1 Hydrocarbon Emissions Characterization in the Colorado Front Range – a Pilot 2 Study 3 4 Gabrielle Pétron1,2, Gregory Frost1,2, Benjamin R
1 Hydrocarbon Emissions Characterization in the Colorado Front Range – A Pilot 2 Study 3 4 Gabrielle Pétron1,2, Gregory Frost1,2, Benjamin R. Miller1,2, Adam I. Hirsch1,3, Stephen A. 5 Montzka2, Anna Karion1,2, Michael Trainer2, Colm Sweeney1,2, Arlyn E. Andrews2, 6 Lloyd Miller5, Jonathan Kofler1,2, Amnon Bar-Ilan4, Ed J. Dlugokencky2, Laura 7 Patrick1,2, Charles T. (Tom) Moore Jr.6, Thomas B. Ryerson2, Carolina Siso1,2, William 8 Kolodzey7, Patricia M. Lang2, Thomas Conway2, Paul Novelli2, Kenneth Masarie2, 9 Bradley Hall2, Douglas Guenther1,2, Duane Kitzis1,2, John Miller1,2, David Welsh2, Dan 10 Wolfe2, William Neff2, and Pieter Tans2 11 12 13 1 Cooperative Institute for Research in Environmental Sciences, University of Colorado, 14 Boulder, Colorado, USA 15 2 National Oceanic and Atmospheric Administration, Earth System Research LaBoratory, 16 Boulder, Colorado, USA 17 3 now at the National RenewaBle Energy LaBoratory, Golden, Colorado, USA 18 4 ENVIRON International Corporation, Novato, California, USA 19 5 formerly with Science and Technology Corporation, Boulder, Colorado, USA 20 6Western Governors' Association, Fort Collins, Colorado, USA 21 7NOAA Hollings Scholar now at Clemson University 22 23 24 1 25 Abstract 26 The multi-species analysis of daily air samples collected at the NOAA Boulder 27 Atmospheric Observatory (BAO) in Weld County in northeastern Colorado since 2007 28 shows highly correlated alkane enhancements caused by a regionally distributed mix of 29 sources in the Denver-Julesburg Basin. To further characterize the emissions of methane 30 and non-methane hydrocarbons (propane, n-butane, i-pentane, n-pentane and benzene) 31 around BAO, a pilot study involving automobile-based surveys was carried out during 32 the summer of 2008.
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