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Physical Properties of Martian Meteorites: Porosity and Density Measurements
Meteoritics & Planetary Science 42, Nr 12, 2043–2054 (2007) Abstract available online at http://meteoritics.org Physical properties of Martian meteorites: Porosity and density measurements Ian M. COULSON1, 2*, Martin BEECH3, and Wenshuang NIE3 1Solid Earth Studies Laboratory (SESL), Department of Geology, University of Regina, Regina, Saskatchewan S4S 0A2, Canada 2Institut für Geowissenschaften, Universität Tübingen, 72074 Tübingen, Germany 3Campion College, University of Regina, Regina, Saskatchewan S4S 0A2, Canada *Corresponding author. E-mail: [email protected] (Received 11 September 2006; revision accepted 06 June 2007) Abstract–Martian meteorites are fragments of the Martian crust. These samples represent igneous rocks, much like basalt. As such, many laboratory techniques designed for the study of Earth materials have been applied to these meteorites. Despite numerous studies of Martian meteorites, little data exists on their basic structural characteristics, such as porosity or density, information that is important in interpreting their origin, shock modification, and cosmic ray exposure history. Analysis of these meteorites provides both insight into the various lithologies present as well as the impact history of the planet’s surface. We present new data relating to the physical characteristics of twelve Martian meteorites. Porosity was determined via a combination of scanning electron microscope (SEM) imagery/image analysis and helium pycnometry, coupled with a modified Archimedean method for bulk density measurements. Our results show a range in porosity and density values and that porosity tends to increase toward the edge of the sample. Preliminary interpretation of the data demonstrates good agreement between porosity measured at 100× and 300× magnification for the shergottite group, while others exhibit more variability. -
A Multielement Isotopic Study of Refractory FUN and F Cais: 2 Mass-Dependent and Mass-Independent Isotope Effects 3 Levke Kööp1,2,3,*, Daisuke Nakashima4,5, Philipp R
1 A multielement isotopic study of refractory FUN and F CAIs: 2 Mass-dependent and mass-independent isotope effects 3 Levke Kööp1,2,3,*, Daisuke Nakashima4,5, Philipp R. Heck1,2,3, Noriko T. Kita4, Travis J. Ten- 4 ner4,6, Alexander N. Krot7, Kazuhide Nagashima7, Changkun Park7,8, Andrew M. Davis1,2,3,9 5 1Department of the Geophysical Sciences, The University of Chicago, Chicago, IL 60637, 6 USA ([email protected]) 7 2Chicago Center for Cosmochemistry, The University of Chicago, Chicago, IL 60637, USA 8 3Robert A. Pritzker Center for Meteoritics and Polar Studies, Field Museum of Natural His- 9 tory, Chicago, IL, USA 10 4Department of Geoscience, University of Wisconsin, Madison, WI 53706, USA 11 5Division of Earth and Planetary Material Sciences, Faculty of Science, Tohoku University, 12 Aoba, Sendai, Miyagi 980-8578 Japan 13 6 Chemistry Division, Nuclear and Radiochemistry, Los Alamos National Laboratory, 14 MSJ514, Los Alamos, NM 87545, USA 15 7Hawai‘i Institute of Geophysics and Planetology, School of Ocean and Earth Science and 16 Technology, University of Hawai‘i at M!noa, Honolulu, HI 17 8Korea Polar Research Institute, Incheon 21990, Korea 18 9Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637, USA. 19 20 *E-mail address of the corresponding author: [email protected] 21 ABSTRACT 22 Calcium-aluminum-rich inclusions (CAIs) are the oldest dated objects that formed inside the 23 Solar System. Among these are rare, enigmatic objects with large mass-dependent fractionation 24 effects (F CAIs), which sometimes also have large nucleosynthetic anomalies and a low initial 25 abundance of the short-lived radionuclide 26Al (FUN CAIs). -
Addibischoffite, Ca2al6al6o20, a New Calcium Aluminate Mineral from The
1 Revision 3 2 Addibischoffite, Ca2Al6Al6O20, a new calcium aluminate mineral from 3 the Acfer 214 CH carbonaceous chondrite: A new refractory phase from 4 the solar nebula 5 Chi Ma1,*, Alexander N. Krot2, Kazuhide Nagashima2 6 1Division of Geological and Planetary Sciences, California Institute of Technology, 7 Pasadena, California 91125, USA 8 2Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa, 9 Honolulu, Hawai‘i 96822, USA 10 11 ABSTRACT 12 Addibischoffite (IMA 2015-006), Ca2Al6Al6O20, is a new calcium aluminate mineral 13 that occurs with hibonite, perovskite, kushiroite, Ti-kushiroite, spinel, melilite, 14 anorthite and FeNi-metal in the core of a Ca-Al-rich inclusion (CAI) in the Acfer 15 214 CH3 carbonaceous chondrite. The mean chemical composition of type 16 addibischoffite by electron probe microanalysis is (wt%) Al2O3 44.63, CaO 15.36, 17 SiO2 14.62, V2O3 10.64, MgO 9.13, Ti2O3 4.70, FeO 0.46, total 99.55, giving rise to 18 an empirical formula of 3+ 3+ 2+ 19 (Ca2.00)(Al2.55Mg1.73V 1.08Ti 0.50Ca0.09Fe 0.05)Σ6.01(Al4.14Si1.86)O20. The general 20 formula is Ca2(Al,Mg,V,Ti)6(Al,Si)6O20. The end-member formula is Ca2Al6Al6O20. 21 Addibischoffite has the P1 aenigmatite structure with a = 10.367 Å, b = 10.756 Å, c 22 = 8.895 Å, α = 106.0°, β = 96.0°, γ = 124.7°, V = 739.7 Å3, and Z = 2, as revealed by 23 electron back-scatter diffraction. The calculated density using the measured 24 composition is 3.41 g/cm3. -
Constraints on the Water, Chlorine, and Fluorine Content of the Martian Mantle
Meteoritics & Planetary Science 1–13 (2016) doi: 10.1111/maps.12624 Constraints on the water, chlorine, and fluorine content of the Martian mantle 1* 2,3 4 Justin FILIBERTO , Juliane GROSS , and Francis M. MCCubbin 1Department of Geology, Southern Illinois University, 1259 Lincoln Dr, MC 4324, Carbondale, Illinois 62901, USA 2Department of Earth and Planetary Sciences, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, USA 3Department of Earth and Planetary Sciences, The American Museum of Natural History, New York, New York 10024, USA 4NASA Johnson Space Center, Mail Code XI2, 2101 NASA Parkway, Houston, Texas 77058, USA *Corresponding author. E-mail: fi[email protected] (Received 30 July 2015; revision accepted 22 January 2016) Abstract–Previous estimates of the volatile contents of Martian basalts, and hence their source regions, ranged from nearly volatile-free through estimates similar to those found in terrestrial subduction zones. Here, we use the bulk chemistry of Martian meteorites, along with Martian apatite and amphibole chemistry, to constrain the volatile contents of the Martian interior. Our estimates show that the volatile content of the source region for the Martian meteorites is similar to the terrestrial Mid-Ocean-Ridge Mantle source. Chlorine is enriched compared with the depleted terrestrial mantle but is similar to the terrestrial enriched source region; fluorine is similar to the terrestrial primitive mantle; and water is consistent with the terrestrial mantle. Our results show that Martian magmas were not volatile saturated; had water/chlorine and water/fluorine ratios ~0.4–18; and are most similar, in terms of volatiles, to terrestrial MORBs. Presumably, there are variations in volatile content in the Martian interior as suggested by apatite compositions, but more bulk chemical data, especially for fluorine and water, are required to investigate these variations. -
A Magnetic Susceptibility Database for Stony Meteorites
Direttore Enzo Boschi Comitato di Redazione Cesidio Bianchi Tecnologia Geofisica Rodolfo Console Sismologia Giorgiana De Franceschi Relazioni Sole-Terra Leonardo Sagnotti Geomagnetismo Giancarlo Scalera Geodinamica Ufficio Editoriale Francesca Di Stefano Istituto Nazionale di Geofisica e Vulcanologia Via di Vigna Murata, 605 00143 Roma Tel. (06) 51860468 Telefax: (06) 51860507 e-mail: [email protected] A MAGNETIC SUSCEPTIBILITY DATABASE FOR STONY METEORITES Pierre Rochette1, Leonardo Sagnotti1, Guy Consolmagno2, Luigi Folco3, Adriana Maras4, Flora Panzarino4, Lauri Pesonen5, Romano Serra6 and Mauri Terho5 1Istituto Nazionale di Geofisica e Vulcanologia, Roma, Italy [[email protected]] 2Specola Vaticana, Castel Gandolfo, Italy 3Antarctic [PNRA] Museum of Siena, Siena, Italy 4Università La Sapienza, Roma, Italy 5University of Helsinki, Finland 6“Giorgio Abetti” Museum of San Giovanni in Persiceto, Italy Pierre Rochette et alii: A Magnetic Susceptibility Database for Stony Meteorites 1. Introduction the Museo Nationale dell’Antartide in Siena [Folco and Rastelli, 2000], the University of More than 22,000 different meteorites Roma “la Sapienza” [Cavaretta Maras, 1975], have been catalogued in collections around the the “Giorgio Abetti” Museum in San Giovanni world (as of 1999) of which 95% are stony types Persiceto [Levi-Donati, 1996] and the private [Grady, 2000]. About a thousand new meteorites collection of Matteo Chinelatto. In particular, are added every year, primarily from Antarctic the Antarctic Museum in Siena is the curatorial and hot-desert areas. Thus there is a need for centre for the Antarctic meteorite collection rapid systematic and non-destructive means to (mostly from Frontier Mountain) recovered by characterise this unique sampling of the solar the Italian Programma Nazionale di Ricerche in system materials. -
Petrography and Mineral Chemistry of the Anhydrous Component of the Tagish Lake Carbonaceous Chondrite
Meteoritics & Planetary Science 38, Nr 5, 813–825 (2003) Abstract available online at http://meteoritics.org Petrography and mineral chemistry of the anhydrous component of the Tagish Lake carbonaceous chondrite S. B. SIMON1* and L. GROSSMAN1, 2 1Department of the Geophysical Sciences, 5734 South Ellis Avenue, The University of Chicago, Chicago, Illinois 60637, USA 2The Enrico Fermi Institute, 5640 South Ellis Avenue, The University of Chicago, Chicago, Illinois 60637, USA *Corresponding author. E-mail: [email protected] (Received 30 August 2002; revision accepted 16 January 2003) Abstract–Most studies of Tagish Lake have considered features that were either strongly affected by or formed during the extensive hydrous alteration experienced by this meteorite. This has led to some ambiguity as to whether Tagish Lake should be classified a CI, a CM, or something else. Unlike previous workers, we have focused upon the primary, anhydrous component of Tagish Lake, recovered through freeze-thaw disaggregation and density separation and located by thin section mapping. We found many features in common with CMs that are not observed in CIs. In addition to the presence of chondrules and refractory forsterite (which distinguish Tagish Lake from the CIs), we found hibonite-bearing refractory inclusions, spinel-rich inclusions, forsterite aggregates, Cr-, Al-rich spinel, and accretionary mantles on many clasts, which clearly establishes a strong link between Tagish Lake and the CM chondrites. The compositions of isolated olivine crystals in Tagish Lake are also like those found in CMs. We conclude that the anhydrous inclusion population of Tagish Lake was, originally, very much like that of the known CM chondrites and that the inclusions in Tagish Lake are heavily altered, more so than even those in Mighei, which are more heavily altered than those in Murchison. -
CHAPTER 1 Introduction
Chemical analysis of organic molecules in carbonaceous meteorites Torrao Pinto Martins, Zita Carla Citation Torrao Pinto Martins, Z. C. (2007, January 24). Chemical analysis of organic molecules in carbonaceous meteorites. Retrieved from https://hdl.handle.net/1887/9450 Version: Corrected Publisher’s Version Licence agreement concerning inclusion of doctoral License: thesis in the Institutional Repository of the University of Leiden Downloaded from: https://hdl.handle.net/1887/9450 Note: To cite this publication please use the final published version (if applicable). ______________________________________________________ CHAPTER 1 ______________________________________________________ Introduction 1.1 Heavenly stones-from myth to science Ancient chronicles, from the Egyptian, Chinese, Greek, Roman and Sumerian civilizations documented the fall1 of meteorites, with Sumerian texts from around the end of the third millennium B. C. describing possibly one of the earliest words for meteoritic iron (Fig. 1.1 Left). Egyptian hieroglyphs meaning “heavenly iron” (Fig. 1.1 Right) found in pyramids together with the use of meteoritic iron in jewellery and artefacts show the importance of meteorites in early Egypt. Meteorites were worshiped by ancient Greeks and Romans, who struck coins to celebrate their fall, with the cult to worship meteorites prevailing for many centuries. For example, some American Indian tribes paid tribute to large iron meteorites, and even in modern days the Black Stone of the Ka´bah in Mecca is worshiped and regarded by Muslims as “an object from heaven”. The oldest preserved meteorite that was observed to fall (19th May 861) was found recently (October 1979) in a Shinto temple in Nogata, Japan. It weighted 472 g and it was stored in a wooden box. -
Fine-Grained Antarctic Micrometeorites and Weathered Carbonaceous Chondrites As Possible Analogues of Ceres Surface: Implications on Its Evolution
EPSC Abstracts Vol. 12, EPSC2018-1024, 2018 European Planetary Science Congress 2018 EEuropeaPn PlanetarSy Science CCongress c Author(s) 2018 Fine-grained Antarctic micrometeorites and weathered carbonaceous chondrites as possible analogues of Ceres surface: implications on its evolution. Jacopo Nava (1), Cristian Carli (2), Ernesto Palomba (2), Alessandro Maturilli (3) and Matteo Massironi (1) (1) Università degli studi di Padova – Dipartimento di Geoscienze, Padova, Italy ([email protected]) (2) IAPS-INAF, Istituto Nazionale di Astrofisica e Planetologia Spaziali, Roma, Italy (3) Institute of Planetary Research, German Aerospace Center (DLR), Berlin, Germany. Abstract more weathered and are mainly made of jarosite plus Fe-carbonates and Fe-K sulfides. All of these IR spectra of several micrometeorites (MMs) and samples show the constant presence of carbon Antarctic weathered carbonaceous chondrites compound, which can be poorly graphitized C. (AWCCs) have been acquired and compared to Ceres Phyllosilicates are rare. For what concerns the spectra. We propose these samples as possible AWCCs we found the CM2 sample GRA 98005 with analogues of Ceres. This allowed us to define a more weathering grade Ce that had one side exposed to the precise composition of Ceres and to suggest a Antarctic environment, and is thus heavily altered, possible evolution of this body. and one side that has been preserved with a pristine composition. Spectra on the pristine side are flat and almost featureless. On the contrary spectra of the 1. Introduction weathered side tend to have a shape close to the average Ceres spectra. This meteorite, on the Ceres is an icy body with a surface composition close weathered side, is dominated by Fe-oxides, Ca-Fe to the carbonaceous chondrites (CCs) [1] that carbonates, anidrite and gypsum plus enstatite and suffered aqueous alteration [2] and geothermal forsterite. -
Aqueous Alteration in Martian Meteorites: Comparing Mineral Relations in Igneous-Rock Weathering of Martian Meteorites and in the Sedimentary Cycle of Mars
AQUEOUS ALTERATION IN MARTIAN METEORITES: COMPARING MINERAL RELATIONS IN IGNEOUS-ROCK WEATHERING OF MARTIAN METEORITES AND IN THE SEDIMENTARY CYCLE OF MARS MICHAEL A. VELBEL Department of Geological Sciences, 206 Natural Science Building, Michigan State University, East Lansing, Michigan 48824-1115 USA e-mail: [email protected] ABSTRACT: Many of the minerals observed or inferred to occur in the sediments and sedimentary rocks of Mars, from a variety of Mars-mission spacecraft data, also occur in Martian meteorites. Even Martian meteorites recovered after some exposure to terrestrial weathering can preserve preterrestrial evaporite minerals and useful information about aqueous alteration on Mars, but the textures and textural contexts of such minerals must be examined carefully to distinguish preterrestrial evaporite minerals from occurrences of similar minerals redistributed or formed by terrestrial processes. Textural analysis using terrestrial microscopy provides strong and compelling evidence for preterrestrial aqueous alteration products in a numberof Martian meteorites. Occurrences of corroded primary rock-forming minerals and alteration products in meteorites from Mars cover a range of ages of mineral–water interaction, from ca. 3.9 Ga (approximately mid-Noachian), through one or more episodes after ca. 1.3 Ga (approximately mid–late Amazonian), through the last half billion years (late Amazonian alteration in young shergottites), to quite recent. These occurrences record broadly similar aqueous corrosion processes and formation of soluble weathering products over a broad range of times in the paleoenvironmental history of the surface of Mars. Many of the same minerals (smectite-group clay minerals, Ca-sulfates, Mg-sulfates, and the K-Fe–sulfate jarosite) have been identified both in the Martian meteorites and from remote sensing of the Martian surface. -
Finegrained Precursors Dominate the Micrometeorite Flux
Meteoritics & Planetary Science 47, Nr 4, 550–564 (2012) doi: 10.1111/j.1945-5100.2011.01292.x Fine-grained precursors dominate the micrometeorite flux Susan TAYLOR1*, Graciela MATRAJT2, and Yunbin GUAN3 1Cold Regions Research and Engineering Laboratory, 72 Lyme Road, Hanover, New Hampshire 03755–1290, USA 2University of Washington, Seattle, Washington 98105, USA 3Geological & Planetary Sciences MC 170-25, Caltech, Pasadena, California 91125, USA *Corresponding author. E-mail: [email protected] (Received 15 May 2011; revision accepted 22 September 2011) Abstract–We optically classified 5682 micrometeorites (MMs) from the 2000 South Pole collection into textural classes, imaged 2458 of these MMs with a scanning electron microscope, and made 200 elemental and eight isotopic measurements on those with unusual textures or relict phases. As textures provide information on both degree of heating and composition of MMs, we developed textural sequences that illustrate how fine-grained, coarse-grained, and single mineral MMs change with increased heating. We used this information to determine the percentage of matrix dominated to mineral dominated precursor materials (precursors) that produced the MMs. We find that at least 75% of the MMs in the collection derived from fine-grained precursors with compositions similar to CI and CM meteorites and consistent with dynamical models that indicate 85% of the mass influx of small particles to Earth comes from Jupiter family comets. A lower limit for ordinary chondrites is estimated at 2–8% based on MMs that contain Na-bearing plagioclase relicts. Less than 1% of the MMs have achondritic compositions, CAI components, or recognizable chondrules. Single mineral MMs often have magnetite zones around their peripheries. -
Grossite and Hibonite Bearing Refractory Inclusions in the CO3.1 Chondrite Miller Range 090019. D. K. Ross1 and J. I. Simon2, 1U
49th Lunar and Planetary Science Conference 2018 (LPI Contrib. No. 2083) 2559.pdf Grossite and Hibonite Bearing Refractory Inclusions in the CO3.1 Chondrite Miller Range 090019. D. K. Ross1 and J. I. Simon2, 1University of Texas El Paso/Jacobs Technology/NASA-JSC-ARES (2224 Bay Area Blvd. Houston TX 77058, USA ([email protected]), 2NASA-Johnson Space Center-ARES ([email protected]). Introduction: We have characterized 142 refract- finer grained particles with substantial porosity. Ongo- ory objects by EDS hyperspectral X-ray mapping in the ing reaction with nebular gases produces down-temper- CO3.1 chondrite MIL 090019-13. These include 127 ature phases partially replacing earlier formed phases Ca-Al rich inclusions (CAIs), 14 amoeboidal olivine ag- and infilling porosity, leading to densified objects. gregates (AOAs) and one Al-rich chondrule. These data Most CAIs are not fully equilibrated, but exhibit miner- are being used to reveal the mineralogy, texture and alogy reflecting a considerable range of temperature, bulk composition of these inclusions, and to identify ob- with relict phases. Hibonite is typically intergrown with, jects that represent endmembers within cogenetic popu- and partially replaced by spinel, violating the predicted lations of primitive inclusions, which will be further in- crystallization order from thermodynamic calcula- vestigated by future isotopic studies. Previous work re- tions[3], in which melilite should precede spinel crystal- lated to these refractory inclusions in this chondrite also lization. appear in [1] and [2]. Twenty six inclusions are hibonite-bearing, 18 are grossite-bearing and one inclusion is corundum-rich. In seven of these inclusions, grossite and hibonite coexist. -
The Nakhlite Meteorites: Augite-Rich Igneous Rocks from Mars ARTICLE
ARTICLE IN PRESS Chemie der Erde 65 (2005) 203–270 www.elsevier.de/chemer INVITED REVIEW The nakhlite meteorites: Augite-rich igneous rocks from Mars Allan H. Treiman Lunar and Planetary Institute, 3600 Bay Area Boulevard, Houston, TX 77058-1113, USA Received 22 October 2004; accepted 18 January 2005 Abstract The seven nakhlite meteorites are augite-rich igneous rocks that formed in flows or shallow intrusions of basaltic magma on Mars. They consist of euhedral to subhedral crystals of augite and olivine (to 1 cm long) in fine-grained mesostases. The augite crystals have homogeneous cores of Mg0 ¼ 63% and rims that are normally zoned to iron enrichment. The core–rim zoning is cut by iron-enriched zones along fractures and is replaced locally by ferroan low-Ca pyroxene. The core compositions of the olivines vary inversely with the steepness of their rim zoning – sharp rim zoning goes with the most magnesian cores (Mg0 ¼ 42%), homogeneous olivines are the most ferroan. The olivine and augite crystals contain multiphase inclusions representing trapped magma. Among the olivine and augite crystals is mesostasis, composed principally of plagioclase and/or glass, with euhedra of titanomagnetite and many minor minerals. Olivine and mesostasis glass are partially replaced by veinlets and patches of iddingsite, a mixture of smectite clays, iron oxy-hydroxides and carbonate minerals. In the mesostasis are rare patches of a salt alteration assemblage: halite, siderite, and anhydrite/ gypsum. The nakhlites are little shocked, but have been affected chemically and biologically by their residence on Earth. Differences among the chemical compositions of the nakhlites can be ascribed mostly to different proportions of augite, olivine, and mesostasis.