For Oilfield Drilling Fluids “A Bright Future”

Total Page:16

File Type:pdf, Size:1020Kb

For Oilfield Drilling Fluids “A Bright Future” A COMPANY Hectorite – For Oilfield Drilling Fluids “A Bright Future” 1 Hectorite vs Bentonite . Smectite/Montmorillonite Family of Clays . Hectorite • Trioctahedral hydrous magnesium silicate with some lithium substitution for magnesium. • Commonly used in specialty applications such as cosmetics, coatings, and in drilling fluids. Bentonite • Dioctahedral hydrous aluminum silicate. • Commonly used in drilling fluids, foundry, iron ore pelletizing, cat litter, and specialty applications. 2 Hectorite Deposit Western Lithium USA Corporation . Large Hectorite deposit in Humboldt County, Nevada about 45 miles north of Winnemuca, Nevada . Suitable for extraction of lithium for manufacturing lithium-ion batteries. Frequent occurrences of near surface high purity hectorite (88% - 92%) Kings Valley Lithium Project 3 Drilling Fluids – Function Functions: . Transporting drilling cuttings to the surface where they can be mechanically removed from the fluid before it is reconditioned and re-circulated downhole. Supports and stabilizes the well bore until casing can be set and cemented. Cools the drill string and bit. Balances and overcomes formation pressures in the well bore to maintain control of the well and maintain favorable drilling conditions. 4 Drilling Fluids Function of Hectorite & Bentonite Clay Minerals in Drilling Fluids (water-based and oil-based) . Rheological Additives, Rheolology Modifiers • Viscosifier • Suspending Agent • Gelling Agent • Emulsion stability (oil-based drilling fluids) . Bentonite based additives are the predominate clay mineral used in drilling fluids . Bentonite based additives are lower cost . Currently available Hectorite based additives are expensive due to low purity and high cost of wet purification process 5 Drilling Fluids Types Water-Based Drilling Fluids Oil-Based Drilling Fluids . Fresh water, salt water . Diesel oil, mineral oils . Shallow well drilling . Deep well drilling . Low temperature environments . Horizontal directional drilling through . Stable formations shale formations . High temperature drilling conditions . Drill hole stability Hectorite clay has emerged as the enabling mineral with thermal stability Synthetic-Based Drilling Fluids superior to bentonite clays to perform in . Environmentally sensitive drilling challenging environments known as high environments pressure and high temperature (HPHT) . Improved rheology control to increase drilling efficiency often referred to as “Rate of Penetration” or ROP . Low Equivalent Circulation Density (ECD) 6 Drilling Fluids – Typical Composition Oil-Based Drilling Fluids . Base oil (diesel, mineral, synthetic) . Primary emulsifier . Brine water (30% calcium chloride) . Rheological additive, such as organophilic Hectorite, bentonite, attapulgite, sepiolite . HPHT fluid loss additive, organophilic lignite, asphalt bitumen . Secondary emulsifier or wetting agent . Weighting agent such as barite, hematite Water-Based Drilling Fluids . Water . Rheological additive, bentonite, Hectorite, attapulgite, sepiolite . Viscosity control (viscosity thinning agents), lignite products . Fluid loss control additive, cellulose and starch derivatives . Weighting agent barite, hematite, calcium carbonate 7 Organophilic Clays Bentonite and Hectorite clays have cationic charges on the clay particle surface that can be reacted with various quaternary ammonium chloride compounds to yield an organophilic bentonite or organophilic Hectorite. Wet-process versus dry-process . Currently available Hectorite products are manufactured using a cost intensive “wet process” to remove impurities. Material recovery rates are less than 50%. Hectatone uses a dry process that incorporates 90% purity clays, innovative engineering and chemistry to manufacture cost effective products with unique and superior performance characteristics. 8 Hectorite – Comparative Processing Dry Process Costs: Wet Process Costs: Mining Mining Reactor $ Wet Purification $ Drying/Milling Hydrocycloning $ Packaging Centrifuging $ Reactor $ Drying/Milling Packaging Other Products ProProducts 9 Hectorite “A New Source, a New Opportunity, a Bright Future” . Low cost of mining . High purity . Low manufacturing cost . Innovative product development to engineer and chemically modify new Hectorite products that offer superior performance attributes • RHEOFLAT™ and GELFAST™ performance . Heat stability 10 Hectatone – Organophilic Hectorite . A price competitive alternative to current organophilic Hectorite products. Stable performance in hot environments found in deep well drilling. Unique performance attributes that have attracted the interest of oilfield service companies. RHEOFLAT ™ Technology minimizes viscosity variation over a wider range of temperatures; a flatter viscosity profile with lower viscosity without compromising gel strength. GELFAST™ Technology provides significantly faster development of rheological properties compared to other organophilic clay products. 11 RHEOFLAT™ Technology RHEOFLAT ™ Technology . Flatter rheology profile over a wider range of temperature and shearing conditions . Lower 600/300 rpm viscosity . Maintain 3/6 rpm viscosity . Higher 0.5 rpm Brookfield RVT viscosity 12 GELFAST™ Technology GELFAST™ Technology Faster development of rheological properties compared to other organophilic clay products 13 Hectatone’s Organophilic Hectorite Performance Attributes Significance of RHEOFLAT™ and GELFAST™ organophilic Hectorite products in today’s drilling environment . Greater emphasis on drilling efficiencies, increased rate of penetration (ROP), improved management of Equivalent Circulating Density (ECD), especially in low-toxicity mineral oils. Cost effective GELFAST™ organophilic Hectorite products allows for faster development of rheological properties improving fluid management. Cost effective RHEOFLAT™ organophilic Hectorite products exhibit minimal viscosity variation over a wide range of temperature and a flatter viscosity profile with lower viscosity without compromising gel strength. 14 Solution for Oilfield Drilling Challenges We believe the information is accurate, however, actual product and product specifications may vary and we cannot guarantee the accuracy of the information. This document does not form part of a contract for sale, and as such: (i) purchasers of products should not rely on any statements made herein; (ii) purchasers are responsible for conducting their own investigation to determine if products 15 are suitable for use; and (iii) there is no warranty, express or implied, including a warranty of merchantability and fitness for use. Hectatone Organoclay Plant 16 Nameplate capacity: 10,000 tons per year (practical capacity 24,000) Product mix: Hectorite, bentonite, sepiolite, and other clay rheology modifiers Contact: [email protected] 778-656-5820 17 .
Recommended publications
  • Characterization of Clays and Clay Minerals for Industrial Applications: Substitution Non-Natural Additives by Clays in UV Protection
    Characterization of Clays and Clay Minerals for Industrial Applications: Substitution non-Natural Additives by Clays in UV Protection Dissertation in fulfilment of the academic grade doctor rerum naturalium (Dr. rer. nat.) at the Faculty of Mathematics and Natural Sciences Ernst-Moritz-Arndt-University Greifswald HOANG-MINH Thao (Hoàng Thị Minh Thảo) born on 01.6.1979 in Quang Ninh, Vietnam Greifswald, Germany - 2006 Dekan: Prof. Dr. Klaus Fesser 1. Gutachter: PD. Dr. habil. Jörn Kasbohm 2. Gutachter: Prof. Roland Pusch Tag der Promotion: 17.11.2006 ii CONTENTS LIST OF TABLES . vi LIST OF FIGURES. vii ABBREVIATIONS . x STATEMENT OF ORIGINAL AUTHORSHIP (ERKLÄRUNG). xi ACKNOWLEDGMENTS . xii 1 INTRODUCTION . 1 2 POSSIBLE FUNCTIONS OF CLAYS, CLAY MINERALS IN UV PROTECTION . 2 2.1 Clays, clay minerals and sustainability in geosciences. 2 2.2 Ultraviolet radiation and human skin . 2 2.3 Actual substances as UV protection factor and their problems. 5 2.4 Pharmacy requirement in suncreams. 9 2.5 Clays, clay minerals and their application for human health. 11 2.6 Possible functions of clays, clay minerals in UV protection cream. 13 3 METHODOLOGY . 15 3.1 Clays and clay minerals analyses. 15 3.1.1 X-Ray diffraction. 17 3.1.2 TEM-EDX. 19 3.1.3 X-Ray fluorescence. 22 3.1.4 Mössbauer spectroscopy. 23 3.1.5 Atterberg sedimentation. 23 3.1.6 Dithionite treatment. 24 3.2 Non-clay samples analyses. 24 3.2.1 UV-measurement. 25 3.2.2 Light microscopy. 27 3.2.3 Skin model test by mouse-ear in vivo .
    [Show full text]
  • Hectorite: Synthesis, Modification, Assembly and Applications Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang
    Hectorite: Synthesis, modification, assembly and applications Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang To cite this version: Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang. Hectorite: Synthesis, modification, assembly and applications. Applied Clay Science, Elsevier, 2019, 177, pp.114-138. 10.1016/j.clay.2019.05.001. hal-02363196 HAL Id: hal-02363196 https://hal-cnrs.archives-ouvertes.fr/hal-02363196 Submitted on 2 Dec 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. 1 Hectorite:Synthesis, Modification, Assembly and Applications 2 3 Jing Zhanga, Chun Hui Zhoua,b,c*, Sabine Petitd, Hao Zhanga 4 5 a Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory 6 Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang 7 University of Technology, Hangzhou 310032, China 8 b Key Laboratory of Clay Minerals of Ministry of Land and Resources of the People's Republic of 9 China, Engineering Research Center of Non-metallic Minerals of Zhejiang Province, Zhejiang Institute 10 of Geology and Mineral Resource, Hangzhou 310007, China 11 c Qing Yang Institute for Industrial Minerals, You Hua, Qing Yang, Chi Zhou 242804, China 12 d Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS, Université de 13 Poitiers, Poitiers Cedex 9, France 14 15 Correspondence to: Prof.
    [Show full text]
  • The Nature of Laponite: Pure Hectorite Or a Mixture of Different Trioctahedral Phases?
    minerals Article The Nature of Laponite: Pure Hectorite or a Mixture of Different Trioctahedral Phases? George E. Christidis 1,*, Carlos Aldana 2, Georgios D. Chryssikos 3, Vassilis Gionis 3, Hussein Kalo 4 ID , Matthias Stöter 5, Josef Breu 5 and Jean-Louis Robert 6,† 1 School of Mineral Resources Engineering, Technical University of Crete, 73100 Chania, Greece 2 Institut des Sciences de la Terre d’Orléans, CNRS, 1A Rue de la Ferollerie, 45100 Orléans, France; [email protected] 3 Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Ave., 11635 Athens, Greece; [email protected] (G.D.C.); [email protected] (V.G.) 4 BYK-Chemie GmbH, Stadtwaldstrasse 44, 85368 Moosburg, Germany; [email protected] 5 Lehrstuhl für Anorganische Chimie I, Universität Bayreuth, 95440 Bayreuth, Germany; [email protected] (M.S.); [email protected] (J.B.) 6 IMPMC, Sorbonne Universités, UMR 7590, UPMC, CNRS, MNHN, IRD, 4 Place Jussieu, CEDEX 05, 75231 Paris, France; [email protected] * Correspondence: [email protected] † Deceased. Received: 30 June 2018; Accepted: 24 July 2018; Published: 26 July 2018 Abstract: A series of laponites and synthetic OH- and fluorinated hectorites prepared from hydrothermal and melting experiments at both industrial and laboratory scale were examined with XRD and FTIR (MIR and NIR) to determine their mineralogical composition and possible compositional heterogeneity. The end materials contained both Li- and Na-bearing phases. The industrial hydrothermal OH-smectites prepared at low temperatures consist of random mixed layer hectorite-stevensite-kerolite with about 40–50% hectorite layers, the remaining being stevensite and kerolite at roughly equal proportions.
    [Show full text]
  • AP42 Section: Reference: Title: 11.25 Clays, S. H. Patterson and H. H
    AP42 Section: 11.25 Reference: ~ Title: Clays, S. H. Patterson and H. H. Murray, Industrial Minerals And Rocks, Volume 1, Society Of Mining Engineers, New York, 1983. The term clay is somewhat ambiguous un- less specifically defined, because it is used in three ways: (I) as a diverse group of fine- grained minerals, (2) a5 a rock term, and (3) as a particle-size term. Actually, most persons using the term clay realize that it has several meanings, and in most instances they define it. As a rock term, clay is difficult to define be- cause of the wide variety of materials that com- ,me it; therefore, the definition must be gen- 'eral. Clay is a natural earthy, fine-grained ma- Iterial composed largely of a group of crystalline ;minerals known as the clay minerals. These minerals are hydrous silicates composed mainly of silica, alumina, and water. Several of these minerals also contain appreciable quantities of iron, alkalies, and alkaline earths. Many defini- tions state that a clay is plastic when wet. Most clay materials do have this property, but some clays are not plastic; for exaniple, halloysite and flint clay. As a particle-size term, clay is used for the category that includes the smallest particles. The maximum-size particles in the clay-size grade are defined differently on various grade scales. Soil imestigators and mineralogists gen- erally use 2 micrometers as the maximum size, whereas the widely used scale by Wentworth (1922) defines clay as material finer than ap proximately 4 micrometers. Some authorities find it convenient to'use the term clay'for any fine-grained, natural, earthy, argillaceous material (Grim.
    [Show full text]
  • Information to Users
    INFORMATION TO USERS This manuscript has been reproduced from the microfilm master. UMI films the tact directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter free, while others may be from any type o f computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand comer and continuing from left to right in equal sections with small overlaps. Each original is also photographed in one ocposure and is included in reduced form at the back of the book. Photographs included in the original manuscript have been reproduced xerographically in this copy. Higher quality 6” x 9” black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. UMI A Bell & Howell Information Company 300 North Zeeb Road, Arm Arbor MI 48106-1346 USA 313/761-4700 800/521-0600 A MECHANISTIC STUDY OF SORPTION OF IONIC ORGANIC COMPOUNDS ON PHYLLOSILICATES DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University By Sandip Chattopadhyay ***** The Ohio State University 1997 Dissertation Committee: Approved by Dr.
    [Show full text]
  • Quaternary Am
    SIAM 25, 17-18 October 2007 US/ICCA SIDS INITIAL ASSESSMENT PROFILE Chemical Organoclays Category Category 71011-26-2: Quaternary ammonium compounds, benzyl(hydrogenated tallow CAS numbers alkyl)dimethyl, chlorides, compounds with hectorite, (Benzyl monoalkyl chain quaternary and Chemical ammonium compound [B(Alk)2M] hectorite). Same as CAS numbers 94891-33-5 and Names 12691-60-0. 68953-58-2: Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts with bentonite, (Dialkyl chain quaternary ammonium compound [2M(2Alk)] bentonite). Same as CAS numbers 1340-69-8 and 73138-28-0. 71011-27-3: Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, compounds with hectorite, (Dialkyl chain quaternary ammonium compound [2M(2Alk)] hectorite). Same as CAS numbers 94891-31-3, 97280-96-1 and 12001-31-9. 68153-30-0: Quaternary ammonium compounds, benzylbis(hydrogenated tallow alkyl)methyl, chlorides, compounds with bentonite, (Benzyl dialkyl chain quaternary ammonium compound [B(2Alk)M] bentonite). Same as CAS numbers 121888-66-2 and 89749-77-9. 97952-68-6: Quaternary ammonium compounds, benzylbis(hydrogenated tallow alkyl)methyl, salts with montmorillonite, (Benzyl dialkyl chain quaternary ammonium compound [B(2Alk)M] montmorillonite). 71011-24-0, 71011-25-1, 121888-68-4 and 89749-78-0: Quaternary ammonium compounds, benzyl(hydrogenated tallow alkyl)dimethyl, chlorides, compounds with bentonite; (Benzyl monoalkyl chain quaternary ammonium compound [B(Alk)2M] bentonite). 91080-57-8 and 91080-56-7: Quaternary ammonium compounds, benzyl (hydrogenated tallow alkyl) dimethyl, chlorides, compounds with smectite (Benzyl monoalkyl chain quaternary ammonium compound [B(Alk)2M] smectite). Note that 91080-56-7 is [di-C10- C22 alkyl, dimethyl].
    [Show full text]
  • CIR Report Data Sheet
    Safety Assessment of Alkonium Clays as Used in Cosmetics Status: Final Report Release Date: April 26, 2016 Panel Meeting Date: March 31- April 1, 2016 The 2016 Cosmetic Ingredient Review Expert Panel members are: Chair, Wilma F. Bergfeld, M.D., F.A.C.P.; Donald V. Belsito, M.D.; Ronald A. Hill, Ph.D.; Curtis D. Klaassen, Ph.D.; Daniel C. Liebler, Ph.D.; James G. Marks, Jr., M.D.; Ronald C. Shank, Ph.D.; Thomas J. Slaga, Ph.D.; and Paul W. Snyder, D.V.M., Ph.D. The CIR Director is Lillian J. Gill, D.P.A. This report was prepared by Lillian C. Becker, Scientific Analyst/Writer. © Cosmetic Ingredient Review 1620 L Street, NW, Suite 1200 Washington, DC 20036-4702 ph 202.331.0651 fax 202.331.0088 [email protected] ABSTRACT This is a safety assessment of 8 alkonium clays, including stearalkonium bentonite, as used in cosmetics. These ingredients are reported to function as dispersing agents-nonsurfactant, emulsion stabilizers, and viscosity increasing agents-nonaqueous. The Cosmetic Ingredient Review (CIR) Expert Panel (Panel) reviewed the relevant data related to these ingredients. Information on other alkonium clay-derived ingredients, including quaternium-18 bentonite and benzyl-dimethyl hydrogenated tallow ammonium montmorillonite clay, were used for inference purposes. The Panel concluded that these alkonium clays are safe in cosmetics in the present practices of use and concentration described in this safety assessment when formulated to be non-irritating. INTRODUCTION This is a review of the available scientific literature and unpublished data relevant to assessing the safety of alkonium clays as used in cosmetics.
    [Show full text]
  • THERMOLUMINESCENCE of CLAY MINERALS G. Fbnnenb,Sso, Laborotor,Io Di Chimica Del,L,Eradiazi,Oni E Ch,Imica Nucleare,Ist,Itwto Di
    THE AMERICAN MINERALOGIST, VOL 52, SEPTEMBER_OCTOBER, 1967 THERMOLUMINESCENCE OF CLAY MINERALS G. FBnnenB,sso, Laborotor,io di Chimica del,l,eRadiazi,oni e Ch,imica Nucleare,Ist,itwto di. Chi,micaGenerale,Universi.td, di Roma, Roma, Italy. ArsrRAcr The thermoluminescencebetween - 180and 400'C of fundamental clay minerals groups kaolinite, halloysite, montmorillonite (bentonite, hectorite, pyrophyllite), talc and illite have been studiecl. The thermoluminescence of anhydrous and hydrated amorphous silica, quartz, cristobalite and alumina have also been studied. Each clay minerar group showed a characteristic glou' curve AII the thermoiuminescent peaks of the clay minerals, except the peak at 145'C in montmorillonite, coincided with the quartz and alumina peaks. Most of the observed thermoluminescent peaks are attributed to fundamental structural units of the clay minerals INrnolucrron The thermoluminescenceof igneous and sedimentary rocks minerals has been studied for many years (Angino and Groegler, 1962).Recently, glow curves,between 20 and 400'C of naturally and artificially irradiated clay mineralshave beenpublished (Siegel, Yaz and Ronca, 1966)but no correlationbetween thermoluminescence peaks and structure have been considered.In this work, the study of the thermoluminescenceof irradiated clay mineralsbetween - 180 and 400"C has been initiated to seeif a relationshipexists between glow curvesand chemicalcomposition and structure. Such knowledge is particularly useful for the proposed application of glow curves for archeologicaidating of antique ceramic pottery. Variousfundamental types of clay mineralshave beenstudied, and the dependencebetween glow curves from the type of structural unitl- has been ascertained. ExpBnrltpxt,lr, The materials under study u'ere clay minerals suppiied by the Ward's Natural Science (Rochester, N. Y ), bentonite (Ponza, Italy), illitic clay (M.
    [Show full text]
  • The Classification and Nomenclature of Clay Minerals
    THE CLASSIFICATION AND NOMENCLATURE OF CLAY MINERALS By R. C. MACKENZIE The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen [Received 21st April, 1959] ABSTRACT A report is given of the decisions reached at a meeting on the classifica- tion and nomenclature of clay minerals held under the auspices of Comit~ International pour l'Etude des Argiles at Brussels in July 1958. Tables of recently-proposed classification systems are included and some com- ments made on problems requiring agreement. The increasing interest in the classification and nomenclature of clay minerals over the last decade or so may be attributed largely to the development of investigational methods which enable a much more precise characterization of fine-grained minerals than was previously possible. In addition, however, the absence of any hard-and-fast rules as to new mineral nomenclature has led to a multiplicity of names through "new" minerals being described on the flimsiest of evidence, without regard as to whether they might be considered varieties of an already-established entity or indeed with- out, in many instances, adequate evidence of homogeneity. The resulting confusion is considerable, and the stage has now been reached when international agreement upon the main features of classification and nomenclature ought to be obtained. In an attempt to clarify the position representatives often countries met, under the" auspices of C.I.P.E.A., during the Journ6es Inter- nationales d'Etude des Argiles in Brussels in July, 1958.* Several decisions of interest were made at this meeting. (a) The following definition was adopted, subject to confirmation at the next meeting: Crystalline day minerals are hydrated silicates with layer or chain lattices consisting of sheets of silica tetrahedra arranged in hexagonal form condensed with octahedral layers; they are usually of small particle size.
    [Show full text]
  • Synthesis and Features of Luminescent Bromo- and Iodohectorite Nanoclay Materials
    applied sciences Article Synthesis and Features of Luminescent Bromo- and Iodohectorite Nanoclay Materials Hellen Silva Santos 1,2,*, Isabella Norrbo 1,2 ID , Tero Laihinen 1, Jari Sinkkonen 1, Ermei Mäkilä 2,3, José M. Carvalho 4, Pia Damlin 1,5, Hermi F. Brito 6, Jorma Hölsä 7 and Mika Lastusaari 1,5 1 Department of Chemistry, University of Turku, FI-20014 Turku, Finland; tijnor@utu.fi (I.N.); tero.laihinen@utu.fi (T.L.); jari.sinkkonen@utu.fi (J.S.); pia.damlin@utu.fi (P.D.); mika.lastusaari@utu.fi (M.L.) 2 Doctoral Programme in Physical and Chemical Sciences, University of Turku Graduate School (UTUGS), FI-20014 Turku, Finland; ermei.makila@utu.fi 3 Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland 4 Department of Applied Physics, Institute of Physics, University of São Paulo, São Paulo BR-05508090, Brazil; [email protected] 5 Turku University Centre for Materials and Surfaces (MatSurf), FI-20014 Turku, Finland 6 Department of Fundamental Chemistry, Institute of Chemistry, University of São Paulo, São Paulo BR-05508000, Brazil; [email protected] 7 Department of Physics, University of the Free State, Bloemfontein ZA-9300, South Africa; jorma.holsa@utu.fi * Correspondence: hellen.santos@utu.fi; Tel.: +358-29-450-3202 Received: 1 November 2017; Accepted: 27 November 2017; Published: 30 November 2017 Abstract: The smectites represent a versatile class of clay minerals with broad usage in industrial applications, e.g., cosmetics, drug delivery, bioimaging, etc. Synthetic hectorite Na0.7(Mg5.5Li0.3)[Si8O20](OH)4 is a distinct material from this class due to its low-cost production method that allows to design its structure to match better the applications.
    [Show full text]
  • Laboratory Study on Heterogeneous Decomposition of Methyl Chloroform on Various Standard Aluminosilica Clay Minerals As a Potential Tropospheric Sink S
    Laboratory study on heterogeneous decomposition of methyl chloroform on various standard aluminosilica clay minerals as a potential tropospheric sink S. Kutsuna, Lin Chen, K. Ohno, N. Negishi, K. Takeuchi, T. Ibusuki, K. Tokuhashi, A. Sekiya To cite this version: S. Kutsuna, Lin Chen, K. Ohno, N. Negishi, K. Takeuchi, et al.. Laboratory study on heterogeneous decomposition of methyl chloroform on various standard aluminosilica clay minerals as a potential tropospheric sink. Atmospheric Chemistry and Physics, European Geosciences Union, 2003, 3 (4), pp.1063-1082. hal-00295302 HAL Id: hal-00295302 https://hal.archives-ouvertes.fr/hal-00295302 Submitted on 21 Jul 2003 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Atmos. Chem. Phys., 3, 1063–1082, 2003 www.atmos-chem-phys.org/acp/3/1063/ Atmospheric Chemistry and Physics Laboratory study on heterogeneous decomposition of methyl chloroform on various standard aluminosilica clay minerals as a potential tropospheric sink S. Kutsuna, L. Chen, K. Ohno, N. Negishi, K. Takeuchi, T. Ibusuki, K. Tokuhashi, and A. Sekiya National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan Received: 31 January 2003 – Published in Atmos.
    [Show full text]
  • Minerals of the Montmorillonite Group Their Origin and Relation to Soils and Clays
    If yon no longer need this publication write to the Geological Survey in Washington for an official mailing label to use in returning it UNITED STATES DEPARTMENT OF THE INTERIOR MINERALS OF THE MONTMORILLONITE GROUP THEIR ORIGIN AND RELATION TO SOILS AND CLAYS GEOLOGICAL SURVEY PROFESSIONAL PAPER 205-B UNITED STATES DEPARTMENT OF THE INTERIOR Harold L. Ickes, Secretary GEOLOGICAL SURVEY W. E. Wrather, Director Professional Paper 205-B MINERALS OF THE MONTMORILLONITE GROUP THEIR ORIGIN AND RELATION TO SOILS AND CLAYS BY CLARENCE S. ROSS AND STERLING B. HENDRICKS Shorter contributions to general geology, 1943-44 (Pages 23-79) UNITED STATES GOVERNMENT PRINTING OFFICE WASHINGTON : 1945 For sale by the Superintendent of Documents, U. S. Government Printing Office Washington 25, D. C. - Price 55 cents CONTENTS Page Page Abstract............. ........................... 23 Mineralogy of the montmorillonite group—Continued. Introduction.......... ............................ 23 Derivation of formulas—Continued. Methods of study. ........................... 24 Saponite-hectorite series...................... 46 Previous work.... ........................... 24 Suggested formulas........................... 47 Acknowledgments. ........................... 25 Thermal studies...................................... 48 Nomenclature........ ........................... 25 Essential hydroxyl............................... 48 Montmorillonite.. ........................... 25 Interlayer water................................. 52 Beidellite........ ..........................
    [Show full text]