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C:\Projects\Arizona DEQ\Arizona Clean Fuels\Draft Technical Support TECHNICAL SUPPORT DOCUMENT AND STATEMENT OF BASIS FOR CONSTRUCTION OF ARIZONA CLEAN FUELS YUMA, LLC PETROLEUM REFINERY Permit Number 1001205 August 30, 2004 TABLE OF CONTENTS I. INTRODUCTION ...........................................Page 1 of 449 A. Company Information..................................Page 1 of 449 B. Attainment Classification...............................Page 1 of 449 II. PROCESS DESCRIPTION ...................................Page 1 of 449 A. Crude Distillation Unit .................................Page 4 of 449 B. Gas Concentration Plant ...............................Page 4 of 449 C. Hydrocracker Unit ....................................Page 5 of 449 D. Naphtha Hydrotreater Unit .............................Page 6 of 449 E. Catalytic Reforming Unit ...............................Page 7 of 449 F. Isomerization Unit ....................................Page 7 of 449 G. Distillate Hydrotreater Unit .............................Page 8 of 449 H. Butane Conversion Unit ................................Page 9 of 449 I. Benzene Reduction Unit ...............................Page 10 of 449 J. Delayed Coking Unit ..................................Page 10 of 449 K. Petroleum Coke Storage, Handling, and Loading ..........Page 11 of 449 L. Amine Regeneration Unit ..............................Page 11 of 449 M. Sour Water Stripper ..................................Page 12 of 449 N. Sulfur Recovery Plant ................................Page 12 of 449 O. Hydrogen Plant ......................................Page 14 of 449 P. Group “A” Storage Tanks .............................Page 14 of 449 Q. Group “B” Storage Tanks .............................Page 14 of 449 R. Group “C” Storage Tanks .............................Page 15 of 449 S. Group “D” Storage Tanks .............................Page 15 of 449 T. Group “E” Storage Tank ..............................Page 15 of 449 U. Truck and Rail Car Loading Racks .....................Page 15 of 449 V. Benzene Waste Operation .............................Page 15 of 449 W. Wastewater Treatment Plant ...........................Page 16 of 449 X. Equipment Leaks ....................................Page 18 of 449 Y. Emergency Flares ....................................Page 18 of 449 Z. Steam Boilers ........................................Page 18 of 449 AA. Cooling Tower .......................................Page 19 of 449 BB. Internal Combustion Engines ..........................Page 19 of 449 CC. Mobile Sources and Fugitive Dust Sources ...............Page 19 of 449 III. EMISSIONS ...............................................Page 20 of 449 A. General.............................................Page 20 of 449 B. Process Heaters ......................................Page 25 of 449 C. Boilers..............................................Page 31 of 449 D. Sulfur Recovery Plant.................................Page 33 of 449 E. Group “B” Storage Tanks and Tank Farm Thermal Oxidizer ....................................................Page 35 of 449 F. Wastewater Treatment Plant...........................Page 42 of 449 G. Truck and Rail Car Loading Racks......................Page 45 of 449 H. Group “C” Storage Tanks .............................Page 49 of 449 Arizona Clean Fuels Yuma, LLC Permit Number 1001205 - DRAFTi August 30, 2004 I. Sour Water Tank.....................................Page 52 of 449 J. Emergency Flares ....................................Page 54 of 449 K. Coke Silo Baghouse...................................Page 56 of 449 L. Spray Dryer Baghouse.................................Page 57 of 449 M. Catalyst Regenerators.................................Page 58 of 449 N. Cooling Tower .......................................Page 61 of 449 O. Equipment Leaks.....................................Page 64 of 449 P. Internal Combustion Engines..........................Page 130 of 449 Q. Vehicle Traffic on Paved Areas ........................Page 132 of 449 IV. REGULATORY APPLICABILITY ..........................Page 134 of 449 A. Permit Regulations ..................................Page 134 of 449 1. Class I Permit.................................Page 134 of 449 2. Nonattainment New Source Review ...............Page 134 of 449 3. Prevention of Significant Deterioration............Page 134 of 449 B. New Source Performance Standards (NSPS) .............Page 135 of 449 1. 40 CFR 60 Subpart A, General Provisions .........Page 135 of 449 2. 40 CFR 60 Subpart D, Fossil-Fuel-Fired Steam Generators .............................................Page 135 of 449 3. 40 CFR 60 Subpart Da, Electric Utility Steam Generating Units .............................................Page 136 of 449 4. 40 CFR 60 Subpart Db, Industrial-Commercial-Institutional Steam Generating Units ..............................Page 136 of 449 5. 40 CFR 60 Subpart Dc, Small Industrial-Commercial-Institutional Steam Generating Units ........................Page 136 of 449 6. 40 CFR 60 Subpart J, Petroleum Refineries ........Page 136 of 449 7. 40 CFR 60 Subpart Kb, Volatile Organic Liquid Storage Vessels .............................................Page 137 of 449 8. 40 CFR 60 Subpart UU, Asphalt Processing ........Page 138 of 449 9. 40 CFR 60 Subpart VV, Synthetic Organic Chemicals Manufacturing Industry (SOCMI) Equipment Leaks .............Page 138 of 449 10. 40 CFR 60 Subpart XX, Bulk Gasoline Terminals . Page 139 of 449 11. 40 CFR 60 Subpart GGG, Equipment Leaks of VOC in Petroleum Refineries ....................................Page 139 of 449 12. 40 CFR 60 Subpart NNN, VOC Emissions from SOCMI Distillation Operations ...................................Page 139 of 449 13. 40 CFR 60 Subpart QQQ, VOC Emissions from Petroleum Refinery Wastewater Systems ...........................Page 140 of 449 14. 40 CFR 60 Subpart RRR, VOC Emissions from SOCMI Reactor Processes.....................................Page 140 of 449 C. National Emission Standards for Hazardous Air Pollutants (NESHAP) ...................................................Page 141 of 449 1. 40 CFR 61 Subpart A, General Provisions .........Page 141 of 449 2. 40 CFR 61 Subpart FF, Benzene Waste Operations . Page 141 of 449 3. 40 CFR 63 Subpart A, General Provisions .........Page 142 of 449 4. 40 CFR 63 Subpart B, Control Technology Determinations for Major Arizona Clean Fuels Yuma, LLC Permit Number 1001205 - DRAFTii August 30, 2004 Sources in Accordance with Clean Air Act §§ 112(g) and 112(j) .............................................Page 142 of 449 5. 40 CFR 63 Subparts F and G, SOCMI Process Units .............................................Page 143 of 449 6. 40 CFR 63 Subpart H, Equipment Leaks ..........Page 143 of 449 7. 40 CFR 63 Subpart R, Gasoline Distribution Facilities .............................................Page 144 of 449 8. 40 CFR 63 Subpart CC, Petroleum Refineries ......Page 144 of 449 9. 40 CFR 63 Subpart UUU, Petroleum Refinery Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units .............................................Page 147 of 449 10. 40 CFR 63 Subpart EEEE, Organic Liquids Distribution (Non-Gasoline) .............................................Page 148 of 449 11. 40 CFR 63 Subpart ZZZZ, Stationary Reciprocating Internal Combustion Engines ...........................Page 148 of 449 12. 40 CFR 63 Subpart DDDDD, Industrial Boilers and Process Heaters .............................................Page 148 of 449 D. Arizona Administrative Code..........................Page 149 of 449 1. A.A.C. R18-2-602, Open Burning .................Page 149 of 449 2. A.A.C. R18-2-604, Open Areas, Dry Washes, or Riverbeds .............................................Page 149 of 449 3. A.A.C. R18-2-605, Roadways and Streets ..........Page 149 of 449 4. A.A.C. R18-2-606, Material Handling .............Page 149 of 449 5. A.A.C. R18-2-607, Storage Piles ..................Page 149 of 449 6. A.A.C. R18-2-612, Opacity of Emissions from Nonpoint Sources .............................................Page 149 of 449 7. A.A.C. R18-2-702, General Provisions for Existing Point Sources .............................................Page 150 of 449 8. A.A.C. R18-2-703, Steam Generators and Fuel-Burning Equipment .............................................Page 150 of 449 9. A.A.C. R18-2-704, Incinerators ..................Page 150 of 449 10. A.A.C. R18-2-709, Petroleum Refineries ...........Page 150 of 449 11. A.A.C. R18-2-710, Petroleum Liquid Storage Vessels .............................................Page 151 of 449 12. A.A.C. R18-2-719, Stationary Rotating Machinery . Page 151 of 449 13. A.A.C. R18-2-724, Fossil-fuel Fired Equipment .....Page 151 of 449 14. A.A.C. R18-2-726, Sandblasting Operations ........Page 151 of 449 15. A.A.C. R18-2-727, Spray Painting Operations ......Page 152 of 449 16. A.A.C. R18-2-730, Unclassified Sources ...........Page 152 of 449 17. A.A.C. R18-2-801, General Provisions for Mobile Sources .............................................Page 152 of 449 18. A.A.C. R18-2-802, Off-Road Machinery ...........Page 152 of 449 19. A.A.C. R18-2-804, Roadway and Site-Cleaning Machinery .............................................Page 152 of 449 20. Article 9, New Source Performance Standards ......Page 152 of 449 Arizona Clean Fuels Yuma, LLC Permit Number 1001205 - DRAFTiii August 30, 2004 21. Article 11, Federal Hazardous Air Pollutants .......Page 153 of 449 E. Compliance Assurance Monitoring.....................Page 153 of 449 V. CONTROL TECHNOLOGY ANALYSES .....................Page 155 of 449 A. General............................................Page
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