1 A multielement isotopic study of refractory FUN and F CAIs: 2 Mass-dependent and mass-independent isotope effects 3 Levke Kööp1,2,3,*, Daisuke Nakashima4,5, Philipp R. Heck1,2,3, Noriko T. Kita4, Travis J. Ten- 4 ner4,6, Alexander N. Krot7, Kazuhide Nagashima7, Changkun Park7,8, Andrew M. Davis1,2,3,9 5 1Department of the Geophysical Sciences, The University of Chicago, Chicago, IL 60637, 6 USA (
[email protected]) 7 2Chicago Center for Cosmochemistry, The University of Chicago, Chicago, IL 60637, USA 8 3Robert A. Pritzker Center for Meteoritics and Polar Studies, Field Museum of Natural His- 9 tory, Chicago, IL, USA 10 4Department of Geoscience, University of Wisconsin, Madison, WI 53706, USA 11 5Division of Earth and Planetary Material Sciences, Faculty of Science, Tohoku University, 12 Aoba, Sendai, Miyagi 980-8578 Japan 13 6 Chemistry Division, Nuclear and Radiochemistry, Los Alamos National Laboratory, 14 MSJ514, Los Alamos, NM 87545, USA 15 7Hawai‘i Institute of Geophysics and Planetology, School of Ocean and Earth Science and 16 Technology, University of Hawai‘i at M!noa, Honolulu, HI 17 8Korea Polar Research Institute, Incheon 21990, Korea 18 9Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637, USA. 19 20 *E-mail address of the corresponding author:
[email protected] 21 ABSTRACT 22 Calcium-aluminum-rich inclusions (CAIs) are the oldest dated objects that formed inside the 23 Solar System. Among these are rare, enigmatic objects with large mass-dependent fractionation 24 effects (F CAIs), which sometimes also have large nucleosynthetic anomalies and a low initial 25 abundance of the short-lived radionuclide 26Al (FUN CAIs).