.8 1.07 33.0 28.1 0.59 18.1 M-26 48 1.05 0.87 82.83 84.6 82.0 81.4 82.7 1.00 41.8 29.1 0.36 49.4 M-27 48 0.54 0.43 80.36 83.1 81.7 81.4 82.1 1.02 35.4 29.2 0.63 33.2 M-28 48 0.43 0.33 78.32 80.8 79.4 79.0 79.7 1.02 43.1 38.2 1.37 38.9 M-29 48 0.57 0.50 88.88 91.6 87.6 87.0 88.7 1.00 60.2 52.9 1.97 46.8 M-30 48 0.85 0.62 73.90 81.7 85.2 85.8 84.2 1.14 48.5 39.2 0.20 38.6 M-31 48 0.59 0.36 62.26 77.4 78.6 78.9 78.3 1.26 32.5 26.4 0.58 38.9 M-32 48 0.72 0.52 72.55 84.1 82.4 82.0 82.8 1.14 40.0 31.6 0.74 27.0 M-33 48 0.47 0.34 71.52 78.4 77.4 77.1 77.6 1.09 48.1 43.0 1.71 71.0 M-34 48 0.76 0.57 74.71 80.9 80.2 80.0 80.4 1.08 51.6 42.7 1.66 41.8 M-35 48 1.04 0.61 58.81 73.9 72.1 71.5 72.5 1.23 46.2 35.5 0.74 12.3 M-35 72 1.04 0.61 58.81 70.3 71.2 71.5 71.0 1.21 52.3 42.1 0.74 12.3 M-36 48 0.42 0.34 80.79 85.0 81.5 80.8 82.4 1.02 59.1 54.1 2.16 46.1 M-37 48 1.84 1.56 84.63 89.7 86.2 85.6 87.2 1.03 79.8 56.8 2.39 71.2
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Note: Sol. Ratio = Soluble ratio, Rec = Recovery
13.1.2.4 Conclusions
The samples tested extracted 4 percentage points more copper than their copper solubility ratio. On average, the total Cu extraction was 84.13% and the average solubility ratio was 79.4%. It can be inferred therefore that under the test conditions a fraction of the acid insoluble copper was dissolved. The net (Gangue) acid consumption averaged 39.3 kg/t for the 37 composites.
13.2 Current and Future Tests
13.2.1 Geomet IV
A fourth metallurgical testing program, Geomet IV, is currently being conducted. This plan uses composite samples from the updated mineral subzones (BROC/ATAC, CRIS, WAD, MIX and ENR) with different levels of copper solubility ratio. Tests include Head Chemical Characterization with sequential copper analysis, particle size characterization, 1.5 iso-pH test with and without seawater, acid and chloride leaching tests in 30 cm mini-columns, four 1.5 m columns and ROM leaching in 1 m 3 iso-containers of a WAD and ferrous oxide low- grade sample with lesser presence of chrysocolla, atacamite and sulphides.
Mini-Column Testing Preliminary Results
Material from 15 composite samples, taken from across the Marimaca deposit, were subjected to 30cm column leach tests to identify total recovered copper and total acid consumption as shown on Figure 13-6. Several different testing parameters were used, including agglomerating with and without NaCl. The results were very favourable, indicating strong recoveries and relatively fast leach kinetics across all samples, relative to the acid soluble copper ratios for the samples. Virtually all samples recovered in excess of the acid solubility ratios, in the case of the Mixed mineral sub-zone, quite materially.
Of note, numerous samples from the brochantite, chrysocolla and copper wad zones observed total copper recoveries exceeding the calculated leaching potential of the samples. This is due to black oxides in these zones, which are acid soluble but have slower leach kinetics and, therefore, are not detected in the acid soluble copper test.
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Figure 13-6: Mini-columns Total Copper Recoveries.
Note: Figure prepared by Marimaca Copper, 2020.
1.5 meters Column Testing Preliminary Results
Testing was completed on three composite samples taken from a variety of areas across the Marimaca deposit. A total of four 1.5 m columns were completed. For Oxide and Combined samples, no additional NaCl was added; for the Combined and Sulphide materials, 15 kg/t of NaCl was added during agglomeration.
Again, the results were favourable, with relatively fast leach kinetics and three of the four columns achieving total copper recoveries in excess of 70% within 60 days (Figure 13-7). One sample, which comprised primarily oxides, which are the dominant copper bearing mineral species in the deposit, reached recoveries exceeding 80% within approximately 40 days.
It was noted that there is a linear relationship between time and acid consumption (Figure 13-8), and that a higher material height produced a lower specific acid consumption while still achieving the recovery rates observed in the testing program. This should allow further optimization of design to lower overall acid recoveries.
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Figure 13-7: 1.5 meters Columns Total Copper Recoveries.
Note: Figure prepared by Marimaca Copper, 2020.
Figure 13-8: 1.5 meters Columns Net Acid Consumption.
Note: Figure prepared by Marimaca Copper, 2020.
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13.2.2 Metallurgical Variability Analysis Plan
Currently, work is underway to design a test plan to evaluate the metallurgical variability of the deposit using RC drilling samples that spatially reflect the complete deposit and selected core samples. For these tests a complete head characterization, iso-pH test and additional columns from the samples are planned.
13.2.3 Metallurgical Parameters Optimization
By the end of 2020 or the beginning of 2021, additional metallurgical tests will be carried out to optimize the metallurgical parameters determined with previously developed test programs complemented by current testing programs.
These parameters will include, but are not limited to, agglomeration conditions, column height, particle size distribution, irrigation rate, acid concentration and cycle time.
13.3 Industrial Metallurgical Models
13.3.1 Copper Recovery
13.3.1.1 2020 PEA Copper Recovery
Table 13-8 shows the copper recoveries considered in the block model for the 2020 PEA evaluation by mineral type (calculated over the total copper content of the material that will be processed).
Table 13-8: Total Copper Recoveries used in Block Model and PEA Mineral Feed Plan.
Mineral subzone Predominant CuT Recovery Dynamic (SZmin) species Heap BROC/ATA Brochantite/Atacamite 82% CRIS Chrysocolla 77% WAD Copper Wad 65% MIX Mixt 62% ENR Enriched 49% Average 76%
The values for total copper recovery were defined taking into consideration the copper recovery results of the Geomet I and III iso-pH tests, as well as results from Geomet I and II crushed columns (Figure 13-9, Figure 13-10, Figure 13-11 & Figure 13-12) and expectations regarding the influence of seawater use and salt addition during agglomeration. The Geomet IV experimental program included tests with and without salt addition in agglomeration to confirm these assumptions.
Table 13-9: Summary Results CuT Rec. and Acid Consumption Geomet I and II
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Average total copper recovery in iso-pH tests is 79.9%, therefore being higher than the value considered in the current mine plan. The tests on 1m high columns show an average of 72.8% for a time of 35 days, these copper dissolution kinetics (Figure 13-9) show that it is possible to achieve an additional recovery delta for a longer time (positive marginal values). The 1.6 to 3.0 m columns for a 61-day leaching time show an average of 77.4%.
Figure 13-9: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Days).
Note: Figure prepared by Jo & Loyola Process Consultants, 2020.
Figure 13-10: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Leaching Ratio).
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 13-11: CuT Recovery and Net Acid Consumption P90 ½” Geomet II Columns (vs Days).
Note: Figure prepared by Marimaca Copper, 2020.
Figure 13-12: CuT Recovery and Net Acid Consumption P90 ½” Geomet I Columns (vs Leaching Ratio).
Note: Figure prepared by Marimaca Copper, 2020.
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In column testing of crushed materials, the highest total copper recoveries correspond to minerals from the oxidized mineral subzones BROC/ATA and CRIS with recoveries close to 80%, followed by the WAD type samples with 70% and the MIX sample with a value closer to 60%.
To scale up these results to deeper columns and longer leaching times, a dynamic METSIM model was built by Jo y Loyola Process Consulting based on the experimental data. The copper dissolution and acid consumption kinetics dependency with the acid concentration were established. The model was calibrated using the experimental data and the total copper recovery and acid consumption kinetics for different depth of bed and leaching times were calculated. The 4 m column model results and the expected total copper recoveries show a good consistency across all different mineral subzones (Figure 13-13).
Figure 13-13: Total Copper Recovery and Net Acid Consumption Kinetics for a 4 meters Column (Model).
Note: Figure prepared by Marimaca Copper, 2020.
The BROC/ATA mineral subzone has a predominant species of atacamite and brochantite, which are highly soluble in sulphuric acid and therefore result in high recoveries through leaching. The mineral subzone CRIS is mainly composed of chrysocolla, a copper silicate with high solubility, although slightly less than atacamite. The WAD subzone is dominated by copper wad which corresponds to a less soluble oxide and therefore lower recoveries are to be expected. In the MIX minerals, in addition to some oxides, there is a significant presence of secondary copper sulphides, which have a low solubility in sulphuric acid but a high solubility in the ferric/chloride environment. Finally, the minerals in the ENR subzone correspond mainly to secondary copper sulphide.
For all minerals, but particularly for those in the MIX and ENR subzones, an estimated total copper recovery is considered for mine planning. This planning incorporates the effect of leaching the secondary sulphide in an acid chloride environment and therefore, recoveries above the sulphuric acid solubility ratio are expected, moving the target towards the "Leach Potential = CuS + CuCN”. Such potential corresponds to the sum of the soluble copper in sulphuric acid and sodium cyanide (determined by a “sequential” copper analysis) and can be
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considered equivalent to the content of acid soluble oxides and secondary sulphide present in the material.
Subsequent to the date when total copper recoveries were defined for the evaluation of the 2020 PEA mine plan, the cyanide soluble copper content was incorporated into the mine block model using the values available in the drilling database. This work is reflected in the report “Cyanurable Copper Estimate for the Marimaca Copper Project, Antofagasta Province, Region II, Chile” elaborated by NCL Engineering and Construction SpA in January 2020.
This report indicates it is possible to verify at the mine-block level the presence of secondary sulphide and thus the appropriate use of leaching in the chloride environment for the project. This planning includes the subzones which are predominantly MIX and ENR, but also includes other subzones where these materials may be elevated (>10%). The pertinent values are summarized in Table 13-10
Table 13-10: Solubility Block Model by Mineral Sub-Zone (different cut-off grades).
Cyanide Cu Mine Plan Leaching Solubility Ratio Ratio CuT Mineral Potential (%RS) (%) Recovery Subzone (%) Oxides Secondary (%) Oxides + SS Sulphide BROC/ATA 62–71 12–20 82–83 82 CRIS 69–72 10–16 82–87 77 WAD 49–58 7–27 61–80 65 MIX 20–27 46–52 72–73 62 ENR 18–21 45–47 65–68 49
The ROM will treat a low-grade oxide material mostly of the WAD type. Based on benchmark values, a total copper recovery of 40% is defined. This value must be corroborated with experimental results from metallurgical tests that adequately reflect the proposed process design.
13.3.1.2 Future Copper Recovery Models (Post-2020 PEA)
The development of metallurgical copper recovery models for the Marimaca deposit under optimized processing conditions is being considered for the future.
The next stages will include the development of models based on:
Chemical material characterization dependent model with differentiated dissolution factors for CuS, CuCN and CuRes fractions and with factors dependent on the operational conditions used. Mineralogy dependent model with dissolution factors by species and with factors dependent on the operational conditions being used.
These models will be continuously improved as more information becomes available from the Geomet IV metallurgical tests, variability analysis plan and metallurgical optimization tests.
This modelling is becoming a powerful tool for the evaluation and planning of the project, substantially improving the predictive capacity of the behaviour of minerals in comparison to the criteria used in the 2020 PEA. Some positive aspects that will be considered in the future are optimized particle size distribution, chloride leaching, a better understanding of the mineralogical copper species and its behaviour for the mineral types.
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13.3.2 Acid Consumption
13.3.2.1 2020 PEA Acid Consumption
The following sections contain estimates for sulphuric acid consumption in the Marimaca Project, differentiating between oxide and sulphide materials.
Using the identified trends, an estimated net (Gangue) acid consumption of 40 kg/t for oxide (BROC/ATA, CRIS y WAD) and 35 kg/t for sulphide materials (MIX y ENR) were defined. Those values must be corroborated in future metallurgical characterization and optimization programs.
To optimize the project base case, a strategy to reduce the acid consumption will be evaluated. Options such as those described by (Scheffel, Miller) will be investigated. The idea is to match the acid concentration to the demand of the material during the leach cycle. Given that acid concentration affects the kinetics of acid consumption, options of higher irrigation rate at lower acid concentration is one such option. Both the acid concentration and copper retained by ripios moisture will also be optimized in future testing.
Another aspect that is important to consider is the impurities dissolution from the mineralization because, a higher concentration of impurities in the leaching solution produces a slower dissolution of the impurities from the minerals reducing the reaction of the gangue. The leaching tests were not performed with equilibrium leaching solutions so some decrease in acid consumption can be expected from this effect.
Estimation of Sulphuric Acid Consumption for Oxide Materials
The results of the Geomet I and II column testing indicate that the net acid consumption, under the conditions used for the 1.5 to 3.0m column depth and 50 days of irrigation at a rate of 10 L/h/m2 and 10 g/L of acid average in the range of 40 to 50 kg/t. The summary of these results is presented in Table 13-5. The acid consumption rate is shown in Figure 13-2, Figure 13-3, Figure 13-4 and Figure 13-5 and its connection to the acid fed to the columns in Figure 13-14 and Figure 13-15.
The experimental data indicate a reduction in the specific acid consumption, kgH 2SO 4/t, when the column height increases from 1 to 3 m. This is due to the effect of the acid concentration has on the gangue reaction kinetics. As the acid concentration in equilibrium with the material decreases the acid consumption rate decreases. There is an acid profile through the mineral bed decreasing from the top to the bottom and changing with time allowing the acid to reach the lower fraction of the bed. According to the METSIM model, an equivalent acid consumption is achieved with a 4 m column and 95 leaching days, which is the current process definition (Figure 13-11).
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Figure 13-14: Net Acid Consumption P90 ½” Geomet I Columns vs Added Acid.
Note: Figure prepared by Marimaca Copper, 2020.
Figure 13-15: Net Acid Consumption P90 ½” Geomet II Columns vs Added Acid.
Note: Figure prepared by Marimaca Copper, 2020.
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Seven samples of the deposit were used in this acid consumption testing, six of which could be classified as oxidized mineral from subzones (BROC/ATA, CRIS and WAD) and one as a mixed mineral (MIX). All of gave solubilities in sulphuric acid that were higher than the average values expected according to 2020 PEA mine plan (Figure 13-16). This means that the samples have a higher proportion of oxidized minerals than the expected composition of the material in the process, at the expense of the sulphide fraction.
Figure 13-16: Mine Plan Solubility Ratio by Mineral Subzone.
Note: Figure prepared by Marimaca Copper, 2020.
A key objective for the Project will be to optimize operating conditions in to control acid consumption. Parameters such as the following must be improved: particle size, heap height, acid dosage in agglomeration, irrigation and frequency rate and the acid concentration in the leaching solution.
Additionally, strategies aimed to adjust the leaching time and acid concentration of the solutions in contact with the material, such as those described by (Scheffel, Miller), will be investigated.
Preliminary but consistent results of the Geomet IV tests show a dependence of the acid consumption rate with the acid concentration in irrigation, which can be used to optimize consumption through changes in operational conditions.
On this basis, and considering the optimization aspects, an average acid consumption for the project of 40 kg/t for oxide and 35 kg/t for sulphide materials were used for the 2020 PEA evaluation. These values must be corroborated with future metallurgical characterization and optimization programs.
Estimation of Sulphuric Acid Consumption of Sulphide Materials
In general, in copper deposits, the oxide mineral gangue consumes more acid than sulphide mineral gangue. To date, Marimaca Copper's experimental programs have been oriented towards the characterization of oxide materials. However, the Marimaca deposit contains
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resources with secondary sulphide content that contributes to the 2020 PEA mining plan, i.e., < 20% of the plant feed.
Considering that the samples used in the column tests with crushed material are mainly oxidized materials, the results of the iso-pH tests from Geomet I and III are used for this estimation, which significantly increases the number of samples characterized.
A total of 44 samples were used in the Geomet I and III metallurgical programs (refer to Table 13-11). It is observed that these were mainly oxides bearings with a ratio of acid soluble copper over 59%.
According to their mineralogical classification, 43 of the samples correspond to mineral subzones BROC/ATA, CRIS and WAD and one to the MIX subzone. The sample classified as MIX shows a ratio of acid soluble copper of 69%, suggesting an oxidized mixed material.
It is necessary to gain a better understanding of the solubility ratio versus the acid consumption for the sulphide material to see if a usable correlation can be developed.
There is no correlation between the AAC and the solubility ratio (Figure 13-17), observing high and low values in the whole range of solubility ratio of the characterized samples.
For the net acid consumption of the iso-pH tests, there is a slight tendency for decreasing net acid consumption when the acid copper solubility ratio decreases (Figure 13-18).
Figure 13-17: AAC vs Solubility Ratio.
Note: Figure prepared by Marimaca Copper, 2020.
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Figure 13-18: iso-pH Geomet I, II & III Gangue Acid Consumption vs Solubility Ratio.
Note: Figure prepared by Marimaca Copper, 2020.
To expand the analysis of this trend, in Table 13-11, the maximum and minimum average values are presented for iso-pH test results subdivided between those with a higher and lower RS than the average of the 2020 PEA mine plan, which assumes 64%.
Although only 3 of the 44 samples were below this value, it is possible to see that total (CHT) and gangue (CHG) acid consumptions are on average lower than the average of those samples with higher solubility, 12.1 and 10.3 kg/t less respectively.
It should be emphasized that the values of these characterizations with pulverized or granulated samples are indicative values of the industrial acid consumption but not necessarily directly related to this parameter.
Considering this trend evidenced by the samples with the lowest solubility ratio, assuming them to have a higher proportion of the sulphide copper, a net acid consumption of 35 kg/t is preliminarily estimated for sulphide, a reduction in relation to the 40 kg/t for oxide materials. This value needs to be better defined with future metallurgical characterization and optimization programs.
13.3.2.2 Future Acid Consumption Models (Post-2020 PEA)
The development of metallurgical models for the acid consumption under the currently assumed process conditions is ongoing, particularly considering the chloride leaching environment and more knowledge about the mineral types.
The next stages of the project include the development of a model dependent on the chemical characterization, copper-bearing species and the gangue mineralogy, as well as the operational conditions used.
This model will be refined as more information becomes available from metallurgical testing.
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Table 13-11: Summary CuT Rec. and Acid Consumption iso-pH Test Geomet I and III.
13.3.2.3 Dissolution and Impurity Balances
To determine the possible sources of impurities in the leach circuit, it is appropriate to review the mineral characterization and the gangue composition.
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Table 13-12 shows the mineralogical copper distribution of the seven characterized samples used in the Geomet I and II tests.
Table 13-12: Distribution in Mineral Weight (Samples Marimet 1 to 7).
Minerals Formula Marimet 1 % Marimet 2 % Marimet 3 % Marimet 4 % Marimet 5 % Marimet 6 % Marimet 7 %
Chalcopyrite CuFeS 2 0.01 0.04 - 0.06 0.03 0.10 0.04
Chalcocite Cu5Fe2+S4 - 0.08 0.06 0.0019 - 0.04 0.10 Covelline CuS - 0.31 - - 0.003 - 0.10 Bornite Cu5Fe2+S4 - 0.02 - - - 0.04 0.02
Copper Wad Cu-Mn-Si Oxides 0.30 0.37 0.31 0.20 0.26 0.30 0.30
Atacamite Cu2(OH)3Cl 0.91 1.43 0.32 0.84 1.26 0.58 0.56 Chrysocolla (Cu,Al)2H2Si2O5(OH)4 0.34 0.25 0.13 0.29 0.44 0.16 0.11 Malachite Cu2(CO3)(OH)2 0.02 0.19 - 0.10 - - - Pyrite FeS2 0.004 0.02 0.49 0.07 0.07 0.08 0.42 Magnetite Fe3O4 - 0.41 0.44 0.52 0.26 0.16 0.15 Hematite Fe2 O3 6.45 8.78 8.53 7.33 7.64 6.11 5.42 Limonite FeOH 2.12 3.29 2.22 0.63 3.15 0.69 0.85 Rutile Ti O2 - 0.34 0.27 0.56 0.15 0.32 0.19 Clay Al4 (Si4O10)(OH)3 10.67 10.29 9.37 10.72 9.64 9.93 10.46 Chlorite (Mg,Al)3(AlSi3O10)(OH)2Mg3(OH) 6 7.69 5.25 7.11 5.51 4.03 5.36 5.69 Amphibole Ca2Mg4Al0.75Fe3+0.25(Si7AlO22)(OH)2 - 0.63 - - 1.75 1.80 0.64 Apatite Ca5(PO4)3(OH)0.33F0.33Cl0.33 - - - - 0.47 0.49 - Sericite KAl2(AlSi3O10)(OH)2 6.31 3.75 5.73 5.30 6.24 6.46 3.50 Plagioclase NaAlSi3O8 12.08 10.69 12.32 12.61 8.01 8.25 10.86 Feldspar NaAlSi3O8 22.62 25.73 25.31 28.32 33.74 34.77 31.38 Biotite K(Mg,Fe++)3[AlSi3O10(OH,F)2 1.23 0.19 0.44 0.44 0.27 0.30 - Calcite CaCO3 2.21 3.44 3.13 2.82 1.08 1.91 1.95 Quartz SiO2 22.16 21.37 16.42 17.86 18.02 18.57 21.73 Epidote CaSrAl2Fe+++(Si2O7)(SiO4)O(OH) 2.64 2.42 6.20 4.50 3.09 3.18 2.74 Tourmaline NaMg3Al6(BO3)3Si6O18(OH)4 0.64 0.25 0.22 0.42 - - 1.26 Plaster Ca(SO4)•2(H2O) 1.43 0.46 0.41 0.89 0.26 0.26 0.93 Jarosite KFe3+3(SO4)2(OH)6 0.17 - 0.55 - 0.14 0.14 0.61 Total 100.00 100.00 100.00 100.00 100.00 100.00 100.00
Sulphide minerals are identified in most of the samples albeit at low but sufficiently significant amount a to play a role in soluble copper content. In samples Marimet-2 and Marimet-7, chalcopyrite, chalcocite, covellite and bornite were observed. In the Marimet-1 sample only chalcopyrite was observed, while in Marimet-3 only covelline. In the Marimet-4 sample, chalcopyrite and chalcocite were observed, while in Marimet-6 chalcopyrite, covellite and bornite were observed, as well as pyrite, except in the samples Marimet-3 and Marimet-7, where it is more frequently observed.
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In the Marimet-1 sample only chalcopyrite was observed, while in Marimet-3 only covellite was noted. In the Marimet-4 sample, chalcopyrite and chalcocite were observed, while in Marimet-6 chalcopyrite, covellite and bornite were observed, as well as pyrite, except in the samples Marimet-3 and Marimet-7, where is more frequently observed.
The samples have a high concentration of hematite, fluctuating in the range of 5.42–8.78%. Limonite, varying between 0.63–3.29% was observed. Pyrite and magnetite were detected at low levels.
Considering the area where the deposit is located, moderate levels of calcite are observed, in the range of 1.08–3.44%. This is a particularly relevant characteristic considering its impact on the acid consumption. This observation is repeated when analysing the carbonate contents obtained in the head characterization of the 43 samples used in Geomet I, II and III, which fluctuate within the range 0.05–3.96%, as shown in Table 13-13 and Table 13-14.
Table 13-13: Head Chemical Characterization Geomet I and II Samples.
CuT CuS Rz FeT Al Mg Mn Cl CO 3 CAA Sample (%) (%) (%) (%) (%) (%) (%) (%) (%) (kg/t) Marimet-1 0.87 0.73 83.87 9.19 8.27 1.09 0.08 0.23 1.00 48.69
Marimet-2 1.50 1.13 75.42 10.69 7.99 1.05 0.09 0.31 1.67 32.49
Marimet-3 0.45 0.26 57.77 11.16 8.01 1.17 0.08 0.26 1.48 53.31
Marimet-4 0.85 0.71 83.99 8.38 8.44 1.16 0.05 0.22 1.28 39.33
Marimet-5 1.16 0.98 84.47 9.76 8.37 0.99 0.07 0.34 0.50 39.37
Marimet-6 0.61 0.44 71.56 7.58 8.71 1.10 0.08 0.24 0.49 30.12
Marimet-7 0.63 0.40 64.19 7.32 8.04 1.28 0.08 0.26 1.08 23.20
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Table 13-14: Head Chemical Characterization Geomet III Samples.
CuT CuSH+ Rz FeT Al Mg CAA CO 3 AlS FeTS MgS Nº (%) (%) (%) (%) (%) (%) (kg/t) (%) (%) (%) (%) 1 1.01 0.81 80.00 6.72 6.85 1.28 28.82 0.15 0.16 0.28 0.04 2 0.74 0.48 64.73 7.33 6.59 1.19 35.54 0.15 0.17 0.38 0.05 3 0.37 0.26 70.05 6.27 6.87 1.42 48.15 1.10 0.13 0.27 0.06 4 0.87 0.55 63.35 9.15 6.79 0.96 37.85 0.05 0.16 0.27 0.04 5 1.66 1.36 81.64 8.92 6.18 1.02 40.25 0.05 0.18 0.39 0.04 6 1.13 0.87 77.10 7.55 6.94 1.46 50.32 0.45 0.18 0.26 0.05 7 0.67 0.53 79.54 5.84 6.77 1.37 37.45 0.40 0.14 0.31 0.07 8 0.61 0.47 76.78 6.07 6.94 1.50 34.55 0.60 0.16 0.35 0.06 9 1.05 0.96 90.93 6.57 6.79 1.47 48.22 0.10 0.19 0.38 0.06 10 0.65 0.56 86.27 4.84 6.78 1.29 52.23 0.40 0.14 0.32 0.05 11 0.50 0.43 85.03 7.23 7.10 1.35 36.76 0.82 0.18 0.48 0.07 12 0.46 0.37 81.08 6.48 7.05 1.00 37.46 0.86 0.19 0.49 0.06 13 0.62 0.48 77.56 7.40 6.35 0.89 35.29 1.05 0.20 0.48 0.08 14 1.77 1.63 91.90 6.24 6.69 0.68 83.04 1.90 0.15 0.29 0.05 15 1.32 1.09 82.39 5.94 7.45 1.09 69.18 2.48 0.15 0.29 0.06 16 0.83 0.63 75.55 7.57 6.48 0.63 70.75 2.62 0.16 0.23 0.05 17 0.38 0.28 74.84 5.76 6.49 0.98 74.97 3.86 0.15 0.37 0.07 18 0.78 0.68 87.42 7.70 6.28 1.03 61.07 0.32 0.24 0.52 0.09 19 0.54 0.45 82.54 6.62 6.60 1.58 58.08 1.65 0.23 0.49 0.16 20 1.14 0.90 78.78 7.37 6.23 1.11 68.36 2.57 0.19 0.47 0.15 21 0.82 0.72 88.46 8.24 6.46 1.01 30.51 4.34 0.20 0.53 0.11 22 1.18 1.09 92.83 7.86 6.34 1.10 44.48 2.13 0.23 0.54 0.12 23 1.65 1.58 95.62 6.61 6.32 0.85 86.53 3.96 0.20 0.43 0.09 24 1.62 1.41 86.82 7.08 6.46 0.90 37.31 0.31 0.27 0.51 0.08 25 0.40 0.31 77.70 4.91 6.66 1.19 18.12 0.59 0.12 0.32 0.06 26 1.05 0.87 82.83 6.02 6.44 1.30 49.38 0.36 0.18 0.39 0.09 27 0.54 0.43 80.36 4.46 6.59 1.31 33.18 0.63 0.13 0.31 0.07 28 0.43 0.33 78.32 6.43 6.81 1.49 38.90 1.37 0.16 0.40 0.10 29 0.57 0.50 88.88 6.92 6.70 1.56 46.83 1.97 0.17 0.45 0.10 30 0.85 0.62 73.90 7.23 7.34 1.35 38.63 0.20 0.18 0.41 0.06 31 0.59 0.36 62.26 6.03 7.17 1.12 38.87 0.58 0.14 0.26 0.04 32 0.72 0.52 72.55 6.86 7.14 1.22 26.95 0.74 0.17 0.41 0.05 33 0.47 0.34 71.52 5.57 7.12 1.22 71.01 1.71 0.12 0.27 0.05 34 0.76 0.57 74.71 6.29 6.91 1.04 41.76 1.66 0.14 0.32 0.05 35 1.04 0.61 58.81 9.75 6.89 1.09 12.31 0.74 0.18 0.35 0.07 36 0.42 0.34 80.79 6.92 6.20 1.27 46.09 2.16 0.14 0.33 0.07 37 1.84 1.56 84.63 6.04 6.06 0.72 71.18 2.39 0.16 0.22 0.10
Notwithstanding this moderate carbonate content, it can also be seen from the chemical characterizations that the analytical acid consumption is in the medium to high range. Therefore, it is important to determine where this consumption comes from, which was also
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observed in the results of the respective metallurgical tests, iso-pH and columns when available
Another important observation from the experimental results was that the acid consumption increases linearly with time of contact with acid solution. This trend was evidenced at the test level with both pulverized and crushed material, in all of them the longer the time the greater the consumption. Therefore, an understanding of their operational control will be key in the development of the project in reducing acid consumption. Preliminary Geomet- IV results also show a dependency of the acid consumption rate on the acid concentration of the irrigation solution.
The total acid consumption can be broken down into its different sources according to the following expression: