Chapter 6. Time Evolution in Quantum Mechanics
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Symmetry Conditions on Dirac Observables
Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 2, 671–676 Symmetry Conditions on Dirac Observables Heinz Otto CORDES Department of Mathematics, University of California, Berkeley, CA 94720 USA E-mail: [email protected] Using our Dirac invariant algebra we attempt a mathematically and philosophically clean theory of Dirac observables, within the environment of the 4 books [10,9,11,4]. All classical objections to one-particle Dirac theory seem removed, while also some principal objections to von Neumann’s observable theory may be cured. Heisenberg’s uncertainty principle appears improved. There is a clean and mathematically precise pseudodifferential Foldy–Wouthuysen transform, not only for the supersymmeytric case, but also for general (C∞-) potentials. 1 Introduction The free Dirac Hamiltonian H0 = αD+β is a self-adjoint square root of 1−∆ , with the Laplace HS − 1 operator ∆. The free Schr¨odinger√ Hamiltonian 0 =1 2 ∆ (where “1” is the “rest energy” 2 1 mc ) seems related to H0 like 1+x its approximation 1+ 2 x – second partial sum of its Taylor expansion. From that aspect the early discoverers of Quantum Mechanics were lucky that the energies of the bound states of hydrogen (a few eV) are small, compared to the mass energy of an electron (approx. 500 000 eV), because this should make “Schr¨odinger” a good approximation of “Dirac”. But what about the continuous spectrum of both operators – governing scattering theory. Note that today big machines scatter with energies of about 10,000 – compared to the above 1 = mc2. So, from that aspect the precise scattering theory of both Hamiltonians (with potentials added) should give completely different results, and one may have to put ones trust into one of them, because at most one of them can be applicable. -
An Introduction to Quantum Field Theory
AN INTRODUCTION TO QUANTUM FIELD THEORY By Dr M Dasgupta University of Manchester Lecture presented at the School for Experimental High Energy Physics Students Somerville College, Oxford, September 2009 - 1 - - 2 - Contents 0 Prologue....................................................................................................... 5 1 Introduction ................................................................................................ 6 1.1 Lagrangian formalism in classical mechanics......................................... 6 1.2 Quantum mechanics................................................................................... 8 1.3 The Schrödinger picture........................................................................... 10 1.4 The Heisenberg picture............................................................................ 11 1.5 The quantum mechanical harmonic oscillator ..................................... 12 Problems .............................................................................................................. 13 2 Classical Field Theory............................................................................. 14 2.1 From N-point mechanics to field theory ............................................... 14 2.2 Relativistic field theory ............................................................................ 15 2.3 Action for a scalar field ............................................................................ 15 2.4 Plane wave solution to the Klein-Gordon equation ........................... -
Relational Quantum Mechanics and Probability M
Relational Quantum Mechanics and Probability M. Trassinelli To cite this version: M. Trassinelli. Relational Quantum Mechanics and Probability. Foundations of Physics, Springer Verlag, 2018, 10.1007/s10701-018-0207-7. hal-01723999v3 HAL Id: hal-01723999 https://hal.archives-ouvertes.fr/hal-01723999v3 Submitted on 29 Aug 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Noname manuscript No. (will be inserted by the editor) Relational Quantum Mechanics and Probability M. Trassinelli the date of receipt and acceptance should be inserted later Abstract We present a derivation of the third postulate of Relational Quan- tum Mechanics (RQM) from the properties of conditional probabilities. The first two RQM postulates are based on the information that can be extracted from interaction of different systems, and the third postulate defines the prop- erties of the probability function. Here we demonstrate that from a rigorous definition of the conditional probability for the possible outcomes of different measurements, the third postulate is unnecessary and the Born's rule naturally emerges from the first two postulates by applying the Gleason's theorem. We demonstrate in addition that the probability function is uniquely defined for classical and quantum phenomena. -
On the Time Evolution of Wavefunctions in Quantum Mechanics C
On the Time Evolution of Wavefunctions in Quantum Mechanics C. David Sherrill School of Chemistry and Biochemistry Georgia Institute of Technology October 1999 1 Introduction The purpose of these notes is to help you appreciate the connection between eigenfunctions of the Hamiltonian and classical normal modes, and to help you understand the time propagator. 2 The Classical Coupled Mass Problem Here we will review the results of the coupled mass problem, Example 1.8.6 from Shankar. This is an example from classical physics which nevertheless demonstrates some of the essential features of coupled degrees of freedom in quantum mechanical problems and a general approach for removing such coupling. The problem involves two objects of equal mass, connected to two different walls andalsotoeachotherbysprings.UsingF = ma and Hooke’s Law( F = −kx) for the springs, and denoting the displacements of the two masses as x1 and x2, it is straightforward to deduce equations for the acceleration (second derivative in time,x ¨1 andx ¨2): k k x −2 x x ¨1 = m 1 + m 2 (1) k k x x − 2 x . ¨2 = m 1 m 2 (2) The goal of the problem is to solve these second-order differential equations to obtain the functions x1(t)andx2(t) describing the motion of the two masses at any given time. Since they are second-order differential equations, we need two initial conditions for each variable, i.e., x1(0), x˙ 1(0),x2(0), andx ˙ 2(0). Our two differential equations are clearly coupled,since¨x1 depends not only on x1, but also on x2 (and likewise forx ¨2). -
An S-Matrix for Massless Particles Arxiv:1911.06821V2 [Hep-Th]
An S-Matrix for Massless Particles Holmfridur Hannesdottir and Matthew D. Schwartz Department of Physics, Harvard University, Cambridge, MA 02138, USA Abstract The traditional S-matrix does not exist for theories with massless particles, such as quantum electrodynamics. The difficulty in isolating asymptotic states manifests itself as infrared divergences at each order in perturbation theory. Building on insights from the literature on coherent states and factorization, we construct an S-matrix that is free of singularities order-by-order in perturbation theory. Factorization guarantees that the asymptotic evolution in gauge theories is universal, i.e. independent of the hard process. Although the hard S-matrix element is computed between well-defined few particle Fock states, dressed/coherent states can be seen to form as intermediate states in the calculation of hard S-matrix elements. We present a framework for the perturbative calculation of hard S-matrix elements combining Lorentz-covariant Feyn- man rules for the dressed-state scattering with time-ordered perturbation theory for the asymptotic evolution. With hard cutoffs on the asymptotic Hamiltonian, the cancella- tion of divergences can be seen explicitly. In dimensional regularization, where the hard cutoffs are replaced by a renormalization scale, the contribution from the asymptotic evolution produces scaleless integrals that vanish. A number of illustrative examples are given in QED, QCD, and N = 4 super Yang-Mills theory. arXiv:1911.06821v2 [hep-th] 24 Aug 2020 Contents 1 Introduction1 2 The hard S-matrix6 2.1 SH and dressed states . .9 2.2 Computing observables using SH ........................... 11 2.3 Soft Wilson lines . 14 3 Computing the hard S-matrix 17 3.1 Asymptotic region Feynman rules . -
Identical Particles
8.06 Spring 2016 Lecture Notes 4. Identical particles Aram Harrow Last updated: May 19, 2016 Contents 1 Fermions and Bosons 1 1.1 Introduction and two-particle systems .......................... 1 1.2 N particles ......................................... 3 1.3 Non-interacting particles .................................. 5 1.4 Non-zero temperature ................................... 7 1.5 Composite particles .................................... 7 1.6 Emergence of distinguishability .............................. 9 2 Degenerate Fermi gas 10 2.1 Electrons in a box ..................................... 10 2.2 White dwarves ....................................... 12 2.3 Electrons in a periodic potential ............................. 16 3 Charged particles in a magnetic field 21 3.1 The Pauli Hamiltonian ................................... 21 3.2 Landau levels ........................................ 23 3.3 The de Haas-van Alphen effect .............................. 24 3.4 Integer Quantum Hall Effect ............................... 27 3.5 Aharonov-Bohm Effect ................................... 33 1 Fermions and Bosons 1.1 Introduction and two-particle systems Previously we have discussed multiple-particle systems using the tensor-product formalism (cf. Section 1.2 of Chapter 3 of these notes). But this applies only to distinguishable particles. In reality, all known particles are indistinguishable. In the coming lectures, we will explore the mathematical and physical consequences of this. First, consider classical many-particle systems. If a single particle has state described by position and momentum (~r; p~), then the state of N distinguishable particles can be written as (~r1; p~1; ~r2; p~2;:::; ~rN ; p~N ). The notation (·; ·;:::; ·) denotes an ordered list, in which different posi tions have different meanings; e.g. in general (~r1; p~1; ~r2; p~2)6 = (~r2; p~2; ~r1; p~1). 1 To describe indistinguishable particles, we can use set notation. -
Advanced Quantum Mechanics
Advanced Quantum Mechanics Rajdeep Sensarma [email protected] Quantum Dynamics Lecture #9 Schrodinger and Heisenberg Picture Time Independent Hamiltonian Schrodinger Picture: A time evolving state in the Hilbert space with time independent operators iHtˆ i@t (t) = Hˆ (t) (t) = e− (0) | i | i | i | i i✏nt Eigenbasis of Hamiltonian: Hˆ n = ✏ n (t) = cn(t) n c (t)=c (0)e− n | i | i n n | i | i n X iHtˆ iHtˆ Operators and Expectation: A(t)= (t) Aˆ (t) = (0) e Aeˆ − (0) = (0) Aˆ(t) (0) h | | i h | | i h | | i Heisenberg Picture: A static initial state and time dependent operators iHtˆ iHtˆ Aˆ(t)=e Aeˆ − Schrodinger Picture Heisenberg Picture (0) (t) (0) (0) | i!| i | i!| i Equivalent description iHtˆ iHtˆ Aˆ Aˆ Aˆ Aˆ(t)=e Aeˆ − ! ! of a quantum system i@ (t) = Hˆ (t) i@ Aˆ(t)=[Aˆ(t), Hˆ ] t| i | i t Time Evolution and Propagator iHtˆ (t) = e− (0) Time Evolution Operator | i | i (x, t)= x (t) = x Uˆ(t) (0) = dx0 x Uˆ(t) x0 x0 (0) h | i h | | i h | | ih | i Z Propagator: Example : Free Particle The propagator satisfies and hence is often called the Green’s function Retarded and Advanced Propagator The following propagators are useful in different contexts Retarded or Causal Propagator: This propagates states forward in time for t > t’ Advanced or Anti-Causal Propagator: This propagates states backward in time for t < t’ Both the retarded and the advanced propagator satisfies the same diff. eqn., but with different boundary conditions Propagators in Frequency Space Energy Eigenbasis |n> The integral is ill defined due to oscillatory nature -
The First Law of Thermodynamics for Closed Systems A) the Energy
Chapter 3: The First Law of Thermodynamics for Closed Systems a) The Energy Equation for Closed Systems We consider the First Law of Thermodynamics applied to stationary closed systems as a conservation of energy principle. Thus energy is transferred between the system and the surroundings in the form of heat and work, resulting in a change of internal energy of the system. Internal energy change can be considered as a measure of molecular activity associated with change of phase or temperature of the system and the energy equation is represented as follows: Heat (Q) Energy transferred across the boundary of a system in the form of heat always results from a difference in temperature between the system and its immediate surroundings. We will not consider the mode of heat transfer, whether by conduction, convection or radiation, thus the quantity of heat transferred during any process will either be specified or evaluated as the unknown of the energy equation. By convention, positive heat is that transferred from the surroundings to the system, resulting in an increase in internal energy of the system Work (W) In this course we consider three modes of work transfer across the boundary of a system, as shown in the following diagram: Source URL: http://www.ohio.edu/mechanical/thermo/Intro/Chapt.1_6/Chapter3a.html Saylor URL: http://www.saylor.org/me103#4.1 Attributed to: Israel Urieli www.saylor.org Page 1 of 7 In this course we are primarily concerned with Boundary Work due to compression or expansion of a system in a piston-cylinder device as shown above. -
The Liouville Equation in Atmospheric Predictability
The Liouville Equation in Atmospheric Predictability Martin Ehrendorfer Institut fur¨ Meteorologie und Geophysik, Universitat¨ Innsbruck Innrain 52, A–6020 Innsbruck, Austria [email protected] 1 Introduction and Motivation It is widely recognized that weather forecasts made with dynamical models of the atmosphere are in- herently uncertain. Such uncertainty of forecasts produced with numerical weather prediction (NWP) models arises primarily from two sources: namely, from imperfect knowledge of the initial model condi- tions and from imperfections in the model formulation itself. The recognition of the potential importance of accurate initial model conditions and an accurate model formulation dates back to times even prior to operational NWP (Bjerknes 1904; Thompson 1957). In the context of NWP, the importance of these error sources in degrading the quality of forecasts was demonstrated to arise because errors introduced in atmospheric models, are, in general, growing (Lorenz 1982; Lorenz 1963; Lorenz 1993), which at the same time implies that the predictability of the atmosphere is subject to limitations (see, Errico et al. 2002). An example of the amplification of small errors in the initial conditions, or, equivalently, the di- vergence of initially nearby trajectories is given in Fig. 1, for the system discussed by Lorenz (1984). The uncertainty introduced into forecasts through uncertain initial model conditions, and uncertainties in model formulations, has been the subject of numerous studies carried out in parallel to the continuous development of NWP models (e.g., Leith 1974; Epstein 1969; Palmer 2000). In addition to studying the intrinsic predictability of the atmosphere (e.g., Lorenz 1969a; Lorenz 1969b; Thompson 1985a; Thompson 1985b), efforts have been directed at the quantification or predic- tion of forecast uncertainty that arises due to the sources of uncertainty mentioned above (see the review papers by Ehrendorfer 1997 and Palmer 2000, and Ehrendorfer 1999). -
Law of Conversation of Energy
Law of Conservation of Mass: "In any kind of physical or chemical process, mass is neither created nor destroyed - the mass before the process equals the mass after the process." - the total mass of the system does not change, the total mass of the products of a chemical reaction is always the same as the total mass of the original materials. "Physics for scientists and engineers," 4th edition, Vol.1, Raymond A. Serway, Saunders College Publishing, 1996. Ex. 1) When wood burns, mass seems to disappear because some of the products of reaction are gases; if the mass of the original wood is added to the mass of the oxygen that combined with it and if the mass of the resulting ash is added to the mass o the gaseous products, the two sums will turn out exactly equal. 2) Iron increases in weight on rusting because it combines with gases from the air, and the increase in weight is exactly equal to the weight of gas consumed. Out of thousands of reactions that have been tested with accurate chemical balances, no deviation from the law has ever been found. Law of Conversation of Energy: The total energy of a closed system is constant. Matter is neither created nor destroyed – total mass of reactants equals total mass of products You can calculate the change of temp by simply understanding that energy and the mass is conserved - it means that we added the two heat quantities together we can calculate the change of temperature by using the law or measure change of temp and show the conservation of energy E1 + E2 = E3 -> E(universe) = E(System) + E(Surroundings) M1 + M2 = M3 Is T1 + T2 = unknown (No, no law of conservation of temperature, so we have to use the concept of conservation of energy) Total amount of thermal energy in beaker of water in absolute terms as opposed to differential terms (reference point is 0 degrees Kelvin) Knowns: M1, M2, T1, T2 (Kelvin) When add the two together, want to know what T3 and M3 are going to be. -
Two-State Systems
1 TWO-STATE SYSTEMS Introduction. Relative to some/any discretely indexed orthonormal basis |n) | ∂ | the abstract Schr¨odinger equation H ψ)=i ∂t ψ) can be represented | | | ∂ | (m H n)(n ψ)=i ∂t(m ψ) n ∂ which can be notated Hmnψn = i ∂tψm n H | ∂ | or again ψ = i ∂t ψ We found it to be the fundamental commutation relation [x, p]=i I which forced the matrices/vectors thus encountered to be ∞-dimensional. If we are willing • to live without continuous spectra (therefore without x) • to live without analogs/implications of the fundamental commutator then it becomes possible to contemplate “toy quantum theories” in which all matrices/vectors are finite-dimensional. One loses some physics, it need hardly be said, but surprisingly much of genuine physical interest does survive. And one gains the advantage of sharpened analytical power: “finite-dimensional quantum mechanics” provides a methodological laboratory in which, not infrequently, the essentials of complicated computational procedures can be exposed with closed-form transparency. Finally, the toy theory serves to identify some unanticipated formal links—permitting ideas to flow back and forth— between quantum mechanics and other branches of physics. Here we will carry the technique to the limit: we will look to “2-dimensional quantum mechanics.” The theory preserves the linearity that dominates the full-blown theory, and is of the least-possible size in which it is possible for the effects of non-commutivity to become manifest. 2 Quantum theory of 2-state systems We have seen that quantum mechanics can be portrayed as a theory in which • states are represented by self-adjoint linear operators ρ ; • motion is generated by self-adjoint linear operators H; • measurement devices are represented by self-adjoint linear operators A. -
2.-Time-Evolution-Operator-11-28
2. TIME-EVOLUTION OPERATOR Dynamical processes in quantum mechanics are described by a Hamiltonian that depends on time. Naturally the question arises how do we deal with a time-dependent Hamiltonian? In principle, the time-dependent Schrödinger equation can be directly integrated choosing a basis set that spans the space of interest. Using a potential energy surface, one can propagate the system forward in small time-steps and follow the evolution of the complex amplitudes in the basis states. In practice even this is impossible for more than a handful of atoms, when you treat all degrees of freedom quantum mechanically. However, the mathematical complexity of solving the time-dependent Schrödinger equation for most molecular systems makes it impossible to obtain exact analytical solutions. We are thus forced to seek numerical solutions based on perturbation or approximation methods that will reduce the complexity. Among these methods, time-dependent perturbation theory is the most widely used approach for calculations in spectroscopy, relaxation, and other rate processes. In this section we will work on classifying approximation methods and work out the details of time-dependent perturbation theory. 2.1. Time-Evolution Operator Let’s start at the beginning by obtaining the equation of motion that describes the wavefunction and its time evolution through the time propagator. We are seeking equations of motion for quantum systems that are equivalent to Newton’s—or more accurately Hamilton’s—equations for classical systems. The question is, if we know the wavefunction at time t0 rt, 0 , how does it change with time? How do we determine rt, for some later time tt 0 ? We will use our intuition here, based largely on correspondence to classical mechanics).