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Ternary Systems Sodium Iodate 343 COMPONENTS: ORIGINAL MEASUREMENTS: (1) Sodium iodate; NaI03; [7681-55-2] Ricci, J.E.; Linke, W.F. (2) Di sodium (I-4)-tetraoxomo1ybdate (2-) J. Am. Chern. SO~. 1947, 69, 1080-3. (disodium molybdate); Na2Mo04; [7631-95-0] (3) Water; H 0; [7732-18-5] 2 VARIABLES: PREPARED BY: Composition at 298.2 K Hiroshi Miyamoto EXPERIMENTAL VALUES: Composition of saturated solutions Na2Mo04 NaI03 Density Nature of mass % mol % mass % mol % g cm- 3 the solid (compiler) (compiler) phasea 39.38 5.378 0.00 0.000 1.432 A 39.16 5.375 0.58 0.083 1.437 " 38.63 5.354 1. 79 0.258 1.450 " 38.46 5.349 2.20 0.318 1.453 A+B 38.51 5.358 2.18 0.316 1.452 " 38.43 5.343 2.21 0.320 1.451 " 38.43 5.343 2.21 0.320 1.454 " 38.47 5.350 2.18 0.315 1.455 " 38.46 5.349 2.20 0.318 1.453 " 37.23 5.090 2.24 0.319 1.436 B 31.49 3.995 2.54 0.335 1.368 " 24.24 2.825 3.08 0.373 1.277 " 17.89 1. 943 3.42 0.386 1.204 " 11.41 1.163 4.16 .'1.441 1.143 " 5.57 0.543 5.67 0.575 1.099 " 0.00 0.000 8.49b 0.838 1.074 " a A'" Na2Mo04·2H20; B = NaI03·H20 b For the binary system the compiler computes the following: 1 soly of NaI03 = 0.469 mol kg- AUXILIARY INFORMATION METHOD/APPARATUS/PROCEDURE: SOURCE AND PURITY OF MATERIALS: Solubilities determined isothermally by C.p. grade sodium molybdate dihydrate com- stirring complexes of known compositions in plete1y dehydrated by heating to 180· C, Pyrex tubes, and sampling the equilibrated and stored at 150·C. The purity of solutions by means of calibrated pipets this anhydrous salt was found to be 100.0 %. fitted with filtering tips. Total solids C.p. grade sodium iodate was found to be were determined by evaporation of an pure within 1/1000. aliquot of saturated solution and drying to r-~C70MME~=NT~S~AN~D~/~O~R~A~D~D~I=T=I70N~A~L~D~A~T~A~:-----------; constant weight at 125·C. H20 ~~ Na2Mo04-NaI03-H20 The iodate content in the saturated solu­ tion was determined iodometrically. A \ large excess of acid (HC1) was necessary to obtain the correct end-point within the short titration time in the presence of the molybdate. ESTIMATED ERROR: Soly: the accuracy of titrations was within 0.1 %. Temp: precision ± 0.04 K. 344 Sodium Iodate COMPONENTS: ORIGINAL MEASUREMENTS: [49l7-l9~81 (1) Sodium carbonate; Na2C03; Foote, H.W.; Vance, J.E. (2) Sodium iodate; NaI03; [7681-55-2] Am. J. S~{. 1933, 25, 499-502. (3) Water; H20; [7732-18-5] VARIABLES: PREPARED BY: Composition Hiroshi Miyamoto T/K os 273 - 323 EXPERIMENTAL VALUES: Composition of saturated solutions Nature of the NaI03 Na2C03 mass % mol % mass % mol % solid phasea (compiler) (compiler) o - - 6.42 1.15 A 0.81 0.078 6.30 1.14 A+C 0.83 0.080 6.27 1.13 " 2.42b 0.225 - - C 25 - - 22.60 4.728 A 0.52 0.059 22.44 4.715 " 2.16 0.247 22.22 4.745 A+D 2.17 0.248 22.22 4.746 " 2.54 0.282 18.82 3.898 D 8.66b 0.856 - - " 40 - - 32.83 7.670 B 0.50 0.063 32.67 7.667 " 1.79 0.227 32.09 7.603 B+D 1. 75 0.222 32.00 7.570 " 2.00 0.248 29.87 6.918 D 11. 71b 1.193 - - " continued••••• AUXILIARY INFORMATION METHOD/APPARATUS/PROCEDURE: SOURCE AND PURITY OF MATERIALS: Sodium iodate, sodium carbonate and water The authors only state that sodium iodate were placed in glass stoppered bottles and and carbonate were purified by customary rotated in a thermostat. Twenty-four hours methods. were allowed for the attainment of equili­ brium at which time samples of the solution were drawn off through glass wool filters for analysis. Sodium iodate content was determined by add­ ing excess KI, acidifying with sulfuric acid, and titrating the liberated iodine with thio­ sulfate solution. Sodium carbonate was detd in a second sample by titration with HCl using methyl orange indicator. In these ESTIMATED ERROR: carbonate titrations, a constant light source was used and the end point was com­ Nothing specified. pared with a standard made by saturating water containing a few drops of methyl orange with carbon dioxide. The composition of the dry solid phase was REFERENCES: determined by the method of Schreinemakers. Sodium Iodate 345 COHPONENTS: ORIGINAL HEASUREMENTS: (1) Sodium carbonate; Na2C03; [4917-19-8] Foote, H.W.; Vance, J.E. (2) Sodium iodate; NaI03; [7681-55-2] Am. J. Se~. 1933, 25, 499-502. (3) Water; H20; [7732-18-5] EXPERIMENTAL VALUES: (Continued) Composition of saturated solutions Nature of the NaI03 Na2C03 a t/"C mass % mol % mass % mol % solid phase (compiler) ( comp.!ler) 50 32.16 7.457 B 1. 30 0.163 31.52 7.374 2.42 0.307 31.31 7.411 B+D 2.54 0.322 31.23 7.396 " 3.34 0.401 25.44 5.701 D 14.06 1.468 a A = Na2C03·l0H20; B = Na2C03·H20; C = NaI03·5H20; D = NaI03·H20 b For the binary system the compiler computes the following: soly of NaI03 = 0.125 mol kg-l at O°C = 0.479 mol kg-l at 25°C = 0.6702 mol kg-l at 40°C = 0.8267 mol kg-l at 50°C COMMENTS AND/OR ADDITIONAL DATA: The phase diagram is given below (based on mass % units). System NaIO...Na,CO...H,O. showing the solubility isotherms at four temperatures, and the stability areas of the nVl: solid phases. No double salt exists. 346 Sodium Iodate COMPONENTS: ORIGINAL MEASUREMENTS: (1) Sodium nitrate; NaN03; [7631-99-4] Foote, H.W.; Vance, J.E. (2) Sodium iodate; NaI03; [768l-55-2J Am. J. Sci. 1929, 18, 375-82. (3) Water; H20; [7732-l8-5J VARIABLES: PREPARED BY: Composition Hiroshi Miyamoto T!K .. 273 - 308 EXPERIMENTAL VALUES: Composition of saturated solutions NaI0 .. NaN0 Nature of the 3 3 a t!OC mass % mol % mass % mol % solid phase (compiler) (compiler) o - - 42.13 13.37 A 0.82 0.113 41.76 13.34 A+D 0.82 0.112 41, 71 13.32 " 0.86 0.117 41.15 13.06 D 1.00 0.131 37.53 11.44 " 1.16 0.147 34.61 10.24 " 1. 31 0.163 32.57 9.438 " 1.38 0.171 32.19 9.298 B+D 1.31 0.163 32.45 9.391 " 1.26 0.151 29.18 8.153 B 1.06 0.117 21.42 5.526 " 2.42b 0.225 - - " 8 - - 43.99 14.27 A 1.67 0.236 43.28 14.25 A+D 1.67 0.236 43.21 14.21 " 1.88 0.259 40.80 13.08 D 1.96 0.266 39.54 12.50 C+D 2.02 0.274 39.36 12.42 C 2.27 0.285 32.23 9.418 " continued..... AUXILIARY INFORMATION METHOD/APPARATUS/PROCEDURE: SOURCE AND PURITY OF MATERIALS: Sodium iodate, sodium nitrate and water Sodium iodate and nitrate used were c.p. were placed in glass stoppered bottles and products which were recrystallized once. rotated in a thermostat. Samples of the solution were drawn off through glass wool filters. The iodate content was determined by adding KI to the solution, acidifying with sulfuric acid, and titrating the free iodine with sodium thiosulfate solution. The nitrate content was calculated from the iodate concentration and the total mass of salts in solution. Water was found by difference. The solid phases were analyzed as wet residues after largely freeing them from water by pressing ESTIMATED ERROR: between filter papers. The composition of the dry residue was determined by Nothing specified. Schreinemakers' method. REFERENCES: Sodium Iodate 347 COHPONENTS: DRIGINAL MEASUREMENTS: (1) Sodium nitrate; NaN03; [7631-99-4] Foote, H.W.; Vance, J.E. (2) Sodium iodate; NaI03; [7681-55-2] Am. J. SQ{. 1929, 78, 375-82. (3) Water; H20; [7732-18-5] EXPERIMENTAL VALUES: (Continued) Composition of saturated solutions NaI03 NaN03 Nature of the t/oC mass % mol % mass % mol % solid phasea (compiler) ( compiler) 8 2.25 0.279 31. 03 8.948 B+C 2.22 0.274 30.83 8.868 " 3.90b 0.368 - - B 25 -- 48.04 16.39 A 1.09 0.161 47.39 16.29 " 2.30 0.343 46.73 16.21 A+C 2.25 0.335 46.65 16.16 " 2.38 0.340 43.18 14.34 C 2.55 0.350 39.88 12.76 " 3.69 0.400 15.94 4.018 " 8.66b 0.856 - - " 35 - - 50.15 17.58 A 1.58 0.241 49.25 17.47 " 2.55 0.391 48.68 17.39 A+C 2.55 0.391 48.68 17.39 " 2.60 0.399 48.68 17.41 " 2.66 0.400 46.99 16.45 C 3.85 0.456 24.96 6.886 " 10.57b 1.065 - - " a A = NaN03; B = NaI03.5H20; C = NaI03·H20; D = 2NaI03' 3NaN03' 15H20 b For the binary system the compiler computes the following: soly of NaT03 = 0.125 mol kg-1 at OOC; = 0.205 mol kg-1 at 8°C = 0.479 mol kg-1 at 25°C; = 0.5973 mol kg-1 at 35°C COMMENTS AND/OR ADDITIONAL DATA: Isotherms based on mass % units are reproduced below on the following page.
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