View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Archive Ouverte en Sciences de l'Information et de la Communication Effects of Rare-Gas Matrices on the Optical Response of Silver Nanoclusters R. Schira, Franck Rabilloud To cite this version: R. Schira, Franck Rabilloud. Effects of Rare-Gas Matrices on the Optical Response ofSil- ver Nanoclusters. JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122, pp.27656-27661. 10.1021/acs.jpcc.8b10388. hal-02289870 HAL Id: hal-02289870 https://hal-univ-lyon1.archives-ouvertes.fr/hal-02289870 Submitted on 16 Jan 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Effects of Rare-Gas Matrices on the Optical Response of Silver Nanoclusters Romain SCHIRA and Franck RABILLOUD* Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, F-69622, Villeurbanne, France Corresponding author:
[email protected] Abstract: The optical response of silver clusters, Agn with n = 8, 20, 35, 58, 92, embedded in a rare-gas matrix are calculated in the framework of the Time-Dependent Density Functional Theory (TDDFT). We present a methodology able to reproduce with unprecedented accuracy the experimental spectra measured on metal clusters embedded in neon, argon, krypton and xenon solid matrices.