DIMETHYL TEREPHTHALATE Dimethyl Terephthalate (DMT) Is Used Mainly to Produce Polyester Resins, Fibres and Films As Well As Engineering Resins

Total Page:16

File Type:pdf, Size:1020Kb

DIMETHYL TEREPHTHALATE Dimethyl Terephthalate (DMT) Is Used Mainly to Produce Polyester Resins, Fibres and Films As Well As Engineering Resins DIMETHYL TEREPHTHALATE Dimethyl terephthalate (DMT) is used mainly to produce polyester resins, fibres and films as well as engineering resins. The polyesters generated are employed in fibres used by the textile industry, the manufacture of food and beverage containers such as polyethylene terephthalate (PET) bottles, and polyester film which has applications in photography, computers, audio-visual equipment and packaging. DMT is available in molten (liquid) and flake (solid) forms. The most widely used method of manufacture is based on paraxylene using oxidation and esterification steps. DMT is stable under normal temperatures and pressures but is a significant dust explosion hazard if in powder or granular form and mixed with air. It degrades in the atmosphere with an estimated half-life of 28 days. ICIS pricing quotes DMT in Europe. Frequency: Published weekly on Fridays. DMT (EUROPE) Weekly Price Assessments: Liquid DMT contract prices. FD NWE Monthly (EUR/MT & conversion to USD/MT) DMT Feedstock Prices Methanol FOB RDAM Quarterly Contract (EUR/MT) Paraxylene FD NWE Monthly Contract (EUR/MT) General Information: Assessment window: Price assessments are based on information supplied by market participants through the week up to close of business on Fridays at 1700 hours in London. Specifications: Prime molten material (liquid) unless otherwise specified. Timing: Cargoes loading or delivered four to six weeks forward from the date of publication. Terms: 30-60 days after bill of lading date. Standard cargo size: Assessments reflect values for small, medium and large-size customers. Assessment basis: ICIS contract prices are mathematically derived using upstream paraxylene (PX) and methanol contracts. The DMT delta equals 0.62 of the monthly FD NWE PX price move plus 0.38 of the quarterly FOB Rotterdam methanol contract price move. Following the price assessments there is market commentary on paraxylene (PX), methanol, polyethylene terephtalate (PET) and purified terephthalic acid (PTA). 10 April 2013 .
Recommended publications
  • Terephthalic Acid and Dimethyl Terephthalate Supplement B
    Report No. 9B TEREPHTHALIC ACID AND DIMETHYL TEREPHTHALATE SUPPLEMENT B by LLOYD M. ELKIN With contributions by Shigeyoshi Takaoka Kohsuke Ohta September 1970 e A private report by the PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA e I CONTENTS 1 INTRODUCTION . 1 2 SUMMARY........................... 3 3 INDUSTRY STATUS . 13 4 CHEMISTRY......................... 23 Terephthalic Acid from p-Xylene by Liquid Phase Oxidation in the Presence of Large Amounts of Catalyst . 23 Bis(2-hydroxyethyl) Terephthalate from Ethylene Oxide and Terephthalic Acid . , . , . 25 Ammoxidation of p-Xylene . 26 dlycolysis of Terephthalonitrile . 28 Terephthalic Acid by Bromine-Promoted Catalytic Oxidation of p-Xylene ., . 30 Terephthalic Acid by Catalytic Oxidation of p-Xylene in the Presence of Methyl Ethyl Ketone Activator . 32 Terephthalic Acid by Nitric Acid Oxidation of p-Xylene . 32 Terephthalic Acid from Phthalic Anhydride . 33 5 REVIEW OF PATENTS . , . 37 Terephthalic Acid by Bromine-Promoted Catalytic Air Oxidation of p-Xylene . , . 37 Terephthalic Acid by Catalytic Oxidation of p-Xylene in the Presence of Activators . 38 Dimethyl Terephthalate from p-Xylene by Successive Oxidations and Esterifications . , . 39 Terephthalic Acid by Nitric Acid Oxidation of p-Xylene . 40 Terephthalic Acid from p-Xylene by Liquid Phase Oxidation in the Presence of Large Amounts of Catalyst . , . 40 Terephthalic Acid from p-Xylene by Other Oxidation Processes . , . , 42 Terephthalic Acid from Phthalic Anhydride or Benzoic Acid . 42 Terephthalonitrile, Preparation and Purification . 42 Dimethyl Terephthalate by Esterification of Terephthalic Acid.......................... 43 Bis(2-hydroxyethyl) Terephthalate from Terephthalic Acid and Ethylene Oxide or from Terephthalonitrile . 44 Purification of Terephthalic Acid . 44 Miscellaneous . 45 CONTENTS 6 TEREPHTHALIC ACID FROM p-XYLENE BY LIQUID PHASE OXIDATION IN THE PRESENCE OF LARGE AMOUNTS OF CATALYST , , .
    [Show full text]
  • Synthesis of Polyesters by the Reaction of Dicarboxylic Acids with Alkyl Dihalides Using the DBU Method
    Polymer Journal, Vol. 22, No. 12, pp 1043-1050 (1990) Synthesis of Polyesters by the Reaction of Dicarboxylic Acids with Alkyl Dihalides Using the DBU Method Tadatomi NISHIKUBO* and Kazuhiro OZAKI Department of Applied Chemistry, Faculty of Engineering, Kanagawa University, Rokkakubashi, Kanagawa-ku, Yokohama 221, Japan (Received July 6, 1990) ABSTRACT: Some polyesters with moderate viscosity were synthesized by reactions of dicarboxylic acids with alkyl dihalides using 1,8-diazabicyclo-[5.4.0]-7-undecene (DBU) in aprotic polar solvents such as dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) under relatively mild conditions. The viscosity and yield of the resulting polymer increased with increasing monomer concentration. Although polymers with relatively high viscosity were obtained when the reaction with p-xylylene dichloride was carried out at 70°C in DMSO, the viscosity of the resulting polymers decreased with increasing reaction temperature when the reaction with m-xylylene dibromide was carried out in DMSO. KEY WORDS Polyester Synthesis/ Dicarboxylic Acids/ Alkyl Dihalides / DBU Method / Mild Reaction Condition / Although poly(ethylene terephthalate) is favorable method for the synthesis of polyes­ synthesized industrially by transesterification ters because the preparation and purification between dimethyl terephthalate and ethylene of the activated. dicarboxylic acids is un­ glycol at relatively high temperatures using necessary. certain catalysts, many polyesters are usually Some polyesters have also been prepared8 prepared by the polycondensation of dicarbox­ by reactions between alkali metal salts of ylic-acid chlorides with difunctional alcohols dicarboxylic-acids and aliphatic dibromides or phenols. These reactions are carried out using phase transfer catalysis (PTC)s, which is under relatively mild conditions; however, the a very convenient method for chemical activated dicarboxylic-acid chlorides must be modification, especially esterification9 or ether­ prepared and purified before the reaction.
    [Show full text]
  • Polymer Exemption Guidance Manual POLYMER EXEMPTION GUIDANCE MANUAL
    United States Office of Pollution EPA 744-B-97-001 Environmental Protection Prevention and Toxics June 1997 Agency (7406) Polymer Exemption Guidance Manual POLYMER EXEMPTION GUIDANCE MANUAL 5/22/97 A technical manual to accompany, but not supersede the "Premanufacture Notification Exemptions; Revisions of Exemptions for Polymers; Final Rule" found at 40 CFR Part 723, (60) FR 16316-16336, published Wednesday, March 29, 1995 Environmental Protection Agency Office of Pollution Prevention and Toxics 401 M St., SW., Washington, DC 20460-0001 Copies of this document are available through the TSCA Assistance Information Service at (202) 554-1404 or by faxing requests to (202) 554-5603. TABLE OF CONTENTS LIST OF EQUATIONS............................ ii LIST OF FIGURES............................. ii LIST OF TABLES ............................. ii 1. INTRODUCTION ............................ 1 2. HISTORY............................... 2 3. DEFINITIONS............................. 3 4. ELIGIBILITY REQUIREMENTS ...................... 4 4.1. MEETING THE DEFINITION OF A POLYMER AT 40 CFR §723.250(b)... 5 4.2. SUBSTANCES EXCLUDED FROM THE EXEMPTION AT 40 CFR §723.250(d) . 7 4.2.1. EXCLUSIONS FOR CATIONIC AND POTENTIALLY CATIONIC POLYMERS ....................... 8 4.2.1.1. CATIONIC POLYMERS NOT EXCLUDED FROM EXEMPTION 8 4.2.2. EXCLUSIONS FOR ELEMENTAL CRITERIA........... 9 4.2.3. EXCLUSIONS FOR DEGRADABLE OR UNSTABLE POLYMERS .... 9 4.2.4. EXCLUSIONS BY REACTANTS................ 9 4.2.5. EXCLUSIONS FOR WATER-ABSORBING POLYMERS........ 10 4.3. CATEGORIES WHICH ARE NO LONGER EXCLUDED FROM EXEMPTION .... 10 4.4. MEETING EXEMPTION CRITERIA AT 40 CFR §723.250(e) ....... 10 4.4.1. THE (e)(1) EXEMPTION CRITERIA............. 10 4.4.1.1. LOW-CONCERN FUNCTIONAL GROUPS AND THE (e)(1) EXEMPTION.................
    [Show full text]
  • Synthesis and Characterization of Amorphous Cycloaliphatic Copolyesters with Novel Structures and Architectures
    Synthesis and Characterization of Amorphous Cycloaliphatic Copolyesters with Novel Structures and Architectures Yanchun Liu Dissertation submitted to the faculty of the Virginia Polytechnic Institute and State University in partial fulfillment of the requirements for the degree of Doctor of Philosophy In Chemistry S. Richard Turner, Committee Chair Timothy E. Long Paul A. Deck Herve Marand Judy S. Riffle March 22, 2012 Blacksburg, Virginia Keywords: amorphous copolyesters, cycloaliphatic monomers, melt-phase polymerization, glass transition temperature, structure-property relationship Copyright @ 2012 by Yanchun Liu Synthesis and Characterization of Amorphous Cycloaliphatic Copolyesters with Novel Structures and Architectures Yanchun Liu ABSTRACT A series of random and amorphous copolyesters containing different cycloaliphatic rings within the polymer chains were prepared by melt polycondensaton of difunctional monomers (diesters and diols) in the presence of a catalyst. These polyesters were characterized by nuclear magnetic resonance (NMR), size exclusion chromatography (SEC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), tensile tests and/or dynamic mechanical analysis (DMA). The copolyester based on dimethyl bicyclo[2.2.2]octane-1,4-dicarboxylate (DMCD-2) was observed to have a higher Tg, about 115 ºC, than the other copolyesters with the same compositions in this study. For copolyesters containing different compositions of dimethyl-1,4-cyclohexane dicarboxylate (DMCD) and DMCD-2, the Tg increased linearly with the increase of DMCD-2 mole content. DMA showed that all of the cycloaliphatic copolyesters had secondary relaxations, resulting from conformational transitions of the cyclohexylene rings. The polyester based on DMCD-3 in the hydrolytic tests underwent the fastest hydrolytic degradation among these samples. A new triptycene diol (TD) was synthesized and incorporated into a series of cycloaliphatic copolyester backbones by melt condensation polymerization.
    [Show full text]
  • TR-121: Dimethyl Terephthalate (CASRN 120-61-6)
    National Cancer Institute CARCINOGENESIS Technical Report Series NO. 121 1979 BIOASSAY OF DIMETHYL TEREPHTHALATE FOR POSSIBLE CARCINOGEN ICITY CAS No. 120-61-6 NCI-CG-TR-121 U.S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE Public Health Service National Institutes of Health BIOASSAY OF DIMETHYL TEREPHTHALATE FOR POSSIBLE CARCINOGENICITY Carcinogenesis Testing Program Division of Cancer Cause and Prevention National Cancer Institute National Institutes of Health Bethesda, Maryland 20205 U.S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE Public Health Service National Institutes of Health NIH Publication No. 79-1376 BIOASSAY OF DIMETHYL TEREPHTHALATE FOR POSSIBLE CARCINOGENICITY Carcinogenesis Testing Program Division of Cancer Cause and Prevention National Cancer Institute National Institutes of Health FOREWORD! This report presents the results of the bioassay of dimethyl terephthalate conducted for the Carcinogenesis Testing Program, Division of Cancer Cause and Prevention, National Cancer Institute (NCI), National Institutes of Health, Bethesda, Maryland. This is one of a series of experiments designed to determine whether selected chemicals have the capacity to produce cancer in animals. A negative result, in which the test animals do not have a greater incidence of cancer than control animals, does not necessarily mean that the test chemical is not a carcinogen, inasmuch as the experi­ ments are conducted under a limited set of circumstances. A positive result demonstrates that the test chemical is carcinogenic for animals under the conditions of the test and indicates that exposure to the chemical is a potential risk to man. The actual determination of the risk to man from chemicals found to be carcinogenic in animals requires a wider analysis.
    [Show full text]
  • AP-42, CH 6.11: Terephthalic Acid
    6.11 Terephthalic Acid 6.11.1 Process Description1 Terephthalic acid (TPA) is made by air oxidation of p-xylene and requires purification for use in polyester fiber manufacture. A typical continuous process for the manufacture of crude terephthalic acid (C-TPA) is shown in Figure 6.11-1. The oxidation and product recovery portion essentially consists of the Mid-Century oxidation process, whereas the recovery and recycle of acetic acid and recovery of methyl acetate are essentially as practiced by dimethyl terephthalate (DMT) technology. The purpose of the DMT process is to convert the terephthalic acid contained in C-TPA to a form that will permit its separation from impurities. C-TPA is extremely insoluble in both water and most common organic solvents. Additionally, it does not melt, it sublimes. Some products of partial oxidation of p-xylene, such as p-toluic acid and p-formyl benzoic acid, appear as impurities in TPA. Methyl acetate is also formed in significant amounts in the reaction. 6.11.1.1 C-TPA Production - Oxidation Of p-Xylene - p-Xylene (stream 1 of Figure 6.11-1), fresh acetic acid (2), a catalyst system such as manganese or cobalt acetate and sodium bromide (3), and recovered acetic acid are combined into the liquid feed entering the reactor (5). Air (6), compressed to a reaction pressure of about 2000 kPa (290 psi), is fed to the reactor. The temperature of the exothermic reaction is maintained at about 200°C (392°F) by controlling the pressure at which the reaction mixture is permitted to boil and form the vapor stream leaving the reactor (7).
    [Show full text]
  • (TPA) Is Made by Air Oxidation of P-Xylene and Requires Purification for Use in Polyester Fiber Manufacture
    6.11 Terephthalic Acid 6.11.1 Process Description1 Terephthalic acid (TPA) is made by air oxidation of p-xylene and requires purification for use in polyester fiber manufacture. A typical continuous process for the manufacture of crude terephthalic acid (C-TPA) is shown in Figure 6.11-1. The oxidation and product recovery portion essentially consists of the Mid-Century oxidation process, whereas the recovery and recycle of acetic acid and recovery of methyl acetate are essentially as practiced by dimethyl terephthalate (DMT) technology. The purpose of the DMT process is to convert the terephthalic acid contained in C-TPA to a form that will permit its separation from impurities. C-TPA is extremely insoluble in both water and most common organic solvents. Additionally, it does not melt, it sublimes. Some products of partial oxidation of p-xylene, such as p-toluic acid and p-formyl benzoic acid, appear as impurities in TPA. Methyl acetate is also formed in significant amounts in the reaction. 6.11.1.1 C-TPA Production - Oxidation Of p-Xylene - p-Xylene (stream 1 of Figure 6.11-1), fresh acetic acid (2), a catalyst system such as manganese or cobalt acetate and sodium bromide (3), and recovered acetic acid are combined into the liquid feed entering the reactor (5). Air (6), compressed to a reaction pressure of about 2000 kPa (290 psi), is fed to the reactor. The temperature of the exothermic reaction is maintained at about 200°C (392°F) by controlling the pressure at which the reaction mixture is permitted to boil and form the vapor stream leaving the reactor (7).
    [Show full text]
  • Terephthalic Acid & Dimethyl Terephthalate
    Report No. 9-A TEREPHTHALICACID AND DIMETHYLTEREPHTHALATE SUPPLEMENT A by LLOYD M. ELKIN m . contributions by SHIGEYOSHI TAKAOKA January 1967 A private report by the l PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA I CONTENTS I INTRODUCTION. ........................ 1 II SUMMARY ........................... 3 III INDUSTRY STATUS . 9 IV CHEMISTRY . 15 Ammoxidation of p-Xylene . 15 Terephthalic Acid by Bromine-Promoted Catalytic Air Oxidation ofp-Xylene......................... 17 Terephthalic Acid by Catalytic Oxidation of p-Xylene in the Presence of Methyl Ethyl Ketone (MEK) Activator , . 18 Terephthalic Acid by Nitric Acid Oxidation of p-Xylene . 19 Terephthalic Acid from Phthalic Anhydride . 19 Dimethyl Terephthalate from p-Xylene by Successive Oxidations and Esterifications . 20 V BIS(B-HYDROXYETHYL) TEREPHTHALATE FROM TEREPHTHALONITRILE MADE BY AMMOXIDATION OF P-XYLENE ................. 23 Review of Processes ..................... 23 Crude Terephthalonitrile Production and Purification .... 23 Ammonia Recovery ...................... 27 Bis(2-hydroxyethyl) terephthalate Production and Purification ....................... 27 Process Description ..................... 29 Process Discussion ..... ; ................ 51 Crude Terephthalonitrile Production ............ 51 Ammonia Recovery ...................... 52 Terephthalonitrile Purification .............. 52 Bis(2-hydroxyethyl) terephthalate Production ........ 52 Bis(2-hydroxyethyl) terephthalate Purification ....... 53 Ethylene Glycol Recovery .................
    [Show full text]
  • Process for Separating Cyclohexane Dimethanol
    Europaisches Patentamt (19) European Patent Office Office europeenpeen des brevets EP 0 724 559 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) intci.6: C07C 67/54, C07C 67/52, of the grant of the patent: C07C 67/03, C07C 69/82 30.12.1998 Bulletin 1998/53 (86) International application number: (21) Application number: 94930681.5 PCT/US94/11461 Date of 11.10.1994 (22) filing: (87) International publication number: WO 95/11218 (27.04.1995 Gazette 1995/18) (54) PROCESS FOR SEPARATING CYCLOHEXANE DIMETHANOL FROM DIMETHYL TEREPHTHALATE VERFAHREN ZUM TRENNEN VON CYCLOHEXANDIMETHYLOL UND DIMETHYLTEREPHTHALATE PROCEDE DE SEPARATION DU DIMETHANOL DE CYCLOHEXANE DU DIMETHYLTEREPHTALATE (84) Designated Contracting States: • YAU, Cheuk, Chung AT BE CH DE DK FR GB GR IE IT LI LU NL PT SE Kingsport, TN 37660 (US) • SINK, Chester, Wayne (30) Priority: 22.10.1993 US 139672 Kingsport, TN 37660 (US) (43) Date of publication of application: (74) Representative: 07.08.1996 Bulletin 1996/32 Wibbelmann, Jobst, Dr., Dipl.-Chem. Wuesthoff & Wuesthoff, (73) Proprietor: EASTMAN CHEMICAL COMPANY Patent- und Rechtsanwalte, Kingsport, TN 37660 (US) Schweigerstrasse 2 81541 Miinchen (DE) (72) Inventors: • HEISE, William, Herbert (56) References cited: Kingsport, TN 37663 (US) DE-B- 1 247 291 US-A- 3 776 945 • FOLK, Daniel, Paul Kingsport, TN 37660 (US) DO O) CM Is- Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice the Patent Office of the Notice of shall be filed in o to European opposition to European patent granted.
    [Show full text]
  • Biotransformation of P-Xylene Into Terephthalic Acid by Engineered Escherichia Coli
    ARTICLE Received 4 Feb 2017 | Accepted 18 Apr 2017 | Published 31 May 2017 DOI: 10.1038/ncomms15689 OPEN Biotransformation of p-xylene into terephthalic acid by engineered Escherichia coli Zi Wei Luo1 & Sang Yup Lee1,2,3 Terephthalic acid (TPA) is an important industrial chemical currently produced by energy intensive and potentially hazardous p-xylene (pX) oxidation process. Here we report the development of metabolically engineered Escherichia coli system for biological transformation of pX into TPA. The engineered E. coli strain harbours a synthetic TPA pathway optimized through manipulation of expression levels of upstream and downstream modules. The upstream pathway converts pXtop-toluic acid (pTA) and the downstream pathway transforms pTA to TPA. In a two-phase partitioning fermentation, the engineered strain converts 8.8 g pX into 13.3 g TPA, which corresponds to a conversion yield of 96.7 mol%. These results suggest that the E. coli system presented here might be a promising alternative for the large-scale biotechnological production of TPA and lays the foundations for the future development of sustainable approaches for TPA production. 1 Metabolic and Biomolecular Engineering National Research Laboratory, Department of Chemical and Biomolecular Engineering (BK21 Plus Program), Center for Systems and Synthetic Biotechnology, Institute for the BioCentury, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea. 2 BioProcess Engineering Research Center, KAIST, Daejeon 34141, Republic of Korea. 3 BioInformatics Research Center, KAIST, Daejeon 34141, Republic of Korea. Correspondence and requests for materials should be addressed to S.Y.L. (email: [email protected]).
    [Show full text]
  • Executive Summary Dimethyl Terephthalate (Dmt)
    EXECUTIVE SUMMARY DIMETHYL TEREPHTHALATE (DMT) 1. DMT is used in the manufacture of polyester fibre yarn and film and also certain polyester resins. Of these, polyester fibre and yarn account for a major portion of DMT used. DMT production in the world commenced as early as 1949 in England, whereas in India the first DMT plant was set up in 1973 by Indian Petrochemical Corporation Limited (IPCL) at Baroda. 2. At present there are three (3) major producers of DMT in India with a total installed capacity of 1,35,000 TPY (Indian Petrochemical Corporation Limited - 30,000, Bongaigaon Refinery & Pet- rochemicals Limited - 45,000, Bombay Dyeing & Manufacturing Company Limited-60,000). The targeted production for 1985-86 was 55,000 TPY because two of the units i.e. BRPL and BDML commenced production during 1985 only. The two main raw materials required for DMT manu- facture are p-xylene and methanol. For p-xylene, IPCL and BRPL have production capacity of 46,000 TPY which is not adequate to meet the demand of the installed DMT production capa- city. Therefore, p-xylene is being imported to meet the short-fall. The total methanol capacity on the other hand, shared between four (4) units is 81,000 TPY. Additional capacity of 5,31,000 TPY is covered by licences and with the progress of their implementation the total installed capacity would be adequate to meet the projected demand for polyester during the VII Five Year Plan. 3. DMT is produced in the country by the well-known Witten Process involves stepwise indirect oxidation/esterification of p-xylene.
    [Show full text]
  • Synthesis, Properties and Applications of Biodegradable Polymers Derived from Diols and Dicarboxylic Acids: from Polyesters to Poly(Ester Amide)S
    Int. J. Mol. Sci. 2014, 15, 7064-7123; doi:10.3390/ijms15057064 OPEN ACCESS International Journal of Molecular Sciences ISSN 1422-0067 www.mdpi.com/journal/ijms Review Synthesis, Properties and Applications of Biodegradable Polymers Derived from Diols and Dicarboxylic Acids: From Polyesters to Poly(ester amide)s Angélica Díaz 1, Ramaz Katsarava 2,* and Jordi Puiggalí 1,* 1 Chemical Engineering Department, Polytechnic University of Catalonia, Av. Diagonal 647, E-08028 Barcelona, Spain; E-Mail: [email protected] 2 Institute of Chemistry and Molecular Engineering, Agricultural University of Georgia, 13 km. David Aghmashenebeli Alley, Tbilisi 0159, Georgia * Authors to whom correspondence should be addressed; E-Mails: [email protected] (R.K.); [email protected] (J.P.); Tel.: +995-59-915-9209 (R.K.); +34-93-401-6684 (J.P.); Fax: +995-32-233-7594 (R.K.); +34-93-401-7150 (J.P.). Received: 27 February 2014; in revised form: 31 March 2014 / Accepted: 31 March 2014 / Published: 25 April 2014 Abstract: Poly(alkylene dicarboxylate)s constitute a family of biodegradable polymers with increasing interest for both commodity and speciality applications. Most of these polymers can be prepared from biobased diols and dicarboxylic acids such as 1,4-butanediol, succinic acid and carbohydrates. This review provides a current status report concerning synthesis, biodegradation and applications of a series of polymers that cover a wide range of properties, namely, materials from elastomeric to rigid characteristics that are suitable for applications such as hydrogels, soft tissue engineering, drug delivery systems and liquid crystals. Finally, the incorporation of aromatic units and α-amino acids is considered since stiffness of molecular chains and intermolecular interactions can be drastically changed.
    [Show full text]