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Ice Ic” Werner F
Extent and relevance of stacking disorder in “ice Ic” Werner F. Kuhsa,1, Christian Sippela,b, Andrzej Falentya, and Thomas C. Hansenb aGeoZentrumGöttingen Abteilung Kristallographie (GZG Abt. Kristallographie), Universität Göttingen, 37077 Göttingen, Germany; and bInstitut Laue-Langevin, 38000 Grenoble, France Edited by Russell J. Hemley, Carnegie Institution of Washington, Washington, DC, and approved November 15, 2012 (received for review June 16, 2012) “ ” “ ” A solid water phase commonly known as cubic ice or ice Ic is perfectly cubic ice Ic, as manifested in the diffraction pattern, in frequently encountered in various transitions between the solid, terms of stacking faults. Other authors took up the idea and liquid, and gaseous phases of the water substance. It may form, attempted to quantify the stacking disorder (7, 8). The most e.g., by water freezing or vapor deposition in the Earth’s atmo- general approach to stacking disorder so far has been proposed by sphere or in extraterrestrial environments, and plays a central role Hansen et al. (9, 10), who defined hexagonal (H) and cubic in various cryopreservation techniques; its formation is observed stacking (K) and considered interactions beyond next-nearest over a wide temperature range from about 120 K up to the melt- H-orK sequences. We shall discuss which interaction range ing point of ice. There was multiple and compelling evidence in the needs to be considered for a proper description of the various past that this phase is not truly cubic but composed of disordered forms of “ice Ic” encountered. cubic and hexagonal stacking sequences. The complexity of the König identified what he called cubic ice 70 y ago (11) by stacking disorder, however, appears to have been largely over- condensing water vapor to a cold support in the electron mi- looked in most of the literature. -
A Primer on Ice
A Primer on Ice L. Ridgway Scott University of Chicago Release 0.3 DO NOT DISTRIBUTE February 22, 2012 Contents 1 Introduction to ice 1 1.1 Lattices in R3 ....................................... 2 1.2 Crystals in R3 ....................................... 3 1.3 Comparingcrystals ............................... ..... 4 1.3.1 Quotientgraph ................................. 4 1.3.2 Radialdistributionfunction . ....... 5 1.3.3 Localgraphstructure. .... 6 2 Ice I structures 9 2.1 IceIh........................................... 9 2.2 IceIc........................................... 12 2.3 SecondviewoftheIccrystalstructure . .......... 14 2.4 AlternatingIh/Iclayeredstructures . ........... 16 3 Ice II structure 17 Draft: February 22, 2012, do not distribute i CONTENTS CONTENTS Draft: February 22, 2012, do not distribute ii Chapter 1 Introduction to ice Water forms many different crystal structures in its solid form. These provide insight into the potential structures of ice even in its liquid phase, and they can be used to calibrate pair potentials used for simulation of water [9, 14, 15]. In crowded biological environments, water may behave more like ice that bulk water. The different ice structures have different dielectric properties [16]. There are many crystal structures of ice that are topologically tetrahedral [1], that is, each water molecule makes four hydrogen bonds with other water molecules, even though the basic structure of water is trigonal [3]. Two of these crystal structures (Ih and Ic) are based on the same exact local tetrahedral structure, as shown in Figure 1.1. Thus a subtle understanding of structure is required to differentiate them. We refer to the tetrahedral structure depicted in Figure 1.1 as an exact tetrahedral structure. In this case, one water molecule is in the center of a square cube (of side length two), and it is hydrogen bonded to four water molecules at four corners of the cube. -
Benthic Community Response to Iceberg Scouring at an Intensely Disturbed Shallow Water Site at Adelaide Island, Antarctica
Vol. 355: 85–94, 2008 MARINE ECOLOGY PROGRESS SERIES Published February 26 doi: 10.3354/meps07311 Mar Ecol Prog Ser Benthic community response to iceberg scouring at an intensely disturbed shallow water site at Adelaide Island, Antarctica Dan A. Smale*, David K. A. Barnes, Keiron P. P. Fraser, Lloyd S. Peck British Antarctic Survey, Natural Environment Research Council, High Cross, Madingley Road, Cambridge CB3 OET, UK ABSTRACT: Disturbance is a key structuring force influencing shallow water communities at all latitudes. Polar nearshore communities are intensely disturbed by ice, yet little is known about benthic recovery following iceberg groundings. Understanding patterns of recovery following ice scour may be particularly important in the West Antarctic Peninsula region, one of the most rapidly changing marine systems on Earth. Here we present the first observations from within the Antarc- tic Circle of community recovery following iceberg scouring. Three grounded icebergs were marked at a highly disturbed site at Adelaide Island (~67° S) and the resultant scours were sampled at <1, 3, 6, 12, 18 and 30 to 32 mo following formation. Each iceberg impact was catastrophic in that it resulted in a 92 to 96% decrease in abundance compared with reference zones, but all post- scoured communities increased in similarity towards ‘undisturbed’ assemblages over time. Taxa recovered at differing rates, probably due to varying mechanisms of return to scoured areas. By the end of the study, we found no differences in abundance between scoured and reference samples for 6 out of 9 major taxonomic groups. Five pioneer species had consistently elevated abundances in scours compared with reference zones. -
Dielectric Properties of Water Under Extreme Conditions and Transport of Carbonates in the Deep Earth
Dielectric properties of water under extreme conditions and transport of carbonates in the deep Earth Ding Pana,1, Leonardo Spanua,2, Brandon Harrisonb, Dimitri A. Sverjenskyb, and Giulia Gallia,c Departments of aChemistry and cPhysics, University of California, Davis, CA 95616; and bDepartment of Earth and Planetary Sciences, Johns Hopkins University, Baltimore, MD 21218 Edited by Russell J. Hemley, Carnegie Institution of Washington, Washington, DC, and approved February 22, 2013 (received for review December 11, 2012) Water is a major component of fluids in the Earth’s mantle, where We computed the dielectric constant of hot, compressed water its properties are substantially different from those at ambient using ab initio calculations (16, 17) with semilocal density func- conditions. At the pressures and temperatures of the mantle, tionals (18) and used our results to predict the solubility of car- experiments on aqueous fluids are challenging, and several fun- bonates in the Earth’s upper mantle, well into subduction zones. damental properties of water are poorly known; e.g., its dielectric We predict that MgCO3—an important mineral stable in the constant has not been measured. This lack of knowledge of water mantle up to 82 GPa (19) and insoluble in water at ambient dielectric properties greatly limits our ability to model water–rock conditions—becomes slightly soluble, at least millimolal levels at interactions and, in general, our understanding of aqueous fluids ∼10 GPa and 1,000 K. This result suggests that aqueous fluids below the Earth’s crust. Using ab initio molecular dynamics, we may be carbon hosts and transport carbonate in the deep Earth, computed the dielectric constant of water under the conditions of with important implications for the dynamics of the global car- the Earth’s upper mantle, and we predicted the solubility products bon cycle (20, 21). -
River Ice Management in North America
RIVER ICE MANAGEMENT IN NORTH AMERICA REPORT 2015:202 HYDRO POWER River ice management in North America MARCEL PAUL RAYMOND ENERGIE SYLVAIN ROBERT ISBN 978-91-7673-202-1 | © 2015 ENERGIFORSK Energiforsk AB | Phone: 08-677 25 30 | E-mail: [email protected] | www.energiforsk.se RIVER ICE MANAGEMENT IN NORTH AMERICA Foreword This report describes the most used ice control practices applied to hydroelectric generation in North America, with a special emphasis on practical considerations. The subjects covered include the control of ice cover formation and decay, ice jamming, frazil ice at the water intakes, and their impact on the optimization of power generation and on the riparians. This report was prepared by Marcel Paul Raymond Energie for the benefit of HUVA - Energiforsk’s working group for hydrological development. HUVA incorporates R&D- projects, surveys, education, seminars and standardization. The following are delegates in the HUVA-group: Peter Calla, Vattenregleringsföretagen (ordf.) Björn Norell, Vattenregleringsföretagen Stefan Busse, E.ON Vattenkraft Johan E. Andersson, Fortum Emma Wikner, Statkraft Knut Sand, Statkraft Susanne Nyström, Vattenfall Mikael Sundby, Vattenfall Lars Pettersson, Skellefteälvens vattenregleringsföretag Cristian Andersson, Energiforsk E.ON Vattenkraft Sverige AB, Fortum Generation AB, Holmen Energi AB, Jämtkraft AB, Karlstads Energi AB, Skellefteå Kraft AB, Sollefteåforsens AB, Statkraft Sverige AB, Umeå Energi AB and Vattenfall Vattenkraft AB partivipates in HUVA. Stockholm, November 2015 Cristian -
Jökulhlaups in Skaftá: a Study of a Jökul- Hlaup from the Western Skaftá Cauldron in the Vatnajökull Ice Cap, Iceland
Jökulhlaups in Skaftá: A study of a jökul- hlaup from the Western Skaftá cauldron in the Vatnajökull ice cap, Iceland Bergur Einarsson, Veðurstofu Íslands Skýrsla VÍ 2009-006 Jökulhlaups in Skaftá: A study of jökul- hlaup from the Western Skaftá cauldron in the Vatnajökull ice cap, Iceland Bergur Einarsson Skýrsla Veðurstofa Íslands +354 522 60 00 VÍ 2009-006 Bústaðavegur 9 +354 522 60 06 ISSN 1670-8261 150 Reykjavík [email protected] Abstract Fast-rising jökulhlaups from the geothermal subglacial lakes below the Skaftá caul- drons in Vatnajökull emerge in the Skaftá river approximately every year with 45 jökulhlaups recorded since 1955. The accumulated volume of flood water was used to estimate the average rate of water accumulation in the subglacial lakes during the last decade as 6 Gl (6·106 m3) per month for the lake below the western cauldron and 9 Gl per month for the eastern caul- dron. Data on water accumulation and lake water composition in the western cauldron were used to estimate the power of the underlying geothermal area as ∼550 MW. For a jökulhlaup from the Western Skaftá cauldron in September 2006, the low- ering of the ice cover overlying the subglacial lake, the discharge in Skaftá and the temperature of the flood water close to the glacier margin were measured. The dis- charge from the subglacial lake during the jökulhlaup was calculated using a hypso- metric curve for the subglacial lake, estimated from the form of the surface cauldron after jökulhlaups. The maximum outflow from the lake during the jökulhlaup is esti- mated as 123 m3 s−1 while the maximum discharge of jökulhlaup water at the glacier terminus is estimated as 97 m3 s−1. -
Genesis and Geographical Aspects of Glaciers - Vladimir M
HYDROLOGICAL CYCLE – Vol. IV - Genesis and Geographical Aspects of Glaciers - Vladimir M. Kotlyakov GENESIS AND GEOGRAPHICAL ASPECTS OF GLACIERS Vladimir M. Kotlyakov Institute of Geography, Russian Academy of Sciences, Moscow, Russia Keywords: Chionosphere, cryosphere, equilibrium line, firn line, glacial climate, glacier, glacierization, glaciosphere, ice, seasonal snow line, snow line, snow-patch Contents 1. Introduction 2. Properties of natural ice 3. Cryosphere, glaciosphere, chionosphere 4. Snow-patches and glaciers 5. Basic boundary levels of snow and ice 6. Measures of glacierization 7. Occurrence of glaciers 8. Present-day glacierization of the Arctic Glossary Bibliography Biographical Sketch Summary There exist ten crystal variants of ice and one amorphous form in Nature, however only one form ice-1 is distributed on the Earth. Ten other ice variants steadily exist only under a certain combinations of pressure, specific volume and temperature of medium, and those are not typical for our planet. The ice density is less than that of water by 9%, and owing to this water reservoirs are never totally frozen., Thus life is sustained in them during the winter time. As a rule, ice is much cleaner than water, and specific gas-ice compounds called as crystalline hydrates are found in ice. Among the different spheres surrounding our globe there are cryosphere (sphere of the cold), glaciosphere (sphere of snow and ice) and chionosphere (that part of the troposphere where the annual amount of solid precipitation exceeds their losses). The chionosphere envelopes the Earth with a shell 3 to 5 km in thickness. In the present epoch, snow and ice cover 14.2% of the planet’s surface and more than half of the land surface. -
Snow and Ice Control Around Structures - George D
COLD REGIONS SCIENCE AND MARINE TECHNOLOGY - Snow and Ice Control Around Structures - George D. Ashton SNOW AND ICE CONTROL AROUND STRUCTURES George D. Ashton Consultant, Lebanon, NH 03766 Keywords: ice jams, ice control, flooding, snow drifting, snow loads, river ice Contents 1. Introduction 2. Nature of ice jams 2.1. Frazil Ice 2.1.1. Hanging Dams 2.1.2. Blockage of Intakes 2.2. Breakup Ice Jams 3. Control of ice jams 3.1. Frazil Ice Jams 3.2. Breakup Ice Jams 3.2.1. Ice Suppression 3.2.2. Dikes 3.2.3. Ice Booms 3.2.4. Ice Control Structures 3.2.5. Ice Removal 3.2.6. Ice Breaking 3.2.7. Ice Weakening 3.2.8. Blasting 4. Other Ice Control Techniques 4.1. Air Bubbler Systems 4.1.1. Requirements 4.1.2. Limitations 4.1.3. Operation 4.2. Other Ice Control Techniques 5. Snow control around structures 5.1. Buildings 5.1.1. Snow UNESCOLoads on Roofs – EOLSS 5.1.2. Blowing Snow 5.2. Roads 5.2.1 Snow Fences 6. Conclusion SAMPLE CHAPTERS Glossary Bibliography Biographical Sketch Summary Two main topics are treated here: control of ice jams including mitigation measures, and control of snow accumulations around structures. The nature of ice jams is described and the difference between jams formed of frazil ice and jams formed of broken ice is ©Encyclopedia of Life Support Systems (EOLSS) COLD REGIONS SCIENCE AND MARINE TECHNOLOGY - Snow and Ice Control Around Structures - George D. Ashton discussed. Also discussed are various ice control techniques used for specific problems. -
Ground (Subsurface) Ice Shumskii, P
NRC Publications Archive Archives des publications du CNRC Ground (subsurface) ice Shumskii, P. A.; National Research Council of Canada. Division of Building Research For the publisher’s version, please access the DOI link below./ Pour consulter la version de l’éditeur, utilisez le lien DOI ci-dessous. Publisher’s version / Version de l'éditeur: https://doi.org/10.4224/20386780 Technical Translation (National Research Council of Canada), 1964 NRC Publications Archive Record / Notice des Archives des publications du CNRC : https://nrc-publications.canada.ca/eng/view/object/?id=b714ab23-775f-4f1d-9a1e-ab4bc8f71c00 https://publications-cnrc.canada.ca/fra/voir/objet/?id=b714ab23-775f-4f1d-9a1e-ab4bc8f71c00 Access and use of this website and the material on it are subject to the Terms and Conditions set forth at https://nrc-publications.canada.ca/eng/copyright READ THESE TERMS AND CONDITIONS CAREFULLY BEFORE USING THIS WEBSITE. L’accès à ce site Web et l’utilisation de son contenu sont assujettis aux conditions présentées dans le site https://publications-cnrc.canada.ca/fra/droits LISEZ CES CONDITIONS ATTENTIVEMENT AVANT D’UTILISER CE SITE WEB. Questions? Contact the NRC Publications Archive team at [email protected]. If you wish to email the authors directly, please see the first page of the publication for their contact information. Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n’arrivez pas à les repérer, communiquez avec nous à [email protected]. -
Modeling the Ice VI to VII Phase Transition
Modeling the Ice VI to VII Phase Transition Dawn M. King 2009 NSF/REU PROJECT Physics Department University of Notre Dame Advisor: Dr. Kathie E. Newman July 31, 2009 Abstract Ice (solid water) is found in a number of different structures as a function of temperature and pressure. This project focuses on two forms: Ice VI (space group P 42=nmc) and Ice VII (space group Pn3m). An interesting feature of the structural phase transition from VI to VII is that both structures are \self clathrate," which means that each structure has two sublattices which interpenetrate each other but do not directly bond with each other. The goal is to understand the mechanism behind the phase transition; that is, is there a way these structures distort to become the other, or does the transition occur through the breaking of bonds followed by a migration of the water molecules to the new positions? In this project we model the transition first utilizing three dimensional visualization of each structure, then we mathematically develop a common coordinate system for the two structures. The last step will be to create a phenomenological Ising-like spin model of the system to capture the energetics of the transition. It is hoped the spin model can eventually be studied using either molecular dynamics or Monte Carlo simulations. 1 Overview of Ice The known existence of many solid states of water provides insight into the complexity of condensed matter in the universe. The familiarity of ice and the existence of many structures deem ice to be interesting in the development of techniques to understand phase transitions. -
Ice-VII Inclusions in Diamonds: (18)
RESEARCH GEOCHEMISTRY on the basis of x-ray diffraction data that are presented here (Fig. 1). Ice-VII is a high-pressure form of water ice that is stable above 2.4 GPa Ice-VII inclusions in diamonds: (18). As we show, ice-VII (along with magnesian calcite, ilmenite, and halite) sensitively records high remnant pressures, which then also constrain Evidence for aqueous fluid the pressure and temperature where it has been encapsulated in the host diamond crystal, similar in Earth’s deep mantle to other micrometer-scale inclusions of soft molec- ular materials such as CO2,CO2-H2O, and N2 in diamond (19–23). O. Tschauner,1* S. Huang,1 E. Greenberg,2 V. B. Prakapenka,2 C. Ma,3 G. R. Rossman,3 By retaining high pressures, ice-VII inclusions A. H. Shen,4 D. Zhang,2,5 M. Newville,2 A. Lanzirotti,2 K. Tait6 monitor the former presence of H2O-rich fluid at different depths in the diamond-bearing man- Water-rich regions in Earth’s deeper mantle are suspected to play a key role in the global tle. Remnants of former fluids and melts have water budget and the mobility of heat-generating elements. We show that ice-VII occurs been found as inclusions in many diamonds as inclusions in natural diamond and serves as an indicator for such water-rich regions. through infrared (IR) spectroscopy and micro- Ice-VII, the residue of aqueous fluid present during growth of diamond, crystallizes upon chemical analysis (19, 22). On the basis of IR ascent of the host diamonds but remains at pressures as high as 24 gigapascals; it is spectroscopy, a lower-pressure ice phase, VI, has now recognized as a mineral by the International Mineralogical Association. -
First International Conference on Mars Polar Science and Exploration
FIRST INTERNATIONAL CONFERENCE ON MARS POLAR SCIENCE AND EXPLORATION Held at The Episcopal Conference Center at Carnp Allen, Texas Sponsored by Geological Survey of Canada International Glaciological Society Lunar and Planetary Institute National Aeronautics and Space Administration Organizers Stephen Clifford, Lunar and Planetary Institute David Fisher, Geological Survey of Canada James Rice, NASA Ames Research Center LPI Contribution No. 953 Compiled in 1998 by LUNAR AND PLANETARY INSTITUTE The Institute is operated by the Universities Space Research Association under Contract No. NASW-4574 with the National Aeronautics and Space Administration. Material in this volume may be copied without restraint for library, abstract service, education, or personal research purposes; however, republication of any paper or portion thereof requires the written permission of the authors as well as the appropriate acknowledgment of this publication. Abstracts in this volume may be cited as Author A. B. (1998) Title of abstract. In First International Conference on Mars Polar Science and Exploration, p. xx. LPI Contribution No. 953, Lunar and Planetary Institute, Houston. This report is distributed by ORDER DEPARTMENT Lunar and Planetary Institute 3600 Bay Area Boulevard Houston TX 77058-1 113 Mail order requestors will be invoiced for the cost of shipping and handling. LPI Contribution No. 953 iii Preface This volume contains abstracts that have been accepted for presentation at the First International Conference on Mars Polar Science and Exploration, October 18-22? 1998. The Scientific Organizing Committee consisted of Terrestrial Members E. Blake (Icefield Instruments), G. Clow (U.S. Geologi- cal Survey, Denver), D. Dahl-Jensen (University of Copenhagen), K. Kuivinen (University of Nebraska), J.