Decolorization of Acid Blue 25 Dye by Individual and Mixed Bacterial Consortium Isolated from Textile Effluents

Total Page:16

File Type:pdf, Size:1020Kb

Decolorization of Acid Blue 25 Dye by Individual and Mixed Bacterial Consortium Isolated from Textile Effluents Int.J.Curr.Microbiol.App.Sci (2015) 4(5): 1015-1024 ISSN: 2319-7706 Volume 4 Number 5 (2015) pp. 1015-1024 http://www.ijcmas.com Original Research Article Decolorization of Acid Blue 25 dye by individual and mixed bacterial consortium isolated from textile effluents B.Aruna, L.Rathna Silviya, E.Shiva Kumar, P.Roja Rani, Durbaka V.R Prasad and D.VijayaLakshmi* Department of Microbiology, Yogi Vemana University, Kadapa-516003, India *Corresponding author A B S T R A C T The dye decolorizing bacterial isolates Bacillus sp1, Bacillus sp2, Acinetobacter sp., Citrobacter sp. and klebsiella sp. were isolated from the textile effluents. Different parameters such as carbon source, nitrogen source, temperature, pH and K e y w o r d s dye concentrations were optimized for decolorization of acid blue 25 dye by using selected bacterial isolates. The aim of the study was the decolorization of acid blue Anthraquinone 25 dye showed maximum 70% decolorization under optimum conditions. Among dye, Bio- all isolates the klebsiella sp. was found to be most efficient in dye decolorization. decolorization, All the selected isolates showed maximum decolorization in static condition Bacterial compared to shaking condition. The optimum pH obtained for decolorization of isolates, Acid acid blue 25 by bacterial isolates was 7-8 but Citrobacter sp. showed maximum blue dye 25, decolorization at optimum pH of 6-7 at 370C and in Citrobacter sp. it was at 250C. static condition Bacterial consortium i.e. combination of five bacterial isolates showed highest decolourization potential activity when compared to the individual isolates at different parameters. Maximum decolorization potential was observed in the presence of glucose as carbon source and yeast extract as a nitrogen source. Introduction Synthetic dyes have variety of colors and a discharging. Insufficient treatment of high stability to light, temperature and dyestuff wastes of the industries leads to microbial attack. Furthermore, some contamination of soil and natural water synthetic dyes such as Anthraquinone dyes bodies. Physical-chemical treatment are carcinogenic or mutagenic (Spadaro et processes have disadvantages where the al., 1992). (Poonam Dayaram et al., 2008,) contaminant is not destroyed, while reported that the synthetic and reactive dyes biological treatment methods are cheap and showed decolorization of textile effluents of offers the best alternative with proper dye contaminated soil. analysis and control the environmental pollution (Banat et al., 1996). One Synthetic dyes are widely used in the textile promising strategy is the use of microbes industries and their effluents are that possess the ability to decolourize 1015 Int.J.Curr.Microbiol.App.Sci (2015) 4(5): 1015-1024 synthetic dyes. Microbial decolourization isolates (Bacillus sp.1, Acinetobacter sp., and degradation is an environment friendly, Citrobacter sp.). But combination of five cost-competitive and alternative to physico- bacterial isolates showed highest chemical decomposition processes for the decolourization capability when compared treatment of industrial effluents (Verma and to other combinations like four and three Madamwar, 2003). Many bacterial and bacterial isolates. fungal species have the ability to absorb or degrade the textile dyes. Bacterial Materials and Methods decolourization of Anthraquinone dyes is either aerobic or anaerobic (Pandey et al., Sample collection 2007). Nature offers wide microbial community for decolorizing the textile dyes, Waste water along with soil samples anthraquinone dye decolourizing bacteria contaminated with textile effluents and can be isolated from soil and effluent water, dyeing industry were collected from the however their potential ecological niches discharges of Siera Silk Mills from were targeted. Bangalore. The water samples were collected sterilized screw cap bottles and Anthraquinone dyes represent the second soil samples were collected by polythene largest class of textile dyes extensively used bags. in the industries due to their wide array of color shades. They are resistant to Dye degradation due to their fused aromatic structure which remains for long time Acid blue 25 an Anthraquinone based dye causing considerable concern to the supplied by sigma Aldrich chemicals environmental pollution and also dye limited, water soluble and widely used in retention of the soils or effluents. textile industries. Its maximum absorption Bioremediation techniques have gained was 600-630 nm with the following much attention, microbial decolorization and chemical structure. degradation is cost- effective and eco- friendly compared to different conventional Medium methods. Some potential bacteria have the ability to decolorize synthetic / commercial The Bacterial cultures grown at 370C in the dyes used for textile dyeing. Effluents from basal medium viz Zhou and Zimmermann textile and dyeing industries cause serious medium (ZZ) containing the following in pollution to the environment. g/l, Glucose 0.5%,Yeast extract 0.5%, (NH4)2SO4- 0.5g/l, KH2PO4 - 2.66g/l, In the present study, we record to isolate Na2HPO4 - 4.32 g/l, dye - 100 mg/l. potential dye degrading bacteria and the development of bacterial consortium from Isolation and Screening of potential individual isolates. We tried with different strains combinations by mixing of five bacterial isolates (Bacillus sp.1, Bacillus sp.2, For isolation the textile effluents were Acinetobacter sp., Citrobacter sp. and collected as sources of microorganisms Klebsiella sp.) four bacterial isolates Cultures were obtained through serial (Bacillus sp.1, Bacillus sp.2, Acinetobacter dilution by pour plate method. Isolated sp., Citrobacter sp.) and three bacterial colonies were then obtained was preserved 1016 Int.J.Curr.Microbiol.App.Sci (2015) 4(5): 1015-1024 for the further use. Fresh culture was then culture supernatants at 600 nm using UV- inoculated in to nutrient broth and incubated Vis spectrophotometer. Percentage of for 24 hrs at 370C.In order to screen decolourization calculated by the following potential strain 2% 24 hrs fresh inoculums formula: was transferred in to the 100 ml of ZZ medium containing dye and incubated at D = [D0-D1/D0] x 100 370C.Potential strains utilizing dye as a nutrient source which were placed on ZZ Where, D=Decolorization in percentage, agar plates and incubated. From these D0=Initial absorbance, D1=Final absorbance. enriched cultures isolated colonies were repeatedly & subsequently inoculated on Results and Discussion nutrient agar to obtain potential cultures. Therefore strains that showed high Total Fourteen bacterial cultures were decolourization potential were chosen to be isolated, identified and screened for the for decolorization and degradation studies at decolorization degradation of different concentration, pH temperature & Anthraquinone dyes from textile effluent. other nutrient factors etc.. All the strains tested were further selected & screened for dye degradation on Screening and identification of dye morphologically and biochemically degrading bacterial isolates characterized for identification. Based on biochemical test they were identified as The organisms isolated on nutrient agar was Bacillus sp.1, Bacillus sp.2, Acinetobacter further sub cultured on modified ZZ medium sp., Citrobacter sp. and Klebsiella sp. were containing 100mg of acid blue 25 dye and selected for Acid blue 25 dye degradation. incubated at 37oC under static conditions. Dye degradation experiments were tested on After six days of incubation the selective medium i.e. ZZ medium and decolourization potential was calculated. decolorization potential was observed by The bacterial isolates utilizing the dyes as a five bacterial isolates individually and by the source of nutrient, showing high efficiency development of bacterial consortium of decolourization were selected for the (Nachiyar et al .2012 & Maulin p.Shah study. 2014). Bacterial consortium with combinations of five bacterial isolates Decolorization was studied on various (Bacillus sp.1, Bacillus sp.2, Acinetobacter carbon sources such as (Glucose, Fructose, sp., Citrobacter sp. and Klebsiella sp.), four Maltose, Sucrose & Mannitol), Nitrogen bacterial isolates (Bacillus sp.1, Bacillus sources (Yeast extract, Beef extract & sp.2, Acinetobacter sp., and Citrobacter sp.) Peptone), different dye concentration (100- and three bacterial isolates (Bacillus sp.1, 600mg/l) pH values (5, 6, 7,8and 9) and Acinetobacter sp., and Citrobacter sp.) were temperature (250,370,450C).Growth was tested and the percentage was recorded monitored by using spectrophotometrically. (Table 1). Among three combinations the most potential decolourization activity was After decolorization, the decolourized observed. With combination of five bacterial medium was centrifuged at 10000 rpm for isolates (Bacterial consortium) showed high 20 minutes to separate the cell lysate and decolourization percentage and further study supernatant. Decolourization potential was was carried. determined by measuring the absorbance of 1017 Int.J.Curr.Microbiol.App.Sci (2015) 4(5): 1015-1024 Effect of carbon source on dye decolorization in the presence of yeast decolorization extract. In combination of five bacterial isolates showed the decolorization activity Optimization of dye decolorization with five of Acid blue 25 with yeast extract was about bacterial isolates was analysed by the 86%, beef extract 56% and peptone 59% incorporation of Glucose, Sucrose, Fructose, under static conditions. Among all
Recommended publications
  • Batik Workshop
    Batik Workshop Batik is one of the "resist" processes for making designs on fabric, like Tie Dye, Shibori, Serti technique, etc., using wax on fabric to prevent dye from penetrating the cloth. Wax is applied to fabric, followed by dye, perhaps in many successive layers in complex Batiks. Batik is especially unique because the wax will crackle during handling, either intentionally or not. On subsequent dye baths, the crackles in the wax fill in with darker colors. Batik can be done with many types of dye or fabric paints & waxes on cottons, silks and other natural fabrics, particularly the finer weaves for detail work. "Faux" batik employs types of water soluble resists that are easier to remove than wax (and safer to work with for children), but never quite achieve that beautiful crackling. In this example we will be using Dharma Pigment Dyes and Soy Wax, on cotton, but can be adapted to other fabrics or dyes. The basic principles remain the same. Introduction to Batik Batik masters employ a process of repeated waxing and tub dyeing to achieve the final result. This method requires mastery of color mixing and over dyeing, as each layer of dye is applied over the last, producing a mixed color. After many different applications, the background usually comes out dark brown, black, or gray. The waxed areas remain the lighter shades produced by each individual application and combinations thereof. The Tub Dye technique is described below in more detail. An easier method of batik, especially for beginners, is the Paint-on method. This method has fewer steps and allows for great variations of color and shade without having to master the complicated blending of successive layers of color.
    [Show full text]
  • Alum Mineral and the Importance for Textile Dyeing
    Current Trends in Fashion Technology & Textile Engineering ISSN: 2577-2929 Mini-Review Curr Trends Fashion Technol Textile Eng Volume 3- Issue 4 - April 2018 Copyright © All rights are reserved by Ezatollah Mozaffari DOI: 10.19080/CTFTTE.2018.03.555619 Alum Mineral and the Importance for Textile Dyeing Ezatollah Mozaffari* and Bijan Maleki Imam khomeini international university, Qazvin, Iran Submission: Published: April 25, 2018 *Corresponding April author: 10, 2018; Email: Ezatollah Mozaffari, Imam khomeini International University, Qazvin, Iran, Tel: +9828-33901133; Abstract The importance of alum as a natural mordant in textile dyeing is explained. The history of alum mineral processing was reviewed to emphasise on the heritage knowledge inherited by current trends in fashion technology and textile engineering. The review will also demonstrate the conservative environmental preservation nature of alum mineral as mordant. The need for modern evaluation of natural dyes and mordants will be highlighted. Keywords: Alum; Mordant; Industrial heritage Introduction the calcined mass the calcined shale was barrowed to a series Alum was known as one of the most imperative components of stone leaching pits nearby with typical dimensions of 9 x of textile industry before the introduction of chemical dyes in 4.5 x 1.5m. Fresh liquid was added to the leaching tanks and the process repeated for several weeks. The waste solids were alum quarrying and trade in several geographical areas [1]. In the 1850s. Its significance could be explored when studying the literature, interesting notes on alum as a mordant for textile liquor from leaching rose to 1.12, indicating 12 tons of dissolved dyeing of yarn, cloth and leather in North America, China, Libya, eventually dug out and discarded.
    [Show full text]
  • Batik Wax Instructions
    Instructions Batik Wax Batik: A History Although its exact origin is uncertain, the earliest known batiks were discovered in Egyptian tombs dating back to the 4th century BCE. Wax-resist techniques were probably developed independently by disparate cultures throughout the ancient world. By the seventh century AD, patterning fabric using resists such as wax was a widespread practice throughout Asia and Africa and was perhaps most fully developed as an artform in Indonesia, where batik predates written records. By the thirteenth century, it became a highly respected art form and pastime for the women of Java and Bali, as recognizable motifs, patterns and colors became signifiers of one’s family and geographical area. Distinct styles and traditions proliferated and spread with the exchange of cultures through trade and exploration (see the “inland” and “coastal” batiks of Java, for instance — the two traditions couldn’t be more different). In the seventeenth century, as the world grew smaller, batik was introduced in Holland and other parts of Europe, where it became increasingly fashionable. Europeans and Americans traveling and living in the East encountered the ancient process and brought it back to their homelands — and spread it to colonies far away — where new traditions of batik branched out. Today, art schools across the United States and Europe offer batik courses as an essential part of their textile curricula. For more tips and techniques see www.jacquardproducts.com JACQUARD PRODUCTS Manufactured by Rupert, Gibbon & Spider, Inc. Healdsburg, CA 95448 | www.jacquardproducts.com | 800.442.0455 Batik Instructions Preparing and designing your fabric All new fabrics must be washed with hot soapy water, rinsed and dried to remove factory-applied sizings which may inhibit color penetration.
    [Show full text]
  • The Maiwa Guide to NATURAL DYES W H at T H Ey a R E a N D H Ow to U S E T H E M
    the maiwa guide to NATURAL DYES WHAT THEY ARE AND HOW TO USE THEM WA L NUT NATURA L I ND IG O MADDER TARA SYM PL O C OS SUMA C SE Q UO I A MAR IG O L D SA FFL OWER B U CK THORN LIVI N G B L UE MYRO B A L AN K AMA L A L A C I ND IG O HENNA H I MA L AYAN RHU B AR B G A LL NUT WE L D P OME G RANATE L O G WOOD EASTERN B RA ZIL WOOD C UT C H C HAMOM IL E ( SA PP ANWOOD ) A LK ANET ON I ON S KI NS OSA G E C HESTNUT C O C H I NEA L Q UE B RA C HO EU P ATOR I UM $1.00 603216 NATURAL DYES WHAT THEY ARE AND HOW TO USE THEM Artisans have added colour to cloth for thousands of years. It is only recently (the first artificial dye was invented in 1857) that the textile industry has turned to synthetic dyes. Today, many craftspeople are rediscovering the joy of achieving colour through the use of renewable, non-toxic, natural sources. Natural dyes are inviting and satisfying to use. Most are familiar substances that will spark creative ideas and widen your view of the world. Try experimenting. Colour can be coaxed from many different sources. Once the cloth or fibre is prepared for dyeing it will soak up the colour, yielding a range of results from deep jew- el-like tones to dusky heathers and pastels.
    [Show full text]
  • Watercolors, Facepaint, Tie-Dye, and More!
    Playing with Plant Pigments: Watercolors, Facepaint, Tie-Dye, and More! Have you ever cooked with beets to find that your fingertips and cutting board are stained a vibrant red? Or maybe your favorite white coffee mug has a brown tint to the inside? If so, you’ve already experienced a plant pigment! There are some simple but magical techniques you can use to harness the brilliant colors found in plants - including the very ones found in your fridge. These pigments are easy to source, a ton of fun to experiment with, and a great way to use up some less-than-fresh produce. They are also an excellent alternative to harsh chemical dyes. Materials - Richly-pigmented food like: beet skins (pink), avocado peels and pits (pale pink), onion skins (yellow-orange), purple cabbage leaves (purple-blue), spinach (green), black beans (blue, believe it or not!), turmeric (golden yellow) - Saucepan - Strainer or slotted spoon Directions 1. Gather your pigmented ingredients. You’ll want at least one chopped cup of each item to create a deeply-saturated dye. 2. Add the chopped ingredients to a saucepan, and cover with twice as much water as the fruit or vegetable. Place over medium heat, and simmer for one hour. You can have multiple pots simmering at the same time. 3. Keep in mind: if you plan to dye fabric, you’ll want to make sure you have enough dye for the fabric item to float freely while it picks up color. When in doubt, make more dye than you think you need (which means you’ll need to use more fruits and vegetables).
    [Show full text]
  • ANTHRAQUINONE and ANTHRONE SERIES Part IX
    ANTHRAQUINONE AND ANTHRONE SERIES Part IX. Chromatographic Adsorption of Aminoanthraquinones on Alumina BY N. R. RAo, K. H. SHAH AND K. VENKATARAMAN, F.A.Sc. (Department of Chemical Technology. University of Bombay, Bombay) Received November 10, 1951 CORRELATIONS between chemical constitution and chromatograpl~c behaviour can only be attempted in molecales of the same or similar types and under specified conditions of chromatographic treatment, since complex solvent- adsorbent, solute-solvent and solute-adsorbent relationships are involved. Changes in the sequence of adsorption of the constituents in a mixture have been observed, ooth when the adsorbent is changed and when the deve- loping solvent is changed. Thus Strain was able tc separate some ternary mixtures in four of the six pessible sequences by changing the solvent1; and LeRosen found that cryptoxanthin is aloove lycopene on alumina and on calcium carbonate columns, but the order is inverted on a column of calcium hydroxide, using benzene as developer with all the three adsoroents. 2 An inversion of the sequence of adsorption of N-ethyl-N, N'-diphenylurea and 4-nitro-N-ethylaniline was observed by Schroeder when a slight alteration in the composition of the developer (2 or 5~o of ethyl acetate in light petro- leum) was made. 3 LeRosen has defined the adsorption affinity R as the rate of movement of the adsorptive zone (mm./min.) divided by the rate of flow of developing solvent. 2 R values have been used for standardizing adsorbents and for determining the efficiency of developers; using the same adsorbent and solvent, R values provide a quantitative measure of the adsorption affinities of a series of compounds which can then be correlated with their chemical constitution.
    [Show full text]
  • Removal of Acid Blue 25 Dye by Using Dried Water Hyacinth from Aqueous Solution
    REMOVAL OF ACID BLUE 25 DYE BY USING DRIED WATER HYACINTH FROM AQUEOUS SOLUTION A thesis submitted in the the fulfillment of the requirements for the award of the degree of Bachelor of Chemical Engineering Faculty of Chemical Engineering & Natural Resources Universiti Malaysia Pahang iv ABSTRACT Water hyacinth (Eichhornia crassipes) is a free floating aquatic weeds that robustness in its growth used as an adsorbent to remove Acid Blue 25 dye from aqueous solution. The parameters studied include the adsorbent dosage, initial dye concentration, pH, and also contact time in a batch adsorption process at room temperature 21ºC. The results shows the optimum conditions for each parameter studied, adsorbent dosage at 0.60 g, initial concentration 400 mg/L, pH 2 and 100 minutes contact time. The samples after the dye uptake were analyzed by using UV-Vis spectrophotometer. Furthermore, before and after the experiments, FTIR analyses were studied to know the functional groups of the water hyacinth. In addition, the equilibrium data fitted well pseudo-second order kinetics, Langmuir and Freundlich isotherm. The maximum sorption capacities for Langmuir equation were 83.33 mg/g whereas the amount of n for Freundlich is favourable. While for pseudo-second-order kinetics, it has a low error for equilibrium sorption capacity for experimental and calculated values. This study is favourable and economically feasible for the removal of Acid Blue 25. v ABSTRAK Keladi bunting merupakan gulma air yang mengambang yang digunakan sebagai adsorben untuk menyingkirkan pewarna Asid Biru 25 dari akuas larutan. Parameter yang dipelajari meliputi dos adsorben, kepekatan pewarna awal, pH, dan juga masa tindakbalas dalam proses jerapan batch pada suhu bilik 21º C.
    [Show full text]
  • CIBA Acid F.Pdf
    ./ Fiber Types · Safety InUse• Ciba Washfast Acid Dyes may be used on the Although no chemical is entirely freefrom hazard, · following fiber types: these products will pres�nt a low to no health risk, • Wool (includirg Cashmere, Alpaca, Angora, provided that good standards of studio· hygiene are and other protein fi�rs) observed in their use and storage. All persons. • Silk handling them should take precautions to avoid Techniques• Nylon· accidental ingestion, inhalation, skin and eye contact and should be aware of any limitations of use of specific products. While dyes and the • high temperature immersion chemicals associated with their use are not highly • handpainting silkscreening ,. toxic, they are industrtal chemicals and should be • block prtnting handled with care. Chemical productsshould not • airbrushing be allowed to get into the eyes, but 1f they should • warp painting by accident, wash eyes with clean water and then_ • resist (paste resist, gutta, bound) obtain medical treatment. Prolonged or repeated • batch dyeing (tie dyeing, rainbow dyeing) contact with skin should be avoided. Wear rubber gloves and use implements to stir solutions and ColorSeereverse Availablefor further deta ils.· dyebaths. Inhalation of'dusts .should be avoided by careful handling of powders. If the dyes are handled where particles may become airborne, a Yellow, Gold Yellow, Scarlet, Fuchsia, Turquoise, suitable dust respirator should be worn. Navy, Brown, Black, Green, Blue, and Violet. Obviously, chemicals slJ.ould ,not be taken -WhatNote: These Youdyes- Willare Need completely intennixable. internally, and the use of food, drink and smoking materials should be prohibited where chemicals are employed. The utensils used fordyeing should Stainless steel, enamel, plastic or glass measuring.
    [Show full text]
  • Real Time Analysis and Control of Batch Dyeing Processes
    C95S4 Page 1 Project Title: Real Time Analysis And Control of Batch Dyeing Processes Project Number: C95-S4 PI(s): R. McGregor (Leader NCSU), K. R. Beck, G. K. F. Lee, C. B. Smith, W J. Jasper Graduate Students: M. S. Arora, C. E. Bright, R. P. Joshi, M. R. Lefeber Wallace, J. T. Merritt. Industrial Collaborator: W. Hunter (Cotton Inc.). Goals: The overall objective of this project is to optimize batch-dye process control by monitoring dyebaths, and by understanding and controlling the state of the dyeing process, both in the laboratory and commercial dyeing machines. Specific objectives are to: 1. Educate graduate students and advance dyeing knowledge and technology. 2. Develop neural network/fuzzy logic control for dyebath monitoring and colorant formulation. 3. Develop control systems and strategies for closed loop control via dosing, fuzzy logic and neural networks. 4. Comparatively evaluate control strategies and the absolute levels of control possible. 5. Develop useful theoretical kinetic and thermodynamic models and generic process models. Abstract: This report describes our (Dye Applications Research Group, DARG) recent progress in real-time monitoring, modeling, and controlling batch dyeing processes. The flow injection analysis (FIA) system was modified to allow injection of a small volume of dyebath into a high performance liquid chromatograph (HPLC). This FIAIHPLC system is being used to study four different procedures for exhaust dyeing cotton with reactive dyes. Data are reported for isothermal dyeings at different temperatures. Preliminary work to develop a spectrophotometric method for monitoring exhaustion of vat dyes, especially indigo, is reported. Calibration models developed from indigo powder and indigo paste under a nitrogen atmosphere indicate significant differences in the purity of the dye in these two forms.
    [Show full text]
  • United States Patent (19) 11 3,923,453 Lazar Et Al
    United States Patent (19) 11 3,923,453 Lazar et al. (45) Dec. 2, 1975 54 NEW DYE COMPOSITIONS twenty parts by weight of a dye assist consisting of a 75 Inventors: Remus I. Lazar, Berwyn; Richard C. mixture of benzyl alcohol and Reichel, Chicago, both of Ill. 73) Assignee: Welsicol Chemical Corporation, Chicago, Ill. 22 Filed: Dec. 3, 1973 (21) Appl. No.: 420,998 52 U.S. Ci............................ 8/39; 8/42 R; 8/42 B; 8/93; 81173 5 l l Int. Cl......................... D06P 1120; D06P 5/04 (58) Field of Search................... 8/93, 173, 39, 42 R Primary Examiner-Lewis T. Jacobs having a boiling point of about 1 17°C at 9 mm Hg Attorney, Agent, or Firm-Robert J. Schwarz; Dietmar pressure, a refractive index of about 1.5262 at 20°C H. Olesch and an infrared spectrum having strong bands at about 9.4, 10. 1, 12.7 and 14.4 microns, in a weight ratio of (57) ABSTRACT from 4:1 to 1:4. This invention discloses a dye composition comprising one part by weight of an acid dyestuff and from one to 5 Claims, No Drawings 3,923,453 1 2 anthraquinone, exemplified by CI Blue 45 (C.I. No. NEW DYE COMPOSITIONS 63010); azine, exemplified by CI Acid Blue 59 (C.I. This invention relates to dye compositions which are No. 50315); and quinoline, exemplified by CI Acid useful in the dyeing of natural proteinaceous and syn Yellow 3 (C.I. No. 47005). thetic polyamide fibers. r The mordant acid dyes similarly fall into several The art of dyeing is a complex procedure requiring a chemical types, such as anthraquinone, exemplified by variety of techniques and chemicals: The dyeing of nat CI Mordant Red 3 (C.I.
    [Show full text]
  • Adsorption of Food Dyes Onto Chitosan: Optimization Process and Kinetic
    Carbohydrate Polymers 84 (2011) 231–238 Contents lists available at ScienceDirect Carbohydrate Polymers journal homepage: www.elsevier.com/locate/carbpol Adsorption of food dyes onto chitosan: Optimization process and kinetic G.L. Dotto, L.A.A. Pinto ∗ Unit Operation Laboratory, School of Chemistry and Food, Federal University of Rio Grande – FURG, Rio Grande, RS, Brazil article info abstract Article history: Adsorption of food dyes acid blue 9 and food yellow 3 onto chitosan was optimized. Chitosan was obtained Received 5 October 2010 from shrimp wastes and characterized. A full factorial design was used to analyze the effects of pH, stirring Received in revised form rate and contact time in adsorption capacity. In the optimal conditions, adsorption kinetics was studied 10 November 2010 and the experimental data were fitted with three kinetic models. The produced chitosan showed good Accepted 11 November 2010 characteristics for dye adsorption. The optimal conditions were: pH 3, 150 rpm and 60 min for acid blue 9 Available online 19 November 2010 and pH 3, 50 rpm and 60 min for food yellow 3. In these conditions, the adsorption capacities values were 210 mg g−1 and 295 mg g−1 for acid blue 9 and food yellow 3, respectively. The Elovich kinetic model was Keywords: Acid blue 9 the best fit for experimental data and it showed the chemical nature of dyes adsorption onto chitosan. Adsorption capacity © 2010 Elsevier Ltd. All rights reserved. Elovich model Food dye Food yellow 3 1. Introduction mainly aromatic structures, which are biologically non-degradable (Srinivasan & Viraraghavan, 2010). Adsorption is found a good way Chitosan, a de-N-acetylated analog of chitin, is a heteropolysac- to treat industrial waste effluents, it has significant advantages in charide consisting of linear b-1,4-linked GlcN and GlcNAc units comparison with conventional methods, especially from econom- (Harish Prashanth & Tharanathan, 2007).
    [Show full text]
  • Opinion on the SCCNFP on Disperse Violet 1 Impurified with Disperse Red
    SCCNFP/0504/01, final OPINION OF THE SCIENTIFIC COMMITTEE ON COSMETIC PRODUCTS AND NON-FOOD PRODUCTS INTENDED FOR CONSUMERS CONCERNING DISPERSE VIOLET 1 IMPURIFIED WITH DISPERSE RED 15 Colipa n° C64 & C61 adopted by the SCCNFP during the 19th Plenary meeting of 27 February 2002 SCCNFP/0504/01, final Evaluation and opinion on : Disperse Violet 1 impurified with Disperse Red 15 ____________________________________________________________________________________________ 1. Terms of Reference 1.1 Context of the question The adaptation to technical progress of the Annexes to Council Directive 76/768/EEC of 27 July 1976 on the approximation of the laws of the Member States relating to cosmetic products. 1.2 Request to the SCCNFP The SCCNFP is requested to answer the following questions : * Is Disperse Violet 1 impurified with Disperse Red 15 safe for use in cosmetic products? * Does the SCCNFP propose any restrictions or conditions for its use in cosmetic products? 1.3 Statement on the toxicological evaluation The SCCNFP is the scientific advisory body to the European Commission in matters of consumer protection with respect to cosmetics and non-food products intended for consumers. The Commission’s general policy regarding research on animals supports the development of alternative methods to replace or to reduce animal testing when possible. In this context, the SCCNFP has a specific working group on alternatives to animal testing which, in co-operation with other Commission services such as ECVAM (European Centre for Validation of Alternative Methods), evaluates these methods. The extent to which these validated methods are applicable to cosmetic products and its ingredients is a matter of the SCCNFP.
    [Show full text]