Final Environmental Impact Assessment Report & Environment Management Plan for Proposed Project for manufacturing of Dye Intermediates – 3049 MTPM

by Orgosynth Chemicals Pvt. Ltd. at

Plot No. J-50, J-51, J-52 and J-53, MPIDC Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh

Project Activity: 5(f), Category: A ToR Letter No. F. No. J-11011/249/2020-IA-II(I) (Study Period: October, 2020 to December, 2020)

Prepared by

San Envirotech Pvt. Ltd. Accredited QCI-NABET Consultant (NABET Accreditation No. NABET/EIA/1619/RA0084; Valid till 26.08.2021) MoEFCC Recognized Environmental Laboratory under EP Act, 1986 Address: 424, Medicine Market, Paldi Cross Road, Ahmedabad-380006, Gujarat Email: [email protected] (July, 2021)

Document No. Revision No. Issue No. Release on EIA/SEPL/2020/OCPL/27 -- 01 27/01/2021 EIA/SEPL/2021/OCPL/29 01 02 29/07/2021

San Envirotech Pvt. Ltd., Ahmedabad Contents Particulars Page No. Index I List of Tables X List of Figures XIII List of Annexures XV Index Chapter 1 Introduction Page No. 1.1 Preface 1-1 1.2 Purpose of the Report 1-1 1.3 Identification of Project & Project Proponent 1-2 1.4 Importance of the project 1-3 1.5 Brief description of project 1-3 1.6 Applicable Environmental Regulatory Framework 1-5 1.7 Scope of the study 1-5 1.8 Compliance to terms of reference 1-6 1.9 Objective of EIA 1-22 1.10 Methodology for EIA 1-22 1.11 List of industries surrounding project site 1-23 1.12 Structure of report 1-24 Chapter 2 Project Description 2.1 Introduction 2-1 2.2 Need For The Project 2-1 2.3 Location of The Project 2-2 2.4 Size or magnitude of operation 2-5 2.4.1 Land breakup & project site layout 2-5 2.4.2 Project Magnitude 2-7 2.5 Infrastructure Facilities (Proposed plant Equipments/ 2-8 machineries) 2.6 Description of manufacturing process 2-8 2.7 Project Components 2-39 2.8 Input Requirements 2-39 2.9 Generation of pollutants 2-44 2.9.1 Wastewater generation 2-44

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2.9.2 Gaseous emission 2-44 2.9.3 Hazardous & solid waste generation 2-46 2.9.4 Noise Generation 2-46 2.10 Pollution control strategy 2-47 2.10.1 Effluent Management 2-47 2.10.2 Air Pollution Control(APC) Measures 2-49 2.10.3 Hazardous/Solid Waste Management 2-50 2.10.4 Noise Pollution Control Measures 2-50 2.11 Rain Water Harvesting 2-51 2.12 Green Belt Development 2-51 2.13 Occupational Health & Safety 2-51 Chapter 3 Description of Environment 3.1 General 3-1 3.2 Study area 3-1 3.3 Study Period 3-2 3.4 Source of environmental data generation 3-2 3.5 Methodology 3-2 3.6 Land Environment 3-3 3.6.1 Land use pattern of the Study Area 3-3 3.6.2 Objective of Land Use Studies 3-3 3.6.3 Topography 3-5 3.6.4 Seismicity of the area 3-5 3.7 Meteorology 3-6 3.7.1 Site specific micro-meteorological data 3-6 3.7.2 Wind Rose 3-7 3.8 Ambient air quality 3-8 3.8.1 Introduction 3-8 3.8.2 Design Network for Ambient Air Quality Monitoring 3-8 Stations 3.8.3 Reconnaissance 3-8 3.8.4 Parameters, Frequency and monitoring Methodology 3-8 3.8.5 Interpretation of the result 3-10 3.9 Water Environment 3-11 3.9.1 Hydro-Geology of the Study Area 3-11 3.10 Water quality 3-12 3.10.1 Introduction 3-12

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3.10.2 Sampling Frequency, Techniques & Methodology 3-13 3.10.3 Surface Water Quality (Primary data) 3-14 3.10.4 Ground Water Quality 3-14 3.10.5 Interpretation 3-14 3.10.6 Conclusion 3-15 3.11 Noise Environment 3-15 3.11.1 Instrument used for Sampling and Monitoring 3-15 3.11.2 Noise Quality Monitoring Locations 3-16 3.11.3 Ambient Noise Standards 3-16 3.11.4 Results 3-16 3.11.5 Conclusion 3-16 3.12 Soil Environment 3-17 3.12.1 Soil sampling locations 3-17 3.12.2 Methodology 3-17 3.12.3 Corollaries 3-18 3.12.4 Conclusion 3-19 3.13 Biological Environment 3-19 3.13.1 Period of the study 3-20 3.13.2 Study methodology 3-20 3.13.3 Floral species in the study area 3-20 3.13.4 Fauna in the study area 3-20 3.14 Socio Economic Environment 3-21 3.14.1 Objective of the study 3-21 3.14.2 Land use pattern and infrastructure 3-22 3.14.3 Demographic and Socio-Economic Environment 3-22 3.14.4 Living Standard and Infrastructure 3-23 Chapter 4 Anticipated Environmental Impacts & Mitigation Measures 4.1 General 4-1 4.2 Identification of Impact 4-2 4.2.1 Identification of Impacting Activities 4-2 4.2.2 Identification of Environment Attributes 4-3 4.3 Impact on Topography 4-3 4.4 Impact on Air Environment 4-3 4.4.1 Air Pollution Dispersion modeling of stack 4-4 4.4.2 Micrometeorology 4-5

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4.4.3 Input data 4-6 4.4.4 Receptor Network 4-6 4.4.5 Output of Model (24-hourly GLCs) 4-7 4.4.6 Incremental & cumulative concentration of pollutants 4-7 4.4.7 Conclusion 4-7 4.5 Impact on Water Environment 4-8 4.6 Impact on Noise Environment 4-9 4.7 Impact on Land Environment 4-10 4.8 Impact on Biological Environment 4-11 4.9 Impact on Socio-Economic Environment 4-12 4.10 Impact on Occupational Health & Safety 4-13 4.11 Impact On Traffic Movement 4-14 Chapter 5 Analysis of Alternatives 5.1 Prologue 5-1 5.2 Site Alternative 5-1 5.3 Process Alternative 5-2 Chapter 6 Environmental Monitoring Program 6.1 Prelude 6-1 6.2 Environment Monitoring Program 6-1 6.3 Objective of Monitoring Plan 6-1 6.4 Schedule for Environment Monitoring 6-2 6.5 Ambient Air Quality Monitoring 6-2 6.6 Water Environment Monitoring 6-3 6.7 Noise Environment Monitoring 6-3 Chapter 7 Additional Studies (A) Public Consultation 7-1 (B) Hazard Analysis & Risk Assessment 7-13 7.1 Introduction 7-13 7.2 Risk Assessment- Identification of Hazards 7-13 7.3 Hazardous Materials Storage 7-15 7.4 Risk Screening Approach 7-16 7.4.1 Acute Exposure Guideline Levels (AEGLs) 7-19 7.4.2 Emergency Response Planning Guidelines (ERPGs) 7-20 7.5 QRA Approach 7-21 7.6 Thermal Hazards 7-22 7.7 Damage due to explosion 7-23

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7.8 Toxic release 7-23 7.9 Acid/Alkali Hazards 7-24 7.10 Likely Failure Scenarios 7-25 7.11 Quantitative Risk Assessment & Consequence Analysis 7-25 7.11 Preamble 7-25 7.11.2 Weather Effect 7-26 7.12 Incidents Impacts 7-26 7.13 Consequential Impacts 7-32 7.13.1 Thermal and Explosion Hazards 7-32 7.13.2 Toxic Hazards 7-32 7.13.3 Other Hazards 7-32 7.13.4 Other Toxic Hazards 7-32 7.14 Occupational Health 7-33 7.15 Conclusion & Recommendations 7-34 7.16 Action plan for handling & safety system of Chemical 7-35 7.16.1 Safety Measures for Transportation and Unloading of 7-35 Hazardous Chemicals 7.16.2 Safety Measures for Storage/Handling of Hazardous 7-36 Chemicals 7.16.3 Safety Measures for Process Units 7-36 7.16.4 Safety Measures for Preventive Maintenance 7-37 7.16.5 Safety measures to prevent spillage/leakage of toxic 7-37 chemicals 7.17 Arrange ments for ensuring health & safety of workers 7-38 engaged in handling of toxic materials 7.18 Disaster Management Plan (DMP) 7-39 7.18.1 Definitions 7-40 7.18.2 Objective of the Disaster Management Plan 7-41 7.19 Onsite Emergency Plan 7-41 7.19.1 Incident Controller 7-41 7.19.1.1 Duties of Incident Controller 7-41 7.19.2 Site Main Controller 7-42 7.19.2.1 Duties of Site Main Controller 7-42 7.19.3 Other Key Personnel 7-43 7.19.3.1 Emergency Response Team 7-43 7.19.3.2 Emergency personnel’s Responsibilities outside Normal 7-44 Working Hours of the Factory 7.19.3.3 Assembly Points 7-44

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7.19.4 Emergency Control Centre 7-44 7.19.4.1 Role of Emergency Control Centre 7-44

7.19.5 Fire & Toxicity Control Arrangements 7-45

7.19.6 Medical Arrangements 7-45

7.19.7 Transport & Evacuation, Mutual Aid Arrangements 7-45

7.20 Communication System 7-45

7.20.1 Declaring the Emergency 7-45 7.20.1.1 Type of Sirens 7-45 7.20.1.2 Location of Siren 7-46 7.20.1.3 Raising alarm 7-46 7.20.2 Internal Communication 7-47 7.20.2.1 Availability of Key Personnel outside Normal Working 7-47 Hours 7.20.3 Communication to the Authorities 7-48

7.21 Pre-emergency Activities 7-48

7.22 Post-emergency Activities 7-48

7.22.1 Evacuation and Transportation 7-48 7.22.2 Safe Close Down 7-48

7.22.3 Use of Mutual Aid 7-49

7.22.4 Use of External Authorities 7-49

7.22.5 Medical Treatment 7-49

7.22.6 Accounting for Personnel 7-49

7.22.7 Access to Records 7-49

7.22.8 Public Relations 7-49 7.22.9 Rehabilitation 7-49 7.23 Causes of emergency 7-50 7.23.1 Risk 7-50 7.23.1.1 Nature 7-50 7.23.1.2 Various emergency actions 7-50 7.23.1.3 Response time-minutes 7-51 7.24 Off-site emergency plan 7-51 7.24.1 Need of the site emergency plan 7-51

7.24.2 Structure of the off-site emergency plan 7-52

7.24.3 Role of the Factory Management 7-52

7.24.4 Role of Emergency Co-ordination office (ECO) 7-52

7.24.5 Role of local Authority 7-52

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7.24.6 Role of fire Authorities 7-52

7.24.7 Role of the police and evacuation Authorities 7-52 7.24.8 Role of Health Authorities 7-52

7.24.9 Role of Mutual aid Agencies 7-53

7.24.10 Role of Factory Inspectorate 7-53

7.25 Mock Drills and Records 7-53

7.25.1 Need of Rehearsal & Training 7-53

7.25.2 Some check points 7-53 7.25.3 Records and updating the plan 7-53 (C) Social Impact Assessment 7-54 Chapter 8 Project Benefits 8.1 Introduction 8-1 8.2 Improvement in Physical Infrastructure 8-1 8.3 Improvement in Social Infrastructure 8-1 8.4 Employment Potential 8-2 8.5 Other Tangible Benefits 8-2 Chapter 9 Environmental Cost Benefit Analysis 9-1 Chapter 10 Environment Management Plan 10.1 Introduction 10-1 10.2 Environmental Management during Construction Phase 10-1 10.2.1 Air and Noise Environment 10-2 10.2.2 Water Environment 10-2 10.2.3 Socio-Economic Environment 10-2 10.2.4 Health and Safety 10-2 10.3 Environmental Management during Operational Phase 10-3 10.3.1 Air Pollution Management 10-3 10.3.1.1 Source of Air Pollution and Control Measures 10-3 10.3.1.2 Measures for Solvent Recovery 10-4 10.3.1.3 Odour Control Plan 10-4 10.3.2 Water Environment 10-5 10.3.3 Hazardous/Solid Waste Management 10-5 10.3.4 Noise Control 10-6 10.3.5 Green Belt Development 10-7 10.3.6 Occupational Health & Safety Plan 10-10 10.4 Post-Project Environmental Monitoring 10-13 10.4.1 Details of Work Place Air Quality Monitoring Plan 10-14

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10.5 Environment Management Budget Allocation 10-14 10.6 Environmental Management Cell 10-15 10.6.1 Hierarchical Structure of Environmental Management 10-15 Cell 10.6.2 Environment Policy 10-16 10.6.3 Reporting System of Non-Compliances/Violations of 10-16 Environmental Norms 10.6.4 Framework for Continual Improvement of 10-17 Environmental Performance of Organization 10.7 Resource Conservation And Cleaner Production 10-17 10.8 Energy Conservation Programme 10-18 10.9 Socio-Economic Activities 10-18 Chapter 11 Summary & Conclusion 11.1 Project Description 11-1 11.1.1 General Introduction 11-1 11.1.2 Salient features of the proposed project 11-1 11.1.3 Investment of the project 11-2 11.1.4 List of products 11-2 11.2 Description of Environment 11-3 11.2.1 Baseline Environmental Study 11-3 11.2.2 Air Environment 11-3 11.2.3 Water Environment 11-4 11.2.4 Noise Environment 11-5 11.2.5 Soil Quality 11-6 11.2.6 Biological Environment 11-6 11.2.7 Socio-Economic Environment 11-6 11.3 Anticipated Environmental Impacts and Mitigation 11-6 Measures 11.3.1 Summary of Impacts on Air Environment 11-6 11.3.2 Summary of Impacts on Water Environment 11-7 11.3.3 Impacts on Noise quality & Mitigation measures 11-8 11.3.4 Summary of Impacts on Land Environment 11-8 11.3.5 Summary of Impact on Socio Economy 11-9 11.3.6 Summary on Impact on Ecology 11-9 11.4 Environment Monitoring Programme 11-9 11.5 Additional Studies 11-10 11.5.1 Risk Assessment 11-10

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11.6 Project Benefits 11-10 11.7 Environmental Management Plan 11-10 11.8 Conclusion 11-12 Chapter-12 Disclosure of Consultant engaged 12.1 Preface 12-1 12.2 Details of EIA Consultant Organization 12-1

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. IX San Envirotech Pvt. Ltd., Ahmedabad List of Tables Table Name Page No. No. 1.1 Salient Features of the Project 1-3 1.2 Product Details 1-4 2.1 Boundary coordinates of the site 2-5 2.2 Land area breakup 2-5 2.3 List of products with its capacity 2-7 2.4 List of Machineries/Equipment 2-8 2.5 Raw materials Requirement ,Availability and Mode of Transport 2-39 2.6 Breakup of water consumption & w/w generation 2-42 2.7 Details of fuel consumption 2-44 2.8 Details of stacks 2-45 2.9 Estimated Emission quality of stack 2-45 2.10 Details of Solid & Hazardous waste 2-46 2.11 Name and size of ETP units, Design Capacity-250 m3/day 2-48 2.12 Characteristic of untreated and treated effluent 2-49 3.1 Environmental setting of the study area 3-2 3.2 Land use statistics work out based on satellite imaginary 3-5 3.3 Monitoring Methodology of Meteorological Data 3-7 3.4 Meteorological Data for the Monitoring Period 3-7 (October, 2020, to December, 2020) 3.5 Methodology of Ambient Air Monitoring 3-9 3.6 Monitored Parameters and Frequency of Sampling 3-9 3.7 Sampling locations with source & date of sampling 3-13 3.8 Monitoring Methodology of Noise 3-16 3.9 Location of soil sampling 3-17 3.10 Methodology of Soil Sample analysis 3-18 3.11 Ambient Air Quality Monitoring Locations 3-25 3.12 Ambient Air Quality Status 3-26

3.13 Ambient Air Quality Status (PM10) 3-27

3.14 Ambient Air Quality Status (PM2.5) 3-28

3.15 Ambient Air Quality Status (SO2) 3-29

3.16 Ambient Air Quality Status (NOx) 3-30 3.17 Ambient Air Quality Status (CO, HC (Methane & non Methane), 3-31

VOC, HCl, HBr & NH3) 3.18 National Ambient Air Quality Standards 3-32

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3.19 Results of Groundwater Quality in the Study Area 3-33 3.20 Surface water analysis of Study Area 3-34 3.21 Indian Standard Specification for Drinking Water 3-35 3.22 Ambient Noise Levels in the Study Area 3-36 3.23 Ambient Air Quality Standards with respect to Noise 3-36 3.24 Soil Analysis of Study area 3-37 3.25 Floral Diversity 3-38 3.26 Faunal Biodiversity 3-41 3.27 Traffic Survey 3-43 3.28 Land Use Pattern 3-44 3.29 Summary of Socio-Economic Status of Study area 3-46 (Demography) 3.30 Summary of Socio-Economic Status of Study area (Amenities) 3-46 4.1 Input data for air quality modeling 4-15 4.2 Cumulative Concentrations at various locations 4-16 4.3 24-hourly average GLC Concentration Values for SPM 4-17

4.4 24-hourly average GLC Concentration Values for SO2 4-18 4.5 24-hourly average GLC Concentration Values for NOx 4-19 4.6 24-hourly average GLC Concentration Values for HCl 4-20 4.7 24-hourly average GLC Concentration Values for HBr 4-21

4.8 24-hourly average GLC Concentration Values for NH3 4-22 6.1 Environment Monitoring Plan 6-4 7.1 Public Hearing Details 7-1 7.2 Issues Raised during Public Hearing and Action Plan with 7-5 Budgetary Provision 7.3 Bulk Storage of Hazardous Chemicals 7-15 7.4 Hazards Analysis - Raw materials (stored in Bulk) 7-16 7.5 Properties of Hazard-raw Materials (stored in Bulk) 7-18 7.6 Risk Classification 7-21 7.7 Effects due to Incident Radiation intensity 7-22 7.8 Thermal Radiation Impact to human 7-22 7.9 Tolerable Intensities for various objects 7-23 7.10 Damage due to overpressure 7-23 7.11 Different failure scenarios 7-25 7.12 Hazards scenario impact 7-30 7.13 Detailed Expenditures breakup for CER Activities 7-56 10.1 Plant Species Suggested for Greenbelt 10-8

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10.2 Budget for Proposed Greenbelt Development 10-10 10.3 Environment Monitoring Plan 10-13 10.4 Budget Allocation for Environment Management 10-15 10.5 Budgetary Provisions for the Social Upliftment 10-19

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. XII San Envirotech Pvt. Ltd., Ahmedabad List of Figures

Figure Name Page No. No. 2.1 Location of the project site 2-3 2.2 Location on Google map (5 to 10 km radius) 2-4 2.3 Image showing all boundaries coordinates of the site 2-4 2.4 Plant Layout 2-6 2.5 Water Balance Diagram 2-43 2.6 Effluent Treatment Plant flow Diagram 2-48 3.1 Land use map 3-4 3.2 Ambient air quality status 3-26

3.3 Graphical representation for PM10 3-27

3.4 Graphical representation for PM2.5 3-28

3.5 Graphical representation for SO2 3-29

3.6 Graphical representation for NOx 3-30 3.7 Location of AAQM station 3-53 3.8 Wind Rose Diagram 3-54 3.9 Water sampling Locations 3-55 3.10 Noise monitoring Locations 3-56 3.11 Soil sampling location 3-57 3.12 Toposheet of location with site location map of 10 km radius 3-58 (1:50,000 scale) 4.1 Isopleths for Ground Level Concentrations for SPM 4-23

4.2 Isopleths for Ground Level Concentrations for SO2 4-24 4.3 Isopleths for Ground Level Concentrations for NOx 4-25 4.4 Isopleths for Ground Level Concentrations for HCl 4-26 4.5 Isopleths for Ground Level Concentrations for HBr 4-27

4.6 Isopleths for Ground Level Concentrations for NH3 4-28 7.1 Photographs of Public Hearing 7-2 7.2 Sulphuric Acid Spillage and Evaporating Toxic Pool 7-26 7.3 Hydrochloric Acid Tank leakage Toxic Impact 7-27 7.4 Nitric Acid (Anhydrous) Spillage and Evaporating Toxic Pool 7-27 7.5 Ammonia Release & Toxic Evaporating Pool 7-28 7.6 Chlorine Cylinder Leakage Stability Class-C 7-28 7.7 Chlorine Cylinder Leakage Stability Class-F 7-29 7.8 Toluene Spillage—Toxic Impact Zone; Stability Class D 7-29 7.9 Bromine Spillage & Toxic Impact Zone Stability Class D 7-30

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7.10 Bromine Spillage & Toxic Impact Zone Stability Class F 7-30 10.1 Environment Management Cell 10-15

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. XIV San Envirotech Pvt. Ltd., Ahmedabad List of Annexures

Sr. No. Name of Annexures Page no. I. NABET-QCI Certificate A–1 II. Letter from MPIDC for water supply A–3 III. Photographs of the Project site A–4 IV. Land Document A–5 V. Conservation Plan for Schedule-I species A–7 VI. Detailed AAQM (Raw data), Ground Water, Surface Water, A–19 Soil, Noise Results VII. Material Safety Data Sheet of Chemicals A–35 VIII. Public Hearing Proceeding A-101 IX. Undertaking from Consultant & Project Proponent A-120 X. Copy of Terms of Reference (TOR) A–108

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Introduction

1.1 PREFACE An Environmental Impact Assessment (EIA) is an assessment of the possible impacts that a proposed project may have on the environment - consisting of the environmental, social and economic aspects. It is an assessment and management tool that evaluates the possible impacts, positive or negative, that a proposed project may have on the environment. EIA systematically examines both beneficial and adverse consequences of the project and ensures that these effects are taken into account during project design. The purpose of the assessment is to ensure that decision makers consider the ensuing environmental impacts when deciding to proceed with a project. In India, Ministry of Environment and Forests has defined elaborated “Environmental Clearance (EC)” framework along with requirements for preparing Environmental Impact Assessment (EIA) under the Environmental (Protection) Act, 1986 (Environmental Impact Assessment Notification, 2006) for establishing/expanding and industry/development projects. 1.2 PURPOSE OF THE REPORT Industrialization and infrastructure development have increased economic growth and improved living standards of people in India. However, development has led to rapid consumption of natural resources and increased emissions of waste. To control the pollutions from industrial activity, government has framed regulations which are governed by Ministry of Environment, Forest & Climate Change in India. Environment Impact analysis is mandatory as per the Environment Impact Assessment (EIA) Notification issued by Ministry of Environment, Forest & Climate Change (MoEF&CC), New Delhi dated 14th September, 2006 and its subsequent amendment; for setting up a new projects or activities, or expansion or modernization of existing projects or activities based on their potential environmental impacts as indicated in the Schedule to the notification, being undertaken in any part of India, unless prior environmental clearance has been accorded.

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Proposed activity of M/s. Orgosynth Chemicals Pvt. Ltd. falls under the schedule of 5(f) - Synthetic Organic Chemicals Industry (dyes & dye intermediates; bulk drugs and intermediates excluding drug formulations; synthetic rubbers; basic organic chemicals, other synthetic organic chemicals and chemical intermediates) and categorized under Category “A”. Therefore, unit requires prior Environmental Clearance for proposed project. EIA Consultant In view of the above, legal aspect and monitoring work has been carried out for all the environmental attributes by M/s. San Envirotech Pvt. Ltd. (SEPL), Ahmedabad. SEPL is accredited as Category-A organization under the QCI-NABET Scheme for accreditation of EIA consultant Organizations: Version 3 for preparing EIA-EMP reports in 10 sectors. Draft Environment Impact Assessment (EIA) and Environmental Management Plan (EMP) have been prepared after obtaining Terms of References (ToRs) from MoEF&CC, New Delhi. The public hearing was conducted by SPCB based on the submission of draft EIA/EMP report. Final EIA/EMP report is submitted to MoEF&CC, New Delhi incorporating to comments of Public hearing and compliance of the Terms of References. 1.3 IDENTIFICATION OF PROJECT & PROJECT PROPONENT M/s. Orgosynth Chemicals Pvt. Ltd. is a Greenfield project, proposes to set up Dyes intermediates manufacturing unit at Plot No. J-50, J-51, J- 52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center, Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Required facilities like infrastructure, communication, medical facilities, fuel, water, power, unskilled & skilled manpower, raw materials, road network etc. are readily available, therefore, no other optional site or area was considered. There is no Rehabilitation and Resettlement involved. Nearest city Chhindwara is about 51.0 km away from the site, which is having connectivity with other parts of the country by road, rail & air.

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PROJECT PROPONENT Project is promoted by 4 experienced Directors in different areas. The summary of promoters is given below. Mr. R. N. Dravid is a Post Graduate in Organic Chemistry started his career as a Lecturer and Research scholar. He has several research papers published in reputed Journals of Chemistry to his credit. He has set up his own Chemicals manufacturing unit in 1981 at M.I.D.C. Nagpur. In 1997 he set up a new unit Premier Industries which is involved in manufacturing and exporting Dyes Intermediates to Japan, China, Germany, Brazil, Mexico and many other countries. Mr. Jayant Joshi is a Mechanical Engineer with 35 years‟ experience of working in different organizations in various capacity. Last Job was General Manager (Engineering) with Raymond Ltd. Mr. Harshal Tajne is a Civil Engineer having own Civil Engineering construction Co. since five years and is involved construction of Industrial Infrastructure. Mrs. Deepaika Dravid a C.A. and is working as Manager Finance with Stanford India P. Ltd in Chennai since four years. The company is involved in training mid corporate entrepreneurs by the faculty of Stanford University, U.S.A. 1.4 IMPORTANCE OF THE PROJECT The global dyes market is projected to reach USD 42.00 billion by 2021, at a CAGR of 5.0% from 2016 to 2021. The growth of the market is primarily due to increasing population, coupled with growing demand for dyes, pigments from various applications, such as textile, paints & coatings, and plastics, among others. This has prompted proponent to start manufacturing of dye intermediate. 1.5 BRIEF DESCRIPTION OF PROJECT Salient features of the project and list of products are given in Table 1.1 and Table 1.2, respectively. Table 1.1 Salient Features of the Project

Production capacity 3049 MT/month Project cost Rs. 20.25 Crore Manpower requirement About 100 persons

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Location Plot No. J-50, J-51, J-52 and J-53, MPIDC Growth Center Village Borgaon Tehsil Sausar District Chhindwara State Madhya Pradesh Coordinates of the site Latitude: 21°33'14.27"N Longitude: 78°48'15.86"E Altitude 378 – 380 m above MSL Survey of India Toposheet F44M10, F44M11, F44M14, F44M15 No. Nearest Human habitation Borgaon, about 0.9 km Town Sausar, about 9.5 km City Chhindwara, about 55.6 km Railway Station Lodhikhera Railway Station, about 5.6 km Highway National Highway NH-26B (Savner-Chhindwara), about 1.2 km Air Port Chhindwara, about 51.0 km Water Body Borgaon, about 1.0 km National Park/Wildlife Sanctuary None, within 10 km radius Note: Aerial distances are mentioned in above table.

Table 1.2 Product details

Sr. Name of the Product CAS No Qty. No. MT/Month 1 2,5/3,4 Dichloro Nitro Benzene 611-06-3 400 2 2, 4 Di Nitro Chloro Benzene (2,4-DNCB) 97-00-7 600 3 3, 4 Di Nitro Chloro Benzene (3,4-DNCB) 611-06-3 100 4 Para Chloro Ortho Nitro Aniline (PCONA) 89-63-4 350 5 Ortho Chloro Para Nitro Aniline (OCPNA) 121-87-9 90 6 2,4-Dinitro Aniline (2,4-DNA) 97-02-9 540 7 Ortho Nitro Aniline (ONA)/ 88-74-4 100 Para Nitro Aniline (PNA) 100-01-6 8 6 Bromo 2,4 Dinitro Aniline 1817-73-8 200 (6 Bromo 2,4-DNA) 9 6 Chloro 2,4 Dinitro Aniline 3631-19-8 200 (6 Chloro 2,4-DNA) 10 2:6 Di Bromo Para Nitro Aniline 827-94-1 100 (2,6-DBPNA) 11 2:6 Di Chloro Para Nitro Aniline 99-30-9 100 (2,6-DCPNA) 12 2,6-DB Para Toluidine 6968-24-7 100 13 Fast Red B Base & Fast Scarlet R Base 97-52-9 20 14 Fast Bordeaux GP Base 96-96-8 20

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15 Meta Nitro Para Toluidine (MNPT) 89-62-3 10 16 2, Cyano Para Nitro Aniline 17420-30-3 30 17 2-Chloro-4-6 Dimethoxy-[1,3,5] Triazine 3140-73-6 50 18 4-Bromo Anisole 104-92-7 5 19 Para Bromo Phenol/4-Bromo Phenol 106-41-2 5 20 4-Hydroxy Anisole 150-76-5 5 21 Veratrol 91-16-7 5 22 2-Methyl 4,5 Dimethoxy Benzoic Acid 5653-40-7 5 23 2-(2-Methoxy Phenoxy) Ethyl Amine 1836-62-0 5 24 2-Amino 4-Fluoro Benzophenone 3800-06-4 5 25 Miconazole Nitrate 22916-47-8 2 26 Hydrochlorothaizide 58-93-5 2 Total 3049 1.6 APPLICABLE ENVIRONMENTAL REGULATORY FRAMEWORK The proposed project will abide and function under the purview of the following Rules, Acts & Regulations which are formulated by the Govt. of India to protect the environment and development in a sustainable way.  The Water (Prevention & Control of Pollution) Act, 1974  The Air (Prevention & Control of Pollution) Act, 1981  The Environmental (Protection) Act, 1986  Environmental Impact Assessment Notification dated 14th September 2006 and subsequent amendments  The Hazardous & Other Waste (Management and Transboundary Movement) Rules, 2016  Noise Pollution (Regulation and Control) Rules, 2000 and its amendments  The Public Liability Insurance Act, 1991 1.7 SCOPE OF THE STUDY The scope of the EIA study is based on the guideline provided by MoEF&CC. The scope of the study broadly includes:  Field sampling of environmental attributes at various representative locations in the study area to establish the baseline status;  Collect & compile secondary data including socio-economic data;  Identification, assessment and evaluation of the beneficial & adverse impacts on surrounding environment due to proposed project activities considering the existing baseline status.  Analysis of project proposal and data analysis.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-5 San Envirotech Pvt. Ltd., Ahmedabad

 Assessment of pollution potential due to proposed project.  Predict the incremental levels of pollutants in the study area due to the proposed project;  Evaluate the predicted impacts on the various environmental attributes by using scientifically developed & widely accepted models.  Identification and assessment of risks associated with the proposed project and their appropriate management through proper Risk Assessment (RA) and Disaster Management Plan (DMP).  Prepare an Environmental Management Plan (EMP) to mitigate the predicted impacts; and  Identify critical environmental attributes required to be monitored during the project execution and to suggest post project monitoring. The scope also includes all the conditions outlined in the ToR issued by MoEF&CC and the compliance to the ToR is given below. 1.8 COMPLIANCE TO TERMS OF REFERENCE MoEF&CC has prescribed Standard Terms of Reference (TOR) vide ToR letter no. IA-J-11011/249/2020-IA-II (I), dated 26/10/2020 for undertaking detailed EIA study for the purpose of obtaining EC. Compliance of Standard TOR for “Synthetic Organic Chemicals Industry (dyes and dye intermediates; bulk drugs and intermediates excluding drug formation; synthetic rubber; basic organic chemicals, other synthetic organic chemicals and chemical intermediates” Issued by MoEF&CC for EIA/EMP report for Projects/Activities requiring Environmental Clearance under EIA Notification, 2006 is given below:

Sr. ToR Points Compliance of ToR Reference in No. EIA Report A Standard Terms of Reference 1. Executive Summary Incorporated in EIA/EMP Report. Chapter-11 2. Introduction i. Details of the EIA EIA Consultant: M/s. San Envirotech Chapter 12 Consultant including Pvt. Ltd., Ahmedabad (Disclosure of NABET accreditation. NABET accreditation Certificate No. Consultant) NABET/EIA/1619/RA0084) NABET accreditation certificate is Annexure-I attached as Annexure of EIA Report. (Page no. A-1- 2) ii. Information about the Project is promoted by 4 experienced Chapter-1, project proponent. Directors in different area. Section 1.3 (Page

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report no. 1-2) iii. Importance and benefits Proposed products are dyes Chapter 1, of the project. intermediates and will be used in dyes Section 1.4 (Page manufacturing hence project will play a no. 1-3 and vital role in enhancing the Global Dyes Chapter 8 sector and thereby increase infrastructure facilities & social benefits. Details are given in of EIA/EMP report. 3. Project Description i. Cost of project and time Total cost of the project is Rs. 20.25 Chapter 2, of completion. Crore. Section 2.1 Time of project completion will be (Paragraph 2; about 1.0 - 1.5 years after accordance Page no. 2-1) of the EC. ii. Products with capacities This is a proposed unit for Chapter 2, for the proposed project. manufacturing of dyes intermediates. Section 2.4.2 & Total capacity of the plant will be 3049 Table 2.3 (Page MT/month. no. 2-7) iii. If expansion project, Not applicable (New project proposal). -- details of existing products with capacities and whether adequate land is available for expansion, reference of earlier EC if any. iv. List of raw materials Raw materials are indigenously Chapter 2, required and their source available and will be transported by Section 2.8a & along with mode of road; and in case of unavailability, will Table 2.5 (Page transportation. be imported. List of raw materials, no. 2-39) quantity, source along with mode of transportation is given in EIA/EMP report. v. Other chemicals and Storage details of other materials are Chapter 7, materials required with given in EIA Report. Table 7.3 (Page quantities and storage no. 7-15) capacities. vi. Details of emission, Emission: Emission & effluents, hazardous Flue gas emission will be from the APCM: waste generation and stack attached with Steam boiler, Chapter 2, their management. Thermic Fluid Heater and stack of Section 2.9.2 & stand by D.G. Sets (500 kVA x 2 nos.). Table 2.8 (Page APCM: Cyclone separator followed by no. 2-44 & 2-45). bag filter Process gas emission will be from

the stack attached with Process Vessel

of MPP-1, MPP-2, Spin Flash Dryer (6

Nos.)

APCM: Water scrubber, Acid Scrubber,

Alkali Scrubber will be provided on

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-7 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report Process Vessel of MPP-1, MPP-2 and In built cyclone and bag filter will be provided on Spin Flash Dryer. Effluent: Effluent: Total effluent (242.7 KLD) will be taken Chapter 2, into ETP, after treatment, effluent will Section 2.9.1 be passed through RO. RO permeate (Page no. 2-44), (170 KLD) will be reused within w/w treatment premises and RO reject will be sent to details is given in MEE/ATFD. MEE condensate (60 KLD) Chapter 2, will be reused. Thus, unit proposed to Section 2.10.1 achieve Zero Liquid Discharge (Page no. 2-47), (ZLD). Table 2.11 & Figure 2.6 (Page

no. 2-48)

Haz. waste: Hazardous waste: Chapter 2, Table Hazardous wastes like ETP sludge, MEE 2.10 (Page no. 2- salt from wastewater treatment, 46) process streams like Spent Sulphuric Acid (45-70%), Spent Hydrochloric Acid (25-28%), Hydrobromic Acid (25- 28%), Acetic Acid (40-42%), Liq.

Ammonia, AlCl3 (30-35%), Used lubricating oil, discarded drums/ containers/liners will be generated. Entire quantity of hazardous waste will be handled & disposed as per Hazardous & Other waste (Management & Transboundary Movement) Rules, 2016. vii. Requirement of water, Particular Total Source Water: power, with source of Requirement Chapter 2, Water 300 KLD MPIDC supply, status of Table 2-6 (Page (Fresh water approval, water balance 70 KLD) no. 2-42). Water diagram, man-power Power 1000 kVA Madhya balance diagram requirement (regular and Pradesh is given as Poorva contract). Kshetra Figures 2.5 (Page Vidyut no. 2-43) Vitaran MPIDC letter for Company water usage is Ltd. 500 kVA x 2 Stand by D attached as nos. G Set Annexure-II Manpower 100 persons Unskilled/ (Page no.A- 3) during semi- Power: operation skilled from local Chapter 2, areas Section 2.8(c) Skilled (Page no. 2-43) from local & outside area

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report

viii. Process description along Process description along with flow Chapter 2, with major equipments chart from raw materials to product is Section 2.6 (Page and machineries, process given in EIA Report. no. 2-8 to 2-38) flow sheet (quantities) The detailed list of proposed Chapter 2, from raw material to equipments & machinery are given in Table 2.4 (Page products to be provided. the EIA Report. no. 2-8) ix. Hazard identification and Hazard identification is described in EIA Chapter-7, details of proposed safety Report. Section 7.2 (Page systems. no. 7-13). Risk Details of proposed safety system are screening covered in Risk Assessment Report. approach is covered in Section 7.4 (Page no. 7- 16) x. Expansion/modernization proposals: a. Copy of all the Not applicable -- Environmental (New project proposal) Clearance(s) including Amendments thereto obtained for the project from MOEF/SEIAA shall be attached as an Annexure. A certified copy of the latest Monitoring Report of the Regional Office of the Ministry of Environment and Forests as per circular dated 30th May, 2012 on the status of compliance of conditions stipulated in all the existing environmental clearances including Amendments shall be provided. In addition, status of compliance of Consent to Operate for the ongoing/ existing operation of the project from SPCB shall be attached with the EIA- EMP report. b. In case the existing Not applicable -- project has not obtained (New project proposal) environmental clearance, reasons for not taking EC under the provisions of the EIA Notification 1994

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-9 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report and/or EIA Notification 2006 shall be provided. Copies of Consent to Establish/No Objection Certificate and (Consent to Operate (in case of units operating prior to EIA Notification, 2006, CTE and CTO of FY 2005- 2006) obtained from the SPCB shall be submitted. Further, compliance report to the conditions of consents from the SPCB shall be submitted. 4. Site Details: i. Location of the project The project site is located at Plot No. J- Chapter 2, site covering village, 50, J-51, J-52 and J-53, Madhya Figure 2.1 to 2.3 Taluka/Tehsil, District and Pradesh Industrial Development (Page no. 2-3 to State, Justification for Corporation Limited (MPIDC) Growth 2-4) selecting the site, Center, Borgaon, Tehsil: Sausar, Dist. whether other sites were Chhindwara, Madhya Pradesh. considered. Justification of site selection is given in Chapter 5, EIA/EMP report. Section 5.2 (Page no. 5-1) ii. A Toposheet of the study Toposheet of the study area is included Chapter 3, area of radius of 10km in EIA/EMP report. Figure 3.11 (Page and site location on no. 3-58) 1:50,000/ 1:25,000 scale on an A3/A2 sheet. (Including all eco- sensitive areas and environmentally sensitive places). iii. Details w.r.t. option Justification of site selection is given in Chapter 5, analysis for selection of EIA/EMP report. Section 5.2 (Page site. no. 5-1) iv. Co-ordinates (lat-long) of Google Earth image showing boundary Chapter 2, all four corners of the Coordinates of the site is given in Figure 2.3 (Page site. EIA/EMP report. no. 2-4) v. Google map-Earth Google Earth image showing project Chapter 2, as downloaded of the project site is given in EIA/EMP report. Figure 2.2 (Page site. no. 2-4) vi. Layout maps indicating Plant Layout showing plant area, Chapter 2, existing unit as well as storage area, greenbelt area, utilities Figure 2.4 (Page proposed unit indicating etc. is given in EIA/EMP Report. no. 2-6) storage area, plant area, Total plot area of the project is 17432 greenbelt area, utilities m2. etc. If located within an The project site is located in industrial Industrial area/Estate/ area/Estate/ developed by MPIDC.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-10 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report Complex, layout of Industrial Area indicating location of unit within the Industrial area/ Estate. vii. Photographs of the Photographs of the proposed site are Annexure-III proposed and existing (if given in EIA Report. (Page no. A-4) applicable) plant site. If existing, show photographs of plantation/greenbelt, in particular. viii. Land use break-up of Proposed unit will be set up in Madhya Annexure-IV total land of the project Pradesh Industrial Development (Page no. A-5) site (identified and Corporation Limited (MPIDC) Growth acquired), government/ Center having an area of 17432 m2. private-agricultural, Total land is in Notified Industrial area Chapter 2, Table forest, wasteland, water by MPIDC. Land possession document 2.2 (Page 2-5) bodies, settlements, etc. is attached in EIA/EMP Report. shall be included. (Not Plant area break up showing various required for industrial plant components is provided in area). EIA/EMP report. ix. A list of major industries List of major industries with name and Chapter 1, with name and type type within study area (10 km radius) Section 1.11 within study area (10km is provided in EIA Report. (Page no. 1-23)

radius) shall be Land use details of the study area are Chapter 3, Incorporated. Land use included in EIA Report. Section 3.6 (Page details of the study area. no. 3-3), Figure 3.1 (Page no. 3- 4) x. Geological features and Geological features and Geo- Chapter 3, Geo-hydrological status of hydrological status of the study area is Section 3.9 (Page the study area shall be included in EIA Report. no. 3-11) included. xi. Details of Drainage of the There is no river & flood hazard zone -- project up to 5 km radius within 1 km radius from the project site of study area. If the site hence drainage pattern may not be is within 1 km radius of required to submit. any major river, peak and lean season river discharge as well as flood. Occurrence frequency based on peak rainfall data of the past 30 years. Details of Flood Level of the project site and maximum Flood Level of the river shall also be provided. (mega green field projects) xii. Status of acquisition of The proposed unit will be set up in land Annexure-IV

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-11 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report land. If acquisition is not developed by Madhya Pradesh (Page no. A-5) complete, stage of the Industrial Development Corporation acquisition process and Limited (MPIDC) Growth Center. Land expected time of document is given in EIA/EMP report. complete possession of the land. xiii. R&R details in respect of No R&R is involved. -- land in line with state Government policy. 5. Forest and wildlife related issues (if applicable): i. Permission and approval No forest land is involved in proposed -- for the use of forest land project hence no such permission/ (forestry clearance), if approval are required. any, and recommendations of the State Forest Department. (if applicable) ii. Land use map based on Proposed Project does not involve -- High resolution satellite forest land. imagery (GPS) of the proposed site delineating the forestland (in case of projects involving forest land more than 40 ha). iii. Status of Application Not Applicable -- submitted for obtaining the Stage I forestry clearance along with latest status shall be submitted. iv. The projects to be located No National Parks, Sanctuaries, -- within 10 km of the Biosphere reserves exists within 10 km National Parks, radius of the project site. Sanctuaries, Biosphere Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location and the recommendations or comments of the Chief Wildlife Warden-thereon. v. Wildlife Conservation Plan Conservation plan for Schedule-I Annexure-V duly authenticated by the Species recorded within the study area (Page no. A-7) Chief Wildlife Warden of of 10 km radius was submitted to DFO, the State Government for Chhindwara. Conservation Plan with conservation of Schedule budget allocation is attached in I fauna, if any exists in EIA/EMP Report.

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report the study area. vi. Copy of application Not Applicable -- submitted for clearance under the Wildlife (Protection) Act, 1972, to the Standing Committee of the National Board for Wildlife. 6. Environmental Status i. Determination of Site-specific micro-meteorological data Chapter 3, atmospheric inversion (temperature, relative humidity, hourly Section 3.7 (Page level at the project site wind speed and direction and rainfall) 3-6) and site-specific micro- were collected for the period of meteorological data using October, 2020 to December, 2020. temperature, relative Details are provided in EIA Report. humidity, hourly wind speed and direction and rainfall.

ii. AAQ data (except AAQ monitoring for PM10, PM2.5, SO2, Chapter 3,

monsoon) at 8 locations NOX, CO, VOCs, HC and project specific Table 3.12 to 3.17

for PM10, PM2.5, SO2, NOX, parameters – HCl, HBr, NH3 at 8 (Page no. 3-26 to CO and other parameters locations were done for Post Monsoon 3-31) relevant to the project Season (October, 2020 to December, Figure 3.7 (Page shall be collected. The 2020). Results of the same are no. 3-53) monitoring stations shall tabulated in Air monitoring stations are be based CPCB guidelines shown in EIA Report. and take into account the pre-dominant wind The monitoring stations were selected Figure 3.8 (Page direction, population zone taking into account the pre-dominant no. 3-54) and sensitive receptors wind direction and sensitive receptors including reserved and up and down wind direction. forests. iii. Raw data of all AAQ All AAQ stations along with min., max., Chapter 3, Table measurement for 12 average and 98% values for each of 3.12 to 3.17 weeks of all stations as the AAQ parameters are given in EIA (Page 3-26 to 3- per frequency given in Report. 31) the NAAQM Notification of Nov. 2009 along with - Raw data of all AAQ stations are given Annexure-VI min., max., average and in Annexure of EIA/EMP Report. (Page no. A-19) 98% values for each of the AAQ parameters from data of all AAQ stations should be provided as an annexure to the EIA Report. iv. Surface water quality of Unit will not discharge in surface water Chapter 3, Table nearby River (100 m body. 3.20 (Page no. 3- upstream and Surface water samples were collected 34) downstream of discharge from 6 locations. Result of same is point) and other surface given in EIA Report.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-13 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report drains at eight locations as per CPCB/MoEF&CC Surface water sampling locations are Chapter 3, guidelines. shown in EIA Report. Figure 3.9 (Page no. 3-55) v. Whether the site falls Project site doesn‟t falls near to -- near to polluted stretch of polluted stretch of the river identified river identified by the by the CPCB/MoEF&CC. CPCB/ MoEF&CC, if yes give details. vi. Ground water monitoring Ground water monitoring was carried Chapter 3, Table at minimum at 8 locations out at 8 locations within study area. 3.19 (Page no. 3- shall be included. Result of same is given in EIA Report. 33) vii. Noise levels monitoring at Noise level monitoring was carried out Chapter 3, Table 8 locations within the at 9 locations within study area. Result 3.22 (Page no. 3- study area. is given in EIA Report. 36) viii. Soil Characteristic as per Soil sampling was carried out at 8 Chapter 3, Table CPCB guidelines. locations within study area. Result is 3.24 (Page no. 3- given in EIA Report with interpretation. 37) ix. Traffic study of the area, Traffic study of the area in respect of Chapter 3, Table type of vehicles, existing traffic, type of vehicles, their 3.27 (Page no. 3- frequency of vehicles for frequency, and additional traffic due to 43) transportation of proposed project was conducted and materials, additional covered in EIA Report. traffic due to proposed There will be negligible impact on project, parking existing traffic due to proposed project arrangement etc. as existing road network has adequate capacity to take increase load. x. Detailed description of Flora & Fauna found within the study Chapter 3, Table flora and fauna area is given in EIA Report. 3.25 (Page no. 3- (terrestrial and aquatic) 38) & Table 3.26 existing in the study area (Page no. 3-41) shall be given with special reference to rare, endemic and endangered species. If Schedule-I Conservation Plan for Schedule I Annexure-V fauna are found within species is attached in EIA/EMP Report. (Page no. 7-18) the study area, a Wildlife Conservation Plan shall be prepared and furnished. xi. Socio-economic status of Socio-economic status of the study Chapter 3, the study area. area is given in EIA Report. Section 3.14 (Page no. 3-21); and Table 3.29 (Page no. 3-46) & 3.30 (Page no. 3- 48) 7. Impact and Environment Management Plan i. Assessment of ground Assessment of incremental ground

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-14 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report level concentration of level concentration of pollutant from pollutants from the stack the stack emission based on site emission based on site- specific meteorological features has specific meteorological been predicted via computation done features. In case the through mathematical modeling and project is located on a incorporated in EIA/EMP Report. hilly terrain, the AQIP Modeling shall be done Cumulative impact of all sources of Chapter 4, Table using inputs of the emissions on AAQ of the area is given 4.2 (Page no. 4- specific terrain in EIA/EMP report. 16) characteristics for determining the potential Input parameters used for modeling Chapter 4, Table impacts of the project on and additional inputs - maximum 50 4.1 (Page no. 4- the AAQ. Cumulative (24-hr) average concentration values 15), Table 4.3 to

impact of all sources of for SPM, SO2, NOx, HCl, HBr NH3 are 4.8 (Page no. 4- emissions (including provided in EIA/EMP Report. 17 to 4-22) transportation) on the AAQ of the area shall be Isopleths showing air quality contours Chapter 4, Figure assessed. Details of the plotted on location map is provided in 4.1 to 4.6 (Page model used and the input EIA/EMP report. no. 4-23 to 4-28) data used for modeling shall also be provided. The air quality contours shall be plotted on a location map showing the location of project site, habitation nearby, sensitive receptors, if any. ii. Water Quality modeling - Not required, as no wastewater will be -- in case of discharge in discharged from proposed unit. water body. iii. Impact of the transport of There will be no major impact of the Chapter 3, Table the raw materials and end transport of the raw materials and end 3.27 (Page no. 3- products on the products on the surrounding 43) surrounding environment environment due to proposed project shall be assessed and as proper mitigation measures will be provided. In this regard, adopted. Traffic study is provided in options for transport of EIA Report. raw materials and finished products and Details regarding impact of the Chapter 4, wastes (large quantities) transport of the raw materials and end Section 4.11 by rail or rail-cum road products on the surrounding (Page no. 4-14) transport or conveyor- environment are given in EIA Report. cum-rail transport shall be examined. iv. A note on treatment of Total trade effluent will be taken into Chapter 2, wastewater from different ETP, after treatment, entire effluent Section 2.10.1 plant operations, extent will be passed through RO. RO (Page no. 2-47) recycled and reused for permeate will be reused within

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report different purposes shall premises and RO reject will be sent to be included. Complete MEE/ATFD. MEE condensate will be scheme of effluent reused. Thus, unit proposed to achieve treatment. Characteristics Zero Liquid Discharge (ZLD). of untreated and treated ETP units along with ETP flow diagram Table 2.11 & effluent to meet the is given in EIA/EMP report. Figure 2.6 (Page prescribed standards of Characteristic of untreated and treated no. 2-48) discharge under E(P) effluent is given in EIA/EMP report. Rules. v. Details of stack emission Flue gas emission: Chapter 2, and action plan for From stack attached with Boiler (1 no. Table 2.8 (Page control of emissions to - 6 TPH), Thermic Fluid Heater (1 no. - no. 2-45) meet standards. 20 Lakhs Kcal/hr.), one stack of stand by D.G. Sets (500 kVA x 2 nos.)

APCM: Cyclone separator followed by

bag filter.

Process gas emission:

Process Vessel of MPP-1, MPP-2, Spin

Flash Dryer (6 Nos.) APCM: Water Scrubber, Alkali Scrubber, Acid Scrubber for process vessel, In built Cyclone and bag filter on Spin Flash Dryer vi. Measures for fugitive Fugitive emission control measures are Chapter 2, emission control. provided in EIA report. Section 2.10.2 (Page no. 2-49) vii. Details of hazardous Hazardous waste generation includes Chapter 2, waste generation and ETP sludge, MEE salt, Spent Sulphuric Table 2.10 (Page their storage, utilization Acid (45-70%), Spent Hydrochloric no. 2-46) and management. Copies Acid (25-28%), Hydrobromic Acid (25- of MOU regarding 28%), Acetic Acid (40-42%), Liq.

utilization of solid and Ammonia, AlCl3 (30-35%), Used hazardous waste in lubricating oil, discarded drums/ cement plant shall also be containers/liners. included. EMP shall Entire quantity of hazardous waste will include the concept of be handled & disposed as per waste-minimization, Hazardous & Other waste recycle/reuse/recover (Management & Transboundary techniques, Energy Movement) Rules, 2016. Chapter 10, conservation, and natural Unit will adopt waste-minimization, Section 10.7 resource conservation. Resource & energy conservation and (Page no. 10-17) cleaner production. & 10.8 (Page no. 10-18) viii. Proper utilization of fly Fly Ash will be sent to brick Chapter 10, ash shall be ensured as manufacturers periodically. Section 10.3.3 per Fly Ash Notification, (Page no. 10-5) 2009. A detailed plan of action shall be provided. ix. Action plan for the green Unit will develop 5763 m2 (33% of total Chapter 2, belt development plan in plot area) of greenbelt. Layout plan Figure 2.4 (Page

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report 33% area i.e. land with earmarking space for development of no. 2-6) not less than 1,500 trees green belt peripheral of project site is per ha. Giving details of given in EIA/EMP report.

species, width of Detailed Green Belt Development Plan Chapter 10, plantation; planning is provided in EIA report. Total 1450 Section 10.3.5 schedule etc. shall be saplings will be planted within 5 years. (Page no. 10-7) included. The green belt shall be around the project boundary and a scheme for greening of the roads used for the project shall also be incorporated. x. Action plan for rainwater The rain water from the building roofs Chapter 2, harvesting measures at will be directed through the drainage to Section 2.11 plant site shall be the covered storm water drainage line. (Page no. 2-51) submitted to harvest All drainage system will be concreted rainwater from the roof lined and located along the roads up to tops and storm water rain water harvesting pit. Roof top rain drains to recharge the water will be collected in tanks and ground water and also to reused after filtration as per use for the various requirements. activities at the project site to conserve fresh water and reduce the water requirement from other sources. xi. Total capital cost and Total Capital Cost for Environmental Chapter 10, recurring cost/annum for Management System will be Rs. 1.84 Section 10.5 environmental pollution Crores and Recurring Cost will be Rs. (Page no. 10-14) control measures shall be 2.37 Crores. included. Cost breakup of Environment Management is given in EIA report. xii. Action plan for post- Action plan for post-project Chapter 10, project environmental environmental monitoring is adopted Table 10.3 (Page monitoring shall be and included in EIA report. no. 10-13) submitted. xiii. Onsite and Offsite Onsite and Offsite Disaster (natural Chapter 7, Disaster (natural and and man-made) Preparedness and Section 7.19 Man-made) Preparedness Emergency Management Plan are (Page no. 7-41) & and Emergency included in EIA Report. Section 7.24 Management Plan (Page no. 7-51) including Risk Assessment and damage control. Disaster management plan should be linked with District Disaster Management Plan. 8. Occupational health: i. Plan and fund allocation Occupational health & safety plan will Chapter 10,

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report to ensure the be adopted by unit. Section 10.3.6 occupational health & Rs. 2.0 Lakhs per annum has been (Page no. 10-10); safety of all contract and allocated to ensure the occupational and Chapter 7, casual workers. health and safety of workers. Section 7.14 (Page no. 7-33) ii. Details of exposure This is a proposed project. Unit will Chapter 7, specific health status adopt Occupational Health & Safety Section 7.14 evaluation of worker. If programme need based as per the (Page no. 7-33); the workers‟ health is statutory requirements. and Chapter 10, being evaluated by pre Section 10.3.6 designed format, chest x (Page no. 10-10) rays, Audiometry, Spirometry, Vision testing (Far & Near vision, color vision and any other ocular defect) ECG, during pre-placement and periodical examinations give the details of the same. Details regarding last month analyzed data of above mentioned parameters as per age, sex, duration of exposure and department wise. iii. Details of existing No existing Occupational & Safety Chapter 7, Table Occupational & Safety Hazards, as this is a new project 7.3 (Page no. 7- Hazards. What are the proposal. 15). Properties of exposure levels of Hazardous hazards and whether they materials are are within Permissible given in Table 7.5 Exposure Level (PEL)? If (Page no. 7-18) these are not within PEL, Hazard analysis of materials is Section 7.4.1 what measures the provided in EIA Report including acute (Page no. 7-19), company has adopted to Exposure Guideline Levels (AEGLS), Section 7.4.2 keep them within PEL so Emergency Response Planning (Page no. 7-20), that health of the workers Guidelines (ERPGs), Immediately Section 7.8 (Page can be preserved. dangerous to life or health air no. 7-23) concentration values (IDLH values) etc. iv. Annual report of health Not applicable (New project proposal). -- status of workers with special reference to Occupational Health and Safety. 9. Corporate Environment Policy i. Does the company have a Company has laid down Environment Chapter 10, well laid down Policy. Section 10.6.2 Environment Policy (Page no. 10-16) approved by its Board of Directors? If so, it may be

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report detailed in the EIA report. ii. Does the Environment Environment Policy prescribes for Chapter 10, Policy prescribe for standard operating process to Section 10.6 standard operating implement the environmental (Page no. 10-15) process/procedures to standards. bring into focus any Additionally, company will set up a infringement/deviation/ dedicated Environment Management violation of the Cell (EMC) to bring into focus any environmental or forest infringement/deviation/violation of the norms/conditions? If so, it environment. may be detailed in the EIA. iii. What is the hierarchical Hierarchical system of the company is Chapter 10, system or Administrative discussed in EIA Report. Figure 10.1 (Page order of the company to no. 10-15) deal with the environmental issues and for ensuring compliance with the environmental clearance conditions? Details of this system may be given. iv. Does the company have Reporting mechanism will be adopted Chapter 10, system of reporting of by unit. Section 10.6.3 non-compliances/ (Page no. 10-16) violations of environmental norms to the Board of Directors of the company and/or shareholders or stakeholders at large? This reporting mechanism shall be detailed in the EIA report. 10. Details regarding During construction & operation phase, -- infrastructure facilities adequate infrastructure facilities like such as sanitation, fuel, restroom, sanitation, drinking water, restroom etc. to be etc. will be provided to the labor force provided to the labor including truck drivers. force during construction Also food facilities available during the as well as to the casual operation phase. workers including truck drivers during operation phase. 11. Enterprise Social Commitment (ESC) i. Adequate funds (at least Rs. 40.5 Lakhs (2.0% of project cost) Chapter 7, Table 2.5% of the project cost) will be earmarked towards Corporate 7.13 (Page no. 7- shall be earmarked Environment Responsibility (CER) as 56) towards the Enterprise per the MoEFCC OM dated 01.05.2018. Social Commitment based Social Commitment based on Public Chapter 7, Table on Public Hearing issues Hearing issues and item-wise details 7.2 (Page no. 7-

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-19 San Envirotech Pvt. Ltd., Ahmedabad

Sr. ToR Points Compliance of ToR Reference in No. EIA Report and item-wise details along with time bound action plan is 5) along with time bound provided in EIA/EMP report. action plan shall be included. Socio-economic development activities need to be elaborated upon. 12. Any litigation pending No litigation is pending against the -- against the project and/or project and/or any direction/order any direction/order passed by any Court of Law against the passed by any Court of project. Law against the project, if so, details thereof shall also be included. Has the unit received any notice under the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and Water Acts? If so, details thereof and compliance/ATR to the notice(s) and present status of the case. 13. A tabular chart with index Point-wise ToR compliance in the Chapter 1, for point wise compliance tabular form is given in EIA/EMP Section 1.8 (Page of above ToRs. report. no. 1-6 to 1-22) B Specific Terms of Reference 1 Details on solvent to be Unit will use solvents Ortho Chloro Chapter 10, used, measures for Benzene Methanol, Ethyl Acetate, MDC, Section 10.3.1.2 solvent recovery and for N-Butanol and Toluene. Recovered (Page no. 10-4) emission control. solvent will be utilized in respective product. 2 Details of process Process gas emission: Chapter 2, Table emission from the unit From vent attached with Process Vessel 2.8 (Page no. 2- and its arrangement to of MPP-1, MPP-2, Spin Flash Dryer (6 45) control. Nos.) APCM: Water scrubber, Acid Scrubber, Alkali Scrubber for reaction vessel, In built cyclone & bag filter will be provided on Spin Flash Dryer. 3 Ambient air quality data Ambient air quality data includes VOCs, Chapter 3, Table should include VOC, HC, CO and process-specific pollutants 3.17 (Page no. 3-

other-process-specific – HCl, HBr, NH3 are monitored and 31)

pollutants* like NH3*, incorporate in EIA Report. All the chlorine*, HCl*, HBr*, results are found within the norms

H2S*, HF*, etc. (*-as fixed by CPCB. applicable). 4 Work zone monitoring Unit will carry out work zone Chapter 10, arrangements for monitoring after start of project. Section 10.4.1 hazardous chemicals. (Page no. 10-14)

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report

5 Detailed effluent Total trade effluent will be taken into Chapter 2, treatment scheme ETP, after treatment, effluent will be Section 2.10.1 including segregation of passed through RO. RO permeate will (Page no. 2-47, effluent streams for units be reused within premises and RO Table 2.11 & adopting „Zero‟ Liquid reject will be sent to MEE/ATFD. MEE Figure 2.6 (Page Discharge. condensate will be reused. Thus, unit no. 2-48) proposed to achieve ZLD. Detailed effluent treatment scheme for adopting ZLD is provided in EIA/ EMP report. 6 Action plan for odour Action plan for odour control is Chapter 10, control to be submitted. described in EIA Report. Section 10.3.1.3 (Page no. 10-4) 7 A copy of the Unit will consider obtaining such -- Memorandum of Memorandum of Understanding signed Understanding signed with cement manufacturers before with cement commissioning of plant. manufactures indicating Unit will obtain membership of clearly that they co- common hazardous waste disposal process organic solid/ facility before establishment. Hazardous waste in TSDF if any. 8 Authorization/Membership Unit will perform ZLD with in-house -- for the disposal of liquid ETP, RO and MEE setup; hence effluent in CETP and membership of CETP is not required. solid/hazardous waste in Unit will obtain membership of TSDF, if any. common hazardous waste disposal facility before establishment. 9 Action plan for utilization No usable salt generation from MEE. Chapter 2, Table of MEE/ dryers salts. Salt from MEE will be sent to TSDF site. 2.10 (Page no. 2- 46) 10 Material Safety Data MSDS of Hazardous chemicals is Annexure-VII Sheet for all the attached with EIA Report. Unit will (Page no.A-35) Chemicals are being sickly follow the storage and handling used/will be used. instruction or handling and storage of Hazardous chemicals. 11 Authorization/Membership Unit will obtain membership of -- for the disposal of solid/ common hazardous waste disposal hazardous waste in TSDF. facility before establishment. 12 Details of incinerator if to Not applicable as no proposal for -- be installed. installment of Incinerator. 13 Risk assessment for Risk assessment for storage and Chapter 7, storage and handling of handling of hazardous chemicals is Section 7.3 (Page hazardous chemicals/ covered in EIA/EMP report. no. 7-15), Table solvents. Action plan for Hazard analysis of materials, Acute 7.4 & Table 7.5 handling & safety system Exposure Guideline Levels (AEGLS), (Page no. 7-16 to to be incorporated. Emergency Response Planning 7-18) Guidelines (ERPGs), Immediately Section 7.4.1

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Sr. ToR Points Compliance of ToR Reference in No. EIA Report dangerous to life or health air (Page no. 7-19); concentration values (IDLH values) are Section 7.4.2 provided in the report. (Page no. 7-20); Section 7.8 (Page no. 7-23) Action plan for handling & safety Section 7.16 system is also covered in the report. (Page no. 7-35) 14 Arrangements for Arrangements for ensuring health and Chapter-7, ensuring health and safety of workers engaged in handling Section 7.17 safety of workers of toxic materials are given in EIA/EMP (Page no. 7-38) engaged in handling of report. Proper care of health and safety toxic materials. of workers will be taken. Public consultation 1. Details of Public The Public Hearing was conducted by Chapter-7, Table consultation. MPPCB on 28.06.2021 as per the 7.1 (Page no. 7- provision of EIA Notification, 2006 and 1), Table 7.2 its amendment therein. Public Hearing (Page no. 7-5) details along with Time Bound Action Plan and Budgetary provision are given in EIA/EMP report. Minutes of PH is attached in EIA/EMP Annexure-VIII report. (Page no. A- 101) 1.9 OBJECTIVE OF EIA The objectives of the present EIA study are to identify potential source of pollution, assess the impacts on various environmental components due to the proposed project activity, and recommend appropriate environmental management system and environment management plan for the unit to ensure that the adverse impacts, if any, will be minimized. 1.10 METHODOLOGY FOR EIA Considering the nature and magnitude of the project, surrounding area and various guidelines available, an area of 10-km radius from the center of proposed plant site was considered for the purpose of environmental impact assessment study. The methodology is briefly reported below, Baseline data collection: The baseline data for the impact zone have been generated for the following environmental parameters.  Ambient Air Quality  Micrometeorology  Noise Level

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 Surface & Ground Water Quality  Soil Quality  Ecology & Biodiversity  Land use pattern  Socio-Economics The baseline status of the above environmental parameters has been worked out based on the rapid monitoring/analysis carried out during the study period of October, 2020 to December, 2020 supplemented by data collected from various Govt. Dept., census publications etc. The data is collected and analyzed as per the standard methods for establishing the baseline data and so determine the impact of proposed activity on the same. Evaluation of Impact from Project Activities The Environmental Impact resulting from the various project activities, have been identified, predicted and evaluated based on the study of manufacturing process and other project related activities as well as correlating the same with existing baseline status. Preparation of Environmental Management Plan Environmental Management Plan has been prepared covering pollution prevention measures at source in terms of air and water pollution control measures, solid waste/hazardous waste management, safety management, greenbelt development, environmental surveillance and environmental surveillance and environmental management team. Finally, the detailed assessment of the resultant environmental impacts have been made based on the impacts identification and evaluated from the activities over the baseline status of various environmental components to reduce the pollution and to delineate a comprehensive environment management plan along with recommendations and suggestions to improve environment management system. 1.11 LIST OF INDUSTRIES SURROUNDING PROJECT SITE List of industries in the study area are shown below. Name of Industries within 10 km radius Raymond Ltd. KJV Alloys Pvt. Ltd. Bhansali Polymer Ltd. Royal Roofing Pvt. Ltd.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-23 San Envirotech Pvt. Ltd., Ahmedabad

JCO Gas Pipes Premier Industries Gulshan Polyols Ltd. Krishna Belts Pvt. Ltd. 1.12 STRUCTURE OF REPORT The report consists of twelve chapters and the content is briefly described in this section.  Chapter 1: Introduction The chapter gives brief outline of the project and its proponent, brief description nature, size and location of the project, purpose of the EIA study including the scope of the study, TORs compliance etc. and work to be covered under each Environmental component.  Chapter 2: Project Description This chapter includes project details and Infrastructure facilities including all industrial & environmental aspects of the unit as well as manufacturing process details. It also gives information about utilities, raw material, water & wastewater quantitative details, stack details, hazardous waste generation, storage & disposal facility.  Chapter 3: Description of the Environment This chapter covers data of existing condition of Valued Environmental Components like air, water, noise, soil, biological environment and socio-economic aspects, basic amenities land use pattern. It also gives details of study area, period of study, component of environment & its methodology. Various sections of the chapter discuss the existing land use and drainage pattern, climate and meteorological parameters. Both primary and secondary data collected for the study are depicted in this chapter.  Chapter 4: Anticipated Environmental Impacts and Mitigation Measures This chapter describes the overall impacts of the project activities on various environmental components. It predicts the overall impact of the project activities on different components of the environment viz. Air, Water, Land, Noise, Biological and Socio-Economic and its mitigation measures.  Chapter 5: Analysis of Alternatives

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This chapter gives details of analysis of alternatives in terms of technology & site.

 Chapter 6: Environmental Monitoring Programme This chapter describes technical aspects of monitoring (including measurement methodologies, frequency, location and data analysis, reporting schedules, emergency procedures, detailed budget and procurement schedules.  Chapter 7: Additional Studies This chapter describes Risk assessment and on-site, off-site emergency plan and occupational health & safety programme.  Chapter 8: Project Benefits This chapter focuses on benefits of project on improvement in physical infrastructure, social infrastructure & other tangible benefits.  Chapter 9: Environmental Cost Benefit Analysis  Chapter 10: Environmental Management Plan This chapter describes Environment Management Plan (EMP) to be adopted for mitigation of anticipated adverse impacts if any and to ensure acceptable impacts.  Chapter 11: Summary & Conclusion It gives brief of the EIA Report and chapters there in. It also describes about overall justification for implementation of the project and explanation on various mitigation measures.  Chapter 12: Disclosure of Consultants engaged This chapter describes the name of the consultant engaged with their brief nature of consultancy activities.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 1-25 San Envirotech Pvt. Ltd., Ahmedabad Chapter-2 Project Description

2.1 INTRODUCTION M/s. Orgosynth Chemicals Pvt. Ltd. is a Greenfield project, proposes to setup Various Dye Intermediates manufacturing unit at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center, Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Total production capacity of the plant will be 3049 MT/month. Detailed product list is given in Table 2.3. As per the EIA Notification, 2006, proposed activity is listed at S. No. 5(f) - Synthetic Organic Chemicals industry under Category “A”. The estimated cost of the proposed project will be around Rs. 20.25 Crores. Out of this, around Rs. 1.84 Crores will be capital cost for EMS and Rs. 2.37 Crores will be recurring cost per annum. Time of project completion will be about 1.0 – 1.5 years after accordance of the EC. Based on the type of project, following are the expected aspects:  Air Emissions,  Waste water generation,  Noise generation,  Hazardous waste generation, and  Occupational Health, Hazards & Safety Risk 2.2 NEED FOR THE PROJECT The dyestuff sector is one of the important segments of the chemicals industry in India, having forward and backward linkages with a variety of sectors like textiles, leather, paper, plastics, printing inks and foodstuffs. The textile industry accounts for the largest consumption of dyestuffs (about 80% of the total dye production). In contrast, 40-50% of dyes produced in the developed countries find application in paint industry, 30%-40% in other industries and less than 10% of the aggregate is used in textile sector. From being importers and distributors in the 1950s, the dyestuff sector has now emerged as a very strong industry and a major foreign exchange earner. India has emerged as a global supplier of

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-1 San Envirotech Pvt. Ltd., Ahmedabad

dyestuffs and dye intermediates. Dyestuff production is meeting more than 95% of the domestic requirement. The demand for dyes & dye intermediates intended to be manufactured is increasing in the country. Setting up this unit, PP will be able to meet the demand of various products locally. The unit will use good faith efforts to employ local people from the nearby villages depending upon the local availability of skilled & un-skilled human resource. The proposed project will give direct employment to local people based on qualification and requirement. In addition to direct employment, indirect employment shall generate ancillary business to some extent for the local population. In operation phase, the proposed project would require significant workforce of non-technical and technical grade. Migration of highly educated and skilled experience persons will result in increase of literacy in the surrounding villages. In view of the availability of scientific staff that able to develop sustainable process at relatively low cost, and high demand of product in market company has decided to produce above products. 2.3 LOCATION OF THE PROJECT The site for the proposed project is located in MPIDC Growth Center Borgaon of Chhindwara District. Geographical coordinates of the site is 21°33'14.27"N Latitude & 78°48'15.86"E Longitude. Location of the project, Google map and boundary Co-ordinates of the site are shown in Figure 2.1, Figure 2.2 and Figure 2.3, respectively. The project site is approachable by Chhindwada Road. Nearest railway station is Lodhikheda Railway Station at about 5.6 km and Chhindwara Airport at about 51.0 km. There is no National Park, wildlife Sanctuary, Eco Sensitive Areas present in surrounding 10 km radius.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-2 San Envirotech Pvt. Ltd., Ahmedabad

Figure 2.1 Location of the project site

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-3 San Envirotech Pvt. Ltd., Ahmedabad

Figure 2.2 Location on Google map (5 & 10 km Radius)

Figure 2.3 Image showing all boundaries coordinates of the site

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-4 San Envirotech Pvt. Ltd., Ahmedabad

Table 2.1 Boundary coordinates of the site Latitude Longitude Latitude Longitude A 21°33'13.45"N 78°48'12.16"E H 21°33'16.46"N 78°48'17.41"E B 21°33'15.76"N 78°48'12.89"E I 21°33'15.91"N 78°48'20.17"E C 21°33'15.49"N 78°48'13.97"E J 21°33'12.07"N 78°48'17.45"E D 21°33'16.45"N 78°48'14.13"E K 21°33'12.39"N 78°48'16.21"E E 21°33'16.34"N 78°48'14.51"E L 21°33'12.74"N 78°48'14.88"E F 21°33'15.98"N 78°48'15.84"E M 21°33'13.10"N 78°48'13.49"E G 21°33'15.67"N 78°48'16.97"E 2.4 SIZE OR MAGNITUDE OF OPERATION 2.4.1 Land Breakup & Project Site Layout Total land area of the project is 17432 m2. Greenbelt will be developed in around 5763 m2 which will be 33% of the project area. Detailed break up of land is given below in Table 2.2 and plant layout is given in Figure 2.4. Table 2.2: Land area breakup Sr. Particular Area No. (m2) 1. Manufacturing Plant area 2650 2. Raw Materials & Finished Goods Storage 400 3. ETP, MEE, RO 600 4. Utilities area 1070 5. Green Belt area 5763 6. Tank Farm 1296 7. Haz. Waste storage area 332 8. Internal Road & Open Space 1700 9. Miscellaneous 3621 Total 17432 (Source: M/s. Orgosynth Chemicals Pvt. Ltd.)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-5 San Envirotech Pvt. Ltd., Ahmedabad

Figure 2.4 Plant Layout

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-6 San Envirotech Pvt. Ltd., Ahmedabad

2.4.2 Project Magnitude Complete list of proposed products is given in below Table. Table 2.3: List of products with its capacity Sr. Name of the Product CAS No Qty. No. MT/Month 1 2,5/3,4 Dichloro Nitro Benzene 611-06-3 400 2 2, 4 Di Nitro Chloro Benzene 97-00-7 600 (2,4-DNCB) 3 3, 4 Di Nitro Chloro Benzene 611-06-3 100 (3,4-DNCB) 4 Para Chloro Ortho Nitro Aniline (PCONA) 89-63-4 350 5 Ortho Chloro Para Nitro Aniline (OCPNA) 121-87-9 90 6 2,4-Dinitro Aniline (2,4-DNA) 97-02-9 540 7 Ortho Nitro Aniline (ONA)/ 88-74-4 100 Para Nitro Aniline (PNA) 100-01-6 8 6 Bromo 2,4 Dinitro Aniline 1817-73-8 200 (6 Bromo 2,4-DNA) 9 6 Chloro 2,4 Dinitro Aniline 3631-19-8 200 (6 Chloro 2,4-DNA) 10 2:6 Di Bromo Para Nitro Aniline 827-94-1 100 (2,6-DBPNA) 11 2:6 Di Chloro Para Nitro Aniline 99-30-9 100 (2,6-DCPNA) 12 2,6-DB Para Toluidine 6968-24-7 100 13 Fast Red B Base & Fast Scarlet R Base 97-52-9 20 14 Fast Bordeaux GP Base 96-96-8 20 15 Meta Nitro Para Toluidine (MNPT) 89-62-3 10 16 2, Cyano Para Nitro Aniline 17420-30-3 30 17 2-Chloro-4-6 Dimethoxy-[1,3,5] Triazine 3140-73-6 50 18 4-Bromo Anisole 104-92-7 5 19 Para Bromo Phenol/4-Bromo Phenol 106-41-2 5 20 4-Hydroxy Anisole 150-76-5 5 21 Veratrol 91-16-7 5 22 2-Methyl 4,5 Dimethoxy Benzoic Acid 5653-40-7 5 23 2-(2-Methoxy Phenoxy) Ethyl Amine 1836-62-0 5 24 2-Amino 4-Fluoro Benzophenone 3800-06-4 5 25 Miconazole Nitrate 22916-47-8 2 26 Hydrochlorothaizide 58-93-5 2 Total 3049 (Source: Orgosynth Chemicals Pvt. Ltd.)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-7 San Envirotech Pvt. Ltd., Ahmedabad

2.5 INFRASTRUCTURE FACILITIES (PROPOSED PLANT EQUIPMENTS/ MACHINERIES) The list of tentative proposed equipment/machineries is given below in Table 2.4. Table 2.4: List of machineries/equipment

Sr. No. Equipments/Machineries Qty. MOC Capacity Equipments/ Machineries 1 Reactor 4 SS 10 KL 5 SS 5 KL 4 MS 10 KL 8 MS 6 KL 5 SS 6 KL 5 SS 5 KL 6 SS 3 KL 2 Reactor 3 GLR 10 KL 5 GLR 6.3 KL 5 GLR 5 KL 3 Auto Clave 8 MS/CI 6 KL 4 MS/CI 5 KL 4 Dumping Vessel 3 PP/FRP 16 KL 4 PP/FRP 25 KL 4 PP/FRP 30 KL 5 Isolation Vessel 2 PP/FRP 15 KL 3 PP/FRP 25 KL 3 PP/FRP 40 KL 6 Holding Tanks 5 MS 50 KL 4 SS 25 KL 3 Aluminium 30 KL 7 Filter Press 5 PP 48'' x 48'' 3 PP 36'' x 36'' 8 Nutch 6 PP 13 m3 9 Centrifuge/ANF 9 SS 48'' Utilities 1 Boiler 1 -- 6 TPH 2 Thermic Fluid Heater 1 -- 20 Lakhs Kcal/hr. 3 D G Set 2 -- 500 KVA 4 Cooling Tower 1 -- 1000 TR 5 Spin Flash Dryer 6 -- 200 kg/hr. 6 Air Compressor 2 -- 300 CFM 2.6 DESCRIPTION OF MANUFACTURING PROCESS The company will use the Best Available Process Technology (BAT) for the production. Manufacturing process of all products, with chemical reactions & mass balance are given below.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-8 San Envirotech Pvt. Ltd., Ahmedabad

1. 2, 5 /3, 4 Dichloro Nitro Benzene Process Description: Mixed acid containing concentrated nitric acid and concentrated Sulphuric acid is reacted with Para Di Chloro benzene to produce 2, 5 Di Chloro nitro benzene. The reaction gets completed in series of Nitrators with cooling coils and jackets. Reaction is followed by spent acid separation, washing by water, drying to get 2, 5 Di Chloro Nitro Benzene. 3, 4 Di Chloro benzene is used to produce 3, 4 Di Chloro Nitro Benzene. Chemical Reaction:

2, 5 DCNB

3, 4 DCNB NO 2

+ HNO3 + H2SO4 + H2O Cl Cl Cl Cl 3,4 - Dichloro Nitric Sulphuric 3,4- Dichloro Benzene Water Acid Acid Nitro Benzene Mass Balance:

Mass balance of 2, 5 /3, 4 Dichloro Nitro Benzene

INPUT KG OUTPUT KG

PDCB/ODCB 1180 98% Nitric Acid 530 Nitration Sulphuric Acid 710

Water 270 Spent Acid (60 - 70%) 1180 Separation

Water 430 Washing & Effluent 670 Centrifuge

Drying Loss 270 Drying 2, 5 /3, 4 Dichloro Nitro Benzene 1000

Total 3120 3120

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-9 San Envirotech Pvt. Ltd., Ahmedabad

2. 2,4-DNCB (2, 4 Di Nitro Chloro Benzene) Process Description: Mixed acid containing concentrated nitric acid and concentrated sulphuric acid is reacted with Para Nitro Chloro Benzene to produce 2, 4 Di Nitro Chloro Benzene (Only Operation parameter will change). The reaction gets completed in series of Nitrators with cooling coils and jackets. Reaction is followed by spent acid separation, washing by water, drying to get a 2, 4 Di Nitro Chloro Benzene. Chemical Reaction:

Mass Balance: Mass balance of 2,4-DNCB

INPUT KG OUTPUT KG

PNCB 1020 98% Nitric Acid 450 Nitration Sulphuric Acid 390 Spent Sulphuric Acid 295

Water 395 Spent Acid (60 - 70%) 920 Separation

Water 525 Washing & Effluent 840 Centrifuge

Drying Loss 315 Drying 2,4-DNCB 1000

Total 3075 3075

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-10 San Envirotech Pvt. Ltd., Ahmedabad

3. 3,4-DNCB (3, 4 Di Nitro Chloro Benzene) Process Description: Mixed acid containing concentrated nitric acid and concentrated sulphuric acid is reacted with Para Nitro Chloro Benzene to produce 3, 4 Di Nitro Chloro Benzene (Only Operation parameter will change). The reaction gets completed in series of Nitrators with cooling coils and jackets. Reaction is followed by spent acid separation, washing by water, drying to get a 3, 4 Di Nitro Chloro Benzene. Chemical Reaction:

Mass Balance:

Mass balance of 3,4-DCNB

INPUT KG OUTPUT KG

DNCB 1020 98% Nitric Acid 450 Nitration Sulphuric Acid 390 Spent Sulphuric Acid 295

Water 395 Spent Acid (60 - 70%) 920 Separation

Water 525 Washing & Effluent 840 Centrifuge

Drying Loss 315 Drying 3,4-DCNB 1000

Total 3075 3075

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-11 San Envirotech Pvt. Ltd., Ahmedabad

4. Para Chloro Ortho Nitro Aniline 5. Ortho Chloro Para Nitro Aniline 2,5 Di Chloro Nitro Benzene, recycled liquor Ammonia & anhydrous Ammonia are taken together in an autoclave for manufacturing of Ortho Chloro Para Nitro Aniline. Desired temperature and pressure maintain are 6 to 8 hours to complete the reaction. When reaction is over &excess of Ammonia is blown off through vent valve and scrubber in water to from 32% w/w Ammonia solution. Same above manufacturing process is applied by taking 3,4 Di Chloro Nitro Benzene instead of 3,4 Di Chloro Nitro Benzene for manufacturing of Para Chloro Ortho Nitro Aniline. Chemical Reaction:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-12 San Envirotech Pvt. Ltd., Ahmedabad

Mass Balance (Para Chloro Ortho Nitro Aniline):

Mass balance of PCONA

INPUT KG OUTPUT KG

3,4 Di Chloro Nitro Benzene1152 Ammonia Gas 373 Autoclave liquor Ammonia 2375 Water 2002 Amination Anhydrous Ammonia 1270 2375

liquor Ammonia 2575 Autoclave Ammonia Gas 573 Anhydrous Ammonia 1270 Amination Water 2002 2575

Ammonia Gas 350 Reactor Water 1652 2002

Water 1500 Washing & Effluent 3902 Centrifuge

Drying Loss 290 Drying PCONA 1000

Total 10142 10142

Mass Balance (Ortho Chloro Para Nitro Aniline):

Mass balance of OCPNA

INPUT KG OUTPUT KG

2,5 Di Chloro Nitro Benzene1152 Ammonia Gas 373 Autoclave liquor Ammonia 2375 Water 2002 Amination Anhydrous Ammonia 1270 2375

liquor Ammonia 2575 Autoclave Ammonia Gas 573 Anhydrous Ammonia 1270 Amination Water 2002 2575

Ammonia Gas 350 Reactor Water 1652 2002

Water 1500 Washing & Effluent 3902 Centrifuge

Drying Loss 290 Drying OCPNA 1000

Total 10142 10142

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-13 San Envirotech Pvt. Ltd., Ahmedabad

6. 2,4-DNA (2,4-Dinitro Aniline): 2, 4-Dinitro Chloro Benzene (2,4-DNCB) and Ammonia liquor are taken in an autoclave and heated together to desired temperature. Heating is stopped and due to exotherm both temperature and pressure start rising. After desired temperature is achieved the reaction mass is maintained at this temperature for 2 to 3 hrs for the completion of reaction. After reaction is complete reaction mass is cooled, excess Ammonia is drained off and it is filtered, washed and dried if required.

Chemical Reaction:

Mass Balance:

Mass balance of 2,4 Dinitro Aniline

INPUT KG OUTPUT KG

2,4 Di Nitro Chloro Benzene 1110 Autoclave Ammonia Gas 85 Anhydrous Ammonia 450 Amination

Water 790 Washing & Effluent 965 Centrifuge

Drying Loss 300 Drying 2,4 Dinitro Aniline 1000

Total 2350 2350

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-14 San Envirotech Pvt. Ltd., Ahmedabad

7. ONA (Ortho Nitro Aniline)/PNA (Para Nitro Aniline): Para Nitro Chloro Benzene, recycled liquor Ammonia & anhydrous Ammonia are taken together in an autoclave for manufacturing of Para Nitro Aniline. Desired temperature and pressure maintain are 15 to 16 hours to complete then reaction. When reaction is over & excess of Ammonia is blown off through vent and scrubber in water to from 32% w/w Ammonia solution. ChemicalChemical Reaction: Reaction: PNA

Mass Balance:

Mass balance of ONA/PNA

INPUT KG OUTPUT KG

ONCB/PNCB 1152 Ammonia Gas 373 Autoclave liquor Ammonia 2375 Water 2002 Amination Anhydrous Ammonia 1270 2375

liquor Ammonia 2575 Autoclave Ammonia Gas 573 Anhydrous Ammonia 1270 Amination Water 2002 2575

Ammonia Gas 350 Reactor Water 1652 2002

Water 1500 Washing & Effluent 3902 Centrifuge

Drying Loss 290 Drying ONCB/PNCB 1000

Total 10142 10142

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-15 San Envirotech Pvt. Ltd., Ahmedabad

8. 6 Bromo 2,4-DNA (6 Bromo 2,4 Dinitro Aniline) In the glass lined reaction vessel first hydrochloric acid is charged. Di- nitro aniline is then added. The mass is stirred for 2 hours. Bromine is then slowly charged for 2 to 3 hours. The reaction mass is maintained for 2 hours. Chlorination is then carried out under cooling conditions with the help of chlorine gas. Reacted material is checked and if found as per desired quality it is filtered in filter notch. Filtrate is reused in next batch. Chlorine, HCl and Bromine gases generated during reaction are sent to caustic scrubber. The process involves acidification, chlorination and Bromination. Chemical Reaction:

183 80.5 36.5 35.5 262.5 73 Dinitro Aniline 6 Bromo 2,4 Dinitro Aniline

Mass Balance:

Mass balance of 6 Bromo 2,4 Dinitro Aniine

INPUT KG OUTPUT KG

Hydro Chloric Acid 1285 DNA 565 Glass Lined Bromine 255 Reactor HBr 45

Chlorine 115 HCl gas 150 Chlorination Water 505

Washing & Water 800 Effluent 895 Centrifuge

Drying Loss 425 Drying 6 Bromo 2,4 Dinitro Aniine 1000

Total 3020 3020

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-16 San Envirotech Pvt. Ltd., Ahmedabad

9. 6 Chloro 2,4-DNA (6 chloro 2,4 Dinitro Aniline) In the glass lined reaction vessel first hydrochloric acid is charged. Dinitro aniline is then added. Chlorination is then carried out under cooling conditions with the help of chlorine gas for 12 to 24 hours. Reacted material is checked and if found as per desired quality it is filtered in filter nutch. Filtrate is reused in next batch. Chlorine, HCl gases generated during reaction are sent to Alkali scrubber. The process involves mainly chlorination. Finally washing is given to the cake with water up to congo

negative. The wastewater goes to ETP. Cake is dried and packed. Chemical Reaction:

+ 2HCL

183 36.5 71 237.5 2(36.5) Dinitro Aniline 6 chloro 2,4 Dinitro Aniline Mass Balance:

Mass balance of 6 Chloro 2,4 Dinitro Aniine

INPUT KG OUTPUT KG

Hydro Chloric Acid 1285 Glass Lined DNA 650 Reactor

Clorine 280 HCl gas 110 Chlorination Water 450

Washing & Water 800 Effluent 915 Centrifuge

Drying Loss 540 Drying 6 Chloro 2,4 Dinitro Aniine 1000

Total 3015 3015

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-17 San Envirotech Pvt. Ltd., Ahmedabad

10. 2,6-DBPNA (2:6 Di Bromo Para Nitro Aniline) In the reaction vessel first Para nitro aniline and Hydrochloric acid is charged. Stirring is carried out for 1 hour. Chilled liquid bromine is charged gradually with the help of dip pipe. Chlorination is then carried out under cooling conditions with the help of chlorine gas for 6 to 7 hours. Reacted material is checked and if found as per desired quality it is filtered in filter notch. Filtrate is reused in next batch. Chlorine, HCl, Bromine gases generated during reaction is sent to Alkali scrubber. The process involves chlorination and bromination. Finally washing is given to the cake with water. The wastewater goes to ETP. Cake is dried and packed. Chemical Reaction: Br O2N NH2 + Br2 + Cl2 + 2 HCLH20 = O2N NH2 + 2HCLH2O

+ 2HCL Br

138 161 71 109 297 109 73 Para Nitro Aniline 2:6 Di Bromo Para Nitro Aniline Mass Balance:

Mass balance of 2:6 Di Bromo Para Nitro Aniline

INPUT KG OUTPUT KG

Hydro Chloric Acid 1285 PNA 565 Glass Lined Bromine 575 Reactor HBr 72

Chlorine 275 HCl gas 175 Chlorination Effluent 403

Washing & Water 450 Effluent 1050 Centrifuge

Drying Loss 450 Drying 2:6 Di Bromo Para Nitro Aniline 1000

Total 3150 3150

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-18 San Envirotech Pvt. Ltd., Ahmedabad

11. 2,6-DCPNA (2:6 Di Chloro Para Nitro Aniline) In the reaction vessel first Para nitro aniline and Hydrochloric acid is charged. Stirring is carried out for 1 hour. Chlorination is then carried out under cooling conditions with the help of chlorine gas for 6 to 7 hours. Reacted material is checked and if found as per desired quality it is filtered in filter nutch. Filtrate is reused in next batch. Chlorine, HCl generated during reaction is sent to scrubber. The process involves chlorination. Finally washing is given to the cake with water. The wastewater goes to ETP. Cake is dried and packed. Chemical Reaction: Cl O2N NH2 + 2 Cl2 + 2 HCLH20 = O2N NH2 + 2HCLH2O

+ 2HCL Cl

138 142 109 207 109 73 Para Nitro Aniline 2:6 Di Chloro Para Nitro Aniline Mass Balance: Mass balance of 2:6 Di Chloro Para Nitro Aniline

INPUT KG OUTPUT KG

Hydro Chloric Acid 1620 PNA 525 Glass Lined Reactor

Clorine 550 HCl gas 175 Chlorination Water 450

Washing & Water 450 Effluent 1070 Centrifuge

Drying Loss 450 Drying 2:6 Di Chloro Para Nitro Aniline 1000

Total 3145 3145

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-19 San Envirotech Pvt. Ltd., Ahmedabad

12. 2,6-Di Bromo Para Toluidine In the reaction vessel first hydrochloric acid charged. Para toluidine is then added. The material is stirred for two hours. Liquid bromine is then added gradually. Material is allowed to react completely for 2 to 3 hours. Hydrogen peroxide is slowly and the reaction is finally carried out for 3 hours. Reacted material is checked and if found as per desired quality it is filtered in filter nutch. Filtrate is reused in next batch. Hydrochloric acid is recovered partially and reused in next batch. ChemicalCHEMICAL Reaction:REACTION:

NH2 NH2

Br Br

+ Br2 + H202 + HCL Br + HCL + 2H2O

CH3 CH3

107 162 34 36.5 266 36.5 36

PARA TOLUDINE 2,6 DI BROMO PARA TOLUDINE Mass Balance:

Mass balance of 2:6 Di Bromo Para Toluidine

INPUT KG OUTPUT KG

Hydro Chloric Acid 2900 Para Toludene 400 Glass Lined Bromine 635 Reactor HBr 68

Hydrogen Peroxide 200 Glass Lined Reactor

Washing & Water 435 Effluent 3082 Centrifuge

Drying Loss 420 Drying 2:6 Di Bromo Para Toluidine 1000

Total 4570 4570

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-20 San Envirotech Pvt. Ltd., Ahmedabad

13. Fast Red B Base and Fast Scarlet R Base Acetylation & Nitration Take Ortho Ansidine in SS Vessel Heat it up to 50°C. Cool to 40°C. Charge Acetic Anhydride between Temp 40 to 45°C within 4 hours, then maintain for 1 hour Check Tlc. If ok, then recover Acetic Acid by Vacuum Distillation. After Acetic Acid recovery, Charge MDC 25°C. Cool to 20°C

Charge HNO3 (98%) Between Temp 20 to 25°C within 4 Hours Check Tlc If Ok Then Charge Water, Stirring for 15 Minutes Settle for Half Hours Separate Organic Layer from Bottom O.L. Transfer to another SS Vessel. In SS Vessel Recover the MDC Then Cool to Rt. Filter the Nitro mass In Nutch. This N.M W/C Charge in Hydrolysis Vessel. Hydrolysis Take water charge Caustic Flakes then charge nitro mass w/c heat it up to 70 to 72°C maintain for 6 hours check TLC then cool to RT filter it wash with water C.F it and dry it. Pack in bag and dispatch it. Separation Take Sulphuric Acid with Water and separate effluent and then send to Drying and final product fast B Base 875 Kg and effluent neutral with caustic and separate as by product Fast Scarlet R Base. ChemicalChemical Structure Reaction :

OCH3 OCH3

NH2 NH2

NO2 NO2

Chemical Name of Fast Red Chemical Name of Fast Sacrlet R B Base is 2-Amino 5 Nitro Anisole Base is 4-Nitro ortho Anisidine

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-21 San Envirotech Pvt. Ltd., Ahmedabad

Mass Balance: Mass balance of Fast Red B Base and Fast Scarlet R Base

INPUT KG OUTPUT KG

Ortho Anisidine 830 SS Reactor Acetic Anhydride 690 Acetic Acid 408 Acetylation

MDC 4166 SS Reactor Water 2400 MDC Recover 4000 Nitration Nitric Acid (60%) 715 Effluent 1960

Caustic Flacks 208 Hydrolysis Water 2000

Washing & Water 450 Effluent 3681 Centrifuge

Drying Loss 410 Drying Fast Red B Base 875 Fast Scarlet R Base 125

Total 11459 11459

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-22 San Envirotech Pvt. Ltd., Ahmedabad

14. Fast Bordeaux GP Base: Acetylation & Nitration Take Para Ansidine in SS Vessel Heat it up to 50°C Cool to 40°C Charge Acetic Anhydride Between Temp 40 To 45°C Within 4 Hours Then Maintain For 1 Hour Check Tlc If Ok Then Recover Acetic Acid By Vacuum Distillation After Acetic Acid Recovery Charge MDC 25°C Cool to 20°C 0 Charge HNO3 (60%) Between Temp 20 to 25 C within 4 hours Check Tlc If ok Then Charge Water 2400 Liter Staring For 15 Minutes Settle for Half Hours Separate Organic Layer from Bottom O.L. Transfer to another SS Vessel. In SS Vessel Recover the MDC Then Cool to Rt. Filter the Nitro mass In Nutch. This N.M W/C Charge in Hydrolysis Vessel. Hydrolysis Take water, charge Caustic Flakes then charge nitro mass w/c heat it up to 70 to 72°C maintain for 6 hours check TLC then cool to RT filter it wash with water C.F it and dry it. Pack in bag and dispatch it. Chemical Reaction:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-23 San Envirotech Pvt. Ltd., Ahmedabad

Mass Balance: Mass balance of Fast Bordeaux GP Base

INPUT KG OUTPUT KG

Para Anisidine 830 SS Reactor Acetic Anhydride 690 Acetic Acid 408 Acetylation

MDC 4166 SS Reactor Water 2400 MDC Recover 4000 Nitration Nitric Acid (60%) 715 Effluent 1960

Sulphuric Acid 200 Hydrolysis Water 1500

Washing & Water 450 Effluent 3173 Centrifuge

Drying Loss 410 Drying Fast Bordeaux GP Base 1000

Total 10951 10951

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-24 San Envirotech Pvt. Ltd., Ahmedabad

15. MNPT (Meta Nitro Para Toluidine) Acetylation & Nitration Take Para Toluedine In SS Vessel Heat it up to 50°C Cool to 40°C Charge Acetic Anhydride Between Temp 40 To 45°C Within 4 Hours Then Maintain For 1 Hour Check Tlc If ok Then Recover Acetic Acid by Vacuum Distillation After Acetic Acid Recovery Charge MDC 25°C Cool to 20°C

Charge HNO3 (98%) Between Temp 20 to 25°C Within 4 Hours Check Tlc If ok Then Charge Water Staring for 15 Minutes Settle for Half Hours Separate Organic Layer from Bottom O.L. Transfer to another SS Vessel. In SS Vessel Recover the MDC Then Cool to Rt. Filter the Nitro mass In Nutch. This N.M W/C Charge in Hydrolysis Vessel. Hydrolysis Take water charge Caustic Flakes then charge nitro mass w/c heat it up to 70 to 72°C maintain for 6 hours check TLC then cool to RT filter it wash with water C.F it and dry it. Pack in bag and dispatch it. Chemical Reaction:

Mass Balance: Mass balance of Meta Nitro Para Toluidine

INPUT KG OUTPUT KG

Para Anisidine 830 SS Reactor Acetic Anhydride 795 Acetic Acid 465 Acetylation

MDC 4166 SS Reactor Water 2400 MDC Recover 4000 Nitration Nitric Acid (98%) 600 Effluent 1960

Caustic Flacks 311 Hydrolysis Water 2000

Washing & Water 450 Effluent 3717 Centrifuge

Drying Loss 410 Drying Meta Nitro Para Toluidine 1000

Total 11552 11552

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-25 San Envirotech Pvt. Ltd., Ahmedabad

16. 2, Cyano Para Nitro Aniline Nitration: Charge Sulphuric acid and in a reactor and Charge OCBN (Ortho Chloro Benzene Nitrile). Charge Nitric acid slowly and test TLC and GC. Charge water and Ice. Filter Nitro mass and wash with water. Unload Wet product cake for Ammonolysis in stage 2. Ammonolysis Charge MCB in a reactor and add WPC of stage 1. Distil MCB-Water azeotrope and dehydrate and reject water layer recycle MCB in a rector. Transfer reaction mass to Autoclave. Purge Ammonia gas and start heating. Gradually heat till 90 deg C and Pressure 30 bar. Maintain for 2 hrs and check TLC. Recover ammonia. Cool to RT. Filter and wash WPC with water. Collect ML and separate MCB and water. Recycle MCB in next batch. Mass Balance:

Mass balance of 2, Cyano Para Nitro Aniline

INPUT KG OUTPUT KG

Ortho Chloro Benze Nitrile500 Sulfuric Acid 2960 SS Reactor Nitric Acid 240 Spent Sulphuric Acid 7870 Nitration Ice 4000 Water 1800

MCB 1000 Ammonia Gas 240 Amminolysis MCB Recover 960 Effluent 120

Washing & Water 1450 Effluent 1830 Centrifuge

Drying Loss 410 Drying 2, Cyano Para Nitro Aniline 1000

Total 12190 12190

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-26 San Envirotech Pvt. Ltd., Ahmedabad

17. 2-Chloro-4-6 Dimethoxy–[1,3,5] Triazine In a mixture of sodium bicarbonate, water and methanol, cyanuric chloride is added at 5 to 10 deg over a period. Heated to 40-45 deg and maintained till completion of reaction. Product is diluted by water and extracted by dichloromethane. Concentration of dichloromethane is carried out to isolate the product. Chemical Reaction:

Mass Balance:

Mass balance of 2-Chloro-4-6 dimethoxy –[1,3,5] Triazine

INPUT KG OUTPUT KG

Methanol 2370 NaHCO3 687 SS Reactor Cynuric Chloride 855 Methanol 2290 Cynuration

MDC/Ethyl Acetate 1074 MDC/Acetyle Acetate 960 Water 2370 Reactors Effluent 2331 Toluene 855 Toluene 840

Washing & Water 1450 Effluent 1830 Centrifuge

Drying Loss 410 2-Chloro-4-6 dimethoxy Drying –[1,3,5] Triazine 1000

Total 9661 9661

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-27 San Envirotech Pvt. Ltd., Ahmedabad

18. 4-Bromo anisole Charge dichloromethane, anisole and HBr in the reactor. Cool to 10-40 deg C. Hydrogen peroxide is added over a period keeping temperature 10-40 deg C and maintain till completion of reaction. Chemical Reaction:

Mass Balance: Mass balance of 4- Bromo anisole

INPUT KG OUTPUT KG

Anisole 700 MDC 1000 SS Reactor BHr 540 Hydrogen Peroxide 520

Reflucx & MDC 950 Distillation

Washing & Water 1600 Effluent 1980 Centrifuge

Drying Loss 430 Drying 4- Bromo anisole 1000

Total 4360 4360

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-28 San Envirotech Pvt. Ltd., Ahmedabad

19. Para Bromo Phenol/4-Bromo phenol Bromination of phenol is carried out at 0-5 deg C using ethyl acetate and bromine. Product is isolated by neutralization followed by distillation of bromophenol. Chemical Reaction:

Mass Balance:

Mass balance of Para Bromo Phenol/ 4-Bromo phenol

INPUT KG OUTPUT KG

Phenol 570 Ethyl Acetate 2000 SS Reactor Bromine 560 HBr 65 Hydrogen Peroxide 930

Reflux & Ethyl Acetate Recovery 1960 Distillation

Washing & Water 1000 Effluent 1605 Centrifuge

Drying Loss 430 Drying 4- Bromo anisole 1000

Total 5060 5060

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-29 San Envirotech Pvt. Ltd., Ahmedabad

20. 4-Hydroxy Anisole In a mixture of anisole, Dichloromethane and HBr is charged in reactor and cooled to 10-15 deg. Add hydrogen peroxide over a period of 4 to 5 hrs. Separate layer. Product is treated with aqueous sodium hydroxide. Product is isolated by acidification followed by purification. Chemical Reaction:

Mass Balance:

Mass balance of 4- Hydroxy anisole

INPUT KG OUTPUT KG

Anisole 1070 MDC 1400 SS Reactor HBr 1250 Hydrogen Peroxide 825

Reflucx & MDC 1350 Distillation

NaOH 1025 HCl 1400 Recovered n-Butenol 950 Hydrolysis n-Butenol 1000 Sodium Bromide 900 Water 4000 Effluent 5410

Centrifuge Effluent 1500

Drying Loss 860 Drying 4- Hydroxy anisole 1000

Total 11970 11970

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-30 San Envirotech Pvt. Ltd., Ahmedabad

21. Veratrol Manufacturing process: Take Catechol, caustic flakes and water. Add toluene and DMS at 35-40 deg. Reflux for eight hours. Separate layers and distil product. Chemical Reaction:

Mass Balance:

Mass balance of Veratrol

INPUT KG OUTPUT KG

Catechol 840 Toluene 2400 Dimethyl Sulphate 2115 SS Reactor NaOH 415 Water 2000

Reflucx & Recover Toluene 2330 Distillation

Filtration Effluent 2580

Effluent 1000 Centrifuge

Drying Loss 860 Drying Veratrol 1000

Total 7770 7770

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-31 San Envirotech Pvt. Ltd., Ahmedabad

22. 2-Methyl 4,5 Dimethoxy Benzoic Acid Manufacturing Process: To 4-methyl catechol and sodium hydroxide added DMS and maintains at 50-60 deg C. Product extracted in toluene and then taken for next stage. The product is acytylated using Aluminium Chloride and acetyl chloride. The obtained intermediate is oxidized using hydrogen peroxide to get the final benzoic acid. Chemical Reaction:

Mass Balance:

Mass balance of 2-Methyl 4,5 Dimethoxy Benzoic Acid

INPUT KG OUTPUT KG

2-Methyl Catechol 1560 NaOH (50%) 830 SS Reactor Toluene 2400 Dimethyl Sulphate 1570

Reflucx & Recover Toluene 2350 Distillation Effluent 3675

MDC 3000 Acetyl Chloride 780 Aluminum Chloride 1330 SS Reactor Alluminum Chloride 3000 Water 3000 Recover MDC 2850 Hydrogen Peroxide 2135

Effluent 2000 Filtration

Effluent 870 Centrifuge

Drying Loss 860 Drying 2-Methyl 4,5 Dimethoxy Benzoic Acid 1000

Total 16605 16605

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-32 San Envirotech Pvt. Ltd., Ahmedabad

23. 2-(2-Methoxy Phenoxy) Ethyl Amine Charge Guaiacol and EDC in the reactor. Add Sodium hydroxide solution. Heat reaction mass to reflux and maintain till completion of reaction. Add potassium phthalimide and reflux for 3-hours. Isolate product by filtration. Filtered product is acidified with hydrochloric acid, followed by toluene extraction. Product is distilled at high temperature. Chemical Reaction:

Mass Balance:

Mass balance of 2-(2-methoxy phenoxy) ethyl amine

INPUT KG OUTPUT KG

Guaicol 1120 EDC 890 SS Reactor Water 1200 Sodium Hydroxide 515

DMF 1000 Reflucx & Pottesium Phthalimide 963 Recover DMF 950 Distillation

Water 2700 Effluent 3250 Filtration

Sodium Hydroxide 630 Toluene 1000 Recover Toluene 950 Hydrochloric Acid 560 SS Reactor Effluent 2818

Effluent 750 Centrifuge

Drying Loss 860 Drying 2-(2-methoxy phenoxy) ethyl amine 1000

Total 10578 10578

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-33 San Envirotech Pvt. Ltd., Ahmedabad

24. 2-Amino-4-Fluoro benzophenone Phthalimide is reacted with flurobenzene in presence of Aluminium Chloride. The intermediate is isolated and reacted with sodium hypochlorite. Product isolated by filtration. Chemical Reaction:

Mass Balance:

Mass balance of 2-Amino-4-Fluoro benzophenone

INPUT KG OUTPUT KG

Phthalamide 760 Alluminum Chloride 830 SS Reactor Flurobenzene 600

Water 1000 Recover AlCl3 1400 Sodium Hydroxide 1150 SS Reactor Effluent 920

Effluent 430 Centrifuge

Drying Loss 590 Drying 2-Amino-4-Fluoro benzophenone 1000

Total 4340 4340

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-34 San Envirotech Pvt. Ltd., Ahmedabad

25. Miconazole Nitrate Three stage process - Stage-I: Reaction of metadichloro benzene with Lewis acid catalyst aluminium chloride and chloroacetyl chloride under cold conditions. The hydrochloric acid gas is scrubbed in scrubber and reaction is monitored by TLC or GC. After completion of reaction the mass is drowned in ice and hydrochloric acid mixture. The product is extracted by toluene. Aqueous layer is acidic and neutralized or sold as aluminium chloride hydrate. Stage-II: The stage I is subjected for sodium borohydride reduction at 10-50 deg C. To the above solution caustic flakes and imidazole is added and stirred at 50 deg C till completion of reaction. Product is isolated by filtration. Stage-III: In toluene solution of stage -II DCBC is added and maintained for 5 hrs at 50-55 deg C. After completion of reaction layers are separated and to organic layer 60% nitric acid is added. The salt precipitate out is filtered and dried. Stage-I:

Stage-II:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-35 San Envirotech Pvt. Ltd., Ahmedabad

Stage -III:

Mass Balance:

Mass balance of Miconazole Nitrate

INPUT KG OUTPUT KG

MDCB 400 CAC 310 Acylation Sodium Hydroxide 100

Water 500 Toluene 1200 Mixing Effluent 1025

Recover Toluene 1160 Distillation Residue 125

Toluene 1000 Reduction Sodium Bisulphite 10

Imidazole 170 DMSO 100 Recover Toluene 950 Condansation Sodium Hydroxide 100 Residue 225 Toluene 1000

Imidazole 2-4 Dichloro Benzyl 860 Chloride Condansation Nitric Acid 810 Recover Toluene 950 Sodium Hydroxide 500 Residue 225 Toluene 1000

Filter & Effluent 2000 Centrifuge

Drying Loss 400 Drying Miconazole Nitrate 1000

Total 8060 8060

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-36 San Envirotech Pvt. Ltd., Ahmedabad

26. Hydrochlorothaizide Three stage process- Stage-I: Reaction of sulphonation established between m-Chloroamine with Chloro Sulphonic Acid under cold and control conditions. The Reaction is exothermic. After completion of reaction the mass is drowned in ice and water. Stage-II: During the dumping, entire mass stirrer for desire time. After completion of reaction, entre mass separate by layer separation/filtration. Recover mass is taken for next state of process and filtrate is dilute Sulphuric Acid recover for sale to actual users. Stage-III: Ammonia Solution is added at this stage for amination of mass. Here Amminolysis reaction established and Aluminum Chloride separate out for sale to actual users. Stage-IV: Reaction mass after crystallization in MCB. After crystallization, MCB recovered for next uses. Then mass centrifuge, Drying and packing to dispatch. Chemical Reaction:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-37 San Envirotech Pvt. Ltd., Ahmedabad

Mass Balance:

Mass balance of Hydrochlorothiazide

INPUT KG OUTPUT KG

m-Chloro Amine 430 Chloro Sulphonic Acid 785 Sulphonation

Ice 1050 Water 1500 Dumping Dilute Sulphuric Acid 1500

Ammonia Solution 200 Recover AlCl3 1500 Amminolysis

Water 500 Filtration

Formaldehyde 100 MCB 1800 Recover MCB 1750 Crystalization Residue 125

Effluent 229 Centrifuge

Drying Loss 261 Drying Hydrochlorothiazide 1000

Total 6365 6365

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-38 San Envirotech Pvt. Ltd., Ahmedabad

2.7 PROJECT COMPONENTS Components of the project include all facilities required for the operation, which is summarized below: a) Input Requirement: Raw materials, Water, Fuel, Power b) Utility requirement: Boiler, TFH, D.G Set, Spin Flash Dryer etc. c) Treatment Facilities:  Water treatment facilities: ETP, RO, MEE/ATFD  Air Pollution Control Facilities: Cyclone and bag filter as APCM for flue gas stack. Water, Alkali scrubber, Acid Scrubber for process vents. In-built cyclone and bag filter for Spin Flash Dryer.  Hazardous waste disposal facilities: It includes hazardous waste storage and final disposal facility. d) Other facilities: Greenbelt area and water harvesting facilities. 2.8 INPUT REQUIREMENTS a) Raw material requirement: The transportation of raw materials will be done by road complying with all safety requirements. Raw materials are indigenously available and will be transported by road; and in case of unavailability, will be imported. The raw materials will be stored/inventory will be maintained as per market requirement of the products and production schedule. The list of raw material of each product is given below Table 2.5. Table 2.5: Raw Materials Requirement, Availability & Mode of Transport

Sr. Product Raw Material CAS No. Quantity Source Mode of No. name Name (MT/Month) Transport 1 2, 5/3, 4 Ortho/ Para Dichloro 89-61-2 472 Local Road Dichloro Nitro Benzene Benzene Conc. Nitric Acid 7697-37-5 212 Local Road Sulphuric acid 7664-93-9 284 Local Road Weak Sulphuric Acid 7664-93-9 302 Local Road 2 2,4-DNCB PNCB 100-00-5 612 Conc. Nitric Acid 7697-37-5 270 Local Road Sulphuric Acid 7664-93-9 234 Local Road Weak Sulphuric Acid 7664-93-9 430 Local Road 3 3,4-DCNB Ortho Dichloro 89-61-2 102 Local Road Benzene Conc. Nitric Acid 7697-37-5 45 Local Road Sulphuric Acid 7664-93-9 39 Local Road Weak Sulphuric Acid 7664-93-9 72 Local Road 4 PCONA 2,5-DCNB 611-06-3 403 Local Road Anhydrous Ammonia 7664-41-7 889 Local Road 5 OCPNA 3,4-DCNB 611-06-3 103 Local Road

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-39 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Product Raw Material CAS No. Quantity Source Mode of No. name Name (MT/Month) Transport Anhydrous Ammonia 7664-41-7 228 Local Road 6 2,4-DNA 2,4-DNCB 97-00-7 600 Local Road Anhydrous Ammonia 7664-41-7 243 Local Road 7 PNA Para Nitro Chloro 88-73-3 115 Local Road Benzene Anhydrous Ammonia 7664-41-7 254 Local Road 8 6 Bromo 2,4- 2,4-DNA 97-02-9 257 Local Road DNA Bromine 7726-95-6 112 Local Road Chlorine 7782-50-5 51 Local Road Hydrochloric Acid 7647-01-0 23 Local Road 9 6 Chloro 2,4- 2,4-DNA 97-02-9 257 Local Road DNA Chlorine 7782-50-5 130 Local Road Hydrochloric Acid 7647-01-0 56 Local Road 10 2,6-DBPNA PNA 100-01-6 56 Local Road Chlorine 7782-50-5 27 Local Road Bromine 7726-95-6 57 Local Road Hydrochloric Acid 7647-01-0 28 Local Road 11 2,6-DCPNA PNA 100-01-6 52 Local Road Chlorine 7782-50-5 55 Local Road Hydrochloric Acid 7647-01-0 162 Local Road 12 2,6-DB Para Para Toluidine 106-49-0 40 Local Road Toluidine Bromine 7726-95-5 63 Local Road Hydrogen Peroxide 7722-84-1 20 Local Road Hydrochloric Acid 7647-01-1 290 Local Road 13 Fast Red B Para Anisidine 97-52-9 16.6 Local Road Base Acetic Anhydride 108-24-7 13.8 Local Road Conc. Nitric Acid 7697-37-5 15 Local Road MDC 75-09-2 10 Local Road Caustic Soda 1310-73-2 5.4 Local Road Sulphuric Acid 7664-93-9 4 Local Road 14 Fast Bordeaux Ortho Anisidine 96-96-8 16.6 Local Road GP Base Acetic Anhydride 108-24-7 13.8 Local Road Conc. Nitric Acid 7697-37-5 14.2 Local Road MDC 75-09-2 10 Local Road Sodium Hydroxide 131-73-2 5.4 Local Road 15 MNPT (Meta Para Toluidine 119-32-4 8.3 Local Road Nitro Para Acetic Anhydride 7697-37-5 8.0 Local Road Toludine) Conc. Nitric Acid 7664-93-9 6.0 Local Road MDC 75-09-2 8.0 Local Road Sodium Hydroxide 1310-73-2 3.2 Local Road 16 2-Cyano Para OCBN 873-32-5 15 Local Road Nitro Aniline Sulphuric Acid 7664-93-9 88 Local Road Nitric Acid 7697-37-5 7.2 Local Road MCB 108-90-7 1.2 Local Road Anhydrous Ammonia 7664-41-7 7.2 Local Road 17 2-Chloro-4-6 Cyanuric Chloride 108-77-00 42.0 Local Road dimethoxy – Methanol 67-56-1 4.0 Local Road [1,3,5] Sodium Bicarbonate 144-55-8 6.87 Local Road Triazine MDC 75-09-2 5.7 Local Road Toluene 108-88-3 1.0 Local Road 18 4-Bromo Anisole 100-66-3 3.5 Local Road anisole MDC 75-09-2 1.0 Local Road

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-40 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Product Raw Material CAS No. Quantity Source Mode of No. name Name (MT/Month) Transport Hydrobromic Acid 10035-10-6 2.7 Local Road Hydrogen Peroxide 124-43-6 2.6 Local Road 19 Para Bromo Phenol 108-95-2 2.85 Local Road Phenol/ 4- Ethyl Acetate 141-78-6 0.2 Local Road Bromo phenol Bromine 7726-95-6 2.8 Local Road 20 4- Hydroxy Anisole 100-66-3 5.4 Local Road anisole MDC 75-09-2 0.25 Local Road Hydrobromic Acid 10035-10-6 6.25 Local Road Hydrogen Peroxide 124-43-6 4.1 Local Road Sodium Hydroxide 1310-73-2 5.1 Local Road Hydrochloric Acid 7647-01-0 7.0 Local Road N-Butanol 71-36-3 5.0 Local Road 21 Veratrol Catechol 120-80-9 4.2 Local Road Toluene 108-88-3 10 Local Road Dimethyl Sulphate 77-781 11 Local Road Sodium Hydroxide 1310-73-2 4.6 Local Road 22 2-Methyl 4,5 4-Methyl Catechol 452-86-8 7.8 Local Road Dimethoxy Sodium Hydroxide 1310-73-2 16 Local Road Benzoic Acid Toluene 108-88-3 10 Local Road Dimethyl Sulphate 77-78-1 8.0 Local Road MDC 75-36-5 15 Local Road Acetyl Chloride 7446-70-0 3.9 Local Road Aluminium Chloride 124-43-6 6.7 Local Road Hydrogen Peroxide 452-86-8 10.7 Local Road 23 2-(2-Methoxy 2-Methoxy Phenol 90-05-1 11.2 Local Road Phenoxy) Ethylene Dichloride 25952-53-8 9.0 Local Road Ethyl Amine Sodium Hydroxide 1310-73-2 2.6 Local Road 50% DMF 68-12-2 10 Local Road Potassium 1074-82-4 9.7 Local Road Phthalimide Sodium Hydroxide 1310-73-2 14.3 Local Road Toluene 108-88-3 10.0 Local Road Hydrochloric Acid 7647-01-0 12.6 Local Road 24 2-Mino 4- Phthalimide 85-41-6 3.8 Local Road Fluoro Aluminium Chloride 7446-70-0 4.2 Local Road Benzophenone Fluoro Benzene 462-06-6 3.0 Local Road Sodium Hypochlorite 7681-52-9 5.75 Local Road 25 Miconazole MDCB 541-73-1 0.8 Local Road Nitrate Chloro Acetyl 79-40-9 0.62 Local Road Chloride Toluene 108-88-3 2.28 Local Road Imidazole 288-32-4 0.34 Local Road 2,4-Dichloro Benzyl 94-99-5 1.72 Local Road Chloride Sodium Hydroxide 1310-73-2 1.4 Local Road Nitric Acid 7664-93-9 1.62 Local Road 26 Hydro Chloro m-Chloramine 127-65-1 0.86 Local Road Thaizide Chlorosulphonic Acid 7790-94-5 1.57 Local Road Aqueous Ammonia 7641-64-7 0.4 Local Road Formaldehyde 50-00-0 0.2 Local Road

MCB 108-90-7 0.1 Local Road

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-41 San Envirotech Pvt. Ltd., Ahmedabad

b) Water requirement: Total water requirement (Industrial + Domestic + Greenbelt) of the unit will be 300 KLD; out of which 70 KLD will be fresh water requirement & 230 KLD will be recycle/treated water (ETP-RO permeate, MEE Condensate). Unit will satisfy its fresh water requirement from MPIDC. Major water demand will be for industrial – mainly Process (130 KLD), Washing (10 KLD), Scrubber (30 KLD) and Utility (100 KLD). Water requirement for Domestic will be 10 KLD and Greenbelt will be 15 KLD. Detailed breakup of water consumption and water balance diagram is given in Table 2.6 & Figure 2.5, respectively. Table 2.6: Breakup of water consumption & w/w generation

Sr. Source Water Wastewater Remark No. Consumption Generation (KLD) (KLD) 1. Domestic 10.0 8.0 Fresh 2. Greenbelt 15.0 -- Fresh 3. Industrial A Process 130 205 45 Fresh + 85 Recycle B Scrubber 30.0 5.7 Recycle C Boiler 20.0 2.0 Recycle D Cooling 80.0 15.0 Recycle E Washing 15.0 15.0 Recycle Total Industrial 275 242.7 -- Total (1 + 2 + 3) 300 250.7 -- Less recycle 230 -- -- Actual fresh water 70.0 -- -- consumption

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-42 San Envirotech Pvt. Ltd., Ahmedabad

Figure 2.5 Water Balance Diagram

Total water consumption-300 KLD (70 KLD Fresh water + 230 KLD recycle)

Domestic Process Scrubber Washing Utility Gardening 10.0 45 +85 30.0 15.0 100.0 15.0

Soak pit 8.0 Water retained with 3.3 Boiler Cooling RM 119.8 HCl (25-28%) 20.0 80

HBr (25-28%)

Liq Ammonia 21

Total Volume 298.8

Drying Loss 28 40.0

Spent H2SO4 AlCl3 (30-35%)-1.0 52 Acetic Acid - 0.8

Spent H2SO4 2.0 15

24 Bow Bleed down off 5.7 15 205

ETP 205+ 5.7 + 15 + 2.0 + 15.0 = 242.7

RO Permeates 242.7 water 170

System Loss MEE/ATFD Condensate 9.2 72.7 60

Salt 3.5

c) Power: Total power requirement will be 1000 kVA, which will be fulfilled by Madhya Pradesh Poorva Kshetra Vidyut Vitaran Company Ltd. Unit will also install 2 stand by D.G. Sets of 500 kVA to meet the power requirement in case of power failure from grid.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-43 San Envirotech Pvt. Ltd., Ahmedabad

d) Fuel: Unit proposes to use Agro Briquettes/Coal in proposed utilities. Details of fuel consumption are given below. Table 2.7: Details of fuel consumption

Sr. Utility Capacity Fuel Type Consumption No. Rate 1. Steam Boiler 6 TPH Agro Briquettes/ 30 TPD Coal 2. Thermic Fluid 20 Agro Briquettes/ 15 TPD Heater Lakhs Kcal/hr. Coal 3. D G Set 500 kVA x 2 HSD 105 lit/hr. nos. e) Manpower: Total manpower for proposed project will be 100 nos., which include manpower at all levels. 2.9 GENERATION OF POLLUTANTS The sources of generation of pollutants are given below; 2.9.1 Wastewater Generation Total industrial wastewater generation will be 242.7 KLD. The main source of the industrial wastewater generation will be from process (205 KLD), washing (15.0 KLD), Boiler Blow down (2.0 KLD), Cooling bleed off (15.0 KLD) and Scrubber (5.7 KLD). Domestic sewage generation will be 8.0 KLD. The details of the wastewater generation are depicted in Table 2.6. Water balance diagram is given in Figure 2.5. 2.9.2 Gaseous Emission Flue gas emission will be from stack attached to Boiler (6 TPH), one stack of Thermic Fluid Heater (20 Lakhs Kcal/hr.) and one common stack of 2 nos. of stand by D.G. Sets (500 kVA x 2). Agro Briquettes/Coal will be used as a fuel in Boiler & TFH and HSD in stand by D.G. Set. Most

probable pollutants will be SPM, SO2 and NOx. Process emission will be from 1 vent attached to process vessel of MPP- 1, two vents of process vessel of MPP-2 and 1 common vent attached to 6 nos. of Spin Flash Dryers. Pollutants from process stacks will be will be

PM, HCl, HBr and NH3. The details of the flue gas stacks & process gas stacks and emission quality of stacks are given in Table 2.8 and Table 2.9, respectively.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-44 San Envirotech Pvt. Ltd., Ahmedabad

Sources of fugitive emission: Fugitive emission, dust is expected during storage, handling, loading/ unloading of raw materials, material transfer point, generation of acid mist & VOCs from material handling, storage area and solvent storage area. There will be also chances of generation of fugitive emission from vehicular movement for transportation of raw materials & finished goods. Table 2.8: Details of stacks

Sr. Stack Fuel Type Stack APC Probable No. attached to Height measures emission (m) Flue Gas Stacks 1. Steam Boiler Agro 30 Cyclone SPM<150 mg/Nm3 (6 TPH) Briquettes/Coal separator & SO2<100 ppm 30 TPD Bag Filter NOx<50 ppm 2. Thermic Fluid Agro 30 Cyclone SPM<150 mg/Nm3 Heater Briquettes/Coal separator & SO2<100 ppm (20 Lakhs 15 TPD Bag Filter NOx<50 ppm Kcal/hr.) 3. D G Set HSD-105 lit/hr. 11 -- SPM<150 mg/Nm3 (500 kVA x 2) SO2<100 ppm NOx<50 ppm Process Gas Stacks 3 1. Process Vessel -- 11 Water & NH3<175 mg/Nm MPP-1 Acid Scrubber 2. Process Vessel -- 11 Water & HCl<20 mg/Nm3 MPP-2 Alkali Scrubber 3. Process Vessel -- 11 Water & HBr<5 mg/Nm3 MPP-2 Alkali Scrubber 4. Spin Flash -- 21 In built SPM<45 mg/Nm3 Dryer-6 Sets cyclone & bag filter Table 2.9: Estimated Emission Quality of Stack

Sr. Stack attached Stack Temp. Velocity Dia. Concentration No. to Height (C) (m/s) (m) (mg/Nm3)

(m) SPM SO2 NOx 1. Steam Boiler 30 433 6.5 0.450 105 35 30 2. Thermic Fluid 30 443 7.5 0.450 105 35 35 Heater 3. D G Set 11 483 15.0 0.225 65 30 40 3 4. Process Vent-1 11 328 5.5 0.225 NH3=125 mg/Nm 5. Process Vent-2 11 328 5.5 0.225 HCl=15 mg/Nm3 6. Process Vent-2 11 328 5.5 0.225 HBr=2 mg/Nm3 7. Spin Flash Dryer 21 338 6.5 0.225 SPM=35 mg/Nm3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-45 San Envirotech Pvt. Ltd., Ahmedabad

2.9.3 Hazardous & Solid waste generation Main source of hazardous waste generation will be ETP sludge (200 MT/Month) & MEE salt (90 MT/Month) from wastewater treatment. Additional wastes from the process streams will be Spent Sulphuric Acid (45-70%) (1350 MT/Month), Spent Hydrochloric Acid (25-28%) and Hydrobromic Acid (25-28%) (85 MT/Month), Acetic Acid (40-42%) (20

MT/Month), Liq. Ammonia (550 MT/Month), AlCl3 (30-35%) (85 MT/Month), Used lubricating oil (1.0 Kl/year), discarded drums/ containers/liners (3000 nos. of barrel/month & 2.0 MT liners/month). Details of hazardous waste and solid waste generation with its category and quantity are given in Table 2.10. Table 2.10: Details of Solid & Hazardous waste

Sr. Type of Category Quantity Method of Disposal No. Waste No. as per Proposed HWM rules, 2016 1. ETP Waste 35.3 200 Collection, Storage, Transportation, MT/month Disposal at TSDF site. 2. Salt of MEE 35.3 90 Collection, Storage, Transportation, MT/month disposal at TSDF site. 3. Used Oil 5.1 1.0 Collection, Storage, Transportation, KL/year sell to registered re-processors or use for lubrication within premises. 4. Discarded 33.1 3000 Collection, Storage, Transportation, Containers/ Nos./month Sell to registered recyclers. Liners/Bags 2.0 MT/month 5. Spent B-15 1350 Collection, Storage and partly Sulphuric Acid MT/month reuse in-house and partly will be (45-70%) sold to actual users under Rule-9. 6. Hydrochloric B-15 85 Collection, Storage and partly Acid (25-28%) MT/month reuse in-house and partly will be 7. Hydro Bromic B-15 sold to actual users under Rule-9. Acid (25-28%) 8. Acetic Acid B-15 20 Collection, Storage and sold to (40-42%) MT/month actual users under Rule-9. 9. Liq Ammonia B-15 550 Collection, Storage and reuse in- MT/month house in same or other products.

10. AlCl3 B-15 85 Collection, Storage and sold to (30-35%) MT/month actual users under Rule-9. Solid Waste 1. Fly Ash -- 120 Collection, Storage and sell to brick MT/month manufacturers. 2.9.4 Noise generation Main source of noise generation will be of Boiler, Thermic Fluid Heater, process plant, vehicular transportation & other machineries. General noise level in the plant is expected to come below acceptable limit.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-46 San Envirotech Pvt. Ltd., Ahmedabad

2.10 POLLUTION CONTROL STRATEGY The details of pollution control strategy for various parameters are, 2.10.1 Effluent Management Sources of industrial effluent generation will be from process, washing, scrubber and utilities. Total trade effluent (242.7 KLD) will be taken into ETP, after treatment, effluent will be passed through RO. RO permeate (170 KLD) will be reused within premises and RO reject will be sent to MEE/ATFD. MEE condensate (60 KLD) will be reused. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD). Unit will built full-fledged ETP with capacity of 250 m3/day to treat effluent. Sewage (8.0 KLD) will be disposed into soak pit though septic tank. The details of the wastewater generation are shown in Table 2.6. Effluent treatment scheme ETP consist collection tank, neutralization tank, lime dosing tank, filter press, alum dosing tank, poly flock dosing tank, holding tank, pressure sand & carbon filter and sludge drying area. Effluent from manufacturing plant, washing and utilities are collected in collection tank. In primary treatment, pH of the effluent is adjusted as per the acidity/alkalinity of the effluent. In the chemical treatment, Lime + Alum + Polyelectrolytes will be added for proper flocculation/ coagulation. Then treated effluent is passed through filter press to separate out solid sludge. Clear effluent from filter press is allowed to holding tank then effluent pass though pressure sand filter, carbon filter. Treated effluent is finally passed though RO. RO permeated will be reuse and reject of RO will be evaporated in MEE. Thus, Zero Liquid Discharge (ZLD) will be achieved. Characteristic of untreated and treated effluent of process wastewater and of recycle water recovered at different stage of effluent treatment is provided in Table 2.11. Sludge will be dewatered from filter press and it will be transferred to the sludge drying bed. After drying, the dried sludge will be collected, packed in HDPE bags and stored in separate storage area and disposed at approved TSDF site.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-47 San Envirotech Pvt. Ltd., Ahmedabad

Table 2.11: Name and size of ETP units, Design capacity: 250 m3/day

Sr. Name of Unit Dimension (m) No. of Capacity No. Unit (m3) 1 Collection/ Equalization Tank 6.0 x 6.0 x 4.0, LD: 3.5 2 126 x 2=252 2 Chemical Treatment Tank 4.0 x 4.0 x 3.5, LD: 3.0 1 48 3 Lime Dosing Tank 2.0 x 2.0 x 3.0 WD: 2.5 1 10.0 4 Alum Dosing Tank 1.0 x 1.0 x 2.0, WD: 1.5 1 1.5 5 Poly Flock Dosing Tank HDPE Tank 1 1 6 Filter Press 40” x 40” x 36” plates 1 - 7 Holding tank 6.0 x 6.0 x 4.0, LD: 3.5 1 126 8 Pressure Sand Filter Standard supply 1 12 KL/Hr 9 Carbon Filter Standard supply 1 12 KL/hr. 10 RO System Standard supply 2 7.5 x 2 11 MEE/ATFD Standard supply 1 12 Sludge Drying area 10 x 15 x 1.2 4 4 x 150=600 m2 surface area Figure 2.6 Effluent Treatment Plant Flow Diagram

3 4 5

Raw Effluent

Collection/ Chemical Filter Holding Tank Equalization Treatment Press Tank Tank

Sludge

Sludge Drying Bed

Filter Dual MediaDual Sludge will be disposed to TSDF site Reverse Osmosis

RO Permeate water (for reuse)

Collection Tank RO Reject Collection Tank

Evaporation MEE/ loss ATFD

Salt to TSDF site

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-48 San Envirotech Pvt. Ltd., Ahmedabad

Table 2.12: Characteristic of untreated and treated effluent

Parameters Unit Untreated Treated RO MEE effluent effluent Permeate Condensate pH pH Unit 3.5 7.5-7.7 7.5-8.0 7.5-8.0 Color Co-Pt 890 75-100 <15 <15 Unit SS mg/L 575 95-100 <10 <10 TDS mg/L 32500 31000-32500 125 50 COD mg/L 8225 2830-2900 95 125 BOD mg/L 3410 1250-1300 25 30 Oil & Grease mg/L 15 7.0-7.5 <1.0 <1.0 Ammonical mg/L 30 25-30 <5.0 <5.0 Nitrogen 2.10.2 Air Pollution Control (APC) Measures The main source of gaseous emission will be flue gas emission & process gas emission. Flue gas emission will be will be due to the combustion of fuel Agro Briquettes/Coal in Boiler & Thermic Fluid Heater and HSD in stand by D G Set. Cyclone followed by bag filter will be installed as APCM with adequate stack height to achieve the emission norms. No need to install any APCM to stack of D.G. set as it will not be the constant source of emission. Process gas emission will be from stack attached with process vessel of MPP-1, MPP-2 and 6 sets of Spin Flash Dryer. Most probable process

pollutants will be NH3, HCl, HBr and SPM. Process stack will be installed with Water Scrubber, Acid Scrubber and Alkali scrubber to achieve the emission standards, whereas to control particulate emission, In-built bag filter will be installed as APCM on Spin Flash Dryer. Furthermore, adequate stack height and facility for sampling such as ladder, platform & sampling point will be provided as per the SPCB guidelines. The details of stacks with their APC measures & height are given in Table 2.7. Fugitive Emission Control To control fugitive emission, following steps will be implemented:  Entire process will be carried out in closed reactors  Close handling system provided for transfer of chemicals  Pneumatically transfer of liquid raw material in reactor  Provision of mechanical seals in pumps

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-49 San Envirotech Pvt. Ltd., Ahmedabad

 Raw material will be stored in the covered structure.  Regular maintenance of valves, pipes etc.  Provision water sprinklers to control air borne dust.  Fly ash will be stored in covered sheds only.  Internal road will be concreted/paved to reduce the fugitive emission during vehicular movement.  Greenbelt will be developed to arrest the fugitive emission.  Frequent work area monitoring will be done ensure fugitive emissions level. 2.10.3 Hazardous/Solid Waste Management Entire quantity of hazardous waste will be handled & disposed as per Hazardous & Other Waste (Management & Transboundary Movement) Rules, 2016. ETP sludge & MEE salt will be sent to TSDF site for land filling. Spent Sulphuric Acid (45-70%), Spent HCl (25-28%) and HBr (25- 28%) will be partly reuse in-house and partly will be sold to actual users

under Rule-9. Acetic Acid and AlCl3 will be sold to actual users under Rule-9. Liq. Ammonia will be reused in-house in same or other products. Used lubricating oil will be used within premises or disposed by selling to

registered re-processors and discarded barrels & liners will be disposed of by selling to registered recyclers. The unit will provide isolated area with impervious flooring & roof cover for the storage of hazardous waste. Details of hazardous waste disposal methods are given in Table 2.10. Fly Ash management Fly ash generation after proposed project will be around 120 MT/month. Fly ash will be sold to brick manufacturer working in 25 km radius from project site and also supplied to the companies for land leveling, conditioning & road construction, etc. 2.10.4 Noise Pollution Control Measures The main noise generating sources in the plant will be Boiler, TFH, process plant, D G Set, vehicular transportation & other machineries. All these sources will generate continuous noise. However, the noise transmitted outside the plant boundary will be low because most of the noise generating equipment will be low noise generating equipments. Equipments will be statically and dynamically balanced. Ear muff, ear

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-50 San Envirotech Pvt. Ltd., Ahmedabad

plug will be provided to all workers working at noisy area. Additionally, extensive oiling, lubrication, periodic monitoring and regular maintenance will be carried out for the machineries and equipments to reduce noise generation. Moreover, adequate greenbelt will be developed within premises and around the periphery to prevent the noise pollution. By taking measures as mentioned, it is anticipated that noise levels in the plant will be maintained below the permissible limit. 2.11 RAIN WATER HARVESTING The rain water from the building roofs will be directed through the drainage to the covered storm water drainage line. All drainage system will be concreted lined and located along the roads up to rain water harvesting pit. Roof top rain water will be collected in tanks and reused after filtration as per requirements. 2.12 GREEN BELT DEVELOPMENT Total land area is 17432 m2. The unit will develop greenbelt in area of 5763 m2. Overall greenbelt area will be 33% of the total area of the project. 2.13 OCCUPATIONAL HEALTH & SAFETY The company is concerned with the health, safety and environment protection. The company will formulate and develop an ‘Occupational Health & Safety Policy’ to ensure good health and safety of its employees. Following key safety measures shall be a part of the Health & Safety policy of the company & shall be followed after the project implementation:  Safety Training shall be provided to the employees.  Safety Sirens with alarm system shall be provided.  Fire Extinguishers shall be provided.  Mock drills shall be periodically conducted.  First Aid Facility and training shall be provided.  Personnel protective Equipment shall be provided to the employees.  Health check-ups shall be organized at regular intervals.  Safety/Health records and MSDS shall be maintained.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 2-51 San Envirotech Pvt. Ltd., Ahmedabad Chapter-3

Description of Environment 3.1 GENERAL To assess environmental impacts from proposed project at a specific location, it is essential to monitor the existing environmental quality prevailing in the surrounding area prior to implementation of the project. The environmental status within the impact zone could be used for identification of significant environmental issues to be addressed in the impact assessment study. Baseline data generation forms a part of the Environmental Impact Assessment (EIA) study and helps to evaluate the predicted impacts on the various environmental attributes in the study area by using scientifically developed and widely accepted impact assessment methodologies. This section contains the description of baseline studies of 10 km radius surrounding the project site. The baseline study was carried out to understand following environmental parameters.  Land Environment  Meteorology  Air Environment  Water Environment  Soil Environment  Noise Environment  Biological Environment  Socio-economic Environment The data collected has been used to understand the existing environment scenario around the project site against which the potential impacts of the proposed project can be assessed. 3.2 STUDY AREA The unit will be located at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. An area of 10 km radius from the boundary of the project site is considered as study area for the EIA study as per the ToR issued by MoEF&CC.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-1 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.1 Environmental setting of the study area

Location MPIDC Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara Coordinates of the site Latitude: 21°33'14.27"N Longitude: 78°48'15.86"E Altitude 378 – 380 m above MSL Topography Plain Survey of India Toposheet No. F44M10, F44M11, F44M14, F44M15 Seismic Zone Seismic Zone-III Nearest Human habitation Borgaon, about 0.9 km Town Sausar, about 9.5 km City Chhindwara, about 55.6 km Railway Station Lodhikheda Railway Station, about 5.6 km Highway National Highway NH-26B (Savner-Chhindwara), about 1.2 km Air Port Chhindwara, about 51.0 km Water body Borgaon, about 1.0 km National Park/Wildlife Sanctuary None, within 10 km radius Note: Aerial distances are mentioned in above table

3.3 STUDY PERIOD Baseline environmental quality represents the background scenario of various environmental components. As part of EIA study, baseline environmental monitoring was done over a radial distance of 10 km around the project site during the period of October, 2020 to December, 2020. 3.4 SOURCE OF ENVIRONMENTAL DATA GENERATION Baseline information on micrometeorology, ambient air quality, water quality, noise level, soil quality and ecology (flora-fauna) are generated by M/s. San Envirotech Pvt. Ltd., Ahmedabad. Apart from these, secondary data have been collected from census book, revenue records, soil survey and forest department, meteorological department etc. The generation of primary as well as collection of secondary data & information from the site and surrounding was carried out during the study period. 3.5 METHODOLOGY The process & methodology adopted for various environmental attributes in the study is as follows:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-2 San Envirotech Pvt. Ltd., Ahmedabad

 To assess the Air environment in the study area, monitoring of the Air quality was done by setting up reconnaissance. The samples were collected by installation of Respirable Dust Sampler (RDS) (with gaseous attachment & FPS facility) at different locations for monitoring of primary air pollutants to work out the existing status of air quality.  Ground water samples & surface water samples were analyzed for the parameters necessary to determine water quality (based on IS: 10500-2012 criteria) and those which are relevant from the point of view of environmental impacts of the project site.  Soil samples were collected using an Auger and analyzed for relevant physico-chemical characteristics in order to assess the impact on soil.  The noise level monitoring was done at various locations at different intervals of time with the help of sound level meter.  Socio-economic data was collected from field studies and secondary sources like Census of India 2011, Revenue record, etc. 3.6 LAND ENVIRONMENT Land Cover is the physical material at the surface of the earth (includes grass, trees, bare ground, water etc.); whereas Land use is the human use of land. Studies on land use aspects of eco-system play an important role in identifying susceptible issues and to take appropriate action to uphold ecological equilibrium in the region. Main objective is to provide a baseline status of the study area so that temporal changes due to the proposed activities on the surroundings can be assessed in future. 3.6.1 Land use pattern of the Study Area The study area of 10-km around the project site is considered in the land use pattern study. The term land-use indicates the way in which the land is utilized for different purposes. The land-use distribution of the study area is given in Table 3.2. Land-use map is given in Figure 3.1.

3.6.2 Objective of Land Use Studies The objectives of land use studies are (i) to develop land use & land cover map using land coordinates of the project area, (ii) to identify and mark important basic features according primary and secondary data, and (iii) to suggest measures for conservation and sustainable use of land.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-3 San Envirotech Pvt. Ltd., Ahmedabad Figure 3.1 Land use map

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-4 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.2 Land use statistics work out based on satellite imaginary

Level 1 Level 2 Area (Sq. km.) Area (%) Agricultural Agricultural land 165.83 52.78 Commercial/ 0.19 0.06 Public Utilities Plantation 0.06 0.02 Built-up land Commercial/ 0.5 0.16 Public Utilities Mining/Industrial 1.1 0.35 Rural 11.25 3.58 Transportation 2.48 0.79 Urban 7.38 2.35 Forest Forest 48.89 15.56 Waste land Scrub land 63.78 20.3 Water body Canal, Lake/Ponds, 12.73 4.05 Reservoirs, Streams Total 314.2 100

3.6.3 Topography The site area is plain with little undulating at few places. Agriculture and allied activities are most predominant in this area. Fallow land and barren lands were less observed near project site. There was no Eco Fragile Zone or Natural Forest near project site in study area. Toposheet of 10-km radius with site location is shown in Figure 3.12. 3.6.4 Seismicity of the area Seismicity of the Area Catastrophic earthquakes of magnitude greater than 8 (Richter scale) have occurred in the western, northern and eastern parts of India and adjacent countries in the past 100 years. By contrast, peninsular India is relatively seismically less active, having suffered only infrequent earthquakes of moderate strength. The main seismogenic belts are associated with the collision plate boundary between the Indian and Eurasian plates. Madhya Pradesh is vulnerable to various natural and manmade disasters. Looking towards the vulnerability it's very important to address all in a holistic manner for sustainable development. There are 28 districts that come under Zone-III, having moderate seismic risk viz. Jabalpur, Khargaone, Indore, Khandwa, Dhar, Raisen, Dewas, Sehore, Betul, Sidhi, Shadol, Damoh,Narsinghpur, Hoshangabad, Badwani,

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Jhabua, Umaria, Chhindwara Harda, Burhanpur, Anuppur, Sagar, Seoni, Mandla, Dindori, Katni, Singrauli and Alirajpur and rest 22 districts come under Zone-II of Earthquake. The Project site as well as study area lies in Zone-II of Seismic Zoning Map, and thus can be said to be located in an area of low seismic hazard by national standards. Hence the risk of earthquake at the site is minimal and so the site is safe. Floods As per the “Vulnerability Atlas- 2nd Edition; Peer Group, MoH & UPA; based on digitized data of SOI, GOI; Flood Atlas, Task Force Report, C.W.C., GOI” the project site does not fall Under “area liable to flood”.

3.7 METEOROLOGY Meteorology is the key to understand the air quality. Wind fluctuations over a very wide range of time, accomplish dispersion and strongly influence other processes associated with them. The micrometeorological conditions at the project site will be regulating the transport and diffusion of air pollutants released into the atmosphere. 3.7.1 Site specific micro-meteorological data The data on surface meteorological parameters in the study area were collected from October, 2020 to December, 2020, by setting up portable weather monitoring station placed at project site. The sensor of the equipment was kept at sufficient height (about 10 m) from ground level with free exposure to the atmosphere. The monitoring methodology is given in Table 3.3 & data collected are presented in Table 3.4. The following parameters were recorded at hourly intervals during monitoring period:

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• Wind speed & Wind direction • Temperature • Relative humidity • Rainfall Table 3.3: Monitoring Methodology of Meteorological Data

Sr. Sampling Sample Collection Total Sampling Methodology No. Parameters Sampling Sensitivity/ Sampling Frequency Equipment Detection Period Limit 1 Wind Speed Anemometer 0.25 m/s Hourly As per cup counter manufacturer‟s (0 to 65 m/s) manual, 2 Wind Wind vane 10 Instruments Direction (0° to 359°) December, are 3 Temperature Thermometer 0.10C 2020 to calibrated (-40° to 60°) February, 4 Humidity Hygrometer 3% 2020 5 Rainfall Rain gauge 0.5 mm 6 Cloud Cover -- -- 4 Hourly Visual Inspection by the observer

Table 3.4: Meteorological Data for the Monitoring Period (October, 2020 to December, 2020) Month Wind Pre Temp. Relative Rain fall speed dominant (0C) Humidity (mm) (km/hr.) wind (%) Max Min direction Max Min Max Min 24 hrs. No. of highest rainy days Oct,20 24.0 0.0 NNE 29 18 96 37 10.6 7 Nov,20 21.0 0.0 NNE 29 14 89 22 1.9 8 Dec,20 18.0 0.0 NE 30.0 12 87 17 2.4 5 3.7.2 Wind Rose Wind rose is the diagrammatic representation of wind speed in a specified direction with its arms representing sixteen directions, each arms give a clear frequency distribution of wind speed in a particular direction for a given period of time. It is one of the most important meteorological parameters and governs dispersion, diffusion & transportation of pollutants. % frequencies of wind in 16 directions have been computed from the recorded data during the study period for 24-hourly intervals to plot wind rose. The predominant wind directions – NNE, NE, ENE, E, ESE; implying that winds come from these directions for most of the time during the period. The wind speed class 1-5 kmph occurred for 13.18%, 6-10 kmph about 39.63%, 11-15 kmph 22.41% and above 15 kmph and

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below 40 kmph occurred for 5.44% of the study period. Calm wind during this period is 19.34%. Wind rose diagram is shown as Figure 3.8. 3.8 AMBIENT AIR QUALITY 3.8.1 Introduction To quantify impact of proposed project on ambient air quality, it is necessary to evaluate existing ambient air quality of area. Ambient air quality monitoring around the site was done for the baseline information. 3.8.2 Design Network for Ambient Air Quality Monitoring Stations The baseline status of the ambient air quality has been assessed through a scientifically designed ambient air quality monitoring network. The design of monitoring network is based on the following considerations: . Topography/Terrain of the study area . Populated areas within the region . Prediction of maximum concentrations and distances of their likely occurrence under prevailing meteorological conditions . Representation of regional background . Representatives of likely impact areas Ambient Air Quality Monitoring (AAQM) stations were placed at eight locations with due consideration to the above mentioned points. 3.8.3 Reconnaissance Reconnaissance was undertaken to establish the baseline status of air environment in the study region. The prime objective of the NAAQ survey, within 10 km radial study area around the proposed project, was to establish the existing ambient air quality levels. The monitoring locations (relative directions and distances) are given in Table 3.11 & shown in Figure 3.7 and results are given in Table 3.12 to 3.17. 3.8.4 Parameters, Frequency and monitoring Methodology

The existing ambient air quality, in terms of Particulate Matter-10 (PM10),

Particulate Matter-2.5 (PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen (NOx), Carbon Monoxide (CO), Hydrocarbons (HC), Hydrochloric Acid

(HCl), Hydro bromic acid (HBr), Ammonia (NH3) & Volatile Organic Compounds (VOCs) has been measured. It was ensured that, the equipment was placed at open space free from any obstacles at a height of at least 3 to 4 m above the ground level at each monitoring station to

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avoid the effects of wind-blown ground dust. Monitoring has been carried out as per the latest CPCB and MoEF&CC guidelines and notifications. Details of methodology are given in Table 3.5. Table 3.5 Methodology of Ambient Air Monitoring

Sampling Instrument used Analytical Detection Test method Parameters equipment Limit 3 PM10 RDS (Respirable Dust Electronic 1 μg/m Gravimetric IS: 5182 Sampler) Balance (Part 23) 2006 3 PM2.5 FPM (Fine Particulate Electronic 1 μg/m Gravimetric CPCB Sampler) APM 550 Balance Guidelines for Ambient Air Monitoring 3 SO2 Gaseous flow Spectro 2.5 μg/m Colorimetric IS: 5182: attachment with RDS Photometer (Part II) 2001 sampler 3 NOx Gaseous flow Spectro 6.0 μg/m Colorimetric IS: 5182: attachment with RDS Photometer (Part VI) 2006 sampler HCl Gaseous flow Titrimetric 1 μg/m3 Titrimetric attachment with RDS sampler HBr Gaseous flow Spectro 1 μg/m3 Colorimetric attachment with RDS Photometer sampler 3 NH3 Gaseous flow Spectro 10 μg/m CPCB Guidelines for attachment with RDS Photometer Ambient Air Monitoring sampler CO Bladder & Pump Gas 1 ppm Gas Chromatograph Chromatography HC Bladder & Pump Gas 1 ppm Gas Chromatograph Chromatography VOC Bladder & Pump Gas 1 ppm Gas Chromatograph Chromatography

The duration of sampling of PM2.5, PM10, SO2 & NOx was 24-hourly

continuous sampling per day and CO, HC, VOCs, HCl, HBr, NH3 were sampled for 8-hours duration. The monitoring was done for twice a week for three months. Parameters and frequency of sampling is given in Table 3.6.

Table 3.6 Monitored Parameters and Frequency of Sampling

Parameters Sampling frequency

Fine Particulate Matter (PM2.5) 24 hourly sample twice a week for three months

Respirable Particulate Matter (PM10) 24 hourly sample twice a week for three months

Sulphur dioxide (SO2) 24 hourly sample twice a week for three months Oxides of Nitrogen (NOx) 24 hourly sample twice a week for three months Hydrochloric Acid (HCl) 8 hourly sampling Hydro bromic acid (HBr) 8 hourly sampling

Ammonia (NH3) 8 hourly sampling

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Carbon Monoxide (CO) 8 hourly sampling Hydro Carbon (HC) 8 hourly sampling Volatile Organic Compounds (VOCs) 8 hourly sampling 3.8.5 Interpretation of result

The existing baseline levels with respect to PM10, PM2.5, SO2, NOX, HCl,

HBr, NH3, CO, HC, VOCs are tabulated in Tables 3.12 to 3.16 & chart is given as Figure 3.2 to 3.6.

Particulate Matter (PM10) th An average and 98 percentile value of 24-hourly PM10 values at all the locations are found from 61.3-71.3 g/m3 and 67.2 – 82.9 g/m3. The results were found well within the National Ambient Air Quality Standards (NAAQS-CPCB) of 100 g/m3.

Particulate Matter (PM2.5) th An average and 98 percentile value of 24-hourly PM2.5 values at all the locations ranges from 35.6-40.5 g/m3 and 39.7-46.1 g/m3. The values are well within National Ambient Air Quality Standards (NAAQS-CPCB) of 60 g/m3.

Sulphur Dioxide (SO2) th An average and 98 percentile value of 24-hourly SO2 value of arithmetic mean at all the locations ranged from 10.7 – 14.5 g/m3 and 13.2-21.1 g/m3 respectively, which are well below National Ambient Air Quality Standards (NAAQS-CPCB) of 80 g/m3.

Oxides of Nitrogen (NOx) An average and 98th percentile value of 24 hourly NOx value of arithmetic mean at all the locations ranged from 15.0-20.9 g/m3 and 18.3- 28.1g/m3 respectively, which are well below the National Ambient Air Quality Standards (NAAQS-CPCB) of 80 g/m3. Carbon Monoxide (CO) Minimum & Maximum value of CO at all the locations ranged from 1094 - 1410 g/m3. Hydro Carbon (HC) Minimum & Maximum value of HC at all the locations ranged from 1104 – 1267 g/m3.

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Volatile Organic Compounds (VOCs) Minimum & Maximum value of VOC at all the locations ranged from 0.46 g/m3 – 0.91 g/m3. Hydrochloric Acid (HCl) HCl value at all the locations found BDL. Hydrobromic acid (HBr) HBr value at all the locations found BDL.

Ammonia (NH3)

NH3 value at all the locations found BDL. Conclusion: The quality of ambient air in the study area is compared with AAQM Standards prescribed by CPCB & found below the prescribed standards. 3.9 WATER ENVIRONMENT 3.9.1 Hydro-Geology of the Study Area Hydrology: The major part of the district is occupied by Deccan Trap, consisting of different lava flows whose thickness ranges between 7 to 21 m. The recent alluvium deposits are found at places along the Pench and the Kanhan rivers with thickness varying from 5.00 to 20.00 m. Alluvium comprises clayey material with intercalated layers of sand and gravels. Archaeans are exposed in parts of Sausar, Bichhua, Chhindwara, Jamai and Mohkhed blocks whereas the Coal bearing lower Gondwanas in parts of Jamai, Parasia and Jamai blocks. The upper Gondwanas occupy parts of Harrai and Tamia blocks. Ground water occurs under phreatic and semi-confined to confined conditions. Alluvium, weathered granites/ gneisses, lower Gondwana sandstones, weathered, fractured and jointed massive basalts and vesicular basalts form the major phreatic aquifers; and weathered fractured granites are noticed as main water-bearing zones at deeper levels. It is observed that the discharge of dug wells tapping alluvium and vesicular basalt ranges between 80 and 235 m3/day respectively and jointed massive basalts and weathered gneisses range from 44 to 177 m3/day and from 61 to 77 m3/day respectively. Hydrogeological details of some of CGWB exploratory bore wells are given in Table 2. Water bearing fractured zones is encountered between depths

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of 71.00 and 176.00 m bgl at deeper levels. The discharge in weathered, fractured granite at deeper levels ranges from 0.2 to 10.00 l/s. The impact has been assessed on randomly selected surface and ground water sources falling within the impact zone. In order to assess the existing water quality, the Ground water samples were collected from 8 different locations and Surface Water quality from 3 locations within the study area and analysed it as per the procedure specified in standard methods for examination of water and wastewater published by American Public Health Association and Bureau of Indian Standards (APHA/BIS). Monitored values have been used for describing the water environment and assessing the impacts on it. To assess the water quality impacts, water resources in the impact area have been grouped into 2 classes. Ground water resources in the deeper strata of the ground. Surface water resources Regional Geology: The manganese occurs a manganese-oxide-quartzite formations and impure manganese silicate rocks, derived from the metamorphism of banded pure and impure manganese formations. The ore bodies are generally braunite quartzite rocks consisting of alternating layers of manganese oxide, braunite and dark manganiferous quartzite. 3.10 WATER QUALITY 3.10.1 Introduction Water quality assessment is one of the essential components of EIA study. Such assessment helps in evaluating the existing health of water body and suggesting appropriate mitigation measures to minimize the potential impact from development projects. The water quality at the site and other locations within the 10-km impact zone was monitored during study period. The purpose of the study is to:  Assess the water quality characteristics for critical parameters;  Evaluate the impact on agricultural productivity, habitat conditions recreational resources and aesthetics in the vicinity; and  Predict the likely impacts on water quality due to the project and related activities.

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Reconnaissance survey was undertaken and monitoring locations were finalized based on:  Location of residential areas representing different activities/likely impact areas; and  Likely areas, which can represent baseline conditions. 3.10.2 Sampling Frequency, Techniques & Methodology Six surface water and eight groundwater samples were collected during the study period. Ground water samples were collected from the existing bore wells, while surface water was collected from ponds by surface water sampler. These samples were taken as grab samples. Necessary precautions were taken for preservation of samples. Sampling locations with source & date of sampling is given in Table 3.7. The samples collection procedure was adopted from „Standard Methods‟ for the examination of Water and Wastewater published by American Public Health Association (APHA) and IS 10500-2012. The samples were analyzed for Physico-chemical parameters to assess the existing water quality of the area (based on IS: 10500-2012 & APHA/AWWA, 23rd edition). The water sampling locations marked within the study area and the result of the analysis (ground water and surface water) is presented in the Figure 3.9 & Table 3.19 & 3.20 respectively. Table 3.7 Sampling locations with source & date of sampling Ground Water Sampling Locations Sample Location Date of Tehsil District Code Sampling GW1 Nr. Project Site 25/11/2020 Sausar Chhindwara GW2 Lodhikheda 25/11/2020 Sausar Chhindwara GW3 Borgaon 25/11/2020 Sausar Chhindwara GW4 MPIDC 25/11/2020 Sausar Chhindwara GW5 Jamlapani 26/11/2020 Sausar Chhindwara GW6 Tinkheda 26/11/2020 Sausar Chhindwara GW7 Khaparkheda 26/11/2020 Sausar Chhindwara GW8 Khairitaygaon 26/11/2020 Sausar Chhindwara

Surface Water Sampling Locations Sample Location Date of Tehsil District Code Sampling SW1 Pond Nr. Borgaon 25/11/2020 Sausar Chhindwara SW2 Pond Nr. Jamalpani 25/11/2020 Sausar Chhindwara

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SW3 Pond Nr. Khairitaygaon 25/11/2020 Sausar Chhindwara SW4 Pond Nr. Raibasa 25/11/2020 Sausar Chhindwara SW5 Kanhan River 26/11/2020 Sausar Chhindwara SW6 Jam River 26/11/2020 Sausar Chhindwara 3.10.3 Surface Water Quality (Primary data) Surface water samples were collected from Pond Nr. Borgaon, Pond Nr. Jamalpani, Pond Nr. Khairitaygaon, Pond Nr. Raibasa and Kanhan River Jam River. Analysis of the same is given in Table 3.20. The results have been compared with the drinking water quality standards specified in IS: 10500-2012. It was observed that all the physico-chemical parameters and heavy metals except turbidity from surface water samples are below stipulated drinking water standards & it is suitable for drinking and other purposes. 3.10.4 Ground Water Quality The results of the ground water quality monitored during the study period are given in Table 3.19. 3.10.5 Interpretation The samples were taken as grab samples and analyzed for various parameters of ground water. Sampling location is shown in Figure 3.9. The results are shown in Table 3.19. Color: All the samples were found color less meeting desirable norms. pH: All the samples meet the desirable standards (pH ranges from 7.27- 7.78). Total Dissolved Solids (TDS): TDS in samples ranges from 471 mg/L (Khaparkheda) to 645 mg/L (Borgaon), all the samples meet the permissible limit of 2000 mg/L, (If alternate sources of potable water are not available). Calcium: Calcium contents in the water ranges from 39 mg/L (Tinkheda) to 52 mg/L (Borgaon), all the samples meet the permissible limit of 200 mg/L, (If alternate sources of potable water is not available). Magnesium: Magnesium content in the water ranges from 14 mg/L (Khaparkheda) to 20 mg/L (Borgaon). All the samples meet the permissible limit of 100 mg/L (if alternate source of potable water in not available).

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Sulfate: Sulfate content in the water ranges from 30 mg/L (Khaparkheda) to 55 mg/L (MPIDC). All the samples meet the permissible limit of 400 mg/L for drinking water (if alternate source of potable water in not available). Fluoride: Fluoride content in the water ranges from 0.45 mg/L (Jamlapani) to 0.74 mg/L (Khairitaygaon). All the samples meet the permissible limit (1.5 mg/L). Total Alkalinity: Total alkalinity in the water samples ranges from 227 mg/L (Jamlapani) to 257 mg/L (Khairitaygaon). All the samples are within the permissible limit of drinking water (600 mg/L) (if alternate source of portable water is not available). Other Parameters: Potassium (ranges from 16 mg/L to 28 mg/L), Sodium (ranges from 93 mg/L to 134 mg/L) and Chloride (ranges from 82 mg/L to 156 mg/L). Heavy metals like copper, lead, chromium and zinc are well below the limit in all samples. 3.10.6 Conclusion The results have been compared with the drinking water quality standards specified in IS: 10500-2012 & meet the permissible limit set by the authority (BIS). Indian Standard specification for drinking water is given in Table 3.21. Selected ground water samples analyzed can be considered fit for drinking purpose. 3.11 NOISE ENVIRONMENT Noise can be defined as an unwanted sound. The definition of noise as unwanted sound implies that it has an adverse effect on human beings and their environment. The noise level variation can be temporal, spatial. It interferes with speech and hearing and is intense enough to damage hearing or is otherwise annoying. Noise can also disturb natural wildlife and ecological system. It is therefore, necessary to measure both the quality as well as the quantity of noise in and around the proposed site. 3.11.1 Instrument used for Sampling and Monitoring The intensity of sound energy in the environment is measured in a logarithmic scale and is expressed in a decibel, dB(A) scale. Sound Level Meter (SLM) is used for the collection of data related to noise at an

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interval of one hour. The day noise levels have been monitored during 6:00 am to 10:00 pm and night noise levels during 10:00 pm to 6:00 am at all the nine locations. Noise levels recorded at each station are computed for equivalent noise levels. Noise monitoring methodology is given in below Table 3.8. Table 3.8 Monitoring Methodology of Noise

Environment Sampling Test method Instrument Make Component Location used Ambient 09 As per manufacturers Sound Level Mextech- Noise level Locations Manual Meter SL-4012

3.11.2 Noise Quality Monitoring Locations The noise survey was conducted to assess the background noise levels in different zones. Noise level measurements have been made at 9 locations within the study area using Sound Level Meter. Based on the Gazettes Notification (S.O. 123(E)) of MoEF dated February 14, 2000 on ambient air quality standards, 9 monitoring locations were selected. The noise monitoring locations & its results are given in Figure 3.10 & Table 3.22 respectively. 3.11.3 Ambient Noise Standards Ministry of Environment & Forests (MoEF) has notified noise standards vide Gazette Notification dated February 14, 2000 for different zones viz. industrial, commercial, residential and silence zones under Environment Protection Act (1986). These standards are given in Table 3.23. 3.11.4 Results The noise levels of various locations are given in Table 3.22. The monitored noise level in the day time Leq (Ld) varies from 50.1 to 53.4 dB(A) and the night time Leq (Ln) varies from 38.5 to 42.9 dB(A) within the study area. Higher noise value of 53.4 dB(A) was recorded during day time Project Site & lower noise value of 38.5 dB(A) was recorded during night time in Village Jamlapani. 3.11.5 Conclusion Based on the observations made during the studies, it is concluded that; the noise levels recorded at various locations in the study area show considerable fluctuations because of changes in traffic movement, commercial and other domestic activities in the study area. Overall the

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ambient noise level in the monitored locations was found to be within the permissible limits stipulated for residential, industrial areas, silence and commercial zone. 3.12 SOIL ENVIRONMENT Soils may be defined as a thin layer of earth‟s crust that serves as a natural medium for the growth of plants. It is the unconsolidated mineral matter that has been subjected to and influenced by genetic and environmental factors. Soils serve as a reservoir of nutrients for plants and crops and also provide mechanical anchorage and favorable tilth. The objective of the soil sampling is:  To determine the baseline soil characteristics;  To monitor impact on soil (pollutant deposition/other) in long run 3.12.1 Soil sampling locations Soil quality of the study area is one of the important components for environment impact assessment. The composite soil samples were collected from the study area from eight locations (Project Site, Lodhikheda, Borgaon, MPIDC, Jamlapani, Tinkheda, Khaparkheda and Khairitaygaon and were analyzed for different parameters. The location of the monitoring is given below in Table 3.9. Results are given in Table 3.24 and depicted in Figure 3.11. Table 3.9 Location of soil sampling

Sample Locations Date of Tehsil District Code sampling S1 Project Site 25/11/2020 Sausar Chhindwara S2 Lodhikheda 25/11/2020 Sausar Chhindwara S3 Borgaon 25/11/2020 Sausar Chhindwara S4 MPIDC 25/11/2020 Sausar Chhindwara S5 Jamlapani 26/11/2020 Sausar Chhindwara S6 Tinkheda 26/11/2020 Sausar Chhindwara S7 Khaparkheda 26/11/2020 Sausar Chhindwara S8 Khairitaygaon 26/11/2020 Sausar Chhindwara 3.12.2 Methodology To understand the soil quality of the study area, analysis of all eight locations including the project site was conducted by making suspension of soil sample. The samples were examined for various physical and chemical characteristics in order to assess the impact on soil. Analysis was done by using following methodology.

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Table 3.10 Methodology of Soil Sample analysis

Sampling Sample Analytical Methodology Remarks Parameters collection Equipment Porosity - IS: 2720 Part 7 Trial pit Water holding - - method capacity for topsoil Permeability - IS: 2720 Part 17 sample Moisture Electronic IS: 2720 Part 2 collection; content Balance disturbed Texture - IS: 2720 Part 4 samples Particle size Glass wares IS: 2720 Part 4 Distribution Cation Centrifuge IS: 2720 Part 24 5% Leachate Manual Exchange (1976) to sample Capacity be made and Collection in SAR F. Photometer Calculation analyzed as polyethylene (Na, K) per bags using Titration APHA, an Auger (Ca & Mg) “Standard pH pH Meter 4500 H+B Methods” All method Electrical Conductivity As per IS 14767 numbers are Conductivity Meter -2000 as Calcium Glass wares 3500 Ca B per APHA Magnesium Glass wares 3500 Mg B “Standard Sodium (Na) Flame 3500 Na B Methods” Photometer (23rd edition) Potassium Flame 3500 K B Photometer

3.12.3 Corollaries Physical Parameters . Particle Size: A Particle size of the different constituents (clay, silt, sand and gravel) controls the porosity and water holding characteristic of the soil. Clay (size<0.002 mm) amount in the soil samples ranges from 23% to 31%; Silt (size 0.002 to 0.075 mm) in the soil samples is 11% to 23% and Sand (size 0.075 to 0.475 mm) in the soil samples is 34% to 47%, while Gravel (size>4.75 mm) in the soil samples is 11% to 23%. Analysis shows that the soil has moderate water holding capacity. . Porosity: Porosity is a measure of space in between soil particles caused by structural conditions and determined under identical conditions. Porosity of soil samples of the study area ranges from 39.6% to 45.7%. . Water Holding Capacity (WHC): Water Holding Capacity (WHC) of soil samples of the study area ranges between 36% to 42%. . Bulk Density: Bulk Density of soils in the study area is found to be in the range from 1.34 to 1.49 g/cm3.

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Chemical Parameters . pH: pH of soils in the study area is found to be in the range of 7.39 to 7.82. . Chloride: Chloride content in soils of the study area is found to be in the range of 251 to 462 mg/kg.

. Soluble Calcium: The soluble calcium as CaCO3 in soil samples is found to be in the range of 172 to 260 mg/kg. . Magnesium: Magnesium content in soil samples of the study area ranges from 108 to 242 mg/kg. . Total Phosphorus: Available Phosphorus content in soil samples of the study area ranges from 69 to 116 mg/kg. . Total Nitrogen: Available nitrogen content in soil samples of the study area is found to be in the range from 210 to 235 mg/kg. . Potassium: Potassium content in soil samples of the study area is found to be in the range from 142 to 276 mg/kg. . Sodium: Sodium content in soil samples of the study area is found to be in the range from 285 to 402 mg/kg. . Total Organic Matter (TOM): Total organic matter content in soil samples of the study area is found to be in the range of 1.8 to 2.3 mg/kg. 3.12.4 Conclusion In the study area, variations in the pH value ranging from 7.39 to 7.82 which shows that the soil is slightly alkaline in nature. Organic Matter ranges from 1.8 to 2.3 mg/kg in the soil samples. Soil of the study area is known to be good for cultivation. Generally, soils with low bulk density have favorable physical conditions (porosity and permeability) whereas those with high bulk density exhibit poor physical conditions for agriculture crops. 3.13 BIOLOGICAL ENVIRONMENT An ecological study of the ecosystem is essential to understand the impact of industrialization and urbanization on existing flora and fauna of the study area. The biological study was undertaken as a part of the EIA study report to:  Understand the present status of ecosystem prevailing in the study area.

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 Compare it with past condition with the help of available data.  Predict changes in the biological environment as a result of present activities and to suggest measures for maintaining its health. The survey was conducted to study the flora & fauna in 10 km radius. Some of the information was gathered from the local habitants. All the collected data were classified to interpret the impact of pollution on the flora and fauna of the region. 3.13.1 Period of the study The baseline study, for the assessment of the floral and faunal biodiversity of the terrestrial environment, within 10 km radius from the site was conducted during October, 2020 to December, 2020. 3.13.2 Study methodology Survey methodology was based on the flora and fauna species identification in person, recently recorded and found in the region by the localities. Sampling of grass species was carried out by quadrat sampling method to examine species distribution and its frequency in the region. Quadrate Sampling Method: A quadrat (or plot-based) survey is a quantitative examination of species distribution & abundance. Quadrats are more likely to detect inconspicuous species because a smaller area is sampled in a concentrated search. The survey was carried out for the vegetation ground cover found in the road edges by 1 m2 quadrat and study on the edge effect due to rapid industrialization and urbanization. 3.13.3 Floral species in the study area Flora is basically the plant life that is present in a particular region or habitat at a particular time. List of flora found in the study area is tabulated in Table 3.25. 3.13.4 Fauna in the study area Fauna is the animal life that is present in a particular region or habitat at a particular time. Irrespective of its unfriendly terrain, MP gives shelter to a variety of animals and birds. They live in smaller herds and thrive mainly on wild grasses and various types of shrubs. Faunal biodiversity with their scientific names and common names is presented in Table 3.26.

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No threatened, Rare, Endangered or Endemic species were observed during the survey in core zone. There are 3 Schedule I Species found (not sighted during study period but included based on conversations with locals) in buffer zone namely Peafowl (Pavo cristatus), Indian Bison (Bos gaurus), Bengal monitor (Varanus bengalensis) as per Wildlife (Protection) Act, 1972 (amended in 2002). Conservation plan along with budgetary provisions for conservation of Schedule I species have been prepared and submitted to DFO, Chhindwara for approval. Acknowledgement copy along with conservation plan is attached as Annexure-V. 3.14 SOCIO-ECONOMIC ENVIRONMENT An essential part of environmental study is socio-economic environment incorporating various facts related to socio-economic conditions in the area, which deals with the total environment. Socio economic study includes demographic structure of the area, provision of basic amenities viz., housing, education, health and medical services, occupation, water supply, sanitation, communication, transportation as well as feature of aesthetic significance such as temples, historical monuments etc. at the baseline level. This would help in visualizing and predicting the possible impact depending upon the nature and magnitude of the project. Socio- economic study of an area provides a good opportunity to assess the socioeconomic conditions of an area. This study will possibly make a change in living and social standards of the particular area benefitted due to the project. The gross economic production of area will be increased substantially due to the existence of this project. It can undoubtedly be said that this plant will provide direct and indirect employment and improve the infrastructural facilities and standards of living of the area. 3.14.1 Objective of the study The objectives of this socio-economic report consist of:  To conduct socio-economic assessment study in lease Area  To help in providing better living standards.  To know the current socio-economic situation in the region to cover the sub sectors of education, health, sanitation, water and food security.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-21 San Envirotech Pvt. Ltd., Ahmedabad

 To provide employment opportunities. 3.14.2 Land use pattern and infrastructure The land use pattern indicates the manner in which different parts of land in an area is being utilized or non-utilized. It is an important indicator of environmental health; human activity and a degree of inter play between these two. Even though the soil quality, water availability and climate have strong influence on agriculture and vegetation, the human activity may alter the natural environment to a large extent to suit human needs. Unnatural land use often triggers rapid environmental deterioration and disturbs ecological balance. In census records, major land use classifications are; Forests, Culturable land, Culturable wasteland and area not available for cultivation. Culturable land is further classified as: irrigated and un-irrigated. Area not available for cultivation includes lands put to non-agriculture uses as well as barren and uncultivable lands. The main land use in area is for dwellings, infrastructure and related activities. However, the land use pattern for rural areas is discussed below. The information is preliminary based on 2011 Census as depicting in Table 3.25. Total land area is 31730.09, out of that Irrigated area is 4031.3 ha and it constitutes 12.70%. 16253.5 ha are un-irrigated by source and it constitutes 51.22% of total land area. The study area consist of Cultivable wasteland is 1158.9 ha (3.65%). Area not available for cultivation is 1653.5 ha & it constitute 5.21%. 3.14.3 Demographic and Socio-Economic Environment The demographic and Socio-economic details of the study area are discussed below. These are primarily based on census data of 2011. Data on number of households, population as well as literacy and employment pattern in the study area have been presented in Table 3.29. The employment pattern in the area is indicator of number of persons employed in various sectors. It also indicates the various categories of employment flourishing in the area. The total no. of household in the villages are 16882 and the total population is 70247 (51.71% men & 48.29% women). 73.11% of are literate while literacy rate among women & men is 78.12% & 67.74% respectively. 45.60% of male population is part of main worker, while

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-22 San Envirotech Pvt. Ltd., Ahmedabad

only 23.64% of female population is a part of main workers. 6.06% of male workers are marginal workers, while 9.93% of female workers are engaged in such type of activities. 42.36% of male population and 63.41% of female population are non-workers. 3.14.4 Living Standard and Infrastructure In India it is not possible to setup a primary standard of living because of wide variations in terms of income, economic conditions, social custom, employment opportunity, pattern of spending, etc. However, availability of amenities like education, medical, water supply, communication, road network, electricity, etc. significantly reflects the level of development of the area. Information on available amenities in the study area has been extracted from census record of 2011. Total numbers of village in study area are 63. On the basis of data presented in the Table 3.30, the status of available amenities is discussed in following sub-sections: Educational Facilities As per 2011 census, there are primary schools in all 63 villages, 56 Pre- primary schools, 18 Secondary schools, 12 Senior Secondary schools. Medical Facilities 63 villages in the study area have 4 primary health centers, 14 primary health sub centers, 2 Maternity & Child Welfare Centre and 2 Veterinary Hospital in study area of 10 km. Drinking Water Supply All the 63 villages in the study area have two or more sources of drinking water. Most of the villages in study area have Well water supply in addition to Hand pump. Moreover, some villages have Tap water or other some facilities for water. Communication and Transport The main mode of public transport available in the study area is by bus service. Most of villages have approach to railway station as western railway meter gauge line is passing through nearby. In addition to land transport all the villages have water bound macadam roads. All villages in the study area are connected with Pucca road, Kaccha road and footpath.

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Post and Telegraph As per 2011 census record out of 63 villages in study area, all the villages have phone facility at doorstep & sub post office facility. Almost Villages have facility of Public Call Office and Post Office service at door step. Power Supply As per 2011 census record all the villages are getting power supply for all purposes.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-24 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.11: Ambient Air Quality Monitoring Locations (Monitoring Period: October, 2020 to December, 2020)

Sr. Sampling Direction Distance Coordinates Type of No. Location w.r.t. center (km) Area of Industry 1 Project Site (A1) -- 00 21°33'14.78"N Industrial 78°48'17.93"E 2 Lodhikheda (A2) NE(UW) 6.07 21°34'52.26"N Residential 78°51'24.34"E 3 Borgaon (A3) NE(UW) 1.05 21°33'42.96"N Residential 78°48'42.67"E 4 MPIDC (A4) E(UW) 1.12 21°33'15.21"N Residential 78°48'58.40"E 5 Jamlapani (A5) WSW(DW) 0.95 21°33'2.00"N Residential 78°47'42.53"E 6 Tinkheda (A6) SSW(DW) 1.80 21°32'15.16"N Residential 78°48'8.20"E 7 Khaparkheda (A7) SW(DW) 7.2 21°29'39.72"N Residential 78°46'29.87"E 8 Khairitaygaon (A8) SE(DW) 3.6 21°32'4.31"N Residential 78°49'58.01"E

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-25 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.12: Ambient Air Quality Status (Monitoring Period: October, 2020 to December, 2020)

Sr. Sampling Station PM10 PM2.5 SO2 NOx No. (g/m3) (g/m3) (g/m3) (g/m3) Average (Min-Max) 1 Project Site (A1) 71.3 39.8 14.5 20.9 (61.6-81.4) (33.7-46.5) (10.4-21.2) (15.8-29.1) 2 Lodhikheda (A2) 68.5 40.5 12.2 17.2 (61.9-78.8) (36.9-47.3) (9.6-16.7) (13.1-21.4) 3 Borgaon (A3) 66.8 37.6 12.9 15.8 (55.4-75.6) (30.5-42.8) (9.9-18.5) (12.5-21.2) 4 MPIDC (A4) 64.3 37.1 11.2 15.1 (59.6-69.1) (31.2-44.7) (8.3-13.3) (11.6-19.3) 5 Jamlapani (A5) 63.4 35.6 10.7 15.6 (58.6-67.9) (31.6-40.5) (8.2-14.0) (12.4-19.3) 6 Tinkheda (A6) 61.3 36.9 11.0 15.4 (52.6-67.8) (32.0-43.2) (7.7-14.5) (12.0-19.5) 7 Khaparkheda (A7) 64.4 38.1 10.7 15.0 (57.5-69.3) (33.3-46.0) (8.3-15.2) (11.6-18.8) 8 Khairitaygaon (A8) 62.6 37.9 11.6 16.1 (52.7-72.8) (31.2-43.9) (8.4-15.5) (12.2-20.1)

Figure 3.2 Graphical representation of Ambient Air quality

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Table 3.13: Ambient Air Quality Status (PM10) (Monitoring Period: October, 2020 to December, 2020) Average - 24 Hours Unit - g/m3

Station Name Max Min 98th 75th 50th 25th Avg. SD Percentile Percentile Percentile Percentile Project Site (A1) 84.1 61.6 82.9 73.9 70.9 68.5 71.3 5.2 Lodhikheda (A2) 78.8 61.9 77.4 70.1 68.2 66.5 68.5 4.0 Borgaon (A3) 75.6 55.4 75.1 71.5 67.7 62.8 66.8 5.9 MPIDC(A4) 69.1 59.6 69.0 67.5 64.8 61.6 64.3 3.3 Jamlapani (A5) 67.9 58.6 67.9 65.7 63.7 60.6 63.4 2.9 Tinkheda (A6) 67.8 52.6 67.2 64.0 62.2 58.6 61.3 3.8 Khaparkheda (A7) 69.3 57.5 69.0 67.2 64.4 62.3 64.4 3.1 Khairitaygaon (A8) 72.8 52.7 71.4 66.6 63.0 59.5 62.6 5.3

Figure 3.3 Graphical representations for PM10

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Table 3.14: Ambient Air Quality Status (PM2.5)

(Monitoring Period: October, 2020 to December, 2020) Average - 24 Hours Unit - g/m3

Station Name Max Min 98th 75th 50th 25th Avg. SD Percentile Percentile Percentile Percentile Project Site (A1) 46.5 33.7 45.4 41.7 39.8 38.4 39.8 3.0 Lodhikheda (A2) 47.3 36.9 46.1 42.3 39.9 38.4 40.5 2.8 Borgaon (A3) 42.8 30.5 42.1 39.7 37.9 35.9 37.6 2.9 MPIDC(A4) 44.7 31.2 43.3 38.5 36.6 35.5 37.1 2.9 Jamlapani (A5) 40.5 31.6 39.7 37.0 35.5 34.5 35.6 2.2 Tinkheda (A6) 43.2 32.0 42.3 39.0 37.0 34.4 36.9 2.9 Khaparkheda (A7) 46.0 33.3 45.7 40.0 37.3 35.8 38.1 3.4 Khairitaygaon(A8) 43.9 31.2 43.6 39.7 38.1 35.8 37.9 3.3

Figure 3.4 Graphical representations for PM2.5

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Table 3.15: Ambient Air Quality Status (SO2) (Monitoring Period: October, 2020 to December, 2020) Average-24 Hours Unit-g/m3

Station Name Max Min 98th 75th 50th 25th Avg. SD Percentile Percentile Percentile Percentile Project Site (A1) 21.2 10.4 21.1 16.0 13.9 12.4 14.5 3.0 Lodhikheda (A2) 16.7 9.6 16.0 13.2 12.1 11.1 12.2 1.7 Borgaon (A3) 18.5 9.9 17.9 14.0 13.0 11.3 12.9 2.1 MPIDC(A4) 13.3 8.3 13.2 12.1 11.1 10.7 11.2 1.2 Jamlapani (A5) 14.0 8.2 13.7 11.8 10.8 9.7 10.7 1.5 Tinkheda (A6) 14.5 7.7 14.3 12.4 10.9 9.4 11.0 1.9 Khaparkheda (A7) 15.2 8.3 14.6 11.7 10.4 9.4 10.7 1.8 Khairitaygaon(A8) 15.5 8.4 15.0 12.8 11.9 10.1 11.6 2.0

Figure 3.5 Graphical representations for SO2

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Table 3.16: Ambient Air Quality Status (NOx) (Monitoring Period: October-2020 to December-2020) Average-24 Hours Unit-g/m3

Station Name Max Min 98th 75th 50th 25th Avg. SD Percentile Percentile Percentile Percentile Project Site (A1) 29.1 15.8 28.1 23.1 20.2 18.8 20.9 3.5 Lodhikheda (A2) 21.4 13.1 21.4 18.4 17.0 15.7 17.2 2.0 Borgaon (A3) 21.2 12.5 19.9 17.2 16.3 13.8 15.8 2.1 MPIDC (A4) 19.3 11.6 18.8 16.3 15.2 13.8 15.1 2.0 Jamlapani (A5) 19.3 12.4 18.8 16.6 15.9 14.8 15.6 1.8 Tinkheda (A6) 19.5 12.0 19.3 17.2 15.6 13.5 15.4 2.3 Khaparkheda (A7) 18.8 11.6 18.3 16.2 14.9 13.7 15.0 1.8 Khairitaygaon (A8) 20.1 12.2 20.1 17.6 16.4 14.0 16.1 2.3

Figure 3.6 Graphical representations for NOX

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Table 3.17: Ambient Air Quality Status

(CO, HC (Methane & non Methane), VOC, HCl, HBr & NH3) (Monitoring Period: October, 2020 to December, 2020)

Station Name CO Hydro Carbon VOC HCl HBr NH3 3 (g/m3) (g/m ) (BTX) (g/m3) (g/m3) (g/m3) 3 Methane Non- (g/m ) Methane Project Site (A1) 1410 1123 32 0.91 BDL BDL BDL Lodhikheda (A2) 1395 1210 28 0.23 BDL BDL BDL Borgaon (A3) 1216 1235 16 BDL BDL BDL BDL MPIDC (A4) 1308 1196 23 0.3 BDL BDL BDL

Jamlapani (A5) 1094 1090 20 BDL BDL BDL BDL Tinkheda (A6) 1123 1146 14 BDL BDL BDL BDL Khaparkheda (A7) 1145 1105 19 0.18 BDL BDL BDL Khairitaygaon (A8) 1205 1234 26 BDL BDL BDL BDL

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Table 3.18: National Ambient Air Quality Standards (EP, 7th amendment rules-2009) Pollutants Time- Concentration in ambient air weighted Industrial, Ecologically Method of average Residential, Sensitive area Measurement Rural and (Notified by others area Central Government) Sulphur Dioxide Annual 50 20 . Improved west and 3 (SO2), µg/m Average* Gaeke 24 hours** 80 80 . Ultraviolet fluorescence Oxides of Annual 40 30 . Modified Jacob & Nitrogen as Average* Hochheiser 3 (NO2), µg/m 24 hours** 80 80 (Na-Arsenate) . Chemiluminescence Particulate Matter Annual 60 60 . Gravimetric (Size less than 10 Average* . TOEM 3 µm or PM10, µg/m 24 hours** 100 100 . Beta attenuation Particulate Matter Annual 40 40 . Gravimetric (Size less than 2.5 Average* . TOEM 3 µm or PM2.5, µg/m 24 hours** 60 60 . Beta attenuation

Ozone (O3) 8 hours ** 100 100 . UV photometric 3 µg/m 1hours** 180 180 . Chemiluminescence . Chemical Method Lead (Pb) Annual 0.50 0.50 . AAS/ICP method after µg/m3 Average* sampling on EPM 24 hours** 1.0 1.0 2000 or equivalent filter paper . ED-XRF using Teflon filter Carbon Monoxide 8 hours** 02 02 . Non Dispersive Infra 3 (CO) mg/m 1 hour** 04 04 Red (NDIR) spectroscopy

Ammonia (NH3) Annual 100 100 . Chemiluminescence µg/m3 Average* . Indophenol Blue 24 hours** 400 400 Method

Benzene (C6H6) Annual* 05 05 . Gas chromatography µg/m3 based continuous analyzer . Adsorption and desorption followed by GC analysis Benzo(a) Pyrine Annual* 01 01 . Solvent extraction (BaP)-particulate followed by HPLC/GC phase only, µg/m3 analysis Arsenic (As), Annual* 06 06 . AAS/ICP method after µg/m3 sampling on EPM 2000 or equivalent filter paper Nickel (Ni) Annual* 20 20 . AAS/ICP method after µg/m3 sampling on EPM 2000 or equivalent filter paper * Annual Arithmetic mean of minimum 104 measurements in a year taken twice a week 24 hourly at uniform interval. ** 24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied with 98% of the time in a year. 2% of the time, they may exceed the limits but not two consecutive days of monitoring.

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Table 3.19: Results of Groundwater Quality in the Study Area (Date of Sampling: 25 to 26, November, 2020) Parameters Unit CONCENTRATION Nr. Project Lodhikheda Borgaon MPIDC Jamlapani Tinkheda Khaparkheda Khairitaygaon Site (GW2) (GW3) (GW4) (GW5) (GW6) (GW7) (GW8) (GW1) pH pH Unit 7.53 7.43 7.78 7.39 7.64 7.27 7.58 7.44 Color Co-Pt Unit Color Color Color Color Color Color Color Color less less less less less less less less Conductivity Micro 755 725 940 865 775 785 690 810 mhos/cm Turbidity NTU 5.5 6.1 3.7 4.9 6.5 6.8 6.0 6.2 TDS mg/L 516 492 645 592 530 542 471 552 Total Hardness as mg/L 188 197 212 191 181 172 160 181 CaCO3 Total Alkalinity mg/L 246 253 249 228 227 235 239 257 Sodium as Na+ mg/L 94 93 134 123 118 123 95 119 Potassium as K+ mg/L 23 19 28 25 21 16 20 23 +2 Calcium as Ca mg/L 49 51 52 47 46 39 41 41 Magnesium as Mg+2 mg/L 16 17 20 18 16 18 14 19 Chlorides as Cl- mg/L 102 82 156 130 109 116 82 102 -2 Sulfates as SO4 mg/L 42 37 52 55 46 34 30 49 Fluoride as F- mg/L 0.63 0.64 0.49 0.68 0.45 0.65 0.69 0.74 -3 Nitrates as NO3 mg/L 26 32 18 22 27 30 25 24 Phenol mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Iron as Fe mg/L 0.16 0.32 0.28 0.35 0.29 0.30 0.27 0.25 Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 % Sodium -- 48.3 47.6 53.9 54.3 55.1 58.0 52.5 55.0

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Table 3.20: Surface Water analysis of study area (Date of Sampling: 25 to 26, November, 2020) Parameters Unit CONCENTRATION Borgaon Jamalpani Khairitaygaon Raibasa Kanhan Jam (SW1) (SW2) (SW3) (SW4) River River (SW5) (SW6) pH pH Unit 7.64 7.68 7.84 7.69 7.52 7.48 Conductivity Micro 488 556 603 557 448 489 mhos/cm Turbidity NTU 12 10 14 18 8 16 TDS mg/L 342 392 423 392 310 346 DO mg/L 5.9 5.3 5.1 5.5 6.2 6.5 Total Hardness as mg/L 113 124 116 103 116 113

CaCO3 Total Alkalinity mg/L 226 237 255 240 232 245 Sodium as Na+ mg/L 69 84 106 97 66 79 Potassium K+ mg/L 14 16 23 20 14 16 +2 Calcium Ca mg/L 23 20 20 18 20 14 Magnesium Mg+2 mg/L 16 18 16 14 16 19 Chlorides as Cl- mg/L 58 75 102 85 56 62 -2 Sulfates as SO4 mg/L 22 20 31 17 10 16 -3 Nitrates as NO3 mg/L 10.2 9.5 6.7 7.2 6.9 7.3

Phenol as CH3OH mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Iron as Fe mg/L 0.12 0.09 0.11 0.21 0.17 0.18 Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Total Coliform MPN/ml 492 686 574 770 552 560

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Table 3.21: Indian Standard Specification for Drinking Water

Sr. Parameters Desirable Permissible No. Limit Limit in the Absence of Alternate Source I Essential Characteristics 1. Colour, Hazen Units, Max. 5 25 2. Odour Unobjectionable - 3. Taste Agreeable - 4. Turbidity, NTU, Max. 5 10 5. pH 6.5-8.5 No Relaxation

6. Total Hardness (as CaCO3) mg/l, Max. 300 600 7. Iron (as Fe) mg/l, Max. 0.3 1.0 8. Chlorides (as Cl) mg/l, Max. 250 1000 9. Residual Free Chlorine, mg/l, Min. 0.20* - II Desirable Characteristics 10. Dissolved Solids, mg/l, Max. 500 2000

11. Alkalinity (as CaCO3), mg/l, Max. 200 600

12. Sulphate (as SO4) mg/l, Max. 200 400

13. Nitrate (as NO3) 45 100 14. Fluoride (as F) mg/l, Max. 1.0 1.5 15. Calcium (as Ca) mg/l, Max. 75 200 16. Magnesium (as Mg) mg/l, Max. 30 100 17. Copper (as Cu) mg/l, Max. 0.05 1.5 18. Manganese (as Mn) mg/l, Max. 0.1 0.3 19. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation 20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation 21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation 22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation 23. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation 24. Lead (as Pb) mg/l, Max. 0.05 No Relaxation 25. Zinc (as Zn) mg/l, Max. 5 15 26. Aluminium (as Al) mg/l, Max. 0.03 0.2 27. Boron (as B) mg/l, Max. 1 5 28. Chromium (as Cr) mg/l, Max. 0.05 No Relaxation

29. Phenolic Compounds (as C6H5OH) mg/l, 0.001 0.002 Max. 30. Anionic Detergents (as MBAS) mg/l, 0.2 1.0 Max. mg/l, Max. 31. Mineral Oil mg/l, Max. 0.01 0.03 32. Pesticides Absent 0.001 33. Radioactive Materials a. Alpha Emitters, Bq/I, Max. - 0.1 b. Beta Emitters, Pci/I, Max - 0.037 Note: * Applicable only when water is chlorinated Source: IS: 10500, 2012

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Table 3.22: Ambient Noise Levels in the Study Area (Date of Sampling: 24 to 26, November, 2020) Sr. Locations Ld/Ln Noise Level No. dB(A) 1 Project site (N1) Ld 53.4 Ln 42.9 2 100 m West from the site (N2) Ld 53.1 Ln 42.5 3 250 m South from the site (N3) Ld 50.7 Ln 40.1 4 500 m North from the site (N4) Ld 50.5 Ln 40.3 5 1000 m East from the site (N5) Ld 52.9 Ln 40.8 6 Primary School Borgaon (N6) Ld 52.1 Ln 39.4 7 Village Jamlapani (N7) Ld 50.5 Ln 38.7 8 Village Tinkheda (N8) Ld 50.1 Ln 38.5 9 Village Khaparkheda (N9) Ld 52.8 Ln 40.1

Table 3.23 Ambient Air Quality Standards with respect to Noise

Zone Limits Leq, dB(A) Day Time Night Time Industrial 75 70 Commercial 65 55 Residential 55 45 Silence 50 40

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-36 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.24: Soil Analysis of Study area (Date of Sampling: 25 to 26, November, 2020) Parameters Unit Concentration Project Lodhikheda Borgaon MPIDC Jamlapani Tinkheda Khaparkheda Khairitaygaon Site (S2) (S3) (S4) (S5) (S6) (S7) (S8) (S1) pH (5%) Solution -- 7.82 7.57 7.75 7.68 7.59 7.39 7.49 7.56 Loss of Ignition % 10.9 10.2 10.8 10.9 10.2 11.5 10.8 8.58 Particle Size Clay (< 0.002 mm) % 16 18 23 20 19 25 20 17 Silt (0.002 to 0.075 mm) % 22 25 23 18 19 25 27 18 Sand (0.075 to 0.475 % 52 43 39 49 50 36 42 50 mm gravel (size > 4.75 mm) % 10 14 15 13 12 14 11 15 Water Holding Capacity % 42.3 43.5 42.8 40.7 45.9 43.9 46.2 46.1 Permeability cm/hr 3.16 3.20 3.24 3.18 3.29 3.28 3.28 3.23 Bulk Density g/cm3 1.42 1.45 1.47 1.46 1.5 1.47 1.49 1.46 Porosity % 42.5 41.3 40.5 40.9 39.2 40.5 39.7 40.9 Sodium Absorption Ratio - 24.14 28.37 20.57 22.76 29.48 23.18 25.66 24.54 Sodium mg/kg 331 344 285 321 402 300 339 305 Potassium mg/kg 193 201 276 151 237 172 142 222 Calcium mg/kg 260 172 242 260 242 213 227 201 Magnesium mg/kg 116 122 142 138 130 122 122 108 Chlorides mg/kg 462 407 251 318 251 404 335 327 Sulphates mg/kg 198 173 177 152 177 164 130 161 Organic Matter mg/kg 1.9 2.1 1.8 1.8 2.2 1.9 2.3 2.1 Available Nitrogen mg/kg 210 230 235 223 210 232 229 223 Available Phosphorus mg/kg 69 86 93 85 95 97 102 116 Iron mg/kg 1.89 1.68 1.79 1.68 1.79 1.58 1.79 1.79 Manganese mg/kg 3.22 2.40 3.22 3.54 1.64 2.55 2.55 2.40 Cation exchange - 4.2 3.89 4.43 4.23 4.65 3.83 3.99 3.8 capacity (CEC)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-37 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.25 Floral Diversity

Sr. No. Botanical Name Common Name 1 Acacia catechu Khaira 2 Achyranthes aspera Apamaranga 3 Adina cordifolia Haldu 4 Aegle marmelos Bel 5 Alangium salviifolium Arinjl 6 Albizia odoratissima Siras 7 Aloe vera Gheekuanri 8 Alstonia scholaris Devil tree 9 Andrographis paniculata Bhuinnimba 10 Anogeissus acuminate Phasi 11 Anogeissus latifolia Dhaora 12 Antidesma diandrum Khatua 13 Aphanamixis polystachya Pithraj 14 Apium graveolens Ajmud 15 Apluda mutica Mauritian Grass 16 Mauritian Grass Agarwood 17 Artocarpus heterophyllus Kathal 18 Asparagus racemosus Satabari 19 Azadirachta indica Neem 20 Bambusa arundinacea Bambooo 21 Barringtonia acutangula Hinjal 22 Bauhinia racemosa Ashta 23 Bauhinia vahlii Maloo creeper 24 Bombax ceiba Semal 25 Boswellia serrate Salai 26 Bridelia retusa Spinous Kino Tree 27 Buchanania lanzan Chironji Tree 28 Butea superba Palas 29 Careya arborea Kumbhi 30 Carissa carandas Karonda 31 Cassia fistula Amaltas 32 Cassia tora Chakunda 33 Chloroxylon swietenia Ceylon Satinwood 34 Cochlospermum religiosum Golden Silk cotton Tree 35 Combretum decandrum Devanagari 36 Cordia macleodii Samarsinga 37 Croton oblongifolius Ghanasura 38 Curcuma aromatic Palua 39 Dalbergia latifolia Shisham 40 Dendrocalamus strictus Bamboo 41 Desmodium gangeticum Salaparni 42 Digitaria setigera Indian crabgrass 43 Diospyros peregrine Makar Kendu 44 Emblica officinalis Amla 45 Eragrostis amabilis Japanese lovegrass 46 Eugenia cumini Jamun 47 Eulaliopsis binate Sabai grass

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-38 San Envirotech Pvt. Ltd., Ahmedabad

48 Ficus bengalensis Banyan 49 Ficus cunia Khaina 50 Ficus glomerela Gular 51 Ficus religiosa Peepul 52 Gardenia gummifera Dikamli 53 Gardenia latifolia Papra 54 Garuga pinnata Kharpat 55 Gmelina arborea Gamhar 56 Grewia tiliifolia Dhaman 57 Haldina cordifolia Haldu 58 Helicteres isora Indian screw tree 59 Heteropogon contortus Black Speargrass 60 Holarrhena antidysenterica Kurchi Bark 61 Holoptelea integrifolia Dhauranja 62 Hymenodictyon excelsum Bhaulan 63 Hyptis suaveolens Pignut 64 Imperata cylindrical Cogon grass 65 Kydia calycina Baranga 66 Lagerstroemia parviflora Lendia 67 Lannea coromandelica Moyan 68 Lantana camara Lantana 69 Litsea sebifera Jarasanda 70 Madhuca longifolia Mahuwa 71 Mallotus philippensis kumkum tree 72 Mangifera indica Aam 73 Mesua ferrea Nageswar 74 Millettia auriculata Khacho 75 Mitragyna parvifolia Kaim 76 Monilkra hexandra Khirkoli 77 Morinda tinctoria Achhu 78 Murraya paniculata Kamini 79 Nyctanthes arbotistia Har sinagar 80 Ougeinia oojeinensis Bandhan 81 Perilla ocymoides Bana Tulasi 82 Pongamia pinnata Karanj 83 Pterocarpus marsupium Biju 84 Rauwolfia serpentine Patalgaruda 85 Saccharum spontaneum Kashatandi 86 Sapindus emarginatus Ritha 87 Saraca indica Ashoka 88 Sehima nervosum Sehima 89 Senegalia pennata Climbing Acacia 90 Senna tora Panwar 91 Setaria viridis Green foxtail 92 Shorea robusta Sal 93 Sorghum halepense Johnson grass 94 Spondia smangifera Ambara 95 Stereospermum angustifolium Chhuinpatuli 96 Streblus asper Sahada

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-39 San Envirotech Pvt. Ltd., Ahmedabad

97 Strychnos potatorum Nirmala 98 Symplocos racemosa Lodha 99 Syzygium cumini Jamun 100 Tamarindus indica Tentuli 101 Tamarix dioica Jhau 102 Tectona grandis Teak 103 Terminalia arjuna Arjun tree 104 Terminalia bellirica Baheda 105 Terminalia tomentosa Saja 106 Themeda quadrivalvis Grader grass 107 Tridax procumbens BisalyaKarani 108 Ventilago madraspatana Pitti 109 Woodfordia fruticosa Dhawai 110 Ziziphus xylopyra Ghont

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-40 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.26 Faunal Biodiversity

Type Zoological Name Common Name Reptiles: 1 Calotes versicolor Oriental garden lizard 2 Hemidactylus flaviviridis House lizards 3 Bungarus caeruleus Krait 4 Naja naja Indian Cobra 5 Eryx johnii Sand Boa 6 Vipera russeli Russels Viper 7 Ptyas mucosus Rat Snake 8 Drypin nasutus Whip Snake 9 Chamaleo chameleon Chameleon 10 Trionyx spp Fresh water turtle 11 Lissemys punctate Indian flapshell turtle 12 Tertu elegans Indian starred Tortoise 13 Varanus bengalensis Bengal monitor 14 Melanochelys trijuga Indian black turtle 15 Dendrelaphis tristis Bronzeback Amphibian: 16 Bufo bufo Common Toad 17 Hoplobatrachus tigerinus Frog Mammals: 18 Bos gaurus Indian Bison 19 Axis axis Chital 20 Boselaphus tragocamelus Nilgai 21 Canis aureus Jackal 22 Cynopterus sphinx Short-nosed Indian fruit bat 23 Felischaus Jungle cat 24 Funambulus pennant Northern palm squirrel 25 Herpestes edwardsii Common Mongoose 26 Hyaena hyaena Hyena, Striped 27 Lepus nigricollis Hare, Indian 28 Macaca mulatta Monkey 29 Muntiacus muntjak Barking Deer 30 Presbytis entellus Common Langur 31 Pteropus giganteus Bat, Flying Fox 32 Rusa unicolor Sambar deer 33 Sus scrofa Indian Wild Boar 34 Viverricula indica Small Indian Civet 35 Small Indian Civet Indian Fox 36 Bandicota bengalensis Lesser bandicoot rat 37 Hystrix indica Indian crested porcupine Aves: 43 Acridotheres tristis Myna 44 Bubulcus ibis Cattle egret 45 Butastur teesa White eyed Buzzard 46 Butorides striata Striated heron 47 Chrysomma sinense Yellow – eyed Babbler 48 Columba livia Pigeon

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-41 San Envirotech Pvt. Ltd., Ahmedabad

49 Coracias benghalensis Indian roller 50 Corvus splendens Crow 51 Dendrocopos cathpharius Woodpecker 52 Eudynamys scolopaceus Koel 53 Francolinus pictus Painted francolin 54 Francolinus pondicerianus Grey francolin 55 Gallus sonneratii Grey junglefowl 56 Megalaima asiatica Blue throated Barbet 57 Merops orientalis green bee-eater 58 Milvus migrans Black Kite 59 Orthotomus sutorius Tailor Bird 60 Pavo cristatus Peafowl 61 Pellorneum ruficeps Spotted Babbler 62 Perdicula asiatica Jungle bush quail 63 Ploceus philippinus Baya weaver 64 Psittacula krameri Rose-ringed parakeet 65 Pycnonotus cafer Red-vented bulbul 66 Spilopelia senegalensis laughing dove 67 Terpsiphone paradise Indian paradise flycatcher 68 Treron phoenicoptera Yellow-footed green pigeon 69 Turdoides striatus Jungle Babbler 70 Turdus merula Black Bird Aquatic (Fishes) 71 Wallago attu Freshwater catfish 72 Channa punctate Spotted snakehead 73 Salmophasia bacaila Large razorbelly minnow 74 Catla catla Catla 75 Labeo rohita Rohu 76 Labeo calbasu Orangefin labeo 77 Tor putitora Putitor mahseer 78 Labeo gonius Kuria labeo 79 Channa striata Snakehead murrel 80 Mastacembelus armatus Tire track eel 81 Bagarius bagarius Devil catfish

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-42 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.27 Traffic Survey TRAFFIC SHEET

LOCATION NH-26B @Borgaon point

TIME 09.00 to 10.00 DATE 25/11/2020

TOTAL PCU calculation Total PCU/hr BUSES* 65 PCU x 3 195 CARS/VANS 215 PCU x 1 215 MOTORCYCLES / BICYCLES 495 PCU x0.5 248 Total 658

TIME 18.00 to 19.00 DATE 25/11/2020

TOTAL PCU calculation Total PCU/hr BUSES* 72 PCU x 3 216 CARS/VANS 248 PCU x 1 248 MOTORCYCLES / BICYCLES 512 PCU x0.5 256 Total 710 Note: *Mini-bus, Chartered Bus, School Bus, have been collectively classified as Buses.

Additional traffic from our project will be estimated 45 PCU/day [15 trucks/tankers (in & out) x 3] and 40 PCU/day from car and motorcycle, which have insignificant impact on existing traffic load.

Existing Traffic Scenario and Level of Services The road NH-26B @Borgaon point is 2 lanes with divider, and all types of vehicles move on the road. Capacity of road as per IRC = 1500 PCU‟s/hr Total Volume during Peak Hours = 710 Existing Volume/Capacity ratio = 710/1500= 0.473 The level of service is “C” that is Good

LEVEL OF SERVICE Sr. No. Existing Volume/ Level of Services Capacity Ratio 1. 0.0 to 0.2 “A” (Excellent) 2. 0.2 to 0.4 “B” (Very Good) 3. 0.4 to 0.6 “C” (Good) 4. 0.6 to 0.8 “D” (Fair) 5. 0.8 to 1.0 “E” (Poor)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-43 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.28 Land Use Pattern

Name of Village Total Area Irrigated Un- Cultivable Area not of the by source irrigated waste available for Village (ha) (ha) (ha) cultivation (ha) (ha) Tinkheda 1099.6 187.3 487.8 0 0 Khairitaygaon 534.6 30.1 255.3 16.5 0 Gondiwadhona 1268 130.1 475.8 0 0 Gowariwadhona 634.6 13.9 401.1 26.7 0 Ghoghrikhapa 381.4 59 276.8 0 0 khairipanthwali 967.5 181.4 490.3 18 0 Khapa karimwar 438.2 8.6 206.7 0 178.5 Yalkapar 391.7 72.6 239.1 0 0 Khaparkheda 439.2 102.5 225.7 0 0 Saykheda 762.9 152.2 393.4 0 0 Chhindewani dhadi 1070.6 86.2 544.9 21 269.4 Lodhikheda 116.6 8.9 63.4 11.8 0 Dhotki 777.7 128.3 299 10.7 225 Ridhora 836.8 171.9 394.3 118.3 0 Semra 317.2 36 137.7 3.6 105.1 Dhokdoh 776.8 67.3 476.2 0 145.9 Piplanarayanwar Merged in Town Koprawadi kalan 286.9 70 169.3 0 18.5 Jakhiwara 445 181.1 153.3 0 0 Jam 683.8 143.3 492.6 0 0 Satnoor 548.9 70.9 91.7 29.8 14.7 Paradsinga 387.5 18.5 296.6 0 48.1 Kodadongri dawami 81.6 2.7 52.5 10 5.6 Kodadongri mal. 218.5 10.8 141.8 0 35.4 Kodadongri B1 42.4 0 4.8 0 4.1 Sawanga 678 71.2 469 4.2 32.6 Palora 226.3 21.2 183.9 0 4.1 Chichghat 426.9 2.7 115.6 32 0 Sangam 340.4 28.8 179.4 0 80.8 Kabarpipla 532 446 0 85 0 Razhadi borgaon 676.7 27.9 504 10 12.7 Bramhan pipla 763 28 445 193 0 Waghora 1025 32.6 555.8 76.6 0 Sawli no.1 613.7 12.4 443.4 0 0 Hiwari 408 22.2 179.1 73.3 14.9 Hiwara 763.3 64.2 483.4 15 0 Khanderaywar Mathni 127.2 9.5 70.2 0 0 Rangari 1380.6 165.5 874.2 10 141.5 Ambari 427.8 95.5 244.8 0 6.6 Khedijasodi 329.9 38.1 235.9 0 0 Jamthi 503.8 18.4 376 0 0

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-44 San Envirotech Pvt. Ltd., Ahmedabad

Belgaon 326.2 29.6 255.8 0 0 Gujarkhedi 409.7 85.5 206.7 12.5 0 Berdi 575 82.1 319.6 44.8 117.6 Khatgal 212.1 12.6 180.5 0 0 Dhoda Borgaon Mal. 744.8 102.6 327.5 0 0 Partapur 362 3.9 57.3 24.2 0 Ajangaon 489.5 230.1 158 16.2 0 Vagholi 445.8 60.7 218.5 13.9 4.9 Kodhar Roadikheda 101.6 37.3 29 5.9 13.5 Kondhar Mal 158.9 36 70 4 4.3 Sitapar 72 3.5 55.4 4 1 Wadegaon 192.7 13.4 108.6 0 41.5 Singpur 425.3 65.9 303.5 0 15.4 Dhoda Borgaon No. 41.7 0 35.3 0 0 2 Dhoda Borgaon 189.3 0 52.5 0 0 Jamalpani No. 2 947.4 41.4 167.9 0 0 Jaitgad 750 2.8 351 78.3 0 Bid jatamkhora 533.3 5.8 222.9 17.8 19.4 Jatamkhora 579.1 39.4 378.8 12.4 32.5 Sawali 563.3 28.8 307 80.2 0 Khursapar 641.4 30.1 317.9 66.5 59.9 Bidgaon 238.39 102 0 12.7 0

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-45 San Envirotech Pvt. Ltd., Ahmedabad

Table: 3.29 Summary of Socio-economic status of Study area (Demography) Name of the No. of Total Population Literates Total main Marginal Cultivators Agricultura Non-Worker Village/ Occupie (Including Workers Workers l Laborer Town/Ward d institutional and Resident houseless ial population) House P M F M F M F M F M F M F M F Tinkheda 542 2318 1189 1129 987 794 609 103 179 12 39 83 129 477 696 103 Khairitaygaon 966 3731 1955 1776 1593 1318 1045 61 43 3 3 18 111 849 1374 61 Gondiwadhona 140 643 360 283 239 144 170 48 90 20 33 27 56 142 140 48 Gowariwadhona 85 335 165 170 142 101 91 5 16 0 1 5 15 69 118 5 Ghoghrikhapa 174 840 428 412 296 238 247 0 0 0 0 0 0 181 241 0 Khairipanthwali 159 677 343 334 272 235 212 1 4 0 2 1 1 130 219 1 Khapa Karimwar 1 2 2 0 2 0 0 0 0 0 0 0 0 2 0 0 Yalkapar 102 422 225 197 196 135 78 69 116 12 15 57 101 78 70 69 Khaparkheda 88 348 180 168 132 101 100 12 88 4 31 8 57 68 58 12 Saykheda 413 1649 818 831 629 544 489 7 10 1 1 5 6 322 401 7 Chhindewani 289 1237 620 617 429 332 383 2 3 0 0 0 0 235 295 2 dhadi Lodhikheda 2237 9950 5074 4876 4140 3539 2201 590 418 477 30 19 288 397 2455 3809 Dhotki 196 963 508 455 367 271 15 15 32 4 15 11 14 201 230 15 Ridhora 347 1524 779 745 563 433 434 8 3 1 0 4 2 337 500 8 Semra 122 467 244 223 194 167 148 1 0 1 0 0 0 95 109 1 Dhokdoh 175 773 403 370 296 200 192 88 189 3 39 85 148 123 149 88 Koprawadi Kalan 367 1567 802 765 627 479 426 266 64 191 14 26 49 164 312 308 Jakhiwara 110 535 286 249 210 150 123 13 50 120 3 17 46 103 113 116 Jam 334 1390 723 667 541 438 271 96 130 94 1 1 102 90 322 477 Satnoor 443 1784 932 852 747 617 432 132 31 21 1 2 26 18 469 699 Paradsinga 889 3833 1959 1874 1638 1411 1044 464 23 30 1 3 12 25 892 1380 Kodadongri mal. 49 180 90 90 81 71 43 27 20 23 1 2 18 21 27 40 Sawanga 811 3433 1770 1663 1411 1184 972 631 26 40 1 3 11 29 772 992 Sangam 177 740 380 360 303 224 237 211 2 3 0 0 2 3 141 146

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-46 San Envirotech Pvt. Ltd., Ahmedabad

Kabarpipla 474 2058 1077 981 886 704 93 91 57 177 2 5 50 169 485 588 Razhadi Borgaon 151 652 333 319 263 206 199 135 22 60 14 29 8 30 112 124 Bramhan Pipla 460 1786 955 831 772 627 117 84 32 133 4 8 18 111 450 635 Waghora 287 1240 642 598 492 396 54 58 105 87 24 15 73 71 251 277 Sawli no. 1 378 1592 787 805 585 529 88 87 17 101 2 1 8 95 276 462 Hiwari 60 253 137 116 99 80 15 8 53 71 0 0 30 58 45 43 Hiwara 791 750 400 350 305 221 37 37 1 1 0 0 1 1 179 191 Khanderaywar Mathni 1 1 1 0 1 0 1 0 0 0 0 0 0 0 0 0 Rangari 683 3092 1604 1488 1201 968 847 536 165 225 12 20 150 202 592 727 Ambari 258 1159 590 569 474 383 320 266 53 68 2 10 50 58 217 235 Khedijasodi 116 507 274 233 206 148 116 18 41 93 9 1 22 88 117 122 Jamthi 1 4 2 2 2 1 2 0 0 0 0 0 0 0 0 2 Belgaon 243 1084 546 538 457 437 257 37 0 0 0 0 0 0 173 303 Gujarkhedi 150 670 344 326 264 181 55 8 143 123 1 1 100 110 146 195 Berdi 1292 5745 2992 2753 2318 1826 1658 788 147 227 10 12 107 209 1192 1738 Dhoda Borgaon 108 456 234 222 162 112 140 120 1 1 0 0 1 1 93 101 Mal. Partapur 126 480 276 204 206 107 119 33 35 32 1 5 32 27 122 139 Ajangaon 181 802 416 386 315 277 256 103 2 3 0 1 2 2 158 280 Kodhar 57 234 113 121 76 54 71 80 3 4 0 0 3 4 39 37 Roadikheda Kondhar mal 1 2 1 1 1 0 0 0 0 0 0 0 0 0 0 0 Singpur 159 727 376 351 164 123 141 112 4 19 2 4 2 14 92 108 Jamalpani No. 2 87 360 175 185 135 106 76 11 31 82 5 21 26 61 68 92 Jaitgad 2 6 4 2 3 1 2 1 ------2 1 Jatamkhora 160 626 314 312 249 171 192 178 9 17 3 5 6 11 113 117 Sawali 156 1011 566 445 479 344 196 145 3 1 0 0 1 1 367 299 Khursapar 175 797 411 386 310 245 225 190 19 22 2 2 16 19 167 174 Bidgaon 1109 4812 2523 2289 1919 1604 1326 285 75 52 5 6 13 6 1122 1952

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-47 San Envirotech Pvt. Ltd., Ahmedabad

Table 3.30: Summary of Socio-economic status of Study area (Amenities)

Name of Educational Medical Facility Drinking Communication Transportation Approach to Nearest Power Village Facility Water (Post or Telegraph) Facility Village town Supply Facility (Bus etc.) Tinkheda PP(2),P(1),S(1), CHC(+10),PHC(5- T,W,HP PO(5-10),SPO,P&TO(5- BS,RS(5-10) PR,KR,WBM,FP Lodhikheda EA SS(1) 10),PHS(1),MCW(5-10), 10),PH,PCO(5-10) TBC(5-10),VH(5-10) Khairitaygaon PP(3),P(3),S(1), CHC(+10),PHC(5-10), T,W,HP PO(+10),SPO,P&TO(+10), BS(<5), PR,KR,WBM,FP Lodhikheda EA SS(1) PHS(1),MCW(+10), PH,PCO RS(5-10) TBC(+10) Gondi- PP(1),P(1), CHC(+10),PHC(+10), T,W,HP PO(<5),SPO(<5), BS(<5),RS(<5) PR,KR,WBM,FP Lodhikheda EA wadhona S(<5), SS(<5) PHS(<5), MCW(+10), P&TO(+10),PH,PCO(+10) TBC(+10), VH(<5) Gowari- P(1),S(<5), CHC(+10),PHC(<5), HP PH(5-10),PCO(5-10) BS(<5), RS(5- PR(<5),KR, Lodhikheda EA wadhona SS(<5) PHS(<5),MCW(<5),TBC(<5) 10) WBM, FP ,VH(+10) Ghoghrikhapa PP(1),P(1), CHC(+10),PHC(<5),PHS(1), T,W,HP PO(<5),SPO(<5),P&TO(< BS(<5),RS(+10) PR(<5),KR, Sausar EA S(<5),SS(<5) MCW(+10),TBC(<5),VH(<5) 5), PH(<5)PCO(+10) WBM ,FP Khairipanthw PP(1),P(1), CHC(5-10),PHC(<5), T,W,HP, PO(5-10),SPO(5-10), BS(5-10), PR,KR,WBM,FP Sausar EA ali S(5-10),SS(5- PHS(<5), MCW(5- TW P&TO(5-10),PH(5-10), RS(5-10) 10) 10),TBC(<5),VH(5-10) PCO(<5) Khapa PP(<5),P(<5), CHC(+10),PHC(5- HP PO(+10),SPO(<5), BS(<5),RS(<5) PR(<5), Lodhikheda EA karimwar S(<5),SS(<5) 10),PHS(<5),MCW(+10), PH(<5), PCO(+10) KR(<5),WBM, FP TBC(5-10),VH(+10) Yalkapar P(1),S(+10), CHC(<5),PHC(<5),PHS(<5), T,W,HP, PO(<5),SPO(<5),P&TO(+ No Services PR(<5),KR, Sausar EA SS(+10) MCW(+10),TBC(<5),VH(<5) TW 10),PH(+10),PCO(+10) WBM,FP Khaparkheda P(1),S(+10), CHC(+10),PHC(<5), T,W,HP, PO(+10),SPO(<5),P&TO( BS(<5), PR(<5),KR, Lodhikheda EA SS(+10) PHS(<5), MCW(+10), TW <5),PH(+10),PCO(+10) RS(+10) WBM, FP TBC(<5),VH(<5) Saykheda PP(2),P(2),S(5- CHC(+10),PHC(+10), T,W,HP PO(+10),SPO,P&TO,PH(+ BS,RS(+10) PR,KR,WBM,FP Sausar EA 10),SS(5-10) PHS(1),MCW(+10),VH(1) 10),PCO(+10) Chhindewani PP(1),P(1),S(<5 CHC(<5),PHC(<5),PHS(<5), T,W,HP, PO(<5),SPO(<5),P&TO(< BS(<5),RS(+10) PR,KR,WBM,FP Sausar EA dhadi ),SS(<5) MCW(<5),TBC(<5),VH(<5) TW 5), PH(<5)PCO(+10) Lodhikheda P(<5),S(<5) CHC(+10),PHC(<5), W,R/C PO(<5),SPO(<5),P&TO(< BS(<5),RS(<5) PR(<5),KR, Sausar EA PHS(<5),MCW(<5),VH(<5) 5), PH(<5)PCO(+10) WBM(<5), FP Dhotki PP(1),P(1),S(1), CHC(5-10),PHC(5-10), T,W,HP PO(5-10),SPO(<5), BS(5-10), PR(5-10),KR, Sausar EA SS(5-10) MCW(5-10),TBC(5-10), P&TO(5-10), RS(5-10) WBM(<5),FP VH(5-10) PH,PCO(5-10) Ridhora PP(3),P(1), CHC(+10),PHC(1), T,W,HP, PO(+10),SPO(5- BS,RS(+10) PR(<5),KR, Sausar EA S(+10),SS(1) PHS(+10),MCW(<5), TW 10),P&TO(+10),PH, WBM,FP VH(<5) PCO(+10)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-48 San Envirotech Pvt. Ltd., Ahmedabad

Name of Educational Medical Facility Drinking Communication Transportation Approach to Nearest Power Village Facility Water (Post or Telegraph) Facility Village town Supply Facility (Bus etc.) Semra P(1),S(5- CHC(<5),PHC(5- W,R/C PO(5-10),SPO(5- BS(5- PR(<5),KR, Sausar EA 10),SS(5-10) 10),PHS(<5),MCW(5-10), 10),P&TO(5-10),PH(5- 10),RS(+10) WBM(<5),FP TBC(5-10),VH(5-10) 10),PCO(+10) dhokdoh PP(1),P(1),S(<5 CHC(+10),PHC(<5),PHS(<5 T,W,HP,T PO(<5),SPO(<5),P&TO(< BS(<5),RS(+10) PR,KR,WBM,FP Sausar EA ),SS(<5) ), W,R/C 5), PH(+10),PCO(+10) MCW(<5),TBC(<5),VH(<5) Koprawadi PP(1),P(2),S(1), CHC(+10),PHC(<5),PHS(1), T,W,HP,T PO(+10),SPO(<5),P&TO( BS(<5),RS(+10) PR,KR, Sausar EA kalan SS(1) MCW(<5),TBC(<5),VH(<5) W +10),PH(<5),PCO(+10) WBM(<5),FP Jakhiwara PP(1),P(1),S(5- CHC(5-10),PHC(5- T,W,HP,T PO(+10),SPO(<5),P&TO( NO SERVICES PR(<5),KR, Sausar EA 10),SS(5-10) 10),MCW(5-10),TBC(5- W +10),PH,PCO(+10) WBM(<5),FP 10),VH(5-10) Jam PP(1),P(1),S(<5 CHC(<5),PHC(<5),PHS(<5), T,W,HP,T PO(<5),SPO(<5),P&TO(< BS(<5),RS(<5) PR,KR,WBM,FP Sausar EA ),SS(<5) MCW(<5),TBC(<5),VH(<5) W 5), PH,PCO(+10) Satnoor PP(1),P(2),S(1), CHC(+10),PHC(<5),PHS(1), T,W,HP,R PO(<5),SPO(<5),P&TO(< BS, RS(<5) PR,KR,WBM,FP Sausar EA SS(<5) MCW(<5),TBC(<5),VH(<5) /C 5), PH paradsinga PP(5),P(2),S(2), CHC(+10),PHC(1),MCW(+10 T,W,HP PO(5- BS,RS PR,KR,WBM,FP Sausar EA SS(2) ), 10),SPO,P&TO,PH,PCO VH(5-10) Kodadongri P(1),S(<5),SS( CHC(+10),PHC(5- HP PO(+10),SPO(<5),P&TO,P BS(<5),RS(<5) PR(<5),KR, Lodhikheda EA mal. <5) 10),PHS(<5),MCW(+10), H(+10),PCO(+10) WBM(<5),FP TBC(5-10),VH(+10) Sawanga PP(1),P(2),S(2), CHC(+10),PHC(1), W,HP,TW, PO(+10),SPO,P&TO,PH,P BS(<5),RS(<5) PR(<5), Lodhikheda EA SS(2) MCW(+10) R/C CO(+10) KR(<5),WBM, FP(<5) Sangam PP(1),P(1),S(5- CHC(+10),PHC(5- W,HP,TW, PO(5-10),SPO(5- BS(5- PR(5-10),KR, Lodhikheda EA 10),SS(5-10) 10),PHS(5- R/C 10),P&TO(5-10),PH(5- 10),RS(+10) WBM(<5),FP 10),MCW(+10),TBC(5-10), 10),PCO(5-10) VH(+10) Kabarpipla PP(1),P(3),S(1), CHC(+10),PHC(<5),PHS(1), T,HP,TW PO(<5),SPO,P&TO(<5),P BS(<5),RS(<5) PR,KR,WBM,FP Sausar EA SS(1) MCW(+10),TBC(<5),VH(<5) H,PCO Razhadi PP(1),P(2),S(5- CHC(+10),PHC(5- T,W,HP,T PO(5-10),SPO(5- BS(5- PR(<5) ,KR, Lodhikheda EA borgaon 10),SS(5-10) 10),PHS(5-10),MCW(5- W 10),P&TO(+10),PH,PCO(5 10),RS(+10) WBM, FP *10),TBC(5-10), -10) VH(5-10) Bramhan PP(1),P(2),S(1) CHC(+10),PHC(<5),PHS(1), T,W,HP,T PO(<5),SPO(<5),P&TO(< BS,RS(<5) PR,KR,WBM,FP Sausar EA pipla MCW(+10),TBC(<5),VH(<5) W 5),PH,PCO(+10) Waghora PP(2),P(2),S(<5 CHC(5-10),PHC(5- T,W,HP PO(5- BS(5-10) PR,KR, Sausar EA ),SS(5-10) 10),PHS(5-10),MCW(5- 10),SPO(<5),P&TO(5- WBM(<5), FP 10),TBC(5-10),VH(5-10) 10),PH(5-10),PCO(5-10)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-49 San Envirotech Pvt. Ltd., Ahmedabad

Name of Educational Medical Facility Drinking Communication Transportation Approach to Nearest Power Village Facility Water (Post or Telegraph) Facility Village town Supply Facility (Bus etc.) Sawli no.1 PP(1),P(2),S(5- CHC(5-10),PHC(5- T,W,HP,T PO(5-10),SPO(5- BS(5-10), PR,KR, Sausar EA 10),SS(5-10) 10),PHS(1)MCW(5- W,R/C 10),P&TO(5-10),PH(5- RS(+10) WBM(<5),FP 10),TBC(5-10),VH(5-10) 10),PCO(5-10) Hiwari P(1),S(<5),SS( CHC(<5),PHC(<5),PHS(<5), W,HP PO(<5),SPO(<5),P&TO(< BS(<5),RS(<5) PR(<5),KR, Sausar EA <5) MCW(<5),TBC(<5),VH(<5) 5),PH(<5),PCO(+10) WBM(<5),FP Hiwara PP(1),P(1),S(5- CHC(+10),PHC(5- W,HP,TW PO(5-10),P&TO(5- BS(5-10), PR(<5),KR, Lodhikheda EA khanderaywar 10),SS(5-10) 10),PHS(1),MCW(5- 10),PH(5-10),PCO(5-10) RS(+10) WBM(<5),FP 10),TBC(5-10),VH(5-10) Mathni NO DATA CHC(+10),PHC(+10),PHS(+ No PH(+10),PCO(+10) No Services PR(5-10), Lodhikheda EA AVAILABLE 10),MCW(+10),TBC(+10) Services KR,WBM(<5), FP Rangari PP(1),P(4) CHC(+10),PHC(+10), T,W,HP,T PO(5-10),P&TO,PH,PCO BS,RS PR,KR,WBM,FP Lodhikheda EA PHS(1), MCW(+10), W,R/C TBC(+10), VH(<5) Ambari PP(1),P(1),S(1), CHC(+10),PHC(5-10), T,W,HP PO(<5),SPO(<5),P&TO(< BS(<5),RS(+10) PR(<5),KR, Lodhikheda EA SS(<5) PHS(<5),MCW(+10),TBC(5- 5),PH,PCO WBM, FP 10), VH(5-10) Khedijasodi PP(1),P(1),S(5- CHC(+10),PHC(5- T,HP PO(5-10),P&TO(5- BS(5-10), PR(5-10),KR, Lodhikheda EA 10),SS(+10) 10),PHS(5-10)MCW(5- 10),PH(5-10),PCO(5-10) RS(+10) WBM(<5), FP 10),TBC(5-10),VH(5-10) Jamthi PP(<5),P(<5), CHC(<5),PHC(<5),PHS(<5), HP PO(<5),SPO(<5),P&TO(< BS(<5),RS(<5) PR(<5), KR(<5), Sausar EA S(<5) MCW(<5),TBC(<5),VH(<5) 5),PH(<5),PCO(<5) WBM(<5), FP Belgaon PP(1),P(2),S(1), CHC(<5),PHC(<5),PHS(<5), W,HP PO(<5),SPO(<5),P&TO(< BS(<5),RS(<5) PR,KR,WBM,FP Chaurai EA SS(<5) MCW(<5),TBC(<5),VH(<5) 5),PH,PCO(<5) khas Gujarkhedi PP(1),P(1), CHC(<5),PHC(<5), T,W,HP PO(<5),SPO(5-10), BS(<5),RS(<5) PR,KR,WBM,FP Pandhurna EA S(<5),SS(<5) PHS(+10),MCW(+10), P&TO(<5),PH,PCO(<5) TBC(<5),VH(<5) Berdi PP(4),P(5),S(2), CHC(<5),PHC(1),PHS(<5), W,TW PO(<5),SPO,P&TO(<5),P BS,RS PR(<5), KR(<5), Sausar EA SS(2) MCW(1),VH(1) H,PCO WBM(<5),FP Dhoda P(1),S(5- CHC(+10),PHC(<5), T,W,HP PO(+10),SPO(<5), BS(<5),RS(+10) PR,KR,WBM,FP Sausar EA Borgaon Mal. 10),SS(5-10) PHS(<5),MCW(+10), P&TO(<5),PH(<5),PCO TBC(<5),VH(<5) Partapur P(1),SS(+10) CHC(+10),PHS(1),MCW(1),V W,R/C PO(+10),SPO,P&TO(+10), BS,RS(+10) PR,KR, Harrai EA H(+10) PH(+10),PCO(+10) WBM(<5), FP Ajangaon PP(1),P(1),S(1), CHC(5-10),PHC(5-10), HP PO(5-10),SPO(5-10), BS(5-10), PR,KR, Pandhurna EA SS(5-10) MCW(5-10),TBC(5-10), PH,PCO(5-10) RS(+10) WBM(<5), FP VH(5-10) Kodhar P(1),S(5- CHC(+10),PHC(5-10), W,HP PO(+10),SPO(<5), BS(<5),RS(+10) PR(<5),KR, Pandhurna EA roadikheda 10),SS(5-10) PHS(5-10), MCW(+10), P&TO(+10),PH(<5), WBM(5-10), FP TBC(5-10),VH(5-10) PCO(+10)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-50 San Envirotech Pvt. Ltd., Ahmedabad

Name of Educational Medical Facility Drinking Communication Transportation Approach to Nearest Power Village Facility Water (Post or Telegraph) Facility Village town Supply Facility (Bus etc.) Kondhar mal PP(5-10), CHC(+10),PHC(5- HP,R/C PO(<5),SPO(<5), BS(<5),RS(+10) PR(<5), KR(<5), Pandhurna EA P(<5), S(5- 10),PHS(5- P&TO(+10),PH(<5), WBM(5-10), 10),SS(5-10) 10),MCW(+10),TBC(5- PCO(+10) FP 10),VH(5-10) Singpur PP(1),P(1), CHC(<5),PHC(<5), No PO(<5),SPO(<5), BS(<5),RS(+10) PR,KR,WBM, FP Chhindwara EA S(<5),SS(<5) PHS(+10),MCW(<5), Services P&TO(+10),PH(<5), TBC(<5),VH(<5) PCO(<5) Jamalpani No. P(1),S(<5), CHC(+10),PHC(5- HP,R/C PO(5-10),P&TO(5- BS(5- PR(<5), KR(5- Mohgaon EA 2 SS(5-10) 10),PHS(5-10),MCW(5- 10),PH(5-10),PCO(5-10) 10),RS(+10) 10), WBM(<5),FP 10),TBC(5-10),VH(5-10) Jaitgad PP(5-10),P(<5), CHC(+10),PHC(5-10), W PO(5-10),P&TO(5-10), BS,RS(5-10) PR,KR,WBM, FP Savner EA S(5-10),SS(5- PHS(5-10), MCW(5-10), PH(5-10), PCO(5-10) 10) TBC(5-10),VH(5-10) Jatamkhora PP(2),P(1),S(5- CHC(5-10),PHC(5-10), T,W,TW PO(5-10),P&TO(5- BS,RS(5-10) PR,KR,WBM, FP Savner EA 10),SS(5-10) PHS(1),MCW(5-10),TBC(5- 10),PH,PCO 10),VH(5-10) Sawali PP(2),P(2),S(1), CHC(+10),PHC(+10),PHS(5- T,TW PO(+10),SPO(+10),P&TO BS,RS(+10) PR,KR,WBM, FP Savner EA SS(1) 10), MCW(+10),TBC(+10), (+10),PH,PCO VH(+10) Khursapar PP(2),P(1),S(1), CHC(+10),PHC(+10), T,HP PO(5-10),P&TO(5- BS,RS(+10) PR,KR(<5), Umred EA SS(+10) PHS(1), MCW(+10), 10),PH,PCO WBM(<5),FP TBC(+10),VH(+10) Bidgaon PP(5),P(3), CHC(<5),PHC(<5),PHS(<5), T,W,HP PO(<5),SPO(<5), BS,RS(<5) PR,KR(<5), Nagpur EA S(<5),SS(5-10) MCW(<5),TBC(<5),VH(<5) P&TO(<5),PH,PCO WBM, FP

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-51 San Envirotech Pvt. Ltd., Ahmedabad Abbreviations: Educational PP - Preprimary School P - Primary School S - Secondary School SS - Senior Secondary School C - College Medical Facility MCW - Maternity & Child Welfare Centre PHC - Primary Health Centre PHS - Primary Health Sub-Centre CHC - Community Health Centre HO - Allopathic Hospital D - Dispensary FWC - Family Welfare Centre CWC - Child Welfare Centre HA - Ayurvedic Hospital MHC - Mobile Health Clinic T.B - T.B Clinic Drinking Water T - Tap Water HP - Hand Pump TW - Tube well Water W - Well Water TK - Tank water R/C - River/Canal Post and Telegraph PO - Post Office PH - Telephone Connection SPO - Sub Post Office PCO - Public Call Office Transportation BS - Bus RS - Railway Station Approach to Village PR - Pucca Road KR - Kutccha Road WBM - Water bound macadam FP - Foot path SH - State Highway NH - National Highway Power Supply EA - Electricity for all Purposes

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-52 San Envirotech Pvt. Ltd., Ahmedabad Figure 3.7 Location of AAQM station

Indicating AAQM stations

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-53 San Envirotech Pvt. Ltd., Ahmedabad Figure 3.8 Wind Rose diagram

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-54 San Envirotech Pvt. Ltd., Ahmedabad Figure 3.9 Water sampling Locations

Indicating Ground Water sampling location Indicating Surface Water Sampling location

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-55 San Envirotech Pvt. Ltd., Ahmedabad Figure 3.10 Noise monitoring locations

Indicating Noise Monitoring location

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-56

San Envirotech Pvt. Ltd., Ahmedabad Figure 3.11 Soil Sampling Locations

Indicating locations of Soil sampling

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-57 San Envirotech Pvt. Ltd., Ahmedabad

Figure 3.12 Toposheet of location with site location map of 10 km radius (1:50,000 scale)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 3-58 San Envirotech Pvt. Ltd., Ahmedabad Chapter-4 Anticipated Environmental Impacts &

Mitigation Measures

4.1 GENERAL Environmental Impact can be defined as any change in environmental conditions which may be adverse or beneficial; occurred due to action or set of actions under consideration. It can be assessed by identifying the sources of the impact and predicting the same. The identification of environmental impacts has been made by co-relating the relationship between project activity and environmental parameters. As a part of present EIA study, anticipated environmental impacts associated with the project activity of the unit have been identified. The project activities are usually divided into two phases: Construction Phase and Operation Phase. For evaluation of impacts due to proposed activities, baseline data has been utilized. Changes in the environmental parameters & their impact in terms of short term or long term, positive or negative, reversible & irreversible are identified & predicted. The next step is prediction of impacts, which is an important component in environmental impact assessment process. Several techniques and methodologies are in vogue for predicting the impacts due to proposed industrial development on physical, chemical, biological and socio- economic components of environment. Such predictions delineate contribution in existing baseline condition for the proposed project. The additional impacts due to proposed activities are analyzed by keeping in mind the baseline status. This helps to assess the assimilative capacity of the environment and in turn the gravity of the impacts. Based on the identification & prediction of the nature of impact, it can be evaluated qualitatively and quantitatively. In this chapter, the effect due to construction & operational activity of the proposed project is explained.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-1 San Envirotech Pvt. Ltd., Ahmedabad 4.2 IDENTIFICATION OF IMPACT This chapter deals with the assessment of project impacts on environment. Mitigation measures are suggested to minimize the likely negative impacts. The network method (Cause - effect) was adopted to identify potential impact of the proposed activity. It includes stepwise study of relationship between an activity and its environmental parameters. This method involves in the “Road Map” type of approach to the identification of second & third order effect. The basic idea is to account for the project activity & identify the type of impact that could initially occur followed by the identification of secondary and tertiary impact. The project will have impacts of varying magnitude on different environmental components. These impacts could be categorized as -  Primary impacts, i.e. impacts which occur as a direct result of the project activities.  Secondary and tertiary impacts, i.e. impacts that occur as a result of primary impacts. 4.2.1 Identification of Impacting Activities Various activities involved in the project are divided viz.: A. Construction phase activities: impacts are immediate, in the vicinity and sporadic B. Operation phase activities: impacts are long term, in wide area and continuous The activities identified for the project under each phase are: Construction phase  Excavation  Foundation & Civil work  Transportation of construction materials, equipments & machineries  Installation of equipments & machineries Operation phase  Plant operation  Material storage & handling  Utilities and services  Green belt development

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-2 San Envirotech Pvt. Ltd., Ahmedabad 4.2.2 Identification of Environment Attributes There are various types of impacts arise due to the proposed activities which will be evaluated considering the following environment parameters in construction and operational phase,  Impact on Topography  Impact on Air Environment  Impact on Water Environment  Impact on Noise Environment  Impact on Land Environment (Hazardous/solid waste generation)  Impact on Biological Environment  Impact on Socio-Economic Environment  Impact on Occupational Health & Safety 4.3 IMPACT ON TOPOGRAPHY Orgosynth Chemicals Pvt. Ltd. is located at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Proposed land is already converted from agriculture to non-agriculture for industrial purpose. During the construction, excavated soil will be restored to its original shape. Thus, the impact during the construction is reversible, for short terms and insignificant. Construction of plant & building will be carried out for proposed unit. During the operational phase of the project, no major impact is envisaged on the topography. 4.4 IMPACT ON AIR ENVIRONMENT a. Construction Phase impact & mitigation measures During construction phase, there will be chances of dust generation due to the construction activities to be carried out as per the plant design. It will be limited up to working area only and not likely to spread in wider area. To mitigate the impact, regular sprinkling of the water will be done. Vehicular traffic may lead to increased concentration pollutants through exhaust gases, affecting the ambient air quality of surrounding areas; vehicles only with PUC certificates will be allowed. However, this effect remains localized near to site and during the time of vehicular movement only. Thus, overall impact is short-term negative & reversible in nature.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-3 San Envirotech Pvt. Ltd., Ahmedabad Hence, looking to the overall facts described above, it can be concluded that, the impacts on air due to the construction & erection activities will be minimum or negligible. b. Operational phase impact & mitigation measures Long term impacts on the air quality are anticipated due to operational activities. It depends on various factors like process technology, operation & maintenance, raw material, fuel, air pollution control measures. For the study of impact assessment for air environment, all probable emissions are studied including fugitive emission. The sources and expected emission level are described in below section. Emission from the project Flue gas emission will be from stack attached with Boiler (6 TPH), one stack of Thermic Fluid Heater (20 Lakhs Kcal/hr.) and one stack of 2 nos. of stand by D.G. Sets (500 kVA x 2). Agro Briquettes/Coal will be used as a fuel; and standby D.G. Set in which Diesel will be used as fuel. Process emission will be from the vents attached to Process Vessel of MPP-1, two vents of process vessel of MPP-2. Additionally, 6 nos. of Spin Flash Dryers are also considered as source of process emission. Main pollutant from

flue gas stack will be SPM, SO2, NOx, HCl, HBr and NH3 pollutants emit from process. Mitigation measures The entire flue gas stack, except stack of D.G. Set, will be equipped with Cyclone Separator and Bag Filter as APCM. Water, Acid and Alkali Scrubber will be provided on process gas stacks of MPP-1 & MPP-2. In- built cyclone & bag filter will be provided on Spin Flash Dryer. The details of process gas stacks with their APC measures & height are given in Table 2.8. 4.4.1 Air Pollution Dispersion Modeling of stack Following sub-section give air dispersion modeling details for prediction of changes in GLC of pollutants emitted from the above stacks. Objective: The objective of dispersion modeling is to predict the ground level concentration during the operation of the project and its impact on ambient air quality of the area concentrations and compare with applicable NAAQS.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-4 San Envirotech Pvt. Ltd., Ahmedabad Model used: The impact on air quality due to emissions from single source or group of sources is evaluated by use of mathematical models. The impacts of air pollutants were predicted using Gaussian air dispersion model, which is selected on the basis of existence of multiple point sources within the industrial complex and the plain terrain at the project site. In order to predict the impact of air pollutants on ambient air quality, ISCST3 model (Industrial Source Complex – Short Term (ISCST3) dispersion model) of United State Environmental Protection Agency (USEPA) was used by considering guidelines stipulated by CPCB for air pollution dispersion modeling. The Gaussian model provides estimates of pollutant concentrations at various receptor locations. It is an hour-by-hour steady state Gaussian model which takes into account the following:  Terrain adjustments  Stack-tip downwash  Gradual plume rise  Buoyancy-induced dispersion, and  Complex terrain treatment and consideration of partial reflection  Plume reflection off elevated terrain  Building down wash  Partial penetration of elevated inversions is accounted for Hourly source emission rates, exit velocity and stack gas temperature Only two stability conditions based on the meteorology aspects were used to calculate the theoretical maximum ground level concentration is comparing the actual data and data generated from mathematical modeling, it highlights that the stability condition E & A-B were predominant in the region. Following are the assumptions made while using the model: - No dry and wet depletion of pollutants - Receptors are on flat terrain

The key emitted pollutants will be SPM, SO2, NOx, HCl, HBr & NH3. 4.4.2 Micrometeorology Hourly micrometeorological data collected during the study period (October, 2020 to December, 2020) have been used for modeling.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-5 San Envirotech Pvt. Ltd., Ahmedabad The hourly wind speed, solar insolation & total cloudiness during day time and wind speed & total cloudiness during night time were used to determine the hourly atmospheric stability classes (defined by Pasquill and Gifford as A to F, A being most unstable and F being most stable). The hourly stability classes were determined based on the technique suggested by Turner. Turner’s system used for determining the stability classes is as follows: - For day or night: If total cloud cover (TC) = 10/10 and ceiling <7000 ft (2134 m), NR=0 - For night-time (defined as period from one hour before sunset to one hour after sunrise): a) If TC<4/10, use NR = -2 b) If TC>4/10, use NR = -1 - For daytime: determine isolation class number (IN) a) If TC<5/10, use NR=IN b) If TC>5/10, modify IN by the sum of the following applicable criteria If ceiling<7000 ft (2134 m), modification = -2 If ceiling>7000 ft but <16000 ft (4877 m), modification = -1 - If TC=10/10 and ceiling>7000 ft, modification = -1 and let modified value of IN=NR, except for day-time NR cannot be <+1. During the study period, stability calculated based on above-mentioned Turner method gives average stability as A-B class during Day time and E class during Night time. 4.4.3 Input data Stack emissions data have been used for prediction of incremental GLC

values of SPM, SO2, NOx, HCl, HBr & NH3 using one season meteorological data during (October, 2020 to December, 2020). Input data includes quantitative expected emission levels, temperature, and mixing height from the stack. Input data is given in Table 4.1. 4.4.4 Receptor Network Uniform polar grid and ambient air monitoring locations are considered as discrete Cartesian receptor network for entire study area of 10 km radius.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-6 San Envirotech Pvt. Ltd., Ahmedabad 4.4.5 Output of model (24-hourly GLCs) The 24-hourly average Ground Level Concentration (GLC) values from

project have been computed for SPM, SO2, NOx, HCl, HBr & NH3 considering topographical features around the plant & applicable stability classes. The maximum 50 (24-hr) average concentration values for SPM,

SO2, NOx, HCl, HBr & NH3 are given in Table 4.3 to 4.8. Corresponding Isopleths for 24-hourly predicted value is generated which is shown in Figure 4.1 to 4.6. It may be noted from the computed result for the proposed scenario that,

the highest 24-hourly average GLCs value of SPM, SO2 & NOx, from the proposed activity are 2.673 g/m3, 0.898 g/m3 and 0.986 g/m3. These GLCs are expected to occur at a distance of 1.0 km from the source in W direction. Whereas highest 24-hourly average GLCs value of HCl, HBr & 3 3 3 NH3 are 0.986 g/m , 0.040 g/m and 0.094 g/m respectively. These GLCs are expected to occur at a distance of 1.0 km from the source in S direction. With this marginal contribution due to the proposal of the project, the

levels of PM10, SO2 & NOx will remain well below the 24-hourly ambient 3 3 air quality standards for SO2 & NOx (80 g/m ), PM10 (100 g/m ), PM2.5 (60 g/m3) prescribed by CPCB. 4.4.6 Incremental & cumulative concentration of pollutants

The maximum incremental GLCs due to project for SPM, SO2, NOx, HCl,

HBr & NH3 is superimposed on the baseline concentrations recorded during the study period to arrive at the likely resultant concentrations after implementation of the proposed plant. The cumulative concentrations (baseline + incremental) of the project is tabulated below at Table 4.2. 4.4.7 Conclusion The modeling study proved that, the air emissions from the proposed activities would not likely to cause any significant impact on the ambient air quality of the study area. The ambient air quality around project site will remain within the National Ambient Air Quality Standards (NAAQS) prescribed for residential area.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-7 San Envirotech Pvt. Ltd., Ahmedabad 4.5 IMPACT ON WATER ENVIRONMENT The main sources of impact on water environment will be due to withdrawal of fresh water from the ground during construction and operation phase. These are discussed below. a. Construction Phase impacts & mitigation measures The water requirement for various purposes will be met from ground water. During construction work, water requirement is estimated to be about 30-50 KLD depending upon nature of construction work. In addition to this, about 1-2 KLD fresh water will be required for domestic activities of the construction staff which will also be met through the same source. There will be no wastewater generation from the construction work. Hence, it can be concluded that there will be no adverse impact during construction phase. b. Operational Phase impacts & mitigation measures Total water requirement (Industrial + Domestic + Greenbelt) of the unit will be 300 KLD; out of which 70 KLD will be fresh water requirement & 230 KLD will be recycle/treated water (ETP-RO permeate, MEE Condensate). Unit will satisfy its fresh water requirement from MPIDC. Major water demand will be for industrial – mainly Process (130 KLD), Washing (10 KLD), Scrubber (30 KLD) and Utility (100 KLD). Water requirement for Domestic will be 10 KLD and Greenbelt will be 15 KLD. Detailed breakup of each water consumption and water balance diagram is given in Table 2.5 and Figure 2.5, respectively. Sources of industrial effluent generation will be process; washing, cooling, scrubber, boiler blow down and cooling bleed off. Total industrial wastewater generation will be 242.7 KLD. The main source of the industrial wastewater generation will be from process (205 KLD), washing (15.0 KLD), Boiler Blow down (2.0 KLD), Cooling bleed off (15.0 KLD) and Scrubber (5.7 KLD). Domestic sewage generation will be 8.0 KLD. Total trade effluent (242.7 KLD) will be taken into ETP, after treatment, entire effluent will be passed through RO. RO permeate (170 KLD) will be reused within premises and RO reject will be sent to MEE/ATFD. MEE condensate (60 KLD) will be reused. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD).

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-8 San Envirotech Pvt. Ltd., Ahmedabad c. Impact Assessment As fresh water will be met from MPIDC water supply. Hence, insignificant impact envisage on ground water. Industry will develop rain water harvesting structures nearby project area. So, there will not be any major impact on the water environment due to proposed activities.

Mitigation Measures:  Minimum use of water will be done for construction phase.  Maximum reuse of water from MEE, RO during operational phase.  Regular maintenance of rainwater harvesting structure shall be done. 4.6 IMPACT ON NOISE ENVIRONMENT Any unwanted sound that creates disturbance in hearing is termed as Noise. Hence, it is important to assess present noise quality of the area in order to predict the potential impact of future noise levels due to project. a. Construction Phase Impact & mitigation measures During the construction phase at Orgosynth Chemicals Pvt. Ltd. impacts on noise level will occur due to the noise generation from new equipments/machineries as well as some impact due to transportation. Mainly the impacts of increased noise levels during construction are likely to occur due to increase movement of trucks & other diesel-powered material handling equipment. The impacts of noise during the construction would be restricted to the site only and will be temporary. PPEs like ear muff/ear plug will be provided to the workers. Regular maintenance & lubrication of construction equipment & machineries will be undertaken to reduce the noise generation. Thus, it is envisaged that the impacts on noise during the construction phase would be insignificant after mitigation measure. b. Operational Phase Impact & mitigation measures During operation of Orgosynth Chemicals Pvt. Ltd., noise levels will increase due to manufacturing process activities. The noise anticipated from the project will be confined only within plant boundary. Adequate greenbelt will be developed for prevention of noise propagation outside plant premises. Oiling/lubrication & preventive maintenance will be done to reduce noise generation at source to the permissible limit. However, at places where noise levels may exceed the limit, PPEs will be provided to

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-9 San Envirotech Pvt. Ltd., Ahmedabad workers. Adequate noise control measures such as silencers, anti- vibration pad etc. will be provided. All the equipment will be designed/ operated in such a way that the noise level in work place shall not exceed 85 dB(A) as per the OSHA Standard. During operation, the protective measures like PPEs (ear muff, ear plug) will be provided & the exposure duration of workers/other personnel to noise will be managed as per OSHA standard. The results of baseline monitoring carried out in the region are presented in Chapter-3. The results are below the standards prescribed for Industrial environment. It can be concluded that, the impact on noise environment will be long term but insignificant. 4.7 IMPACT ON LAND ENVIRONMENT The main source of impact on land and soil environment results due to construction activities and hazardous waste disposal. a. Construction Phase Impact & mitigation measures The construction activities like excavation, clearing, leveling & vehicular movements will entail change in the landscape, which are expected to be of short duration and insignificant. Unit will provide sanitation facilities for the staff engaged in construction work which will prevent the impacts on land. Thus, there will not be any issue of impacts on land during the construction phase. b. Operational Phase impact (Solid/Hazardous Waste) During the operation phase, it is identified that the impacts on land would occur due to the contamination by Solid/Hazardous wastes. The hazardous wastes are the major source of impacts on land. Hazardous waste generation from project must be considered to identify the potential impacts. At Orgosynth Chemicals Pvt. Ltd., entire quantity of the hazardous waste will be stored in the isolated hazardous waste storage area within premises having impervious platform having RCC floor, leachate collection system & roof cover and disposed as per the scientific method. Main source of hazardous waste generation will be ETP Waste, salt of MEE, Spent Sulphuric Acid (45-70%), Spent Hydrochloric Acid (25-28%), Hydrobromic Acid (25-28%), Acetic Acid (40-42%), Liq.

Ammonia, AlCl3 (30-35%), Used lubricating oil discarded drums/ containers/liners.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-10 San Envirotech Pvt. Ltd., Ahmedabad Mitigation Measures: Entire quantity of hazardous waste will be handled & disposed as per Hazardous & Other Waste (Management & Transboundary Movement) Rules, 2016. ETP sludge & MEE salt will be sent to TSDF site for land filling. Spent Sulphuric Acid, Spent Hydrochloric Acid and HBr will be partly reuse in-house and partly will be sold to actual users under Rule-9.

Acetic Acid and AlCl3 will be sold to actual users under Rule-9. Liq. Ammonia will be reused in-house in same or other products. Used lubricating oil will be used within premises or disposed by selling to registered re-processors and discarded barrels & liners will be disposed of by selling to registered recyclers. The unit will provide isolated area with impervious flooring & roof cover for the storage of hazardous waste. No adverse impact on the land environment is likely to occur. Hence, no significant negative impact is envisaged on the surrounding soil quality. 4.8 IMPACT ON BIOLOGICAL ENVIRONMENT a. Construction phase impact & mitigation measures This is a Greenfield project; hence minor cutting of trees/shrubs will be done to clean the area. However, it will be balanced by developing greenbelt within premises and along the roads. None of the plants are in the list of endangered plant species. Also, the trees are identified for their sensitivity & pollution tolerance capacity. This concept helps to plan the greenbelt of the area making it less polluted and a pollution absorber. Thus, it is envisaged that there will not be any adverse impacts on the ecology/biological environment in construction phase. b. Operational phase impact & mitigation measures There are no protected areas like national park/wildlife sanctuary within the 10 km radial of the project site, so there will not be any significant impact on ecology. No endangered floral or faunal species has been recorded within the study area. Further, unit will develop greenbelt to enhance the biological feature of the site. Also, the trees are identified for their sensitivity & pollution tolerance capacity. Following is the list of trees which are helpful as pollution absorber and at the same time pollution sensitive.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-11 San Envirotech Pvt. Ltd., Ahmedabad

Family Name Botanical Name Common Sensitive Tolerant Name Anacardiaceae Mangifera indica Mango Cement dust, Dust

Coal dust, SO2 collector

Anonaceae Polyalthialongifolia Asopalav SO2 Dust collector Caesalpini- Cassia fistula Garmalo Cement dust, N.A aceae Poor Dust

collector, SO2

Delonixregia Gulmohar SO2, Fly ash, N.A Cement dust

Meliaceae Azadirachtaindica Neem Cement dust SO2 Mimosaceae Pithecellobiumdulce Gorasamli N.A Better Dust collector,

SO2 There will not be any discharge of effluent from the unit. Entire quantity of hazardous waste will be handled & disposed as per Hazardous & Other Waste (Management & Transboundary Movement) Rules, 2016. Hence there will not be any impact on aquatic ecology of the surrounding area. GLCs of air pollutants will remain low and hence no significant impact on terrestrial ecology is expected. Thus, there will not be any significant impact on ecological environment due to proposed activities. 4.9 IMPACT ON SOCIO-ECONOMIC ENVIRONMENT a. Construction Phase Impacts & mitigation measures During the peak construction phase, construction manpower including construction workers will be employed. However, to the maximum extent possible, construction workers will be employed from within the study area. Since the construction phase of this project will be for short time period, the socio-economic impact due to construction of this project is going to be temporary. Around 30-50 workers will be employed in the construction work. This will increase construction employment in the study area. As the construction phase for the proposed project will be few months, the impact would be temporary. b. Operation Phase Impacts & mitigation measures The proposed unit will be located in private land, so no displacement of person is envisaged. Unit will provide employment opportunity to locally available skilled and un-skilled labors at different level as per the requirement, which in turn result into a positive impact on prevailing socio-economic environment. For the proposed activities, 100 nos. of

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-12 San Envirotech Pvt. Ltd., Ahmedabad workers will be employed. In addition, employment will be generated by the secondary supporting activities e.g. transportation, communication, daily utility services. Surrounding area has got good educational facilities and most of employees will come from the surrounding area. Thus, overall impacts on socio-economic environment are long term and positive in nature. 4.10 IMPACT ON OCCUPATIONAL HEALTH & SAFETY a. Construction Phase Impacts & mitigation measures In the Construction phase, some effects on occupational health & safety of the employees working in the site are envisaged. Major health issues encountered will be physical hazards & accidental hazards. All plans and construction schedule will be followed as per relevant laws approved by competent authority, so as to minimize the occupational health hazards. Mitigation Measures  Necessary PPEs like helmets, ear plug/ear muff, safety shoes, goggles etc. will be provided to workers.  Incident/accident reporting system will be developed and all the employees will be made aware for the same.  Periodic inspection & testing of equipment & machineries will be done. b. Operational Phase Impacts & mitigation measures In operational phase, various effects on occupational health and safety of the employees working in the plant are envisaged. Major health and safety issues encountered will be physical hazards, respiratory hazards, electrical hazards, noise, fire hazards associated while working within the plant. Preventive safety measures shall be taken to minimize the risk of accident with respect to chemical handling. Mitigation Measures  Emergency preparedness plan should be implemented.  First aid/other emergency treatment should be provided.  Workers shall be well equipped with personal protective equipment.  Only authorized persons will be allowed inside the plant.  Fire extinguishers will be installed at different locations within premises.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-13 San Envirotech Pvt. Ltd., Ahmedabad  A health monitoring program shall be in place to monitor the health of the persons working on the site to ensure the health status of all concerned.  Sign boards will be displayed at designated locations indicating appropriate hazard warnings.  Good housekeeping will be ensured within the factory premises. 4.11 IMPACT ON TRAFFIC MOVEMENT Raw materials, products & wastes will be transported in covered trucks by road. Avenue plantation will be developed on both sides of village road leading to the plant site. The traffic load is to be increased due to proposed project for the transportation of finished goods and raw materials. Baseline/Existing Traffic Scenario & Level of Services NH-26B @Borgaon point Road is 2 lanes with divider, all types of vehicles move on the road. Capacity of road as per IRC = 1500 PCU’s/hr. Total Volume during Peak Hours = 710 PCU’s/hr. (Table 3.27 – Chapter 3) Existing Volume/Capacity ratio = 710/1500 = 0.473 The level of service is “C” that is Good Additional traffic from our project will be estimated 45 PCU/day [15 trucks/tankers (in & out) x 3] and 40 PCU/day from car and motorcycle, which have insignificant impact on existing traffic load.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-14 San Envirotech Pvt. Ltd., Ahmedabad Table 4.1 Input data for air quality modeling

Sr. Stack attached to Stack Temp. Velocity Dia. Concentration No. Height (K) (m/s) (m) (g/s)

(m) SPM SO2 NOx 1. Steam Boiler 21 433 6.5 0.450 0.108 0.036 0.031 2. Thermic Fluid Heater 30 443 7.5 0.450 0.125 0.042 0.042 3. D G Set 11 483 15.0 0.225 0.039 0.018 0.024

4. Process Vessel MPP-1 11 328 5.5 0.225 NH3= 0.025 g/s 5. Process Vessel MPP-2 11 328 5.5 0.225 HCl= 0.003 g/s 6. Process Vessel MPP-2 11 328 5.5 0.225 HBr = 0.001 g/s 7. Spin Flash Dryer 21 338 6.5 0.225 SPM = 0.009 g/s

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-15 San Envirotech Pvt. Ltd., Ahmedabad Table 4.2 Cumulative Concentrations at various locations

Station Direction Dist. Baseline Predicted GLC Cumulative (Km) Concentration (g/m3) Concentration (g/m3) (g/m3)

PM SO2 NOx PM SO2 NOx PM SO2 NOx Project Site (A1) -- 00 71.3 14.5 20.9 0.5 0.1 0.2 71.8 14.6 21.1

Lodhikheda (A2) NNE (UW) 1.47 68.5 12.2 17.2 0.1 0.0 0.0 68.6 12.2 17.2

Borgaon (A3) NE(UW) 1.05 66.8 12.9 15.8 0.8 0.4 0.3 67.6 13.3 16.1

MPIDC (A4) E(UW) 1.12 64.3 11.2 15.1 1.1 0.4 0.4 65.4 11.6 15.5

Jamlapani (A5) WSW(DW) 0.95 63.4 10.7 15.6 0.1 0.2 0.8 63.5 10.9 16.4

Tinkheda (A6) SSW(DW) 1.80 61.3 11.0 15.4 2.0 0.6 0.7 63.3 11.6 16.1

Khaparkheda (A7) SW(DW) 7.2 64.4 10.7 15.0 0.5 0.1 0.1 64.9 10.8 15.1

Khairitaygaon (A8) SE(DW) 3.6 62.6 11.6 16.1 0.3 0.1 0.2 62.9 11.7 16.3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-16 San Envirotech Pvt. Ltd., Ahmedabad Table 4.3 The 24-hourly average GLC Concentration Values for SPM RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 2.673 ( -1000.00, .00) GC 26 1.613 ( -1000.00, -1000.00) GC 2 2.347 ( -1000.00, -1000.00) GC 27 1.545 ( -1000.00, 1000.00) GC 3 2.114 ( .00, -2000.00) GC 28 1.538 ( -2000.00, -5000.00) GC 4 2.064 ( -1000.00, -1000.00) GC 29 1.490 ( -1000.00, -1000.00) GC 5 2.052 ( .00, -1000.00) GC 30 1.488 ( -1000.00, .00) GC 6 2.039 ( .00, -1000.00) GC 31 1.470 ( -1000.00, .00) GC 7 2.024 ( .00, -1000.00) GC 32 1.442 ( -1000.00, -1000.00) GC 8 2.023 ( -2000.00, .00) GC 33 1.438 ( -2000.00, -2000.00) GC 9 1.979 ( 1000.00, -1000.00) GC 34 1.436 ( -2000.00, -5000.00) GC 10 1.972 ( .00, -1000.00) GC 35 1.436 ( -3000.00, .00) GC 11 1.949 ( -1000.00, .00) GC 36 1.431 ( -1000.00, -1000.00) GC 12 1.904 ( -1000.00, -1000.00) GC 37 1.418 ( -1000.00, .00) GC 13 1.852 ( -1000.00, -1000.00) GC 38 1.417 ( -1000.00, .00) GC 14 1.846 ( -1000.00, -1000.00) GC 39 1.416 ( -1000.00, 1000.00) GC 15 1.836 ( .00, -1000.00) GC 40 1.405 ( .00, -2000.00) GC 16 1.831 ( -2000.00, -2000.00) GC 41 1.403 ( .00, -4000.00) GC 17 1.828 ( -2000.00, .00) GC 42 1.402 ( -1000.00, 1000.00) GC 18 1.801 ( -1000.00, .00) GC 43 1.387 ( -3000.00, .00) GC 19 1.742 ( .00, -3000.00) GC 44 1.360 ( -1000.00, -1000.00) GC 20 1.736 ( -1000.00, -1000.00) GC 45 1.340 ( .00, -1000.00) GC 21 1.721 ( -1000.00, -1000.00) GC 46 1.323 ( -2000.00, .00) GC 22 1.703 ( .00, -2000.00) GC 47 1.320 ( -1000.00, .00) GC 23 1.687 ( .00, -2000.00) GC 48 1.313 ( -3000.00, -3000.00) GC 24 1.684 ( 1000.00, -1000.00) GC 49 1.308 ( .00, -3000.00) GC 25 1.673 ( .00, -2000.00) GC 50 1.288 ( -1000.00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-17 San Envirotech Pvt. Ltd., Ahmedabad

Table 4.4 The 24-hourly average GLC Concentration Values for SO2 RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 0.898 ( -1000.00, .00) GC 26 0.547 ( -1000.00, -1000.00) GC 2 0.787 ( -1000.00, -1000.00) GC 27 0.526 ( -2000.00, -5000.00) GC 3 0.716 ( .00, -2000.00) GC 28 0.520 ( -1000.00, 1000.00) GC 4 0.694 ( -1000.00, -1000.00) GC 29 0.505 ( -1000.00, -1000.00) GC 5 0.693 ( -2000.00, .00) GC 30 0.492 ( -3000.00, .00) GC 6 0.687 ( .00, -1000.00) GC 31 0.492 ( -2000.00, -2000.00) GC 7 0.676 ( 1000.00, -1000.00) GC 32 0.491 ( -2000.00, -5000.00) GC 8 0.675 ( .00, -1000.00) GC 33 0.490 ( -1000.00, .00) GC 9 0.666 ( .00, -1000.00) GC 34 0.488 ( -1000.00, .00) GC 10 0.662 ( .00, -1000.00) GC 35 0.481 ( .00, -2000.00) GC 11 0.649 ( -1000.00, -1000.00) GC 36 0.480 ( -1000.00, -1000.00) GC 12 0.637 ( -1000.00, .00) GC 37 0.479 ( .00, -4000.00) GC 13 0.630 ( -1000.00, -1000.00) GC 38 0.477 ( -1000.00, -1000.00) GC 14 0.627 ( -1000.00, -1000.00) GC 39 0.474 ( -3000.00, .00) GC 15 0.624 ( -2000.00, -2000.00) GC 40 0.472 ( -1000.00, 1000.00) GC 16 0.622 ( -2000.00, .00) GC 41 0.468 ( -1000.00, .00) GC 17 0.606 ( -1000.00, .00) GC 42 0.467 ( -1000.00, 1000.00) GC 18 0.593 ( .00, -3000.00) GC 43 0.463 ( -1000.00, .00) GC 19 0.592 ( -1000.00, -1000.00) GC 44 0.460 ( -1000.00, -1000.00) GC 20 0.589 ( .00, -1000.00) GC 45 0.453 ( -2000.00, .00) GC 21 0.584 ( -1000.00, -1000.00) GC 46 0.451 ( .00, -1000.00) GC 22 0.578 ( .00, -2000.00) GC 47 0.449 ( -3000.00, -3000.00) GC 23 0.575 ( .00, -2000.00) GC 48 0.447 ( .00, -3000.00) GC 24 0.574 ( 1000.00, -1000.00) GC 49 0.442 ( -1000.00, .00) GC 25 0.573 ( .00, -2000.00) GC 50 0.437 ( -2000.00, .00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-18 San Envirotech Pvt. Ltd., Ahmedabad Table 4.5 The 24-hourly average GLC Concentration Values for NOx RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 0.986 ( -1000.00, .00) GC 26 0.580 ( -1000.00, -1000.00) GC 2 0.851 ( -1000.00, -1000.00) GC 27 0.565 ( -1000.00, 1000.00) GC 3 0.759 ( .00, -1000.00) GC 28 0.541 ( -2000.00, -5000.00) GC 4 0.754 ( .00, -2000.00) GC 29 0.540 ( -1000.00, -1000.00) GC 5 0.750 ( -1000.00, -1000.00) GC 30 0.539 ( -1000.00, .00) GC 6 0.742 ( .00, -1000.00) GC 31 0.533 ( -1000.00, .00) GC 7 0.732 ( -2000.00, .00) GC 32 0.523 ( -1000.00, .00) GC 8 0.726 ( .00, -1000.00) GC 33 0.519 ( -1000.00, -1000.00) GC 9 0.726 ( 1000.00, -1000.00) GC 34 0.516 ( -2000.00, -2000.00) GC 10 0.726 ( .00, -1000.00) GC 35 0.515 ( -1000.00, -1000.00) GC 11 0.713 ( -1000.00, .00) GC 36 0.515 ( -3000.00, .00) GC 12 0.696 ( -1000.00, -1000.00) GC 37 0.512 ( -1000.00, .00) GC 13 0.678 ( -1000.00, -1000.00) GC 38 0.510 ( -1000.00, 1000.00) GC 14 0.676 ( -1000.00, -1000.00) GC 39 0.508 ( .00, -2000.00) GC 15 0.662 ( -1000.00, .00) GC 40 0.506 ( -2000.00, -5000.00) GC 16 0.661 ( -2000.00, .00) GC 41 0.505 ( -1000.00, 1000.00) GC 17 0.660 ( .00, -1000.00) GC 42 0.498 ( -1000.00, -1000.00) GC 18 0.651 ( -2000.00, -2000.00) GC 43 0.498 ( -3000.00, .00) GC 19 0.636 ( -1000.00, -1000.00) GC 44 0.496 ( .00, -1000.00) GC 20 0.632 ( -1000.00, -1000.00) GC 45 0.492 ( .00, -4000.00) GC 21 0.617 ( 1000.00, -1000.00) GC 46 0.478 ( -2000.00, .00) GC 22 0.615 ( .00, -3000.00) GC 47 0.468 ( .00, -3000.00) GC 23 0.614 ( .00, -2000.00) GC 48 0.466 ( -1000.00, -1000.00) GC 24 0.610 ( .00, -2000.00) GC 49 0.464 ( -2000.00, .00) GC 25 0.606 ( .00, -2000.00) GC 50 0.463 ( -3000.00, -3000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-19 San Envirotech Pvt. Ltd., Ahmedabad Table 4.6 The 24-hourly average GLC Concentration Values for HCl RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 0.119 ( .00, -1000.00) GC 26 0.057 ( -1000.00, 1000.00) GC 2 0.113 ( -1000.00, .00) GC 27 0.056 ( .00, -1000.00) GC 3 0.111 ( -1000.00, .00) GC 28 0.052 ( -1000.00, -1000.00) GC 4 0.103 ( .00, -1000.00) GC 29 0.052 ( 1000.00, -1000.00) GC 5 0.098 ( .00, -1000.00) GC 30 0.051 ( -2000.00, .00) GC 6 0.094 ( .00, -1000.00) GC 31 0.051 ( 1000.00, .00) GC 7 0.090 ( -1000.00, -1000.00) GC 32 0.050 ( -1000.00, .00) GC 8 0.077 ( .00, -1000.00) GC 33 0.049 ( 1000.00, .00) GC 9 0.077 ( -1000.00, .00) GC 34 0.049 ( -2000.00, .00) GC 10 0.075 ( -1000.00, .00) GC 35 0.048 ( -1000.00, -1000.00) GC 11 0.075 ( -1000.00, -1000.00) GC 36 0.048 ( .00, -2000.00) GC 12 0.074 ( -1000.00, .00) GC 37 0.046 ( -1000.00, -1000.00) GC 13 0.074 ( -1000.00, .00) GC 38 0.045 ( -1000.00, -1000.00) GC 14 0.065 ( -1000.00, .00) GC 39 0.044 ( .00, -2000.00) GC 15 0.061 ( 1000.00, .00) GC 40 0.043 ( -1000.00, -1000.00) GC 16 0.060 ( -1000.00, -1000.00) GC 41 0.043 ( -1000.00, 1000.00) GC 17 0.059 ( -1000.00, 1000.00) GC 42 0.041 ( .00, -2000.00) GC 18 0.059 ( 1000.00, -1000.00) GC 43 0.040 ( -1000.00, -1000.00) GC 19 0.059 ( -1000.00, -1000.00) GC 44 0.039 ( -1000.00, -1000.00) GC 20 0.058 ( -1000.00, 1000.00) GC 45 0.039 ( -1000.00, 1000.00) GC 21 0.058 ( -1000.00, -1000.00) GC 46 0.038 ( -2000.00, -2000.00) GC 22 0.058 ( -1000.00, -1000.00) GC 47 0.038 ( -1000.00, 1000.00) GC 23 0.058 ( -1000.00, -1000.00) GC 48 0.038 ( -1000.00, .00) GC 24 0.058 ( .00, -2000.00) GC 49 0.038 ( 1000.00, .00) GC 25 0.057 ( -1000.00, -1000.00) GC 50 0.037 ( .00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-20 San Envirotech Pvt. Ltd., Ahmedabad Table 4.7 The 24-hourly average GLC Concentration Values for HBr RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 0.040 ( .00, -1000.00) GC 26 0.019 ( -1000.00, 1000.00) GC 2 0.038 ( -1000.00, .00) GC 27 0.019 ( .00, -1000.00) GC 3 0.037 ( -1000.00, .00) GC 28 0.017 ( -1000.00, -1000.00) GC 4 0.034 ( .00, -1000.00) GC 29 0.017 ( 1000.00, -1000.00) GC 5 0.033 ( .00, -1000.00) GC 30 0.017 ( -2000.00, .00) GC 6 0.031 ( .00, -1000.00) GC 31 0.017 ( 1000.00, .00) GC 7 0.030 ( -1000.00, -1000.00) GC 32 0.017 ( -1000.00, .00) GC 8 0.026 ( .00, -1000.00) GC 33 0.016 ( 1000.00, .00) GC 9 0.026 ( -1000.00, .00) GC 34 0.016 ( -2000.00, .00) GC 10 0.025 ( -1000.00, .00) GC 35 0.016 ( -1000.00, -1000.00) GC 11 0.025 ( -1000.00, -1000.00) GC 36 0.016 ( .00, -2000.00) GC 12 0.025 ( -1000.00, .00) GC 37 0.015 ( -1000.00, -1000.00) GC 13 0.025 ( -1000.00, .00) GC 38 0.015 ( -1000.00, -1000.00) GC 14 0.022 ( -1000.00, .00) GC 39 0.015 ( .00, -2000.00) GC 15 0.020 ( 1000.00, .00) GC 40 0.014 ( -1000.00, -1000.00) GC 16 0.020 ( -1000.00, -1000.00) GC 41 0.014 ( -1000.00, 1000.00) GC 17 0.020 ( -1000.00, 1000.00) GC 42 0.014 ( .00, -2000.00) GC 18 0.020 ( 1000.00, -1000.00) GC 43 0.013 ( -1000.00, -1000.00) GC 19 0.020 ( -1000.00, -1000.00) GC 44 0.013 ( -1000.00, -1000.00) GC 20 0.019 ( -1000.00, 1000.00) GC 45 0.013 ( -1000.00, 1000.00) GC 21 0.019 ( -1000.00, -1000.00) GC 46 0.013 ( -2000.00, -2000.00) GC 22 0.019 ( -1000.00, -1000.00) GC 47 0.013 ( -1000.00, 1000.00) GC 23 0.019 ( -1000.00, -1000.00) GC 48 0.013 ( -1000.00, .00) GC 24 0.019 ( .00, -2000.00) GC 49 0.013 ( 1000.00, .00) GC 25 0.019 ( -1000.00, -1000.00) GC 50 0.012 ( .00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-21 San Envirotech Pvt. Ltd., Ahmedabad

Table 4.8 the 24-hourly average GLC Concentration Values for NH3 RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE 1 0.988 ( .00, -1000.00) GC 26 0.478 ( -1000.00, 1000.00) GC 2 0.941 ( -1000.00, .00) GC 27 0.470 ( .00, -1000.00) GC 3 0.927 ( -1000.00, .00) GC 28 0.433 ( -1000.00, -1000.00) GC 4 0.860 ( .00, -1000.00) GC 29 0.431 ( 1000.00, -1000.00) GC 5 0.816 ( .00, -1000.00) GC 30 0.425 ( -2000.00, .00) GC 6 0.781 ( .00, -1000.00) GC 31 0.423 ( 1000.00, .00) GC 7 0.747 ( -1000.00, -1000.00) GC 32 0.420 ( -1000.00, .00) GC 8 0.642 ( .00, -1000.00) GC 33 0.407 ( 1000.00, .00) GC 9 0.641 ( -1000.00, .00) GC 34 0.405 ( -2000.00, .00) GC 10 0.629 ( -1000.00, .00) GC 35 0.399 ( -1000.00, -1000.00) GC 11 0.625 ( -1000.00, -1000.00) GC 36 0.397 ( .00, -2000.00) GC 12 0.614 ( -1000.00, .00) GC 37 0.380 ( -1000.00, -1000.00) GC 13 0.613 ( -1000.00, .00) GC 38 0.374 ( -1000.00, -1000.00) GC 14 0.543 ( -1000.00, .00) GC 39 0.369 ( .00, -2000.00) GC 15 0.504 ( 1000.00, .00) GC 40 0.361 ( -1000.00, -1000.00) GC 16 0.497 ( -1000.00, -1000.00) GC 41 0.361 ( -1000.00, 1000.00) GC 17 0.496 ( -1000.00, 1000.00) GC 42 0.344 ( .00, -2000.00) GC 18 0.494 ( 1000.00, -1000.00) GC 43 0.334 ( -1000.00, -1000.00) GC 19 0.491 ( -1000.00, -1000.00) GC 44 0.327 ( -1000.00, -1000.00) GC 20 0.485 ( -1000.00, 1000.00) GC 45 0.324 ( -1000.00, 1000.00) GC 21 0.483 ( -1000.00, -1000.00) GC 46 0.320 ( -2000.00, -2000.00) GC 22 0.483 ( -1000.00, -1000.00) GC 47 0.317 ( -1000.00, 1000.00) GC 23 0.482 ( -1000.00, -1000.00) GC 48 0.314 ( -1000.00, .00) GC 24 0.481 ( .00, -2000.00) GC 49 0.313 ( 1000.00, .00) GC 25 0.479 ( -1000.00, -1000.00) GC 50 0.305 ( .00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-22 San Envirotech Pvt. Ltd., Ahmedabad Figure 4.1: Isopleths for Ground Level Concentrations for SPM 10000

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-23 San Envirotech Pvt. Ltd., Ahmedabad

Figure 4.2: Isopleths for Ground Level Concentrations for SO2

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-24 San Envirotech Pvt. Ltd., Ahmedabad Figure 4.3: Isopleths for Ground Level Concentrations for NOx 10000

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-25 San Envirotech Pvt. Ltd., Ahmedabad Figure 4.4: Isopleths for Ground Level Concentrations for HCl 10000

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-26 San Envirotech Pvt. Ltd., Ahmedabad Figure 4.5: Isopleths for Ground Level Concentrations for HBr 10000

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-27 San Envirotech Pvt. Ltd., Ahmedabad

Figure 4.6: Isopleths for Ground Level Concentrations for NH3 10000

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Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 4-28 San Envirotech Pvt. Ltd., Ahmedabad Chapter-5 Analysis of Alternatives

5.1 PROLOGUE Alternative analysis is the process of analyzing the proposed locating for suitability for basic necessities to operate the plant safely, this analysis also covers the environmental aspect of pollution prevention and improvement in quality of life nearby the project vicinity. The project alternative is the course of action in pace of another, that would meet the same purpose and need, but which would avoid or minimize negative impacts and enhance project benefits. Such projects may result in specific impacts which can be avoided or mitigated by adherence to certain predetermined performance standards, guidelines or design criteria. Alternative approaches may therefore be more effective in integrating environmental and social concerns into the project planning process. 5.2 SITE ALTERNATIVE M/s. Orgosynth Chemicals Pvt. Ltd. is a Greenfield project; propose to set up Various Dye Intermediates manufacturing unit at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center, Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Total production capacity of the plant will be tune around 3049 MT/Month. The area of the plot (17432 m2) is sufficient for proposed activities to be carried out. Required facilities like infrastructure, communication, medical facilities, fuel, water, power, unskilled & skilled manpower, raw materials, road network etc. are readily available, too. There is no Rehabilitation and Resettlement involved. Nearest town Sausar is about 9.5 km and nearest city Chhindwara is about 55.6 km away from the site which is having connectivity with other parts of the country by road, rail & air. Therefore, no other site or area was considered.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 5-1 San Envirotech Pvt. Ltd., Ahmedabad 5.3 PROCESS ALTERNATIVE Production Technology Orgosynth Chemicals Pvt. Ltd. will have a team of scientists engaged in R&D activities. Proposed technology of production is result of R&D and no alteration is currently with the proponent. Wastewater Treatment Technology The wastewater will be generated from process; washing, cooling, scrubber and utility. After treatment, effluent passed through RO. RO reject will be evaporated in MEE. RO permeate and condensate of MEE will be reused within premises. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD). Unit will built full-fledged ETP to treat w/w generated from proposed project. Such ETP will be able to achieve zero discharge of liquid effluent and no alternative technology for effluent treatment will be required. Domestic wastewater will be disposed in soak pit. Thus proven, most feasible and best available technology will be used for wastewater management and no other alternatives are with the proponent. Air Pollution Control Technology Flue gas emission is due to the combustion of fuel Agro Briquettes/Coal in Boiler, Thermic Fluid Heater. Cyclone & bag filter will be installed as APCM for each flue gas emission source. Process gas emission will be from the stack attached to process reactors and vent of Spin Flash Dryer. To control the process emission, Water, Acid and Alkali scrubbers will be provided. Thus proven, most feasible and best available technology will be used for Air Pollution Control and no other alternatives are currently with the proponent. Whereas, in built cyclone and will be provided for Spin Flash Dryer. Such APCM will limit the emissions of pollutant to the regulatory permissible limits and no alternative APCM technology will be required.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 5-2 San Envirotech Pvt. Ltd., Ahmedabad Chapter-6 Environmental Monitoring Programme

6.1 PRELUDE Environment monitoring is the sampling and analysis tool to know the environment conditions at particular time. The record of environmental monitoring is most important as the environmental changes are slow in nature and impact appears after many years. Environmental Monitoring is the technical heart of assessment of environmental and social impacts arising due to implementation of the proposed project. An equally essential element of this process is to develop measures to eliminate, offset or reduce impacts to acceptable levels during implementation and operation of projects. The integration of such measures into project implementation and operation is supported by clearly defining the environmental requirements within an Environmental Management Plan. Orgosynth Chemicals Pvt. Ltd. proposed to manufacture Dye Intermediates with production capacity of 3049 MT/month. The environmental monitoring programme is developed as below. 6.2 ENVIRONMENT MONITORING PROGRAM The periodical monitoring of environmental parameters like air, water, noise, soil and performance of pollution control facilities and safety measures in the plant are vital for proper environmental management of any industrial project. Therefore, the company shall create environmental monitoring facilities by the environmental and safety department to monitor air and water pollutants as per the guideline of SPCB & CPCB. Moreover, air and water quality shall be monitored by outside agencies authorized by SPCB at regular frequencies. This department shall also carry out periodical checkup of fire and safety equipments. 6.3 OBJECTIVE OF MONITORING PLAN The basic objective of implementing a monitoring plan on a regular basis is as follows:  To know the pollution status within the plant and its vicinity.  Generate data for corrective action in respect of pollution.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 6-1 San Envirotech Pvt. Ltd., Ahmedabad  Correlate the production operations with emission & control mechanism.  Examine the performance of pollution control system.  Assess the Environmental impacts.  Remedial measures and environment management plant to reverse the impacts. 6.4 SCHEDULE FOR ENVIRONMENT MONITORING The environmental monitoring will be scheduled on regular interval to assess the conditions. The record of these monitoring will be compared with the baseline study to know the changes in environmental conditions. The post-project environmental monitoring suggested herewith should be as per the following guideline. The highlights of the integrated environmental monitoring plan are:  The stack monitoring facilities like ladder, platform and porthole at all the stacks will be maintained in good condition.  Regular monitoring of all gaseous emissions from stacks/vents.  The performance of air pollution control equipment evaluated based on these monitoring results.  Water consumption will be recorded daily.  As far as possible, noise curbed at its source, with the help of acoustic hoods and other such noise reducing equipment. Regular noise level monitoring will be carried out.  Greenbelt will be properly maintained and new plantation programmes will be undertaken frequently.  Continuous environmental awareness programmes will be carried out for the employees and also in the surrounding villages. 6.5 AMBIENT AIR QUALITY MONITORING Flue gas emission will be due to the combustion of fuel Agro Briquettes/ Coal in Boiler & Thermic Fluid Heater and HSD in Stand by D. G. Set. Cyclone separator followed by bag filter will be installed as APCM for each flue gas stacks. Process gas emission will be from the stack attached with vents of MPP-1, MPP-2 and vents of Spin Flash Dryer. Process stack will be installed with Water Scrubber, Acid Scrubber and Alkali scrubber to

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 6-2 San Envirotech Pvt. Ltd., Ahmedabad achieve the emission standards, whereas to control particulate emission, In-built bag filter will be installed as APCM on Spin Flash Dryer. Scheme for monitoring ambient air quality, stack emissions and fugitive emissions are proposed. The ambient air quality monitoring systems are recommended for monitoring the ground level concentrations and fugitive emissions around the plant. Unit should install three monitoring stations 0 around its battery limit (at 120 as per guideline) for monitoring PM, SO2 and NOx. The combined data will provide overall characteristic and emission from the industry. Besides this, stack emissions monitoring as per SPCB guidelines shall be carried out. Proposed monitoring schemes are mentioned in Table 6.1. 6.6 WATER ENVIRONMENT MONITORING Sources of industrial effluent generation will be from process, washing, scrubber and utilities. Total trade effluent (242.7 KLD) will be taken into ETP, after treatment, entire effluent will be passed through RO. RO permeate (170 KLD) will be reused within premises and RO reject will be sent to MEE/ATFD. MEE condensate (60 KLD) will be reused. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD). Sewage (8.0 KLD) will be disposed into soak pit though septic tank. The detail of water usage and wastewater generation is provided comprehensively in Chapter 2. Proposed monitoring schemes are mentioned in Table 6.1. 6.7 NOISE ENVIRONMENT MONITORING Main source of noise generation will be Boiler, TFH, D.G. Set, process plant, vehicular transportation & other machineries. Monitoring of noise levels is essential to assess the efficacy of maintenance schedules undertaken to reduce noise levels and noise protection measures. A good quality digital sound pressure level meter is essential for this purpose. Proposed monitoring schemes are mentioned in Table 6.1.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 6-3 San Envirotech Pvt. Ltd., Ahmedabad Table: 6.1 Environment Monitoring Plan Nature of Frequency of Parameters No. of Method of Analysis analysis with its samples Monitoring analyzer Wastewater Monthly by pH, TDS, SS, 4-6 samples APHA-AWWA analysis external agency COD, BOD, Oil 23rd edition & Grease, etc.

Stack Monthly by PM, SO2, NOX, All stacks Stack Monitoring of external agency HCl, HBr, NH3 monitoring each stack kit

Ambient Air Monthly for 24 PM10, PM2.5, 3-5 locations RDS, Fine Quality hours or as per SO2, NOx, HCl, particulate Monitoring the statutory HBr, NH3 sampler conditions by external agency Noise level Monthly as per Noise level 6-8 locations Sound Level the statutory (Nr. Main gate, Meter conditions by Nr. boiler, Nr. external agency D. G. Set, Process area) Work zone Monthly by RPM, VOCs, 2-3 locations Personal fugitive external agency acid mist sampler, monitoring VOC sampler Health As per the All workers check-up of statutory workers guideline Rs. 5.0 Lakhs is allocated for Environment Monitoring.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 6-4 San Envirotech Pvt. Ltd., Ahmedabad Chapter-7 Additional Studies This chapter contains information of Public Hearing, various risks associated during operational stage of the project, disaster management plan to minimize the risks, onsite & offsite emergency plan and Occupational health & Safety. Social Impact Assessment is part of this chapter. A. PUBLIC CONSULTATION The Public Hearing for proposed project of M/s. Orgosynth Chemicals Pvt. Ltd. to be located at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center, Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh was conducted by MPPCB on 28.06.2021 as per the EIA Notification, 2006 and its amendment therein. 78 people have attended the Public Hearing. Details of Public Hearing are summarized in Table 7.1. The Public Hearing Proceeding is attached as Annexure-VIII. Summary of issues raised during Public Hearing and action plan with budgetary provision is given in Table 7.2. Table 7.1 Public Hearing Details

Particular Description

Date of Public Hearing 28.06.2021 at 12:00 hrs Date of Advertisement 17.06.2021 in Newspapers Name of Newspapers The Times of India, Dainik Patrika Venue of Public Hearing At Project site, M/s. Orgosynth Chemicals Pvt. Ltd., Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh Designation of Presiding Additional District Magistrate, Chhindwara and Officer Regional Officer, MPPCB, Chhindwara Nos. of Attendee 78 Participants

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-1 San Envirotech Pvt. Ltd., Ahmedabad

Figure 7.1: Photographs of Public Hearing

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-2 San Envirotech Pvt. Ltd., Ahmedabad

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-3 San Envirotech Pvt. Ltd., Ahmedabad

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-4 San Envirotech Pvt. Ltd., Ahmedabad

Table 7.2 Issues Raised during Public Hearing and Action Plan with Budgetary Provision Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation Issues Raised during Public Hearing 1. Shri Suresh The polluted water of company We will not discharging any Unit will install Unit has Dhete should be clean so that there is no polluted water outside the plant. ETP, MEE along earmark Rs. 85 Boregaon harm to their domestic animals with Lakhs as Capital and birds. construction of fund and Rs. project work to 135 Lakhs as achieve ZLD recording amount per year. 2. Shri Pratik 1) Chemical From M/s. Orgosynth 1) We will be installing necessary EMS is part of Unit has Chourase Chemical Pvt Ltd. should not pollution control equipments Project and earmark Rs. 184 Boregaon pollute more. like ETP, MEE, Bag filter, etc. implementation Lakhs as Capital and operation of factory will be of EMS start fund and Rs. as per the norms of along with 237 Lakhs as Environment Act. project work. recording amount per year.

2) Employment should be from 2) We will have around 100 Employment Salary will be local village. workers. They will be appointed starts with more than the as per the qualification/Skills project minimum wages requirement from local village implementation. fixed by concern i.e. 90% employment will be authorities. from Chhindwara District.

3) M/s. Orgosynth Chemical Pvt. 3) We will be utilizing 33% of the Greenbelt Unit has Ltd. has to make more tree plot area for development of development earmark Rs. 3.0 plantation for controlling green belt. Also will do required start with Lakhs as Capital

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-5 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation pollution and to make garden plantation outside of the plant. project fund and Rs. 0.5 all around plant. implementation Lakhs as and continuous recording up to five year amount per year till achieve for greenbelt target. development.

4) Due to Orgosynth Chemicals 4) We will be taking electricity ------the village electricity center through Industrial feeder from should not face any problem. MPSEB and it is an industrial area. Hence there will be no problem to electricity supply to village due to our company.

5) Due to M/s. Orgosynth 5) We will not be discharging any Implementation Unit has Chemical Pvt Ltd. there shoud polluted water outside our of EMS starts earmark Rs. 184 not be any damage to farmers plant. Hence there will be no along with Lakhs as Capital and their fields. damage. project work. fund and Rs. 237 Lakhs as recording amount per year. 6) If any accident happens in M/s. 6) We will be operating plant with Safety is part of Unit has Orgosynth Chemical Pvt Ltd. safety and safety will be safe industrial earmark Rs. 5.0 they have to take care of followed as per norms of operation and Lakhs as Capital safety. factory Act. start along with for PPE and construction safety systems 7) Those workers working in 7) All workers will be provided work. and Rs. 2.0 chemicals should be provided personal safety equipment‟s as Lakhs as with safety shoes. per the Factory Act like safety recording

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-6 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation goggles, shoes, masks, etc. amount per year. 3. Dr. Shyam Maintain sustainability of Project Proponent has welcomed Employment Salary will be Kshirsagar, Environment and give priority to their suggestion and assures to starts with more than the Borgaon local people for employment. Dr. provide employment to around 100 project minimum wages Joshi has helped during Covid persons as per Rules. implementation. fixed by concern Vaccination and doing appreciated authorities. work. We have demanded for giving employment to youth. 4. Shri Piyush What is the purpose of arranging Regional Officer Dr. Avinash -- -- Chorase, this Public Hearing? What will be Chandra Karera has given the Borgaon the arrangement make for any information regarding purpose of accident, if occur in in future? this Public Hearing and Mrs. Rani Batad, ADM has given information related to Labor Laws. 5. Shri Dayaram Mentioned the phone number in Project Proponent has agreed for -- -- Soni, Deputy sign board of the unit and arrange the same. Sarpanch plantation programme. Borgaon 6. Shri Prabhakar The polluted water from the We will be installing necessary Implementation Unit has Bobde, factory should treated and made it pollution control equipment‟s like of EMS starts earmarked Rs. Borgaon clean. Local employment should ETP, MEE, Bag Filters, etc. and along with 184 Lakhs as be given and tree plantation to be operation of factory will be as per project work. Capital fund and done. the norms of Environment Act. The Rs. 237 Lakhs as treated water will be recycled for recording use in our own process. There will amount per be no discharge of pollution water. year. We will have around 100 workers. Greenbelt Unit has They will be appointed as per the development earmark Rs. 3.0 qualification/Skills requirement start with Lakhs as Capital

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-7 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation from local villages i.e. 90% project fund and Rs. 0.5 employment will be from implementation Lakhs as Chhindwara District. Necessary and continuous recording tree plantation will be done. up to five year amount per year till achieve for greenbelt target. development. 7. Shri Pankaj Employment should be given to Employment will be given to local Greenbelt Unit has Datarkar, locals, Tree plantation work should people as per their eligibility & development earmark Rs. 3.0 Borgaon be done and maintain the same. skill. Mango and Neem trees will be start with Lakhs as Capital planted as per the schedule of project fund and Rs. 0.5 greenbelt development plan. implementation Lakhs as and continuous recording up to five year amount per year till achieve for greenbelt target. development. Written representation received before/during Public Hearing 1. Shri Pratik This person has already represented their view during the public hearing as per written Chourase representation and addresses above vide sr. no. 2. Boregaon 2. Shri Shailendra My suggestion is that due to this We will have around 100 workes. Employment Salary will be Dahiwale plant, there will be pollution, They will be appointed as per the starts with more than the Boregaon hence village Boregaon should get qualification/Skills requirement project minimum wages 25% employment in your factory. from local village i.e. 90% implementation. fixed by concern employment will be from authorities. Chhindwara District. We will be Installing necessary pollution control equipment‟s and operation of factory will be as per the norms of Environment Act.

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Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation 3. Shri Domaji 1) From our village Boregaon 1) We will have around 100 Employment Salary will be Somkunwar Company should take 25% workers. They will be appointed starts with more than the G.P. Boregaon workers as per their as per the qualification/skills project minimum wages qualification. requirement from local villages implementation. fixed by concern i.e. 90% employment will be authorities. from chhindwara District. 2) To keep Boregaon green and 2) We will be planting the tree Greenbelt Unit has healthy, the tree plantation every year in adjacent area and development earmark Rs. 3.0 should be done yearly and as well as in factory area. We start with Lakhs as Capital plants care to be taken (like will help in preserving these project fund and Rs. 0.5 watering/jail) plants. implementation Lakhs as and continuous recording up to five year amount per year till achieve for greenbelt target. development. 4. Shri Keshavrao This industry will be helpful for Due to our industry there will be -- -- Tajne, every one. Economical development and Boregaon employment generation. Local villagers will be benefitted directly and indirectly. 5. Shri. U.B. After discussion on the above We will be installing necessary -- -- Chipade, subject this industry will make pollution control equipment‟s like Boregaon chemical and pharma ETP, MEE, Bag Filters, etc. and intermediates and is presented for operation of factory will be as per Environment clearance. As both the norms of Environment Act. these items are helful for hummanity it is also necessary to control pollution for human health. 6. Dr. Sevakram This company will be making raw We will have around 100 workers. Implementation Unit has Game material for other manufacturing They will be appointed as per the of EMS starts earmark Rs. 184

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-9 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation Boregaon company. The company should qualification/skills requirement along with Lakhs as Capital provide employment to from local villages i.e. 90% project work. fund and Rs. unemployed people from boregaon empolyment will be installing 237 Lakhs as village and company will take care necessary pollution control recording of pollution. equipment‟s like ETP, MEE, Bag amount per filters, etc. and operation of year. factory will be as per the norms of Environment Act. 7. Shri Dinesh In today‟s scenario unemployment We will be installing necessary -- -- Janglyaji is a big problem. This factory will pollution control equipment‟s like Shende give local employment. ETP, MEE, Bag Filters, etc. and Lodhikheda This factory will help operation of factory will be as per grampanchayat. the norms of Environment Act. We will give help to Grampanchayat as per the rule regulation and time as per the requirement. 8. Shri Ashok In our village unqualified people We will have around 100 workers. Employment Salary will be Shankarrao from poor family is struggling due They will be appointed as per the starts with more than the Gohatre, Ward to unemployment. Such persons qualification/Skills requirement project minimum wages No. 17 should be given employment. from local village i.e. 90% implementation. fixed by concern Paradsinga employment will be from authorities. Chhindwara District. 9. Sri Atul Looking to the environment We will be installing necessary Greenbelt Unit has Hemrajji Barde problem more tree plantation to pollution control equipment‟s like development earmark Rs. 3.0 Kabarpipla be done and prevent pollution. ETP, MEE, Bag Filters, etc. and start with Lakhs as Capital Provide employment to operation of factory will be as per project fund and Rs. 0.5 unemployed person. the norms of Environment Act. implementation Lakhs as Every year we will carry out tree and continuous recording plantation. up to five year amount per year

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-10 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation We will have around 100 workers. till achieve for greenbelt They will be appointed as per the target. development. qualification/Skills requirement from local village i.e. 90% employment will be from Chhindwara District. 10. Shri Mahesh Unemployment is a big problem We will have around 100 workers. Employment Salary will be Gendlaji Bobde due to Corona. Due to this local They will be appointed as per the starts with more than the Boregaon people should be given qualification/skills requirement project minimum wages employment. Help should be given from local villages i.e. 90% implementation. fixed by concern to Grampanchayat. employment will be from authorities. Chhindwara District. We will give help to Greenbelt Unit has Looking to environment more grampanchayat as per the rules development earmark Rs. 3.0 plantation to be done and regulation and time to time as start with Lakhs as Capital per the requirement. project fund and Rs. 0.5 implementation Lakhs as We will be utilizing 33% of our plot and continuous recording area for development of green up to five year amount per year belt. Also will do required till achieve for greenbelt plantation outside of the plant target. development. also. 11. Mr. Vishal Employment should be given to We will have around 100 workers. Employment Salary will be Pandurangji local people. They will be appointed as per the starts with more than the Gajbhiye qualification/ Skills requirement project minimum wages Tinkheda from local villages i.e. 90% implementation. fixed by concern employment will be from authorities. Chhindwara District. We will be utilizing 33% of the plot area for development of green

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-11 San Envirotech Pvt. Ltd., Ahmedabad

Sr. Name & Points represented Reply from project proponent Action Plan Budget No. Address Allocation belt. Also will do required plantation outside of the plant also. 12. Shri Suresh This person has already represented their view during the public hearing as per written Dhete representation and address above vides sr. no. 1. Boregaon 13. Shri Shankar We welcome the opening of We will have around 100 workers. Employment Salary will be Katole company. However looking to the They will be appointed as per the starts with more than the pollution company should see qualification/ Skills requirement project minimum wages that/ there should not be any from local villages i.e. 90% implementation. fixed by concern accident and local employment employment will be from authorities. should be given Chhindwara District. Pollution norms will be maintained and all safety precautions will be taken as per the Factory Act. 14. Shri Prabhakar This person has already represented their view during the public hearing as per written Bobde, representation and addresses above vide Sr. No. 6. Borgaon

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-12 San Envirotech Pvt. Ltd., Ahmedabad

B. Hazard Analysis & Risk Assessment 7.1 INTRODUCTION Industrial plants deal with materials, which are generally hazardous in nature by virtue of their intrinsic chemical properties or their operating temperatures or pressures or a combination of these. Fire, explosion, toxic release or combinations of these are the hazards associated with industrial plants using hazardous chemicals. More comprehensive, systematic and sophisticated methods of Safety Engineering, such as, Hazard Analysis and Quantitative Risk Assessment have now been developed to improve upon the integrity, reliability and safety of industrial plants. The primary emphasis in safety engineering is to reduce risk to human life, property and environment. Some of the more important methods used to achieve this are:  Quantitative Risk Analysis: Provides a relative measure of the likelihood and severity of various possible hazardous events by critically examining the plant process and design.  Work Safety Analysis: The technique discerns whether the plant layout and operating procedures in practice have any inherent infirmities.  Safety Audit: Takes a careful look at plant operating conditions, work practices and work environments to detect unsafe conditions. 7.2 RISK ASSESSMENT-IDENTIFICATION OF HAZARDS M/s. Orgosynth Chemicals Pvt. Ltd is proposed to produce Dye Intermediates at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Total production capacity of the proposed products will be 3049 MT/Month Dye Intermediates. A three „levels‟ risk assessment approach has been adopted. The risk assessment levels are generally consistent with the practices encountered through various assignments for medium and large chemical complexes. The brief outline of the three tier approach is given below:  Level 1 – Risk Screening This is top-down review of worst-case potential hazards/risks, aimed primarily at identifying plant sites or areas within plant, which pose the highest risk. Various screening factors considered include:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-13 San Envirotech Pvt. Ltd., Ahmedabad

 Inventory of hazardous materials;  Hazardous Materials properties;  Storage conditions (e.g. temperature and pressure);  Location sensitivity (distance to residential areas/populace). The data/information is obtained from plant. The results provide a relative indication of the extent of hazards and potential for risk exposure.  Level 2 – Major Risk Survey (Semi - Quantitative) The survey approach combines the site inspection with established risk assessment techniques applied both qualitative as well quantitative mode. The primary objective is to identify and select major risks at a specific location in the plant considering possible soft spots during operation/maintenance. Aspects covered in the risk usually include:  Process Hazards;  Process Safety Management Systems;  Fire Protection and Emergency response equipment and programs.  Security Vulnerability;  Impact of hazards consequences (equipment damage, business interruption, injury, fatalities);  Qualitative risk identification of scenarios involving hazardous materials;  Risk reduction measures. Selection of critical scenarios and their potential of damage provide means of prioritising mitigative measures and allocate the resources to the areas with highest risks.  Level 3 – Quantitative Risk Assessment (Deterministic) This is the stage of assessment of risks associated with all credible hazards (scenarios) with potential to cause an undesirable outcome such as human injury, fatality or destruction of property. The four basic elements include:  Hazards identification utilizing formal approach (Level 2, HAZOP etc.);  Frequency Analysis. Based on past safety data (incidents/accidents); Identifying likely pathway of failures and quantifying the toxic material release;  Hazards analysis to quantify the consequences of various hazards scenarios (fire, explosion, BLEVE, toxic vapour release etc.). Establish

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-14 San Envirotech Pvt. Ltd., Ahmedabad

minimum value for damage (e.g. IDLH, over pressure, radiation flux) to assess the impact on environment.  Risk Quantification: Quantitative techniques are used considering effect/impact due to weather data, population data, and frequency of occurrences and likely hood of ignition/toxic release. Data are analyzed considering likely damage (in terms of injury/fatality, property damage) each scenarios is likely to cause. QRA provides a means to determine the relative significance of a number of undesired events, allowing analyst and the team to focus their risk reduction efforts where they will be beneficial most. The QRA for this plant is based on Level 1 and Level 2. Table 2.2 in Chapter 2 gives the list of products (and their monthly production capacity) to be manufactured. Table below gives the bulk storages of hazardous chemicals and their consumption. 7.3 HAZARDOUS MATERIALS STORAGE The solid raw materials will be received in bags or drums and will be stored in chemicals godowns. The products will be packed in bags or drums and stored in product godowns as per market demand. The bulk storages of liquid hazardous materials are given in the Table 7.3 below. In addition unit will store fuels mainly Agro Briquettes/Coal for boiler, TFH and Diesel (in limited quantity) for D.G. Set (during power failure only). The solid material powder or granules spillage can results in polluting small area only. The damage to personnel can be through ingress- dermal (if individual come in contact), oral (if individual food gets infected through fugitive dust) or inhalation (fugitive dust). The main route is fugitive dust which in covered area will move to short distance only. The risk is through liquid products which are volatile material. The toxic vapours due to spillage of such material can travel to some distance (as they are stored in covered godowns) and cause damage. Table 7.3: Bulk Storage of Hazardous Chemicals Sr. Name of State Stored MOC Storage No. Chemicals (Solid/ in (MT) Liquid/Gas) 1 Sulphuric Acid Liquid Tank MS 30 x 2 (98%)

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-15 San Envirotech Pvt. Ltd., Ahmedabad

2 HCl Liquid Tank HDPE 10 x 2 3 Nitric Acid Liquid Tank Aluminum 30 x 2 4 Acetic Anhydride Liquid Tank HDPE 5 5 Caustic Lye Liquid Tank MS 10 6 Anhydrous Ammonia Liquid Tank MS 15 x 2 7 Liq. Chlorine Liquid/Gas Tonner MS 0.9 x 40 8 Bromine Liquid Bottles Glass 50 Nos x 2.8 kgs Plastic Crates 9 MDC Liquid Tank MS 20 10 Toluene Liquid Tank MS 20 7.4 RISK SCREENING APPROACH Risk screening of Orgosynth Chemicals was undertaken through process study and study of data/information provided by the unit. Data of major/ bulk storages of raw materials, intermediates and other chemicals were collected. MSDS of hazardous chemicals were studied vis a vis their inventories and mode of storage. The chemicals stored in bulk and defined under MSIHC Rule will be considered for detailed analysis. None of the products are covered under MSIHC Rules. Raw materials under hazardous category as specified by MSIHC Rules, 1989 (including subsequent amendments) are as below, Table 7.4: Hazards Analysis – Raw materials (stored in Bulk)

Sr. Raw Description Sr. No & Threshold Chemicals Hazards No. material Quantity (in MT) Potential as per MSHIC Rules Sch-1, Sch- Sch- Part- 2, 3, II Part- Part- I I 1. Sulphuric Colorless thick oily 591 ------Very hazardous in case of acid liquid with strong skin contact (corrosive, CAS No: marked acid taste. irritant, permeator), of eye 7664-93-9 contact (irritant, corrosive), UN No: 1830 of ingestion, of inhalation. 2. Hydrochloric Colorless to light 313 ------Very hazardous in case of Acid yellow liquid with skin contact (corrosive, CAS No: pungent strong irritant, permeator), of eye 7647-01-0 irritating odor, contact (irritant, corrosive), UN No: 1789 soluble in water of ingestion. Slightly and diethyl ether hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. 3. Nitric Acid Colorless to light 423 ------Very hazardous in case of CAS No.: yellow colored skin contact (corrosive, 7697-37-2 liquid with strong irritant, permeator), of eye UN No.: acrid, disagreeable contact (irritant, corrosive), 2031 and choking odor, of ingestion. Slightly

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-16 San Envirotech Pvt. Ltd., Ahmedabad

easily soluble in hazardous in case of water, soluble in inhalation (lung sensitizer). diethyl ether. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. 4. Acetic Colorless to light 3 ------Flammable, corrosive, Liquid anhydride yellow colored is volatile and causes little CAS No. liquid with strong irritation on uncovered skin. 108-24-7 odor and test. However, causes severe UN No: 1715 burns when clothing is wet with the chemical or if it enters gloves or shoes. Causes skin and eye burns and irritation of respiratory tract. Nausea and vomiting may develop after exposure. 5. Caustic Lye Clear colorless, ------Very hazardous in case of CAS No.: odorless liquid with skin contact (corrosive, 1310-73-2 strong alkaline irritant, permeator), of eye UN No.: bitter taste, easily contact (irritant, corrosive), 1824 soluble in cold of ingestion. Slightly water. hazardous in case of inhalation (lung sensitizer). 6. Anhydrous Ammonia, anhydro 31 2 105 Fire Hazards: (Gas); Mixing Ammonia us appears as a TQ- TQ- of ammonia with several CAS No: clear colorless gas 1: 1: chemicals can cause fire 7664-41-7 with a strong odor. 60 50 hazards/or explosions; UN No: 1005 MT MT vapours are toxic- irritation TQ- TQ- to eyes and respiratory tract. 2: 2: 600 500 MT MT 7. Liq. Chlorine Chlorine is a 119 5 108 Poisonous; may be fatal if CAS greenish yellow gas TQ1: TQ1: inhaled. Contact may cause No:7782-50- at room 10 10 burns to skin and eyes. 5 temperature and MT MT Bronchitis or chronic lung UN No: 1017 atmospheric TQ2: TQ2: conditions. pressure. It is two 25 25 and a half times MT MT heavier than air. It becomes a liquid at -34°C (-29°F). 8. Bromine Bromine is red- 84 --- 106 Non-combustible, corrosive, CAS No: brown liquid at TQ1: inhalation, ingestion or skin 7726-95-6 room temperature 40 contact with material may UN No: 1744 that evaporates MT cause severe injury or death. readily to form a Contact with molten similarly coloured substance may cause severe gas. burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. 9. MDC MDC is a 400 ------Noncombustible by if (Dichloromet clear, colorless exposed to high hane) liquid, mildly sweet temperatures may emit toxic

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-17 San Envirotech Pvt. Ltd., Ahmedabad

CAS No: 75- odor chloride fumes. Vapors are 09-2 narcotic in high UN No: 1593 concentrations. Used as a solvent and paint remover. 10. Toluene Toluene is a 628 ------Hazardous in case of skin CAS No: clear, colorless contact (irritant), of eye 108-88-3 liquid with a contact (irritant), of UN No: 1294 distinctive smell. ingestion, of inhalation. sweetish odor - Slightly hazardous in case of pleasant odor - skin contact (permeator). benzene-like

Table 7.5: Properties of Hazard – Raw materials (stored in Bulk)

Name of Physical BP FP LEL UEL TLV LD50 Vapour Specific Chemicals form oC oC % % ppm mg/Kg & Density Gravity

LC50 mg/l Sulphuric Liquid 270 NA NA NA 1 LD : 2140 3.4 1.84 3 50 acid mg/m LC : 510 50

Hydrochloric Liquid 108.58 NA NA NA 5 LD50: 900 1.267 1.1- acid LC50: 3124 1.19 Nitric Acid Liquid 121 NA NA NA 2 LC : 244 2.5 1.408 50

Acetic Liquid 139.9 49 2.7 10.3 NA LD50:4000 3.52 1.08 Anhydride LC50: 1000 Caustic Lye Liquid 140 NA NA NA 2 NA 0.62 1.53 mg/m3 (Water) Liq. Chlorine Liquid 100 NA NA NA NA NA 0.62 1

Bromine Liquid 58.78 NA NA NA 0.2 LD50: 2600 7.1 3.11 LC50: 750 Liquid 40 NA 13 23 100 LD : 1600 2.9 1.32 MDC 50 LC50: 52 Liquid 110.6 4.44 1.1 7.1 300 LD : 630 3.1 0.8636 Toluene 50 LC50: 440 Note: TQ-I: Threshold quantity (for application of rules 4, 5,7 to 9 and 13 to 15) TQ-II: Threshold quantity (for application of rules 10 to 12)

1. Oral Toxicity (OT) in LD50 (mg/kg)

2. Dermal Toxicity (DT) in LD50 (mg/kg)

3. Inhalation Toxicity in LC50 (mg/l) [4 hrs.] Summary: None of the raw materials are listed in Schedule 2 and 3 of MSIHC Rules. None of the raw materials are extremely toxic. Sr. Toxicity Oral toxicity Dermal Inhalation

No. LD50 toxicity toxicity (mg/kg) LD50 (mg/kg) LC50 (mg/l) 1. Extremely toxic <5 <40 <0.5 2. Highly toxic >5-50 >40-200 <0.5-2.0 3. Toxic >50-200 >200-1000 >2-10

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-18 San Envirotech Pvt. Ltd., Ahmedabad

7.4.1 Acute Exposure Guideline Levels (AEGLs) AEGLs estimate the concentrations at which most people - including sensitive individuals such as old, sick, or very young people - will begin to experience health effects if they are exposed to a hazardous chemical for a specific length of time (duration). For a given exposure duration, a chemical may have up to three AEGL values, each of which corresponds to a specific tier of health effects. The 3 tiers are defined as follows:

 AEGL-3 is “the airborne concentration of a substance above which it is predicted that the general population, including susceptible individuals, could experience life-threatening adverse health effects or death.”

 AEGL-2 is “the airborne concentration of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting adverse health effects or an impaired ability to escape.”

 AEGL-1 is “the airborne concentration of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic no sensory effects.” AEGLs of the materials are as below.

10 min 30 min 60 min 4 hr 8 hr Unit Sulphuric acid (7664-93-9) AEGL 1 0.20 0.20 0.20 0.20 0.20 mg/m3 AEGL 2 8.7 8.7 8.7 8.7 8.7 mg/m3 AEGL 3 270 200 160 110 93 mg/m3 Hydrogen Chloride (7647-01-0) AEGL 1 1.8 1.8 1.8 1.8 1.8 ppm AEGL 2 100 43 22 11 11 ppm AEGL 3 620 210 100 26 26 ppm Nitric Acid (7697-37-2) AEGL 1 0.16 0.16 0.16 0.16 0.16 ppm AEGL 2 43 30 24 6.0 3.0 ppm AEGL 3 170 120 92 23 11 ppm Caustic Lye(1310-73-2) AEGL 1 100 100 100 NR NR ppm AEGL 2 170 170 130 80 42 ppm AEGL 3 300 300 270 170 ppm Ammonia (7664-41-7) AEGL 1 30 30 30 30 30 ppm AEGL 2 220 220 160 110 110 ppm AEGL 3 2700 1600 1100 550 390 ppm Chlorine (7782-50-5) AEGL 1 0.5 0.5 0.5 0.5 0.5 ppm

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-19 San Envirotech Pvt. Ltd., Ahmedabad

AEGL 2 2.8 2.8 2 1 0.71 ppm AEGL 3 50 28 20 10 7.1 ppm

Bromine (7726-95-6) AEGL 1 0.033 0.033 0.033 0.033 0.033 ppm AEGL 2 0.55 0.33 0.24 0.13 0.095 ppm AEGL 3 19 12 8.5 4.5 3.3 ppm Methylene Di Chloride (75-09-2) AEGL 1 290 230 200 NR NR ppm AEGL 2 1700 1200 560 100 60 ppm AEGL 3 12000 8500 6900 4900 2100 ppm Toluene ( 108-88-3 )

AEGL 1 67 67 67 67 67 ppm AEGL 2 1400* 760 560 310 250 ppm AEGL 3 10000** 5200 3700* 1800* 1400* ppm NR = Not recommended due to insufficient data * indicates value is 10-49% of LEL. Safety consideration against explosions must be taken into account. ** indicates value is 50-99% of LEL. Extreme safety consideration against explosions must be taken into account. 7.4.2 Emergency Response Planning Guidelines (ERPGs) ERPGs estimate the concentrations at which most people will begin to experience health effects if they are exposed to a hazardous airborne chemical for 1 hour. (Sensitive members of the public - such as old, sick, or very young people - aren't covered by these guidelines and they may experience adverse effects at concentrations below the ERPG values). ERPGs of the materials at Orgosysnth are as below.

ERPG-1 ERPG-2 ERPG-3 Unit Sulphuric Acid 2 10 30 mg/m3 Hydrogen Chloride 3* 20 150 ppm Nitric Acid 1* 10 78 ppm Acetic Anhydride 0.5 15 100 ppm Sodium Hydroxide 0.5 5.0 50 mg/m3 Ammonia 25 150 1500 ppm Chlorine 1 3 20 ppm Bromine 0.1* 0.5 5 ppm MDC 300 750 4000 ppm Toluene 50* 300 1000 ppm *indicates that odor should be detectable near ERPG-1 **indicates the value is 10-49% of LEL. The 3 tiers are defined as follows:

 ERPG-3 is "the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing life-threatening health effects."

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-20 San Envirotech Pvt. Ltd., Ahmedabad

 ERPG-2 is "the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing irreversible or other serious health effects or symptoms which could impair an individual's ability to take protective action."

 ERPG-1 is "the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing other than mild transient health effects or perceiving a clearly defined, objectionable odor." 7.5 QRA APPROACH Identification of hazards and likely scenarios (based on Level-1 and Level-2 activities) calls for detailed analysis of each scenario for potential of damage, impact area (may vary with weather conditions/wind direction) and safety system in place. Subsequently each incident is classified according to relative risk classifications provided in Table 7.6. Table 7.6: Risk Classification

Stage Description High A failure which could reasonably be expected to occur within the (> 10-2/yr.) expected life time of the plant. Examples of high failure likelihood are process leaks or single instrument or valve failures or a human error which could result in releases of hazardous materials. Moderate A failure or sequence of failures which has a low probability of (10-2 --10-4/yr.) occurrence within the expected lifetime of the plant. Examples of moderate likelihood are dual instrument or valve failures, combination of instrument failures and human errors, or single failures of small process lines or fittings. Low A failure or series of failures which have a very low probability of (<10-4) occurrence within the expected lifetime of plant. Examples of „low‟ likelihood are multiple instruments or valve failures or multiple human errors, or single spontaneous failures of tanks or process vessels. Minor Incidents Impact limited to the local area of the event with potent for „knock – on- events‟. Serious Incident One that could cause:  Any serious injury or fatality on/off site;  Property damage of more than 50 Lakhs INR Extensive Incident One that is five or more times worse than a serious incident.

Assigning a relative risk to each scenario provides a means of prioritising associated risk mitigation measures and planned actions.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-21 San Envirotech Pvt. Ltd., Ahmedabad

7.6 THERMAL HAZARDS In order to understand the damages produced by various scenarios, it is appropriate to understand the physiological/physical effects of thermal radiation intensities. The thermal radiation due to tank fire usually results in burn on the human body. Furthermore, inanimate objects like equipment, piping, cables, etc. may also be affected and also need to be evaluated for damages. Table 7.7, Table 7.8 and Table 7.9 (below), respectively give tolerable intensities of various objects and desirable escape time for thermal radiation. Thermal hazards could be from fires or explosion. Fire releases energy slowly while explosion release energy very rapidly (typically in micro seconds). Explosion is rapid expansion of gases resulting in rapidly moving shock wave. BLEVE (boiling liquid expanding vapour explosion) occurs if a vessel containing a liquid at a temperature above its atmospheric boiling point ruptures. The subsequent BLEVE is the explosive vaporization of large fraction of its vapour contents; possibly followed by combustion or explosion of the vaporized cloud if it is combustible. Thermal hazards have been considered for various scenarios including: Fire in inflammable chemicals storage tanks. Table 7.7: Effects due to Incident Radiation Intensity Incident Radiation Damage Type kW/m2 0.7 Equivalent to Solar Radiation 1.6 No discomfort on long duration 4.0 Sufficient to cause pain within 20 sec. Blistering of skin (first degree burn are likely). 9.5 Pain threshold reached after 8 sec. Second degree burn after 20 sec. 12.5 Minimum energy required for piloted ignition of wood, melting of plastic tubing etc. 25 Minimum Energy required for piloted ignition of wood, melting, plastic tubing etc. 37.5 Sufficient to cause damage to process equipment. 62.0 Spontaneous ignition of wood. Table 7.8: Thermal Radiation Impact to Human

Exposure Radiation Energy Radiation Energy Radiation Energy Duration {1% lethality; for 2nd degree for 1st degree kW/m2} burns; kW/m2 burns; kW/m2 10 sec 21.2 16 12.5 30 9.3 7.0 4.0

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-22 San Envirotech Pvt. Ltd., Ahmedabad

Table 7.9: Tolerable Intensities for Various Objects

Sl. Tolerable Intensities Objects No. (kw/m2) 1 Drenched Tank 38 2 Special Buildings 25 (No window, fire proof doors) 3 Normal Buildings 14 4 Vegetation 10-12 5 Escape Route 6 (up to 30 secs.) 6 Personnel in Emergencies 3 (up to 30 secs.) 7 Plastic Cables 2 8 Stationary Personnel 1.5 7.7 DAMAGE DUE TO EXPLOSION The explosion of a dust or gas (either as a deflagration or detonation) results in a reaction front moving outwards from the ignition source preceded by a shock wave or pressure front. After the combustible material is consumed the reaction front terminates but the pressure wave continues its outward movement. Blast damage is based on the determination of the peak overpressure resulting from the pressure wave impacting on the object or structure. Damage estimates based on overpressure are given in Table 7.10 below: Table 7.10: Damage due to Overpressure

Sr. Overpressure Damage No. (psig/bar) 1. 0.04 Loud Noise/sonic boom glass failure 2. 0.15 Typical pressure for glass failure 3. 0.5 - 1 Large and small windows usually shattered 4. 0.7 Minor damage to house structure 5. 1 Partial demolition of houses, made uninhabitable 6. 2.3 Lower limit of serious structure damage 7. 5 - 7 Nearly complete destruction of houses 8. 9 Loaded train box wagons completely demolished 9. 10 Probable total destruction of houses 10. 200 Limits of crater lip In case of Orgosynth Chemicals, explosion probability is remote. 7.8 TOXIC RELEASE For toxic release the damage criteria considered is IDLH concentration (if data are available). The immediately dangerous to life or health air concentration values (IDLH values) developed by the National Institute for Occupational Safety and Health (NIOSH) characterize these high-risk exposure concentrations and conditions and are used as a component of

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respirator selection criteria. IDLH values are established (1) to ensure that the worker can escape from a given contaminated environment in the event of failure of the respiratory protection equipment and (2) to indicate a maximum level above which only a highly reliable breathing apparatus, providing maximum worker protection, is permitted. IDLH of all the materials stored in bulk are as below.

IDLH Value Unit

Sulfuric Acid 15 mg/m3 Hydrochloric acid 50 ppm Nitric acid 25 ppm Acetic Anhydride 200 ppm Sodium Hydroxide 10 mg/m3 Ammonia 300 ppm Chlorine 10 ppm Bromine 3 ppm MDC 2300 ppm Toluene 500 ppm 7.9 ACID/ALKALI HAZARDS Various hazards that can occur due to the acid and alkali incidents are  Skin irritation and corrosive effects after spillage  Spill pool evaporation of hydrochloric acid or Caustic lye storage tanks catastrophic failure are limited only  Catastrophic failure giving rise to spill pool evaporation dispersion

up to LC50, IDLH and TLV level Based on the outcome of the risk assessment, following recommendation has been made to avoid any risk associated with the storage and use of acids in the plant:  Full body protection will be provided to operator.  Caution note and emergency first aid will be displayed.  All employees will be trained for use of emergency first aid.  Safety shower and eye wash will be provided in storage tank area and plant area.  Dyke wall will be provided to storage tank.  Tanker unloading procedure will be prepared.  SOP will be prepared for Hydrochloric acid, Nitric acid , and Sulfuric acid handling.

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 Training programme will be conducted for safe handling and emergency handling of Acids.  In Storage Tank Area, reaction with water generating fumes should be displayed and avoided.  Suitable extinguishing media-Extinguish with dry powder/sand. DO NOT USE WATER. 7.10 LIKELY FAILURE SCENARIOS Few likely failure scenarios have been selected after critical appraisal of raw materials and storage inventories. Failure scenarios selected are as given in Table 7.11 below: Table 7.11: Different Failure Scenarios

Raw materials Scenario Remark Sulphuric acid Tank leakage Toxic/Corrosive Hydrochloric acid Tank leakage Toxic Nitric Acid Tank leakage Toxic Ammonia Ammonia pipe Leakage from pipe of leakage cylinder Chlorine Chlorine Leakage Toxic leakage from pipe of from Tonner Cylinder cylinder/Cylinder Toluene Toluene tank leakage Flammable Area of burning puddle resulting from Leak from cylindrical tank Bromine Bromine spillages Toxic spillages from Bottle from Bottle 7.11 QUANTITATIVE RISK ASSESSMENT & CONSEQUENCE ANALYSIS 7.11.1 PREAMBLE In the previous section we have carried out the hazards analysis of Orgosynth Chemicals considering various aspects including bulk storages of hazardous chemicals, plant process system, plant incidents/accidents records, critical appraisal and discussion at site for soft spots in the plant etc. Based on the hazards analysis few critical scenarios have been selected for QRA and consequence analysis. QRA quantifies vulnerable zones for a conceived incident with various levels of severity. In consequence calculation, use is made of a number of calculation models to estimate the physical effects of an accident (spill of hazardous material) and to predict the damage (lethality, injury, material

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destruction and other property damage). The risk assessment modelling can be roughly divided into three groups:  Determination of source strength parameters;  Determination of consequential effects;  Determination of damage or damage distances (with specific severity rates) 7.11.2 Weather Effect The effect of ambient conditions on the impact of fire/heat radiation and GLC of hazardous/toxic material can be beneficial as well as harmful. A high wind (turbulence) can dilute the toxic material while stable

environment can extend the reach of IDLH or IT (inhalation LC50 rats for products) concentration to long distance. Any inflammable gas/vapour release in turbulent weather will soon dilute the hazardous gases below LEL and thus prevent the disaster. 7.12 INCIDENTS IMPACTS The identified failure scenarios (Table 7.11) have been analyzed (Using ALOHA and EFFECT Modules) for the impact zones considering damage due to thermal and toxic impacts. Each incident will have Impact on the surrounding environment which in extreme case may cross plant boundary. The impact zones for various scenarios are given in Table 7.12 and shown in Figure 7.2 to 7.10.

Figure 7.2: Sulphuric Acid Spillage and Evaporating Toxic Pool

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Figure 7.3: Hydrochloric Acid Tank leakage Toxic Impact

Figure 7.4: Nitric Acid (Anhydrous) Spillage and Evaporating Toxic Pool

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Figure 7.5: Ammonia Release & Toxic Evaporating Pool

Figure 7.6: Chlorine Cylinder Leakage Stability Class-C

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Figure 7.7: Chlorine Cylinder Leakage Stability Class-F

Figure 7.8: Toluene Spillage—Toxic Impact Zone; Stability Class D

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Figure 7.9: Bromine Spillage & Toxic Impact Zone Stability Class D

Figure 7.10: Bromine Spillage & Toxic Impact Zone Stability Class F Table 7.12: Hazards Scenario Impact

Raw Scenario Impact Remarks material Zone Sulphuric Acid Toxic/Corrosive 410 m Red : 410 meters --- (25 Figure 3 Impact from mg/m = AEGL-3 [60 min]) 7.2 Leakage of tank Orange: 29 meters --- (22 ppm = AEGL-2 [60 min]) Note: Threat zone was not drawn because effects of near- field patchiness make dispersion predictions less reliable for short distances. Yellow: 105 meters --- (1.8 ppm = AEGL-1 [60 min]) Hydrochloric Toxic Impact 13 m Red: 13 meters --- (100 Figure Acid from Leakage of ppm = AEGL-3 [60 min]) 7.3 tank Orange: 2150 meters --- (4.4 mg/m3 = AEGL-2 [60

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Raw Scenario Impact Remarks material Zone min]) Yellow: >10000 meters --- (0.1 mg/m3 = AEGL-1 [60 min]) Nitric Acid Spillage and -- Red: (92 ppm = AEGL-3 Figure Leakage of tank [60 min]) 7.4 Orange (25 ppm = IDLH-2 [60 min]) Yellow: 245 meters --- (0.16 ppm= AEGL-1 [60 min]) Ammonia Toxic Impact 2300 m Red: 2300 meters (1100 Figure from Leakage of ppm = AEGL-3 [60 min]) 7.5 tank Orange:4400 meters (300 ppm = IDLH-2 [60 min]) Yellow: 6250 meters --- (160 ppm= AEGL-1 [60 min]) Chlorine Chlorine Cylinder 285 m Red: 285 meters (20 ppm Figure Leakage Stability = AEGL-3 [60 min]) 7.6 Class-C Orange:565 meters (10 ppm = IDLH-2 [60 min]) Yellow: 1450 meters --- (2 ppm= AEGL-1 [60 min]) Chlorine Chlorine Cylinder 750 m Red: 750 meters (20 ppm Figure Leakage Stability = AEGL-3 [60 min]) 7.7 Class-F Orange:1325 meters (10 ppm = IDLH-2 [60 min]) Yellow: 3430 meters --- (2 ppm= AEGL-1 [60 min]) Toluene Toxic Impact -- Red : (3700 ppm = AEGL-3 Figure from Leak from [60 min]) 7.8 Tank Orange: 81 meters (500 ppm = AEGL-2 [60 min]) Note: Threat zone was not drawn because effects of near- field patchiness make dispersion predictions less reliable for short distances. Yellow: 503 meters (67 ppm = AEGL-1 [60 min]) Bromine Toxic Impact -- Red : (8.5 ppm = AEGL-3 Figure from Leak from [60 min]) 7.9 bottles Note: Threat zone was not Stability Class D drawn because effects of near- field patchiness make dispersion predictions less reliable for short distances. Orange: 65 meters (3 ppm = IDLH [60 min]) Yellow: 170 meters (0.5 ppm = AEGL-2 [60 min]

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Raw Scenario Impact Remarks material Zone Bromine Toxic Impact 115 m Red : 115 meters (8.5 ppm Figure from Leak from = AEGL-3 [60 min]) 7.10 bottles Orange: 200 meters (3 Stability Class F ppm = IDLH [60 min]) Yellow: 785 meters (0.24 ppm = AEGL-2 [60 min] 7.13 CONSEQUENTIAL IMPACTS The consequential impacts from each incident scenarios can be though mainly toxic route. The damage can be on plant personnel (and neighboring premises in case incident crosses boundary). The impact zones for some of the hazards are shown in Figure 7.2 to 7.10. 7.13.1 Thermal and Explosion Hazards Incidents involving thermal and explosion hazards are mainly due to fire in tank farm. In case of Orgosynth, no explosive chemicals stored in premises because no use of solvent or highly explosive chemicals. 7.13.2 Toxic Hazards Toxic hazards are mainly due to chemicals/gas leakage/spillage and their impact is limited to plant boundary and adjacent premises based on the wind direction (Sulphuric acid ~410 meters; HCl Tank leakage ~ 13 m, Chlorine-285 m (Stability Class-C) & 750 m (Stability Class-F) and Bromine-115 m (Stability Class-F) . However, the consequences may go outside the plant boundary if the incidents lead to domino effect. 7.13.3 Other Hazards The other hazards in the plant include (but not limited to):  Other toxic hazards due to acids/other toxic spillages.  Mechanical hazards due to machines/equipment.  Hazards due to individual soft spots like walking casually and noticing a pit and falling or colliding or slipping (not noticing a wet place etc.). 7.13.4 Other Toxic Hazards Acid spillage-its impact will be limited to spillage area. The spillage if comes in contact with metal parts will produce hydrogen which is highly flammable gas. Any person moving in area and getting splash will get the injury. In addition the spillage will cause pollution problem. The spillage is to be collected and neutralized for toxic contents before disposal.

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7.14 OCCUPATIONAL HEALTH In any eventuality, injured personnel will be immediately rushed to hospital after giving first aid. All employees will be having regular medical checkup as per norms. One dedicated on-site vehicle and local ambulance service will be always (round the clock) accessible for meeting any eventuality. Treatment of workers affected by Accidental Spillage of Chemicals There is wide range of chemicals present in the Chemical plants. The safe cleanup of a chemical spill requires some knowledge of the properties and hazards posed by the chemical & any added dangers posed by the location of the spill. Employees must notify their immediate supervisor of injury by spillage of chemicals or exposure to hazardous materials. All injuries must be reported. Supervisor is responsible for reporting any injuries or occupational illnesses to the management. Following steps will be immediate taken by the Supervisor.  Identify spillage/leakages of hazardous chemicals  Chemical Exposure to Skin: Immediately flush with cool water for at least 15 minutes. If there are no visible burns, remove the cloth from burning part of body. Seek medical attention if exposure/spillages occur major possible problems.  Chemical Exposure to Skin – Serious: Remove all contaminated clothing. Locate the nearest emergency shower and soak for at least 15 minutes. Have someone contact the Hospital for immediate medical attention.  Chemicals in Eyes: Irrigate eyes for at least 15 minutes with tempered water from emergency eyewash station. Remove contact lenses if there is. Notify the management and immediate medical attention.  Acid Fumes: Anyone overcome by fumes should be removed to fresh air. Never attempt to enter location where potentially dangerous fumes might place you at risk. If someone is down, contact emergency personnel and let them enter. Self-breathing apparatus is required for persons entering the affected area. Seek medical attention for exposure as soon as possible.

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 Chemical Spills: The safe clean-up of an acid spill requires some knowledge of the properties and hazards posed by the acid and any added dangers posed by the location of the spill. If you believe a spill is beyond your capacity to clean up, do not attempt to do so by your own, immediately contact to nearest fire/emergency station. Spill kits with instructions, absorbents, neutralizing agents if applicable, protective equipment, and sealable waste buckets should be present in plant area. Following Steps to be taken for ensuring health and safety of workers engaged in handling of Hazardous materials  Identify chemicals to be used, amounts required, condition followed as per the MSDS guideline.  Evaluate the hazards posed by the chemicals and the process conditions. The evaluation should cover toxic, physical, reactive, as well as any other potential hazards posed by the respective chemicals.  Select appropriate controls to minimize risk, including use of engineering controls, administrative controls, and Personal Protective Equipment to protect workers from hazards. The controls must ensure that OSHA‟s Permissible Exposure Limits (PELs) are not exceeded.  Before working with chemicals, know the facility‟s policies and procedures for how to handle an accidental spill or fire. Emergency telephone numbers should be posted in a prominent area. Know the location of all safety equipment and nearest fire alarm and telephone.  Provide popper Ventilation in the plant/process area.  Corrosive chemicals that require vented storage should be stored in vented cabinets instead of in a chemical hood.  Chemicals should be separated and stored according to hazard category and compatibility. 7.15 CONCLUSION & RECOMMENDATIONS The hazard analysis and risk assessment of few possible selected incident scenarios indicates that most incidents will be limited to plant battery limits, and have impact on adjoining area in very unlikely scenarios only. Toxic hazards are mainly due to chemicals leakage/spillage and their impact is limited to plant boundary and adjacent premises based on the

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wind direction. The direction of impact will be in down wind direction (wind direction and speed varies with season). Some of the recommendations for Tank farm storage system are as given below:  Dyke wall will be provided to storage tanks.  SOP will be prepared for Hydrochloric acid, Nitric acid, and Sulfuric acid handling.  Fixed foam system with adequate capacity.  Regular „Hazard Survey‟ ensures the detection of leakage in the plant.  In house „capability building‟ to attend hazardous scenarios is to be taken up through mock drills.  Train staff in attending such scenarios. Human Factors: Human factors role in safety cannot be ignored. Odd hours working and over/long hours work can drain out individual. It shows in lack of efficiency and also the lack of apt attention the modern chemical complex demand. They are to be closely looked into and avoided, as- a. If no accident has happened so far probability of incident/accident occurring increases. b. „No accident‟/good safety record develops complacency inertia/over confidence in the team. This attitude gives rise to gaps/soft spots in the system giving chances to incidents/accidents. c. Safety requires novelty. Routine training practices get stale with no positive results. Look for novel scheme of training/ safety practices to build up fresh impetus in safety.

MATERIAL HANDLING AND SAFETY MEASURES 7.16 ACTION PLAN FOR HANDLING & SAFETY SYSTEM OF CHEMICAL Hazardous chemicals will be stored and handle in dispensing room for taking out sample from the container for quality check-up purpose or for the partial use. This activity for Hazardous material handling will be carried out by using all PPEs with proper ventilation & under supervision. 7.16.1 Safety Measures for Transportation and Unloading of Hazardous Chemicals  Static earthing provision will be made for tanker unloading.

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 Drum handling trolleys will be used for transportation of drums up to plant and internal handling from storage to process area.  Display Boards will be provided on all storage tanks which include the name of the chemicals and its major hazardous characteristics.  Fire extinguishers will be provided as required.  First aid boxes will also be provided at different places wherever required.  Water showering system will be provided to the hazardous chemicals storage area.  Area will be declared as “NO SMOKE ZONE”. 7.16.2 Safety Measures for Storage/Handling of Hazardous Chemicals All Hazardous chemicals will store separately and away from the strong oxidant & kept it in well ventilated room. Adequate firefighting system will be installed. Safety shower and eye washer will be installed near storage area. Flame proof light fitting will be provided at storage area. Sprinkler system will be installed near storage area. Safety permit system will be followed for loading and unloading. Isolate storage will be provided with wire fencing under lock and key. Caution note, hazardous identification board will be provided. Only authorized person will be permitted in storage area and register will be maintained. “NO SMOKING” board will be displayed and Wind Indicator and siren will be provided. 7.16.3 Safety Measures for Process Units Safety measures are the most important aspect of selection of process technology to ensure safety in production unit. For the safety in production area some important critical safety measures will be provided within the process technology/equipment itself & will put continue efforts for developing new technology/equipment. Company will ensure such provision in the technology/equipment/machineries at time of purchase. The details of the critical safety measures for process unit are as below; any reaction upsets will be confined to the reaction vessel itself as defined quantity of raw materials will be issued to the reaction vessel by metering pumps/load cells. Process parameters control will be provided as per SOP- Standard Operating Procedures. Materials will be transferred by pumping through pipeline or by vacuum from drums. All reaction vents

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will be connected to vapor condensers system. Hazardous materials will be transferred by pipelines and in controlled manners. Trained person will be engaged for handling of hazardous materials. Proper safety precautions will be taken during handling of hazardous materials. All liquid hazardous material with required quantity will be charge in reactor by pump or by gravity. All the vessels will be examined periodically by a recognized competent person. All the vessels and equipments will be well earthed appropriately and well protected against Static Electricity. Temperature indicators will be provided near all reactor and distillation systems. Flame proof light fittings will be installed in the plant. All the Plant Personnel will be provided with Personal Protection Equipments to protect against any adverse health effect during operations, leakage, spillages or splash. PPE like Helmets, Safety Shoes and Safety Glasses will be provided to the employees. 7.16.4 Safety Measures for Preventive Maintenance The safety measures in the form of the general Do's & Don'ts for safety in process & other plant area are as below:  Do not work on equipments without permission from plant head and maintenance head.  Make sure equipment is empty and flushed with nitrogen and air.  Keep proper and adequate fire extinguisher near work area.  Use proper PPE.  Do not allow any employment without pre-medical check-up or without checking fitness.  Work in any equipment must be conducted in presence of supervisor.  Additional safety measures in form of checklist covering Do's & Don'ts of preventive maintenance, strengthening of HSE, manufacturing utility staff for safety related measures will be updated timely and will be made available to all concern department & personnel. 7.16.5 Safety measures to prevent spillage/leakage of toxic chemicals The preventive maintenance will be planned and carried out as per plan to avoid the failure of valve, pipelines and other component of transferring line. The spillage will be confined to the dyke area underneath the vessel. The resultant splash of such chemicals will result

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in exposure of toxic chemicals to employees. Decontamination facilities (Safety shower and eye wash fountains) will be provided in the plant area, which can be used to decontaminate the affected employees. Suitable decontamination procedure will be used to decontaminate the spilled or leaked material. The SOP for decontamination will be available with all related department. 7.17 ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS The significance of Safety & Health in plant has been a vital issue in achieving productivity and quality standard. Following are basic fundamental principles properly underlie all the workers working in the plant. Consideration of each should be encouraged before beginning work as part of the culture of safety within the plant.  Plan ahead. Determine the potential hazards associated with production.  Minimize exposure to chemicals. Do not allow toxic chemicals to come in contact with skin. Provide proper ventilation devices to prevent/minimize airborne.  Do not underestimate hazards or risks. Assume that any mixture of chemicals will be more toxic than its most toxic component. Treat all the chemicals as toxic substances.  Be prepared for accidents. Before beginning of any batch reaction, know what specific steps to take which cause to accident if any hazardous substance release accidently. Proper follow SOP- Standard Operating procedure to take batch reaction. Unit will assess is careful examination of what, at work, could cause harm to workers, accidents and ill health. All risks in the workplace must be identified and assessed for control measures to be put in place. Follow the five steps of hazard identification will be taken by unit namely;  Identify the hazards  Decide who might be harmed and how  Evaluate the risks and decide on precaution  Record your findings and implement them  Review your assessment and update if necessary

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Following Information workers should know regarding hazardous chemicals Unit shall ensure that the employee is adequately trained with regard to:  The contents of the hazardous chemical substances  Potential source exposure to chemicals  Measures taken by the employer to protect employees against any risk from exposure  Precautions to be taken by an employee to protect himself against the health risks associated exposure  Correct use, maintenance of safety equipment, facilities and engineering controls  Importance of good housekeeping at the workplace & personal hygiene  Safe working procedures  Procedures to be followed in the event of spillages or leakages. EMERGENCY MANAGEMENT PLAN (EMP) Emergency Management Plan (EMP) for Orgosynth Chemicals is proposed here to meet the extremely adverse situations caused by the various hazardous accident scenarios. Mock drills are to be carried out in association with district authorities. Any weak points observed during the mock drills are to be strengthened. 7.18 DISASTER MANAGEMENT PLAN (DMP) Disaster/Emergency Management Plan is essential for a chemical plant as the processes adopted for manufacturing are classified under Factory Act as Hazardous due to handling and storage of toxic/ hazardous materials. Primarily, DMP is prepared to furnish details which may require at the time of the emergency, to delegate responsibility, to estimate the consequences in advance and to prepare ourselves to control any type of emergency. The plan explains basic requirements as follows:  Definition,  Action on site,  Objectives,  Link with Off-site Emergency Plan,  Organization set up,  Training rehearsal and record aspect.  Communication System,

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7.18.1 Definitions Various definitions on different analogy used on On-site & Off-site Emergency Plan are as follows: Accident: An accident may be defined as “an undesirable and unplanned event with or without or major damage consequence of life and /or property. Major Accident: It is a sudden, unexpected, unplanned event resulting from uncontrolled developments during an industrial activity, which causes or has the potential to cause, death or hospitalization to a number of people, damage to environment, evacuation of local population or any combination of above effects. Emergency: This can be defined as any situation, which presents a threat to safety of person's or/and property. It may require outside help. Major Emergency: Occurring at a work is one that may affect several departments within and/or may cause serious injuries, loss of life, extensive damage to properly or serious disruption outside the works. It will require the use of outside resources to handle it effectively. Disaster: Disaster is a sudden calamitous event, bringing great damage, loss or destruction. Hazards: Hazard may be defined as “the potential of an accident”. Hazard exists in man and the system of materials and machines. Chemical Hazards: It is a hazard due to chemical(s) (including its storage, process, handling, etc.) and it is realized by fire, explosion, toxicity, corrosively, radiation, etc. Risk: Risk may be defined as the combination of consequence and probability or likelihood of an accident being caused in a given man- material – machine system. On-Site Emergency plan: It deals with measures to prevent and control emergencies within the factory and not affecting outside public or environment. Off-Site Emergency plan: It deals with measures to prevent and control emergencies affecting public & environment outside the premises.

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7.18.2 Objective of the Disaster Management Plan The DMP document is prepared keeping in view and to confirm the requirements of the provisions of The Factories Act, 1948, Guidelines issued by the MoEFCC and MSIHC, 1989 amended in 2000, Schedule 11 under EP Act, 1986. Following are the main objectives of the plan to:  Defined and assess emergencies, including hazards and risk  Control and contain incidents.  Safeguard employees and people in vicinity.  Minimize damage to property and/or the environment.  Minimization of risk and impact of event accident.  Preparation of action plan to handle disasters and to contain damage.  Inform employees, the general public and the authority about the hazards/risk assessed and to provide safeguard, and the role to be played by them in the event of emergency.  Be ready for 'mutual aid' if need arises to help neighboring unit.  Inform authorities and mutual aid centres to come for help.  Effect rescue and treatment of casualties.  Effective rehabilitation of the affected persons and prevention of damage to the property.  Secure the safe rehabilitation of affected areas and to restore normalcy.  Provide authoritative information to the news media. 7.19 ONSITE EMERGENCY PLAN 7.19.1 Incident Controller Incident Controller‟s role is to control the emergency at the incident site. 7.19.1.1 Duties of Incident Controller Incident Controller will proceed to the place of emergency after hearing siren/announcement. He will:  Assess the scale of emergency and decide if a major emergency exists or is likely, accordingly activate emergency procedure.  Immediately give his feedback to Emergency Control Centre (ECC) regarding emergency.  Direct all operations within the area with following priorities. o Secure the safety of personnel

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o Minimize damage to plant property and environment. o Minimize loss of material.  Direct rescue and firefighting operations till the arrival of the outside Fire Brigade; he will relinquish control to Sr. Officer of Fire Brigade.  Ensure that the affected area is searched for causalities.  Ensure that all non-essential workers in the affected area evacuate to the appropriate assembly point.  Set up communication point to establish Radio/Telephone/Messenger contact as with emergency control centre.  Pending arrival of works site controller, assume the duties of the post in particular to: o Direct the shutting down and evacuation of plant and areas likely to be threatened by emergency. o Ensure that the outside emergency services have been called in.  Ensure that the key personnel have been called in.  Report all significant development to the Site Main Controller.  Provide advice and information, as required to the Senior Officer of the Fire Brigade.  Preserve evidence that would facilitate any subsequent inquiry into the cause and circumstances of emergency. Dy. Incident Controller will carry out above said duties in absence of Incident Controller. 7.19.2 Site Main Controller Site Main Controller will be overall in-charge of emergency organization 7.19.2.1 Duties of Site Main Controller:  Relieve the Incident Controller of responsibility of overall main control.  Co-ordinate ECC or if required, security for raising evacuation siren and also all clear siren, in case emergency is over.  Declaration of major emergency ensures that outside emergency services will be called and when required nearby firms will be informed.  Ensure that key personnel will be called in.  Exercise direct operational control on parts of the works outside the affected area.

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 Maintain a speculative continuous review of possible development and assess these to determine most possible cause of events.  Direct the shutting down and evacuation of plants in consultation with key personnel.  Ensure causalities are receiving adequate attention; arrange for additional help if required. Ensure relatives are advised.  Ensure the accounting of personnel.  Control traffic movement within the work.  Arrange for a chronological record of the emergency to be maintained.  During prolonged emergency, arrange for the relief of the personnel and provision of catering facilities.  Contact the local office to receive early notification of impending changes in weather conditions, in case of prolonged emergency.  Issue authorized statements to the news media and informs H.O.  Ensure that proper consideration is given.  Control rehabilitation of affected areas after control of the emergency. 7.19.3 Other Key Personnel The key personnel required for taking decision about further action for shutting down the plant, evacuate the personnel, and carry out emergency engineering works in consultation with Site Main Controller in light of the information received. HOD‟s/Senior Managers/ Section Heads will be responsible for safety, security, fire, gas and pollution control, spillage control, communication system including telephone, wireless etc. Also medical services, transport, engineering, production, technical services, will form part of advising team. 7.19.3.1 Emergency Response Team The role of Emergency Response Team members is to actually combat the emergency at the site and control the emergency situation and carry out rescue operations. All team members will be thoroughly trained to deal with fires, explosions, chemical spills and atmospheric releases, first aid. As per priority list during emergency, the activities will be carried out as per emergency control plan.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-43 San Envirotech Pvt. Ltd., Ahmedabad

7.19.3.2 Emergency Personnel’s Responsibilities outside Normal Working Hours of the Factory The duties of Shift In-charge & team members have been brought out in emergency control plan. All team members after evacuating the area shall report to ECC/ Incident Place. The non-essential workers shall be evacuated from the plants if need arises and this will be determined with the forcible rate with which incident may escalate. Non-essential workers shall assemble at the earmarked/specified point of assembly. 7.19.3.3 Assembly Points At the plant, at least 2 assembly points will be identified and marked properly. 7.19.4 Emergency Control Centre It will be headed by Site Main Controller, HOD – PD, HOD-P&A and it is sited in Office of Site Main Controller in Admin Building & security office (after office hours), which is readily accessible & with minimum risk, equipped with telephone facilities and other announcements extra communications facilities needed. It has enough means to receive and transmit information and directions from site main controller to incident controller and other areas. In emergency, control centre due to its safer location and advantage of easier accessibility, all necessary personnel protective equipments, fire-fighting extinguishers will be stocked in sufficient quantity. 7.19.4.1 Role of Emergency Control Centre In case of mishap or accident like fire, toxic gas leakage, explosion in the factory, The Emergency Control Centre will be Office of Head-Operations.  The plot plan indicating all the activities in the factory premises including that of storage‟s utility services, production area, administration, will be kept for ready reference, showing the location of fire hydrant and fire-fighting aids.  Normal roll of employees, work permits, gate entries and documents for head count, employees blood group, other information and addresses will be available and the person, who will handle this operation will HOD P&A.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-44 San Envirotech Pvt. Ltd., Ahmedabad

 Stationery required is available in the Control Centre (ECC) and HOD (P & A) looks after it.  The requirement of PPEs and other material, like torches, have been worked out and the quantity required during emergency will be kept in the Control Room (ECC). The responsible person for maintaining the said requirement/inventory will be HOD-HSE. 7.19.5 Fire & Toxicity Control Arrangements The plant will be well equipped with suitable numbers of fire-fighting and personnel protective equipment. The staff will be trained regularly to handle the various emergency situations. 7.19.6 Medical Arrangements Availability of first aid facilities in sufficient quantity will be always ensured. In case of emergency arrangements will be made to avail outside medical help immediately. Emergency transport facility will be available. 7.19.7 Transport & Evacuation, Mutual Aid Arrangements Transport & Evacuation and Mutual Aid arrangements will be available in the factory. 7.20 COMMUNICATION SYSTEM 7.20.1 Declaring the Emergency In case of any emergency in the plant, speedy and effective communication of the same to all concerned in least possible time is the most important aspect of any emergency-handling plan. An early communication increases the chances of control of emergency in the bud stage. Blowing siren will be adopted as method of communication of emergency, to all employees in the plant. 7.20.1.1 Type of Sirens Three different types of sirens have been identified for communication of emergency. Alert Siren: Single Continuous Siren for One Minute. This indicates that there is some accidental happening in the plant. All have to become alert. Incident controller will be rush to the site of emergency. Plant area people have to start safe shut down. Rescue team and other emergency control teams have to reach at the site of emergency.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-45 San Envirotech Pvt. Ltd., Ahmedabad

Siren for evacuation: wailing & waning siren for three minutes. This siren indicates that emergency is of serious proportion and everybody has to leave his work place. All people having their role in emergency control have to assume their assigned role. All non-essential workers have to proceed immediately to assembly area and wait for further instruction. All clear siren: Long continuous siren for two minutes. This is a sign of return of normalcy. On hearing this siren everybody should go back to his or her respective workplace. 7.20.1.2 Location of Siren Siren will be located in centre of the plant for wide coverage of the whole campus. The switch at Security gate should be operated only as a general rule. Emergency manual call bell will be installed which will be used in case of total failure of electricity. It is responsibility of HOD (HSE) to maintain the upkeep of electric call bell and HOD-Security and administration to maintain manual and hand operated siren. 7.20.1.3 Raising Alarm Any person noticing any emergency situation in the plant should immediately call security gate with following information:  Identify oneself  State briefly the type of emergency  Give the location of the incident  Estimated severity of the incident Security personnel after ensuring genuineness of the call shall raise the ALERT SIREN. At the same time he will also contact the incident controller and ECC in order and inform about the incident. He will keep the gate open and rush his two security personnel at the site of emergency with appropriate PPEs. ECC will be located at the office of Head-Operations on normal working hours and at Security gate after normal working hours (during night). ECC shall be immediately manned on hearing alert siren. If the authorized people to handle ECC are not available, any senior most people out of the available person nearby shall occupy ECC till authorized person comes. Incident controller, on hearing alert siren or by any other way of information of the emergency, will

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-46 San Envirotech Pvt. Ltd., Ahmedabad

immediately reach at the site of incident and assess the situation. He will immediately give his feed back to ECC. ECC shall direct security gate to raise evacuation siren, if the need arise. SIREN FOR EVACUATION shall be raised on instruction from Site Main Controller or any Manager of the plant in the ECC. Security gate person will be authorized to raise ALL CLEAR SIREN on instruction from Site Main Controller or ECC, after the emergency is over. Incident controller shall assume the responsibility of site main controller in his absence. 7.20.2 Internal Communication It shall be responsibility of ECC to communicate to all employees in the plant. They may take help of telephone operator for such communication. However, telephone operator can directly communicate information about emergency to all internal departments, if such message comes from incident controller or site main controller. Telephone operator will continue to operate the switchboard advising the callers that staffs are not available and pass all calls connected with the incident to ECC. 7.20.2.1 Availability of Key Personnel outside Normal Working Hours The details of key personnel availability after working hours will be made available at Security Gate, ECC, telephone operator as well as production units. Security personnel shall call required key personnel from their residence in case emergency occurs outside normal working hours. Availability of emergency vehicle/Ambulance will be ensured to fetch the key personnel residing outside. It will be the responsibility of HOD (P & A) to maintain it. To the Outside Emergency Services Decision to call outside help to deal with emergency like fire brigade, ambulance, police, etc., shall be taken by Site Main Controller. However, in absence of Site Main Controller, if the incident controller realizes the situation going out of control, he may ask for immediate help from outside. ECC will be responsible for calling help from outside. A list of emergency services available in the area with their telephone numbers will be provided at ECC, at Security gate and with telephone operator. Facilities such as phones, emergency vehicle, and security personnel will be available to help calling outside emergency services and authorities.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-47 San Envirotech Pvt. Ltd., Ahmedabad

7.20.3 Communication to the Authorities The emergency will be immediately communicated to the government officers and other authorities such as SPCB, police, district emergency authority, Factory Inspectorate, hospital etc. by Emergency Control Centre. Communication to Neighboring Firms & the General Public In case of emergency having its outside impact, public will be cautioned regarding the same. Co-ordination of police will be sought for speedy action. This is to be ensured by ECC. 7.21 Pre-emergency activities Internal Safety survey with regard to identification of hazards, availability of protective equipment‟s, checking for proper installation of safety devices will be carried out periodically.  Periodic pressure testing of equipment & testing of lines  Periodic safety/relief valve testing & fire hydrant system testing  Mock drill to check up level of confidence, extent of preparedness of personnel to face emergency is being contemplated  Regular training is being imparted to all personnel to create awareness  Adequate safety equipment will be made available  Periodic check-up of emergency lights  Storage of adequate first aid treatment facilities 7.22 POST-EMERGENCY ACTIVITIES Following post emergency actions will be carried out to study in detail and preventive measures to be taken-  Collection of records, Inquiries  Insurance claims  Preparation of reports comprising suggestion and modification  Rehabilitation of affected personnel  Normalization of plant 7.22.1 Evacuation and Transportation In case of emergency, evacuation and transportation of non-essential workers will be carried out immediately. The affected personnel will be transported for medical aid. 7.22.2 Safe Close Down

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-48 San Envirotech Pvt. Ltd., Ahmedabad

During emergency plant shut down will be carried out if situation warrants. This will be as per the instruction of site main controller under guidance of incident controller. 7.22.3 Use of Mutual Aid Mutual aid agreement with nearby industries will be ensures to provide help to each other in the emergency, 7.22.4 Use of External Authorities As and when necessary, statutory authorities, police, pollution control personnel, medical aid/centre, ambulance etc. will be contacted. 7.22.5 Medical Treatment The affected personnel will be brought to safer place immediately to give them first aid. Immediate medical attention will be sought. 7.22.6 Accounting for Personnel Proper accounting for personnel will be laid down in all the shifts. The number of persons present inside the plant premises, their duty etc. will be available with the P&A. This record will be regularly updated and will be made available. 7.22.7 Access to Records The relatives of affected personnel will be informed. The details regarding all employees will be made available to Administration building. 7.22.8 Public Relations In case of emergency, Manager P&A will be available for official release of information pertaining to the incident. 7.22.9 Rehabilitation The affected area will be cleared from emergency activities only after positive ascertaining of the system in all respects. The entry to affected area will have to be restricted until statutory authorities visit and inspect the spot of incident. Nothing should be disturbed from the area till their clearance. The site main controller will be in charge of the activities to be undertaken. The plan will cover emergencies, which can be brought under control by the works with the help of emergency team/fire services. The DISASTER CONTROL PLAN for gas leak and fire will be prepared.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-49 San Envirotech Pvt. Ltd., Ahmedabad

7.23 CAUSES OF EMERGENCY 7.23.1 Risk 7.23.1.1 Nature In the plant, the nature of dangerous events could be of the following:  Fire : Chemical/Electrical  Toxic Release : From chemicals  Leakages : Equipment, pipe lines, valves, etc. Release of vapours of gases can result in highly toxic environment or in fire or explosion.  Improper handling of products (raw materials/finished products)  Large spillage to ground floors resulting in pollution & fire.  Failures of Equipment/Instruments.  Release of safety valves or ruptures of vessels due to excessive pressures. 7.23.1.2 Various Emergency Actions a) Onsite  Safe shut down of the plant and utilities  Emergency control measures.  To attempt with the help of trained crew in firefighting to contain the fire spread up/gas emission and limit within limited space.  To cut off source of oxygen by use of firefighting appliances/to cut off source of gas emission.  Cut off fall sources of ignition like electrical gadgets.  To protect fire prone area from the fire.  To remove material this can catch fire to the extent possible from fire prone area.  Evacuation of non-essential persons.

b) Medical Facilities/Treatment  Part time doctor will be appointed by the unit, who will visit the plant periodically. Vehicle will be available round the clock. Ambulance will be also made available in the campus on regular basis. c) In the event of Fatal Accidents The information shall be given to following authorities:

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-50 San Envirotech Pvt. Ltd., Ahmedabad

 Inspector of Police  Regd. Office  Inspector of Factories  Insurance the plant  Mamlatdar  Regional Officer, SPCB  Corporate Office d) Emergency Siren Emergency siren shall be blown for announcing the emergency which shall have different sound for identification/differentiation than the normally used for commencement of factory working etc.  Location of Siren Above Plant  Type of Siren Industrial Siren  Position of siren switch Located at Main Gate e) Seeking help from neighboring industries/sources for fire engine f) Advise for vacation of other areas  Since the effect of fire/gas emission shall be contained within the area of the plant advice of vacation of other areas is not necessary. 7.23.1.3 Response Time-Minutes

Hazard Fire Fighting Police Medical Services Fire & Immediate with whatever 10 10 minutes Explosion facilities available with the plant min. External Help within 15 minutes

7.24 OFF-SITE EMERGENCY PLAN 7.24.1 Need of the Site Emergency Plan Depending upon the wind direction and velocity of the effects of accident in factory may spread to outside its premises. To avert major disaster it is essential to seek guidance/assistance of statutory authorities, police and health department. The movement of traffic may have to be restricted. Required information will be given to the authority and consultation will be sought for remedial measures. A purpose of the off-site emergency plan is:  To provide the local/district authorities, police, fire, brigade, doctors, surrounding industries and public the basic information of risk and environmental impact assessment and appraise them of the consequences and the protection/prevention measures and to seek their help to communicate with public in case of major emergency.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-51 San Envirotech Pvt. Ltd., Ahmedabad

 To assist district authorities for preparing the off-site emergency plan for district or particular area and to organize rehearsals from time to time and initiate corrective actions on experience. 7.24.2 Structure of the Off-Site Emergency Plan Available with concerned authorities. 7.24.3 Role of the Factory Management The site main controller will provide a copy of action plan to the statutory authorities in order to facilitate preparedness of district/area off-site emergency plan. 7.24.4 Role of Emergency Co-ordination Office (ECO) He will be a senior police or fire officer co-ordination with site main controller. He will utilize emergency control centre. 7.24.5 Role of Local Authority Preparation of Off Site Plan lies with local authorities. An emergency- planning officer (EPO) works to obtain relevant information for preparing basis for the plan and ensures that all those organization involved in offsite emergency and to know their role and responsibilities. 7.24.6 Role of Fire Authorities The fire authorities will take over the site responsibility from incident controller after arrival. They will be familiarized with site of flammable materials, water and foam applies points, fire-fighting equipment. 7.24.7 Role of the Police and Evacuation Authorities Senior Police Officer designated, as emergency co-ordination officer shall take over all control of an emergency. The duties include protection of life, property and control of traffic movement. Their functions include controlling standards, evacuating public and identifying dead and dealing with casualties and informing relatives of dead or injured. There may be separate authorities/agencies to carry out evacuation and transportation work. Evacuation depends upon the nature of accident, in case of fire only neighboring localities shall be alerted. Whole areas have to be evacuated in case of toxic release. 7.24.8 Role of Health Authorities After assessing the extent of effect caused to a person the health authorities will treat them.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-52 San Envirotech Pvt. Ltd., Ahmedabad

7.24.9 Role of Mutual Aid Agencies Various types of mutual aid available from the surrounding factories and other agencies will be utilized. 7.24.10 Role of Factory Inspectorate In the event of an accident, the Factory Inspector will assist the District Emergency Authority for information and helping in getting Neighbouring Industries/mutual aid from surrounding factories. Factory Inspector may wish to ensure that the affected areas are rehabilitated safely. 7.25 MOCK DRILLS AND RECORDS 7.25.1 Need of Rehearsal & Training Regular training and rehearsal program of emergency procedures shall be conducted with elaborate discussions and testing of action plan with mock drill. If necessary, the co-operation/guidance of outside agencies will be sought. 7.25.2 Some Check Points  The extent of realistic nature of incidents.  Availability of sufficient resources such as water, fire-fighting aids, personnel.  Logical sequences of actions.  The involvement of key personnel in the preparation of plan.  Satisfactory co-operation with local emergency services and district or regional emergency planning offices. 7.25.3 Records and Updating the Plan All records of various on-site and off-site emergency plans of the factory will be useful alone with those of the factors by which statutory authorities draw a detailed plan for the whole area/district. The records of the activity will be updated regularly.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-53 San Envirotech Pvt. Ltd., Ahmedabad

C. SOCIAL IMPACT ASSESSMENT There will be no Rehabilitation & Resettlement (R&R) involved as there is no habitation or livestock in the acquired land. Around 30-50 workers will be employed in the construction work. During the operational phase, around 100 nos. of manpower will be employed. However, preference will be given to local people for employment. Social Corporate Responsibilities Corporate Environmental Responsibility (CER) refers to a company‟s duties to withdraw from damaging natural environments. These efforts can range from donating money to non-profits to implementing environmentally-friendly policies in the workplace. The group's CER activities are rooted in the knowledge that businesses have a duty to enable all living beings to get a fair share of the planet's resources. Survey Methodology The survey aims to document the living conditions, level of socio- economic development of the region and the socio-economic profile of people in the core and buffer zones of the study area. The village level data were collected from Census. Study of Village Profile This study includes village level survey of Population, Economics, Land use Pattern, Employment pattern, Healthcare Facilities, Amenities for Livelihood. Sources of Information As per the scope of present study, the information on the sociological aspects like demography, human settlements, social aspects like SC & ST population, literacy levels and economic aspects like occupational structure of workers has been gathered and complied from secondary sources viz. the District Census Statistical Handbook, 2011 as these documents being comprehensive and authentic. Socio Economic Survey within study area: The study area in 10 km radius has 63 villages including project site. The total no. of household in the villages are 16882 and the total population is 70247 (51.71% men & 48.29% women).

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-54 San Envirotech Pvt. Ltd., Ahmedabad

1) Educational facility Literacy is an important indicator for understanding the socio-economic development of any area. 73.11% of are literate while literacy rate among women & men is 78.12% & 67.74% respectively. 45.60% of male population is part of main worker, while only 23.64% of female population is a part of main workers. 6.06% of male workers are marginal workers, while 9.93% of female workers are engaged in such type of activities. 42.36% of male population and 63.41% of female population are non-workers. Many villages of study area have no proper education facility and literacy rate is very low especially in women. As per 2011 census, there are primary school in all 63 villages, 56 Pre-primary schools, 18 Secondary schools, 12 Senior Secondary schools in the given 10 km study area. Keeping in view of the industrialization around these villages and there is need of semi-skilled and skilled labor for the industrial units. Unit will motivate educational activities by awarding meritorious school students in SSC & HSC, science lab-equipment & books in libraries for schools, supports for sport & cultural competitions in schools. Women bear larger losses in terms of educational attainment, employment & wages. Thus, more focus will be on women education considering gap in literacy rate & employment rate. 2) Health & Family welfare 63 villages in the study area have 4 primary health centers, 14 primary health sub centers, 2 Maternity & Child Welfare Centre and 2 Veterinary Hospital in study area. Unit will contribute in health checkup camps organized by different agencies by providing man, medicine and money. 3) Preservation of Environment and Sustainable Development For Preservation of Environment, unit will promote tree plantation in surrounding villages. Unit will promote uses of non-conventional source of energy i.e. solar power. Additionally, unit will raise awareness and promote rain water harvesting in nearby villages.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-55 San Envirotech Pvt. Ltd., Ahmedabad

Details of expenditure for CER activities: Estimated cost of the project : Rs. 20.25 Crores Expenditure earmarked towards CER : Rs. 40.5 Lakhs (2% of the project cost) Proposed activities are shown below. Table 7.13: Detailed expenditure break-up for CER activities

Sr. Activities Years (Rs. in Lakhs) Total Budget No. 1st 2nd 3rd 4th 5th (Rs. in Lakhs) 1 Educational activities 2.0 2.0 2.0 2.0 2.0 10.0 2 Health and Family 1.0 1.0 1.0 1.0 1.0 5.0 Welfare Facilities 3 Drinking water and 2.0 2.0 2.0 2.0 2.0 10.0 sanitation facilities 4 Women Empowerment & 0.6 0.6 0.6 0.6 0.6 3.0 children Development activities 5 Preservation of 2.5 2.5 2.5 2.5 2.5 12.5 Environment and Sustainable Development Total 8.10 8.10 8.10 8.10 8.10 40.5

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 7-56 San Envirotech Pvt. Ltd., Ahmedabad Chapter-8 Project Benefits

8.1 INTRODUCTION Project benefit focus on those points which will become beneficial to the surrounding area or community in terms of infrastructural development, social development, employment and other tangible benefits due to project. Proposed project of M/s. Orgosynth Chemicals Pvt. Ltd. has a potential for employment of skilled, semi-skilled and unskilled employees during construction phase as well as operational phase. 8.2 IMPROVEMENT IN PHYSICAL INFRASTRUCTURE Proposed project of Orgosynth Chemicals Pvt. Ltd. will have requirement of an infrastructure, so direct benefits of infrastructure development is anticipated. The project proposes to employ local people which will help to increase the income of local people & improve their living standard. The construction and commissioning phase will require a substantial manpower and resources. Hence, with the growth in the economic conditions, the project may lead to growth in the social stature & improvement of the quality of life in the surrounding area. It will also help in improvement in local amenities. Thus, the project will have considerable indirect benefits to the public physical infrastructures. 8.3 IMPROVEMENT IN SOCIAL INFRASTRUCTURE The company will conduct social welfare activities which include the funding & contribution for public infrastructure/facilities development, maintenance & improvement on basis of as & when required. Due to proposed project activity of unit, social infrastructure will improve by means of civilization, vocational training and basic amenities. Civilization: Due to the project, employment and other infrastructural facilities will boost up income of surrounding people and improve quality of life. This will indirectly boost up the civilization of the surrounding people. Vocational Training: Unit will provide vocational training opportunity to the surrounding people and motivate the education activities that will

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 8-1 San Envirotech Pvt. Ltd., Ahmedabad

lead the change in life style of the surrounding, hence, improving social infrastructure. Basic Amenities: Unit will consider providing or improving education facilities, healthcare, and drinking water facilities in the area, which will help in uplifting the living standards of local communities. 8.4 EMPLOYMENT POTENTIAL In the construction phase, direct and indirect manpower will be involved. Thus temporary and permanent employment will be generated during construction phase. The proposed manpower requirement during construction will be 30-50 nos. During the operation phase, 100 nos. of skilled and unskilled manpower will be required. Moreover, unit will provide first priority to local workers for the employment. Further, the indirect employment via increased transportation, ancillary units & local economic activities will also add in the employment potential of the project. Thus, the unit will result in considerable benefits in terms of employment. 8.5 OTHER TANGIBLE BENEFITS In addition to mentioned above, the project will have many employment & trade opportunities, which will eventually result in appreciable economic benefits to the local people & businesses/contractors. Indirectly, the project will help the Government by paying different taxes from time to time, which is a part of revenue and thus, will help in developing the area. M/s. Orgosynth Chemicals Pvt. Ltd. has proposed to spend about Rs. 40.5 Lakhs (i.e. 2.0% of project cost) towards various CER activities which will be considerably beneficial to the surrounding area. Detailed Expenditure break-up for CER activities

Sr. Activities Years (Rs. in Lakhs) Total Budget No. 1st 2nd 3rd 4th 5th (Rs. in Lakhs) 1 Educational activities 2.0 2.0 2.0 2.0 2.0 10.0 2 Health and Family 1.0 1.0 1.0 1.0 1.0 5.0 Welfare Facilities 3 Drinking water and 2.0 2.0 2.0 2.0 2.0 10.0 sanitation facilities 4 Women Empowerment & 0.6 0.6 0.6 0.6 0.6 3.0 children Development

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 8-2 San Envirotech Pvt. Ltd., Ahmedabad

activities 5 Preservation of 2.5 2.5 2.5 2.5 2.5 12.5 Environment and Sustainable Development Total 8.10 8.10 8.10 8.10 8.10 40.5

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 8-3 San Envirotech Pvt. Ltd., Ahmedabad Chapter-9

Environmental Cost Benefit Analysis

As per EIA Notification 2006, this Chapter of the ‘Environmental Cost Benefit Analysis’ is applicable only if it is recommended at the Scoping stage. As per the standard ToR issued by MoEF&CC, New Delhi vide File No. IA-J- 11011/249/2020-IA-II(I) dated 26.10.2020, the Environmental Cost Benefit Analysis is not applicable and hence has not been prepared.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 9-1 San Envirotech Pvt. Ltd., Ahmedabad Chapter-10

Environment Management Plan

10.1 INTRODUCTION Assessment of environmental and social impacts arising due to implementation of the project activities is the technical heart of EIA process. An equally essential element of this process is to develop measures to eliminate, offset or reduce impacts to acceptable levels during implementation and operation of projects. The integration of such measures into project implementation and operation is supported by clearly defining the environmental requirements within an Environment Management Plan (EMP). The EMP of M/s. Orgosynth Chemicals Pvt. Ltd. has been formulated considering all necessary mitigation measures to prevent/ minimize/ eliminate environmental impacts associated with the proposed activities. Unit will develop an Environment Management Cell to keep a close watch on the performance of the pollution control equipments, emissions from the sources and the quality of surrounding environment in accordance with the monitoring program. OBJECTIVE OF ENVIRONMENT MANAGEMENT PLAN The EMP is prepared with the main objective of enlisting all the requirements to ensure effective mitigation of adverse impacts for all the components of the proposed project. The key objectives of the Environment Management Plan are, . To limit/reduce the degree, extent, magnitude or duration of adverse impacts, . To treat all the pollutants i.e. liquid effluent, air emissions and hazardous waste with adoption of adequate and efficient technology, . To reduce risk/hazards and design the disaster management plan, . To make budgetary provision and allocation of funds for environment management system and for timely revision of budgetary provisions. 10.2 ENVIRONMENTAL MANAGEMENT DURING CONSTRUCTION PHASE Construction phase results in temporary environmental pollution except for the permanent change in local land use pattern & aesthetics in certain

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-1 San Envirotech Pvt. Ltd., Ahmedabad cases. Such pollution is mainly due to site preparation, civil works, transportation, storage & handling of construction materials, construction worker’s sanitation etc. These are usually short-term impacts. 10.2.1 Air and Noise Environment During construction work, air pollution is expected in the form of increased suspended particulate matter concentration. Installation work will generate noise and dust, but it will be within working areas. Vehicular movement in the premises will also generate dust. To mitigate the impact, following measures will be taken:  Regular sprinkling of the water will be done.  Regular preventing maintenance of machinery and transportation vehicles will be carried out.  Provision of silencer to noise generating machines, if required, and  Noise protection devices such as earmuffs/earplugs will be provided to workers working in noisy area. 10.2.2 Water Environment During construction phase, water will be provided to workers for their requirement & for construction activity. Water supply will be met from Madhya Pradesh Industrial Development Corporation Limited (MPIDC). Portable sanitation facilities will be provided to maintain proper standards of hygiene. These facilities would preferably be connected to a septic tank and shall be maintained properly to have least environmental impact. 10.2.3 Socio-Economic Environment The proposed manpower requirement during construction phase will be 30-50 nos. Unit will give preference to local people through both direct and indirect employment. 10.2.4 Health and Safety Adequate rest area will be provided to the construction workers and truck drivers. Unit will also supply potable water and portable sanitation facilities. The safety department will supervise the safe working of the contractor and their employees. Work spots will be maintained clean, provided with optimum lighting and enough ventilation to eliminate dust/fumes.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-2 San Envirotech Pvt. Ltd., Ahmedabad 10.3 ENVIRONMENTAL MANAGEMENT DURING THE OPERATIONAL PHASE EMP proposed for implementation is detailed under the following heads:  Air Pollution Management  Wastewater Management  Solid/Hazardous Waste Management  Noise Management  Greenbelt Development  Occupational Safety and Health  Implementation of EMP and monitoring programme 10.3.1 Air Pollution Management 10.3.1.1 Source of Air Pollution and Control Measures Flue gas emission will be from stack attached to Boiler (6 TPH), one stack of Thermic Fluid Heater (20 Lakhs Kcal/hr.) and one stack of 2 nos. of stand by D.G. Sets (500 kVA x 2). Agro Briquettes/Coal will be used as a fuel in Boiler & TFH and HSD in stand by D.G. Set. Cyclone followed by bag filter will be installed as APCM with adequate stack height to achieve the emission norms. No need to install any APCM to stack of D.G. set as it will not be the constant source of emission. Most probable pollutants will

be SPM, SO2 and NOx. Process emission will be from 1 vent attached to process vessel of MPP- 1, two vents of process vessel of MPP-2 and 1 common vent attached to 6 nos. of Spin Flash Dryers. Pollutants from process stacks will be will be

PM, HCl, HBr and NH3. Process stack will be installed with Water Scrubber, Acid Scrubber and Alkali scrubber to achieve the emission standards, whereas to control particulate emission, In-built bag filter will be installed as APCM on Spin Flash Dryer. Furthermore, adequate stack height and facility for sampling such as ladder and sampling point will be provided as per the SPCB guidelines. Measures to control fugitive emission The fugitive pollutants of PM, VOCs & Acid mist are likely to emit from process area. Unit will adopt following measures,  Entire process will be carried out in closed reactors,  Close handling system provided for transfer of chemicals,

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-3 San Envirotech Pvt. Ltd., Ahmedabad  Pneumatically transfer of liquid raw material in reactor,  Raw material will be stored in the covered structure,  Regular maintenance of valves, pipes, etc.,  Provision dust suppression system (water sprinklers) to control air borne dust,  Fly ash will be stored in covered sheds only,  Internal road will be concreted/paved to reduce the fugitive emission during vehicular movement,  Greenbelt will be developed around the plant to arrest the fugitive emission,  Frequent work area monitoring will be done ensure fugitive emissions level. 10.3.1.2 Measures for Solvent Recovery Unit will recover solvents Ortho Chloro Benzene Methanol, Ethyl Acetate, MDC, N-Butanol and Toluene. Recovered solvent will be utilized in respective product.

Process Step of Solvent Recovery Most of the solvents as above shall be recovered from reaction vessels. Each reaction vessels shall have overhead condenser (primary and a vent condenser). The primary condenser shall have the utility connection of either cooling water (32-37°C) or chilled water (5-10°C) or both. Based on boiling point of solvent as per the table, the vent condenser shall have a utility connection of chilled water (5-10°C). By these measures the utilities in the condensers shall always be below the condensing temperature of various solvents and there for least vapour pressure or mole fraction at condensing temperature. Unit shall be using dry vaccum pump with vaccum control device to maintain constant pressure. Each vaccum device shall also have a knockout pot and a condenser before suction of the vaccum pump. 10.3.1.3 Odour Control Plan All solid raw materials shall be charged directly to reactor through special air lock hopper against slight negative pressure (in water column) so that no odour is emitted to the environment. Solid charging nozzle in reactor shall be projected inside so that it directly falls in to the solvent media,

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-4 San Envirotech Pvt. Ltd., Ahmedabad thereby eliminating carrying over of solid to vapour nozzle. Powder transfer system shall also be used wherever applicable to have zero loss of powder into the atmosphere. All liquid raw material handled in drum shall be cooled down before charging so as to minimize its vapour pressure and control of odour. Alternatively vacuum lock could also be used in day tank for transfer of liquid from drum (pumping under vacuum). Proper Personal Protective Equipment (PPEs) will be provided to the workers who are involved in handling odorous materials. 10.3.2 Water Environment Total water requirement (Industrial + Domestic + Greenbelt) will be 300 KLD; out of which 70 KLD will be fresh water requirement & 230 KLD will be recycle/treated water (RO Permeate & MEE Condensate). Unit will satisfy its fresh water requirement from MPIDC. Major water demand will be for industrial – mainly Process (130 KLD), Washing (10 KLD), Scrubber (30 KLD) and Utility (100 KLD). Water requirement for Domestic will be 10 KLD and Greenbelt will be 15 KLD. Effluent Management: Total trade effluent (242.7 KLD) will be taken into ETP, after treatment, entire effluent will be passed through RO. RO permeate (170 KLD) will be reused within premises and RO reject will be sent to MEE/ATFD. MEE condensate (60 KLD) will be reused. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD). Unit will built full-fledged ETP with capacity of 250 m3/day to treat effluent. Sewage (8.0 KLD) will be disposed into soak pit though septic tank. Thus, unit will achieve Zero Liquid Discharge (ZLD). Comprehensive details on the wastewater treatment are provided in Chapter 2. 10.3.3 Hazardous/Solid Waste Management Entire quantity of hazardous waste will be handled & disposed as per Hazardous & Other waste (Management & Transboundary Movement) Rules, 2016. ETP sludge & MEE salt will be sent to TSDF site for land filling. Spent Sulphuric Acid (45-70%), Spent Hydrochloric Acid (25-28%) and Hydrobromic Acid (25-28%) (85 MT/Month) will be partly reuse in- house and partly will be sold to actual users under Rule-9. Acetic Acid

and AlCl3 will be sold to actual users under Rule-9. Liq. Ammonia will be

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-5 San Envirotech Pvt. Ltd., Ahmedabad reused in-house in same or other products. Used lubricating oil will be used within premises or disposed by selling to registered re-processors and discarded barrels & liners will be disposed of by selling to registered recyclers. Unit will provide isolated area with impervious flooring & roof cover for the storage of hazardous waste. Details of hazardous waste disposal are given comprehensively in Chapter 2. Solid waste generation & Management: Fly ash generation will be around 120 MT/month. Dedicated storage facility will be made for Fly Ash storage. Fly ash will be sold to brick manufacturer working in 25 km radius from project site and also supplied to the companies for land leveling, conditioning & road construction, etc. Storage and Transportation of Solid/Hazardous Waste:  Proper Hazardous waste storage area with impervious flooring and covered shed is provided for storage of solid/hazardous waste.  Entire quantity of the hazardous waste is stored in the isolated hazardous waste storage area within premises having leachate collection system and roof cover. The storage yard shall be properly labeled for identification of wastes.  Hazardous waste shall not be stored for a period more than 90 days. Records of the same shall be maintained and make them available for inspection.  Properly packed & labeled waste shall be transported through dedicated vehicle to authorized TSDF facility. 10.3.4 Noise Control Unit proposes following noise control measures to minimize the impact of noise on the environment during the operational phase,  Noise suppression measures such as enclosures, buffers and/or protective measures should be provided, if required (wherever noise level is more than 90 dB (A)).  Extensive oiling, lubrication and preventive maintenance will be carried out for the machineries and equipments to reduce noise generation.  Silencers, anti-vibration pad, acoustic enclosure to equipment will be provided.  Acoustic enclosure shall be provided for D.G. set.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-6 San Envirotech Pvt. Ltd., Ahmedabad  PPEs like ear muff, ear plug will be provided to all workers working at noisy area.  The transportation contractor shall be informed to avoid unnecessary speeding of the vehicles inside the premises.  Areas with high noise levels will be identified and segregated where possible and will include prominently displayed caution boards.  Adequate greenbelt will be developed within industrial premises and around the periphery to prevent the noise pollution.  Periodic monitoring of noise levels as per post-project monitoring plan shall be done on regular basis. By taking measures as mentioned above, it is anticipated that noise levels in the plant will be maintained below the permissible limit. 10.3.5 Green Belt Development Greenbelt not only provides habitat for faunal species but also helps to suppress air and noise pollutants up to some extent. This will not only mitigate the ecological problem but also enhance the beauty of project area that will attract avifauna, small mammals & insect species, and by this way ecological balance can be maintained to great extent. Unit proposes to do extensive plantation in 5763 m2. Overall greenbelt area will be 33% of the total area of the project. Selection of Plant Species: Considering the environmental status of project area four main parameters like salinity, draught, fire resistance, species with faster growth rate and ever green nature will be considered while selecting the species. Facts considered during selection of plant species for greenbelt development are:  Agro climatic zone (Semi-arid to dry sub humid – as per CPCB) of the project area;  Evergreen species to mitigate cumulative impacts due to other industries also;  Type of pollutant (mainly air) likely to disperse from project activities;  Biological–filter Efficiency: Absorption of gases, Dust capturing and Noise control.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-7 San Envirotech Pvt. Ltd., Ahmedabad Plantation Technique: Following basic procedures will be followed for greening the area:  Since the project area having good quality soil for plantation. Species required approx. 1 m3 pit for soil enrichment;  Pit will be filled with imported soil with 3:1:1 the ratio of sand, silt and form yard manure;  Procure well grown saplings of recommended species from the nearby Forest Department nursery;  Make 1 m diameter ring bund around the planted saplings for water retention;  Watering of sapling will be species specific, therefore watering need to be done 2 days for a period of two years except during monsoons. Locations of the Proposed Greenbelt: As per the CPCB guideline, unit has to develop 33% of greenbelt area of total project land. Based on these criteria, unit proposes to do extensive plantation in 5763 m2 and around the project boundary. Plantation will be carried out around periphery, near / around built-up areas and along internal roads of the project area. Plant species suggested for Greenbelt and Landscaping at various locations are tabulated in Table 10.1. Table 10.1: Plant Species Suggested for Greenbelt

S. Scientific Name Common Ecological Type Location No. Name performance of Plant 1 Aegle marmelos Bel CN, DC Evergreen A 2 Azardirachta indica Neem CN, OGE, DC Evergreen A,B 3 Delbergia sissoo Shesham DC, DR, FR Evergreen A,B 4 Ficus bengalensis Banyan, CN, DC Evergreen B Vad 5 Ficus religiosa Peepal CN, OGE, DC Evergreen B 6 Tamarindus indica Emali CN, OGE, DC Evergreen B 7 Terminalia arjuna Arjun CN, OGE, DC Evergreen B Ecological performance: CN - Control Noise level, OGE–Absorb Gas Emission (Sexena 1991) and (Abbasi & Khan 2000), DC - Dust Controller (CPCB 2007). Location of Plant: A-Around built-up area and along internal road, B-on Project periphery/boundary

Design of Green Belt As far as possible, following guidelines will be considered in greenbelt development.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-8 San Envirotech Pvt. Ltd., Ahmedabad  The spacing between the trees will be maintained as per SPCB guideline i.e. 1 tree/4 sqm.  Spaces, so that the trees may grow vertically and slightly increase the effective height of the greenbelt.  Planting of trees in each row will be in staggered orientation.  The short trees (< 10 m height) will be planted in the first two rows (towards plant side) of the green belt. The tall trees (> 10 m height) will be planted in the outer three rows (away from plant side). Planting methodology The plantation shall be done in pits. The pit shall be refilled with soil after the planting. The sampling of healthy, nursery raised, seedlings in polythene containers shall be transported in baskets. Planting shall be done after first monsoon showers. The level of soil is about 10 cm above of ground level. The soil around the plant shall be pressed to form a low through. About 25 gm chemical fertilizers shall be added. Watering shall be continued after plantation if any dry spells follows. Planted area shall be inspected and mortality rate ensured for each species. The dead and drying plant shall be replaced by fresh seedlings. Selection of species for greenbelt For the development of greenbelt, plants having simple big leaves and native species are preferred to the plants. The plants are suitable for greenbelt development based on gaseous exchange capacity of foliage which is ascertained by the following characteristics:  The plant should be fast growing.  It should have thick canopy cover.  It should be perennial and evergreen.  It should have large leaf area index.  It should be indigenous.  It should be efficient in absorbing pollutants without significant effects on plant growth. The objectives of the industrial greenbelt are to improve the micro- environment. The success depends on the type of land available and selection of suitable tree species for pollution control. Selection of tree species for industrial areas is influenced by the nature of industry. The

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-9 San Envirotech Pvt. Ltd., Ahmedabad objective should be to ensure a green cover tolerating pollutant gases and solid particulates present in the atmosphere. It is also advisable to select suitable tree species and adopt simple techniques which require minimum investment and care. Greenbelt Development Programme & Budget Allocation:

Greenbelt will be developed within 5 yrs. Budget break-up is as per Table 10.2. Table 10.2: Budget for Proposed Greenbelt Development

Work or 1st 2nd 3rd 4th 5th Budget Activity Year Year Year Year Year (INR) Within Project Site, totally 1450 saplings will be planted (Approx. Cost @ INR 200 per sapling/plant) Saplings 290 290 290 290 290 290000 Required Amount 58000/- 58000/- 58000/- 58000/- 58000/- Total Budget 290000

Survival rate of trees and post plantation care Considering the availability of water and general survey of surrounding area, the survival rate is expected to be around 70-75%. Moreover, the wire net guards will be provided to protect the saplings. The same will be properly manured and watered so that it can grow well. Protection of plantation site:  Protection from grazing will be done by erecting tree guards around planted sapling.  Though the tree suggested for plantation will require very less water, however during the first year watering will be done twice in a day. There after watering will be done twice in a week.  The manuring will be done when plantation take up. For this propose cow dung will be dump in the pit. No other manuring will require for proposed plantation. Cow dung is easily available in the study area.  Damaged plants will be replaced with new plants.  Strict surveillance will be made to increase the survival rate of trees. 10.3.6 Occupational Health & Safety Plan To maintain high standard in Health, Safety and Environment, necessary key mitigation measures & action plan as EMP has been suggested as described below.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-10 San Envirotech Pvt. Ltd., Ahmedabad  Post-employment health check-up programs will be carried out on annually and all records & documents related with employee health check-up program will be maintained.  As per RA report, all risk control & prevention measures in the unit will be implemented.  Necessary PPEs, safety equipments/materials to ensure healthy & safe work conditions will be provided to employees.  The project does not envisage conditions that could lead to excess heating. Consequently, special requirements for protection against heat stress are not anticipated. However, ventilation for heat evacuation, suitable PPEs such as heat for occasional handling of heated equipment or materials.  All employees will be provided with required set of PPEs like ear plug, ear muff etc. where noise levels in excess of 80 dB(A)  It is recommend that Pre-employment health check-up programs shall be carried out for every new employee and all records & documents related with employee health check-up program shall be maintained by the proponent.  Safety documents, procedures, guidelines along with MSDS shall be provided to the associated/concerned personnel engaged in respective operational activities.  Training programs & safety audit shall be done on regular basis to prevent impacts of the operational activities on occupational health as well as to improve workplace condition & safe work system.  The proponent shall ensure implementation of emergency management plan with provision of fire-fighting equipment/facilities, first aid & medical facilities, evacuation procedures etc.  Proponent shall also ensure proper implementation & functioning as well as assess effectiveness of this safety & emergency system on regular basis throughout the project operation phase. Details of the separate isolated storage area: Unit will provide isolated storage area for corrosive chemicals. Details of storage are given in Table 7.1 of Chapter-7 of EIA report. All the raw materials are stored in isolated storage area and containers are tightly

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-11 San Envirotech Pvt. Ltd., Ahmedabad closed. The following precautions shall be taken to avoid foreseeable accident like spillage, fire and explosion hazards and to minimize the effect of any such accident and to combat the emergency at site level in case of emergency.  Various emergency spots in plant area will be identified and kept in sharp and alert watch.  Protective equipment will be regularly checked and will be kept easily accessible and easily workable during emergency.  Safety installations like available quantity of running water will be regularly watched.  Fire bucket and hose reels will be provided to withstand the fire.

 Various types of fire extinguishers such as (Foam type, water CO2

type, CO2 type) will be provided inside the factory premises.  Every pressure vessel will be provided with minimum one or more pressure relief devices.  The design of the valve is made in such a way that the breakage of any part will not obstruct force discharge of the liquid under pressure. Moreover, relief valves are tested and a periodic schedule for their testing shall be maintained. The defective valves will be removed if found unsafe for the operation. Plans for Periodic Medical Checkup  Part time doctor is periodically visited the plant for health check-up of each employee.  Pre-employment health check-up will be followed by periodical health check-up with special attention to occupational health.  Medical records of each employee will be maintained in prescribed format as per Factory Act.  The health check-up will be conducted as per the pre-designed format which will include chest X-rays, Audiometry, Spirometry, Vision Testing, ECG, Blood and urine test etc.  The work zone monitoring will be conducted on regular basis. Monitoring of the Occupational Injury & It’s Impact on workers The action plan will be prepared to monitor the injury to workers:  Each workplace will be evaluated for the existing work conditions.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-12 San Envirotech Pvt. Ltd., Ahmedabad  Unsafe Act &unsafe Practices will be identified.  Unsafe equipment, unsafe areas, etc., will be identified.  Area will be checked for proper Ventilation and Illumination.  Air-borne concentration of toxic chemicals will be measured and records will be kept.  Evaluation of training & on the job work.  Impact of the above mentioned unsafe conditions on workers will be studied and remedial measures for the same will be adopted. 10.4 POST-PROJECT ENVIRONMENTAL MONITORING The highlights of the integrated environmental monitoring plan are:  The stack monitoring facilities like ladder, platform and port-hole of all the stacks maintained in good condition.  Regular monitoring of all gaseous emissions from stacks & fugitive emissions in the process areas.  The performance of air pollution control equipment such as cyclones and scrubbers will be evaluated based on these monitoring results.  Water consumption in the unit recorded daily.  Analysis of untreated and treated effluent will be carried out regularly.  Performance of effluent treatment plant units, RO and MEE evaluated based on above analysis results.  Greenbelt properly maintained and new plantation programmes undertaken frequently.  Continued environmental awareness programmes carried out within the employees and also in the surrounding villages. Table 10.3: Environment Monitoring Plan

Nature of Frequency of Parameters No. of Method of Analysis analysis with its samples Monitoring analyzer Wastewater Monthly by pH, TDS, SS, 4-6 samples APHA- analysis external agency COD, BOD, Oil AWWA 23rd & Grease, etc. edition

Stack Monthly by PM, SO2, NOX, All stacks Stack Monitoring of external agency HCl, HBr, NH3 monitoring each stack kit

Ambient Air Monthly for 24 PM10, PM2.5, 3-5 locations RDS, Fine Quality hours or as per SO2, NOx, HCl, particulate Monitoring the statutory HBr, NH3 sampler conditions by

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-13 San Envirotech Pvt. Ltd., Ahmedabad

external agency Noise level Monthly as per Noise level 6-8 locations Sound Level the statutory (Nr. Main gate, Meter conditions by Nr. boiler, Nr. external agency D. G. Set, Process area) Work zone Monthly by RPM, VOCs, 2-3 locations Personal fugitive external agency acid mist sampler, monitoring VOC sampler Health As per the All workers check-up of statutory workers guideline **Budgetary provision for environment & safety management system has been made in the project planning with Rs. 1.84 Crores will be used for Environmental Management System and Rs. 2.37 Crores as recurring cost per annum. Rs. 5.0 Lakhs are allocated for Environment Monitoring.

10.4.1 Details of Work Place Air Quality Monitoring Plan Work zone monitoring will be carried out by independent competent third party every month. Records will be kept in Form No. 37 as per the Factories Rules. Location for samplings will be identified. Following information will be incorporated in the format for maintaining records of work zone monitoring:  Location/Operation monitored  Identified contaminant, Sampling instrument used  Number of Samples  Range of contaminant concentration as measured in sample  Average concentration  TWA concentration of contaminant  Reference method used for analysis  Number of workers exposed at the location being monitored  Signature of the person taking samples 10.5 ENVIRONMENT MANAGEMENT BUDGET ALLOCATION Total capital cost and recurring cost/annum earmarked for environment pollution control measures will be as under. Table 10.4: Budget Allocation for Environment Management Sr. Particulars Capital Cost Recurring Cost No. (Rs. in Lakhs) per annum (Rs. in Lakh) 1 Air Pollution Control 60 35 2 Water Pollution Control 85 135

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-14 San Envirotech Pvt. Ltd., Ahmedabad

3 Noise Pollution Control 1 0.5 4 Solid/Hazardous Waste Management 15 60 5 Environment Monitoring and 5 3 Management 6 Occupational Health 5 2 7 Green Belt Development Plan 3 0.5 8 Rain Water Harvesting System 10 1 Total 184 237

10.6 ENVIRONMENTAL MANAGEMENT CELL Unit will set up separate Environment Management Cell. The major duties & responsibilities of EMC will be as follows:  To implement the Environmental Management Plan,  To ensure regular operation & maintenance of APCM,  To assure regulatory compliance with all relevant rules & regulations,  To minimize environmental impacts by strict adherence to the EMP,  To initiate environmental monitoring as per approved schedule,  Review & interpretation of monitored results and corrective measures in case monitored results are above the specified limit,  Maintain documentation of good environmental practices and applicable environmental laws as ready reference,  Maintain environmental related records,  Coordination with regulatory agencies, external consultants and monitoring laboratories, and  Maintaining log of public complaints and the action taken 10.6.1 Hierarchical Structure of Environmental Management Cell The hierarchical structure is given below: Figure 10.1: Environment Management Cell

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-15 San Envirotech Pvt. Ltd., Ahmedabad 10.6.2 ENVIRONMENT POLICY There will be an Environment Policy approved by the management. They commit themselves to:  Ensure continuous improvement in environmental performance of our works through protective Environmental management system.  Comply with applicable legal and other requirements related to environmental aspects.  Conserve the resources particularly water, power by fixing and improving consumption norms.  Concept of cleaner production will be adopted.  Ensure involvement of all employees and contractors in effective implementation of Environment Management System through training and awareness.  Promote awareness among local surrounding community for preservation and maintaining clean environment. 10.6.3 Reporting System of Non-Compliances/Violations of Environmental Norms Records are maintained for regulatory, monitoring and operational issues. Unit will develop reporting systems of non-compliances/violations of environmental norms. The mechanism is summarized below: 1. Identify deviation/non-compliance/violation of environmental norms as lay down in consent to operate and letter of Environmental clearance. Record to communication/complain received from plausible stake holder. 2. The EHS manager will identify deviation/non-compliance/violation from failure to comply with statutory requirements. 3. Respond from EHS manager within reasonable time limit to concern authorities with c/c mark to Technical head. 4. Technical head will take it in action and give necessary guideline to comply this deviation/non-compliance/violation of environmental norms. Parallel arrange budget for necessary action to comply the condition. 5. Communication received from the EHS manager will be discussed in technical management meeting.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-16 San Envirotech Pvt. Ltd., Ahmedabad 6. Board discussion, Decision and Action  The chairperson will review the information available and take a decision depending on the seriousness of the violation.  The decision will be taken to ensure the compliance of non- compliance/violation of environmental norms and it’s safeguarded. The decision will be taken by consensus and if no consensus is arrived at, voting will be conducted.  Enlist measures that would undertake to ensure that deviations/ non-compliance/violations of Environmental norms and take care not to occur same violation in future. 10.6.4 Framework for Continual Improvement of Environmental Performance of Organization

EMP Review and revision of EMP based on Environmental Implementation Improvement Performance Evaluation

Monitoring as Mitigation per EMP measures requirement

Internal and Corrective and External Audits Preventive Actions

10.7 RESOURCE CONSERVATION AND CLEANER PRODUCTION Steps that are undertaken by the industry are given below:  RO permeate and MEE condensate will be reused to reduce fresh water demand.  Housekeeping will be regularly maintained.  Solid wastes e.g. powders, spills, etc. in process and packaging are to be separately collected and disposed of instead of allowing these to effluent streams. This will reduce load to treatment and increase the efficiency of treatment system.  Mechanical seals will be provided to the process vessels having agitator for reduction of fugitive emissions and leakages.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-17 San Envirotech Pvt. Ltd., Ahmedabad 10.8 ENERGY CONSERVATION PROGRAMME Energy conservation measures are often the easiest, quickest and cheapest way to reduce costs and be environmentally pro-active. The conservation efforts would consist of the following:  Ensure proper selection fuel-firing equipments - Burners, mechanical stokers, etc.  Reduce radiation losses from boilers, furnaces and auxiliary equip- meant by improved thermal insulation. This will also improve the working conditions within the building and eliminate unnecessary ventilation,  Schedule process operations to avoid fluctuations in boiler loads,  Keep the heat transfer surfaces clean by preventing excessive scale formation,  Pressure vessels should be designed with a length to diameter ratio of roughly three as they are the most economical,  Maximize the use of natural lighting through design,  CFLs or LED lights are used in administration building and plant premises,  Constant monitoring of energy consumption and defining targets for energy conservation,  Maximize the use of laptop computers over desk top computers as Laptops use less energy than desk tops and leave a smaller environmental footprint at end of life,  Adjusting the settings and illumination levels to ensure minimum energy used for desired comfort levels,  Recycling of water will be done, and  Training to staffs on methods of energy conservation. 10.9 SOCIO-ECONOMIC ACTIVITIES Corporate Social Responsibility refers to voluntary actions undertaken by company/organization to either improve the living conditions (economically, socially, environmentally) of local communities or to reduce the negative effects of the project. Socio-economic development activities is a concept of organization whereby organizations serve the interests of society by taking responsibility for the impact of their

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-18 San Envirotech Pvt. Ltd., Ahmedabad activities on customers, employees, shareholders, communities and the environment in all aspects of their operations. Unit will actively contribute to improve the Socio-economic conditions of the area by providing assistance for local persons preferable from the nearby villages. The continuing commitment by business to behave ethically and contribute to economic development while improve the quality of life of workforce and their families as well as that of the local community and society at large. Socio economic study provides direction for the Corporate Environment Responsibility (CER) activities and gives clear picture about the areas of intervention for improvement by CER activities to the project proponent. Socio Economic Survey within study area is prescribing in Chapter-7 of EIA report. Based on the SIA study, outcomes are health, education, Drinking water and sanitation facilities, Women Empowerment & children Development activities, sanitation, sustainable livelihood & infrastructure development in the target project area for CER activities. Based on the primary study and secondary data of the socio-economic condition for villages within 10 km radius of the project site, the following socio- economic development activities under CER programme are suggested/ recommended. Proposed activities are shown below. Details of expenditure for CER activities: Cost of the proposed project : Rs. 20.25 Crores Expenditure earmarked towards CER : Rs. 40.5 Lakhs (2% of the project cost) Table 10.5: Budgetary Provisions for the Social Upliftment

Sr. Activities Years (Rs. in Lakhs) Total Budget No. 1st 2nd 3rd 4th 5th (Rs. in Lakhs) 1 Educational activities 2.0 2.0 2.0 2.0 2.0 10.0 2 Health and Family 1.0 1.0 1.0 1.0 1.0 5.0 Welfare Facilities 3 Drinking water and 2.0 2.0 2.0 2.0 2.0 10.0 sanitation facilities 4 Women Empowerment & 0.6 0.6 0.6 0.6 0.6 3.0 children Development activities 5 Preservation of 2.5 2.5 2.5 2.5 2.5 12.5 Environment and Sustainable Development Total 8.10 8.10 8.10 8.10 8.10 40.5

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 10-19 San Envirotech Pvt. Ltd., Ahmedabad Chapter-11

Summary & Conclusion

11.1 PROJECT DESCRIPTION 11.1.1 General Introduction M/s. Orgosynth Chemicals Pvt. Ltd. is a Greenfield project, proposes to setup Various Dye Intermediates manufacturing unit at Plot No. J-50, J-51, J-52 and J-53, Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center Borgaon, Tehsil: Sausar, Dist. Chhindwara, Madhya Pradesh. Total production capacity of all products will be 3049 MT/month. Project activity falls under item 5(f) of the Schedule of EIA Notification, 2006 and its subsequent amendments. 11.1.2 Salient features of the proposed project

Proposed production capacity 3049 MT/month Proposed project cost Rs. 20.25 Crore Manpower requirement About 100 persons Location Plot No. J-50, J-51, J-52 and J-53, MPIDC Growth Center Village Borgaon Tehsil Sausar District Chhindwara State Madhya Pradesh Coordinates of the site Latitude: 21°33'14.27"N Longitude: 78°48'15.86"E Altitude 378 – 380 m above MSL Survey of India Toposheet No. F44M10, F44M11, F44M14, F44M15 Nearest Human habitation Borgaon, about 0.9 km Town Sausar, about 9.5 km City Chhindwara, about 55.6 km Railway Station Lodhikhera Railway Station, about 5.6 km Highway National Highway NH-26B (Savner-Chhindwara), about 1.2 km Air Port Chhindwara, about 51.0 km Water Body Borgaon, about 1.0 km National Park/Wildlife Sanctuary None, within 10 km radius Proposed Power Requirement 1000 kVA, Source: Madhya Pradesh Poorva Kshetra Vidyut Vitaran Company Ltd. Water Requirement Total: 300 KLD; Fresh water: 70 KLD; Source of raw water: MPIDC

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-1 San Envirotech Pvt. Ltd., Ahmedabad

Wastewater Generation Industrial: 242.7 KLD Domestic: 8.0 KLD Fuel Requirement Agro Briquettes/Coal: 45 TPD; HSD for D.G. Set: 105 lit/hr. Source of Air Emission Flue gas emission from stack of Boiler, Thermic Fluid Heater, D. G. Set Process emission from stack of reaction vessel of MPP-1, MPP-2 and vent of Spin Flash Dryer Solid & Haz. Waste Generation Hazardous waste: ETP Waste, MEE Salt, Used Oil, Discarded Containers/Liners/

Bags, Spent H2SO4, Spent HCl, HBr, Acetic Acid, Liq Ammonia, AlCl3 Solid waste: Fly Ash 11.1.3 Investment of the project Estimated cost of the proposed project will be around Rs. 20.25 Crore. Out of this, Rs. 1.84 Crore will be earmarked as capital investment for EMS and Rs. 2.37 Crore will be recurring cost per annum. 11.1.4 List of products Product details with its capacity are given below.

Sr. Name of the Product CAS No Qty. No. MT/Month 1 2,5/3,4 Dichloro Nitro Benzene 611-06-3 400 2 2, 4 Di Nitro Chloro Benzene (2,4-DNCB) 97-00-7 600 3 3, 4 Di Nitro Chloro Benzene (3,4-DNCB) 611-06-3 100 4 Para Chloro Ortho Nitro Aniline (PCONA) 89-63-4 350 5 Ortho Chloro Para Nitro Aniline 121-87-9 90 (OCPNA) 6 2,4-Dinitro Aniline (2,4-DNA) 97-02-9 540 7 Ortho Nitro Aniline (ONA)/ 88-74-4 100 Para Nitro Aniline (PNA) 100-01-6 8 6 Bromo 2,4 Dinitro Aniline 1817-73-8 200 (6 Bromo 2,4-DNA) 9 6 Chloro 2,4 Dinitro Aniline 3631-19-8 200 (6 Chloro 2,4-DNA) 10 2:6 Di Bromo Para Nitro Aniline 827-94-1 100 (2,6-DBPNA) 11 2:6 Di Chloro Para Nitro Aniline 99-30-9 100 (2,6-DCPNA) 12 2,6-DB Para Toluidine 6968-24-7 100 13 Fast Red B Base & Fast Scarlet R Base 97-52-9 20 14 Fast Bordeaux GP Base 96-96-8 20 15 Meta Nitro Para Toluidine (MNPT) 89-62-3 10 16 2, Cyano Para Nitro Aniline 17420-30-3 30 17 2-Chloro-4-6 Dimethoxy-[1,3,5] Triazine 3140-73-6 50 18 4-Bromo Anisole 104-92-7 5 19 Para Bromo Phenol/4-Bromo Phenol 106-41-2 5

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-2 San Envirotech Pvt. Ltd., Ahmedabad

20 4-Hydroxy Anisole 150-76-5 5 21 Veratrol 91-16-7 5 22 2-Methyl 4,5 Dimethoxy Benzoic Acid 5653-40-7 5 23 2-(2-Methoxy Phenoxy) Ethyl Amine 1836-62-0 5 24 2-Amino 4-Fluoro Benzophenone 3800-06-4 5 25 Miconazole Nitrate 22916-47-8 2 26 Hydrochlorothaizide 58-93-5 2 Total 3049 11.2 DESCRIPTION OF ENVIRONMENT 11.2.1 Baseline Environmental Study To predict the impact of the project on the surrounding environment, the current baseline environmental status was studied by collecting the data and carrying out monitoring during October, 2020 to December, 2020 in the study area of 10 km radius from project site as per the ToR. 11.2.2 Air Environment The ambient air quality monitoring was carried out at 8 locations to assess the existing sub-regional air quality status during the period of October, 2020 to December, 2020. Respirable Dust Sampler (RDS) (with gaseous attachment & FPS facility) along with the analytical methods, prescribed by CPCB was used for

carrying out air quality monitoring. At all these sampling locations; PM10,

PM2.5, SO2 and NOx were monitored on 24-hourly basis to enable the comparison with ambient air quality standards prescribed by the CPCB. The data on concentrations of various pollutants were processed for different statistical parameters like arithmetic mean, standard deviation,

minimum and maximum concentration and various percentile values. The results are summarized below:

Particulate Matter (PM10) th An average and 98 percentile value of 24-hourly PM10 values at all the locations varied between 61.3-71.3 g/m3 and 67.2 – 82.9 g/m3, which are well within the stipulated standard of CPCB, 100 g/m3.

Particulate Matter (PM2.5) th An average and 98 percentile value of 24-hourly PM2.5 values at all the locations varied between 35.6-40.5 g/m3 and 39.7-46.1 g/m3, which are well within the stipulated standard of CPCB, 60 g/m3.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-3 San Envirotech Pvt. Ltd., Ahmedabad

Sulphur Dioxide (SO2) th An average and 98 percentile value of 24-hourly SO2 value of arithmetic mean at all the locations ranged between 10.7 – 14.5 g/m3 and 13.2- 21.1 g/m3 respectively, which are well within the stipulated standards of 80 g/m3.

Oxides of Nitrogen (NOx) th An average and 98 percentile value of 24-hourly NOx value of arithmetic mean at all the locations ranged between 15.0-20.9 g/m3 and 18.3-28.1 g/m3 respectively, which are much lower than the standards stipulated by CPCB, i.e. 80 g/m3. Conclusion: The quality of ambient air in the study area is compared with AAQM Standards prescribed by CPCB & found below the prescribed standards. 11.2.3 Water Environment Six surface water & eight ground water samples were collected during the study period. Surface Water Quality Surface water samples were collected from Pond Nr. Borgaon, Pond Nr. Jamalpani, Pond Nr. Khairitaygaon, Pond Nr. Raibasa and Kanhan River Jam River. Results of the same are given in Chapter-3 of EIA report. Conclusion: It was observed that, results of all the physico-chemical parameters and heavy metals except turbidity are below the stipulated drinking water standards IS: 10500-2012. Selected samples are suitable for drinking and other purposes. Ground Water Quality Ground water samples have been collected from Project Site, Lodhikheda, Borgaon, MPIDC, Jamlapani, Tinkheda, Khaparkheda and Khairitaygaon. The summary of the analysis is as below: pH: All the samples meet the desirable standards (pH ranges from 7.27- 7.78). Total Dissolved Solids (TDS): TDS in samples ranges from 471 mg/L (Khaparkheda) to 645 mg/L (Borgaon), all the samples meet the

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-4 San Envirotech Pvt. Ltd., Ahmedabad permissible limit of 2000 mg/L, (If alternate sources of potable water are not available). Calcium: Calcium contents in the water ranges from 39 mg/L (Tinkheda) to 52 mg/L (Borgaon), all the samples meet the permissible limit of 200 mg/L, (If alternate sources of potable water is not available). Magnesium: Magnesium content in the water ranges from 14 mg/L (Khaparkheda) to 20 mg/L (Borgaon). All the samples meet the permissible limit of 100 mg/L (if alternate source of potable water in not available). Sulfate: Sulfate content in the water ranges from 30 mg/L (Khaparkheda) to 55 mg/L (MPIDC). All the samples meet the permissible limit of 400 mg/L for drinking water (if alternate source of potable water in not available). Fluoride: Fluoride content in the water ranges from 0.45 mg/L (Jamlapani) to 0.74 mg/L (Khairitaygaon). All the samples meet the permissible limit (1.5 mg/L). Total Alkalinity: Total alkalinity in the water samples ranges from 227 mg/L (Jamlapani) to 257 mg/L (Khairitaygaon). All the samples are within the permissible limit of drinking water (600 mg/L) (if alternate source of portable water is not available). Other Parameters: Potassium (ranges from 16 mg/L to 28 mg/L), Sodium (ranges from 93 mg/L to 134 mg/L) and Chloride (ranges from 82 mg/L to 156 mg/L). Heavy metals like copper, lead, chromium and zinc are found below detectable limit in all samples. Conclusion: Ground water samples from villages meet the permissible limit set by the Bureau of Indian Standard (BIS). 11.2.4 Noise Environment Noise monitoring has been conducted at nine locations in the study area.

The Leq (Ld) values of noise levels during day-time varies from 50.1 to 53.4 dB(A) and the night time Leq (Ln) varied from 38.5 to 42.9 dB(A) within the study area. Higher noise value of 53.4 dB(A) was recorded

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-5 San Envirotech Pvt. Ltd., Ahmedabad during day time Project Site & lower noise value of 38.5 dB(A) was recorded during night time in Village Jamlapani. 11.2.5 Soil Quality Soil samples were collected from 8 different locations and analyzed to assess the soil quality prevailing in the study area. Physical characteristics of soil have been delineated through specific parameters, viz. particle size distribution, porosity, water holding capacity and permeability whereas data for chemical characterization of soil, viz. pH, electrical conductivity, cation exchange capacity and sodium absorption ratio have been analyzed. 11.2.6 Biological Environment Baseline data for flora & fauna has been collected with its family. No endangered floral or faunal species were found in the study area. 11.2.7 Socio-Economic Environment

Socio-economic study includes the description of demography, available basic amenities like housing, healthcare services, transportation, education facilities. Information on the above said parameters has been collected to define the socio-economic profile of the study area (10-km radius). 11.3 ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION MEASURES The summary of anticipated adverse environmental impacts due to proposed project and mitigation measures is given below. 11.3.1 Summary of impacts on Air Environment: (a) During construction phase & Mitigation measures Main sources of impact during construction phase will be due to the movement of vehicles & construction equipment at site, foundation works, transportation of construction material etc. Water sprinkling in the vicinity of the construction area will be done to control dust. PUC certified vehicles will be used. Temporary barricades will be provided to reduce spreading of particulates from construction area. (b) During operation phase & Mitigation measures Flue gas emission will be from stack attached to Boiler (6 TPH), one stack of Thermic Fluid Heater (20 Lakhs Kcal/hr.) and one stack of 2 nos.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-6 San Envirotech Pvt. Ltd., Ahmedabad of stand by D.G. Sets (500 kVA x 2). Agro Briquettes/Coal will be used as a fuel in Boiler & TFH and HSD in stand by D.G. Set. Most probable

pollutants will be SPM, SO2 and NOx. Process emission will be from 1 vent attached to process vessel of MPP- 1, two vents of process vessel of MPP-2 and 1 common vent attached to 6 nos. of Spin Flash Dryers. Pollutants from process stacks will be will be

PM, HCl, HBr, and NH3. Prediction of impacts on air environment is quantified using ISCST3 model. Maximum Ground level concentrations of 24-hr average for SPM, 3 3 SO2 & NOx, from the proposed activity are 2.673 g/m , 0.898 g/m and 0.986 g/m3. These GLCs are expected to occur at a distance of 1.0 km from the source in W direction. Whereas highest 24-hourly average GLCs 3 3 3 value of HCl, HBr & NH3 are 0.986 g/m , 0.040 g/m and 0.094 g/m respectively. These GLCs are expected to occur at a distance of 1.0 km from the source in S direction. The obtained GLCs are well within the 24- hourly ambient air quality standards stipulated by CPCB. However, to mitigate the impact, cyclone & bag filter will be installed as APCM to flue gas stacks and water scrubber, acid scrubber & alkali scrubber will be installed to process stacks. To control particulate emission, In-built bag filter will be installed as APCM on Spin Flash Dryer.

Adequate stack height will be provided fo r proper atmospheric dispersion as per the norms. 11.3.2 Summary of impacts on Water Environment (a) Impacts during construction phase & Mitigation measures: Temporary impacts are likely to occur due to water consumption & sewage generation. It will not be significant as water requirement would be temporary during construction phase. Proper sanitation facilities with adequate disposal system will be provided within the operational plant. (b) Impacts during operation phase & Mitigation measures: Fresh water requirement of the unit will be satisfied from MPIDC water supply. Total water requirement (Industrial + Domestic + Greenbelt) will be 300 KLD; Out of which, 70 KLD will be fresh water requirement. Total industrial effluent generation will be 242.7 KLD. It will be taken into ETP, after treatment, entire effluent will be passed through RO. RO

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-7 San Envirotech Pvt. Ltd., Ahmedabad permeate (170 KLD) will be reused within premises and RO reject will be sent to MEE/ATFD. MEE condensate (60 KLD) will be reused. Thus, unit proposed to achieve Zero Liquid Discharge (ZLD). Unit will built full- fledged ETP with capacity of 250 m3/day to treat effluent. Domestic sewage (8.0 KLD) will be disposed into soak pit though septic tank. Hence, no impact on the water environment is envisaged. 11.3.3 Impacts on Noise quality & Mitigation measures (a) Impacts during construction phase & Mitigation measures: During construction phase, major sources of noise will be vehicle’s movement & construction activities. High noise producing activities will be restricted to daytime only. Well maintained equipments will be used to prevent noise. Usage of PPE by workers will be made compulsory. (b) Impacts during operation phase & Mitigation measures: During the operation phase, noise levels may be due to the operation of Boiler, Thermic Fluid Heater, D.G. set and other machineries. The impact will found to be insignificant outside the premises. Unit will provide necessary PPEs like earplugs or earmuffs to all workers where exposure is 85 dB(A) or more. Selection of any new plant equipment will be made with specification of low noise levels. 11.3.4 Summary of Impacts on Land Environment (a) Impacts during construction phase & Mitigation measures: The construction activities like excavation, leveling will change the landscape, which are expected to be of short duration & insignificant. Preliminary activities like proper storage of construction materials & proper management will be done within the project area. Therefore, impact will be negligible outside of the factory premises. Unit will provide sanitation facilities for the staff engaged in construction work which will prevent the impacts on land. (b) Impacts during operation phase & Mitigation measures: Hazardous wastes will have significant negative impacts if disposed unsystematically. Unit will provide all required structural facilities like separate hazardous waste storage room with RCC floor, leachate collection system, and concrete floors within premises. Hence, no significant negative impact is envisaged on the land environment.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-8 San Envirotech Pvt. Ltd., Ahmedabad 11.3.5 Summary of impact on Socio Economy (a) Impacts during construction phase & Mitigation measures: Proposed project will set up in the land developed for Industrial purpose by Madhya Pradesh Industrial Development Corporation Limited (MPIDC) Growth Center, Borgaon, so no R&R is required. Workers for the construction work will be required. Local contractors to be employed for construction, so no other issues like social conflict are envisaged. Temporary employment generated during construction of project will have beneficial impacts on economic environment. (b) Impacts during operation phase & Mitigation measures: Proposed project will require about 100 persons for its operation, which result into a positive impact on prevailing socio-economic environment. Project will also have potential of indirect employment due to the increase transportation activities, contractual works as well as opportunity of trade. Thus, overall impacts on socio-economic environment will be long term and positive in nature. 11.3.6 Summary of impact on Ecology There are no protected areas like National Park/Wildlife Sanctuary within the 10 km radial periphery of the project site. So there will not be any significant impact on ecology. 11.4 ENVIRONMENT MONITORING PROGRAMME: The unit will have dedicated Environment Management Cell to monitor and evaluate the environmental performance and to supervise the Environment Management System (EMS). Below Post-project monitoring programme will be followed. Environment Monitoring Program

Nature of Analysis Frequency of analysis with Parameters its analyzer Wastewater analysis Monthly by external agency pH, TDS, SS, COD, BOD, Oil & Grease, etc.

Stack Monitoring of Monthly by external agency PM, SO2, NOX, HCl, each stack HBr, NH3

Ambient Air Quality Monthly for 24 hours or as per PM10, PM2.5, SO2, NOx, Monitoring the statutory conditions by HCl, HBr, NH3 external agency Noise level Monthly as per the statutory Noise level conditions by external agency

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-9 San Envirotech Pvt. Ltd., Ahmedabad

Work zone fugitive Monthly by external agency RPM, VOCs, acid mist monitoring Health check-up of As per the statutory guideline All workers workers

11.5 ADDITIONAL STUDIES 11.5.1 Risk Assessment Risk analysis and study have been carried out for identification of accident hazards, selection of credible scenarios, Risk Mitigation measures etc. All the hazardous chemicals will be stored and handled as per MSDS guidelines. The detail study is prescribed in Chapter-7. 11.6 PROJECT BENEFITS Proposed project has a potential for employment of skilled, semi-skilled & unskilled employees. The direct employment potential is estimated as 100 persons and many others will be indirectly employed. Indirectly, the proposed project will help the Government by paying different taxes from time to time, which is a part of revenue and thus, will help in developing the area. The company has allocated a budget of Rs. 40.5 Lakhs for CER activities, which can lead to improve social infrastructure. 11.7 ENVIRONMENTAL MANAGEMENT PLAN EMP includes the protection & mitigation measures to be implemented to reduce the adverse impact on the environment. Management plan of impacts identified is detailed below: Air Pollution Management Cyclone followed by bag filter will be installed as APCM on stack attached with Boiler & Thermic Fluid Heater. No need to install any APCM to stack of D.G. set as it will not be the constant source of emission. To control the process emission, Water Scrubber, Acid Scrubber and Alkali scrubber on vent of process vessel of MPP-1 & MPP-2. To control particulate emission, In-built bag filter will be installed on Spin Flash Dryer. Adequate stack height and SMF will also be provided as per the guideline. Following mitigation measures will be adopted to control

fugitive emission: • Entire process will be carried out in closed reactors • Close handling system provided for transfer of chemicals • Pneumatically transfer of liquid raw material in reactor

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-10 San Envirotech Pvt. Ltd., Ahmedabad • Pumps will be provided with mechanical seals to prevent leakages. • Internal roads will be paved to reduce fugitive emission during vehicular movement. • Air borne dust will be controlled with water sprinklers. • Greenbelt will be developed around the plant boundary. • Regular monitoring of work area will be done to check the fugitive emission. Water Pollution Management • Industrial wastewater will be segregated based on its concentration and treated in ETP & RO followed by MEE/ATFD. • Condensate of MEE and Permeate of RO will be reused within the premises. • Regular monitoring of working of ETP, RO and MEE will be done. • Sewage will be disposed off into soak pit. • Unit will maintain the records for the total water consumption. • Rain water harvesting structure will be installed in the unit. Hazardous Waste Management The entire quantity of hazardous waste will be handled and disposed as per Hazardous & Other Waste (Management & Transboundary Movement) Rules, 2016. ETP sludge & MEE salt will be sent to TSDF site for land filling. Spent Sulphuric Acid (45-70%), HCl (25-28%) and HBr (25-28%) will be partly reuse in-house and partly will be sold to actual users under

Rule-9. Acetic Acid and AlCl3 will be sold to actual users under Rule-9. Liq. Ammonia will be reused in-house in same or other products. Used lubricating oil will be used within premises or disposed by selling to registered re-processors and discarded barrels & liners will be disposed of by selling to registered recyclers. Generated Fly Ash 120 MT/month will be sold to brick manufacturer and also supplied to the companies for land leveling, conditioning & road construction, etc. Thus, there will not be any major impact on the environment due to hazardous waste management. Noise Pollution Management • Lubrication and regular maintenance will be carried out for the machineries and equipments to reduce noise generation.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-11 San Envirotech Pvt. Ltd., Ahmedabad • PPEs will be provided to the workers working in high noise area. • Acoustic enclosure will be provided to D.G. set. • Greenbelt will be developed within premises to prevent noise pollution. • Periodic monitoring of noise levels will be done. Green Belt Development Total land area is 17432 m2. The unit will develop greenbelt in area of 5763 m2. Overall greenbelt area will be 33% of the total area of the project. 11.8 CONCLUSION Based on the study it is concluded that-  There will be no major impact on water environment as effluent will be treated in ETP followed by RO and MEE, achieving Zero Liquid Discharge (ZLD).  Condensate of MEE and RO permeate will be reused/recycled within

plant premises. Thus, reducing fresh water consumption load.  Cyclone and bag filter will be used as pollution control equipments for control of flue gas emission.  Water scrubber, Acid scrubber & Alkali scrubber will be installed as pollution control equipments to control process emission.  In built cyclone & bag filter will be installed on vent of Spin Flash Dryer.  Fugitive emission will be controlled by close material handling system and proper storage of materials.  Selection of any new plant equipment will be made with specification of low noise levels.  Entire quantity of hazardous waste will be handled and disposed as per Hazardous & Other Waste (Management & Transboundary Movement) Rules, 2016.  Greenbelt will be developed in 33% of the total area.  Fire protection and safety measures will be provided.  Direct and indirect employment opportunities will have positive impact. After taking above steps towards pollution control, impact of the proposed project on surrounding area will be negligible.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 11-12 San Envirotech Pvt. Ltd., Ahmedabad Chapter-12

Disclosure of Consultant engaged

12.1 PREFACE San Envirotech Pvt. Ltd. (SEPL) has been appointed by Orgosynth Chemicals Pvt. Ltd. to carry out this Environmental Impact Assessment Study as per the EIA Notification, 2006 as amended till date. SEPL is accredited as Category-A organization under the QCI-NABET Scheme for accreditation of EIA consultant Organizations: Version 3 for preparing EIA-EMP reports in 10 sectors (Certificate No. NABET/EIA/1619/RA0084; Valid till 26.08.2021). 12.2 DETAILS OF EIA CONSULTANT ORGANIZATION San Envirotech Pvt. Ltd. has started its work in 1990 to serve the environment as a trustee of next generation with a small infrastructure under the dynamic leadership of Dr. Mahendra Sadaria. SEPL has wide spectrum of national and multinational clients covering the industries - Bulk Drugs and Pharmaceuticals, Dyes and Dye Intermediates, Pesticides, Fertilizers, Chemicals, Cement, Mining, and Infrastructure. During last two decades, SEPL has been taking care of client’s unique problems and concerns in order to develop cost effective strategies to meet their regulatory obligations. SEPL focuses on strategic planning and comprehensive solutions to address both short and long term needs of the clients. SEPL has in-house multi-disciplinary analytical testing laboratory that is MoEFCC approved under EP Act. SEPL is also a recognized Schedule-II Environmental Auditor appointed by Gujarat Pollution Control Board as per the directives of the Honorable High Court of Gujarat. SEPL is also an ISO 9001:2008, 14001:2008 and OHSAS: 18001 certified company. SEPL team consists of qualified & experienced personnel. Experts involved in the preparation of this EIA/EMP report are given in EIA report as ‘declaration by experts’.

Final EIA Report of Orgosynth Chemicals Pvt. Ltd. 12-1