United States Patent (19) 11 Patent Number: 4,764,566 Swedo (45
United States Patent (19) 11 Patent Number: 4,764,566 Swedo (45. Date of Patent: Aug. 16, 1988 54 PENDANT BIPHENYLENE ASA OTHER PUBLICATIONS CROSS-LINKING SITE IN AROMATIC THERMOPLASTC POLYMERS Garapon & Stille, Macromolecules, 10, 627 (1977). Recca & Stille, ibid., 10, 1344 (1977) & 11, 479 (1978). (75) Inventor: Raymond J. Swedo, Mt. Prospect, Ill. Swedo and Marvel, J. PolymerSci, Polymer Chem. Ed., 16, 2711 (1978). (73 Assignee: Allied-Signal Inc., Morristown, N.J. Ibid, 15, 683 (1977) and 17, 2815 (1979). M Primary Examiner-Theodore E. Pertilla 21 Appl. No.: 46,813 Attorney, Agent, or Firm-Thomas K. McBride; Eugene I. Snyder Fied: May 7, 1987 22 57 ABSTRACT (51) Int. Cl.' ...... 0 v 0 p a y who C08 L 71/04 Thermally stable polymers may be cross-linked by ap (52) U.S. C. .................................... 525/390; 525/397; pending biphenylene moieties to the polymer backbone, w 525/462; 525/471 then heating the modified polymer at a temperature in (58) Field of Search ................ 525/462,390, 397, 471 excess of about 300' C. The cross-link density of the cured polymer can be controlled by varying the relative 56) References Cited population of biphenylene moieties on the polymer U.S. PATENT DOCUMENTS backbone. Properties of the modified but uncured poly mer are essentially the same as those in the original 4,197,393 4/1980 Swedo et al. ....................... 528/173 4,269,953 5/1981 Brand .................................. 52.5/534 thermally stable polymer. 4,414,380 1 1/1983 Swedo ................................. 528/173 4,507,462 3/1985 Stille .................................... 528/125 14 Claims, No Drawings 4,764,566 1.
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