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1 Fundamentals of Polymer Chemistry
1 Fundamentals of Polymer Chemistry H. Warson 1 THE CONCEPT OF A POLYMER 1.1 Historical introduction The differences between the properties of crystalline organic materials of low molecular weight and the more indefinable class of materials referred to by Graham in 1861 as ‘colloids’ has long engaged the attention of chemists. This class includes natural substances such as gum acacia, which in solution are unable to pass through a semi-permeable membrane. Rubber is also included among this class of material. The idea that the distinguishing feature of colloids was that they had a much higher molecular weight than crystalline substances came fairly slowly. Until the work of Raoult, who developed the cryoscopic method of estimating molecular weight, and Van’t Hoff, who enunciated the solution laws, it was difficult to estimate even approximately the polymeric state of materials. It also seems that in the nineteenth century there was little idea that a colloid could consist, not of a product of fixed molecular weight, but of molecules of a broad band of molecular weights with essentially the same repeat units in each. Vague ideas of partial valence unfortunately derived from inorganic chem- istry and a preoccupation with the idea of ring formation persisted until after 1920. In addition chemists did not realise that a process such as ozonisation virtually destroyed a polymer as such, and the molecular weight of the ozonide, for example of rubber, had no bearing on the original molecular weight. The theory that polymers are built up of chain formulae was vigorously advocated by Staudinger from 1920 onwards [1]. -
LIBRARY. This Thesis Has Been Approved for the Department of Chemical Engineering and the College of Engineering and Technology
~.. STUDY OF A COUNTER-ROTATING, INTERMESHING EXTRUDER AS A POLYCONDENSATION REACTOR /" A Thesis Presented to the Faculty of The College of Engineering and Technology Ohio University In Partial Fulfilment of the Requirements for the Degree Master of Science by Edward R. Crowe November, 1992 LIBRARY. This Thesis has been approved for the Department of Chemical Engineering and the College of Engineering and Technology Associate Prof Chem1cal Engineering Dean of the College of Engineering and Technology iii Abstract An experimental study and model development have been performed to better understand the reactive extrusion of polyethylene terephthalate. A process was developed using a 34 mm counter-rotating twin screw extruder to depolymerize a commercial grade of polyethylene terephthalate into an acceptable pre-polymer for reactive extrusion experiments. Residence time d Ls'tr Ibut.Lon experiments were conducted at different screw speeds and feed rates to characterize the flow patterns of the extruder. Based on these results an idealized plug-flow model was developed to simulate this process. An experimental design using the controllable process variables of zone temperature, feed rate and nitrogen flow sweeping across the surface of the polymer melt was developed to stUdy the individual effects of each of these variables as well as any interactive effects. The results indicate that the feed rate and nitrogen flow have an effect on the degree of polymerization of the product. However, the stUdy clearly shows the dominant effect to be ,the average residence time of the polymer melt in the vent zone. The idealized plug-flow model presents a reasonable representation of this process. -
HDPE: High Density Polyethylene LDPE
Abbreviations: HDPE: high density polyethylene LDPE: low density polyethylene PET: polyethylene terephthalate PP: polypropylene PS: polystyrene PVA: polyvinyl alcohol PVC: polyvinyl chloride addition polymerization: a chemical reaction in which simple molecules are linked together to form long chain molecules. amorphous: non-crystalline polymer or non-crystalline areas in a polymer. Bakelite: a polymer produced by the condensation of phenol and formaldehyde. branched polymer: polymer having smaller chains attached to the polymer backbone. cellulose: a natmal polymer found in wood and other plant material. composite polymer: a filled or reinforced plastic. condensation polymer: one in which two or more molecules combine resulting in elimination of water or other simple molecules, with the process being repeated to form a long chain molecule. configuration: related chemical structme produced by the making and breaking ofprimary valence bonds. copolymer: a macromolecule consisting of more than one type of building unit. creep: cold flow of a polymer. cross-linking: occms when primary valence bonds are formed between separate polymer molecules. crystalline polymer: polymer with a regular order or pattern of molecular arrangement and a sharp melting point. dimer: a polymer containing two monomers. domains: sequences or regions in block copolymers. elastomer: a type of polymer that exhibits rubber-like qualities. Ekonol: a moldable, high temperatme polymer. end group: functional group at the end of a chain in polymers, e.g. carboxylic group. extrusion: a fabrication process in which a heat-softened polymer is forced continually by a screw through a die. filler: a relatively inert material used as the discontinuous phase of a polymer composite. free radical: A chemical component that contains a free electron which covalently bonds with a free electron on another molecule. -
Synthesis of Functionalized Polyamide 6 by Anionic Ring-Opening Polymerization Deniz Tunc
Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization Deniz Tunc To cite this version: Deniz Tunc. Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization. Poly- mers. Université de Bordeaux; Université de Liège, 2014. English. NNT : 2014BORD0178. tel- 01281327 HAL Id: tel-01281327 https://tel.archives-ouvertes.fr/tel-01281327 Submitted on 2 Mar 2016 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Logo Université de cotutelle THÈSE PRÉSENTÉE POUR OBTENIR LE GRADE DE DOCTEUR DE L’UNIVERSITÉ DE BORDEAUX ET DE L’UNIVERSITÉ DE LIEGE ÉCOLE DOCTORALEDE SCIENCES CHIMIQUES (Université de Bordeaux) ÉCOLE DOCTORALE DE CHIMIE (Université de Liège) SPÉCIALITÉ POLYMERES Par Deniz TUNC Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization Sous la direction de Stéphane CARLOTTI et Philippe LECOMTE Soutenue le 30 octobre 2014 Membres du jury: M. PERUCH, Frédéric Directeur de recherche, Université de Bordeaux Président M. HOOGENBOOM, Richard Professeur, Ghent University Rapporteur M. MONTEIL, Vincent Chargé de recherche, Université Claude Bernard Rapporteur M. YAGCI, Yusuf Professeur, Istanbul Technical University Examinateur M. AMEDURI, Bruno Directeur de recherche, Institut Charles Gerhardt Examinateur M. SERVANT, Laurent Professeur, Université de Bordeaux Invité Preamble This PhD had been performed within the framework of the IDS FunMat joint doctoral programme. -
The Effects of Sulfide Stress Cracking on the Mechanical Properties And
3HW6FL '2,V 7KHHIIHFWVRIVXO¿GHVWUHVVFUDFNLQJRQWKH mechanical properties and intergranular cracking of P110 casing steel in sour environments Hou Duo, Zeng Dezhi , Shi Taihe, Zhang Zhi and Deng Wenliang 6WDWH.H\/DERUDWRU\RI2LODQG*DV5HVHUYRLU*HRORJ\DQG([SORLWDWLRQ6RXWKZHVW3HWUROHXP8QLYHUVLW\&KHQJGX Sichuan 610500, China © China University of Petroleum (Beijing) and Springer-Verlag Berlin Heidelberg 2013 Abstract: 9DULDWLRQDQGGHJUDGDWLRQRI3FDVLQJVWHHOPHFKDQLFDOSURSHUWLHVGXHWRVXO¿GHVWUHVV cracking (SSC) in sour environments, was investigated using tensile and impact tests. These tests ZHUHFDUULHGRXWRQVSHFLPHQVZKLFKZHUHSUHWUHDWHGXQGHUWKHIROORZLQJFRQGLWLRQVIRUKRXUV WHPSHUDWXUH&SUHVVXUH03D+26SDUWLDOSUHVVXUH03DDQG&22SDUWLDOSUHVVXUH03D SUHORDGVWUHVVRIWKH\LHOGVWUHQJWK ıs PHGLXPVLPXODWHGIRUPDWLRQZDWHU7KHUHGXFWLRQLQ WHQVLOHDQGLPSDFWVWUHQJWKVIRU3FDVLQJVSHFLPHQVLQFRUURVLYHHQYLURQPHQWVZHUHDQG 54%, respectively. The surface morphology analysis indicated that surface damage and uniform plastic GHIRUPDWLRQRFFXUUHGDVDUHVXOWRIVWUDLQDJLQJ,PSDFWWRXJKQHVVRIWKHFDVLQJGHFUHDVHGVLJQL¿FDQWO\ DQGLQWHUJUDQXODUFUDFNLQJRFFXUUHGZKHQVSHFLPHQVZHUHPDLQWDLQHGDWDKLJKVWUHVVOHYHORIıs. Key words: Acidic solutions, high-temperature corrosion, hydrogen embrittlement, intergranular FRUURVLRQVXO¿GHVWUHVVFUDFNLQJ 1 Introduction corrosion cracking (SCC) which is an anodic cracking mechanism. 6WHHOVUHDFWZLWKK\GURJHQVXO¿GHIRUPLQJPHWDOVXO¿GHV Specifically, testing methods using the bend specimen and atomic hydrogen as corrosion byproducts. The atomic JHRPHWU\GHVFULEHGLQWKH$670VWDQGDUGV -
Polymer Exemption Guidance Manual POLYMER EXEMPTION GUIDANCE MANUAL
United States Office of Pollution EPA 744-B-97-001 Environmental Protection Prevention and Toxics June 1997 Agency (7406) Polymer Exemption Guidance Manual POLYMER EXEMPTION GUIDANCE MANUAL 5/22/97 A technical manual to accompany, but not supersede the "Premanufacture Notification Exemptions; Revisions of Exemptions for Polymers; Final Rule" found at 40 CFR Part 723, (60) FR 16316-16336, published Wednesday, March 29, 1995 Environmental Protection Agency Office of Pollution Prevention and Toxics 401 M St., SW., Washington, DC 20460-0001 Copies of this document are available through the TSCA Assistance Information Service at (202) 554-1404 or by faxing requests to (202) 554-5603. TABLE OF CONTENTS LIST OF EQUATIONS............................ ii LIST OF FIGURES............................. ii LIST OF TABLES ............................. ii 1. INTRODUCTION ............................ 1 2. HISTORY............................... 2 3. DEFINITIONS............................. 3 4. ELIGIBILITY REQUIREMENTS ...................... 4 4.1. MEETING THE DEFINITION OF A POLYMER AT 40 CFR §723.250(b)... 5 4.2. SUBSTANCES EXCLUDED FROM THE EXEMPTION AT 40 CFR §723.250(d) . 7 4.2.1. EXCLUSIONS FOR CATIONIC AND POTENTIALLY CATIONIC POLYMERS ....................... 8 4.2.1.1. CATIONIC POLYMERS NOT EXCLUDED FROM EXEMPTION 8 4.2.2. EXCLUSIONS FOR ELEMENTAL CRITERIA........... 9 4.2.3. EXCLUSIONS FOR DEGRADABLE OR UNSTABLE POLYMERS .... 9 4.2.4. EXCLUSIONS BY REACTANTS................ 9 4.2.5. EXCLUSIONS FOR WATER-ABSORBING POLYMERS........ 10 4.3. CATEGORIES WHICH ARE NO LONGER EXCLUDED FROM EXEMPTION .... 10 4.4. MEETING EXEMPTION CRITERIA AT 40 CFR §723.250(e) ....... 10 4.4.1. THE (e)(1) EXEMPTION CRITERIA............. 10 4.4.1.1. LOW-CONCERN FUNCTIONAL GROUPS AND THE (e)(1) EXEMPTION................. -
United States Patent C Patented Aug
3,336,412 United States Patent C Patented Aug. 15, 1967 1 2 3,336,412 tion reaction can be eliminated by the addition of a halogen PRODUCTION OF UNSATURATED HYDROCAR gas to the reaction mixture. In one preferred embodiment BGNS BY PYROLYSIS 0F SATURATED HY it has now been discovered that the addition of chlorine DROCARBONS to a mixture of methane and oxygen increases the yield of Richard Kenneth Lyon, Elizabeth, and William Bartok, acetylene and eliminates the need for preheating‘ the West?eld, N.J., assignors to Esso Research and Engi neering Company, a corporation of Delaware methane and oxygen reactants. While not wishing to be No Drawing. Filed June 29, 1964, Ser. No. 379,031 bound by any particular theory, it is believed that the ad_ 8 Claims. (Cl. 260-679) dition of chlorine promotes the formation of acetylene in the reaction 3H2+C2<:>2CH4 by formation of HCl This invention relates ‘to an improved process for the 10 thereby driving the reaction in accordance with familiar pyrolysis of certain saturated hydrocarbons to obtain un principles of equilibrium reaction. Furthermore, the re saturated hydrocarbons. More particularly, this invention action H2+Cl2—>2HCl is exothermic and therefore adds relates to the production of unsaturated hydrocarbons additional heat to the reaction. The utilization of chlorine by partial combustion of saturated hydrocarbons. In a pre gas with the unsaturated hydrocarbon-oxygen mixture ferred embodiment, this invention relates to the produc 15 possesses a further advantage in that the halogen gas will tion of acetylene by partial combustion of hydrocarbons not react with the unsaturated hydrocarbon as will water, such as methane. -
Studies of the Temporary Anion States of Unsaturated Hydrocarbons by Electron Transmission Spectroscopy
University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Paul Burrow Publications Research Papers in Physics and Astronomy 1978 Studies of the Temporary Anion States of Unsaturated Hydrocarbons by Electron Transmission Spectroscopy Kenneth D. Jordan Paul Burrow Follow this and additional works at: https://digitalcommons.unl.edu/physicsburrow Part of the Atomic, Molecular and Optical Physics Commons This Article is brought to you for free and open access by the Research Papers in Physics and Astronomy at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Paul Burrow Publications by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. digitalcommons.unl.edu Studies of the Temporary Anion States of Unsaturated Hydrocarbons by Electron Transmission Spectroscopy Kenneth D. Jordan Mason Laboratory, Department of Engineering and Applied Science, Yale University, New Haven, Connecticut 06520 Paul D. Burrow Behlen Laboratory of Physics, University of Nebraska, Lincoln, Nebraska 68588 The concept of occupied and unoccupied orbitals has provided a useful means for visualizing many of the most important properties of mo- lecular systems. Yet, there is a curious imbalance in our experimen- tal knowledge of the energies of occupied and unoccupied orbitals. Whereas photoelectron spectroscopy has provided a wealth of data on positive ion states and has established that they can be associated, within the context of Koopmans’ theorem, with the occupied orbitals of the neutral molecule, the corresponding information for the neg- ative ion states, associated with the normally unoccupied orbitals, is sparse. In part this reflects the experimental difficulties connected with measuring the electron affinities of molecules which possess sta- ble anions. -
Guide for Certification of Offshore Containers 2020
GUIDE FOR CERTIFICATION OF OFFSHORE CONTAINERS FEBRUARY 2020 American Bureau of Shipping Incorporated by Act of Legislature of the State of New York 1862 © 2020 American Bureau of Shipping. All rights reserved. 1701 City Plaza Drive Spring, TX 77389 USA Foreword (1 February 2020) IMO has issued MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas. This circular is intended to assist the competent authorities in developing the requirements for approving the offshore containers. IMO requires that all intermodal containers conform to the requirements of the International Convention for Safe Containers (CSC). The requirements of the CSC convention may not be applicable to offshore containers primarily due to non-standard designs, exposure to the marine environment for extended periods as well as the lifting of offshore containers by padeyes. EN 12079 has been published based on the MSC/Circ.860 and is currently used as an International industry standard to approve offshore containers. Containers built to the ABS Guide for Certification of Offshore Containers will meet all the requirements of MSC/Circ.860, EN 12079:2006 and ISO 10855:2018. This Guide provides guidance for manufacturing facilities to build offshore containers. It also serves to assist the ABS Engineers and Surveyors in certifying offshore containers around the globe. This Guide becomes effective on the first day of the month of publication. Users are advised to check periodically on the ABS website www.eagle.org to verify that this version of this Guide is the most current. We welcome your feedback. Comments or suggestions can be sent electronically by email to [email protected]. -
MODULE 11: GLOSSARY and CONVERSIONS Cell Engines
Hydrogen Fuel MODULE 11: GLOSSARY AND CONVERSIONS Cell Engines CONTENTS 11.1 GLOSSARY.......................................................................................................... 11-1 11.2 MEASUREMENT SYSTEMS .................................................................................. 11-31 11.3 CONVERSION TABLE .......................................................................................... 11-33 Hydrogen Fuel Cell Engines and Related Technologies: Rev 0, December 2001 Hydrogen Fuel MODULE 11: GLOSSARY AND CONVERSIONS Cell Engines OBJECTIVES This module is for reference only. Hydrogen Fuel Cell Engines and Related Technologies: Rev 0, December 2001 PAGE 11-1 Hydrogen Fuel Cell Engines MODULE 11: GLOSSARY AND CONVERSIONS 11.1 Glossary This glossary covers words, phrases, and acronyms that are used with fuel cell engines and hydrogen fueled vehicles. Some words may have different meanings when used in other contexts. There are variations in the use of periods and capitalization for abbrevia- tions, acronyms and standard measures. The terms in this glossary are pre- sented without periods. ABNORMAL COMBUSTION – Combustion in which knock, pre-ignition, run- on or surface ignition occurs; combustion that does not proceed in the nor- mal way (where the flame front is initiated by the spark and proceeds throughout the combustion chamber smoothly and without detonation). ABSOLUTE PRESSURE – Pressure shown on the pressure gauge plus at- mospheric pressure (psia). At sea level atmospheric pressure is 14.7 psia. Use absolute pressure in compressor calculations and when using the ideal gas law. See also psi and psig. ABSOLUTE TEMPERATURE – Temperature scale with absolute zero as the zero of the scale. In standard, the absolute temperature is the temperature in ºF plus 460, or in metric it is the temperature in ºC plus 273. Absolute zero is referred to as Rankine or r, and in metric as Kelvin or K. -
Very-High-Cycle Fatigue and Charpy Impact Characteristics of Manganese Steel for Railway Axle at Low Temperatures
applied sciences Article Very-High-Cycle Fatigue and Charpy Impact Characteristics of Manganese Steel for Railway Axle at Low Temperatures Byeong-Choon Goo 1,* , Hyung-Suk Mun 2 and In-Sik Cho 3 1 Advanced Railroad Vehicle Division, Korea Railroad Research Institute, Uiwang 16105, Korea 2 New Transportation Innovative Research Center, Korea Railroad Research Institute, Uiwang 16105, Korea; [email protected] 3 Department of Advanced Materials Engineering, Sun Moon University, Asan 31460, Korea; [email protected] * Correspondence: [email protected]; Tel.: +82-31-460-5243 Received: 29 June 2020; Accepted: 21 July 2020; Published: 22 July 2020 Featured Application: This work can be applied to the development of new axle materials and to the high-cycle fatigue testing of materials at low temperatures. Abstract: Railway vehicles are being exposed with increasing frequency to conditions of severe heat and cold because of changes in the climate. Trains departing from Asia travel to Europe through the Eurasian continent and vice versa. Given these circumstances, the mechanical properties and performance of vehicle components must therefore be evaluated at lower and higher temperatures than those in current standards. In this study, specimens were produced from a commercial freight train axle made of manganese steel and subjected to high-cycle fatigue tests at 60, 30, and 20 C. − − ◦ The tests were conducted using an ultrasonic fatigue tester developed to study fatigue at low temperatures. Charpy impact testing was performed over the temperature range of 60 to 60 C − ◦ to measure the impact absorption energy of the axle material. The material showed a fatigue limit above 2 million cycles at each temperature; the lower the test temperature, the greater the fatigue limit cycles. -
On Impact Testing of Subsize Charpy V-Notch Type Specimens*
DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsi• bility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Refer• ence herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recom• mendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. ON IMPACT TESTING OF SUBSIZE CHARPY V-NOTCH TYPE SPECIMENS* Mikhail A. Sokolov and Randy K. Nanstad Metals and Ceramics Division OAK RIDGE NATIONAL LABORATORY P.O. Box 2008 Oak Ridge, TN 37831-6151 •Research sponsored by the Office of Nuclear Regulatory Research, U.S. Nuclear Regulatory Commission, under Interagency Agreement DOE 1886-8109-8L with the U.S. Department of Energy under contract DE-AC05-84OR21400 with Lockheed Martin Energy Systems. The submitted manuscript has been authored by a contractor of the U.S. Government under contract No. DE-AC05-84OR21400. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes. Mikhail A.