Boron-Based Nanomaterials Under Extreme Conditions Remi Grosjean
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Superhard and Superconducting B6C
Superhard and Superconducting B6C Kang Xia a, Mengdong Ma b, Cong Liu a, Hao Gao a, Qun Chen a, Julong He b, Jian Sun a,*, Hui-Tian Wang a, Yongjun Tian b, and Dingyu Xing a a National Laboratory of Solid State Microstructures, School of Physics and Collaborative Innovation Center of Advanced Microstructure, Nanjing University, Nanjing 210093, China b State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China ABSTRACT Crystal structure searching and ab initio calculations have been used here to explore low-energy structures of boron carbides under high pressure. Under pressures of 85–110 GPa, a metastable B6C with R3 m symmetry is found to be energetically more stable than the mixture of previous B4C and elemental boron. This B6C is a rhombohedral structure and contains mooncake-like B24 clusters with stuffing of C2 pairs. The mechanical and dynamical stabilities of this structure at ambient pressure are confirmed by its elastic constants and phonon dispersions. The bulk modulus and shear modulus of this newly predicted B6C at ambient pressure reach high values of 291 GPa and 272 GPa, respectively. The Vickers hardness is calculated to be around 48 GPa, and its melting temperature at ambient pressure is estimated to be around 2500 K, indicating that this metastable B6C is a potential superhard material with very good thermal stability. Interestingly, this superhard B6C structure is also found to be superconducting and its superconducting critical temperature (Tc) is evaluated to be around 12.5 K at ambient pressure by electron-phonon coupling. * Corresponding author. E-mail address: [email protected] 1. -
Materials Design and Band Gap Engineering of Complex
University of Louisville ThinkIR: The University of Louisville's Institutional Repository Electronic Theses and Dissertations 8-2016 Materials design and band gap engineering of complex nanostructures using a semi-empirical approach : low dimensional boron nanostructures, h-BN sheet with graphene domains and holey graphene. Cherno Baba Kah Follow this and additional works at: https://ir.library.louisville.edu/etd Part of the Condensed Matter Physics Commons Recommended Citation Kah, Cherno Baba, "Materials design and band gap engineering of complex nanostructures using a semi- empirical approach : low dimensional boron nanostructures, h-BN sheet with graphene domains and holey graphene." (2016). Electronic Theses and Dissertations. Paper 2491. https://doi.org/10.18297/etd/2491 This Doctoral Dissertation is brought to you for free and open access by ThinkIR: The University of Louisville's Institutional Repository. It has been accepted for inclusion in Electronic Theses and Dissertations by an authorized administrator of ThinkIR: The University of Louisville's Institutional Repository. This title appears here courtesy of the author, who has retained all other copyrights. For more information, please contact [email protected]. MATERIALS DESIGN AND BAND GAP ENGINEERING OF COMPLEX : LOW NANOSTRUCTURES USING A SEMI-EMPIRICAL APPROACH , h DIMENSIONAL BORON NANOSTRUCTURES - BN SHEET WITH GRAPHENE DOMAINS AND HOLEY GRAPHENE By Cherno Baba Kah M.S, University of Louisville, 2013 M.S, Clark Atlanta University, 2011 B.S, University of The Gambia, -
LOUISIANA SCIENTIST Vol. 1A No. 3
LOUISIANA SCIENTIST THE NEWSLETTER of the LOUISIANA ACADEMY OF SCIENCES Volume 1A, No. 3 (2007 Annual Meeting Abstracts) Published by THE LOUISIANA ACADEMY OF SCIENCES 15 June 2012 Louisiana Academy of Sciences Abstracts of Presentations 2007 Annual Meeting Southern University and A&M College Baton Rouge, Louisiana 16 March 2007 Table of Contents Division/Section Page Division of Agriculture, Forestry, and Wildlife . 5 Division of Biological Sciences . 11 Botany Section . 11 Environmental Sciences Section . 11 Microbiology Section . 17 Molecular and Biomedical Biology Section . 21 Zoology Section . 23 Division of Physical Sciences . 28 Chemistry Section . 28 Computer Science Section . 34 Earth Sciences Section . 41 Materials Science and Engineering Section . 43 Mathematics and Statistics Section . 46 Physics Section . 49 Division of Science Education . 52 Higher Education Section . 52 K-12 Education Section . 55 Division of Social Sciences . 57 Acknowledgement . 64 2 The following abstracts of oral and poster presentations represent those received by the Abstract Editor. Authors’ affiliations are abbreviated as follows: ACHRI Arkansas Children’s Hospital Research Institute ARS Agriculture Research Services, Little Rock, AR AVMA-PLIT American Veterinary Medical BGSU Bowling Green State University BNL Brookhaven National Laboratory, Upton, NY BRCC Baton Rouge Community College CC Centenary College CIT California Institute of Technology CL Corrigan Laboratory, Baton Rouge, LA CTF Cora Texas Manufacturing CU Clemson University DNIRI Delta -
Lecture 25: Main Group Chemistry
Lecture 23: Main Group Chemistry An Introduction We have spent the better part of the school year developing physical models to describe atomic structure, chemical bonding and the thermodynamics and kinetics physical and chemical phenomena. In all of that, however, we have been just as content to use generic symbols like A + B Æ C + D or to describe a weak acid as HA, as to actually assign it a real chemical structure with real chemical reactivity. In this chapter we right this wrong, working systematically through the main groups of the periodic table, learning for each group and particularly significant elements in those groups: • The natural forms in which the elements are found, including the hydrides and oxides • The famous chemical reactions that involve the chemical compounds containing those elements • The important practical uses of the compounds containing those elements. Common themes in Main Group Chemistry: We must have learned something useful during the year that will help to explain the chemistry of the main group elements. Here are some important themes that appear to explain pretty much everything that happens 1. The number of valence electrons in atoms drive the chemistry of a compound. And the main group number corresponds to the number of valence electrons 2. Compounds formed by main group elements pretty much always satisfy the octet rule if they can, achieving noble gas- like electronic configurations 3. There are trends in the periodic table that are pretty much determined by the effective nuclear charge and overall number of electrons in an atom. These trends are: a) atomic radius decreases moving to the right and up the periodic table b) ionization energy increases moving to the right and up the periodic table c) electronegativity increases to the right and up the periodic table d) polarizability increases to the right and down the periodic table e) non-metallic character increases to the right and up the periodic table 4. -
Materials Science
Plutonium Futures—The Science Materials Science Materials Science 91 Poster Session 92 P u F u t u r e s — T h e S c i e n c e XANES and EXAFS Studies of Plutonium(III, VI) Sorbed on Thorium Oxide The study of plutonium sorption mechanisms on mineral surfaces seems very R. Drot, interesting considering radwaste management and, in particular, for underground E. Ordonez-Regil, disposal after advanced reprocessing. Indeed, radionuclides retention processes E. Simoni on engineered or geological barriers could enhance retardation. Thus, it appears Institut de Physique important to understand such phenomena at both the macroscopic and molecular Nucléaire, Université Paris Sud, Groupe de levels.1,2 In this context, as plutonium is a very radiotoxic element, it is necessary Radiochimie, to model its behavior in the geosphere and its interaction with natural minerals. 91406 Orsay Cedex, Such an investigation is complicated by the existence of several oxidation states France for plutonium. Then, sorption mechanisms could be different considering Pu(III), Ch. Den Auwer, (IV), or (VI). This work deals with the influence of the oxidation state of pluto- Ph. Moisy nium on the structure of the sorbed complex. X-ray absorption spectroscopy has CEA Marcoule, DCC/ been chosen to perform this study. We have considered thorium oxide as a reten- DRRV/SEMP, Valrhô, tion matrix because, on one hand, it is a sparingly soluble material; thus, dissolu- 30207 Bagnols-sur- tion processes of the solid can be neglected during sorption experiments. On the Cèze, France other hand, only one type of sorption site is expected, which allows us to simplify the study. -
Growth and Characterization of Bn Thin Films Deposited by Pacvd
GROWTH AND CHARACTERIZATION OF BN THIN FILMS DEPOSITED BY PACVD A thesis for the degree of Ph.D. Presented to DUBLIN CITY UNIVERSITY by MD. ZIAUL KARIM, M. Sc.(EEE) SCHOOL OF ELECTRONIC ENGINEERING DUBLIN CITY UNIVERSITY RESEARCH SUPERVISOR DR. DAVID C. CAMERON February, 1993. TO THE DEAREST MEMBERS OF SHAPBNIL LODGE MUM, DAD PIAS, LUCKY, SOHAIL & BIPLAB DECLARATION I hereby certify that this material, which I now submit for the assessment on the programme of study leading to the award of Ph.D. is entirely my own work and has not been taken from the work of others save and to the extent that such work has been cited and acknowledged within the text of my work. Signed: Date: February 2, 1993. ACKNOWLEDGEMENTS I am greatly indebted to Dr. David Cameron for his guidance and tuition in the course of this work. Without his enthusiasm and continual drive to increase our understanding of plasma technology, we would not have acquired such an in-depth knowledge of plasma techniques. To Professor M. S. J. Hashmi, a special word of appreciation and gratitude for his guidance and enthusiasm and for affording me the opportunity to pursue this work. I must also acknowledge the help of my fellow Mend, Michael Murphy for his continuous cooperation throughout the last few years and for helping me in writing this thesis. Without the continued assistance of both Hafizur Rahman and Rowshan Hafiz in preparing this thesis, it would not have been possible to complete it for me in the present time scale just after my glandular fever. -
Melting and Decomposition of Orthorhombic B6si Under High Pressure
Melting and decomposition of orthorhombic B6Si under high pressure Vladimir L. Solozhenko,1,* Vladimir A. Mukhanov 1 and Vadim V. Brazhkin 2 1 LSPM–CNRS, Université Paris Nord, 93430 Villetaneuse, France 2 Institute for High Pressure Physics, Russian Academy of Sciences, 108840 Troitsk, Russia Abstract Melting of oorthorhombicrthorhombic boron silicide B6Si has been studied at pressures up to 8 GPa using in situ electrical resistivity measurements and quenching. It has been found that in the 2.6–7.7 GPa range B6Si melts congruently, and the melting curve exhibits negative slope of -31(2) K/GPa that points to a higher density of the melt as compared to the solid phase. At very high temperatures B6Si melt appears to be unstable and undergoes disproportionation into silicon and boron-rich silicides BnSi (n 12). The onset temperature of disproportionation strongly depends on pressure, and the corresponding low-temperature boundary exhibits negative slope of -92(3) K/GPa which is indicative of significant volume decrease in the course of B6Si melt decomposition. Keywords: boron silicide, melting, decomposition, high pressure, high temperature. 1. Introduction The boron–silicon system – despite of rather long research history – remains not fully understood even at ambient pressure [1]. There are three main groups of B–Si binary compounds usually referred to as "B3Si" (with the stoichiometry ranging from B2.8Si to B4.8Si); B6Si; and boron-rich silicides i.e. BnSi (12 n 50) (for details see [2] and references therein). Boron silicides attract considerable attention due to superior thermal stability, excellent chemical resistance, promising mechanical and electronic properties that offers potential for their use as advanced engineering and smart functional materials. -
Layered Ternary and Quaternary Transition Metal Chalcogenide Based Catalysts for Water Splitting
catalysts Review Layered Ternary and Quaternary Transition Metal Chalcogenide Based Catalysts for Water Splitting Anand P. Tiwari 1,†, Travis G. Novak 1,†, Xiuming Bu 2, Johnny C. Ho 2,* and Seokwoo Jeon 1,* 1 Department of Materials Science and Engineering, KAIST Institute for the Nanocentury, Advanced Battery Center, KAIST, Daejeon 305-701, Korea; [email protected] (A.P.T.); [email protected] (T.G.N.) 2 Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong; [email protected] * Correspondence: [email protected] (J.C.H.); [email protected] (S.J.); Tel.: +82-42-350-3342 (S.J.) † These authors contributed equally. Received: 30 October 2018; Accepted: 13 November 2018; Published: 16 November 2018 Abstract: Water splitting plays an important role in the electrochemical and photoelectrochemical conversion of energy devices. Electrochemical water splitting by the hydrogen evolution reaction (HER) is a straightforward route to producing hydrogen (H2), which requires an efficient electrocatalyst to minimize energy consumption. Recent advances have created a rapid rise in new electrocatalysts, particularly those based on non-precious metals. In this review, we present a comprehensive overview of the recent developments of ternary and quaternary 6d-group transition metal chalcogenides (TMCs) based electrocatalysts for water splitting, especially for HER. Detailed discussion is organized from binary to quaternary TMCs including, surface engineering, heterostructures, chalcogen substitutions and hierarchically structural design in TMCs. Moreover, emphasis is placed on future research scope and important challenges facing these electrocatalysts for further development in their performance towards water splitting. -
New Synthesis Route for Complex Borides
www.nature.com/scientificreports OPEN New Synthesis Route for Complex Borides; Rapid Synthesis of Thermoelectric Yttrium Aluminoboride via Liquid-Phase Assisted Reactive Spark Plasma Sintering Hyoung-Won Son1,2, David Berthebaud3, Kunio Yubuta4, Akira Yoshikawa4, Toetsu Shishido4, Keiko Suzuta5 & Takao Mori1,2 ✉ YxAlyB14 ceramics are of high interest as high temperature thermoelectric materials with excellent p, n control. In this study, direct synthesis of dense polycrystalline YxAlyB14 (x ~0.64, 0.52 ≤ y ≤ 0.67) ceramics was successfully carried out by spark plasma sintering using commercially available precursors. YB4, AlB2 and B powders were reactively sintered with an additive AlF3 at 1773 K for 5–60 min in reduced Ar atmosphere. The sinterability was remarkably enhanced by liquid phase sintering comparing to conventional synthesis techniques. Phase composition analysis by X-ray difraction showed that main peaks belong to YxAlyB14 with the MgAlB14 structure type and no peaks of AlF3 were detected. The thermoelectric behavior was changed from p-type to n-type with increasing Al occupancy. Power factor and ZT values measured in this study were found to be in the same range as the best values previously reported. This original synthesis process is found to be less precursor-consuming as compared to previous synthesis processes, and strikingly, less time-consuming, as the synthesis time, is shortened from 8 h to 5 min for p-type and to 1 h for n-type. The total process time is shortened from ≥3 days to ~4–5 h. This discovery opens the door for more accessible synthesis of complex borides. Termoelectric materials utilize the solid state Seebeck efect and thereby can directly convert heat to electricity. -
Synthesis and Atomic Scale Investigation of Borophene on Au(111)
Synthesis and Atomic Scale Investigation of Borophene on Au(111) A thesis submitted towards partial fulfilment of BS-MS Dual Degree Programme By Navathej P Genesh (BS-MS student, Registration No.: 20121004) Under the guidance of Dr. Aparna Deshpande Department of Physics Indian Institute of Science Education and Research (IISER) Pune, India 1 2 3 Acknowledgements I would like to express my sincere gratitude to Dr. Aparna Deshpande for her valuable suggestions and guidance without which this project would not have come till this point. I also want to thank my lab members who have helped me throughout this year at all the phases of this project. I would like to thank Dr. Sumati Patil for the help in procuring boron powder. I am grateful to Rejaul for all his overnight discussions which made the course of this work easier. I also wanted to thank Thasneem, Imran and Nilesh Sir for their constant support. I am grateful to Nithin Raj PD, Anjana Raj, other friends and my family for their motivation and support. 4 TABLE OF CONTENTS List of Figures and List of Tables 7 List of Abbreviations 9 Abstract 10 INTRODUCTION 1.1 Introduction 11 1.2 Two dimensional materials 11 1.3 Boron 12 1.4 Borophene 13 METHODS 2.1 Scanning Tunneling Microscope (STM) 17 2.2 UHV - LT Scanning Tunneling Microscope: what is UHV and what is 20 LT? 2.3 Rotary pump 21 2.4 Turbo molecular pump 23 2.5 Titanium sublimation pump 24 2.6 Ion pump 25 2.7 Ion gauge 25 2.8 Pirani gauge 26 2.9 Noise reduction 27 2.10 Tip preparation 28 2.11 Sputtering and annealing 29 2.12 Molecular evaporator 29 2.13 Atomic force microscope (AFM) 30 2.14 Energy dispersive X-Ray analysis (EDAX) 31 2.15 Sample preparation 31 RESULTS AND DISCUSSION 3.1 Cleaning bare Au(111) 32 5 3.2 The first trial 36 3.3 Second trial 38 3.4 Third trial 39 3.5 Fourth trial 43 CONCLUSIONS AND OUTLOOK 45 BIBILIOGRAPHY 46 6 LIST OF FIGURES Figure Caption Page No. -
Single-Crystal Calcium Hexaboride Nanowires: Synthesis And
NANO LETTERS 2004 Single-Crystal Calcium Hexaboride Vol. 4, No. 10 Nanowires: Synthesis and 2051-2055 Characterization Terry T. Xu,† Jian-Guo Zheng,‡ Alan W. Nicholls,§ Sasha Stankovich,† Richard D. Piner,† and Rodney S. Ruoff*,† Department of Mechanical Engineering, Northwestern UniVersity, EVanston, Illinois 60208, NUANCE Center, Northwestern UniVersity, EVanston, Illinois 60208, and Research Resource Center, UniVersity of Illinois at Chicago, Chicago, Illinois 60612 Received August 17, 2004 ABSTRACT Catalyst-assisted growth of single-crystal calcium hexaboride (CaB6) nanowires was achieved by pyrolysis of diborane (B2H6) over calcium oxide (CaO) powders at 860−900 °C and ∼155 mTorr in a quartz tube furnace. TEM electron diffraction and Raman spectroscopy indicate that the nanowires are single-crystal CaB6 and have a preferred [001] growth direction. Analysis of TEM/EDX/EELS data proves the nanowires consist of CaB6 cores and thin (1−2 nm) amorphous oxide shell material. The CaB6 nanowires have diameters of ∼15−40 nm, and lengths of ∼1−10 µm. -2 22 Calcium hexaboride (CaB6), one of the divalent alkaline- (CaCO3) and boron carbide (B4C) at 1400 °C and 10 Pa, earth cubic hexaborides, has low density (2.45 g/cm3), high by reduction of calcium oxide (CaO) with B at 1200-1800 3 melting point (2235 °C), high hardness (Knoop: 2600 kg/ °C in vacuum, and by reaction of calcium chloride (CaCl2) 2 mm ), high Young’s modulus (379 GPa), and high chemical with sodium borohydride (NaBH4)at500°C in an autoclave 1,2 23 stability. CaB6 has found application as a high-temperature for8h. The finest crystalline CaB6 powders synthesized material, is used for surface protection, and as a wear resistant so far have an average size of 180 nm.23 1,2 material. -
"Boron Halides"
138 BORON HALIDES Vol. 4 BORON HALIDES 1. Introduction The boron trihalides boron trifluoride [7637-07-2], BF3, boron trichloride [10294- 34-5], BCl3, and boron tribromide [10294-33-4], BBr3, are important industrial chemicals having increased usage as Lewis acid catalysts and in chemical vapor deposition (CVD) processes (see ELECTRONIC MATERIALS). Boron halides are widely used in the laboratory as catalysts and reagents in numerous types of organic reactions and as starting material for many organoboron and inorganic boron compounds. An exhaustive review of the literature on boron halides up to 1984 is available (1–5). Of particular interest are review articles on BCl3 (1), BBr3 (2), and boron triiodide [13517-10-7], BI3 (3). An excellent review on diboron tetrahalides and polyhedral boron halides is available (6). Kirk-Othmer Encyclopedia of Chemical Technology. Copyright John Wiley & Sons, Inc. All rights reserved. Vol. 4 BORON HALIDES 139 2. Physical Properties 2 Boron trihalides, BX3, are trigonal planar molecules which are sp hybridized. The X–B–X angles are 1208. Important physical and thermochemical data are presented in Table 1 (7–13). Additional thermodynamic and spectroscopic data may be found in the literature (1–5). Table 1. Physical Properties of the Boron Trihalides References Property BF3 BCl3 BBr3 BI3 BCl3 BBr3 BI3 BF3 mp, 8C À128.37 À107 À46 À49:977714 bp, 8C À99.9 12.5 91.3 210 7 7 7 14 a : 0 : 18 density , g/mL (liq) 1 4344 2 6434 3.35 8 9 : 11 1 3494 critical temperature, À12.25 Æ 0.03 178.8 300 7 7 14 8C critical pressure,